CN105646970A - Non-slip and folding-resistant sole material and preparing method thereof - Google Patents
Non-slip and folding-resistant sole material and preparing method thereof Download PDFInfo
- Publication number
- CN105646970A CN105646970A CN201610037393.2A CN201610037393A CN105646970A CN 105646970 A CN105646970 A CN 105646970A CN 201610037393 A CN201610037393 A CN 201610037393A CN 105646970 A CN105646970 A CN 105646970A
- Authority
- CN
- China
- Prior art keywords
- parts
- sole
- shoe
- folding material
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a non-slip and folding-resistant sole material. The non-slip and folding-resistant sole material is prepared from, by weight, 20-30 parts of butadiene styrene rubber, 20-30 parts of natural rubber, 5-15 parts of PVC resin, 5-12 parts of petroleum resin, 2-5 parts of phenyl salicylate, 5-10 parts of poly(butylene succinate), 1-3 parts of sodium pyrophosphate, 2-5 parts of dimethylsilicone fluid, 0.5-1 part of nanometer titanium oxide, 5-6 parts of calcium stearate, 3-6 parts of N220 carbon black, 1.5-2 parts of an accelerator CZ, 1-2 parts of a coupling agent and 1.5-3.5 parts of an anti-aging agent. The invention discloses a preparing method of the sole material. The sole material is good in non-slip performance, large in elasticity, resistant to folding and good in breathability, and has a certain antibacterial capability. In addition, the method is simple in process, easy to implement and low in cost.
Description
Technical field:
The present invention relates to material for sole of shoe field, be specifically related to a kind of anti-slip folding material for sole of shoe.
Background technology:
Continuous progress along with socioeconomic development and scientific level, people often there has also been more demand for comfortableness and the safety of footwear, such as the requirement of the performances such as the on-slip of footwear, wear-resisting and damping is improved constantly, and the antiskid property of sole directly influences safety when footwear wear, antiskid property is poor, people is easily skidded wrestling when walking, particularly on wet, light, sliding road surface.
The footwear that China is maximum in the world produce and exported country; annual footwear yield accounts for the whole world more than 50%; external in order to protect environment and personal safety to consider in recent years; improve constantly the requirement of footwear standard; and China's footwear outlet has been carried out certain restriction; and the current footwear material of China and technology, the requirement specified with these technology, environmental standard remains in a certain distance. Therefore, the on-slip characteristic of footwear how is improved, it is ensured that the safety of consumer, it has also become the focus that shoe industry and footwear researcher are paid close attention to.
Chinese patent (201410292697.4) discloses a kind of high abrasion anti-slip sole composite, including natural rubber, maleic acid modified natural rubber, butadiene-styrene rubber, Malin's acid modified styrene butadiene rubber, butadiene rubber, white carbon black, terpene resin, phenolic resin, aromatic naphtha, zinc oxide, age resistor, accelerant CZ and sulfur, further butadiene-styrene rubber is modified by maleic anhydride free in Malin's acid modified styrene butadiene rubber, maleic acid modified natural rubber, so that each raw material crosslinked action strengthens, wear-resisting, the slip resistance of material for sole of shoe are improved.
Summary of the invention:
It is an object of the invention to provide a kind of anti-slip folding material for sole of shoe, this material antiskid property is good, elastic big, folding, and good permeability has certain antibacterial ability.
The preparation method that it is a further object to provide this material for sole of shoe, the method technique is simple, it is easy to operation, cost is low.
For achieving the above object, the present invention is by the following technical solutions:
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
Butadiene-styrene rubber 20-30 part, natural rubber 20-30 part,
Polyvinyl chloride resin 5-15 part, Petropols 5-12 part,
Phenyl salicylate 2-5 part, poly butylene succinate 5-10 part,
Sodium pyrophosphate 1-3 part, organic silicone oil 2-5 part,
Nano-titanium oxide 0.5-1 part, calcium stearate 5-6 part,
N220 white carbon black 3-6 part, accelerant CZ 1.5-2 part,
Coupling agent 1-2 part, age resistor 1.5-3.5 part.
Preferred as technique scheme, a kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
25 parts of butadiene-styrene rubber, natural rubber 28 parts,
Polyvinyl chloride resin 10 parts, Petropols 8 parts,
Phenyl salicylate 4 parts, poly butylene succinate 7 parts,
Sodium pyrophosphate 2.5 parts, organic silicone oil 5 parts,
Nano-titanium oxide 0.8 part, calcium stearate 5 parts,
N220 white carbon black 4 parts, accelerant CZ 1.5 parts,
Coupling agent 1.6 parts, 2 parts of age resistor.
Preferred as technique scheme, described butadiene-styrene rubber is emulsion polymerized styrene butadiene rubber, and wherein the weight percent content of butadiene is 25.5%, and cinnamic weight percent content is 74.5%.
Preferred as technique scheme, in described natural rubber, 90-95% is rubber hydrocarbon.
Preferred as technique scheme, described Petropols are C5 Petropols, and its softening point is 110-115 DEG C.
Preferred as technique scheme, the size of described nano-titanium oxide is 10-30nm.
Preferred as technique scheme, described coupling agent is the mixture of silane coupler, titanate coupling agent, and the two volume ratio is 3:1.
The preparation method of a kind of anti-slip folding material for sole of shoe, comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 3-5min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 10-20min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Preferred as technique scheme, in step (1), described in the temperature begun to pratise be 50 �� 5 DEG C, the time begun to pratise is 300-330s.
Preferred as technique scheme, in step (2), the temperature of described sulfuration is 160 �� 5 DEG C, and the time of sulfuration is 180-200s.
The method have the advantages that
The addition of C5 Petropols reduces the strand free volume in rubber, make that chain is intersegmental, between filler and between segment and filler friction increase, so that the material for sole of shoe skid resistance of preparation is greatly improved, and C5 Petropols are fine with the compatibility of each rubber, on its processing characteristics without impact;
Phenyl salicylate, poly butylene succinate addition the elasticity of material for sole of shoe is greatly improved, macromolecular chain is wound around mutually, and wearability is greatly improved, and phenyl salicylate can absorb ultraviolet light, it is possible to be effectively improved the anti-ultraviolet function of material for sole of shoe.
Detailed description of the invention:
In order to be better understood from the present invention, the present invention is further described by the examples below, and embodiment is served only for explaining the present invention, and the present invention will not constitute any restriction.
Embodiment 1
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
20 parts of butadiene-styrene rubber, natural rubber 20 parts,
Polyvinyl chloride resin 5 parts, Petropols 5 parts,
Phenyl salicylate 2 parts, poly butylene succinate 5 parts,
Sodium pyrophosphate 1 part, organic silicone oil 2 parts,
Nano-titanium oxide 0.5 part, calcium stearate 5 parts,
N220 white carbon black 3 parts, accelerant CZ 1.5 parts,
Coupling agent 1 part, 1.5 parts of age resistor.
Its preparation method comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 3min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 10min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Embodiment 2
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
30 parts of butadiene-styrene rubber, natural rubber 30 parts,
Polyvinyl chloride resin 15 parts, Petropols 12 parts,
Phenyl salicylate 5 parts, poly butylene succinate 10 parts,
Sodium pyrophosphate 3 parts, organic silicone oil 5 parts,
Nano-titanium oxide 1 part, calcium stearate 6 parts,
N220 white carbon black 6 parts, accelerant CZ 2 parts,
Coupling agent 2 parts, 3.5 parts of age resistor.
Its preparation method comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 5min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 20min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Embodiment 3
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
22 parts of butadiene-styrene rubber, natural rubber 22 parts,
Polyvinyl chloride resin 7 parts, Petropols 7 parts,
Phenyl salicylate 3 parts, poly butylene succinate 6 parts,
Sodium pyrophosphate 1.5 parts, organic silicone oil 3 parts,
Nano-titanium oxide 0.6 part, calcium stearate 5.2 parts,
N220 white carbon black 4 parts, accelerant CZ 1.6 parts,
Coupling agent 1.2 parts, 2 parts of age resistor.
Its preparation method comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 4min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 12min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Embodiment 4
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
24 parts of butadiene-styrene rubber, natural rubber 24 parts,
Polyvinyl chloride resin 9 parts, Petropols 8 parts,
Phenyl salicylate 3.5 parts, poly butylene succinate 7 parts,
Sodium pyrophosphate 2 parts, organic silicone oil 3.5 parts,
Nano-titanium oxide 0.7 part, calcium stearate 5.4 parts,
N220 white carbon black 4.5 parts, accelerant CZ 1.7 parts,
Coupling agent 1.4 parts, 2.5 parts of age resistor.
Its preparation method comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 3min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 14min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Embodiment 5
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
26 parts of butadiene-styrene rubber, natural rubber 26 parts,
Polyvinyl chloride resin 11 parts, Petropols 10 parts,
Phenyl salicylate 4 parts, poly butylene succinate 8 parts,
Sodium pyrophosphate 2.5 parts, organic silicone oil 4 parts,
Nano-titanium oxide 0.8 part, calcium stearate 5.6 parts,
N220 white carbon black 5 parts, accelerant CZ 1.8 parts,
Coupling agent 1.6 parts, 3 parts of age resistor.
Its preparation method comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 4min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 16min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Embodiment 6
A kind of anti-slip folding material for sole of shoe, with parts by weight, including following components:
28 parts of butadiene-styrene rubber, natural rubber 28 parts,
Polyvinyl chloride resin 13 parts, Petropols 11 parts,
Phenyl salicylate 4.5 parts, poly butylene succinate 9 parts,
Sodium pyrophosphate 3 parts, organic silicone oil 4.5 parts,
Nano-titanium oxide 0.9 part, calcium stearate 5.8 parts,
N220 white carbon black 5.5 parts, accelerant CZ 1.9 parts,
Coupling agent 1.8 parts, 3.5 parts of age resistor.
Its preparation method comprises the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 5min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 18min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
Claims (10)
1. an anti-slip folding material for sole of shoe, it is characterised in that with parts by weight, including following components:
Butadiene-styrene rubber 20-30 part, natural rubber 20-30 part,
Polyvinyl chloride resin 5-15 part, Petropols 5-12 part,
Phenyl salicylate 2-5 part, poly butylene succinate 5-10 part,
Sodium pyrophosphate 1-3 part, organic silicone oil 2-5 part,
Nano-titanium oxide 0.5-1 part, calcium stearate 5-6 part,
N220 white carbon black 3-6 part, accelerant CZ 1.5-2 part,
Coupling agent 1-2 part, age resistor 1.5-3.5 part.
2. a kind of anti-slip folding material for sole of shoe as claimed in claim 1, it is characterised in that with parts by weight, including following components:
25 parts of butadiene-styrene rubber, natural rubber 28 parts,
Polyvinyl chloride resin 10 parts, Petropols 8 parts,
Phenyl salicylate 4 parts, poly butylene succinate 7 parts,
Sodium pyrophosphate 2.5 parts, organic silicone oil 5 parts,
Nano-titanium oxide 0.8 part, calcium stearate 5 parts,
N220 white carbon black 4 parts, accelerant CZ 1.5 parts,
Coupling agent 1.6 parts, 2 parts of age resistor.
3. a kind of anti-slip folding material for sole of shoe as claimed in claim 1, it is characterised in that described butadiene-styrene rubber is emulsion polymerized styrene butadiene rubber, and wherein the weight percent content of butadiene is 25.5%, and cinnamic weight percent content is 74.5%.
4. a kind of anti-slip folding material for sole of shoe as claimed in claim 1, it is characterised in that in described natural rubber, 90-95% is rubber hydrocarbon.
5. a kind of anti-slip folding material for sole of shoe as claimed in claim 1, it is characterised in that described Petropols are C5 Petropols, and its softening point is 110-115 DEG C.
6. a kind of anti-slip folding material for sole of shoe as claimed in claim 1, it is characterised in that the size of described nano-titanium oxide is 10-30nm.
7. a kind of anti-slip folding material for sole of shoe as claimed in claim 1, it is characterised in that described coupling agent is the mixture of silane coupler, titanate coupling agent, and the two volume ratio is 3:1.
8. the preparation method of a kind of anti-slip folding material for sole of shoe as described in as arbitrary in claim 1 to 7, it is characterised in that comprise the following steps:
(1) butadiene-styrene rubber, natural rubber, polyvinyl chloride resin, Petropols, phenyl salicylate, poly butylene succinate are joined in banbury, banburying 3-5min, continuously add sodium pyrophosphate, organic silicone oil, nano-titanium oxide, calcium stearate, N220 white carbon black, coupling agent, age resistor, banburying 10-20min, then proceeds in opening rubber mixing machine, adds accelerant CZ, begin to pratise, begin to pratise after end, naturally cool to room temperature, obtain mixed material;
(2) the mixing logistics that step (1) obtains being vulcanized by vulcanizing press, sulfuration naturally cools to room temperature, obtains anti-slip folding material for sole of shoe after terminating.
9. the preparation method of a kind of anti-slip folding material for sole of shoe as claimed in claim 8, it is characterised in that in step (1), described in the temperature begun to pratise be 50 �� 5 DEG C, the time begun to pratise is 300-330s.
10. the preparation method of a kind of anti-slip folding material for sole of shoe as claimed in claim 8, it is characterised in that in step (2), the temperature of described sulfuration is 160 �� 5 DEG C, and the time of sulfuration is 180-200s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610037393.2A CN105646970A (en) | 2016-01-20 | 2016-01-20 | Non-slip and folding-resistant sole material and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610037393.2A CN105646970A (en) | 2016-01-20 | 2016-01-20 | Non-slip and folding-resistant sole material and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105646970A true CN105646970A (en) | 2016-06-08 |
Family
ID=56487747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610037393.2A Pending CN105646970A (en) | 2016-01-20 | 2016-01-20 | Non-slip and folding-resistant sole material and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105646970A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916348A (en) * | 2017-04-12 | 2017-07-04 | 德艺文化创意集团股份有限公司 | A kind of wear-resisting high-strength degree slipper sole and its production technology and application |
| CN117247610A (en) * | 2023-10-10 | 2023-12-19 | 广东力宇益宝鞋材有限公司 | Vegetarian leather sole material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816354A (en) * | 2012-09-04 | 2012-12-12 | 苏州伟伦运动休闲用品有限公司 | Light-weight bent shoe sole and production method thereof |
| CN102924766A (en) * | 2012-11-26 | 2013-02-13 | 山东忠诚橡胶有限公司 | Mixed rubber for manufacturing rubber |
| CN104231347A (en) * | 2014-09-26 | 2014-12-24 | 四川卡美迪鞋业有限公司 | Tourist shoe formula capable of improving forming stability |
-
2016
- 2016-01-20 CN CN201610037393.2A patent/CN105646970A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816354A (en) * | 2012-09-04 | 2012-12-12 | 苏州伟伦运动休闲用品有限公司 | Light-weight bent shoe sole and production method thereof |
| CN102924766A (en) * | 2012-11-26 | 2013-02-13 | 山东忠诚橡胶有限公司 | Mixed rubber for manufacturing rubber |
| CN104231347A (en) * | 2014-09-26 | 2014-12-24 | 四川卡美迪鞋业有限公司 | Tourist shoe formula capable of improving forming stability |
Non-Patent Citations (1)
| Title |
|---|
| 路雪峤等: "足球鞋大底中并用天然胶与丁苯胶试验", 《河北化工》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916348A (en) * | 2017-04-12 | 2017-07-04 | 德艺文化创意集团股份有限公司 | A kind of wear-resisting high-strength degree slipper sole and its production technology and application |
| CN117247610A (en) * | 2023-10-10 | 2023-12-19 | 广东力宇益宝鞋材有限公司 | Vegetarian leather sole material and preparation method thereof |
| CN117247610B (en) * | 2023-10-10 | 2024-05-03 | 广东力宇益宝鞋材有限公司 | Vegetarian leather sole material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104744736B (en) | Material for sole of shoe and preparation method thereof | |
| US11104782B2 (en) | Rubber composition for use in tire tread | |
| CN103289150B (en) | Acrylonitrile butadiene packing material of a kind of cold-resistant, wear-resisting and preparation method thereof | |
| CN102796288A (en) | Novel antiskid antistatic rubber sole and preparation method thereof | |
| US6090880A (en) | Rubber composition and tire having tread thereof | |
| CN103205026B (en) | A kind of Ultralight high-elastic rubber sole material and preparation method thereof | |
| CN106459516B (en) | Rubber composition for tire tread | |
| CN105670064B (en) | A kind of motorcycle racing tread mix | |
| KR101878260B1 (en) | Rubber composition for tire tread | |
| CN104072830B (en) | A kind of wear-resisting ageing-resistant rubber material | |
| CN105218902A (en) | High-performance tire rubber combination and production technique thereof | |
| EP2877532A1 (en) | Highly silica loaded styrene butadiene rubber masterbatch | |
| CN105646970A (en) | Non-slip and folding-resistant sole material and preparing method thereof | |
| US7141622B2 (en) | Process for preparing a silica/rubber blend which includes dispersing silica, asilica coupling agent, and a low molecular weight end-group functionalized diene rubber throughout a cement of a conventional rubbery polymer, and subsequently recovering the silica/rubber blend from an organic solvent | |
| JP5289749B2 (en) | Pneumatic tire | |
| CN105504395A (en) | Environmentally-friendly oil-resistant flame-retardant rubber shoe sole material | |
| CN104710658A (en) | Antislip rubber sole material | |
| EP3049447A1 (en) | Low vinyl bond modified elastomeric copolymers | |
| CN106519356A (en) | Abrasion-resistant rubber material and preparation method thereof | |
| CN104448455A (en) | High-performance tire rubber material for agriculture machine | |
| CN104693585A (en) | Non-slip and wear-resisting sole and preparing method thereof | |
| CN108384076B (en) | Outsole formula with high oil resistance, antistatic property and slip resistance and preparation method thereof | |
| CN107129609A (en) | Tire tread and preparation method thereof | |
| CN105315525A (en) | Tire tread rubber material with high wet skid resistance and low rolling resistance as well as preparation method and application thereof | |
| CN105602030A (en) | Winter tread rubber material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160608 |