CN105647117A - Carbon fiber composite compound - Google Patents

Carbon fiber composite compound Download PDF

Info

Publication number
CN105647117A
CN105647117A CN201510946948.0A CN201510946948A CN105647117A CN 105647117 A CN105647117 A CN 105647117A CN 201510946948 A CN201510946948 A CN 201510946948A CN 105647117 A CN105647117 A CN 105647117A
Authority
CN
China
Prior art keywords
carbon fiber
accounts
fiber
chemical compound
germicide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201510946948.0A
Other languages
Chinese (zh)
Inventor
王举
贾自琴
王梦丽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Original Assignee
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd filed Critical ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority to CN201510946948.0A priority Critical patent/CN105647117A/en
Publication of CN105647117A publication Critical patent/CN105647117A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/06Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

The invention provides a carbon fiber composite compound, which comprises carbon fiber, epoxy resin, silicic acid fiber, polyethylene and additives. The carbon fiber is microcrystalline graphite material prepared from a natural fiber by carbonization and graphitization treatment. The invention has the beneficial effects that carbon fiber composite compound provided by the invention remains small coefficient of thermal expansion in a wide temperature span range, has the characteristics of high strength, high temperature resistance, corrosion resistance and fatigue resistance; and the composite compound prepared from carbon fiber and silicic acid fiber has the characteristics of strong compression resistance and durability.

Description

Carbon fiber complex chemical compound
Technical field
The present invention relates to carbon fiber complex chemical compound.
Background technology
Carbon fiber complex chemical compound be complex chemical compound is applied more extensive, a kind of complex chemical compound that performance is comparatively excellent, its specific tenacity, specific modulus overall target, existing structure material is the highest, having the field of strict demand in density, rigidity, weight, fatigue characteristic etc. and requiring the occasion that high temperature, chemical stability are high, carbon fiber complex chemical compound all has much advantage.
But every general character of the thermal expansion of existing carbon fiber complex chemical compound is poor, the coefficient of expansion of elastomerics under multiple temperature condition changes greatly, and under lower temperature conditions, molecular rupture, produces thermally splitting.
Summary of the invention
In view of the defect that prior art exists, it is an object of the invention to provide a kind of less at bigger temperature span scope thermal expansion coefficient, there is the carbon fiber complex chemical compound of high flexibility, high strength.
For achieving the above object, the technology used in the present invention solution: a kind of carbon fiber complex chemical compound, its composition comprises carbon fiber, epoxy resin, silicate fiber, polyethylene and auxiliary agent, described carbon fiber is the micro crystal graphite material obtained through carbonization and graphitization processing by natural fiber, described auxiliary agent comprises toughener, toughner, antioxidant, antiseptic-germicide and thermo-stabilizer, described toughener is boron fibre, described toughner is liquid polyester rubber, described antioxidant is to second phenol and dicyclopentadiene butylation product, described antiseptic-germicide is manganese oxide, described thermo-stabilizer is Dythal.
Described complex chemical compound composition by quality proportioning is: carbon fiber accounts for 35-48%, and epoxy resin accounts for 16-22%, and silicate fiber accounts for 12-16%, polyethylene accounts for 8-12%, toughener 3-5%, and toughner accounts for 2-4%, antioxidant 1-3%, antiseptic-germicide account for 1-2%, and thermo-stabilizer accounts for 2-3%.
Described complex chemical compound composition is preferably by quality proportioning: carbon fiber accounts for 44%, and epoxy resin accounts for 20%, and silicate fiber accounts for 14%, and polyethylene accounts for 10%, toughener 4%, and toughner accounts for 3%, and antioxidant 2%, antiseptic-germicide account for 1%, and thermo-stabilizer accounts for 2%.
The mean diameter of described carbon fiber is 10 48nm, and mean length is 5 15um, fibre density: 1.74-1.79G/cm, elongation (%) >=1.5, carbon content: >=95%, in the temperature range of-60 DEG C 248 DEG C, average coefficient of linear expansion is less than 100ppm/k.
The invention has the beneficial effects as follows: the present invention provides a kind of carbon fiber complex chemical compound, less thermal expansivity is still kept within the scope of bigger temperature span, there is the characteristics such as intensity height, high temperature resistant, corrosion-resistant and resistance to fatigue be good, the complex chemical compound being mixed with carbon fiber and silicate fiber, also has that resistance to compression is strong, the characteristic of durable.
Embodiment
A kind of carbon fiber complex chemical compound, its composition comprises carbon fiber, epoxy resin, silicate fiber, polyethylene and auxiliary agent, described carbon fiber is the micro crystal graphite material obtained through carbonization and graphitization processing by natural fiber, described auxiliary agent comprises toughener, toughner, antioxidant, antiseptic-germicide and thermo-stabilizer, described toughener is boron fibre, described toughner is liquid polyester rubber, described antioxidant is to second phenol and dicyclopentadiene butylation product, described antiseptic-germicide is manganese oxide, and described thermo-stabilizer is Dythal.
Described complex chemical compound composition by quality proportioning is: carbon fiber accounts for 35-48%, and epoxy resin accounts for 16-22%, and silicate fiber accounts for 12-16%, polyethylene accounts for 8-12%, toughener 3-5%, and toughner accounts for 2-4%, antioxidant 1-3%, antiseptic-germicide account for 1-2%, and thermo-stabilizer accounts for 2-3%.
Described complex chemical compound composition is preferably by quality proportioning: carbon fiber accounts for 44%, and epoxy resin accounts for 20%, and silicate fiber accounts for 14%, and polyethylene accounts for 10%, toughener 4%, and toughner accounts for 3%, and antioxidant 2%, antiseptic-germicide account for 1%, and thermo-stabilizer accounts for 2%.
The mean diameter of described carbon fiber is 10 48nm, and mean length is 5 15um, fibre density: 1.74-1.79G/cm, elongation (%) >=1.5, carbon content: >=95%, in the temperature range of-60 DEG C 248 DEG C, average coefficient of linear expansion is less than 100ppm/k.
The present invention provides a kind of carbon fiber complex chemical compound, less thermal expansivity is still kept within the scope of bigger temperature span, there is the characteristics such as intensity height, high temperature resistant, corrosion-resistant and resistance to fatigue be good, the complex chemical compound being mixed with carbon fiber and silicate fiber, also has that resistance to compression is strong, the characteristic of durable.

Claims (1)

1. carbon fiber complex chemical compound, its composition comprises carbon fiber, epoxy resin, silicate fiber, polyethylene and auxiliary agent, it is characterized in that, described carbon fiber is the micro crystal graphite material obtained through carbonization and graphitization processing by natural fiber, described auxiliary agent comprises toughener, toughner, antioxidant, antiseptic-germicide and thermo-stabilizer, described toughener is boron fibre, described toughner is liquid polyester rubber, described antioxidant is to second phenol and dicyclopentadiene butylation product, described antiseptic-germicide is manganese oxide, and described thermo-stabilizer is Dythal;
Described complex chemical compound composition by quality proportioning is: carbon fiber accounts for 35-48%, and epoxy resin accounts for 16-22%, and silicate fiber accounts for 12-16%, polyethylene accounts for 8-12%, toughener 3-5%, and toughner accounts for 2-4%, antioxidant 1-3%, antiseptic-germicide account for 1-2%, and thermo-stabilizer accounts for 2-3%.
CN201510946948.0A 2015-12-15 2015-12-15 Carbon fiber composite compound Withdrawn CN105647117A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510946948.0A CN105647117A (en) 2015-12-15 2015-12-15 Carbon fiber composite compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510946948.0A CN105647117A (en) 2015-12-15 2015-12-15 Carbon fiber composite compound

Publications (1)

Publication Number Publication Date
CN105647117A true CN105647117A (en) 2016-06-08

Family

ID=56476594

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510946948.0A Withdrawn CN105647117A (en) 2015-12-15 2015-12-15 Carbon fiber composite compound

Country Status (1)

Country Link
CN (1) CN105647117A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109534772A (en) * 2019-01-16 2019-03-29 山东国帅节能环保科技有限公司 A kind of heat superconducting porcelain film composite material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109534772A (en) * 2019-01-16 2019-03-29 山东国帅节能环保科技有限公司 A kind of heat superconducting porcelain film composite material and preparation method thereof
CN109534772B (en) * 2019-01-16 2022-03-18 上海欧尔塔特种印刷科技有限公司 Novel superconducting ceramic film composite material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN110317522A (en) A kind of solventless epoxy coating and preparation method thereof and the application in oil-gas pipeline in anti-corrosion
CN105647117A (en) Carbon fiber composite compound
CN108892863A (en) A kind of heat-resisting material
CN103183992A (en) Fluorocarbon coating for solar energy battery back panel
CN104558986A (en) Modified PTFE and preparation method thereof
CN105482358A (en) High temperature-resistant glass fiber reinforced plastic composite material
CN113897029B (en) Glass fiber reinforced plastic prepreg for high-speed fan blade
CN106750669B (en) A kind of water pump of resistance to anti-icing fluid gasket and preparation method thereof
CN104017290A (en) Novel, heat-resistant, wear-resistant and low-temperature resistant PVC (Polyvinyl Chloride) pipe material
CN104559006A (en) Preparation method of low-temperature-resistant and scratch-resistant automobile zip-fastener sheath special material
CN104017288A (en) Heat-resistant, wear-resistant and aging-resistant PVC (Polyvinyl Chloride) elastomer material
CN109504254B (en) Concrete anticorrosive material and preparation method thereof
CN104004239A (en) High-performance screw pump stator rubber composition
CN103881191A (en) Carbon-fiber-reinforced polyethylene master batch
CN108912255A (en) A kind of fiber intercalation carbon nanotube and preparation method thereof
CN105440587A (en) High-strength nano carbonfibercomposite material
CN103289223B (en) Novel heat, wear and low temperature resistant PVC pipe
CN202090307U (en) Protective railing for highway
CN105199579A (en) Permeation type anti-corrosion sealing coating
CN104745977A (en) High temperature heat-resisting die steel
KR101401093B1 (en) Carbon fiber bead insulator and preparation method thereof
CN103087475A (en) Carbon fiber reinforced composite material and preparation method thereof
CN104017287A (en) Heat-resistant, wear-resistant and aging-resistant PVC (Polyvinyl Chloride) elastomer material
CN207864370U (en) Pressure vessel high intensity fixing bolt
CN106336826A (en) Polypropylene-reinforced fiber anticorrosive adhesive tape and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20160608

WW01 Invention patent application withdrawn after publication