CN105647070A - Flame-retardant packaging plastic film - Google Patents
Flame-retardant packaging plastic film Download PDFInfo
- Publication number
- CN105647070A CN105647070A CN201610213692.7A CN201610213692A CN105647070A CN 105647070 A CN105647070 A CN 105647070A CN 201610213692 A CN201610213692 A CN 201610213692A CN 105647070 A CN105647070 A CN 105647070A
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- Prior art keywords
- parts
- fire
- retardant
- thin film
- packing plastics
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2234—Oxides; Hydroxides of metals of lead
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Abstract
The invention discloses a flame-retardant packaging plastic film. The flame-retardant packaging plastic film comprises components in parts by weight as follows: 90-100 parts of polyvinyl chloride, 30-50 parts of dioctyl phthalate, 0.1-0.5 parts of a complexing agent, 0.4-0.8 parts of an amide lubricant, 3-5 parts of titanium dioxide, 0.2-0.4 parts of lead oxide, 0.2-0.4 parts of lead sulfate and 1-5 parts of halogenated phosphate. Through the scheme, the flame-retardant packaging plastic film has the flame retardance, original mechanical properties of the plastic film are kept, safety in industrial use for buildings, aerospace, traffic and the like and in life use for packaging materials and the like is guaranteed, and adverse conditions are prevented.
Description
Technical field
The present invention relates to modified plastics plastic cement field, particularly relate to a kind of packing plastics thin film that can be fire-retardant.
Background technology
Flexible package refers in filling or taking out after shape thing, the packaging that container shapes can change. Plastic sheeting is the one of flexible package, generally at the slice plastic of below 0.25mm, thickness is called thin film. Plastic sheeting is transparent, pliable and tough, has good resistance to water, moisture resistance and gas barrier property, mechanical strength better, stable chemical nature, grease resistance, it is easy to be beautifully printed picture and text, it is possible to heat-sealing bag. Existing plastic sheeting fire resistance is bad, is easy to burning, does not have safety when catching fire.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of packing plastics thin film that can be fire-retardant, can effectively prevent the burning of plastic sheeting.
For solving above-mentioned technical problem, the technical scheme that the present invention adopts is: provide a kind of packing plastics thin film that can be fire-retardant, including component have polrvinyl chloride, dioctyl phthalate, chelating agent, amide-type lubricant, titanium dioxide, lead oxide, lead sulfate and Firemaster 836, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 90-100 part, dioctyl phthalate 30-50 part, chelating agent 0.1-0.5 part, amide-type lubricant 0.4-0.8 part, titanium dioxide 3-5 part, lead oxide 0.2-0.4 part, lead sulfate 0.2-0.4 part, Firemaster 836 1-5 part.
In a preferred embodiment of the present invention, described chelating agent is one or more in triethanolamine, edetate, diethylenetriamine pentacarboxylic acid salt.
In a preferred embodiment of the present invention, described can be fire-retardant the hot strength of packing plastics thin film be 10-15MPa.
In a preferred embodiment of the present invention, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 95 parts, dioctyl phthalate 40 parts, chelating agent 0.3 part, amide-type lubricant 0.6 part, titanium dioxide 4 parts, 0.3 part of lead oxide, lead sulfate 0.3 part, Firemaster 836 3 parts.
The invention has the beneficial effects as follows: the present invention can be fire-retardant packing plastics thin film, plastic sheeting is made to have flame resistance, maintain the original mechanical performance of plastic sheeting, ensure that the safety of the uses in life such as and packaging material industrial in building, Aero-Space, traffic etc., prevent the generation of rough sledding.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments. Based on the embodiment in the present invention, all other embodiments that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment one:
A kind of packing plastics thin film that can be fire-retardant is provided, including component have polrvinyl chloride, dioctyl phthalate, chelating agent, amide-type lubricant, titanium dioxide, lead oxide, lead sulfate and Firemaster 836, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 95 parts, dioctyl phthalate 40 parts, chelating agent 0.3 part, amide-type lubricant 0.6 part, titanium dioxide 4 parts, 0.3 part of lead oxide, lead sulfate 0.3 part, Firemaster 836 3 parts. Described chelating agent is diethylenetriamine pentacarboxylic acid salt. Described can be fire-retardant the hot strength of packing plastics thin film be 13MPa.
Embodiment two:
A kind of packing plastics thin film that can be fire-retardant is provided, including component have polrvinyl chloride, dioctyl phthalate, chelating agent, amide-type lubricant, titanium dioxide, lead oxide, lead sulfate and Firemaster 836, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 90 parts, dioctyl phthalate 50 parts, chelating agent 0.1 part, amide-type lubricant 0.4 part, titanium dioxide 5 parts, 0.4 part of lead oxide, lead sulfate 0.4 part, Firemaster 836 1 part. Described chelating agent is triethanolamine. Described can be fire-retardant the hot strength of packing plastics thin film be 10MPa.
Embodiment three:
A kind of packing plastics thin film that can be fire-retardant is provided, including component have polrvinyl chloride, dioctyl phthalate, chelating agent, amide-type lubricant, titanium dioxide, lead oxide, lead sulfate and Firemaster 836, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 100 parts, dioctyl phthalate 30 parts, chelating agent 0.5 part, amide-type lubricant 0.8 part, titanium dioxide 3 parts, 0.2 part of lead oxide, lead sulfate 0.2 part, Firemaster 836 5 parts. Described chelating agent is edetate. Described can be fire-retardant the hot strength of packing plastics thin film be 15MPa.
The invention has the beneficial effects as follows:
One, described can be fire-retardant packing plastics thin film make plastic sheeting have flame resistance, maintain the original mechanical performance of plastic sheeting;
Two, described can be fire-retardant packing plastics thin film ensure that and the safety of the uses in life such as and packaging material industrial in building, Aero-Space, traffic etc. prevent the generation of rough sledding.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the present invention to make or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical field, all in like manner include in the scope of patent protection of the present invention.
Claims (4)
1. one kind can be fire-retardant packing plastics thin film, it is characterized in that, including component have polrvinyl chloride, dioctyl phthalate, chelating agent, amide-type lubricant, titanium dioxide, lead oxide, lead sulfate and Firemaster 836, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 90-100 part, dioctyl phthalate 30-50 part, chelating agent 0.1-0.5 part, amide-type lubricant 0.4-0.8 part, titanium dioxide 3-5 part, lead oxide 0.2-0.4 part, lead sulfate 0.2-0.4 part, Firemaster 836 1-5 part.
2. according to claim 1 can be fire-retardant packing plastics thin film, it is characterised in that described chelating agent is one or more in triethanolamine, edetate, diethylenetriamine pentacarboxylic acid salt.
3. according to claim 1 can be fire-retardant packing plastics thin film, it is characterised in that described can be fire-retardant the hot strength of packing plastics thin film be 10-15MPa.
4. according to claim 1 can be fire-retardant packing plastics thin film, it is characterized in that, described can be fire-retardant packing plastics thin film with parts by weight, including component have: polrvinyl chloride 95 parts, dioctyl phthalate 40 parts, chelating agent 0.3 part, amide-type lubricant 0.6 part, titanium dioxide 4 parts, 0.3 part of lead oxide, lead sulfate 0.3 part, Firemaster 836 3 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610213692.7A CN105647070A (en) | 2016-04-08 | 2016-04-08 | Flame-retardant packaging plastic film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610213692.7A CN105647070A (en) | 2016-04-08 | 2016-04-08 | Flame-retardant packaging plastic film |
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CN105647070A true CN105647070A (en) | 2016-06-08 |
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CN201610213692.7A Pending CN105647070A (en) | 2016-04-08 | 2016-04-08 | Flame-retardant packaging plastic film |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09309993A (en) * | 1996-05-22 | 1997-12-02 | Sumitomo Bakelite Co Ltd | Vinyl chloride resin sheet |
CN1448423A (en) * | 2003-04-29 | 2003-10-15 | 佛山塑料集团股份有限公司 | Soft PVCcalendered film and and its manufacture |
CN101061165A (en) * | 2004-11-22 | 2007-10-24 | 索维公司 | Process for the purification of vinyl chloride polymers (pvc) from heavy metals |
CN102174235A (en) * | 2011-03-21 | 2011-09-07 | 宜兴市光辉包装材料有限公司 | Calcium/zinc thermal stabilizer polyvinyl chloride transparent hard film and preparation method thereof |
CN102260379A (en) * | 2010-05-24 | 2011-11-30 | 深圳职业技术学院 | composite heat stabilizer and method for processing chlorine-containing polymer |
CN102942749A (en) * | 2012-10-12 | 2013-02-27 | 福建师范大学 | Preparation method for PVC photoluminescence soft film by using light-emitting composite heat stabilizer |
CN103172947A (en) * | 2013-03-14 | 2013-06-26 | 安徽天润塑业有限公司 | Polyvinyl chloride (PVC) plastic profiled bar for indoor window margin and door margin decoration and preparation method thereof |
CN105440485A (en) * | 2015-12-10 | 2016-03-30 | 安徽宁国市高新管业有限公司 | High-impact PVC pipe |
-
2016
- 2016-04-08 CN CN201610213692.7A patent/CN105647070A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09309993A (en) * | 1996-05-22 | 1997-12-02 | Sumitomo Bakelite Co Ltd | Vinyl chloride resin sheet |
CN1448423A (en) * | 2003-04-29 | 2003-10-15 | 佛山塑料集团股份有限公司 | Soft PVCcalendered film and and its manufacture |
CN101061165A (en) * | 2004-11-22 | 2007-10-24 | 索维公司 | Process for the purification of vinyl chloride polymers (pvc) from heavy metals |
CN102260379A (en) * | 2010-05-24 | 2011-11-30 | 深圳职业技术学院 | composite heat stabilizer and method for processing chlorine-containing polymer |
CN102174235A (en) * | 2011-03-21 | 2011-09-07 | 宜兴市光辉包装材料有限公司 | Calcium/zinc thermal stabilizer polyvinyl chloride transparent hard film and preparation method thereof |
CN102942749A (en) * | 2012-10-12 | 2013-02-27 | 福建师范大学 | Preparation method for PVC photoluminescence soft film by using light-emitting composite heat stabilizer |
CN103172947A (en) * | 2013-03-14 | 2013-06-26 | 安徽天润塑业有限公司 | Polyvinyl chloride (PVC) plastic profiled bar for indoor window margin and door margin decoration and preparation method thereof |
CN105440485A (en) * | 2015-12-10 | 2016-03-30 | 安徽宁国市高新管业有限公司 | High-impact PVC pipe |
Non-Patent Citations (4)
Title |
---|
严家发等: ""三乙醇胺改性PVC性能的研究"", 《塑料助剂》 * |
张玉龙等: "《塑料配方与制备手册》", 30 June 2010, 北京:化学工业出版社 * |
李文彬等: "《精细化工生产技术》", 31 January 2014, 北京:中央广播电视大学出版社 * |
黄云翔: ""软质聚氯乙烯塑料的阻燃处理"", 《中国氯碱》 * |
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Application publication date: 20160608 |
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