CN105666904B - The technique and its device of graphene tire are produced in a kind of coproduction - Google Patents
The technique and its device of graphene tire are produced in a kind of coproduction Download PDFInfo
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- CN105666904B CN105666904B CN201610211647.8A CN201610211647A CN105666904B CN 105666904 B CN105666904 B CN 105666904B CN 201610211647 A CN201610211647 A CN 201610211647A CN 105666904 B CN105666904 B CN 105666904B
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 140
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 122
- 238000000034 method Methods 0.000 title claims abstract description 34
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 99
- 239000007789 gas Substances 0.000 claims abstract description 78
- 239000001257 hydrogen Substances 0.000 claims abstract description 71
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 71
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 claims abstract description 69
- 239000003245 coal Substances 0.000 claims abstract description 67
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 38
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 36
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 32
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims abstract description 30
- 239000010883 coal ash Substances 0.000 claims abstract description 29
- 230000005611 electricity Effects 0.000 claims abstract description 16
- 239000010881 fly ash Substances 0.000 claims abstract description 11
- 239000006229 carbon black Substances 0.000 claims abstract description 10
- CYKMNKXPYXUVPR-UHFFFAOYSA-N [C].[Ti] Chemical compound [C].[Ti] CYKMNKXPYXUVPR-UHFFFAOYSA-N 0.000 claims description 63
- 229960004424 carbon dioxide Drugs 0.000 claims description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 51
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 32
- 239000001301 oxygen Substances 0.000 claims description 31
- 229910052760 oxygen Inorganic materials 0.000 claims description 31
- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 claims description 29
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 26
- 229910052757 nitrogen Inorganic materials 0.000 claims description 25
- 235000011089 carbon dioxide Nutrition 0.000 claims description 24
- 239000002918 waste heat Substances 0.000 claims description 22
- 238000004880 explosion Methods 0.000 claims description 21
- 239000003054 catalyst Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 19
- 238000012544 monitoring process Methods 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 12
- 239000000498 cooling water Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 7
- 238000006555 catalytic reaction Methods 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 239000012212 insulator Substances 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- -1 aluminium titanium carbon Chemical compound 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 230000001413 cellular effect Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000011162 core material Substances 0.000 claims description 3
- 238000000407 epitaxy Methods 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims description 3
- 238000000053 physical method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000007789 sealing Methods 0.000 abstract description 2
- 238000005087 graphitization Methods 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 12
- 229910002804 graphite Inorganic materials 0.000 description 12
- 239000010439 graphite Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 8
- 230000008859 change Effects 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 206010039203 Road traffic accident Diseases 0.000 description 3
- 229910003481 amorphous carbon Inorganic materials 0.000 description 3
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 3
- 239000003830 anthracite Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- SWAIALBIBWIKKQ-UHFFFAOYSA-N lithium titanium Chemical compound [Li].[Ti] SWAIALBIBWIKKQ-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241000872198 Serjania polyphylla Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- GCNLQHANGFOQKY-UHFFFAOYSA-N [C+4].[O-2].[O-2].[Ti+4] Chemical compound [C+4].[O-2].[O-2].[Ti+4] GCNLQHANGFOQKY-UHFFFAOYSA-N 0.000 description 1
- BECGPAPCGOJSOT-UHFFFAOYSA-N [O-2].O.S.[Zn+2] Chemical compound [O-2].O.S.[Zn+2] BECGPAPCGOJSOT-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000005619 thermoelectricity Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/005—General arrangement or lay-out of plants for the processing of tyres or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/08—Building tyres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Tires In General (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The present invention relates to tire art, more particularly to the technique and its device of graphene tire are produced in a kind of coproduction, by the oily aluminium alloy ferrosilicon of coal base graphene tire coproduction electricity, graphene tire is produced and combines commercial application with tail gas pollution control emission, IGCC generatings, liquefaction.The beneficial effects of the present invention are：First, low cost produces graphene automobile, motorcycle, tractor, bicycle, industry, aircraft safety tire, especially increase broken tyre pricking proof, explosion-proof and increase resistance, extend the life-span；Second, using carbon black, coal ash for manufacturing aluminium alloy and tail gas low cost hydrogen manufacturing caused by ferrosilicon is produced, generated electricity with IGCC and trap carbon dioxide low cost liquefaction；Third, whole sealing and circulating, the problem of CO2 emission of coal electricity and fine coal ash fouling environment are controlled from source, and by carbon dioxide and the utilization of resources of flyash 100%.
Description
Technical field
The present invention relates to tire art, more particularly to a kind of coproduction to produce the technique and its device of graphene tire.
Background technology
Graphene is a kind of by the tightly packed two dimensional crystal formed of carbon atom, and it is transparency in mankind's known substance
By force, flexible, extremely hard, waterproof solar heat protection, resistivity is low, a kind of resourceful perfect material, and as international each row
The focus of industry competition.
Graphene is a kind of New Two Dimensional carbon nanomaterial, because of characteristics such as its is ultra-thin, super-strength, high conductivity, battery,
The fields such as sensor, coating, ultracapacitor have a wide range of applications.
Carbon black is a kind of amorphous carbon.Gently, pine and superfine black powder, surface area are very big, scope from 10~
3000m2/g, black dyes can be made, mainly for the manufacture of ink and rubber tyre.Current art production carbon black raw material be mainly
Carbocoal tar or carbolineum, major defect are that production cost is higher and the resistance of rubber tyre enhancing is relatively low.Report, the whole world in 2010
Because the dead people of traffic accident amounts to 1,240,000 people, wherein pedestrian just up to 270,000 people, in addition, daily because traffic accident is dead
Students in middle and primary schools are more than 2000 people.And cause one of major reason of traffic accident, it is that the tire quality of prior art is poor, such as easily
Blow out and easily punctured.
Graphene is prepared for tire, can effectively solve phenomena such as existing tire quality difference is easily blown out, but graphite
Alkene it is expensive to produce popularization and application and industrialization production of the cost for it unfavorable, how to reduce and produce cost, promote industry
It is one of problem that needs solve to change application.
The content of the invention
The present invention for overcome above-mentioned weak point, and it is an object of the present invention to provide a kind of coproduction produce graphene tire technique and
Its device, graphene tire is produced by technique and device, the eager to do well in everything degree of the tire quality is big, and increase tyre pricking proof is broken, explosion-proof
With increase resistance, extension life-span, accident of blowing out is reduced, while carbon dioxide is trapped by coproduction and is used for liquefaction with flyash, is subtracted
Few environmental pollution.
The present invention is to reach above-mentioned purpose by the following technical programs：The technique of graphene tire is produced in a kind of coproduction, bag
Include following steps：
(1) graphene island, the black island of sial titanium carbon are sent coal base in Mei Ji islands, produce graphene respectively and sial titanium carbon is black, stone
Black alkene and sial titanium carbon is black to send graphene tire island to produce graphene tire；
(2) coal base is sent IGCC carbon oxygen cycle generatings island to be used to generate electricity by Mei Ji islands, produces flyash and carbon dioxide difference
Coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island are sent, aluminium alloy and ferrosilicon production are produced in coal ash for manufacturing aluminium alloy ferrosilicon island
Product；
(3) the black island of sial titanium carbon, coal ash for manufacturing aluminium alloy ferrosilicon island, high-temperature tail gas caused by IGCC carbon oxygen cycle generatings island
Waste heat from tail gas steam island is sent to produce vapor；A part of vapor send tail gas hydrogen manufacturing island, and vapor produces hydrogen with flyash reaction
Gas and carbon dioxide, hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island；A part of vapor power transmission solution steam island electricity
Solution produces hydrogen and oxygen, send hydrogen island, oxygen island respectively；
(4) hydrogen is sent carbon dioxide liquefaction island to produce oil by collecting carbonic anhydride island by the carbon dioxide of trapping, hydrogen island
Product；IGCC carbon oxygen cycle generatings island is sent to be used to generate electricity oxygen in oxygen island；
(5) long-distance anti-explosion monitoring island, including online long-distance anti-explosion is carried out to each system and plant area and monitored, it is ensured that safety is raw
Production.
Preferably, the technique that graphene tire is produced in a kind of coproduction also includes space division island, space division island separates air, oxygen
Pneumatic transmission oxygen island, nitrogen send sial titanium carbon black island.
Preferably, in step (1), epitaxy method, liquid phase or the direct stripping method of gas phase, machine are passed through using physical method
Tool stripping method prepares graphene, and the graphene of preparation is single or multiple lift.
Preferably, the reaction temperature on the black island of sial titanium carbon is 800-3600 DEG C, the reaction temperature on electrolysis steam island is
200—1000℃。
The device of graphene tire is produced in a kind of coproduction, including：Mei Ji islands, the black island of sial titanium carbon, graphene island, graphene
Tire island, IGCC carbon oxygen cycle generatings island, coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, waste heat from tail gas steam island,
Tail gas hydrogen manufacturing island, space division island, carbon dioxide liquefaction island, long-distance anti-explosion monitoring island；The Mei Ji islands and the black island of sial titanium carbon, graphite
Alkene island, the connection of IGCC carbon oxygen cycle generatings island, the black island of sial titanium carbon, graphene island are connected with graphene tire island, IGCC carbon oxygen
Circulating generation island is connected with coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, waste heat from tail gas steam island, and sial titanium carbon is black
Island is connected with waste heat from tail gas steam island, tail gas hydrogen manufacturing island, coal ash for manufacturing aluminium alloy ferrosilicon island and waste heat from tail gas steam island, tail gas system
Hydrogen island connects, and waste heat from tail gas steam island is connected with tail gas hydrogen manufacturing island, waste heat from tail gas steam island by be electrolysed steam island respectively with hydrogen
Gas island, the connection of oxygen island, tail gas hydrogen manufacturing island is connected with hydrogen island, collecting carbonic anhydride island, hydrogen island, collecting carbonic anhydride island and
Carbon dioxide liquefaction island is connected, and oxygen island is connected with space division island, IGCC carbon oxygen cycle generatings island, space division island and the black island of sial titanium carbon
Connection, long-distance anti-explosion monitoring island real time and on line monitoring.
Preferably, the black island of sial titanium carbon is the black device of plasmatorch sial titanium carbon, including：Nitrogen primary air nozzle, nitrogen
Overfiren air port, the feeding port of high alumina coal gangue powder first, the feeding port of high alumina coal gangue powder second, hollow cathode, four multianode, the moon
Pole recirculated cooling water, anode circulation cooling water, catalysis core, insulator, catalyst chamber heat insulation wall, catalyst chamber, dc source, high-tension pulse
Rush power supply, high-voltage pulse device, gas-solid separator, sial titanium carbon black-envelope apparatus system, tail gas recycling and treating device system, long-range anti-
Quick-fried monitor；The hollow cathode is arranged in order with four multianode and symmetrical, the negative pole of the dc source and one
The hollow cathode of side, a multianode connection, the anode of dc source connect with remaining multianode of homonymy；It is described symmetrical hollow
Nitrogen primary air nozzle is provided between negative electrode, be sequentially provided between hollow cathode and multianode nitrogen primary air nozzle, nitrogen overfiren air port,
The feeding port of high alumina coal gangue powder first, the feeding port of high alumina coal gangue powder second；The negative pole and opposite side of the high-voltage pulse power source
Hollow cathode, the connection of multianode；Cellular catalysis core is inserted in the black device center of plasmatorch sial titanium carbon, and one end leads to
Insulator is crossed to connect with high-voltage pulse device；Hollow cathode of the cooled cathode circulating water flow through the left and right sides, anode cooling circulating water
Flow through the multianode of the left and right sides；Nitrogen send catalyst chamber with high alumina coal gangue powder, and catalyst chamber is made up of closed catalyst chamber heat insulation wall；
Catalyst chamber is connected with gas-solid separator, gas-solid separator and sial titanium carbon black-envelope apparatus system, tail gas recycling and treating device system,
Long-distance anti-explosion monitor real time and on line monitoring.
The beneficial effects of the present invention are：First, low cost produces graphene automobile, motorcycle, tractor, bicycle, work
Industry, aircraft safety tire, especially increase broken tyre pricking proof, explosion-proof and increase resistance, extend the life-span；Carbon is produced second, utilizing
Tail gas low cost hydrogen manufacturing caused by black, coal ash for manufacturing aluminium alloy and ferrosilicon, generated electricity with IGCC and trap carbon dioxide low cost liquefaction；
Third, whole sealing and circulating, the problem of CO2 emission of coal electricity and fine coal ash fouling environment are controlled from source, and by dioxy
Change carbon and the utilization of resources of flyash 100%.
Brief description of the drawings
Fig. 1 is the structural representation of apparatus of the present invention；
Fig. 2 is the process flow diagram that graphene island prepares graphene using coal base；
Fig. 3 is coproduction waste heat from tail gas steam, hydrogen manufacturing, catches carbon, the process flow diagram of liquefaction；
Fig. 4 is the structural representation of the black device of plasmatorch sial titanium carbon of the present invention；
Fig. 5 is the structural representation of graphene tire；
Fig. 6 is the structural representation of the device of the embodiment of the present invention 2.
Embodiment
With reference to specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in
This：
Embodiment 1：As shown in figure 1, the device of graphene tire is produced in a kind of coproduction, including：Mei Ji islands, sial titanium carbon are black
Island, graphene island, graphene tire island, IGCC carbon oxygen cycle generatings island, coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride
Island, waste heat from tail gas steam island, tail gas hydrogen manufacturing island, space division island, carbon dioxide liquefaction island, long-distance anti-explosion monitoring island；The Mei Ji islands
Island black with sial titanium carbon, graphene island, IGCC carbon oxygen cycle generatings island are connected, the black island of sial titanium carbon, graphene island and graphene
Tire island is connected, and IGCC carbon oxygen cycle generating islands are steamed with coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, waste heat from tail gas
Vapour island is connected, and the black island of sial titanium carbon is connected with waste heat from tail gas steam island, tail gas hydrogen manufacturing island, coal ash for manufacturing aluminium alloy ferrosilicon island and tail
Gas afterheat steam island, the connection of tail gas hydrogen manufacturing island, waste heat from tail gas steam island are connected with tail gas hydrogen manufacturing island, and waste heat from tail gas steam island passes through
Electrolysis steam island is connected with hydrogen island, oxygen island respectively, and tail gas hydrogen manufacturing island is connected with hydrogen island, collecting carbonic anhydride island, hydrogen
Island, collecting carbonic anhydride island are connected with carbon dioxide liquefaction island, and oxygen island is connected with space division island, IGCC carbon oxygen cycle generatings island,
Space division island is connected with the black island of sial titanium carbon, long-distance anti-explosion monitoring island real time and on line monitoring.
Mei Ji islands, mainly include coal crushing, coal washing, intelligent metering induction system.It is preferred that coal base is high alumina coal or high alumina
Gangue.It is preferred that the coal base on Mei Ji islands is high alumina coal, or high alumina coal gangue, anthracite, coking coal.Send coal base to stone respectively in Mei Ji islands
Mo Xi islands, the black island of sial titanium carbon, IGCC carbon oxygen cycle generatings island.
The black island of sial titanium carbon, including plasmatorch sial titanium carbon are black, water and volatile matter in coal are removed, by coal macromolecule
Fast-neutron fission is into simple substance carbon under nitrogen gas plasma effect.It is preferred that the temperature on the black island of sial titanium carbon is 800-3600 DEG C.
Graphene island, including using coal base as raw material, it is preferably direct by epitaxy method, liquid phase or gas phase with physical method
Stripping method, mechanical stripping method prepare single or multiple lift graphene.These method raw materials are easy to get, and operation is relatively easy, synthesis
The purity of graphene is high, defect is less.
Graphene tire island, including will be black for raw material with graphene and sial titanium carbon, produce graphene tire.Such as：Graphite
Alkene automobile, motorcycle, tractor, bicycle, industry, aircraft safety tire.
IGCC carbon oxygen cycle generatings island, including trapping carbon dioxide recycle produce carbon monoxide with coal, carry out pure oxygen burning
Generate electricity, improve heat energy conversion ratio.Caused flyash send coal ash for manufacturing aluminium alloy ferrosilicon island.
Coal ash for manufacturing aluminium alloy ferrosilicon island, including by flyash caused by IGCC carbon oxygen cycle generatings island, directly extract aluminium
Alloy and silicon iron product.
Collecting carbonic anhydride island, including to carbon dioxide caused by IGCC carbon oxygen cycle generatings island, tail gas hydrogen manufacturing island, carry out
Trap and recycle.
Tail gas steam island, including to IGCC carbon oxygen cycle generatings island, the black island of sial titanium carbon, coal ash for manufacturing aluminium alloy ferrosilicon island
Caused high-temperature tail gas UTILIZATION OF VESIDUAL HEAT IN water vapour.A part of steam send tail gas hydrogen manufacturing island, a part of steam power transmission Xie Zhengqidao.
Tail gas hydrogen manufacturing island, including the oxidation by steam and the black island of sial titanium carbon, coal ash for manufacturing aluminium alloy ferrosilicon island tail gas
Carbon reacts, and produces hydrogen and carbon dioxide.Hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island.
Steam island is electrolysed, including steam is electrolysed, produces hydrogen and oxygen.Hydrogen send hydrogen island, and oxygen send oxygen
Island, for IGCC carbon oxygen cycle generatings island, carry out pure oxygen burning generating.It is preferred that the temperature on electrolysis steam island is 200-1000 DEG C.
Carbon dioxide liquefaction island, including carbon dioxide and hydrogen reformer are produced into oily (gasoline, diesel oil) product.
Space division island, including air is separated, nitrogen send sial titanium carbon black island, and oxygen send oxygen island.
Long-distance anti-explosion monitors island, including carries out online long-distance anti-explosion to each system and plant area and monitor, it is ensured that safety in production.
The technique of graphene tire is produced in a kind of coproduction based on said apparatus, is comprised the following steps：
(1) graphene island, the black island of sial titanium carbon are sent coal base in Mei Ji islands, produce graphene respectively and sial titanium carbon is black, stone
Black alkene and sial titanium carbon is black to send graphene tire island to produce graphene tire；
(2) coal base is sent IGCC carbon oxygen cycle generatings island to be used to generate electricity by Mei Ji islands, produces flyash and carbon dioxide difference
Coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island are sent, aluminium alloy and ferrosilicon production are produced in coal ash for manufacturing aluminium alloy ferrosilicon island
Product；
(3) the black island of sial titanium carbon, coal ash for manufacturing aluminium alloy ferrosilicon island, high-temperature tail gas caused by IGCC carbon oxygen cycle generatings island
Waste heat from tail gas steam island is sent to produce vapor；A part of vapor send tail gas hydrogen manufacturing island, and vapor produces hydrogen with flyash reaction
Gas and carbon dioxide, hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island；A part of vapor power transmission solution steam island electricity
Solution produces hydrogen and oxygen, send hydrogen island, oxygen island respectively；
(4) hydrogen is sent carbon dioxide liquefaction island to produce oil by collecting carbonic anhydride island by the carbon dioxide of trapping, hydrogen island
Product；IGCC carbon oxygen cycle generatings island is sent to be used to generate electricity oxygen in oxygen island；Space division island separates air, and oxygen send oxygen island,
Nitrogen send sial titanium carbon black island；
(5) long-distance anti-explosion monitoring island, including online long-distance anti-explosion is carried out to each system and plant area and monitored, it is ensured that safety is raw
Production.
IGCC carbon oxygen cycle generatings island, the black island of sial titanium carbon, coal ash for manufacturing aluminium alloy ferrosilicon island, waste heat from tail gas steam island,
The combined production device that tail gas hydrogen manufacturing island, hydrogen island, oxygen island, collecting carbonic anhydride island, carbon dioxide liquefaction island are formed, for coproduction
Waste heat from tail gas steam, hydrogen manufacturing, catch carbon, liquefaction.
In process of production, Fig. 2 is the process flow diagram that graphene island prepares coal base graphene using coal base, production
Coal base graphene, can further produce downstream product, such as：Coal base graphene tire, coal base graphene battery, coal base graphene
Fiber (underwear, household articles), coal base graphene cable, coal base graphene alloy (automobile, aircraft, submarine) and coal base graphene
Electronic product etc..Specifically include following steps：
The first step, high-temperature calcination graphitization：By high alumina coal (high alumina coal gangue or anthracite) through more than 2000 DEG C heat at
Reason, because physical change makes hexagonal carbon atomic plane lamina reticularis stacked structure improve development, be transformed into has with graphite two dimension, three-dimensional
The graphite charcoal of sequence structure；
(1) calcination stage is repeated, temperature is to l250 DEG C, for the preheating transition stage at graphitization initial stage, coal base now
With certain thermoelectricity capability and thermal shock resistance；
(2) keep under strict control the temperature rise period, temperature is to 1250-1800 DEG C, and this stage is graphitization key temperatures section, charcoal base
Physical arrangement and chemical composition have a very large change, and the Turbostratic of amorphous carbon gradually changes to graphite crystal, simultaneously
Effusion is constantly decomposed in unstable low molecular hydrocarbon and the impurity element group that amorphous carbon microstructure edge combines；
(3) free temperature rise period, temperature to 1800 DEG C-graphitization maximum temperature, the now crystal structure of graphite of Carbon Materials
Blank has basically formed, and continues to heat up, and promotes its degree of graphitization further to improve；
Coal, as temperature raises, sulphur is removed at 1300-l700 DEG C in calcination process, and remaining metal impurities also exists
2000-2200 DEG C or so start discharge of gasifying from coal, and coal can reach coal after about 2300-2500 DEG C of high-temperature process
High warm melts the purpose of drop ash.In addition after high-temperature process, the lattice of coal improves to transformation, degree of graphitization is aligned,
Real density improves, and resistivity reduces；
The graphited preparation technology of coal base forges technology using high temperature direct current, and main equipment selects high temperature electrical calcination furnace,
About 2300-2500 DEG C of combustion chamber temperature, requirement of the high-grade carbonaceous product to graphite carbon structure and purity can be met；
Second step：Plasma graphitization：Send high alumina coal (high alumina coal gangue or anthracite) to plasma torch graphitization；
3rd step, mechanical stripping：
After coal graphitization, reduced by thermal anneal process, reduction mechanism is can be in graphite in heating quick to coal
Substantial amounts of CO or C0 are produced between carbon plate layer2Simultaneously unexpected expansion occurs for gas.The rapid increase of temperature makes containing in carbon plane
Oxygen functional group resolves into gas and huge pressure (reaching 130MPa at 1000 DEG C) is produced between the lamella of stacking, makes stacking
Graphite carbon plate layer separation.Quick heating process can not only peel off graphite charcoal and can decompose its surface at high temperature
Oxygen-containing functional group is so as to preparing the graphene of functionalization；
4th step, fuel gas IGCC generate electricity：
By caused fuel gas CO during coal base graphitization, IGCC power generation system is sent to generate electricity.
Two kinds of method for graphitizing of high-temperature calcination graphitization and plasma graphitization mentioned above, in actual application also
Ultrasonic wave stove graphitization and micro-wave oven graphitizing method can be used.
If Fig. 3 waste heat from tail gas steam island is heat recovery steam generator, IGCC carbon oxygen cycle generatings island, the black island of sial titanium carbon,
High-temperature tail gas is sent to heat recovery steam generator by coal ash for manufacturing aluminium alloy ferrosilicon island by pipeline, and steam is sent into tail gas hydrogen manufacturing island system
The carbon monoxide that island black with sial titanium carbon, the feeding of coal ash for manufacturing aluminium alloy ferrosilicon island high-temperature tail gas pipeline come in hydrogen reative cell is anti-
Should, hydrogen and carbon dioxide are produced, is re-fed into gas separator separation, hydrogen is sent into hydrogen island, and carbon dioxide is sent into titanium dioxide
Carbon traps island, for carbon dioxide liquefaction island liquefaction；Hydrogen production reaction room long-distance anti-explosion monitor and gas separator long-distance anti-explosion prison
Control device on-line monitoring tail gas hydrogen manufacturing island hydrogen production reaction room and temperature, pressure in gas separator.
As shown in figure 4, the black island of sial titanium carbon is the black device of plasmatorch sial titanium carbon, including：Nitrogen primary air nozzle, nitrogen
Overfiren air port, the feeding port of high alumina coal gangue powder first, the feeding port of high alumina coal gangue powder second, hollow cathode, four multianode, the moon
Pole recirculated cooling water, anode circulation cooling water, catalysis core, insulator, catalyst chamber heat insulation wall, catalyst chamber, dc source, high-tension pulse
Rush power supply, high-voltage pulse device, gas-solid separator, sial titanium carbon black-envelope apparatus system, tail gas recycling and treating device system, long-range anti-
Quick-fried monitor；The hollow cathode is arranged in order with four multianode and symmetrical, the negative pole of the dc source and one
The hollow cathode of side, a multianode connection, the anode of dc source connect with remaining multianode of homonymy；It is described symmetrical hollow
Nitrogen primary air nozzle is provided between negative electrode, be sequentially provided between hollow cathode and multianode nitrogen primary air nozzle, nitrogen overfiren air port,
The feeding port of high alumina coal gangue powder first, the feeding port of high alumina coal gangue powder second；The negative pole and opposite side of the high-voltage pulse power source
Hollow cathode, the connection of multianode, the anode of dc source connects with remaining multianode of homonymy；Cellular catalysis core
The black device center of plasmatorch sial titanium carbon is inserted in, one end is connected by insulator with high-voltage pulse device；Cooled cathode recirculated water
The hollow cathode of the left and right sides is flowed through, anode cooling circulating water flows through the multianode of the left and right sides；Nitrogen and high alumina coal gangue powder
Catalyst chamber is sent, catalyst chamber is made up of closed catalyst chamber heat insulation wall；Catalyst chamber is connected with gas-solid separator, gas-solid separator and sial
Titanium carbon black-envelope apparatus system, tail gas recycling and treating device system, long-distance anti-explosion monitor real time and on line monitoring.
Implementation steps：
The first step, open each system power switch.And cathode circulation cooling water and anode circulation cooling water valve are opened successively
Door, it is sent into recirculated cooling water；
Second step, nitrogen is sent into plasmatorch from nitrogen primary air nozzle and nitrogen overfiren air port, and from high alumina bastard coal
The high alumina coal gangue powder that the feeding port of stone flour first and the feeding port of high alumina coal gangue powder second are sent into, in 800-3600 DEG C of high temperature
Plasma is cooperateed with use with catalysis core, in catalyst chamber, when water and volatile matter in moment fast eliminating coal, second, by
Coal macromolecular is fissioned into simple substance carbon black in high alumina coal gangue；In gas-solid separator, gas is sent into tail gas recycling and treating device
System, solid are sent into sial titanium carbon black-envelope apparatus system；
Temperature in 3rd step, opening long-distance anti-explosion monitor difference on-line monitoring plasmatorch catalyst chamber and gas-solid separator
Degree, pressure.
By graphene tire made of above-mentioned technique and device, can be used on the various vehicles, such as automobile,
Motorcycle, tractor, bicycle, industry, aircraft safety tire.As shown in figure 4, using grapheme material produce including：Graphite
Alkene reinforcing band, graphene lining layer, graphene steel band, graphene steel bead wire, with natural rubber, oil rubber, sial titanium carbon
Black and sulphur zinc oxide and sulphur auxiliary agent, graphene tire is made, substitutes conventional tire, have broken increase tyre pricking proof, explosion-proof and
The advantages of increasing resistance, long lifespan, being not easy to blow out.
Embodiment 2：As shown in fig. 6, the present embodiment and the difference of embodiment 1 are, in addition to graphene new-energy automobile
Island, graphene lithium titanium Rare Earths Battery island, the shellproof anti-sticking pad pasting island of graphene, graphene purification of air filter membrane island, graphene brake
Piece island, graphene Prospect for Flame Retardant Fiber Materials island, graphene engine island, graphene intelligence control electronic component island.Coal base is sent on Mei Ji islands
Graphene island, the black island of sial titanium carbon are sent after the devolatilization of graphitization island, graphene is produced respectively and sial titanium carbon is black, graphene
With sial titanium carbon is black send graphene tire island to produce graphene tire, graphene send graphene brake block island to produce graphene brake
Piece, graphene lithium titanium Rare Earths Battery island is sent to produce graphene battery, send graphene engine island to produce graphene engine, send stone
The black shellproof anti-sticking pad pasting island of alkene produces that graphene is shellproof anti-to be hit pad pasting, send graphene purification of air filter membrane island to produce graphene purification
Filter membrane, graphene Prospect for Flame Retardant Fiber Materials island is sent to produce graphene fiber fire proofing, send graphene intelligence control electronic component island to produce
Graphene intelligence control electronic component, graphene lithium titanium Rare Earths Battery island, the shellproof anti-sticking pad pasting island of graphene, the filter of graphene purification of air
Film island, graphene brake block island, graphene Prospect for Flame Retardant Fiber Materials island, graphene engine island, graphene intelligence control electronic component island
It is connected with graphene new-energy automobile island, graphene brake block, graphene battery, graphene engine, graphene are shellproof to be prevented hitting
Pad pasting, graphene purification filter membrane, graphene fiber fire proofing, graphene intelligence control electronic component send graphene new-energy automobile island
Manufactured for new-energy automobile.
The present embodiment is expanded on the basis of embodiment 1, and the application of graphene is not merely used for tire, also may be used
For on other automobile components.
The technical principle for being the specific embodiment of the present invention and being used above, if conception under this invention institute
The change of work, during the spirit that its caused function is still covered without departing from specification and accompanying drawing, it should belong to the present invention's
Protection domain.
Claims (6)
1. the technique that graphene tire is produced in a kind of coproduction, it is characterised in that comprise the following steps：
(1) graphene island, the black island of sial titanium carbon are sent coal base in Mei Ji islands, produce graphene respectively and sial titanium carbon is black, graphene
With sial titanium carbon is black send graphene tire island to produce graphene tire；
(2) coal base is sent IGCC carbon oxygen cycle generatings island to be used to generate electricity by Mei Ji islands, produces flyash and carbon dioxide difference powder feeding
Aluminium alloy and silicon iron product are produced in coal ash aluminium alloy ferrosilicon island, collecting carbonic anhydride island, coal ash for manufacturing aluminium alloy ferrosilicon island；
(3) the black island of sial titanium carbon, coal ash for manufacturing aluminium alloy ferrosilicon island, high-temperature tail gas send tail caused by IGCC carbon oxygen cycle generatings island
Produce vapor in gas afterheat steam island；A part of vapor send tail gas hydrogen manufacturing island, vapor and flyash reaction produce hydrogen and
Carbon dioxide, hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island；A part of vapor power transmission Xie Zhengqidao electrolysis production
Raw hydrogen and oxygen, send hydrogen island, oxygen island respectively；
(4) hydrogen is sent carbon dioxide liquefaction island to produce oil product by collecting carbonic anhydride island by the carbon dioxide of trapping, hydrogen island；
IGCC carbon oxygen cycle generatings island is sent to be used to generate electricity oxygen in oxygen island；
(5) long-distance anti-explosion monitoring island, including online long-distance anti-explosion is carried out to each system and plant area and monitored, it is ensured that safety in production.
2. the technique that graphene tire is produced in a kind of coproduction according to claim 1, it is characterised in that also including space division
Island, space division island separate air, and oxygen send oxygen island, and nitrogen send sial titanium carbon black island.
3. the technique that graphene tire is produced in a kind of coproduction according to claim 1, it is characterised in that in step (1), adopt
Graphene, the stone of preparation are prepared by epitaxy method, liquid phase or the direct stripping method of gas phase, mechanical stripping method with physical method
Black alkene is single or multiple lift.
4. the technique that graphene tire is produced in a kind of coproduction according to claim 1, it is characterised in that the black island of sial titanium carbon
Reaction temperature be 800-3600 DEG C, the reaction temperature on electrolysis steam island is 200-1000 DEG C.
5. the device of graphene tire is produced in a kind of coproduction, it is characterised in that including：Mei Ji islands, the black island of sial titanium carbon, graphene
Island, graphene tire island, IGCC carbon oxygen cycle generatings island, coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, more than tail gas
Vapours island, tail gas hydrogen manufacturing island, space division island, carbon dioxide liquefaction island, long-distance anti-explosion monitoring island；The Mei Ji islands and sial titanium carbon
Black island, graphene island, the connection of IGCC carbon oxygen cycle generatings island, the black island of sial titanium carbon, graphene island are connected with graphene tire island,
IGCC carbon oxygen cycle generating islands are connected with coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, waste heat from tail gas steam island, silicon
The black island of aluminium titanium carbon is connected with waste heat from tail gas steam island, tail gas hydrogen manufacturing island, coal ash for manufacturing aluminium alloy ferrosilicon island and waste heat from tail gas steam
Island, the connection of tail gas hydrogen manufacturing island, waste heat from tail gas steam island are connected with tail gas hydrogen manufacturing island, and waste heat from tail gas steam island is by being electrolysed steam island
It is connected respectively with hydrogen island, oxygen island, tail gas hydrogen manufacturing island is connected with hydrogen island, collecting carbonic anhydride island, hydrogen island, carbon dioxide
Trapping island is connected with carbon dioxide liquefaction island, and oxygen island is connected with space division island, IGCC carbon oxygen cycle generatings island, space division island and sial
The black island connection of titanium carbon, long-distance anti-explosion monitoring island real time and on line monitoring.
6. the device of graphene tire is produced in a kind of coproduction according to claim 5, it is characterised in that the black island of sial titanium carbon
For the black device of plasmatorch sial titanium carbon, including：Nitrogen primary air nozzle, nitrogen overfiren air port, the feeding of high alumina coal gangue powder first
Mouth, the feeding port of high alumina coal gangue powder second, hollow cathode, four multianode, cathode circulation cooling water, anode circulation cooling water,
It is catalyzed core, insulator, catalyst chamber heat insulation wall, catalyst chamber, dc source, high-voltage pulse power source, high-voltage pulse device, gas solid separation
Device, sial titanium carbon black-envelope apparatus system, tail gas recycling and treating device system, long-distance anti-explosion monitor；The hollow cathode and four
Individual multianode is arranged in order and symmetrical, the negative pole of the dc source and the hollow cathode of side, a multianode company
Logical, the anode of dc source connects with remaining multianode of homonymy；Nitrogen primary air nozzle is provided between the symmetrical hollow cathode, it is empty
Nitrogen primary air nozzle, nitrogen overfiren air port, the feeding port of high alumina coal gangue powder first, height are sequentially provided between the heart-yin pole and multianode
The feeding port of aluminium colliery powder second；The negative pole of the high-voltage pulse power source connects with the hollow cathode of opposite side, a multianode；
Cellular catalysis core is inserted in the black device center of plasmatorch sial titanium carbon, and one end is connected by insulator with high-voltage pulse device；
Hollow cathode of the cooled cathode circulating water flow through the left and right sides, anode cooling circulating water flow through the multianode of the left and right sides；Nitrogen
Catalyst chamber is sent with high alumina coal gangue powder, catalyst chamber is made up of closed catalyst chamber heat insulation wall；Catalyst chamber is connected with gas-solid separator, gas
Solid separator and sial titanium carbon black-envelope apparatus system, tail gas recycling and treating device system, long-distance anti-explosion monitor real-time online prison
Control.
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