CN105648779B - A kind of losing fibre preventing antistatic finishing agent and preparation method thereof - Google Patents
A kind of losing fibre preventing antistatic finishing agent and preparation method thereof Download PDFInfo
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- CN105648779B CN105648779B CN201610200032.5A CN201610200032A CN105648779B CN 105648779 B CN105648779 B CN 105648779B CN 201610200032 A CN201610200032 A CN 201610200032A CN 105648779 B CN105648779 B CN 105648779B
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- temperature
- losing fibre
- fibre preventing
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 33
- 239000000835 fiber Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 11
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 30
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims abstract description 30
- SUSQOBVLVYHIEX-UHFFFAOYSA-N phenylacetonitrile Chemical compound N#CCC1=CC=CC=C1 SUSQOBVLVYHIEX-UHFFFAOYSA-N 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 229940005605 valeric acid Drugs 0.000 claims abstract description 16
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims abstract description 15
- -1 acetoxyl group Chemical group 0.000 claims abstract description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 14
- YFLRYAVDPKONNX-UHFFFAOYSA-N buramate Chemical compound OCCOC(=O)NCC1=CC=CC=C1 YFLRYAVDPKONNX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229950009824 buramate Drugs 0.000 claims abstract description 14
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 14
- 229920001194 natural rubber Polymers 0.000 claims abstract description 14
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000012948 isocyanate Substances 0.000 claims description 11
- 238000010992 reflux Methods 0.000 claims description 11
- 150000002513 isocyanates Chemical class 0.000 claims description 10
- 101100322583 Caenorhabditis elegans add-2 gene Proteins 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- 201000004384 Alopecia Diseases 0.000 abstract description 10
- 208000024963 hair loss Diseases 0.000 abstract description 10
- 230000003676 hair loss Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 4
- RPDJEKMSFIRVII-UHFFFAOYSA-N oxomethylidenehydrazine Chemical compound NN=C=O RPDJEKMSFIRVII-UHFFFAOYSA-N 0.000 abstract description 2
- 125000003963 dichloro group Chemical group Cl* 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 210000004209 hair Anatomy 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
Abstract
The invention discloses a kind of losing fibre preventing antistatic finishing agent, include each component of following percentage by weight：20 35 parts of phenol modified natural rubber resin, 10 20 parts of diisobutyl phthalate, 8 16 parts of buramate, 12 18 parts of 1 naphthyl, 2 aminoisocyanate, 5 10 parts of triethylene glycol butyl ether, 9 17 parts of 4,4' dichloros methanol, 6 12 parts of positive valeric acid, 3 10 parts of sodium acid carbonate, to 6 13 parts of acetoxyl group benzene acetonitrile, 100 150 parts of water.Preparation-obtained finishing agent possesses good losing fibre preventing, antistatic characteristic, and after conventional water wash, hair loss amount is without dramatically increasing, and effect is obvious.
Description
Technical field
The invention belongs to textile auxiliary finishing agent field, more particularly to a kind of losing fibre preventing antistatic finishing agent and its preparation side
Method.
Background technology
At present on the market, what hairs textile turned into people one has deep love for greatly, and it has, and quality is slim and graceful, soft, color
The advantages of damp light, style, attractive in appearance, and energy warming both haves.However, many hairs textiles exist easy fuds fuddled, hair loss,
The deficiencies such as electrostatic are also easy to produce, the use given people is made troubles.Existing anti-dropout finishing agent, although using rear hair loss amount
Reduce, but after conventional water wash, its hair loss amount is dramatically increased again, and finishing effect almost fails；Also do not send out on the market simultaneously
It is existing at the same losing fibre preventing and suppress electrostatic finishing agent.
The content of the invention
For above technical problem present in prior art, the invention provides a kind of losing fibre preventing antistatic finishing agent and
Its preparation method, preparation-obtained finishing agent possesses good losing fibre preventing, antistatic characteristic, after conventional water wash, hair loss
Amount is without dramatically increasing, and access times are more, and effect is obvious.
Technical scheme：A kind of losing fibre preventing antistatic finishing agent, includes each component of following percentage by weight：Phenol modified natural
20-35 parts of rubber resin, 10-20 parts of diisobutyl phthalate, 8-16 parts of buramate, -2 amino of 1- naphthyls-isocyanic acid
12-18 parts of ester, 5-10 parts of triethylene glycol butyl ether, 9-17 parts of 4,4'- dichloro methanol, positive valeric acid 6-12 parts, sodium acid carbonate
3-10 parts, to 6-13 parts of acetoxyl group benzene acetonitrile, 100-150 parts of water.
Further, 25-30 parts of the phenol modified natural rubber resin, 14-18 parts of diisobutyl phthalate, Bradley
10-13 parts of urethane, -2 amino of 1- naphthyls -13-16 parts of isocyanates, 6-9 parts of triethylene glycol butyl ether, 4,4'- dichloro first
12-15 parts of alcohol, positive valeric acid 8-10 parts, 5-8 parts of sodium acid carbonate, to 8-11 parts of acetoxyl group benzene acetonitrile, 120-130 parts of water.
Further, 26 parts of the phenol modified natural rubber resin, 16 parts of diisobutyl phthalate, buramate 12
Part, -2 amino of 1- naphthyls -14 parts of isocyanates, 8 parts of triethylene glycol butyl ether, 13 parts of 4,4'- dichloros methanol, positive valeric acid 9
Part, 7 parts of sodium acid carbonate, to 10 parts of acetoxyl group benzene acetonitrile, 125 parts of water.
A kind of preparation method of losing fibre preventing antistatic finishing agent, is comprised the following steps that：
（1）By 20-35 parts of phenol modified natural rubber resin, 9-17 parts of 4,4'- dichloro methanol, 8-16 parts of buramate
With 100-150 parts of water 1-2h is heated to reflux at 100-120 DEG C of temperature；
（2）To step（1）Middle 5-10 parts of triethylene glycol butyl ether of addition, positive valeric acid 6-12 parts and to acetoxyl group benzene acetonitrile
6-13 parts, rise temperature to 130-140 DEG C, stirring reaction 40-50min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -12-18 parts of isocyanates and the isobutyl of phthalic acid two
Temperature is risen to 160-200 DEG C, stirring reaction 20-40min by 10-20 parts of ester, continuation；
（4）Treat step（3）When temperature is down to 40-50 DEG C, 3-10 parts of sodium acid carbonate is added, 30-60min is stirred, then treats
It is cooled to room temperature and can obtain the losing fibre preventing antistatic finishing agent.
Further, step（1）Described in temperature be 115 DEG C, be heated to reflux 80min.
Further, step（2）Described in temperature be 135 DEG C, stir speed (S.S.) is 150-200r/min, stirring reaction time
For 46min.
Further, step（3）Described in temperature be 175 DEG C, stir speed (S.S.) is 250-300r/min, and mixing time is
28min。
Further, step（4）Described in temperature be 43 DEG C, stir speed (S.S.) is 300-400r/min, and mixing time is
45min。
Beneficial effect：
A kind of preparation method of losing fibre preventing antistatic finishing agent of the present invention, adds buramate, 1- naphthyls -2 in the process
Amino-isocyanates and to acetoxyl group benzene acetonitrile, finishing agent is prepared by techniques such as heating, stirring, mixing；The arrangement
Agent possesses good losing fibre preventing, antistatic characteristic, and after conventional water wash, hair loss amount can be used often without dramatically increasing,
Effect is obvious.
Embodiment
Embodiment 1
（1）By 100 parts of 20 parts of phenol modified natural rubber resin, 9 parts of 4,4'- dichloros methanol, 8 parts of buramate and water
1h is heated to reflux at 100 DEG C of temperature；
（2）To step（1）Middle 5 parts of triethylene glycol butyl ether of addition, 6 parts of positive valeric acid and to 6 parts of acetoxyl group benzene acetonitrile, rise
High-temperature is to 130 DEG C, with speed 150r/min stirring reactions 40min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -12 parts of isocyanates and diisobutyl phthalate 10
Part, temperature is risen to 160 DEG C by continuation, with speed 250r/min stirring reactions 20min；
（4）Treat step（3）When temperature is down to 40 DEG C, 3 parts of sodium acid carbonate is added, 30min is stirred with speed 300r/min, with
After be cooled to room temperature and can obtain the losing fibre preventing antistatic finishing agent.
Comparative example 1
（1）By 100 parts of 20 parts of phenol modified natural rubber resin, 9 parts of 4,4'- dichloros methanol and water in 100 DEG C of temperature
Under be heated to reflux 1h；
（2）To step（1）Middle to add 5 parts of triethylene glycol butyl ether and positive 6 parts of valeric acid, rise temperature is to 130 DEG C, with speed
150r/min stirring reactions 40min；
（3）To step（2）In continuously add 10 parts of diisobutyl phthalate, temperature is risen to 160 DEG C by continuation, with speed
Rate 250r/min stirring reactions 20min；
（4）Treat step（3）When temperature is down to 40 DEG C, 3 parts of sodium acid carbonate is added, 30min is stirred with speed 300r/min, with
After be cooled to room temperature and can obtain finishing agent.
Embodiment 2
（1）By 35 parts of phenol modified natural rubber resin, 17 parts of 4,4'- dichloros methanol, 16 parts of buramate and water 150
Part it is heated to reflux 2h at 120 DEG C of temperature；
（2）To step（1）It is middle to add 10 parts of triethylene glycol butyl ether, 12 parts of positive valeric acid and to acetoxyl group benzene acetonitrile 13
Part, rise temperature is to 140 DEG C, with speed 200r/min stirring reactions 50min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -18 parts of isocyanates and diisobutyl phthalate 20
Part, temperature is risen to 200 DEG C by continuation, with speed 300r/min stirring reactions 40min；
（4）Treat step（3）When temperature is down to 50 DEG C, 10 parts of sodium acid carbonate is added, 60min is stirred with speed 400r/min,
Then being cooled to room temperature can obtain the losing fibre preventing antistatic finishing agent.
Comparative example 2
（1）By 150 parts of 35 parts of phenol modified natural rubber resin, 17 parts of 4,4'- dichloros methanol and water in 120 DEG C of temperature
Under be heated to reflux 2h；
（2）To step（1）Middle to add 10 parts of triethylene glycol butyl ether and positive 12 parts of valeric acid, rise temperature is to 140 DEG C, with speed
Rate 200r/min stirring reactions 50min；
（3）To step（2）In continuously add 20 parts of diisobutyl phthalate, temperature is risen to 200 DEG C by continuation, with speed
Rate 300r/min stirring reactions 40min；
（4）Treat step（3）When temperature is down to 50 DEG C, 10 parts of sodium acid carbonate is added, 60min is stirred with speed 400r/min,
Then being cooled to room temperature can obtain finishing agent.
Embodiment 3
（1）By 25 parts of phenol modified natural rubber resin, 12 parts of 4,4'- dichloros methanol, 10 parts of buramate and water 120
Part it is heated to reflux 1h at 100 DEG C of temperature；
（2）To step（1）Middle 6 parts of triethylene glycol butyl ether of addition, 8 parts of positive valeric acid and to 8 parts of acetoxyl group benzene acetonitrile, rise
High-temperature is to 130 DEG C, with speed 150r/min stirring reactions 50min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -13 parts of isocyanates and diisobutyl phthalate 14
Part, temperature is risen to 160 DEG C by continuation, with speed 250r/min stirring reactions 20min；
（4）Treat step（3）When temperature is down to 40 DEG C, 5 parts of sodium acid carbonate is added, 30min is stirred with speed 400r/min, with
After be cooled to room temperature and can obtain the losing fibre preventing antistatic finishing agent.
Embodiment 4
（1）By 30 parts of phenol modified natural rubber resin, 15 parts of 4,4'- dichloros methanol, 13 parts of buramate and water 130
Part it is heated to reflux 2h at 120 DEG C of temperature；
（2）To step（1）Middle 9 parts of triethylene glycol butyl ether of addition, 10 parts of positive valeric acid and to 11 parts of acetoxyl group benzene acetonitrile,
Temperature is raised to 140 DEG C, with speed 200r/min stirring reactions 40min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -16 parts of isocyanates and diisobutyl phthalate 18
Part, temperature is risen to 200 DEG C by continuation, with speed 300r/min stirring reactions 40min；
（4）Treat step（3）When temperature is down to 50 DEG C, 8 parts of sodium acid carbonate is added, 60min is stirred with speed 300r/min, with
After be cooled to room temperature and can obtain the losing fibre preventing antistatic finishing agent.
Embodiment 5
（1）By 26 parts of phenol modified natural rubber resin, 13 parts of 4,4'- dichloros methanol, 12 parts of buramate and water 125
Part it is heated to reflux 80min at 115 DEG C of temperature；
（2）To step（1）Middle 8 parts of triethylene glycol butyl ether of addition, 9 parts of positive valeric acid and to 10 parts of acetoxyl group benzene acetonitrile,
Temperature is raised to 135 DEG C, with speed 180r/min stirring reactions 46min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -14 parts of isocyanates and diisobutyl phthalate 16
Part, temperature is risen to 175 DEG C by continuation, with speed 260r/min stirring reactions 28min；
（4）Treat step（3）When temperature is down to 43 DEG C, 7 parts of sodium acid carbonate is added, 45min is stirred with speed 350r/min, with
After be cooled to room temperature and can obtain the losing fibre preventing antistatic finishing agent.
Performance test is carried out to the finishing agent obtained by each embodiment above and comparative example, hair loss measures examination according to weaving
Professional standard FZ/T01046-1996, hair loss amount before and after test is arranged；Antistatic test is weaved according to GB-T12703.1-2008
Product static electricity testing method.As a result it is as follows：
| Experiment | Electrostatic pressure half-life period（s） | Hair loss amount（mg/10cm2） | Hair loss amount after washing（mg/10cm2） |
| Embodiment 1 | 1.8 | 5.1 | 5.3 |
| Comparative example 1 | 15 | 12.8 | 50.5 |
| Embodiment 2 | 1.2 | 4.8 | 5.0 |
| Comparative example 2 | 14 | 11.4 | 45.3 |
| Embodiment 3 | 1.0 | 4.1 | 4.3 |
| Embodiment 4 | 0.8 | 3.7 | 4.0 |
| Embodiment 5 | 0.6 | 3.5 | 3.7 |
Claims (8)
1. a kind of losing fibre preventing antistatic finishing agent, it is characterised in that include each component of following percentage by weight：Phenol modified natural
20-35 parts of rubber resin, 10-20 parts of diisobutyl phthalate, 8-16 parts of buramate, -2 amino of 1- naphthyls-isocyanic acid
12-18 parts of ester, 5-10 parts of triethylene glycol butyl ether, 9-17 parts of 4,4'- dichloro methanol, positive valeric acid 6-12 parts, sodium acid carbonate
3-10 parts, to 6-13 parts of acetoxyl group benzene acetonitrile, 100-150 parts of water.
2. a kind of losing fibre preventing antistatic finishing agent according to claim 1, it is characterised in that the phenol modified natural rubber
25-30 parts of resin, 14-18 parts of diisobutyl phthalate, 10-13 parts of buramate, -2 amino of 1- naphthyls-isocyanates
13-16 parts, 6-9 parts of triethylene glycol butyl ether, 12-15 parts of 4,4'- dichloro methanol, positive valeric acid 8-10 parts, sodium acid carbonate 5-8
Part, to 8-11 parts of acetoxyl group benzene acetonitrile, 120-130 parts of water.
3. a kind of losing fibre preventing antistatic finishing agent according to claim 2, it is characterised in that the phenol modified natural rubber
26 parts of resin, 16 parts of diisobutyl phthalate, 12 parts of buramate, -2 amino of 1- naphthyls -14 parts of isocyanates, three second two
8 parts of alcohol monobutyl ether, 13 parts of 4,4'- dichloros methanol, 9 parts of positive valeric acid, 7 parts of sodium acid carbonate, to 10 parts of acetoxyl group benzene acetonitrile,
125 parts of water.
4. a kind of preparation method of losing fibre preventing antistatic finishing agent, it is characterised in that comprise the following steps that：
（1）By 20-35 parts of phenol modified natural rubber resin, 9-17 parts of 4,4'- dichloro methanol, 8-16 parts of buramate and water
100-150 parts are heated to reflux 1-2h at 100-120 DEG C of temperature；
（2）To step（1）Middle 5-10 parts of triethylene glycol butyl ether of addition, positive valeric acid 6-12 parts and to acetoxyl group benzene acetonitrile 6-13
Part, rise temperature to 130-140 DEG C, stirring reaction 40-50min；
（3）To step（2）In continuously add -2 amino of 1- naphthyls -12-18 parts of isocyanates and diisobutyl phthalate 10-
20 parts, temperature is risen to 160-200 DEG C, stirring reaction 20-40min by continuation；
（4）Treat step（3）When temperature is down to 40-50 DEG C, 3-10 parts of sodium acid carbonate is added, 30-60min is stirred, it is then to be cooled
It is that can obtain the losing fibre preventing antistatic finishing agent to room temperature.
5. a kind of preparation method of losing fibre preventing antistatic finishing agent according to claim 4, it is characterised in that step（1）
Described in temperature be 115 DEG C, be heated to reflux 80min.
6. a kind of preparation method of losing fibre preventing antistatic finishing agent according to claim 4, it is characterised in that step（2）
Described in temperature be 135 DEG C, stir speed (S.S.) is 150-200r/min, and the stirring reaction time is 46min.
7. a kind of preparation method of losing fibre preventing antistatic finishing agent according to claim 4, it is characterised in that step（3）
Described in temperature be 175 DEG C, stir speed (S.S.) is 250-300r/min, and mixing time is 28min.
8. a kind of preparation method of losing fibre preventing antistatic finishing agent according to claim 4, it is characterised in that step（4）
Described in temperature be 43 DEG C, stir speed (S.S.) is 300-400r/min, and mixing time is 45min.
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| CN107938366A (en) * | 2017-11-30 | 2018-04-20 | 英泰时尚服饰（苏州）有限公司 | A kind of antistatic microcapsule dressing agent and preparation method thereof |
| CN115434147B (en) * | 2021-05-12 | 2024-02-13 | 菏泽市源林川服饰有限公司 | Anti-falling Mao Shanhu velvet fabric and preparation method thereof |
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| CN103114445A (en) * | 2012-11-08 | 2013-05-22 | 吴江市钱氏纺织有限公司 | Shrink-proof finishing agent for wool fabrics and preparation method thereof |
| CN103643517B (en) * | 2013-11-22 | 2015-05-27 | 江苏波波熊纺织品有限公司 | Fiber fabric antistatic finishing agent and preparation method thereof |
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Effective date of registration: 20231129 Address after: No. 2829 Yuanyuan Road, Shengze Town, Wujiang District, Suzhou City, Jiangsu Province, 215000 (Group 4, Bali Village) Patentee after: Suzhou Boze Textile Co.,Ltd. Address before: Group 4, Bali Village, Shengze Town, Wujiang, Suzhou City, Jiangsu Province, China Patentee before: WUJIANG FUHUIYUAN HOME TEXTILE CO.,LTD. |