CN105666904A - Process and device for preparing graphene tire by coproduction - Google Patents
Process and device for preparing graphene tire by coproduction Download PDFInfo
- Publication number
- CN105666904A CN105666904A CN201610211647.8A CN201610211647A CN105666904A CN 105666904 A CN105666904 A CN 105666904A CN 201610211647 A CN201610211647 A CN 201610211647A CN 105666904 A CN105666904 A CN 105666904A
- Authority
- CN
- China
- Prior art keywords
- island
- graphene
- tail gas
- coal
- carbon black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 146
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 131
- 238000000034 method Methods 0.000 title claims abstract description 36
- 230000008569 process Effects 0.000 title abstract description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 95
- 239000003245 coal Substances 0.000 claims abstract description 85
- 239000007789 gas Substances 0.000 claims abstract description 76
- 239000001257 hydrogen Substances 0.000 claims abstract description 76
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 76
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 69
- 239000006229 carbon black Substances 0.000 claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 claims abstract description 67
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 35
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 34
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 32
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims abstract description 28
- 239000010883 coal ash Substances 0.000 claims abstract description 27
- 238000004880 explosion Methods 0.000 claims abstract description 24
- 239000010881 fly ash Substances 0.000 claims abstract description 13
- CYKMNKXPYXUVPR-UHFFFAOYSA-N [C].[Ti] Chemical compound [C].[Ti] CYKMNKXPYXUVPR-UHFFFAOYSA-N 0.000 claims description 64
- 229960004424 carbon dioxide Drugs 0.000 claims description 56
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 51
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 32
- 229910052760 oxygen Inorganic materials 0.000 claims description 32
- 239000001301 oxygen Substances 0.000 claims description 32
- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 claims description 29
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
- 235000011089 carbon dioxide Nutrition 0.000 claims description 26
- 229910052757 nitrogen Inorganic materials 0.000 claims description 25
- 239000002918 waste heat Substances 0.000 claims description 25
- 238000012544 monitoring process Methods 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 19
- 230000005611 electricity Effects 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 238000005868 electrolysis reaction Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000000498 cooling water Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000004064 recycling Methods 0.000 claims description 8
- 238000006555 catalytic reaction Methods 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 6
- 239000012212 insulator Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 4
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 claims description 4
- 230000001413 cellular effect Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000011162 core material Substances 0.000 claims description 3
- 238000000407 epitaxy Methods 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims description 3
- 238000000053 physical method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010248 power generation Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000005087 graphitization Methods 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 9
- 229910002804 graphite Inorganic materials 0.000 description 8
- 239000010439 graphite Substances 0.000 description 8
- 239000012528 membrane Substances 0.000 description 5
- 210000002381 plasma Anatomy 0.000 description 5
- 239000002994 raw material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 229910003481 amorphous carbon Inorganic materials 0.000 description 3
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 3
- 239000003830 anthracite Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- SWAIALBIBWIKKQ-UHFFFAOYSA-N lithium titanium Chemical compound [Li].[Ti] SWAIALBIBWIKKQ-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- BECGPAPCGOJSOT-UHFFFAOYSA-N [O-2].O.S.[Zn+2] Chemical compound [O-2].O.S.[Zn+2] BECGPAPCGOJSOT-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000005619 thermoelectricity Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/005—General arrangement or lay-out of plants for the processing of tyres or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/08—Building tyres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Tires In General (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention relates to the field of tires and particularly relates to a process and device for preparing a graphene tire by coproduction. By coproducing electric oil aluminum alloy ferrosilicon by a coal-based graphene tire, graphene tire production and tail gas pollution emission management, IGCC power generation and oil production are integrated together to realize industrialized application. The process and the device, provided by the invention, have the beneficial effects that firstly, graphene automobile tires, motorcycle tires, tractor tires, bicycle tires, industrial tires and airplane safety tires can be produced at a low cost;; particularly, the anti-puncturing and anti-explosion properties of the tires can be improved, the resistance is increased and the service life is prolonged; secondly, an aluminum alloy can be prepared by using produced carbon black and coal ash and hydrogen is prepared from tail gas produced by the ferrosilicon at a low cost; carbon dioxide collected from the IGCC power generation is used for preparing oil at a low cost; and thirdly, the problems of coal power carbon dioxide emission and fly ash environment pollution are controlled from the source, and the carbon dioxide and the fly ash are 100% utilized.
Description
Technical field
The present invention relates to tire art, particularly relate to a kind of coproduction and produce technique and the device thereof of Graphene tire.
Background technology
Graphene is a kind of by the tightly packed two dimensional crystal constituted of carbon atom, it is that in the mankind's known substance transparency is strong, flexible, extremely hard, waterproof solar heat protection, resistivity is low, resourceful a kind of perfect material, and becomes the focus of international industry-by-industry competition.
Graphene is a kind of New Two Dimensional carbon nanomaterial, because of characteristics such as it is ultra-thin, super-strength, high conductivity, has a wide range of applications in fields such as battery, sensor, coating, ultracapacitors.
Carbon black is a kind of amorphous carbon. Gently, pine and superfine black powder, surface area is very big, and scope, from 10～3000m2/g, can make black dyes, mainly for the manufacture of ink and rubber tyre. Current art produces the raw material of carbon black and is mainly carbocoal tar or carbolineum, and major defect is that higher and rubber tyre enhancing the resistance of production cost is relatively low. Reporting, within 2010, the global people dead because of vehicle accident amounts to 1,240,000 people, and wherein pedestrian is just up to 270,000 people, additionally, every day is because the students in middle and primary schools of vehicle accident death are more than 2000 people. And one of major reason causing vehicle accident, it is that the tire quality of prior art is poor, as easily blown out and easily being punctured.
Graphene is used for tire prepare, can effectively solve existing tire quality difference the phenomenon such as easily to blow out, but it is unfavorable that what Graphene was expensive produce cost produces for its popularization and application and industrialization, how to reduce and produces cost, promoting commercial application is need one of difficult problem of solving.
Summary of the invention
The present invention overcomes above-mentioned weak point, purpose is in that the technique and the device thereof that provide a kind of coproduction to produce Graphene tire, Graphene tire is produced by technique and device, the good intensity of this tire quality is big, increase that tyre pricking proof is broken, explosion-proof and increase resistance, life-saving, reduce accident of blowing out, be used for liquefaction by coproduction trapping carbon dioxide with flyash simultaneously, reduce environmental pollution.
The present invention reaches above-mentioned purpose by the following technical programs: the technique of Graphene tire is produced in a kind of coproduction, comprises the following steps:
(1) Graphene island, sial titanium carbon black island are sent by coal-based in coal-based island, produce Graphene and sial titanium carbon black, Graphene and sial titanium carbon black respectively and send Graphene tire island to produce Graphene tire;
(2) the coal-based IGCC of sending carbon Oxygen cycle generating island is used for generating electricity by coal-based island, produces flyash and carbon dioxide send coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island respectively, and aluminium alloy and silicon iron product are produced in coal ash for manufacturing aluminium alloy ferrosilicon island;
(3) high-temperature tail gas that sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island, IGCC carbon Oxygen cycle generating island produce send using waste heat from tail gas steam island to produce steam; A part of steam tail gas hydrogen manufacturing island, steam and flyash react generation hydrogen and carbon dioxide, and hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island; The electrolysis of a part of steam power transmission solution steam island produces hydrogen and oxygen, send hydrogen island, oxygen island respectively;
(4) hydrogen is sent carbon dioxide liquefaction island to produce oil product by collecting carbonic anhydride island by the hydrogen of trapping, hydrogen island; Oxygen is sent IGCC carbon Oxygen cycle generating island to be used for generating electricity by oxygen island;
(5) long-distance anti-explosion monitoring island, carries out the monitoring of online long-distance anti-explosion including to each system and plant area, it is ensured that safety in production.
As preferably, a kind of coproduction is produced the technique of Graphene tire and is also included space division island, and air is separated by space division island, and oxygen send oxygen island, and nitrogen send sial titanium carbon black island.
As preferably, in step (1), adopting physical method to prepare Graphene by epitaxy method or liquid phase or the direct stripping method of gas phase or mechanical stripping method, the Graphene of preparation is single or multiple lift.
As preferably, the reaction temperature on sial titanium carbon black island is 800 3600 DEG C, and the reaction temperature on electrolysis steam island is 200 1000 DEG C.
The device of Graphene tire is produced in a kind of coproduction, including: coal-based island, sial titanium carbon black island, Graphene island, Graphene tire island, IGCC carbon Oxygen cycle generating island, coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, using waste heat from tail gas steam island, tail gas hydrogen manufacturing island, space division island, carbon dioxide liquefaction island, long-distance anti-explosion monitoring island, described coal-based island and sial titanium carbon black island, Graphene island, IGCC carbon Oxygen cycle generating island connects, sial titanium carbon black island, Graphene island is connected with Graphene tire island, IGCC carbon Oxygen cycle generating island and coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, using waste heat from tail gas steam island connects, sial titanium carbon black island and using waste heat from tail gas steam island, tail gas hydrogen manufacturing island connects, coal ash for manufacturing aluminium alloy ferrosilicon island and using waste heat from tail gas steam island, tail gas hydrogen manufacturing island connects, using waste heat from tail gas steam island is connected with tail gas hydrogen manufacturing island, using waste heat from tail gas steam island by electrolysis steam island respectively with hydrogen island, oxygen island connects, tail gas hydrogen manufacturing island and hydrogen island, collecting carbonic anhydride island connects, hydrogen island, collecting carbonic anhydride island is connected with carbon dioxide liquefaction island, oxygen island and space division island, IGCC carbon Oxygen cycle generating island connects, space division island is connected with sial titanium carbon black island, long-distance anti-explosion monitoring island real time and on line monitoring.
As preferably, sial titanium carbon black island is plasmatorch sial titanium carbon black device, including: nitrogen primary air nozzle, nitrogen overfiren air port, high alumina coal gangue powder the first feeding port, high alumina coal gangue powder the second feeding port, hollow cathode, four multianode, cathode circulation cooling water, anode circulation cooling water, catalysis core, insulator, catalyst chamber heat insulation wall, catalyst chamber, DC source, high-voltage pulse power source, high-voltage pulse device, gas-solid separator, sial titanium carbon black bag apparatus system, tail gas recycling and treating device system, long-distance anti-explosion watch-dogs; Described hollow cathode and four multianode are arranged in order and symmetrical, and the negative pole of described DC source connects with the hollow cathode of side, a multianode, and the anode of DC source connects with all the other multianode of homonymy; It is provided with nitrogen primary air nozzle between described symmetrical hollow cathode, between hollow cathode and multianode, is sequentially provided with nitrogen primary air nozzle, nitrogen overfiren air port, high alumina coal gangue powder the first feeding port, high alumina coal gangue powder the second feeding port; The negative pole of described high-voltage pulse power source connects with the hollow cathode of opposite side, a multianode, and the anode of DC source connects with all the other multianode of homonymy; Cellular catalysis core is inserted in plasmatorch sial titanium carbon black device central authorities, and one end is connected with high-voltage pulse device by insulator; Cooled cathode circulating water flow is through the hollow cathode of the left and right sides, and anode cooling circulating water flows through the multianode of the left and right sides; Nitrogen and high alumina coal gangue powder send catalyst chamber, and catalyst chamber is made up of airtight catalyst chamber heat insulation wall; Catalyst chamber is connected with gas-solid separator, gas-solid separator and sial titanium carbon black bag apparatus system, tail gas recycling and treating device system, long-distance anti-explosion watch-dog real time and on line monitoring.
The beneficial effects of the present invention is: one is that low cost produces Graphene automobile, motorcycle, tractor, bicycle, industry, aircraft safety tire, especially increase that tyre pricking proof is broken, explosion-proof and increase resistance, life-saving;Two is utilize to produce the tail gas low cost hydrogen manufacturing that carbon black, coal ash for manufacturing aluminium alloy and ferrosilicon produce, with IGCC generating trapping carbon dioxide low cost liquefaction; Three is omnidistance sealing and circulating, the problem controlling coal electricity CO2 emission and flyash contaminated environment from source, and by carbon dioxide and flyash 100% utilization of resources.
Accompanying drawing explanation
Fig. 1 is the structural representation of apparatus of the present invention;
Fig. 2 is that Graphene island utilizes the coal-based process flow diagram preparing Graphene;
Fig. 3 is coproduction using waste heat from tail gas steam, hydrogen manufacturing, catches the process flow diagram of carbon, liquefaction;
Fig. 4 is the structural representation of plasmatorch sial titanium carbon black device of the present invention;
Fig. 5 is the structural representation of Graphene tire;
Fig. 6 is the structural representation of the embodiment of the present invention 2 device.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited to that:
Embodiment 1: as shown in Figure 1, the device of Graphene tire is produced in a kind of coproduction, including: coal-based island, sial titanium carbon black island, Graphene island, Graphene tire island, IGCC carbon Oxygen cycle generating island, coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, using waste heat from tail gas steam island, tail gas hydrogen manufacturing island, space division island, carbon dioxide liquefaction island, long-distance anti-explosion monitoring island, described coal-based island and sial titanium carbon black island, Graphene island, IGCC carbon Oxygen cycle generating island connects, sial titanium carbon black island, Graphene island is connected with Graphene tire island, IGCC carbon Oxygen cycle generating island and coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, using waste heat from tail gas steam island connects, sial titanium carbon black island and using waste heat from tail gas steam island, tail gas hydrogen manufacturing island connects, coal ash for manufacturing aluminium alloy ferrosilicon island and using waste heat from tail gas steam island, tail gas hydrogen manufacturing island connects, using waste heat from tail gas steam island is connected with tail gas hydrogen manufacturing island, using waste heat from tail gas steam island by electrolysis steam island respectively with hydrogen island, oxygen island connects, tail gas hydrogen manufacturing island and hydrogen island, collecting carbonic anhydride island connects, hydrogen island, collecting carbonic anhydride island is connected with carbon dioxide liquefaction island, oxygen island and space division island, IGCC carbon Oxygen cycle generating island connects, space division island is connected with sial titanium carbon black island, long-distance anti-explosion monitoring island real time and on line monitoring.
Coal-based island, mainly includes coal pulverizing, coal washing, intelligent metering induction system. Preferably coal-based for high alumina coal or high alumina coal gangue. Preferred coal-based island coal-based for high alumina coal, or high alumina coal gangue, anthracite, coking coal. Graphene island, sial titanium carbon black island, IGCC carbon Oxygen cycle generating island are sent by coal-based respectively in coal-based island.
Sial titanium carbon black island, including plasmatorch sial titanium carbon black, removes the water in coal and volatile matter, coal macromolecule fast-neutron fission under nitrogen gas plasma effect is become simple substance carbon. The temperature on preferred sial titanium carbon black island is 800 3600 DEG C.
Graphene island, including with coal-based for raw material, it is preferable for preparing single or multiple lift Graphene with physical method by epitaxy method or liquid phase or the direct stripping method of gas phase, mechanical stripping method. These method raw materials are easy to get, and operate relatively easy, and the purity of the Graphene of synthesis is high, defect is less.
Graphene tire island, including by with Graphene and sial titanium carbon black for raw material, produces Graphene tire. As: Graphene automobile, motorcycle, tractor, bicycle, industry, aircraft safety tire.
IGCC carbon Oxygen cycle generating island, produces carbon monoxide including trapping carbon dioxide recycle with coal, carries out pure oxygen burning generating, improve heat energy conversion ratio.The flyash produced send coal ash for manufacturing aluminium alloy ferrosilicon island.
Coal ash for manufacturing aluminium alloy ferrosilicon island, including the flyash that the island that generated electricity by IGCC carbon Oxygen cycle produces, extracting directly aluminium alloy and silicon iron product.
Collecting carbonic anhydride island, including the carbon dioxide that island that IGCC carbon Oxygen cycle is generated electricity, tail gas hydrogen manufacturing island produce, carries out trapping and recycling.
Tail gas steam island, including the high-temperature tail gas UTILIZATION OF VESIDUAL HEAT IN controlling the water circulation steam that island that IGCC carbon Oxygen cycle is generated electricity, sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island produce. A part of steam send tail gas hydrogen manufacturing island, a part of steam power transmission Xie Zhengqidao.
Tail gas hydrogen manufacturing island, including the reaction of carbon monoxide by steam with sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island tail gas, produces hydrogen and carbon dioxide. Hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island.
Electrolysis steam island, including steam carries out electrolysis, produces hydrogen and oxygen. Hydrogen send hydrogen island, and oxygen send oxygen island, for IGCC carbon Oxygen cycle generating island, carries out pure oxygen burning generating. The temperature on preferred electrolysis steam island is 200 1000 DEG C.
Carbon dioxide liquefaction island, produces oil (gasoline, diesel oil) product including by carbon dioxide and hydrogen reformer.
Space division island, separates including by air, and nitrogen send sial titanium carbon black island, and oxygen send oxygen island.
Long-distance anti-explosion monitoring island, carries out the monitoring of online long-distance anti-explosion including to each system and plant area, it is ensured that safety in production.
The technique producing Graphene tire based on a kind of coproduction of said apparatus, comprises the following steps:
(1) Graphene island, sial titanium carbon black island are sent by coal-based in coal-based island, produce Graphene and sial titanium carbon black, Graphene and sial titanium carbon black respectively and send Graphene tire island to produce Graphene tire;
(2) the coal-based IGCC of sending carbon Oxygen cycle generating island is used for generating electricity by coal-based island, produces flyash and carbon dioxide send coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island respectively, and aluminium alloy and silicon iron product are produced in coal ash for manufacturing aluminium alloy ferrosilicon island;
(3) high-temperature tail gas that sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island, IGCC carbon Oxygen cycle generating island produce send using waste heat from tail gas steam island to produce steam; A part of steam tail gas hydrogen manufacturing island, steam and flyash react generation hydrogen and carbon dioxide, and hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island; The electrolysis of a part of steam power transmission solution steam island produces hydrogen and oxygen, send hydrogen island, oxygen island respectively;
(4) hydrogen is sent carbon dioxide liquefaction island to produce oil product by collecting carbonic anhydride island by the hydrogen of trapping, hydrogen island; Oxygen is sent IGCC carbon Oxygen cycle generating island to be used for generating electricity by oxygen island; Air is separated by space division island, and oxygen send oxygen island, and nitrogen send sial titanium carbon black island;
(5) long-distance anti-explosion monitoring island, carries out the monitoring of online long-distance anti-explosion including to each system and plant area, it is ensured that safety in production.
The combined production device that IGCC carbon Oxygen cycle generating island, sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island, using waste heat from tail gas steam island, tail gas hydrogen manufacturing island, hydrogen island, oxygen island, collecting carbonic anhydride island, carbon dioxide liquefaction island are formed, for coproduction using waste heat from tail gas steam, hydrogen manufacturing, catches carbon, liquefaction.
In process of production, Fig. 2 is that Graphene island utilizes the coal-based process flow diagram preparing coal-based Graphene, the coal-based Graphene produced, downstream product can be produced further, as: coal-based Graphene tire, coal-based graphene battery, coal-based graphene fiber (underwear, household articles), coal-based Graphene cable, coal-based Graphene alloy (automobile, aircraft, submarine) and coal-based Graphene electronic product etc.Specifically include following steps:
The first step, high-temperature calcination graphitization: by high alumina coal (high alumina coal gangue or anthracite) through the heat treatments of more than 2000 DEG C, because physical change makes hexagonal carbon atomic plane lamina reticularis stacked structure improve development, it is transformed into the graphite charcoal with graphite two dimension, ordered 3 D structure;
(1) repeating calcination stage, temperature is to l250 DEG C, and for the preheating transition stage at graphitization initial stage, coal base now has certain thermoelectricity capability and thermal shock resistance;
(2) keep under strict control the temperature rise period, temperature is to 1,250 1800 DEG C, this stage is that graphitization key temperatures is interval, physical arrangement and the chemical composition of charcoal base have a very large change, the Turbostratic of amorphous carbon changes to graphite crystal gradually, and the unstable low molecular hydrocarbon and the impurity element group that combine at amorphous carbon microstructure edge constantly decompose effusion simultaneously;
(3) the free temperature rise period, temperature is to 1800 DEG C-graphitization maximum temperature, and now the crystal structure of graphite blank of Carbon Materials basically forms, continues to heat up, promotes its degree of graphitization to improve further;
Coal in calcination process along with temperature raise, sulfur is removed when 1300 l700 DEG C, remaining metal impurities also starts gasification from coal at about 2,000 2200 DEG C and discharges, and coal, after the high-temperature process of about 2,300 2500 DEG C, can reach coal high-temperature hot and melt the purpose dropping ash. Additionally after high-temperature process, the lattice of coal is to aligning transformation, and degree of graphitization improves, and true density improves, and resistivity reduces;
Coal-based graphited preparation technology adopts high temperature unidirectional current to forge technology, and main equipment selects high temperature electrical calcination furnace, combustion chamber temperature about 2,300 2500 DEG C, can meet the high-grade carbonaceous product requirement to graphite carbon structure and purity;
Second step: plasma graphitization: send plasma torch graphitization by high alumina coal (high alumina coal gangue or anthracite);
3rd step, mechanical stripping:
After coal graphitization, being reduced by thermal anneal process, reduction mechanism for can produce substantial amounts of CO or C0 when coal is quickly heated between graphite carbon plate layer2Also there is unexpected expansion in gas. The rapid increase of temperature makes the oxygen-containing functional group in carbon plane resolve into gas and produce huge pressure (reaching 130MPa when 1000 DEG C) between stacking lamella, makes stacking graphite carbon plate layer separate. Quick heating process can not only be peeled off graphite charcoal and can at high temperature decompose the oxygen-containing functional group on its surface thus preparing the Graphene of functionalization;
4th step, fuel gas IGCC generate electricity:
The fuel gas CO that will produce in coal-based graphitizing process, send IGCC power generation system to generate electricity.
Mentioned above high-temperature calcination graphitization and two kinds of method for graphitizing of plasma graphitization, also can adopt ultrasound wave stove graphitization and microwave oven graphitizing method in actual application.
If Fig. 3 using waste heat from tail gas steam island is heat recovery steam generator, high-temperature tail gas is delivered to heat recovery steam generator by pipeline by IGCC carbon Oxygen cycle generating island, sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island, steam sends into the indoor reaction of carbon monoxide come with sial titanium carbon black island, the feeding of coal ash for manufacturing aluminium alloy ferrosilicon island high-temperature tail gas pipeline of tail gas hydrogen manufacturing island hydrogen production reaction, produce hydrogen hydrogen and carbon dioxide, it is re-fed into gas trap to separate, hydrogen sends into hydrogen island, carbon dioxide sends into collecting carbonic anhydride island, for carbon dioxide liquefaction island liquefaction; Temperature in hydrogen production reaction room long-distance anti-explosion watch-dog and gas trap long-distance anti-explosion watch-dog hydrogen production reaction room, on-line monitoring tail gas hydrogen manufacturing island and gas trap, pressure.
As shown in Figure 4, sial titanium carbon black island is plasmatorch sial titanium carbon black device, including: nitrogen primary air nozzle, nitrogen overfiren air port, high alumina coal gangue powder the first feeding port, high alumina coal gangue powder the second feeding port, hollow cathode, four multianode, cathode circulation cooling water, anode circulation cooling water, catalysis core, insulator, catalyst chamber heat insulation wall, catalyst chamber, DC source, high-voltage pulse power source, high-voltage pulse device, gas-solid separator, sial titanium carbon black bag apparatus system, tail gas recycling and treating device system, long-distance anti-explosion watch-dogs; Described hollow cathode and four multianode are arranged in order and symmetrical, and the negative pole of described DC source connects with the hollow cathode of side, a multianode, and the anode of DC source connects with all the other multianode of homonymy; It is provided with nitrogen primary air nozzle between described symmetrical hollow cathode, between hollow cathode and multianode, is sequentially provided with nitrogen primary air nozzle, nitrogen overfiren air port, high alumina coal gangue powder the first feeding port, high alumina coal gangue powder the second feeding port; The negative pole of described high-voltage pulse power source connects with the hollow cathode of opposite side, a multianode, and the anode of DC source connects with all the other multianode of homonymy; Cellular catalysis core is inserted in plasmatorch sial titanium carbon black device central authorities, and one end is connected with high-voltage pulse device by insulator; Cooled cathode circulating water flow is through the hollow cathode of the left and right sides, and anode cooling circulating water flows through the multianode of the left and right sides; Nitrogen and high alumina coal gangue powder send catalyst chamber, and catalyst chamber is made up of airtight catalyst chamber heat insulation wall; Catalyst chamber is connected with gas-solid separator, gas-solid separator and sial titanium carbon black bag apparatus system, tail gas recycling and treating device system, long-distance anti-explosion watch-dog real time and on line monitoring.
Implement step:
The first step, open each system power switch. And open cathode circulation cooling water and anode circulation cooling water valve successively, send into recirculated cooling water;
Second step, nitrogen is sent in plasmatorch from nitrogen primary air nozzle and nitrogen overfiren air port, with the high alumina coal gangue powder sent into from high alumina coal gangue powder the first feeding port and high alumina coal gangue powder the second feeding port, under the high-temperature plasmas of the 800 3600 DEG C collaborative use with catalysis core, in catalyst chamber, one is the water in moment fast eliminating coal and volatile matter, and two is that coal macromole in high alumina coal gangue is fissioned into simple substance carbon black; In gas-solid separator, gas sends into tail gas recycling and treating device system, and sial titanium carbon black bag apparatus system sent into by solid;
3rd step, the temperature opened in long-distance anti-explosion watch-dog on-line monitoring plasmatorch catalyst chamber respectively and gas-solid separator, pressure.
By the Graphene tire that above-mentioned technique and device are made, it is possible to for the various vehicles, as automobile, motorcycle, tractor, bicycle, industry, aircraft safety tire. As shown in Figure 4, utilize grapheme material to produce to include: Graphene reinforcing band, Graphene inner liner, Graphene steel band, Graphene steel bead wire, with natural rubber, oil rubber, sial titanium carbon black and sulfur zinc oxide and sulfur auxiliary agent, make Graphene tire, substitute conventional tire, have increase that tyre pricking proof is broken, explosion-proof and increase resistance, life-span length, the advantage not easily blown out.
Embodiment 2: as shown in Figure 6, the present embodiment and embodiment 1 are distinctive in that, also include Graphene new-energy automobile island, Graphene lithium titanium Rare Earths Battery island, the shellproof antiseized pad pasting island of Graphene, Graphene air cleaning filter membrane island, Graphene brake block island, Graphene Prospect for Flame Retardant Fiber Materials island, Graphene electromotor island, Graphene intelligence control electronic component island. coal-based island by coal-based send graphitization island devolatilization after send Graphene island, sial titanium carbon black island, produces Graphene and sial titanium carbon black, Graphene and sial titanium carbon black respectively and send Graphene tire island to produce Graphene tire, and Graphene send Graphene brake block island to produce Graphene brake block, Graphene lithium titanium Rare Earths Battery island is sent to produce graphene battery, Graphene electromotor island is sent to produce Graphene electromotor, sending the shellproof antiseized pad pasting island of Graphene to produce, Graphene is shellproof anti-hits pad pasting, send Graphene air cleaning filter membrane island to produce Graphene and purify filter membrane, Graphene Prospect for Flame Retardant Fiber Materials island is sent to produce graphene fiber fire proofing, Graphene intelligence control electronic component island is sent to produce Graphene intelligence control electronic component, Graphene lithium titanium Rare Earths Battery island, the shellproof antiseized pad pasting island of Graphene, Graphene air cleaning filter membrane island, Graphene brake block island, Graphene Prospect for Flame Retardant Fiber Materials island, Graphene electromotor island, Graphene intelligence control electronic component island is connected with Graphene new-energy automobile island, Graphene brake block, graphene battery, Graphene electromotor, Graphene is shellproof to be prevented hitting pad pasting, Graphene purifies filter membrane, graphene fiber fire proofing, Graphene intelligence control electronic component send Graphene new-energy automobile island for new-energy automobile manufacture.
The present embodiment has been expanded on the basis of embodiment 1, and the application of Graphene is not merely for tire, it is also possible to for other automobile components and parts.
Be specific embodiments of the invention and the know-why used described in above, if the change that conception under this invention is made, function produced by it still without departing from description and accompanying drawing contain spiritual time, protection scope of the present invention must be belonged to.
Claims (6)
1. the technique that Graphene tire is produced in a coproduction, it is characterised in that comprise the following steps:
(1) Graphene island, sial titanium carbon black island are sent by coal-based in coal-based island, produce Graphene and sial titanium carbon black, Graphene and sial titanium carbon black respectively and send Graphene tire island to produce Graphene tire;
(2) the coal-based IGCC of sending carbon Oxygen cycle generating island is used for generating electricity by coal-based island, produces flyash and carbon dioxide send coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island respectively, and aluminium alloy and silicon iron product are produced in coal ash for manufacturing aluminium alloy ferrosilicon island;
(3) high-temperature tail gas that sial titanium carbon black island, coal ash for manufacturing aluminium alloy ferrosilicon island, IGCC carbon Oxygen cycle generating island produce send using waste heat from tail gas steam island to produce steam; A part of steam tail gas hydrogen manufacturing island, steam and flyash react generation hydrogen and carbon dioxide, and hydrogen send hydrogen island, and carbon dioxide send collecting carbonic anhydride island; The electrolysis of a part of steam power transmission solution steam island produces hydrogen and oxygen, send hydrogen island, oxygen island respectively;
(4) hydrogen is sent carbon dioxide liquefaction island to produce oil product by collecting carbonic anhydride island by the hydrogen of trapping, hydrogen island; Oxygen is sent IGCC carbon Oxygen cycle generating island to be used for generating electricity by oxygen island;
(5) long-distance anti-explosion monitoring island, carries out the monitoring of online long-distance anti-explosion including to each system and plant area, it is ensured that safety in production.
2. the technique that Graphene tire is produced in a kind of coproduction according to claim 1, it is characterised in that also include space division island, air is separated by space division island, and oxygen send oxygen island, and nitrogen send sial titanium carbon black island.
3. the technique that Graphene tire is produced in a kind of coproduction according to claim 1, it is characterized in that in step (1), adopting physical method to prepare Graphene by epitaxy method or liquid phase or the direct stripping method of gas phase or mechanical stripping method, the Graphene of preparation is single or multiple lift.
4. the technique that Graphene tire is produced in a kind of coproduction according to claim 1, it is characterised in that the reaction temperature on sial titanium carbon black island is 800 3600 DEG C, and the reaction temperature on electrolysis steam island is 200 1000 DEG C.
5. the device of Graphene tire is produced in a coproduction, it is characterised in that including: coal-based island, sial titanium carbon black island, Graphene island, Graphene tire island, IGCC carbon Oxygen cycle generating island, coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, using waste heat from tail gas steam island, tail gas hydrogen manufacturing island, space division island, carbon dioxide liquefaction island, long-distance anti-explosion monitoring island, described coal-based island and sial titanium carbon black island, Graphene island, IGCC carbon Oxygen cycle generating island connects, sial titanium carbon black island, Graphene island is connected with Graphene tire island, IGCC carbon Oxygen cycle generating island and coal ash for manufacturing aluminium alloy ferrosilicon island, collecting carbonic anhydride island, using waste heat from tail gas steam island connects, sial titanium carbon black island and using waste heat from tail gas steam island, tail gas hydrogen manufacturing island connects, coal ash for manufacturing aluminium alloy ferrosilicon island and using waste heat from tail gas steam island, tail gas hydrogen manufacturing island connects, using waste heat from tail gas steam island is connected with tail gas hydrogen manufacturing island, using waste heat from tail gas steam island by electrolysis steam island respectively with hydrogen island, oxygen island connects, tail gas hydrogen manufacturing island and hydrogen island, collecting carbonic anhydride island connects, hydrogen island, collecting carbonic anhydride island is connected with carbon dioxide liquefaction island, oxygen island and space division island, IGCC carbon Oxygen cycle generating island connects, space division island is connected with sial titanium carbon black island, long-distance anti-explosion monitoring island real time and on line monitoring.
6. the device of Graphene tire is produced in a kind of coproduction according to claim 5, it is characterized in that, sial titanium carbon black island is plasmatorch sial titanium carbon black device, including: nitrogen primary air nozzle, nitrogen overfiren air port, high alumina coal gangue powder the first feeding port, high alumina coal gangue powder the second feeding port, hollow cathode, four multianode, cathode circulation cooling water, anode circulation cooling water, catalysis core, insulator, catalyst chamber heat insulation wall, catalyst chamber, DC source, high-voltage pulse power source, high-voltage pulse device, gas-solid separator, sial titanium carbon black bag apparatus system, tail gas recycling and treating device system, long-distance anti-explosion watch-dog, described hollow cathode and four multianode are arranged in order and symmetrical, and the negative pole of described DC source connects with the hollow cathode of side, a multianode, and the anode of DC source connects with all the other multianode of homonymy, it is provided with nitrogen primary air nozzle between described symmetrical hollow cathode, between hollow cathode and multianode, is sequentially provided with nitrogen primary air nozzle, nitrogen overfiren air port, high alumina coal gangue powder the first feeding port, high alumina coal gangue powder the second feeding port, the negative pole of described high-voltage pulse power source connects with the hollow cathode of opposite side, a multianode, and the anode of DC source connects with all the other multianode of homonymy, cellular catalysis core is inserted in plasmatorch sial titanium carbon black device central authorities, and one end is connected with high-voltage pulse device by insulator, cooled cathode circulating water flow is through the hollow cathode of the left and right sides, and anode cooling circulating water flows through the multianode of the left and right sides, nitrogen and high alumina coal gangue powder send catalyst chamber, and catalyst chamber is made up of airtight catalyst chamber heat insulation wall, catalyst chamber is connected with gas-solid separator, gas-solid separator and sial titanium carbon black bag apparatus system, tail gas recycling and treating device system, long-distance anti-explosion watch-dog real time and on line monitoring.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2015109692962 | 2015-12-21 | ||
| CN201510969296 | 2015-12-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105666904A true CN105666904A (en) | 2016-06-15 |
| CN105666904B CN105666904B (en) | 2017-11-17 |
Family
ID=56308511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610211647.8A Active CN105666904B (en) | 2015-12-21 | 2016-04-07 | The technique and its device of graphene tire are produced in a kind of coproduction |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105666904B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108995541A (en) * | 2018-07-17 | 2018-12-14 | 中喜（宁夏）新材料有限公司 | A kind of unmanned unlimited continuation of the journey automobile of graphene solar energy |
| CN109401786A (en) * | 2018-11-08 | 2019-03-01 | 山西普皓环保科技有限公司 | A kind of plasma device handling clinical waste |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB969394A (en) * | 1961-07-14 | 1964-09-09 | Dow Chemical Co | Process for the production of dehydrogenation catalysts |
| RU2183658C1 (en) * | 2001-04-06 | 2002-06-20 | Горлов Евгений Григорьевич | Liquid fuel composition and method of preparation thereof |
| CN1635062A (en) * | 2004-11-29 | 2005-07-06 | 长春市红光洁净能源开发有限公司 | Molded coal made from garbage and process for preparing same |
| CN101671578A (en) * | 2009-09-22 | 2010-03-17 | 武汉凯迪控股投资有限公司 | Combustible material plasma high-temperature gasification technique and equipment thereof |
| CN101768651A (en) * | 2008-09-23 | 2010-07-07 | 樊显理 | Hydrogen metallurgy method |
| CN103243228A (en) * | 2013-06-03 | 2013-08-14 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for producing aluminum silicon titanium alloy with high-titanium blast furnace slag and fly ash as raw materials |
| CN103453542A (en) * | 2013-09-03 | 2013-12-18 | 程礼华 | Power plant carbon and oxygen circulation utilization device and process of device |
| CN103990641A (en) * | 2014-05-14 | 2014-08-20 | 程礼华 | Co-production generation process and device for producing oil from household garbage by virtue of carbon-oxygen circulation |
| CN104531214A (en) * | 2014-12-10 | 2015-04-22 | 程礼华 | Integrated carbon-oxygen-hydrogen circulating device and process thereof for producing solar energy, coal, power, aluminum, fertilizers, carbon, oil and paper |
| CN105039773A (en) * | 2015-09-02 | 2015-11-11 | 程礼华 | Production device and process of graphene alloy materials prepared from high-alumina fly ash |
| CN205601199U (en) * | 2015-12-21 | 2016-09-28 | 程礼华 | Device of graphite alkene tire is prepared in coproduction |
-
2016
- 2016-04-07 CN CN201610211647.8A patent/CN105666904B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB969394A (en) * | 1961-07-14 | 1964-09-09 | Dow Chemical Co | Process for the production of dehydrogenation catalysts |
| RU2183658C1 (en) * | 2001-04-06 | 2002-06-20 | Горлов Евгений Григорьевич | Liquid fuel composition and method of preparation thereof |
| CN1635062A (en) * | 2004-11-29 | 2005-07-06 | 长春市红光洁净能源开发有限公司 | Molded coal made from garbage and process for preparing same |
| CN101768651A (en) * | 2008-09-23 | 2010-07-07 | 樊显理 | Hydrogen metallurgy method |
| CN101671578A (en) * | 2009-09-22 | 2010-03-17 | 武汉凯迪控股投资有限公司 | Combustible material plasma high-temperature gasification technique and equipment thereof |
| CN103243228A (en) * | 2013-06-03 | 2013-08-14 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for producing aluminum silicon titanium alloy with high-titanium blast furnace slag and fly ash as raw materials |
| CN103453542A (en) * | 2013-09-03 | 2013-12-18 | 程礼华 | Power plant carbon and oxygen circulation utilization device and process of device |
| CN103990641A (en) * | 2014-05-14 | 2014-08-20 | 程礼华 | Co-production generation process and device for producing oil from household garbage by virtue of carbon-oxygen circulation |
| CN104531214A (en) * | 2014-12-10 | 2015-04-22 | 程礼华 | Integrated carbon-oxygen-hydrogen circulating device and process thereof for producing solar energy, coal, power, aluminum, fertilizers, carbon, oil and paper |
| CN105039773A (en) * | 2015-09-02 | 2015-11-11 | 程礼华 | Production device and process of graphene alloy materials prepared from high-alumina fly ash |
| CN205601199U (en) * | 2015-12-21 | 2016-09-28 | 程礼华 | Device of graphite alkene tire is prepared in coproduction |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108995541A (en) * | 2018-07-17 | 2018-12-14 | 中喜（宁夏）新材料有限公司 | A kind of unmanned unlimited continuation of the journey automobile of graphene solar energy |
| CN109401786A (en) * | 2018-11-08 | 2019-03-01 | 山西普皓环保科技有限公司 | A kind of plasma device handling clinical waste |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105666904B (en) | 2017-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103259062B (en) | A kind of method of waste and old lithium ion battery reclaiming Graphene | |
| CN102108216A (en) | Method for preparing conductive carbon black and hydrogen by plasma technology | |
| Yuwen et al. | Porous carbon materials derived from discarded COVID-19 masks via microwave solvothermal method for lithium‑sulfur batteries | |
| CN108101043B (en) | Preparation method and application of coal-derived artificial graphite material | |
| CN105017815A (en) | Low-cost and highly-conductive nano-carbon material preparation method | |
| CN103613093B (en) | A kind of hydrogen reducing prepares the method for Graphene | |
| CN109065850A (en) | Three-dimensional graphene silicon carbon cathode composite material and preparation method thereof | |
| CN103579631A (en) | Preparation method for copper foil current collector and application | |
| CN103539103A (en) | Low-cost carbon graphene sheet and preparation method thereof | |
| CN104192826A (en) | Method for improving conductivity of nano carbon material | |
| Tang et al. | Waste plastic to energy storage materials: a state-of-the-art review | |
| CN104386676A (en) | Preparation method of graphene | |
| CN205601199U (en) | Device of graphite alkene tire is prepared in coproduction | |
| CN105666904B (en) | The technique and its device of graphene tire are produced in a kind of coproduction | |
| CN107416820A (en) | A kind of N, O, the preparation method of the netted graphitized carbon nano material of S doping | |
| CN114921258B (en) | Recyclable tire microwave in-situ catalytic pyrolysis method for preparing hydrogen-rich gas | |
| CN115172923A (en) | Method for recovering battery powder through low-temperature pyrolysis desorption | |
| CN118335976A (en) | Coal/asphalt-based hard carbon anode material, preparation method and application | |
| CN102637920B (en) | Application of waste contact as lithium ion battery negative material | |
| CN105449243B (en) | A kind of device and method of fine coal sub-prime conversion coupling Direct Carbon Fuel Cells | |
| CN116253307A (en) | Preparation method of high-purity nano carbon black | |
| WO2024198035A1 (en) | Method and device system for producing ethylene-device steam cracking raw oil and nano charcoal material from waste plastics | |
| CN113651316B (en) | Method and device for preparing graphene and hydrogen by utilizing waste plastics converted by Joule heat | |
| CN111377442A (en) | Method for preparing sulfur-free expanded graphite by using natural fine flakes | |
| CN113774365B (en) | Self-heating carbon-carbon vapor deposition furnace |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: Shogun East Gulou District of Nanjing city of Jiangsu Province, No. 199 210000 Patentee after: Cheng Lihua Address before: Hangzhou City, Zhejiang province 311121 Venus two road Mellon Science Park building 306 Patentee before: Cheng Lihua |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20211018 Granted publication date: 20171117 |