CN105642447A - Zinc oxide ore floatation agent and preparation method thereof - Google Patents
Zinc oxide ore floatation agent and preparation method thereof Download PDFInfo
- Publication number
- CN105642447A CN105642447A CN201610086691.0A CN201610086691A CN105642447A CN 105642447 A CN105642447 A CN 105642447A CN 201610086691 A CN201610086691 A CN 201610086691A CN 105642447 A CN105642447 A CN 105642447A
- Authority
- CN
- China
- Prior art keywords
- agent
- mass ratio
- zinc oxide
- oxide ore
- collecting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 81
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 239000011787 zinc oxide Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004088 foaming agent Substances 0.000 claims abstract description 57
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- -1 primary amine salt Chemical class 0.000 claims description 28
- 239000008396 flotation agent Substances 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical class CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 11
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical group CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims description 10
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 8
- 239000010238 camphora Substances 0.000 claims description 8
- 229940025250 camphora Drugs 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000003350 kerosene Substances 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 6
- 150000003863 ammonium salts Chemical class 0.000 claims description 6
- 239000002283 diesel fuel Substances 0.000 claims description 6
- 239000010642 eucalyptus oil Substances 0.000 claims description 6
- 229940044949 eucalyptus oil Drugs 0.000 claims description 6
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- WHSXTWFYRGOBGO-UHFFFAOYSA-N 3-methylsalicylic acid Chemical compound CC1=CC=CC(C(O)=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims description 4
- 150000004982 aromatic amines Chemical class 0.000 claims description 4
- 229960000629 domiphen Drugs 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000000295 fuel oil Substances 0.000 claims description 4
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000012991 xanthate Substances 0.000 claims description 4
- 238000005304 joining Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 238000005188 flotation Methods 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 238000007667 floating Methods 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 125000005526 alkyl sulfate group Chemical group 0.000 description 4
- 125000005313 fatty acid group Chemical group 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002547 new drug Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 229910001656 zinc mineral Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
Landscapes
- Physical Water Treatments (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention provides a zinc oxide ore floatation agent. The zinc oxide ore floatation agent comprises a collecting agent, a foaming agent and an emulsifying agent, wherein the mass ratio of the foaming agent to the collecting agent is 1:6-1:1, and the mass ratio of the emulsifying agent to the collecting agent is 1:6-1:1. A preparation method comprises the steps that (1) the foaming agent is added into the collecting agent, dissolved at the temperature of 25-80 DEG C and stirred evenly, and the mass ratio of the foaming agent to the collecting agent is 1:6-1:1; (2) an appropriate amount of water is added into the mixture evenly mixed in the first step to obtain a solution with the mass concentration being 0.1-10%; and (3) the emulsifying agent is added to the solution obtained in the second step, so that the collecting agent and the foaming agent are fully emulsified in the aqueous solution, and the mass ratio of the emulsifying agent to the collecting agent is 1:6-1:1. The floatation agent has the advantages of being good in floatation effect and water solubility, high in dispersing capacity, low in cost, high in recovery rate and the like.
Description
Technical field
The invention belongs to flotation agent technical field, be specifically related to a kind of zinc oxide ore flotation agent and preparation method thereof.
Background technology
The exploitation of China's zinc resource also faces following two large problems. Problem one, the self-produced zinc concentrate of current China cannot meet demand, annual needs a large amount of Import Zinc Concentrates; Problem two, the sulphide ore that China's overwhelming majority is verified or develops, and reserved resources extremely lacks. Thus the exploitation of Refractory ore product resource is extremely urgent.
Floatation is a kind of important method processing zinc oxide ore. With uncle's amine collector collecting after the mainly sulfuration of conventional method for floating, but owing to zinc oxide ore is usually plumbous zinc mineral intergrowth, its mineral species is various, mutually adulterating association, disseminated grain size is thinner, and argillization is serious, soluble-salt content is high, thus conventional flotation difficulty is bigger. Therefore, the research to zinc oxide ore flotation. Especially the research application of floating agent is directly connected to oxidase complex zinc resource can utilize by effective exploitation.
Both at home and abroad the medicament of zinc oxide ore flotation is studied and have focused largely on new and effective collecting agent, the research and development of activator and applied research aspect, particularly that the research of collecting agent is more, but the research of emulsifying agent and foaming agent is less. This also reflects the direction of zinc oxide ore floating agent future studies.
Many etc. owing to the most complicated component of zinc oxide ore, oxygenation efficiency are high, containing mud, result in its ore dressing difficulty big, recovery rate in ore-dressing is low, and many achievements, also because the reason of technology or economy fails generally to put into commercial production, not yet bring direct economic benefit. Therefore, oxidation reinforced zinc ore floating is theoretical and sulfidation invigoration effect and study mechanism, develops efficient new drug and combination medicament, is of great significance for reducing the beneficiation cost of zinc oxide ore, improving comprehensive resource utilization rate tool.
Summary of the invention
For solving the problem of the flotation effect difference that existing zinc oxide ore flotation agent exists, the present invention proposes a kind of zinc oxide ore flotation agent, has flotation effect good, good water solubility, and dispersibility is strong, and cost is low, response rate advantages of higher.
The technical scheme is that and be achieved in that:
A kind of zinc oxide ore flotation agent, forms including following components: collecting agent, foaming agent and emulsifying agent, and the mass ratio of described foaming agent and described collecting agent is 1:6-1:1, and the mass ratio of described emulsifying agent and described collecting agent is 1:6-1:1.
Further, described collecting agent is selected from the one in aminated compounds, xanthate compounds and chelating compounds or two kinds.
Further, described aminated compounds is primary amine salt, second ammonium salt, tertiary amine salt, quaternary ammonium salt, fatty amine, aromatic amine or ether amines, described xanthate compounds is ethyl xanthate, butyl xanthate or amyl group xanthate, and described chelating compounds is alkyl malonic acid class, ��-oximido dialkyl alkylphosphonate class or octyl group hydroximic acid.
Further, described foaming agent is one or both in Oleum Camphora, Eucalyptus oil, heavy oil, diesel oil, kerosene, terpenic oil, cresotinic acid and higher alcohols.
Further, described emulsifying agent is one or both in fatty acid soaps, alkyl sulfate, alkylbenzenesulfonate, phosphate, N-domiphen and amine derivative, quaternary ammonium salt, polyoxyethylene ether, polyethenoxy ether, polyol fatty acid ester and polyvinyl alcohol.
The preparation method that it is a further object to provide a kind of zinc oxide ore flotation agent, comprises the following steps:
1) joining in collecting agent by foaming agent, dissolve and stir at 25-80 DEG C, the mass ratio of described foaming agent and described collecting agent is 1:6-1:1;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 0.1-10%;
3) to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:6-1:1.
Further, in primary amine salt, second ammonium salt, tertiary amine salt, quaternary ammonium salt, fatty amine, aromatic amine, ether amines, ethyl xanthate, butyl xanthate, amyl group xanthate, alkyl malonic acid class, ��-oximido dialkyl alkylphosphonate class or octyl group hydroximic acid two kinds of described collecting agent, described step 1) in the mass ratio of two kinds of collecting agents be 6:1-1:6.
Further, described foaming agent is two kinds in Oleum Camphora, Eucalyptus oil, heavy oil, diesel oil, kerosene, terpenic oil, cresotinic acid and higher alcohols, described step 1) in the mass ratio of two kinds of foaming agents be 1:3-3:1.
Further, described emulsifying agent is two kinds in fatty acid soaps, alkyl sulfate, alkylbenzenesulfonate, phosphate, N-domiphen and amine derivative, quaternary ammonium salt, polyoxyethylene ether, polyethenoxy ether, polyol fatty acid ester and polyvinyl alcohol, described step 3) in the mass ratio of two kinds of emulsifying agents be 1:3-3:1.
It is good that novel oxidized zinc ore floating agent provided by the invention has flotation effect, good water solubility, and dispersibility is strong, and cost is low, response rate advantages of higher.
Detailed description of the invention
Embodiment 1
A kind of zinc oxide ore flotation agent, forms including following components: collecting agent, foaming agent and emulsifying agent, and the mass ratio of described foaming agent and described collecting agent is 1:4, and the mass ratio of described emulsifying agent and described collecting agent is 1:5. Collecting agent is primary amine salt and alkyl malonic acid class. Foaming agent is Oleum Camphora and Eucalyptus oil. Emulsifying agent is fatty acid soaps and alkyl sulfate.
The preparation method of a kind of zinc oxide ore flotation agent, comprises the following steps:
1) collecting agent is primary amine salt and alkyl malonic acid class, its mass ratio 5:1, is sufficiently mixed uniformly; Foaming agent is Oleum Camphora and Eucalyptus oil, and its mass ratio is 3:1, foaming agent joins collecting agent at 30 DEG C and dissolves and stir, and the mass ratio of described foaming agent and described collecting agent is 1:4;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 2%;
3) emulsifying agent is fatty acid soaps and alkyl sulfate, and its mass ratio is 3:1, to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:5.
Embodiment 2
A kind of zinc oxide ore flotation agent, forms including following components: collecting agent, foaming agent and emulsifying agent, and the mass ratio of described foaming agent and described collecting agent is 1:6, and the mass ratio of described emulsifying agent and described collecting agent is 1:1. Collecting agent is second ammonium salt and butyl xanthate. Foaming agent is kerosene and diesel oil. Emulsifying agent is polyoxyethylene ether and polyethenoxy ether.
The preparation method of a kind of zinc oxide ore flotation agent, comprises the following steps:
1) collecting agent is second ammonium salt and butyl xanthate, its mass ratio 6:1, is sufficiently mixed uniformly; Foaming agent is kerosene and diesel oil, and its mass ratio is 2:1, foaming agent joins collecting agent at 50 DEG C and dissolves and stir, and the mass ratio of described foaming agent and described collecting agent is 1:6;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 3%;
3) emulsifying agent is polyoxyethylene ether and polyethenoxy ether, its mass ratio is 2:1, to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:1.
Embodiment 3
A kind of zinc oxide ore flotation agent, forms including following components: collecting agent, foaming agent and emulsifying agent, and the mass ratio of described foaming agent and described collecting agent is 1:1, and the mass ratio of described emulsifying agent and described collecting agent is 1:6. Collecting agent is primary amine salt and octyl group hydroximic acid. Foaming agent is Oleum Camphora and kerosene. Emulsifying agent is fatty acid soaps and polyethenoxy ether.
The preparation method of a kind of zinc oxide ore flotation agent, comprises the following steps:
1) collecting agent is primary amine salt and octyl group hydroximic acid, its mass ratio 1:6, is sufficiently mixed uniformly; Foaming agent is Oleum Camphora and kerosene, and its mass ratio is 2:1.5, foaming agent joins collecting agent at 60 DEG C and dissolves and stir, and the mass ratio of described foaming agent and described collecting agent is 1:1;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 5%;
3) emulsifying agent is fatty acid soaps and polyethenoxy ether, its mass ratio is 2:1.5, to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:6.
Embodiment 4
A kind of zinc oxide ore flotation agent, forms including following components: collecting agent, foaming agent and emulsifying agent, and the mass ratio of described foaming agent and described collecting agent is 1:3, and the mass ratio of described emulsifying agent and described collecting agent is 1:3. Collecting agent is fatty amine and butyl xanthate class. Foaming agent is terpenic oil and higher alcohols. Emulsifying agent is alkyl sulfate and alkylbenzenesulfonate.
The preparation method of a kind of zinc oxide ore flotation agent, comprises the following steps:
1) collecting agent is fatty amine and butyl xanthate class, its mass ratio 1:4, is sufficiently mixed uniformly; Foaming agent is terpenic oil and higher alcohols, and its mass ratio is 1:1, foaming agent joins collecting agent at 60 DEG C and dissolves and stir, and the mass ratio of described foaming agent and described collecting agent is 1:3;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 3%;
3) emulsifying agent is alkyl sulfate and alkylbenzenesulfonate, its mass ratio is 1:1, to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:3.
Embodiment 5
A kind of zinc oxide ore flotation agent, forms including following components: collecting agent, foaming agent and emulsifying agent, and the mass ratio of described foaming agent and described collecting agent is 1:4, and the mass ratio of described emulsifying agent and described collecting agent is 1:4. Collecting agent is primary amine salt and butyl xanthate. Foaming agent is terpenic oil and cresotinic acid. Emulsifying agent is alkyl sulfate and alkylbenzenesulfonate.
The preparation method of a kind of zinc oxide ore flotation agent, comprises the following steps:
1) collecting agent is primary amine salt and butyl xanthate class, its mass ratio 1:3, is sufficiently mixed uniformly; Foaming agent is terpenic oil and higher alcohols, and its mass ratio is 2:1, foaming agent joins collecting agent at 25 DEG C and dissolves and stir, and the mass ratio of described foaming agent and described collecting agent is 1:4;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 2.5%;
3) emulsifying agent is alkyl sulfate and alkylbenzenesulfonate, its mass ratio is 2:1, to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:4.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all within the spirit and principles in the present invention, any amendment of making, equivalent replacement, improvement etc., should be included within protection scope of the present invention.
Claims (9)
1. a zinc oxide ore flotation agent, it is characterised in that including following components composition: the mass ratio of collecting agent, foaming agent and emulsifying agent, described foaming agent and described collecting agent is 1:6-1:1, the mass ratio of described emulsifying agent and described collecting agent is 1:6-1:1.
2. zinc oxide ore flotation agent according to claim 1, it is characterised in that described collecting agent is selected from the one in aminated compounds, xanthate compounds and chelating compounds or two kinds.
3. zinc oxide ore flotation agent according to claim 2, it is characterized in that, described aminated compounds is primary amine salt, second ammonium salt, tertiary amine salt, quaternary ammonium salt, fatty amine, aromatic amine or ether amines, described xanthate compounds is ethyl xanthate, butyl xanthate or amyl group xanthate, and described chelating compounds is alkyl malonic acid class, ��-oximido dialkyl alkylphosphonate class or octyl group hydroximic acid.
4. zinc oxide ore flotation agent according to claim 1 and 2, it is characterised in that described foaming agent is one or both in Oleum Camphora, Eucalyptus oil, heavy oil, diesel oil, kerosene, terpenic oil, cresotinic acid and higher alcohols.
5. zinc oxide ore flotation agent according to claim 1 and 2, it is characterized in that, described emulsifying agent is one or both in fatty acid soaps, alkyl sulfate, alkylbenzenesulfonate, phosphate, N-domiphen and amine derivative, quaternary ammonium salt, polyoxyethylene ether, polyethenoxy ether, polyol fatty acid ester and polyvinyl alcohol.
6. the preparation method of a zinc oxide ore flotation agent, it is characterised in that comprise the following steps:
1) joining in collecting agent by foaming agent, dissolve and stir at 25-80 DEG C, the mass ratio of described foaming agent and described collecting agent is 1:6-1:1;
2) by step 1) mixing after mixture add suitable quantity of water, be configured to the solution that mass concentration is 0.1-10%;
3) to step 2) solution in add emulsifying agent so that collecting agent and foaming agent all can be fully emulsified in aqueous, and the mass ratio of described emulsifying agent and described collecting agent is 1:6-1:1.
7. the preparation method of zinc oxide ore flotation agent according to claim 6, it is characterized in that, in primary amine salt, second ammonium salt, tertiary amine salt, quaternary ammonium salt, fatty amine, aromatic amine, ether amines, ethyl xanthate, butyl xanthate, amyl group xanthate, alkyl malonic acid class, ��-oximido dialkyl alkylphosphonate class or octyl group hydroximic acid two kinds of described collecting agent, described step 1) in the mass ratio of two kinds of collecting agents be 6:1-1:6.
8. the preparation method of the zinc oxide ore flotation agent according to claim 6 or 7, it is characterized in that, described foaming agent is two kinds in Oleum Camphora, Eucalyptus oil, heavy oil, diesel oil, kerosene, terpenic oil, cresotinic acid and higher alcohols, described step 1) in the mass ratio of two kinds of foaming agents be 1:3-3:1.
9. the preparation method of the zinc oxide ore flotation agent according to claim 6 or 7, it is characterized in that, described emulsifying agent is two kinds in fatty acid soaps, alkyl sulfate, alkylbenzenesulfonate, phosphate, N-domiphen and amine derivative, quaternary ammonium salt, polyoxyethylene ether, polyethenoxy ether, polyol fatty acid ester and polyvinyl alcohol, described step 3) in the mass ratio of two kinds of emulsifying agents be 1:3-3:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610086691.0A CN105642447B (en) | 2016-02-15 | 2016-02-15 | Zinc oxide ore flotation agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610086691.0A CN105642447B (en) | 2016-02-15 | 2016-02-15 | Zinc oxide ore flotation agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105642447A true CN105642447A (en) | 2016-06-08 |
| CN105642447B CN105642447B (en) | 2018-04-17 |
Family
ID=56488426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610086691.0A Active CN105642447B (en) | 2016-02-15 | 2016-02-15 | Zinc oxide ore flotation agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105642447B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108889453A (en) * | 2018-04-28 | 2018-11-27 | 昆明理工大学 | A kind of combination medicament and its application method for zinc-containing ores flotation |
| CN110142144A (en) * | 2019-06-03 | 2019-08-20 | 云南金鼎锌业有限公司 | The method that low-grade difficulty selects Flotation of Zinc Oxide in oxysulphied lead-zinc ore tailings |
| CN110152889A (en) * | 2019-06-04 | 2019-08-23 | 瓮福（集团）有限责任公司 | A kind of silicon calcium quality ore Counterfloatating desiliconization removal of impurities combined capturing and collecting agent and its preparation method and application |
| CN110876987A (en) * | 2019-12-05 | 2020-03-13 | 西南科技大学 | Synchronous enhancer for efficient flotation and separation of refractory zinc oxide ore and preparation and application thereof |
| CN111266195A (en) * | 2020-03-05 | 2020-06-12 | 中南大学 | Zinc oxide ore flotation combined collecting agent and application thereof |
| CN111530633A (en) * | 2020-04-27 | 2020-08-14 | 西部矿业股份有限公司 | Novel composite collecting agent for recovering zinc oxide from peat plaza lead zinc oxide ore, preparation method and application |
| CN112371348A (en) * | 2020-12-15 | 2021-02-19 | 武汉工程大学 | Lead-zinc sulfide ore flotation separation inhibitor and application method thereof |
| CN113843050A (en) * | 2021-10-11 | 2021-12-28 | 内蒙古宏鉮科技发展有限责任公司 | Iron ore dressing method for bayan obo iron-containing surrounding rock |
| CN113976326A (en) * | 2021-10-27 | 2022-01-28 | 江西理工大学 | Flotation separation agent for mud-containing zinc oxide ore and flotation separation process thereof |
| CN114798181A (en) * | 2022-04-27 | 2022-07-29 | 矿冶科技集团有限公司 | Flotation foaming agent for minerals containing easy-to-float gangue and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3640382A (en) * | 1970-02-04 | 1972-02-08 | Basic Inc | Flotation concentration of magnesite with emulsified collector reagents |
| CN1820853A (en) * | 2006-02-09 | 2006-08-23 | 陈铁 | Beneficiation method for zinc oxide mine |
| CN103447156A (en) * | 2012-06-01 | 2013-12-18 | 云南中林地质勘察设计有限公司 | Preparation and application method of emulsion collectors for lead-zinc oxide ore difficult in selection |
| CN103506225A (en) * | 2013-09-16 | 2014-01-15 | 四川晶大矿业科技有限公司 | Zinc oxide mineral beneficiation collecting agent and preparation method of zinc oxide mineral beneficiation collecting agent |
| CN104768653A (en) * | 2012-11-28 | 2015-07-08 | 埃科莱布美国股份有限公司 | Composition and method for improvement in froth flotation |
-
2016
- 2016-02-15 CN CN201610086691.0A patent/CN105642447B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3640382A (en) * | 1970-02-04 | 1972-02-08 | Basic Inc | Flotation concentration of magnesite with emulsified collector reagents |
| CN1820853A (en) * | 2006-02-09 | 2006-08-23 | 陈铁 | Beneficiation method for zinc oxide mine |
| CN103447156A (en) * | 2012-06-01 | 2013-12-18 | 云南中林地质勘察设计有限公司 | Preparation and application method of emulsion collectors for lead-zinc oxide ore difficult in selection |
| CN104768653A (en) * | 2012-11-28 | 2015-07-08 | 埃科莱布美国股份有限公司 | Composition and method for improvement in froth flotation |
| CN103506225A (en) * | 2013-09-16 | 2014-01-15 | 四川晶大矿业科技有限公司 | Zinc oxide mineral beneficiation collecting agent and preparation method of zinc oxide mineral beneficiation collecting agent |
Non-Patent Citations (2)
| Title |
|---|
| 中国冶金百科全书总编辑委员会《选矿》卷编辑委员会: "《中国冶金百科全书∙选矿》", 29 February 2000 * |
| 胡岳华等: "《矿物浮选》", 31 March 2014 * |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108889453A (en) * | 2018-04-28 | 2018-11-27 | 昆明理工大学 | A kind of combination medicament and its application method for zinc-containing ores flotation |
| CN110142144A (en) * | 2019-06-03 | 2019-08-20 | 云南金鼎锌业有限公司 | The method that low-grade difficulty selects Flotation of Zinc Oxide in oxysulphied lead-zinc ore tailings |
| CN110152889A (en) * | 2019-06-04 | 2019-08-23 | 瓮福（集团）有限责任公司 | A kind of silicon calcium quality ore Counterfloatating desiliconization removal of impurities combined capturing and collecting agent and its preparation method and application |
| CN110876987B (en) * | 2019-12-05 | 2021-09-03 | 西南科技大学 | Synchronous enhancer for efficient flotation and separation of refractory zinc oxide ore and preparation and application thereof |
| CN110876987A (en) * | 2019-12-05 | 2020-03-13 | 西南科技大学 | Synchronous enhancer for efficient flotation and separation of refractory zinc oxide ore and preparation and application thereof |
| CN111266195B (en) * | 2020-03-05 | 2021-09-07 | 中南大学 | Zinc oxide ore flotation combined collecting agent and application thereof |
| CN111266195A (en) * | 2020-03-05 | 2020-06-12 | 中南大学 | Zinc oxide ore flotation combined collecting agent and application thereof |
| CN111530633A (en) * | 2020-04-27 | 2020-08-14 | 西部矿业股份有限公司 | Novel composite collecting agent for recovering zinc oxide from peat plaza lead zinc oxide ore, preparation method and application |
| CN112371348A (en) * | 2020-12-15 | 2021-02-19 | 武汉工程大学 | Lead-zinc sulfide ore flotation separation inhibitor and application method thereof |
| CN112371348B (en) * | 2020-12-15 | 2022-04-26 | 武汉工程大学 | Lead-zinc sulfide ore flotation separation inhibitor and application method thereof |
| CN113843050A (en) * | 2021-10-11 | 2021-12-28 | 内蒙古宏鉮科技发展有限责任公司 | Iron ore dressing method for bayan obo iron-containing surrounding rock |
| CN113843050B (en) * | 2021-10-11 | 2023-02-28 | 内蒙古宏鉮科技发展有限责任公司 | Iron ore dressing method for bayan obo iron-containing surrounding rock |
| CN113976326A (en) * | 2021-10-27 | 2022-01-28 | 江西理工大学 | Flotation separation agent for mud-containing zinc oxide ore and flotation separation process thereof |
| CN113976326B (en) * | 2021-10-27 | 2023-12-19 | 江西理工大学 | Flotation separation agent for mud-containing zinc oxide ore and flotation separation process thereof |
| CN114798181A (en) * | 2022-04-27 | 2022-07-29 | 矿冶科技集团有限公司 | Flotation foaming agent for minerals containing easy-to-float gangue and preparation method thereof |
| CN114798181B (en) * | 2022-04-27 | 2024-03-26 | 矿冶科技集团有限公司 | Flotation foaming agent for minerals containing easy-to-float gangue and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105642447B (en) | 2018-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105642447A (en) | Zinc oxide ore floatation agent and preparation method thereof | |
| CN101912822B (en) | Negative/positive ion collector for iron ore flotation and preparation method thereof | |
| CN103394416B (en) | Coal flotation agent and preparation method thereof | |
| CN110000008B (en) | Lead-zinc sulfide ore composite collecting agent, composite flotation reagent, and preparation and application of composite collecting agent and composite flotation reagent | |
| CN109647628A (en) | Application of the 1,3,4- thiadiazole compound in sulfide flotation | |
| WO2021128922A1 (en) | Application of 2-(3-substituted ureido)-n-hydroxy-2-oxoacetimide cyanide compound in flotation | |
| CN102826728A (en) | Cleaning agent applied to treatment of oily sludge by hot washing method and preparation method thereof | |
| CN105238926A (en) | Extraction separation method for yttrium | |
| CN113102113B (en) | Selective flotation separation agent and method for galena and zinc-containing gangue | |
| CN103801462A (en) | Iron mine oxidized ore flotation green collector and production process thereof | |
| CN105880034A (en) | Ilmenite chelating collector | |
| CN107961903B (en) | A kind of composite chemical for floatating of zinc oxide and its preparation method and application | |
| CN109433426A (en) | Oxide ores mineral collectors such as a kind of collecting fluorite and preparation method thereof | |
| CN105750091A (en) | Mineral floatation colleting agent and manufacturing method thereof | |
| CN102925685B (en) | Compound solvent for extraction separation of tungsten and molybdenum and using method thereof | |
| CN101757983B (en) | Tungsten ore floatation collecting agent and application thereof | |
| CN109574423A (en) | A kind of high-efficiency oil sludge demulsifier and preparation method thereof | |
| WO2021128771A1 (en) | Application of 2-cyano-n-(substituted carbamoyl) acetamide compound in calcium-containing mineral flotation | |
| CN109158218A (en) | A kind of composite inhibitor and its application method of galena | |
| CN109225648A (en) | Pegmatite type spodumene flotation collecting agent and preparation method and application thereof | |
| CN105413876A (en) | Mineral separation activating agent used in lepidolite flotation process | |
| CN112808463B (en) | Medicament and method for flotation separation of iron-titanium ore and iron-containing gangue | |
| CN106944262A (en) | A kind of compound cation-collecting agent and preparation method thereof | |
| CN101503760B (en) | Method for extracting zinc from zinc oxide ore ammonia leaching solution | |
| CN112844854B (en) | Flotation collector for copper oxide ore and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |