CN102390968A - Heat insulation fireproofing honeycomb cement board and preparation method thereof - Google Patents
Heat insulation fireproofing honeycomb cement board and preparation method thereof Download PDFInfo
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- CN102390968A CN102390968A CN2011102343055A CN201110234305A CN102390968A CN 102390968 A CN102390968 A CN 102390968A CN 2011102343055 A CN2011102343055 A CN 2011102343055A CN 201110234305 A CN201110234305 A CN 201110234305A CN 102390968 A CN102390968 A CN 102390968A
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- honeycomb cement
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- 239000004568 cement Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000009413 insulation Methods 0.000 title abstract description 7
- 238000004079 fireproofing Methods 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 12
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 7
- 239000011398 Portland cement Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 17
- 150000002978 peroxides Chemical class 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- -1 Zinic stearas Substances 0.000 claims description 7
- 239000000976 ink Substances 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229920005610 lignin Polymers 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- 235000012255 calcium oxide Nutrition 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 230000032683 aging Effects 0.000 abstract description 7
- 239000004566 building material Substances 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 235000012907 honey Nutrition 0.000 abstract 1
- 230000003020 moisturizing effect Effects 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 239000012774 insulation material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229920006328 Styrofoam Polymers 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000011381 foam concrete Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000008261 styrofoam Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004795 extruded polystyrene foam Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 210000003934 vacuole Anatomy 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Building Environments (AREA)
Abstract
The invention belongs to the technical field of building materials and in particular relates to a heat insulation fireproofing cement board and a preparation method thereof. The cement board is made from master batch and auxiliary materials, wherein the master batch is fast hardening sulphate aluminium cement and ordinary Portland cement; and the auxiliary materials are composed of a waterproofing agent, a brightening agent, a foaming agent, a water reducing agent, an accelerating agent, a moisturizing agent, fibres and water. The fireproofing heat insulation honey cement board provided by the invention has the advantages of good fireproofing thermal insulation property, aging resistance, low deformation coefficient, colour approximating to the colour of a wall body and high bonding strength with the wall body; and the preparation method is simple and is convenient to operate.
Description
Technical field
The invention belongs to building material technical field, particularly a kind of insulated fire honeycomb cement plate and preparation method thereof.
Background technology
Existing external wall wall heat insulation material usually adopts organic materialss such as polystyrene foamed plastics, rigid polyurethane fat vacuole foam plastics; Though excellent thermal insulation performance; But such lagging material very easily burns; And produce with a large amount of poison gases and flue gas during burning, bring exceptional hardship, cause casualties and property damage to rescue work of extinguishing fire.Simultaneously such organic insulation material also exist be prone to aging, poor stability, poor durability, with shortcomings such as the body of wall cohesive strength is low.In the last few years; Building fire frequently takes place; People are had higher requirement to the fire resistance of lagging material, inorganic heat insulation material because of have that fire resistance is good, ageing-resistant, deformation coefficient is little and approaching with body of wall, with body of wall cohesive strength advantages of higher, cause people's extensive concern.The research and development thermal conductivity replaces styrofoam and extruded sheet less than 0.06w/m.k and the lower honeycomb cement plate of cost, is prone to aging, poor stability, poor durability, becomes a direction of inorganic heat insulation material research with shortcomings such as the body of wall cohesive strength are low thereby solve existing warming plate.A kind of cellular concrete is provided in the one Chinese patent application 200710055329.8, can have solved the problem that material of construction such as present brick or concrete can not satisfy lightweight in the building, energy-saving and environmental protection needs.But the problem one that this invention exists is the honeycomb agent of using to be formed complicated; Said honeycomb agent is that ydrogen peroxide 50, water and other material (in trolamine, Quilonum Retard, lithium chloride, boric acid, Hydrocerol A, tartrate, calcium lignin sulphonate, sodium lignosulfonate and the magnesium lignosulfonate a kind of) are formed; Because of ydrogen peroxide 50 has strong oxidizing property; Can react with other material, cause the useful effect of ydrogen peroxide 50 and other material to reduce, also be unfavorable for the quality control of cellular concrete material; The 2nd, production technique is unreasonable, can only be used for production building block or body of wall, is difficult to produce density less than 200kg/m
3Sheet material; The 3rd, its thermal conductivity is bigger, and through embodiment is measured, thermal conductivity is all greater than 0.08 W/ (m.K).Application number is in 200910305328.3 the application, to use a large amount of glass beads, exist weight big, be prone to the shortcoming broken, that water-intake rate is high.
Summary of the invention
The object of the present invention is to provide a kind of insulated fire honeycomb cement plate and preparation method thereof, described insulated fire honeycomb cement plate has overcome present inorganic fireproofing insulation material from shortcoming great, that water-intake rate is high, thermal conductivity is big, easy to crack.
The technical scheme that the present invention adopts is following:
Insulated fire honeycomb cement plate is processed by masterbatch and auxiliary material, and wherein, the weight of masterbatch is formed as follows:
Quick hardening sulphoaluminate cement: 20-70 part; Ordinary Portland cement: 30-80 part;
The weight of auxiliary material is formed as follows:
Water-resisting agent: 1-3.5 part;
Brightener: 3-5 part;
Whipping agent: 5-12 part;
Water reducer: 0.1-1 part;
Accelerating chemicals: 1-3.5 part;
Wetting Agent for Printing Inks: 0.05-0.3 part;
Fiber: 0.2-1 part;
Water: 42-55 part.
Water-resisting agent is calcium stearate, Zinic stearas, Magnesium Stearate or organosilicon powder.
Described water reducer is calcium lignin sulphonate, sodium lignosulfonate or magnesium lignosulfonate.
Whipping agent is the ydrogen peroxide 50 of mass concentration more than 25%.
Brightener is light calcined magnesia, unslaked lime or wollastonite powder.
Accelerating chemicals is a powdery sodium silicate.
Wetting Agent for Printing Inks is a CMC 99.5.
Fiber is the polypropylene fibre of length 3-8mm.
The present invention also provides a kind of preparation method of preferred said insulated fire honeycomb cement plate, earlier masterbatch and other auxiliary materials except water, whipping agent is mixed; Add entry afterwards and mix, add whipping agent and mix, foaming forms the honeycomb cement block, cuts apart to obtain the honeycomb cement plate.
Concrete, step is following:
1) takes by weighing masterbatch and other auxiliary materials except water, whipping agent in proportion, mix;
2) take by weighing water in proportion, be added to 1) stir 1-5min in the material that mixes and obtain uniform slurry;
3) take by weighing whipping agent in proportion, be added to 2) uniformly in the slurry, stir 0.5-2min;
4) 3) material that stirs is cast in and begins foaming in the mould, and 2-5h forms the honeycomb cement block;
5) on request the honeycomb cement block is divided into the honeycomb cement plate.
The present invention be with quick hardening sulphoaluminate cement, ordinary Portland cement as gelling material, add other auxiliary materials and stir jointly, pour into mould and can form the honeycomb cement block, and the cutting form.Wet concentration is used common drinking water described in the present invention, and temperature is controlled at 20-45 ℃.
The honeycomb cement plate very high to waterproof requirement can carry out immersion treatment to the honeycomb cement plate in organic silicon solution.
In order to solve the problem that prior art exists, thinking at first is that technology is adjusted among the present invention, because ydrogen peroxide 50 and cement reaction are very fast; With whipping process after material such as cement contacts in just begin foaming; Not only waste ydrogen peroxide 50, and there is the uneven problem of pore opening in the cellular concrete that stirs, volume density is higher; Thermal conductivity strengthens, and the technology that therefore adds ydrogen peroxide 50 earlier is difficult to produce density less than 200kg/m
3Sheet material.
From raw material; Because reaction is very fast between ydrogen peroxide 50 and the cement, can discharge a large amount of heats, temperature is up to 80 ℃; Moisture under this condition in the cement bubble evaporates very soon; Cause the perforation of cement bubble cracking, make the product dry shrinkage and cracking, the application solves cement bubble rimose problem through adding accelerating chemicals, wetting Agent for Printing Inks and fiber.In addition, the honeycomb cement plate requires the lighter and lower thermal conductivity of weight, and stopping composition such as heavy addition flyash is disadvantageous to the finished product in the production of honeycomb cement plate, and therefore, the application does not add stopping composition such as flyash.In addition, the cellular cellular body that forms is case type behind the adding water-resisting agent, and water not porous wherein reaches the hydrophobic effect.Insulated fire honeycomb cement plate main raw of the present invention is made up of inorganic materials, therefore has uninflammability; Since use quick hardening sulphoaluminate cement as gelling material, common after cast 4-6 h intensity reaches the 60-70% of design label, initial hardening self-support moulding.
The described insulated fire honeycomb cement of the application plate has the following advantages: early stage bending and compressive strength is high, not retraction of later strength; Do not chap; Making processes is easy.Lightweight, high-strength, high-efficiency insulated, heat insulation, sound insulation, from waterproof, do not fire, shock resistance, shrinking percentage be little; Its thermal conductivity can be controlled in 0.03-0.06W/ (m.K); Ultimate compression strength can change between 0.1-0.8MPa, and volume density can be controlled in 100-200 (may extend to 250) kg/m
3, the diameter that forms the honeycomb foam is 1-5mm, and is disconnected each other lockedin air space crowd; After burning 120 min with 900 ℃ of high-temperature bakings of blowtorch, lost integrity and heat insulating ability do not have splendid fire-resistant and heat-proof quality.
Production and construct very convenient, both can produce in factory, again can field fabrication.During construction, ability plane, saw, nail etc. as the fire-blocking belt, can be constructed according to the constructional method of XPS, save construction period to greatest extent; As wallboard can with the supporting use of any structure system, reduce the weight of buildings, equal area or volume; The weight of product material of the present invention is merely 1/8th of brick wall; Alleviate load significantly, reduced the bearing capacity of concrete foundation and steel frame, reduced the consumption of other material.
Long service life, the product material weather resistance of made can reach 80 years, and when 200 ℃ of high temperature, 72h is indeformable, and is aging.And now the warming plate that generally adopts of construction market, two-sided color steel, in sandwich styrofoam, back (temperature is at 70 ℃) styrofoam distortion of being heated, color steel promptly fades at solar irradiation, wind, the 7-10 that drenches with rain, and has increased the maintenance cost in house.
The present invention has following advantage with respect to prior art:
Fireproof heat insulating honeycomb cement plate provided by the invention has advantage in light weight, that the fireproof heat insulating performance is good, ageing-resistant, deformation coefficient is little, and is approaching with body of wall, cohesive strength is high; The preparation method simply is convenient to operation.
Embodiment
Below with specific embodiment technical scheme of the present invention is described, but protection scope of the present invention is not limited thereto:
The weight proportion of composing of the masterbatch of embodiment 1-10 and auxiliary material sees following table for details:
The honeycomb foam diameter of the fire prevention heatproof honeycomb cement plate that obtains is 1-8mm.
Adopting the concentration of ydrogen peroxide 50 among the embodiment is 27.5%.
Cellulosic length is 3-8mm.
Used all raw materials are all the commercially available prod.
The preparation method of said fire prevention heatproof honeycomb cement plate may further comprise the steps:
(1) takes by weighing masterbatch, water-resisting agent, brightener, water reducer, accelerating chemicals, wetting Agent for Printing Inks, fiber in proportion, and in whisking appliance, stir;
(2) take by weighing water in proportion, be added in the material that (1) stir and stir, churning time 1-5 minute, be uniform slurry until stirring;
(3) take by weighing ydrogen peroxide 50 in proportion, be added in the slurry that stirs of (2) step, and stir fast, stirring velocity more than 800 commentaries on classics/min, churning time 0.5-2 minute, until stirring;
(4) material that stirs (3) in the casting mold, begins foaming rapidly, and 2-5h forms the honeycomb cement block;
(5) be divided into the honeycomb cement plate to the honeycomb cement block that reaches certain intensity as requested.
(6) the honeycomb cement plate very high to waterproof requirement can carry out immersion treatment to the honeycomb cement plate in organic silicon solution.
After with 900 ℃ of high temperature of blowtorch 120 min being burnt in embodiment 1-10 product baking, all not lost integrity and heat insulating ability; When 200 ℃ of high temperature, can both guarantee that 72h is indeformable, aging.
Claims (9)
1. insulated fire honeycomb cement plate is characterized in that, described cement plate is processed by masterbatch and auxiliary material, and wherein, the weight of masterbatch is formed as follows:
Quick hardening sulphoaluminate cement: 20-70 part;
Ordinary Portland cement: 30-80 part;
The weight of auxiliary material is formed as follows:
Water-resisting agent: 1-3.5 part;
Brightener: 3-5 part;
Whipping agent: 5-12 part;
Water reducer: 0.1-1 part;
Accelerating chemicals: 1-3.5 part;
Wetting Agent for Printing Inks: 0.05-0.3 part;
Fiber: 0.2-1 part;
Water: 42-55 part.
2. insulated fire honeycomb cement plate as claimed in claim 1 is characterized in that water-resisting agent is calcium stearate, Zinic stearas, Magnesium Stearate or organosilicon powder; Described water reducer is calcium lignin sulphonate, sodium lignosulfonate or magnesium lignosulfonate.
3. insulated fire honeycomb cement plate as claimed in claim 1 is characterized in that, whipping agent is the ydrogen peroxide 50 of mass concentration more than 25%.
4. insulated fire honeycomb cement plate as claimed in claim 1 is characterized in that brightener is light calcined magnesia, unslaked lime or wollastonite powder; Accelerating chemicals is a powdery sodium silicate; Wetting Agent for Printing Inks is a CMC 99.5.
5. insulated fire honeycomb cement plate as claimed in claim 1 is characterized in that fiber is the polypropylene fibre of length 3-8mm.
6. the preparation method of the said insulated fire honeycomb cement of claim 1 plate is characterized in that, earlier masterbatch and other auxiliary materials except water, whipping agent is mixed; Add entry afterwards and mix, add whipping agent and mix, foaming forms the honeycomb cement block, cuts apart to obtain the honeycomb cement plate.
7. like the preparation method of the said insulated fire honeycomb cement of claim 6 plate, it is characterized in that step is following:
1) takes by weighing masterbatch and other auxiliary materials except water, whipping agent in proportion, mix;
2) take by weighing water in proportion, be added to 1) stir 1-5min in the material that mixes and obtain uniform slurry;
3) take by weighing whipping agent in proportion, be added to 2) uniformly in the slurry, stir 0.5-2min;
4) 3) material that stirs is cast in and begins foaming in the mould, and 2-5h forms the honeycomb cement block;
5) on request the honeycomb cement block is divided into the honeycomb cement plate.
8. the preparation method of insulated fire honeycomb cement plate as claimed in claim 7 is characterized in that, the honeycomb cement plate is carried out immersion treatment in organic silicon solution.
9. like the preparation method of the described insulated fire honeycomb cement of one of claim 6-8 plate, it is characterized in that water-resisting agent is calcium stearate, Zinic stearas, Magnesium Stearate or organosilicon powder; Water reducer is calcium lignin sulphonate, sodium lignosulfonate or magnesium lignosulfonate; Whipping agent is the ydrogen peroxide 50 of mass concentration more than 25%; Brightener is light calcined magnesia, unslaked lime or wollastonite powder; Accelerating chemicals is a powdery sodium silicate; Wetting Agent for Printing Inks is a CMC 99.5; Fiber is the polypropylene fibre of length 3-8mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110234305 CN102390968B (en) | 2011-08-16 | 2011-08-16 | Heat insulation fireproofing honeycomb cement board and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110234305 CN102390968B (en) | 2011-08-16 | 2011-08-16 | Heat insulation fireproofing honeycomb cement board and preparation method thereof |
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| CN102390968A true CN102390968A (en) | 2012-03-28 |
| CN102390968B CN102390968B (en) | 2013-06-12 |
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| CN102701649A (en) * | 2012-05-14 | 2012-10-03 | 杭州正博新型建筑材料有限公司 | Inorganic cement foam insulation board and preparation method of inorganic cement foam insulation board |
| CN102807332A (en) * | 2012-07-23 | 2012-12-05 | 浙江八达建设集团有限公司 | Self-waterproof sulphoaluminate cement and preparation method of concrete by using self-waterproof sulphoaluminate cement |
| CN103223750A (en) * | 2013-04-25 | 2013-07-31 | 广州新绿环阻燃装饰材料有限公司 | Fiber cement composite plate production process |
| CN104478356A (en) * | 2014-11-27 | 2015-04-01 | 罗海军 | Fiber porous plate |
| CN104692735A (en) * | 2013-12-06 | 2015-06-10 | 金海龙 | Fireproof A1 level inorganic interior and exterior wall heat insulation board and production method thereof |
| CN104944895A (en) * | 2015-06-11 | 2015-09-30 | 江西中科新建材有限公司 | KY inorganic foaming heat-insulating plate and preparation method thereof |
| CN105084808A (en) * | 2015-07-29 | 2015-11-25 | 天津城建大学 | Powder waterproof agent special for raw soil materials and preparing method thereof |
| CN105174820A (en) * | 2015-08-27 | 2015-12-23 | 滁州市瑞景园林建设有限公司 | Fireproof insulation board |
| CN105272019A (en) * | 2015-11-21 | 2016-01-27 | 陆仲权 | Heat insulation cement and preparation method thereof |
| CN105541267A (en) * | 2015-12-09 | 2016-05-04 | 文登蓝岛建筑工程有限公司 | Environmental-protection thermal-insulation board and preparation method thereof |
| CN105669127A (en) * | 2016-01-13 | 2016-06-15 | 王湖彬 | Architectural insulation board by utilization of industrial waste residue and preparation method thereof |
| CN106085366A (en) * | 2016-06-13 | 2016-11-09 | 河南大学 | Phase-change material, light phase transition honeycomb concrete plate and preparation method thereof |
| CN107514091A (en) * | 2017-08-25 | 2017-12-26 | 太仓卡斯特姆新材料有限公司 | A kind of exterior wall fire-retardant heat insulation composite |
| CN109020350A (en) * | 2018-09-30 | 2018-12-18 | 安徽远山电力工程有限公司 | A kind of heat insulation fireproofing honeycomb cement board and preparation method thereof |
| CN109206082A (en) * | 2018-09-30 | 2019-01-15 | 安徽远山电力工程有限公司 | A kind of high-strength composite fiber reinforcement honeycomb cement self-heat conserving filled wall |
Citations (3)
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| CN102701649A (en) * | 2012-05-14 | 2012-10-03 | 杭州正博新型建筑材料有限公司 | Inorganic cement foam insulation board and preparation method of inorganic cement foam insulation board |
| CN102807332A (en) * | 2012-07-23 | 2012-12-05 | 浙江八达建设集团有限公司 | Self-waterproof sulphoaluminate cement and preparation method of concrete by using self-waterproof sulphoaluminate cement |
| CN102807332B (en) * | 2012-07-23 | 2014-10-08 | 浙江八达建设集团有限公司 | Self-waterproof sulphoaluminate cement and preparation method of concrete by using self-waterproof sulphoaluminate cement |
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| CN105084808A (en) * | 2015-07-29 | 2015-11-25 | 天津城建大学 | Powder waterproof agent special for raw soil materials and preparing method thereof |
| CN105174820A (en) * | 2015-08-27 | 2015-12-23 | 滁州市瑞景园林建设有限公司 | Fireproof insulation board |
| CN105272019A (en) * | 2015-11-21 | 2016-01-27 | 陆仲权 | Heat insulation cement and preparation method thereof |
| CN105541267A (en) * | 2015-12-09 | 2016-05-04 | 文登蓝岛建筑工程有限公司 | Environmental-protection thermal-insulation board and preparation method thereof |
| CN105669127A (en) * | 2016-01-13 | 2016-06-15 | 王湖彬 | Architectural insulation board by utilization of industrial waste residue and preparation method thereof |
| CN106085366A (en) * | 2016-06-13 | 2016-11-09 | 河南大学 | Phase-change material, light phase transition honeycomb concrete plate and preparation method thereof |
| CN106085366B (en) * | 2016-06-13 | 2020-01-21 | 河南大学 | Phase-change material, light phase-change honeycomb concrete plate and preparation method thereof |
| CN107514091A (en) * | 2017-08-25 | 2017-12-26 | 太仓卡斯特姆新材料有限公司 | A kind of exterior wall fire-retardant heat insulation composite |
| CN109020350A (en) * | 2018-09-30 | 2018-12-18 | 安徽远山电力工程有限公司 | A kind of heat insulation fireproofing honeycomb cement board and preparation method thereof |
| CN109206082A (en) * | 2018-09-30 | 2019-01-15 | 安徽远山电力工程有限公司 | A kind of high-strength composite fiber reinforcement honeycomb cement self-heat conserving filled wall |
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