CN105669127A - Architectural insulation board by utilization of industrial waste residue and preparation method thereof - Google Patents

Architectural insulation board by utilization of industrial waste residue and preparation method thereof Download PDF

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Publication number
CN105669127A
CN105669127A CN201610021156.7A CN201610021156A CN105669127A CN 105669127 A CN105669127 A CN 105669127A CN 201610021156 A CN201610021156 A CN 201610021156A CN 105669127 A CN105669127 A CN 105669127A
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parts
waste residue
kilograms
insulation board
utilization
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CN201610021156.7A
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CN105669127B (en
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王湖彬
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Shenzhen Zhongzhuang Construction Group Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to an architectural insulation board by the utilization of industrial waste residue. The architectural insulation board is prepared from the following ingredients (by weight): 55-65 parts of ordinary Portland cement, 8-10 parts of halloysite, 15-18 parts of electrolytic manganese residue, 8-10 parts of palygorskite, 18-20 parts of waste residue of zinc hydrometallurgy, 6-8 parts of pine tar, 8-10 parts of polycrystalline alumina fiber cotton, 6-8 parts of polypropylene staple fiber, 1-2 parts of dioctyl sodium sulfosuccinate, 3-4 parts of decyl glucoside, 55-60 parts of water, 1-2 parts of pentaerythritol stearate, 1-2 parts of ammonium sulfate, 5-6 parts of magnesium oxide and 5-6 parts of a polycarboxylate superplasticizer. According to the architectural insulation board by the utilization of industrial waste residue, energy is saved and waste is utilized. The architectural insulation board by the utilization of industrial waste residue has characteristics of high compressive strength, light weight, heat insulation, sound insulation, high temperature resistance, good fireproof performance and the like, especially has prominent compressive strength, and can be applied in building exterior-wall fire barrier and exterior wall insulation, etc.

Description

A kind of insulating board for building and its preparation method utilizing industrial residue
Technical field
The invention belongs to building material technical field, it is specially a kind of insulating board for building and its preparation method that utilize industrial residue.
Background technology
Concrete insulation board be whipping agent joined by cement-based gelling material, gather materials, during the finish mix such as adulterant, admixture and water starches, the lightweight cellular concrete sheet material become through mix and blend, casting, nature or vapor cure. Concrete insulation board has that weight is light, thermal and insulating performance good, the sound absorption good characteristic such as sound insulation, fire prevention, is applicable to exterior-wall heat insulation and fire-blocking belt thereof, meets the urgent needs to fire safety in external wall outer insulation market. Through research and development for many years, this technology is ripe gradually at present, and along with the increasing of Building Fire Protection dynamics, this product will progressively be widely applied, and becomes one of leading product of future architecture insulation. Phenolic aldehyde heat preserving plate is made up of phenol formaldehyde foam, phenol formaldehyde foam be a kind of novel do not fire, low cigarette lagging material of preventing fires, it adds, by resol, the closed pore rigid foam that whipping agent, solidifying agent and other auxiliary agent make. Extruded polystyrene board (xps plate) full name extruded polystyrene cystose, this material is aided with polymkeric substance heating mixing while, injecting catalyst with polystyrene resin, the rigid foam plate of then extrusion molding extrusion continuity closed pore foaming. Rock cotton board is taking basalt and other natural crystal etc. as main raw material, through high-temperature fusion fibroblast, adds appropriate binding agent, and solidification processing is made; Expansion polyphenyl plate (eps plate) full name polystyrene foam plate, this material is by the expandable polystyrene bead containing volatile liquid whipping agent, heats the shaping white solid with fine unicellular structure in a mold after heating pre-sending out.
Summary of the invention
The object of the invention is to overcome deficiency of the prior art, it is provided that a kind of excellent performance the insulating board for building and its preparation method that utilize industrial residue.
The present invention utilizes the insulating board for building of industrial residue, is be made up of the component of following weight part number: ordinary Portland cement 55~65 parts, halloysite 8~10 parts, electrolytic manganese residues 15~18 parts, polygorskite 8~10 parts, 18~20 parts, zinc hydrometallurgy waste residue, Stockholm tar 6~8 parts, 8~10 parts, polycrystalline alumina fiber cotton, polypropene staple 6~8 parts, two fourth sodium dioctyl sulfo 1~2 part, decyl glucoside 3~4 parts, 55~60 parts, water, pentaerythritol stearate 1~2 part, 1~2 part, ammonium sulfate, 5~6 parts, magnesium oxide, polycarboxylate water-reducer 5~6 parts.
As optimization, this utilizes the insulating board for building of industrial residue, is made up of the raw material of following weight part number: cotton 9 parts of ordinary Portland cement 60 parts, halloysite 9 parts, electrolytic manganese residues 16 parts, polygorskite 9 parts, 19 parts, zinc hydrometallurgy waste residue, Stockholm tar 7 parts, polycrystalline alumina fiber, polypropene staple 7 parts, two fourth sodium dioctyl sulfo 1.5 parts, decyl glucoside 3.5 parts, 58 parts, water, pentaerythritol stearate 1.5 parts, 1.5 parts, ammonium sulfate, 5.5 parts, magnesium oxide, polycarboxylate water-reducer 5.5 parts.
Prepare the method that the present invention utilizes the insulating board for building of industrial residue, comprise the following steps, by weight:
(1) by halloysite 9 parts, electrolytic manganese residues 16 parts, polygorskite 9 parts, 19 parts, zinc hydrometallurgy waste residue, the mixed powder A making particle diameter less than 10 μm is pulverized;
(2) by Stockholm tar 7 parts, cotton 9 parts of polycrystalline alumina fiber, polypropene staple 7 parts, mixed powder A, mix, obtain mixture B;
(3) by ordinary Portland cement 60 parts, 58 parts, water, mixture B, 40 minutes are stirred with 800~1000 revs/min of rotating speeds, then pentaerythritol stearate 1.5 parts, 1.5 parts, ammonium sulfate, 5.5 parts, magnesium oxide, polycarboxylate water-reducer 5.5 parts is added, stir 40 minutes with 600~800 revs/min of rotating speeds, obtain mixture C;
(4) by two fourth sodium dioctyl sulfo 1.5 parts, decyl glucoside 3.5 parts, join in mixture C, under 90~100 DEG C of conditions, stir 30 minutes with 400~600 revs/min; Then deliver to form-pressing machine press forming, send into steam-cured 5~7 hours of autoclave, cool and get final product.
The features such as the present invention utilizes the insulating board for building of industrial residue, energy-conserving profit waste, has ultimate compression strength height, light weight, heat insulating, sound insulation, and high temperature resistant, fire resistance is good. Especially there is outstanding ultimate compression strength; Can be applicable to the aspects such as external wall fire-blocking belt and exterior-wall heat insulation.
These insulating board for building performance index are done following inspection, specifically in table 1.
Table 1 related performance indicators assay
Index Embodiment 1 Embodiment 2 Embodiment 3
Volume density 433kg/m3 435kg/m3 439kg/m3
Ultimate compression strength >= 6.5MPa 6.3MPa 6.4MPa
Folding strength >= 2.3MPa 2.2MPa 2.2MPa
Thermal conductivity (normal temperature)≤ 0.065W/m.K 0.065W/m.K 0.066W/m.K
Sound-damping qualities >= 59db 58db 59db
Combustionproperty A level is not fired A level is not fired A level is not fired
Embodiment
The invention will be further described for embodiment given below plan; but can not be interpreted as it is limiting the scope of the invention; those skilled in the art according to content of the present invention to the improvement of some non-intrinsically safes of the present invention and adjustment, still belong to protection scope of the present invention.
Embodiment 1:
(1) by halloysite 9 kilograms, electrolytic manganese residues 16 kilograms, polygorskite 9 kilograms, 19 kilograms, zinc hydrometallurgy waste residue, the mixed powder A making particle diameter less than 10 μm is pulverized;
(2) Fibre diameter Stockholm tar 7 kilograms, Suzhou De Xin ceramic new material company limited produced: 3~12mm polypropene staple 7 kilograms that cotton 9 kilograms of 2~4 μm of polycrystalline alumina fibers, Beijing Peng Yang novel building company limited produce, mixed powder A, mix, obtain mixture B;
(3) by 425 ordinary Portland cement 60 kilograms, 58 kilograms, water, mixture B, 40 minutes are stirred with 800~1000 revs/min of rotating speeds, then the wp12312 polycarboxylate water-reducer 5.5 kilograms of pentaerythritol stearate 1.5 kilograms, 1.5 kilograms, ammonium sulfate, 5.5 kilograms, magnesium oxide, the production of Shanghai Wei Xi Science and Technology Ltd. is added, stir 40 minutes with 600~800 revs/min of rotating speeds, obtain mixture C;
(4) by two fourth sodium dioctyl sulfo 1.5 kilograms, decyl glucoside 3.5 kilograms, join in mixture C, under 90~100 DEG C of conditions, stir 30 minutes with 400~600 revs/min; Then deliver to form-pressing machine press forming, send into steam-cured 5~7 hours of autoclave, cool and get final product.
Embodiment 2:
(1) by halloysite 10 kilograms, electrolytic manganese residues 18 kilograms, polygorskite 10 kilograms, 20 kilograms, zinc hydrometallurgy waste residue, the mixed powder A making particle diameter less than 10 μm is pulverized;
(2) Fibre diameter Stockholm tar 8 kilograms, Suzhou De Xin ceramic new material company limited produced: 3~12mm polypropene staple 8 kilograms that cotton 10 kilograms of 2~4 μm of polycrystalline alumina fibers, Beijing Peng Yang novel building company limited produce, mixed powder A, mix, obtain mixture B;
(3) by 425 ordinary Portland cement 65 kilograms, 60 kilograms, water, mixture B, 40 minutes are stirred with 800~1000 revs/min of rotating speeds, then the wp12312 polycarboxylate water-reducer 6 kilograms of pentaerythritol stearate 2 kilograms, 2 kilograms, ammonium sulfate, 6 kilograms, magnesium oxide, the production of Shanghai Wei Xi Science and Technology Ltd. is added, stir 40 minutes with 600~800 revs/min of rotating speeds, obtain mixture C;
(4) by two fourth sodium dioctyl sulfo 2 kilograms, decyl glucoside 4 kilograms, join in mixture C, under 90~100 DEG C of conditions, stir 30 minutes with 400~600 revs/min; Then deliver to form-pressing machine press forming, send into steam-cured 5~7 hours of autoclave, cool and get final product.
Embodiment 3:
(1) by halloysite 8 kilograms, electrolytic manganese residues 15 kilograms, polygorskite 8 kilograms, 18 kilograms, zinc hydrometallurgy waste residue, the mixed powder A making particle diameter less than 10 μm is pulverized;
(2) Fibre diameter Stockholm tar 6 kilograms, Suzhou De Xin ceramic new material company limited produced: 3~12mm polypropene staple 6 kilograms that cotton 8 kilograms of 2~4 μm of polycrystalline alumina fibers, Beijing Peng Yang novel building company limited produce, mixed powder A, mix, obtain mixture B;
(3) by 425 ordinary Portland cement 55 kilograms, 55 kilograms, water, mixture B, 40 minutes are stirred with 800~1000 revs/min of rotating speeds, then the wp12312 polycarboxylate water-reducer 5 kilograms of pentaerythritol stearate 1 kilogram, 1 kilogram, ammonium sulfate, 5 kilograms, magnesium oxide, the production of Shanghai Wei Xi Science and Technology Ltd. is added, stir 40 minutes with 600~800 revs/min of rotating speeds, obtain mixture C;
(4) by two fourth sodium dioctyl sulfo 1 kilogram, decyl glucoside 3 kilograms, join in mixture C, under 90~100 DEG C of conditions, stir 30 minutes with 400~600 revs/min; Then deliver to form-pressing machine press forming, send into steam-cured 5~7 hours of autoclave, cool and get final product.

Claims (3)

1. one kind utilizes the insulating board for building of industrial residue, it is characterized in that, it it is be made up of the component of following weight part number: ordinary Portland cement 55~65 parts, halloysite 8~10 parts, electrolytic manganese residues 15~18 parts, polygorskite 8~10 parts, 18~20 parts, zinc hydrometallurgy waste residue, Stockholm tar 6~8 parts, 8~10 parts, polycrystalline alumina fiber cotton, polypropene staple 6~8 parts, two fourth sodium dioctyl sulfo 1~2 part, decyl glucoside 3~4 parts, 55~60 parts, water, pentaerythritol stearate 1~2 part, 1~2 part, ammonium sulfate, 5~6 parts, magnesium oxide, polycarboxylate water-reducer 5~6 parts.
2. utilize the insulating board for building of industrial residue according to claim 1, it is characterized in that, it is be made up of the raw material of following weight part number: cotton 9 parts of ordinary Portland cement 60 parts, halloysite 9 parts, electrolytic manganese residues 16 parts, polygorskite 9 parts, 19 parts, zinc hydrometallurgy waste residue, Stockholm tar 7 parts, polycrystalline alumina fiber, polypropene staple 7 parts, two fourth sodium dioctyl sulfo 1.5 parts, decyl glucoside 3.5 parts, 58 parts, water, pentaerythritol stearate 1.5 parts, 1.5 parts, ammonium sulfate, 5.5 parts, magnesium oxide, polycarboxylate water-reducer 5.5 parts.
3. prepare the method for the insulating board for building utilizing industrial residue described in claim 2 for one kind, it is characterised in that, comprise the following steps, by weight:
(1) by halloysite 9 parts, electrolytic manganese residues 16 parts, polygorskite 9 parts, 19 parts, zinc hydrometallurgy waste residue, the mixed powder A making particle diameter less than 10 μm is pulverized;
(2) by Stockholm tar 7 parts, cotton 9 parts of polycrystalline alumina fiber, polypropene staple 7 parts, mixed powder A, mix, obtain mixture B;
(3) by ordinary Portland cement 60 parts, 58 parts, water, mixture B, 40 minutes are stirred with 800~1000 revs/min of rotating speeds, then pentaerythritol stearate 1.5 parts, 1.5 parts, ammonium sulfate, 5.5 parts, magnesium oxide, polycarboxylate water-reducer 5.5 parts is added, stir 40 minutes with 600~800 revs/min of rotating speeds, obtain mixture C;
(4) by two fourth sodium dioctyl sulfo 1.5 parts, decyl glucoside 3.5 parts, join in mixture C, under 90~100 DEG C of conditions, stir 30 minutes with 400~600 revs/min; Then deliver to form-pressing machine press forming, send into steam-cured 5~7 hours of autoclave, cool and get final product.
CN201610021156.7A 2016-01-13 2016-01-13 A kind of insulating board for building of utilization industrial residue and preparation method thereof Active CN105669127B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336611A (en) * 2016-08-27 2017-01-18 赵碧华 Energy-saving light building plate and preparation method thereof
CN109081659A (en) * 2018-08-08 2018-12-25 赵丽敏 A kind of heat insulating board and preparation method thereof with fire-proof function
CN110482950A (en) * 2019-08-20 2019-11-22 湖州师范学院 A kind of low-cost high-strength insulation board and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390968A (en) * 2011-08-16 2012-03-28 岳建伟 Heat insulation fireproofing honeycomb cement board and preparation method thereof
CN102690094A (en) * 2012-05-17 2012-09-26 同济大学 Energy-saving and waste-utilizing concrete block or board and production method thereof
CN102850081A (en) * 2012-08-24 2013-01-02 镇江中瑞节能科技有限公司 Foam cement insulation board containing industrial solid waste and preparation method thereof
CN103833413A (en) * 2013-12-13 2014-06-04 中国神华能源股份有限公司 Foam cement warming plate, and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390968A (en) * 2011-08-16 2012-03-28 岳建伟 Heat insulation fireproofing honeycomb cement board and preparation method thereof
CN102690094A (en) * 2012-05-17 2012-09-26 同济大学 Energy-saving and waste-utilizing concrete block or board and production method thereof
CN102850081A (en) * 2012-08-24 2013-01-02 镇江中瑞节能科技有限公司 Foam cement insulation board containing industrial solid waste and preparation method thereof
CN103833413A (en) * 2013-12-13 2014-06-04 中国神华能源股份有限公司 Foam cement warming plate, and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336611A (en) * 2016-08-27 2017-01-18 赵碧华 Energy-saving light building plate and preparation method thereof
CN109081659A (en) * 2018-08-08 2018-12-25 赵丽敏 A kind of heat insulating board and preparation method thereof with fire-proof function
CN110482950A (en) * 2019-08-20 2019-11-22 湖州师范学院 A kind of low-cost high-strength insulation board and preparation method thereof

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Inventor after: Zhuang Zhong

Inventor after: Zhuang Zhannuo

Inventor after: Zhao Haifeng

Inventor after: Zeng Fanwei

Inventor after: Zhuang Guochan

Inventor after: Lacquer Chunhua

Inventor after: Liu Xuhui

Inventor after: Huang Shuobin

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Denomination of invention: The invention relates to a building insulation board using industrial waste residue and a preparation method thereof

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