CN105642185B

CN105642185B - A kind of anionic-cationic-nonionic surface active agent, its manufacturing method and its application

Info

Publication number: CN105642185B
Application number: CN201410577415.5A
Authority: CN
Inventors: 李应成; 顾松园; 张卫东; 鲍新宁; 沙鸥; 沈之芹; 杨青; 杨一青; 翟晓东
Original assignee: China Petroleum and Chemical Corp; Sinopec Shanghai Research Institute of Petrochemical Technology
Current assignee: China Petroleum and Chemical Corp; Sinopec Shanghai Research Institute of Petrochemical Technology
Priority date: 2014-10-22
Filing date: 2014-10-22
Publication date: 2018-07-31
Anticipated expiration: 2034-10-22
Also published as: CN105642185A

Abstract

The present invention relates to a kind of substantially anion cation nonionic surface active agent, its manufacturing method and its applications in tertiary oil recovery as shown in following formula (I).The anion cation nonionic surface active agent of the present invention shows the interfacial activity and stability significantly improved compared with prior art.Use the anion cation nonionic surface active agent of the present invention, it is possible to produce the displacement composition used for tertiary oil recovery that oil displacement efficiency and washing oil ability improve compared with prior art.

Description

A kind of anionic-cationic-nonionic surface active agent, its manufacturing method and its Using

Technical field

The present invention relates to a kind of anionic-cationic-nonionic surface active agent.Specifically, the present invention relates to one Plant the anionic-cationic-nonionic surface active agent that can be used for tertiary oil recovery, its manufacturing method and its in tertiary oil recovery Application.

Background technology

With the increase of world energy sources demand, the rational exploitation and utilization of oil has caused the very big attention of people, to oil Yield and production efficiency requirement it is also higher and higher.Conventional oil production method (primary and secondary method) normally only produces crude oil The 1/3 of oil in place, there is also about 2/3 crude oil to fail to produce, therefore in the case where being becoming tight energy day, has improved tar productivity As the key subjects of oil exploitation research.

Tertiary oil recovery technology is then a kind of effective method for improving tar productivity.Wherein, chemical displacement of reservoir oil technology is to adopt three times The extremely important and technology implemented on a large scale in oil, including polymer displacement of reservoir oil tech, surfactant flooding technology, caustic flooding The multiple combinations technology of technology etc. and polymer, alkali, surfactant.The chemical displacement of reservoir oil is being total to for physical action and chemical action Together as a result, the effect that involves of displacing fluid is utilized in physical action, and the microcosmic oil drive effect of displacing fluid is then utilized in chemical action. The core of chemical action is to reduce the interfacial tension of displacing fluid and crude oil.Surfactant is due to having both oleophylic (hydrophobic) and hydrophilic (oleophobic) property, when surfactant is dissolved in water, molecule is mainly distributed on oil-water interfaces, can significantly reduce oil-water interfaces Tension.The reduction of oil water interfacial tension means that surfactant system can overcome the cohesive force between crude oil, by larger oil droplet point Small oil droplet is dissipated into, to improve percent of pass when crude oil flows through pore throat.The oil displacement efficiency of surfactant, which is also manifested by, makes oleophylic Wettability of rock surface reversion, emulsification of crude oil, improve surface charge density and the effects that oil droplet coalescence, this is surfactant The reason of playing very important component can be become in displacing fluid.

But there are more problems, the mainly boundary of surface active agent composition for the displacing fluid used for tertiary oil recovery of the prior art Face poor activity causes the oil displacement efficiency for the displacing fluid being produced from it low, simultaneously because the system of displacing fluid is excessively complicated, thus adopts Go out liquid demulsification difficulty, sewage disposal difficulty is big；Since displacing fluid contains inorganic base, injury is brought to stratum and oil well, causes to corrode The problems such as equipment and pipeline, and since inorganic base can seriously reduce the viscosity of polymer, have to greatly to reach required viscosity The big use concentration for improving polymer, makes oil recovery overall cost improve；High temperature resistance, high salt tolerance, the anti-height of surface active agent composition The ability of salinity is limited；Surface active agent composition stability in compounding is poor, easy tos produce precipitation.

Therefore, current present situation is to be still required for a kind of surfactant, can be overcome of the existing technology aforementioned Problem, and show the interfacial activity and stability improved compared with prior art.

Invention content

The present inventor passes through diligent research on the basis of existing technology, it was found that a kind of novel anion-sun from Son-nonionic surface active agent, and it has furthermore been found that displacement of reservoir oil group used for tertiary oil recovery is manufactured by using the surfactant Close object (displacing fluid), so that it may to solve foregoing problems of the existing technology, and have thus completed the present invention.

Specifically, the present invention relates to the contents of following aspect.

1. a kind of anionic-cationic-nonionic surface active agent, which is characterized in that selected from substantially such as following formula (I) At least one of compound represented,

In formula (I), group N⁺It is quaternary nitrogen cation；Group R₁To R₃It is same or different to each other, is each independently selected from optionally Substituted C_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic ring Alkyl (preferably C_5-7Monocyclic cycloalkyl such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl, optionally Substituted C_6-50(preferably C_6-20) aryl and by formulaThe group of representative, on condition that group R₁To R₃At least one of be by formulaThe group of representative, it is so-called herein " optionally to take In generation ", refers to optionally by one or more selected from oxo, hydroxyl, by formulaIt represents Group, C_1-20(preferably C_1-10) linear or branched alkyl group, C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as ring Hexyl), C_2-20(preferably C_2-10) linear chain or branched chain alkenyl and C_6-20(preferably C_6-10) aryl substituent group substitution；Group Rh is selected from The C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or more Ring naphthenic base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50It is (excellent Select C_6-20) aryl；Group X- is selected from halide ion (preferably fluorine ion, chlorion, bromide ion and iodide ion, more preferable chlorion) With hydroxide ion (OH^-)；Group Link is selected from the x+1 valences C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, optionally Substituted x+1 valences C_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferably C_5-7Monocyclic cycloalkyl such as cyclohexyl), The x+1 valences C optionally replaced_2-50(preferably C_2-20) linear chain or branched chain alkenyl, the x+1 valences C that optionally replaces_6-50(preferably C_6-20) aryl The x+1 valences C optionally replaced_3-50(preferably C_3-20) linear chain or branched chain miscellaneous alkyl；Each group Poly is same or different to each other, respectively Independently selected from formulaThe group of representative；Each group L is same or different to each other, each independently Selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene is (preferably respectively solely On the spot it is selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene)；Each group Salt is same or different to each other, and selects each independently Freely-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；X is between 1 to 10 Arbitrary integer (arbitrary integer between preferably 1 to 4, such as 1,2 or 3)；Between each group Poly, each numerical value y phases each other It is same or different, it is each independently selected from any number between 0 to 200 (any number between preferably 0 to 100), on condition that x The sum of a numerical value y is more than 0；Between each group Poly, each group Ru is same or different to each other, and is each independently selected from C_2-6Directly Chain or branched alkylidene (are preferably each independently selected from-CH₂-CH₂And-CH₂-CH(CH₃)-)；It is (excellent that group M is selected from alkali metal Select Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄)；When group M is alkali metal or ammonium root, r=1；Work as base When group M is alkaline-earth metal, r=0.5,

Wherein, do not having especially explicitly, it is so-called " optionally substitution ", it refers to optionally being selected from by one or more Oxo, hydroxyl, C_1-20(preferably C_1-10) linear or branched alkyl group, C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base (ratio Such as cyclohexyl), C_2-20(preferably C_2-10) linear chain or branched chain alkenyl and C_6-20(preferably C_6-10) aryl substituent group substitution, also, institute State one or more group-CH that linear chain or branched chain miscellaneous alkyl is selected from inside linear or branched alkyl group molecular structure₂By selected from- O- ,-S- ,-NR '-(wherein, group R ' is selected from the C optionally replaced_1-20(preferably C_1-10) linear or branched alkyl group, optionally replace C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base, the C that optionally replaces_2-20(preferably C_2-10) linear chain or branched chain alkenyl and appoint Choose the C in generation_6-20(preferably C_6-10) aryl) and(wherein, group N⁺It is quaternary nitrogen cation；Group R ', which is selected from, to be appointed Choose the C in generation_1-20(preferably C_1-10) linear or branched alkyl group, the C that optionally replaces_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic ring Alkyl, the C optionally replaced_2-20(preferably C_2-10) linear chain or branched chain alkenyl and the C that optionally replaces_6-20(preferably C_6-10) aryl；Group Rh is selected from the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) single Ring polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and optionally replace C_6-50(preferably C_6-20) aryl；Group X^-Selected from halide ion (preferably fluorine ion, chlorion, bromide ion and iodide ion, more preferably Chlorion) and hydroxide ion (OH^-)) one of substituting group directly substitute and the group that obtains；And linear chain or branched chain alkane One or more groups inside base molecular structureBy substituting groupOr(its In, group N⁺It is quaternary nitrogen cation；Group Rh is selected from the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, optionally take The C in generation_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) Linear chain or branched chain alkenyl and the C optionally replaced_6-50(preferably C_6-20) aryl；Group X^-Selected from halide ion (preferably fluorine ion, chlorine Ion, bromide ion and iodide ion, more preferable chlorion) and hydroxide ion (OH^-)) directly substitute and obtain group,

On condition that the group R₁, the group R₂, the group R₃With at least one of the group Rh in its knot Include C in structure₈Straight-chain part.

2. anionic-cationic-nonionic surface active agent described in any preceding aspect, wherein each group Poly is each From independently selected from formulaThe ether segment of representative； Between each group Poly, each numerical value m is same or different to each other, any number being each independently selected between 0 to 100, preferably 0 Any number between to 50；Between each group Poly, each numerical value n is same or different to each other, be each independently selected from 0 to Any number between 100, any number between preferably 0 to 50, on condition that the sum of whole numerical value m and whole numerical value n are more than 0；Preferably, the sum of whole numerical value m are more than 0 and are more than 0 no more than the sum of 100 (preferably more than 50) and/or whole numerical value n And no more than 100 (preferably more than 50).

3. anionic-cationic-nonionic surface active agent described in any preceding aspect, selected from substantially such as following formula (I-1) compound represented, substantially such as following formula (I-2) compound represented, substantially such as following formula (I-3) compound represented Substantially at least one of such as following formula (I-4) compound represented, and additional conditions are：These molecular structure of compounds At least one of N atoms be bonded with other group Rh and group X and be rendered as formula(wherein, group N⁺It is The quaternary nitrogen cationic form of at least one N atoms；Group Rh is selected from the C optionally replaced_1-50(preferably C_1-20) linear chain or branched chain Alkyl, the C optionally replaced_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally replace C_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl；Group X^-Selected from halide ion (preferably fluorine ion, chlorion, bromide ion and iodide ion, more preferable chlorion) and hydroxide ion (OH^-)) shown in quaternary ammonium salt And/or the form of quaternary ammonium base,

In formula (I-1), each group Ra is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-20Straight chain Or branched alkyl, the C that optionally replaces_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-10Aryl；Each group Ra ' is mutually the same Or different, the C for being each independently selected from singly-bound, optionally replacing_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Straight chain or Branched alkenylene, carbonyl, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the C optionally replaced_2-10Linear chain or branched chain is sub- Alkenyl carbonyl, the C for being preferably each independently selected from singly-bound and optionally replacing_1-6Linear chain or branched chain alkylidene；B is between 1 to 3 Arbitrary integer, preferably 1；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that when group Y is N, a =1, when group Y is 0, a=0, and at least one group Y is N；X ' be between 1 to 5 arbitrary integer (preferably 1 to 4 it Between arbitrary integer, such as 1,2 or 3)；Each group Rp₁It is same or different to each other, is each independently selected from formulaThe group of representative, hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), The C optionally replaced_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl, on condition that at least one Group Rp₁It is formulaThe group of representative；Each group Rp₂That This is identical or different, is each independently selected from formulaIt represents Group, hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and optionally Substituted C_6-50(preferably C_6-20) aryl；Each numerical value m ' is same or different to each other, and is each independently selected from arbitrary between 0 to 100 Numerical value, any number between preferably 0 to 50, each numerical value n ' are same or different to each other, are each independently selected between 0 to 100 Any number, any number between preferably 0 to 50, each numerical value m " is same or different to each other, be each independently selected from 0 to Any number between 100, any number between preferably 0 to 50, each numerical value n " are same or different to each other, select each independently Any number between from 0 to 100, any number between preferably 0 to 50, on condition that whole numerical value m ', whole numerical value m ", complete The sum of portion numerical value n ' and whole numerical value n " are more than 0 and no more than 200 (are preferably greater than 0 and are no more than 100)；Each group L phases each other It is same or different, it is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Straight chain or branch Chain alkenylene (is preferably each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene)；Each group Salt is mutually the same Or it is different, it is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄)；When group M is When alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5,

On condition that at least one of the group Ra and the group Rh include C in its structure₈Straight-chain part,

In formula (I-2), group Rb is selected from the C optionally replaced_1-49Linear or branched alkyl group, the C optionally replaced_5-49Monocycle is polycyclic Naphthenic base and the C optionally replaced_2-49Linear chain or branched chain alkenyl (is preferably selected from the C optionally replaced_1-29Linear or branched alkyl group optionally takes The C in generation_5-10Monocycle or polycyclic naphthene base and the C optionally replaced_2-29Linear chain or branched chain alkenyl, or selected from the C optionally replaced_8-29Straight chain Or branched alkyl, the C that optionally replaces_5-8Monocycle or polycyclic naphthene base and the C optionally replaced_8-29Linear chain or branched chain alkenyl, or be selected from The C optionally replaced_8-19Linear or branched alkyl group, the C optionally replaced_5-7C monocyclic cycloalkyl (such as cyclohexyl) and optionally replaced_8-19 Linear chain or branched chain alkenyl)；Each group Rb ' is same or different to each other, and is each independently selected from singly-bound and carbonyl；Each group Y phases each other It is same or different, it is each independently selected from N and O, on condition that when group Y is N, a=1, when group Y is O, a=0, and at least one A group Y is N；X " is the arbitrary integer (arbitrary integer between preferably 1 to 4, such as 1,2 or 3) between 1 to 10；Each group Rp₁It is same or different to each other, is each independently selected from formulaIt represents Group, hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle Or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50It is (excellent Select C_6-20) aryl, on condition that at least one group Rp₁It is formulaThe base of representative Group；Each group Rp₂It is same or different to each other, is each independently selected from formulaGeneration The group of table, hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and optionally Substituted C_6-50(preferably C_6-20) aryl；Each numerical value m ' is same or different to each other, and is each independently selected from arbitrary between 0 to 100 Numerical value, any number between preferably 0 to 50, each numerical value n ' are same or different to each other, are each independently selected between 0 to 100 Any number, any number between preferably 0 to 50, each numerical value m " is same or different to each other, be each independently selected from 0 to Any number between 100, any number between preferably 0 to 50, each numerical value n " are same or different to each other, select each independently Any number between from 0 to 100, any number between preferably 0 to 50, on condition that whole numerical value m ', whole numerical value m ", complete The sum of portion numerical value n ' and whole numerical value n " are more than 0 and no more than 200 (are preferably greater than 0 and are no more than 100)；Each group L phases each other It is same or different, it is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Straight chain or branch Chain alkenylene (is preferably each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene)；Each group Salt is mutually the same Or it is different, it is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄)；When group M is When alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5,

On condition that at least one of the group Rb and the group Rh include C in its structure₈Straight-chain part,

In formula (I-3), each group Rc is same or different to each other, and is each independently selected from the C optionally replaced_1-20Linear chain or branched chain Alkyl, the C optionally replaced_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and optionally replace C_2-20Linear chain or branched chain alkenyl carbonyl (or it is each independently selected from the C optionally replaced_1-10Linear or branched alkyl group optionally replaces C_2-10Linear chain or branched chain alkenyl, the C optionally replaced_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkene Base carbonyl, or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkene Base, the C optionally replaced_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Linear chain or branched chain alkenyl carbonyl)；Each group Rd It is same or different to each other, is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Straight chain or Branched alkenylene, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl Base, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl Base (is preferably each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylene Base carbonyl)；X " ' is the arbitrary integer (arbitrary integer between preferably 1 to 4, such as 1,2 or 3) between 1 to 10；Each group Rp It is same or different to each other, is each independently selected from formulaIt represents Group, hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle Or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50It is (excellent Select C_6-20) aryl, on condition that at least one group Rp is formulaGeneration The group of table；Each numerical value m ' is same or different to each other, any number being each independently selected between 0 to 100, preferably 0 to 50 Between any number, each numerical value n ' is same or different to each other, any number being each independently selected between 0 to 100, preferably Any number between 0 to 50, on condition that the sum of whole numerical value m ' and whole numerical value n ' are more than 0 and (are preferably greater than no more than 200 0 and no more than 100)；Each group L is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain is sub- Alkyl and the C optionally replaced_2-10Linear chain or branched chain alkenylene (is preferably each independently selected from the C optionally replaced_1-5Straight chain or branch Chain alkylidene)；Each group Salt is same or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg And Ca) and ammonium root (NH₄)；When group M is alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5,

On condition that at least one of the group Rc and the group Rh include C in its structure₈Straight-chain part,

In formula (I-4), group Rc is selected from the C optionally replaced_1-20Linear or branched alkyl group, the C optionally replaced_2-20Straight chain or Branched-chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and the C optionally replaced_2-20Linear chain or branched chain alkenyl carbonyl (or Person is each independently selected from the C optionally replaced_1-10Linear or branched alkyl group, the C optionally replaced_2-10Linear chain or branched chain alkenyl, optionally Substituted C_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenyl carbonyl, or each independently Selected from the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Directly Chain or branched alkyl carbonyl and the C optionally replaced_8-20Linear chain or branched chain alkenyl carbonyl)；Each group Rd is same or different to each other, respectively From independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, optionally Substituted C_1-10Linear chain or branched chain alkylenecarbonyl, the C optionally replaced_2-10It linear chain or branched chain alkenylene carbonyl, the carbonyl that optionally replaces Base C_1-10Linear chain or branched chain alkylenecarbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl is (preferably respectively solely On the spot it is selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl)；Base Group Y is N or O, on condition that when group Y is N, a=1, when group Y is O, a=0；X " " is the arbitrary integer between 1 to 9 (arbitrary integer between preferably 1 to 3, more preferable 1 or 2)；Each group Rp₁It is same or different to each other, is each independently selected from formulaThe group of representative, hydrogen, the C optionally replaced_1-50(preferably C_1-20) straight Chain or branched alkyl, the C optionally replaced_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substitution C_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl, on condition that at least one group Rp₁It is formulaThe group of representative；Each group Rp₂It is mutually the same Or it is different, it is each independently selected from formulaThe group of representative, is appointed at hydrogen Choose the C in generation_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene Base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) virtue Base；Each group Rp₃It is same or different to each other, is each independently selected from formula The group of representative, hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or Person C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and appoint Choose the C in generation_6-50(preferably C_6-20) aryl；Each numerical value m ' is same or different to each other, and is each independently selected from appointing between 0 to 100 Anticipate numerical value, any number between preferably 0 to 50, each numerical value n ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50, each numerical value m " is same or different to each other, be each independently selected from 0 to Any number between 100, any number between preferably 0 to 50, each numerical value n " are same or different to each other, select each independently Any number between from 0 to 100, any number between preferably 0 to 50, each numerical value m " ' are same or different to each other, respectively solely Any number being on the spot selected between 0 to 100, any number between preferably 0 to 50, each numerical value n " ' are same or different to each other, Any number being each independently selected between 0 to 100, any number between preferably 0 to 50, on condition that whole numerical value m ', The sum of whole numerical value m ", whole numerical value m " ', whole numerical value n ', whole numerical value n " with whole numerical value n " ' are more than 0 and are no more than 200 (be preferably greater than 0 and be no more than 100)；Each group L is same or different to each other, and is each independently selected from the C optionally replaced_1-10Straight chain Or branched alkylidene and the C that optionally replaces_2-10Linear chain or branched chain alkenylene (is preferably each independently selected from the C optionally replaced_1-5 Linear chain or branched chain alkylidene)；Each group Salt is same or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group of representative, Wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal (preferably Li, Na and K), alkaline earth gold Belong to (preferably Mg and Ca) and ammonium root (NH₄)；When group M is alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r =0.5,

Wherein, the optional substitution refers to optionally by one or more selected from hydroxyl, C_1-20(preferably C_1-10) straight chain or branch Alkyl group, C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferably C_2-10) straight chain or branch Alkenyl and C_6-20(preferably C_6-10) aryl substituent group substitution.

4. anionic-cationic-nonionic surface active agent described in any preceding aspect, wherein the group X^-With The group (M)_r ⁺In at least part with (M)_r ⁺X^-Form independently of the anionic-cationic-non-ionic surface Activating agent and exist, it is preferred that in the entire molecular structure of the anionic-cationic-nonionic surface active agent, If the group X^-Total number be e1, the group N⁺Total number be e2, the group A^-Total number be e3, the base Group (M)_r ⁺Total number be e4, as e2=e3,0≤e1≤e2,0≤e4≤e3, as e2 ＞ e3,0 ＜ e1≤e2,0≤e4 ≤ e3, as e2 ＜ e3,0≤e1≤e2,0 ＜ e4≤e3, but on condition that e1+e3=e2+e4, alternatively, e2=e3, e1=0, e4 =0.

5. a kind of manufacturing method of anionic-cationic-nonionic surface active agent, which is characterized in that including following Step：

Step (1)：Make one or more nitrogenous and is selected from-OH ,-NH with one or more₂With the functional group of-NH- Polyfunctional compound is with alkylene oxide shown in one or more following formulas (Y) in basic catalyst (preferred alkali metal hydroxide) In the presence of react, obtain etherification product,

In formula (Y), group Ru ' is selected from C_2-6Linear chain or branched chain alkylidene (is preferably selected from-CH₂-CH₂And-CH₂-CH (CH₃) -),

Step (2)：The etherification product is set to be reacted with quaternizing agent shown in following formula (A), thus to obtain cation- Nonionic surface active agent, wherein the dosage of the quaternizing agent makes at least one of described etherification product molecular structure N atoms form quaternary ammonium salt group,

Rh-X′ (A)

In formula (A), group Rh is selected from the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, optionally replace C_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) straight chain Or branched-chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl；Group X ' be selected from halogen (preferably fluorine, chlorine, bromine and iodine, it is more excellent Select chlorine),

On condition that at least one of the polyfunctional compound and the quaternizing agent include C in its molecular structure₈ Straight-chain part,

Step (3)：Make the cation-nonionic surface active agent and chemical combination shown in one or more following formulas (Z) Object reacts in the presence of basic catalyst (preferred alkali metal hydroxide), thus to obtain anionic-cationic-nonionic Surfactant,

G-L-AS (Z)

In formula (Z), group G is selected from halogen (preferably fluorine, chlorine, bromine and iodine, more preferable chlorine) and hydroxyl；Group L is selected from optional Substituted C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene (is preferably selected from and optionally replaces C_1-5Linear chain or branched chain alkylidene)；Group AS is selected from by-A^-(M′)_r ⁺The group of representative；Group A^-Selected from carboxylate radical (COO^-) and sulphur Acid group (SO₃ ^-)；Group M ' is selected from hydrogen, alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄)； When group M ' is hydrogen, alkali metal or ammonium root, r=1；When group M ' is alkaline-earth metal, r=0.5,

Optionally, step (4)：The anionic-cationic that the arbitrary steps of the manufacturing method are obtained-nonionic table At least part quaternary ammonium salt group in the activating agent of face is converted to corresponding quaternary ammonium base groups, and/or, by the anion-sun At least part quaternary ammonium base groups in ion-nonionic surface active agent are converted to corresponding quaternary ammonium salt group,

Optionally, step (5)：The anionic-cationic obtained from the arbitrary steps of the manufacturing method-nonionic table At least part (preferably all) existing compound (M ') in a free form is isolated in the activating agent of face_rX ',

6. the manufacturing method described in any preceding aspect is changed wherein the polyfunctional compound is selected from shown in lower formula (X) At least one of object is closed,

In formula (X), group R '₁To R '₃It is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50It is (excellent Select C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferably C_5-7 Monocyclic cycloalkyl such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl, the C that optionally replaces_6-50It is (excellent Select C_6-20) aryl and by formulaThe group of representative, on condition that group R '₁To R '₃At least one of It is hydrogen or by formulaThe group of representative, it is so-called herein " optionally substitution ", refer to optionally by one or It is multiple to be selected from oxo, hydroxyl, by formulaGroup, the C of representative_1-20(preferably C_1-10) linear chain or branched chain Alkyl, C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferably C_2-10) linear chain or branched chain Alkenyl and C_6-20(preferably C_6-10) aryl substituent group substitution；Group LA is selected from the x0+1 valences C optionally replaced_1-50(preferably C_1-20) Linear or branched alkyl group, the x0+1 valences C optionally replaced_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferably C_5-7It is single Ring naphthenic base such as cyclohexyl), the x0+1 valences C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl, the x0+ that optionally replaces 1 valence C_6-50(preferably C_6-20) aryl and the x0+1 valences C that optionally replaces_3-50(preferably C_3-20) linear chain or branched chain miscellaneous alkyl；X0 be 1 to Arbitrary integer (the arbitrary integer between preferably 1 to 4, such as 1,2 or 3) between 10；Each group Func is mutually the same or not Together ,-OH, ＞ NH and-NH are each independently selected from₂, also, the linear chain or branched chain miscellaneous alkyl is selected from linear or branched alkyl group point One or more group-CH inside minor structure₂By selected from-O- ,-S- ,-NR '-, (wherein, group R ' is selected from and optionally replaces C_1-20(preferably C_1-10) linear or branched alkyl group, the C that optionally replaces_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally Substituted C_2-20(preferably C_2-10) linear chain or branched chain alkenyl and the C that optionally replaces_6-20(preferably C_6-10) aryl) and (wherein, group N⁺It is quaternary nitrogen cation；Group R ' is selected from the C optionally replaced_1-20(preferably C_1-10) linear or branched alkyl group, optionally Substituted C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base, the C that optionally replaces_2-20(preferably C_2-10) linear chain or branched chain alkene Base and the C optionally replaced_6-20(preferably C_6-10) aryl；Group Rh is selected from the C optionally replaced_1-50(preferably C_1-20) linear chain or branched chain Alkyl, the C optionally replaced_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally replace C_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl；Group X^-Selected from halide ion (preferably fluorine ion, chlorion, bromide ion and iodide ion, more preferable chlorion) and hydroxide ion (OH^-)) one of replacement base Group directly substitutes and the group of acquisition；And one or more groups inside linear or branched alkyl group molecular structureBy substituting groupOr(wherein, group N⁺It is quaternary nitrogen cation；Group Rh choosings From the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or Polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50 (preferably C_6-20) aryl；Group X^-Selected from halide ion (preferably fluorine ion, chlorion, bromide ion and iodide ion, more preferable chlorine from Son) and hydroxide ion (OH^-)) directly substitute and obtain group,

The polyfunctional compound be preferably selected from following formula (X-1) compound represented, following formula (X-2) compound represented, At least one of following formula (X-3) compound represented and following formula (X-4) compound represented,

In formula (X-1), each group Ra is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-20Straight chain Or branched alkyl, the C that optionally replaces_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-20Aryl；Each group Ra ' is mutually the same Or different, the C for being each independently selected from singly-bound, optionally replacing_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Straight chain or Branched alkenylene, carbonyl, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the C optionally replaced_2-10Linear chain or branched chain is sub- Alkenyl carbonyl, the C for being preferably each independently selected from singly-bound and optionally replacing_1-6Linear chain or branched chain alkylidene；B is between 1 to 3 Arbitrary integer, preferably 1；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that when group Y is N, a1 =1, when group Y is O, a1=0, and at least one group Y is N；X1 be between 1 to 5 arbitrary integer (preferably 1 to 4 it Between arbitrary integer, such as 1,2 or 3)；Each group Rp '₁It is same or different to each other, is each independently selected from hydrogen, optionally substitution C_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C optionally replaced_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) Aryl, on condition that at least one group Rp '₁It is hydrogen；Each group Rp '₂Be same or different to each other, be each independently selected from hydrogen, optionally Substituted C_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic ring Alkyl (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl,

In formula (X-2), group Rb is selected from the C optionally replaced_1-49Linear or branched alkyl group, the C optionally replaced_5-49Monocycle or Polycyclic naphthene base and the C optionally replaced_2-49Linear chain or branched chain alkenyl (is preferably selected from the C optionally replaced_1-29Linear or branched alkyl group, The C optionally replaced_5-10Monocycle or polycyclic naphthene base and the C optionally replaced_2-29Linear chain or branched chain alkenyl, or selected from optionally substitution C_8-29Linear or branched alkyl group, the C optionally replaced_5-8Monocycle or polycyclic naphthene base and the C optionally replaced_8-29Linear chain or branched chain alkene Base, or selected from the C optionally replaced_8-19Linear or branched alkyl group, the C optionally replaced_5-7Monocyclic cycloalkyl (such as cyclohexyl) and The C optionally replaced_8-19Linear chain or branched chain alkenyl)；Each group Rb ' is same or different to each other, and is each independently selected from singly-bound and carbonyl Base；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that when group Y is N, a2=1, as group Y When being O, a2=0, and at least one group Y is N；X2 is that the arbitrary integer between 1 to 10 is (arbitrary whole between preferably 1 to 4 Number, such as 1,2 or 3)；Each group Rp '₁It is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as hexamethylene Base), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl, premise It is at least one group Rp '₁It is hydrogen；Each group Rp '₂It is same or different to each other, is each independently selected from hydrogen, optionally replaces C_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C optionally replaced_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) Aryl,

In formula (X-3), each group Rc is same or different to each other, and is each independently selected from the C optionally replaced_1-20Straight chain or branch Alkyl group, the C optionally replaced_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and optionally substitution C_2-20Linear chain or branched chain alkenyl carbonyl (or it is each independently selected from the C optionally replaced_1-10Linear or branched alkyl group optionally takes The C in generation_2-10Linear chain or branched chain alkenyl, the C optionally replaced_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Straight chain or Branched-chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Straight chain Or branched-chain alkenyl, the C that optionally replaces_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Linear chain or branched chain alkenyl carbonyl Base)；Each group Rd is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene, optionally Substituted C_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl, the C optionally replaced_2-10Directly Chain or branched alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the carbonyl C optionally replaced_2-10 Linear chain or branched chain alkenylene carbonyl (is preferably each independently selected from the C optionally replaced_1-5It linear chain or branched chain alkylidene and optionally takes The C in generation_1-5Linear chain or branched chain alkylenecarbonyl)；X3 be between 1 to 10 arbitrary integer (arbitrary integer between preferably 1 to 4, Such as 1,2 or 3)；Each group Rp ' is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as hexamethylene Base), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) aryl, premise Be at least one group Rp ' it is hydrogen,

In formula (X-4), group Rc is selected from the C optionally replaced_1-20Linear or branched alkyl group, the C optionally replaced_2-20Straight chain or Branched-chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and the C optionally replaced_2-20Linear chain or branched chain alkenyl carbonyl (or Person is each independently selected from the C optionally replaced_1-10Linear or branched alkyl group, the C optionally replaced_2-10Linear chain or branched chain alkenyl, optionally Substituted C_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenyl carbonyl, or each independently Selected from the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Directly Chain or branched alkyl carbonyl and the C optionally replaced_8-20Linear chain or branched chain alkenyl carbonyl)；Each group Rd is same or different to each other, respectively From independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, optionally Substituted C_1-10Linear chain or branched chain alkylenecarbonyl, the C optionally replaced_2-10It linear chain or branched chain alkenylene carbonyl, the carbonyl that optionally replaces Base C_1-10Linear chain or branched chain alkylenecarbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl is (preferably respectively solely On the spot it is selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl)；Base Group Y is N or O, on condition that when group Y is N, a4=1, when group Y is O, a4=0；X4 is the arbitrary integer between 1 to 9 (arbitrary integer between preferably 1 to 3, more preferable 1 or 2)；Each group Rp '₁It is same or different to each other, is each independently selected from Hydrogen, the C optionally replaced_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle Or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and optionally replace C_6-50(preferably C_6-20) aryl, on condition that at least one group Rp '₁It is hydrogen；Each group Rp '₂It is same or different to each other, respectively solely The C for being on the spot selected from hydrogen, optionally replacing_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C that optionally replaces_2-50(preferably C_2-20) linear chain or branched chain alkenyl and optionally Substituted C_6-50(preferably C_6-20) aryl；Each group Rp '₃It is same or different to each other, is each independently selected from hydrogen, optionally replaces C_1-50(preferably C_1-20) linear or branched alkyl group, the C that optionally replaces_5-50(preferably C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), the C optionally replaced_2-50(preferably C_2-20) linear chain or branched chain alkenyl and the C that optionally replaces_6-50(preferably C_6-20) Aryl,

Wherein, do not having especially explicitly, it is so-called " optionally substitution ", it refers to optionally being selected from by one or more Oxo, hydroxyl, C_1-20(preferably C_1-10) linear or branched alkyl group, C_5-10(preferably C_5-8Or C_5-7) monocycle or polycyclic naphthene base (ratio Such as cyclohexyl), C_2-20(preferably C_2-10) linear chain or branched chain alkenyl and C_6-20(preferably C_6-10) aryl substituent group substitution.

7. the manufacturing method described in any preceding aspect, wherein the molar ratio of the polyfunctional compound and the alkylene oxide For 1: 0-200 (preferably 1: 0-100), but do not include 0；The polyfunctional compound rubs with the formula (Z) compound represented You are than being 1: 1-10 (preferably 1: 1-3)；The reaction condition of the step (1) includes：Reaction temperature be room temperature to 300 DEG C (preferably 100-200 DEG C), the reaction time is 1-20 hours (preferably 1-10 hours)；The reaction condition of the step (2) includes：Reaction temperature Degree is 0-300 DEG C (preferably 50-150 DEG C), and the reaction time is 1-20 hours (preferably 4-15 hours)；The reaction of the step (3) Condition includes：Reaction temperature is 0-300 DEG C (preferably 50-200 DEG C), and the reaction time is 1-20 hours (preferably 4-10 hours).

8. the manufacturing method described in any preceding aspect wherein the alkylene oxide includes at least propylene oxide, and makes institute Polyfunctional compound is stated first to react with the propylene oxide.

9. a kind of displacement composition used for tertiary oil recovery, which is characterized in that include anion-sun described in any preceding aspect Ion-nonionic surface active agent or the anionic-cationic-manufactured according to the manufacturing method described in any preceding aspect Nonionic surface active agent, Yi Jishui, wherein by the total weight of the displacement composition used for tertiary oil recovery for 100wt% in terms of, The weight percentage of the anionic-cationic-nonionic surface active agent is 0.001-10wt%, preferably 0.005- 5wt%, more preferable 0.02-1wt%.

10. the displacement composition used for tertiary oil recovery described in any preceding aspect, wherein not including inorganic base.

11. a kind of manufacturing method of displacement composition used for tertiary oil recovery, which is characterized in that make described in any preceding aspect Anionic-cationic-nonionic surface active agent or according to the manufacturing method manufacture described in any preceding aspect it is cloudy from Son-cation-nonionic surface active agent is at least mixed with water, wherein with the gross weight of the displacement composition used for tertiary oil recovery Amount is that 100wt% is counted, and the weight percentage of the anionic-cationic-nonionic surface active agent is 0.001- 10wt%, preferably 0.005-5wt%, more preferable 0.02-1wt%.

12. a kind of tertiary oil recovery method, which is characterized in that including use anion-sun described in any preceding aspect from Son-nonionic surface active agent, according to described in any preceding aspect manufacturing method manufacture anionic-cationic-it is non-from Displacement composition used for tertiary oil recovery described in subtype surfactant, any preceding aspect or according to described in any preceding aspect Manufacturing method manufacture displacement composition used for tertiary oil recovery as displacing fluid progress tertiary oil recovery the step of.

13. the tertiary oil recovery method described in any preceding aspect, wherein not using inorganic base.

Technique effect

Anionic-cationic-nonionic surface active agent according to the present invention is shown compared with prior art significantly Improved interfacial activity.For example, being remained under conditions of the dosage of the surfactant is down to 0.01~0.05wt% and underground Crude oil forms 10^-3-10^-4MN/m ultralow interfacial tension.

Anionic-cationic-nonionic surface active agent according to the present invention or displacement composition used for tertiary oil recovery, i.e., Make to be that at high temperature, can also form stable and transparent aqueous solution in water, and in situations where it is preferred, even across length Phase (especially at high temperature) storage, chemical composition and interfacial activity also keep excellent stability.

Anionic-cationic-nonionic surface active agent according to the present invention or displacement composition used for tertiary oil recovery, Be not in chromatographic isolation phenomenon during use, stability in use is excellent.

Displacement composition used for tertiary oil recovery according to the present invention, due to the use of the present invention anionic-cationic-it is non-from Subtype surfactant shows the oil displacement efficiency improved compared with prior art and washing oil ability as surface active agent composition (for example can be more than 40% to the washing oil rate of crude oil), can significantly improve oil recovery factor.

Displacement composition used for tertiary oil recovery according to the present invention, system is simple, does not contain inorganic base, does not have to stratum and oil well There is injury, avoid the corrosion of equipment and pipeline, and demulsification will not be caused difficult.

Specific implementation mode

The specific implementation mode of the present invention is described in detail below, it should be noted however that the protection of the present invention Range is not limited to these specific embodiments, but is determined by the appended claims.

All publications, patent application, patent and the other bibliography that this specification is mentioned all draw in this for reference. Unless otherwise defined, all technical and scientific terms used herein all contains with what those skilled in the art routinely understood Justice.In case of conflict, it is subject to the definition of this specification.

When this specification with prefix " well known to those skilled in the art ", " prior art " or its export material similar to term Whens material, substance, method, step, device or component etc., object derived from the prefix is covered this field when the application proposes and is routinely made Those of with, but also include also being of little use at present, it will but become art-recognized for suitable for those of similar purpose.

In the context of the present specification, other than the content clearly stated, any matters or item that do not mention are equal It is directly applicable in those of known in the art without carrying out any change.Moreover, any embodiment described herein can be with It is freely combined with one or more other embodiments described herein, the technical solution or technological thought formed therefrom regards For the original disclosure of the present invention or a part for original description, and be not considered as not disclosing or be expected herein it is new in Hold, unless those skilled in the art think that the combination is apparent unreasonable.

In the context of the present invention, statement " halogen " refers to fluorine, chlorine, bromine or iodine.

In the context of the present invention, so-called " linear chain or branched chain miscellaneous alkyl ", refers to linear or branched alkyl group molecule knot Inside structure (not including the end of main chain or any side chain in the alkyl molecule structure) one or more (such as 1 to 4,1 to 3,1 to 2 or 1) group-CH₂By selected from-O- ,-S- ,-NR '-andOne of substituting group it is direct Substitute and inside the group or linear or branched alkyl group molecular structure that obtain (do not include in the alkyl molecule structure main chain or The end of any side chain) one or more (such as 1 to 3,1 to 2 or 1) groupBy replacement base GroupOrThe group for directly substituting and obtaining.As the substituting group, preferably-NR '-orMore preferably-NR '-.Here, group R ' is selected from the C optionally replaced_1-20Linear or branched alkyl group, optionally substitution C_5-10Monocycle or polycyclic naphthene base, the C optionally replaced_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-20Aryl.As institute State C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group, specifically Such as methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene Base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As described C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or alkene Propyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.As the group R ', preferably C_1-20Linear or branched alkyl group or C_5-7Monocyclic cycloalkyl, specifically such as methyl, ethyl or cyclohexyl.Group N⁺ It is quaternary nitrogen cation.Group Rh is selected from the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic ring Alkyl, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.In the definition of group Rh, as institute State C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle is polycyclic Naphthenic base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle is polycyclic Naphthenic base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, For example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, 12 carbon Alkenyl, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or Person C_6-10Aryl, specifically such as phenyl or naphthalene.Group X^-Selected from halide ion (including fluorine ion, chlorion, bromide ion and Iodide ion) and hydroxide ion (0H^-), wherein it is preferred that halide ion, more preferable chlorion.Here, so-called " optionally substitution ", refers to Be optionally to be selected from hydroxyl, C by one or more (such as 1 to 4,1 to 3,1 to 2 or 1)_1-20Linear chain or branched chain Alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As described C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group, Huo Zhejia Base or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Straight chain Or branched-chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..Make For the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.It is apparent that from structural stability Angle for, when there are multiple, not Direct Bonding between these substituting groups.In addition, though the linear chain or branched chain alkane The carbon atom number of base is because of group-CH₂Or groupIt is accordingly reduced by replacement, but in order to state simplicity, still uses The carbon atom number of the replacement foregoing description linear or branched alkyl group refers to the carbon atom number of the linear chain or branched chain miscellaneous alkyl.As The linear chain or branched chain miscellaneous alkyl, for concrete example, C₄Straight chained alkyl is such as(formula Group indicated by middle arrow is not in inside molecular structure, but the end in main chain) it is direct by a substituting group-O- It substitutes acquisition-CH₂-O-CH₂-CH₃Or-CH₂-CH₂-O-CH₃, referred to as C₄Linear heteroalkyl group.Alternatively, C₄Branched alkyl is such as(group in formula indicated by arrow is not in inside molecular structure, but in main chain and The end of side chain) by a substituting groupDirectly substituting will obtainClaim Be C₄Branched heteroalkyl groups.According to the present invention, as the linear chain or branched chain miscellaneous alkyl, for example C can be enumerated_3-50Straight chain or branch Chain miscellaneous alkyl, specifically such as C_8-50Linear chain or branched chain miscellaneous alkyl, C_8-30Linear chain or branched chain miscellaneous alkyl or C_8-20Linear chain or branched chain is miscellaneous Alkyl or C_3-20Linear chain or branched chain miscellaneous alkyl, C_3-10Linear chain or branched chain miscellaneous alkyl or C_3-6Linear chain or branched chain miscellaneous alkyl.

In the context of the present specification, expression way " number+valence+group " or its referred to from the group similar to term It removes in corresponding foundation structure (such as chain, ring or combinations thereof etc.) and obtains after the hydrogen atom of the quantity representated by the number Group preferably refers to remove from the carbon atom (preferably saturated carbon atom and/or the non-same carbon atom) contained by the structure The group obtained after the hydrogen atom of quantity representated by the number.For example, " trivalent linear or branched alkyl group " is referred to from this The group for removing 3 hydrogen atoms on linear chain or branched chain alkane (the basic chain i.e. corresponding to the linear or branched alkyl group) and obtaining, And " divalent linear chain or branched chain miscellaneous alkyl " then refers to that (carbon preferably contained by the miscellaneous alkane is former from the miscellaneous alkane of the linear chain or branched chain Son, or further, from the non-same carbon atom) on remove 2 hydrogen atoms and the group that obtains.Obviously, expression way " 0 Valence+group " represents the foundation structure, for example 0 valence alkyl refers to alkane.

In the context of the present specification, so-called " includes C in structure₈Straight-chain part " refers to involved chemical combination Object or group are bonded by 8 carbon atoms by straight chain mode in its whole chemical constitution comprising (such as one or more) in succession Made of structure fragment.It is specifically defined or replaces situation depending on the chemical constitution, this 8 carbon atoms can be respectively independent Ground is rendered as substitution state or unsubstituted state.Moreover, the C₈Straight-chain part may be at the inside (ratio of the chemical constitution Main chain as constituted the chemical constitution), the end that can also be in the chemical constitution (for example constitutes the end group of the chemical constitution Or side chain), it is not particularly limited.For concrete example, if group R1 (as described below) includes C in its structure₈ Straight-chain part, if setting group R₁It is the C optionally replaced₁₀Linear or branched alkyl group, then group R₁May be-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₃、

-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH(CH₃)-CH₃、

-CH₂-CH₂-CH₂-CH₂-CH₂-CH(CH₃)-CH(CH₃)-CH₃、

-CH₂-CH(OH)-CH₂-CH₂-CH₂-CH(CH₃)-CH(CH₃)-CH₃、

-CH₂-CH₂-CH₂-CH₂-CH₂-C(OH)(CH₃)-CH(CH₃)-CH₃、

-CH₂-CH₂- C (=O)-CH₂-CH₂-CH(CH₃)-CH(CH₃)-CH₃Or

-CH₂-CH(CH₃)-CH₂- C (=O)-CH₂-CH₂-CH(CH₃)-CH₃(in these alkyl, shown in each underscore By 8 carbon atoms by the as described C of structure fragment made of straight chain mode in succession bonding₈Straight-chain part) etc., but cannot It is

-CH(CH₃)-CH₂-CH₂-CH₂-CH(CH₃)-CH(CH₃)-CH₃Or

-CH(CH₂CH₂CH₂CH₃)-CH(CH₃)-CH(CH₃)-CH₃Deng (successive there is no straight chain mode is pressed by 8 carbon atoms Structure fragment made of bonding).As shown in this example, as long as group R₁Include C in its structure₈Straight-chain part is as it A part (segment) for structure, and to the C₈The location of straight-chain part does not limit, it may be possible to main chain, end group Or side chain, and obviously the group R is not limited yet₁It is only made of 8 carbon atoms or the C₈Straight-chain part is merely presented as- CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-CH₂-。

In the case where not clearly indicating, all percentages, number, the ratio etc. that are previously mentioned in this specification be all with On the basis of weight, unless not meeting the conventional understanding of those skilled in the art when on the basis of weight.

According to the present invention, it is related to a kind of anionic-cationic-nonionic surface active agent, the anionic-cationic- Nonionic surface active agent is substantially such as following formula (I) compound represented.Formula (I) compound represented can be used only One kind, can also combination of two or more use.

According to the present invention, in formula (I), group N⁺It is quaternary nitrogen cation, so that being somebody's turn to do (I) compound represented becomes Quaternary ammonium type compound.

According to the present invention, in formula (I), group R₁To R₃It is same or different to each other, is each independently selected from and optionally replaces C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkene Base, the C optionally replaced_6-50Aryl and by formulaThe group of representative.Here, so-called " optional Substitution " refers to optionally being selected from oxo (i.e. by one or more (such as 1 to 4,1 to 3,1 to 2 or 1))、 Hydroxyl, by formulaGroup, the C of representative_1-20Linear or branched alkyl group, C_5-10Monocycle is more Ring naphthenic base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, For example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As institute State C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene Base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, such as C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, For example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I), it is desirable that group R₁To R₃At least one of (such as at most two) be by formulaThe group of representative.

According to the present invention, in formula (I), group Rh is selected from the C optionally replaced_1-50Linear or branched alkyl group, optionally substitution C_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.

According to the present invention, in formula (I), in group Rh and group R₁To R₃Definition in, as the C_1-50Straight chain or branch Alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, Lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, such as can To enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example can enumerate C_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, Vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, tool Body such as phenyl or naphthalene.

According to the present invention, in formula (I), group X^-Selected from halide ion (including fluorine ion, chlorion, bromide ion and iodine Ion) and hydroxide ion (OH^-), wherein it is preferred that halide ion, more preferable chlorion.

According to the present invention, in formula (I), by formulaIn the group of representative, group Link is selected from the x+1 valences C optionally replaced_1-50Linear or branched alkyl group, the x+1 valences C optionally replaced_5-50Monocycle or polycyclic naphthene base, The x+1 valences C optionally replaced_2-50Linear chain or branched chain alkenyl, the x+1 valences C optionally replaced_6-50Aryl and the x+1 valences C optionally replaced_3-50 Linear chain or branched chain miscellaneous alkyl.As the x+1 valences C optionally replaced_1-50Linear or branched alkyl group, the x+1 preferably optionally replaced Valence C_1-20Linear or branched alkyl group.As the x+1 valences C optionally replaced_5-50Monocycle or polycyclic naphthene base, for example can enumerate The x+1 valences C optionally replaced_5-10Monocycle or polycyclic naphthene base, the x+1 valences C optionally replaced_5-8Monocycle or polycyclic naphthene base are appointed Choose the x+1 valences C in generation_5-7Monocycle or polycyclic naphthene base, the x+1 valences C especially optionally replaced_5-7Monocyclic cycloalkyl, such as hexamethylene Base.As the x+1 valences C optionally replaced_2-50Linear chain or branched chain alkenyl, the x+1 valences C preferably optionally replaced_2-20Linear chain or branched chain Alkenyl.As the x+1 valences C optionally replaced_6-50Aryl, the x+1 valences C preferably optionally replaced_6-20Aryl, for example, phenyl or Naphthalene.As the x+1 valences C optionally replaced_3-50Linear chain or branched chain miscellaneous alkyl, the x+1 valences C preferably optionally replaced_3-20Linear chain or branched chain Miscellaneous alkyl.

According to the present invention, in formula (I), by formulaIn the group of representative, respectively Group Poly is same or different to each other, and is formula each independentlyThe group of representative.

According to the present invention, in formula (I), by formulaIn the group of representative, each Between group Poly, each numerical value y is same or different to each other, any number being each independently selected between 0 to 200, preferably 0 to Any number between 100.At this point, the numerical value y represents unit-O-Ru- in formulaGeneration Average number in the group of table, therefore can be non-integer.As the numerical value y, for example, can be 0,2.0,3.0,3.5, 7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc..

According to the present invention, in formula (I), it is desirable that the sum of x numerical value y is (i.e. by formulaIt represents Group or formula (I) compound represented overall molecule structure in, the population mean number of unit-O-Ru-) be more than 0, but it is general not More than 200, preferably more than 100.In consideration of it, in formula (I) compound represented or by formulaGeneration In the overall molecule structure of the group of table, it is necessary to contain (a certain number of) unit-O-Ru-, so that changing shown in formula (I) It closes object and is rendered as non-ionic nature.At this point, by formulaThe overall molecule knot of the group of representative In structure or in the overall molecule structure of formula (I) compound represented, as the population mean number of the unit-O-Ru-, Such as can be 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5, 50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc..

According to the present invention, in formula (I), between each group Poly, each group Ru is same or different to each other, respectively independent Ground is selected from C_2-6Linear chain or branched chain alkylidene, preferably-CH₂-CH₂-、-CH₂-CH(CH₃)-or combinations thereof, especially-CH₂-CH (CH₃)-or-CH₂-CH(CH₃)-and other C_2-6The combination of linear chain or branched chain alkylidene.

According to the present invention, in formula (I), in formulaIn the group of representative, as group Ru To be selected from C_2-6It, can be according to nothing between each (different) unit-O-Ru- when two or more in linear chain or branched chain alkylidene The modes such as rule, (two or more) block or alternating are mutually bonded with the ratio arbitrarily determined as needed, but these units is total Body average number is y.For example, when group Ru is-CH₂-CH₂With-CH₂-CH(CH₃)-combination, and y be 2.2 when, Unit-O-CH₂-CH₂With unitBetween can be according to (two or more) block, alternating or nothing Ratio (for example molar ratio between the two can be for 1: 99 to 99: 1) phase of any ways such as rule arbitrarily to determine as needed Mutually bonding, but the population mean number of both units is 2.2.

According to the present invention, there are one or more group Poly, it is preferred that (preferably complete at least one group Poly The group Poly in portion) in, the group Ru of at least part (at least certain amount) is selected from C_3-6Linear chain or branched chain alkylidene is (corresponding In non-O-CH₂-CH₂Unit), wherein it is preferred that-CH₂-CH(CH₃)-(corresponds to unit), by This makes group Poly preferably comprise, and (certain amount is limited to y) non-O-CH thereon₂-CH₂Unit (such as unit) it is used as Component units.

According to embodiment of the present invention, in formula (I), each group Poly is each independently or wherein at least one A group Poly is selected from (two blocks) ether segment that following formula (I-A) represents.At this point, as shown in formula (I-A), unit-O-CH₂-CH₂- With unitBetween be bonded in the way of (two) block.

Embodiment according to the present invention, it is preferred that the ether segment is bonded in the following way with group Link.

The embodiment according to the present invention, between each group Poly (or in group Poly), each numerical value m that This is identical or different, any number being each independently selected between 0 to 100, any number between preferably 0 to 50.At this point, The numerical value m represents unitAverage number in formula (I-A), therefore can be whole with right and wrong Number.As the numerical value m, for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0, 30.2,35.0,40.0,45.5 or 50.5 etc..

The embodiment according to the present invention, between each group Poly (or in group Poly), each numerical value n that This is identical or different, any number being each independently selected between 0 to 100, any number between preferably 0 to 50.At this point, The numerical value n represents unitAverage number in formula (I-A), therefore can be Non-integer.As the numerical value n, for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0, 25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

Embodiment according to the present invention, in formula (I) or by formulaThe base of representative In group, it is preferred that when x group Poly is each independently selected from (two blocks) ether segment of formula (I-A) representative, x The sum of numerical value m is (i.e. in formula (I) compound represented or by formulaThe group of representative it is whole In body molecular structure, unitPopulation mean number) be more than 0, but be usually no more than 100, Preferably more than 50.In consideration of it, in formula (I) compound represented or by formulaIt represents In the overall molecule structure of group, (a certain number of) unit is preferably comprisedAt this point, in formula (I) compound represented or by formulaIn the overall molecule structure of the group of representative, as The unitPopulation mean number, such as can be 0.1,0.5,1.2,2.0,2.5, 3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

Embodiment according to the present invention, in formula (I) or by formulaThe base of representative In group, it is preferred that when x group Poly is each independently selected from (two blocks) ether segment of formula (I-A) representative, x The sum of numerical value n is (i.e. in formula (I) compound represented or by formulaThe group of representative it is whole In body molecular structure, unit-O-CH₂-CH₂Population mean number) be no more than 100, preferably more than 50.In consideration of it, in formula (I) compound represented or by formulaIn the overall molecule structure of the group of representative, appoint Choosing contains (a certain number of) unit-O-CH₂-CH₂-.At this point, in formula (I) compound represented or by formulaIn the overall molecule structure of the group of representative, as the unit-O-CH₂-CH₂ Population mean number, for example, can be 0,0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0, 30.2,35.0,40.0,45.5 or 49.5 etc..

Embodiment according to the present invention, it is preferred that in formula (I) or by formulaGeneration In the group of table, when x group Poly is each independently selected from (two blocks) ether segment of formula (I-A) representative, x numerical value The sum of n is (i.e. in formula (I) compound represented or by formulaThe entirety of the group of representative point In minor structure, unit-O-CH₂-CH₂Population mean number) be more than 0.In consideration of it, in formula (I) compound represented or by formulaIn the overall molecule structure of the group of representative, preferably comprise (a certain number of) single Member-O-CH₂-CH₂-.At this point, in formula (I) compound represented or by formulaThe base of representative In the overall molecule structure of group, as the unit-O-CH₂-CH₂Population mean number, such as can be 0.1,0.5, 1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

Embodiment according to the present invention, it is preferred that in formula (I) or by formula In the group of representative, when x group Poly is each independently selected from (two blocks) ether segment of formula (I-A) representative, x number The sum of value n is (i.e. in formula (I) compound represented or by formulaThe overall molecule of the group of representative In structure, unit-O-CH₂-CH₂Population mean number) with the sum of x numerical value m (i.e. formula (I) compound represented or by FormulaIn the overall molecule structure of the group of representative, unit Population mean number) summation be more than 0, but be usually no more than 200, preferably more than 100.In consideration of it, shown in formula (I) Compound or by formulaIn the overall molecule structure of the group of representative, (one is preferably comprised Fixed number amount) unit-O-CH₂-CH₂And/orAt this point, in formula (I) compound represented or By formulaIn the overall molecule structure of the group of representative, the totality as these units is flat Equal number, for example, can be 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0, 45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc..

According to the present invention, in formula (I), by formulaIn the group of representative, each base Group L is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10 Linear chain or branched chain alkenylene is preferably each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene.

According to the present invention, in formula (I), by formulaIn the group of representative, each base Group Salt is same or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄)；When group M is alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5.

According to embodiment of the present invention, in formula (I), by formulaGeneration In the group of table, the number of group Salt, group A are depended on^-It can be one, can also be x, it is at least one preferably wherein Group A^-It is carboxylate radical (COO^-).In consideration of it, in the overall molecule structure of formula (I) compound represented, preferably there is at least one A carboxylate radical (COO^-)。

According to the present invention, in formula (I), by formulaIn the group of representative, x+1 Represent the valence state value of group Link.At this point, x is the arbitrary integer between 1 to 10, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (I), it is desirable that the group R₁, the group R₂, the group R₃With the group Rh At least one of must include (one or more) C in its structure₈Straight-chain part so that the present invention it is cloudy from Son-cation-nonionic surface active agent shows expected surface-active property.

According to the present invention, in formula (I), in the case where no other explicitly define, so-called optional substitution refers to appointing Choosing is selected from oxo (i.e. by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1)), hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl takes Generation.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear chain or branched chain Alkyl either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle is more Ring naphthenic base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.Make For the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic Or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I), when there are oxos as substituent group, preferably at least there are one oxo substituents Positioned at the carbon atom with N atoms (if any, such as the linear chain or branched chain miscellaneous alkyl N atoms that may include) Direct Bonding On, so that the carbon atom is rendered as carbonyl (i.e.) form, thus in the molecule knot of formula (I) compound represented The structure (such as acylimino) of carbonyl and N atom Direct Bondings is introduced in structure.In addition, stablizing to obtain better hydrolysis Property or chemical stability, it is preferred that at least part (preferably all) and O or S atom (if any) Direct Bonding Carbon atom on the oxo substituent is not present, and/or, at least part (preferably all) (refers to strand in the end of the chain Free end and/or wait for end with other atomistic bindings) oxo substituent is not present on the carbon atom of position, and/or, two Replaced by oxo when the carbon atom difference of a Direct Bonding.By in this way, can be to avoid in the molecule of formula (I) compound represented The chemical activities such as ester group or aldehyde radical or unstable group are introduced in structure.For concrete example, group Link is by 1 oxygen For the divalent straight chained alkyl of substituent group substitution(it includes two carbon atoms for being in chain end position, As shown in arrow in formula) when, then according to aforementioned principle, group Link is such as preferablyOr PersonDeng.Alternatively, group Link is the divalent branch replaced by 1 oxo substituent Chain miscellaneous alkyl(it includes three carbon atoms for being in chain end position, such as Further include the carbon atom of three and N atom Direct Bondings in formula shown in arrow) when, then according to aforementioned principle, group Link ratios As preferablyOrDeng.

According to the present invention, shown in the anionic-cationic-nonionic surface active agent or the formula (I) Compound, for example can specifically enumerate substantially such as following formula (I-1) compound represented, substantially as shown in following formula (I-2) Compound, substantially such as following formula (I-3) compound represented or substantially such as following formula (I-4) compound represented.These One kind can be used only in compound, can also combination of two or more use.

The embodiment according to the present invention, it is desirable that at least one contained in these molecular structure of compounds (such as 1 A, 2,3 or 4 etc.) (these groups are in formula below (I-1), formula (I- with other group Rh and group X for N atoms 2), it is not shown in formula (I-3) or formula (I-4)) it is bonded and is rendered as formulaShown in quaternary ammonium salt (alkali) form. In formulaIn, group N⁺It is the quaternary nitrogen cationic form of at least one N atoms, group Rh is selected from optionally substitution C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkene Base and the C optionally replaced_6-50Aryl.In the definition of group Rh, as the C_1-50Linear or branched alkyl group, for example can lift Go out C_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, hexadecane Base, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle is polycyclic Naphthenic base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, it is specific to compare Such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or allyl Base etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene.Base Group X^-Selected from halide ion (including fluorine ion, chlorion, bromide ion and iodide ion) and hydroxide ion (OH^-), wherein it is preferred that halogen Plain ion, more preferable chlorion.Here, so-called " optionally substitution ", refer to optionally by it is one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight chain or Branched-chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Straight chain Or branched alkyl or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene Base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocycle cycloalkanes Base, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Straight chain or branch Alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Virtue Base, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-1), each group Ra is same or different to each other, and is each independently selected from hydrogen, optionally takes The C in generation_1-20Linear or branched alkyl group, the C optionally replaced_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-10Aryl, preferably Hydrogen, the C optionally replaced_8-20Linear or branched alkyl group and the C optionally replaced_6-10Aryl.

According to the present invention, in formula (I-1), each group Ra ' is same or different to each other, and is each independently selected from singly-bound, appoints Choose the C in generation_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, optionally replaces carbonyl C_1-10Linear chain or branched chain alkylenecarbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, is preferably selected each independently The C from singly-bound and optionally replaced_1-6Linear chain or branched chain alkylidene.

According to the present invention, in formula (I-1), b is the arbitrary integer between 1 to 3, preferably 1.

According to the present invention, in formula (I-1), x ' represents groupNumber, be 1 to 5 it Between arbitrary integer, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.It is apparent that b+x '≤6.

According to the present invention, in formula (I-1), each group Y is same or different to each other, and is each independently selected from N and O, premise It is the a=1 when group Y is N, when group Y is O, a=0.Also, at least one group Y is N.

According to the present invention, in formula (I-1), each (i.e. x ' is a) group Rp₁It is same or different to each other, is each independently selected from FormulaThe group of representative, optionally takes hydrogen The C in generation_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain Alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one (such as one or two) group Rp₁It is formulaThe group of representative.Here, as institute State C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle is polycyclic Naphthenic base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle is polycyclic Naphthenic base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, For example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, 12 carbon Alkenyl, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or Person C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refers to optionally by one or more (ratios Such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene Base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, such as can To enumerate C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10 Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially It is C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example can lift Go out C_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, such as can To enumerate C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-1), each (i.e. x ' × a) group Rp₂It is same or different to each other, each independently Selected from formulaThe group of representative, is appointed at hydrogen Choose the C in generation_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Straight chain or Branched-chain alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20 Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, cetyl, oneself Base, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene Base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as ring Amyl or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20 Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or allyl Deng.As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene. This, it is so-called " optionally substitution ", it refers to optionally being selected from by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) Hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Aryl takes Replace for base.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Straight chain Or branched alkyl either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8It is single Ring or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or ring Hexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, Acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-1), each numerical value m ' is same or different to each other, and is each independently selected between 0 to 100 Any number, any number between preferably 0 to 50.At this point, the numerical value m ' represents unitBe averaged Number, therefore can be non-integer.As the numerical value m ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4, 7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-1), each numerical value n ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n ' represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-1), each numerical value m " is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m " represents unit Average number, therefore can be non-integer.As the numerical value m ", for example, can be 0,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-1), each numerical value n " is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n " represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ", for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-1), it is preferred that all (i.e. x ' is a) numerical value m ' and all (i.e. x ' × a) numbers The sum of value m " (i.e. in the overall molecule structure of formula (I-1) compound represented, unit's Population mean number) it is more than 0, but 100 are usually no more than, preferably more than 50.In consideration of it, in formula (I-1) compound represented Overall molecule structure in, preferably comprise (a certain number of) unitAt this point, in formula (I- 1) in the overall molecule structure of compound represented, as the unitPopulation average Mesh, for example, can be 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0, 40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-1), it is preferred that all (i.e. x ' is a) numerical value n ' and all (i.e. x ' × a) numbers The sum of value n " (i.e. in the overall molecule structure of formula (I-1) compound represented, unit-CH₂-CH₂The population average of-O- Mesh) it is no more than 100, preferably more than 50.As the unit-CH₂-CH₂The population mean number of-O-, for example can be 0, 0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to embodiment of the present invention, it is preferred that in formula (I-1), all (i.e. x ' is a) numerical value n ' with entirely The sum of portion (i.e. x ' × a) numerical value n " (i.e. in the overall molecule structure of formula (I-1) compound represented, unit-CH₂-CH₂- The population mean number of O-) it is more than 0.In consideration of it, in the overall molecule structure of formula (I-1) compound represented, preferably comprise (a certain number of) unit-CH₂-CH₂-O-.At this point, in the overall molecule structure of formula (I-1) compound represented, as institute State unit-CH₂-CH₂The population mean number of-O-, for example, can be 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5, 10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-1), all (i.e. x ' is a) numerical value n ' and all (i.e. x ' × a) numerical value n the sum of " (i.e. in the overall molecule structure of formula (I-1) compound represented, unit-CH₂-CH₂The population mean number of-O-) and all (i.e. x ' is a) numerical value m ' and all the sum of (i.e. x ' × a) numerical value m " are (i.e. in the overall molecule knot of formula (I-1) compound represented In structure, unitPopulation mean number) summation be more than 0, but be usually no more than 200, it is excellent Choosing is no more than 100.In consideration of it, in the overall molecule structure of formula (I-1) compound represented, it is necessary to contain (a certain number of) Unit-O-CH₂-CH₂And/orAt this point, in the entirety point of formula (I-1) compound represented In minor structure, as the population mean number of these units, such as can be 0.1,0.5,1.5,2.0,3.0,3.5,7.5, 10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 Deng.

According to the present invention, in formula (I-1), each group L is same or different to each other, and is each independently selected from and optionally replaces C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene is preferably each independently selected from and optionally takes The C in generation_1-5Linear chain or branched chain alkylidene.

According to the present invention, in formula (I-1), each group Salt is same or different to each other, and is each independently selected from by-A^- (M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄).When group M is alkali metal or ammonium root, r=1；Work as group When M is alkaline-earth metal, r=0.5.

According to the present invention, in formula (I-1), group Ra and group Rh (cover the formula (I-1) compound represented to be wrapped At least one of the whole group Ra and group Rh contained, it is clear that further include the group Rh that quaternary ammonium salt above-mentioned (alkali) is included) (such as 1,2 or 3 etc.) must include (one or more) C in its structure₈Straight-chain part, so that the formula (I-1) compound represented shows expected some surface active property.

According to embodiment of the present invention, in formula (I-1), the number of group Salt, group A are depended on^-It can be with It is one, can also be multiple, wherein at least one group A^-It is carboxylate radical (COO^-).In consideration of it, changing shown in formula (I-1) In the overall molecule structure for closing object, preferably there is at least one carboxylate radical (COO^-)。

According to the present invention, in formula (I-2), group Rb is selected from the C optionally replaced_1-49Linear or branched alkyl group optionally takes The C in generation_5-49Monocycle or polycyclic naphthene base and the C optionally replaced_2-49Linear chain or branched chain alkenyl is preferably selected from the C optionally replaced_1-29 Linear or branched alkyl group, the C optionally replaced_5-10Monocycle or polycyclic naphthene base and the C optionally replaced_2-29Linear chain or branched chain alkenyl, or Person is selected from the C optionally replaced_8-29Linear or branched alkyl group, the C optionally replaced_5-8Monocycle or polycyclic naphthene base and optionally replace C_8-29Linear chain or branched chain alkenyl is preferably selected from the C optionally replaced_8-19Linear or branched alkyl group, the C optionally replaced_5-7Monocycle cycloalkanes C base (such as cyclohexyl) and optionally replaced_8-19Linear chain or branched chain alkenyl.

According to the present invention, in formula (I-2), each group Rb ' is same or different to each other, and is each independently selected from singly-bound and carbonyl Base.

According to the present invention, in formula (I-2), each group Y is same or different to each other, and is each independently selected from N and O, premise It is the a=1 when group Y is N, when group Y is O, a=0.Also, at least one group Y is N.

According to the present invention, in formula (I-2), x " represents groupNumber, be 1 to 10 it Between arbitrary integer, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (I-2), each (i.e. x " is a) group Rp₁It is same or different to each other, is each independently selected from FormulaThe group of representative, hydrogen, optionally substitution C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkene Base and the C optionally replaced_6-50Aryl, on condition that at least one (such as one or two) group Rp₁It is formulaThe group of representative.Here, as described C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group is specific to compare Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl.As the C_5-50Monocycle or polycyclic ring Alkyl, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic ring Alkyl, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, than C can such as be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecylene Base, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refer to optionally by it is one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example can lift Go out C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle Or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7 Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10 Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example can lift Go out C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-2), each (i.e. x " × a) group Rp₂It is same or different to each other, each independently Selected from formulaThe group of representative, is appointed at hydrogen Choose the C in generation_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Straight chain or Branched-chain alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20 Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, cetyl, oneself Base, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene Base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as ring Amyl or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20 Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or allyl Deng.As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene. This, it is so-called " optionally substitution ", it refers to optionally being selected from by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) Hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Aryl takes Replace for base.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Straight chain Or branched alkyl either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8It is single Ring or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or ring Hexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, Acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-2), each numerical value m ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m ' represents unit Average number, therefore can be non-integer.As the numerical value m ', for example, can be 0,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-2), each numerical value n ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n ' represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-2), each numerical value m " is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m " represents unit Average number, therefore can be non-integer.As the numerical value m ", for example, can be 0,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-2), each numerical value n " is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n " represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ", for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-2), it is preferred that all (i.e. x " a) numerical value m ' is counted with all (i.e. x " × a a) The sum of value m " (i.e. in the overall molecule structure of formula (I-2) compound represented, unit's Population mean number) it is more than 0, but 100 are usually no more than, preferably more than 50.In consideration of it, in formula (I-2) compound represented Overall molecule structure in, preferably comprise (a certain number of) unitAt this point, in formula (I- 2) in the overall molecule structure of compound represented, as the unitPopulation average Mesh, for example, can be 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0, 40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-2), it is preferred that all (i.e. x " a) numerical value n ' is counted with all (i.e. x " × a a) The sum of value n " (i.e. in the overall molecule structure of formula (I-2) compound represented, unit-CH₂-CH₂The population average of-O- Mesh) it is no more than 100, preferably more than 50.As the unit-CH₂-CH₂The population mean number of-O-, for example can be 0, 0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to embodiment of the present invention, it is preferred that in formula (I-2), all (i.e. x " is a) numerical value n ' with entirely The sum of portion (i.e. x " × a) numerical value n " (i.e. in the overall molecule structure of formula (I-2) compound represented, unit-CH₂-CH₂- The population mean number of O-) it is more than 0.In consideration of it, in the overall molecule structure of formula (I-2) compound represented, preferably comprise (a certain number of) unit-CH₂-CH₂-O-.At this point, in the overall molecule structure of formula (I-2) compound represented, as institute State unit-CH₂-CH₂The population mean number of-O-, for example, can be 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5, 10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-2), all (i.e. x " a) numerical value n ' and all (i.e. x " × a) numerical value n the sum of " (i.e. in the overall molecule structure of formula (I-2) compound represented, unit-CH₂-CH₂The population mean number of-O-) and all (i.e. x " a) numerical value m ' and all the sum of (i.e. x " × a a) numerical value m " are (i.e. in the overall molecule knot of formula (I-2) compound represented In structure, unitPopulation mean number) summation be more than 0, but be usually no more than 200, it is excellent Choosing is no more than 100.In consideration of it, in the overall molecule structure of formula (I-2) compound represented, it is necessary to contain (a certain number of) Unit-O-CH₂-CH₂And/orAt this point, in the entirety point of formula (I-2) compound represented In minor structure, as the population mean number of these units, such as can be 0.1,0.5,1.5,2.0,3.0,3.5,7.5, 10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 Deng.

According to the present invention, in formula (I-2), each group L is same or different to each other, and is each independently selected from and optionally replaces C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene is preferably each independently selected from and optionally takes The C in generation_1-5Linear chain or branched chain alkylidene.

According to the present invention, in formula (I-2), each group Salt is same or different to each other, and is each independently selected from by-A^- (M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH4).When group M is alkali metal or ammonium root, r=1；Work as group When M is alkaline-earth metal, r=0.5.

According to embodiment of the present invention, in formula (I-2), the number of group Salt, group A are depended on^-It can be with It is one, can also be multiple, wherein at least one group A^-It is carboxylate radical (COO^-).In consideration of it, changing shown in formula (I-2) In the overall molecule structure for closing object, preferably there is at least one carboxylate radical (COO^-)。

According to the present invention, in formula (I-2), group Rb and group Rh (cover the formula (I-2) compound represented to be wrapped At least one of the whole group Rb and group Rh contained, it is clear that further include the group Rh that quaternary ammonium salt above-mentioned (alkali) is included) (such as 1,2 or 3 etc.) must include (one or more) C in its structure₈Straight-chain part, so that the formula (I-2) compound represented shows expected some surface active property.

According to the present invention, in formula (I-3), each group Rc is same or different to each other, and is each independently selected from optional substitution C_1-20Linear or branched alkyl group, the C optionally replaced_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group Carbonyl and the C optionally replaced_2-20Linear chain or branched chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_1-10Straight chain or Branched alkyl, the C optionally replaced_2-10Linear chain or branched chain alkenyl, the C optionally replaced_1-10It linear or branched alkyl group carbonyl and optionally takes The C in generation_2-10Linear chain or branched chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, optionally Substituted C_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Straight chain Or branched-chain alkenyl carbonyl.

According to the present invention, in formula (I-3), each group Rd is same or different to each other, and is each independently selected from optional substitution C_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain Alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylene Base carbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl is preferably each independently selected from and optionally replaces C_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl.

According to the present invention, in formula (I-3), x " ' representative unitsNumber, be arbitrary whole between 1 to 10 It counts, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (I-3), each (i.e. x " ' is a) group Rp is same or different to each other, is each independently selected from FormulaThe group of representative, hydrogen, optionally substitution C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkene Base and the C optionally replaced_6-50Aryl, on condition that at least one (such as one or two) group Rp is formulaThe group of representative.Here, as described C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group is specific to compare Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl.As the C_5-50Monocycle or polycyclic ring Alkyl, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic ring Alkyl, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, than C can such as be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecylene Base, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refer to optionally by it is one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example can lift Go out C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle Or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7 Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10 Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example can lift Go out C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-3), each numerical value m ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m ' represents unit Average number, therefore can be non-integer.As the numerical value m ', for example, can be 0,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-3), each numerical value n ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n ' represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-3), it is preferred that all the sum of (i.e. x " ' is a) numerical value m ' is (i.e. in formula (I-3) institute In the overall molecule structure for the compound shown, unitPopulation mean number) be more than 0, but It is usually no more than 100, preferably more than 50.In consideration of it, in the overall molecule structure of formula (I-3) compound represented, preferably Contain (a certain number of) unitAt this point, in the entirety point of formula (I-3) compound represented In minor structure, as the unitPopulation mean number, such as can be 0.1,0.5, 1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-3), it is preferred that all the sum of (i.e. x " ' is a) numerical value n ' is (i.e. in formula (I-3) institute In the overall molecule structure for the compound shown, unit-CH₂-CH₂The population mean number of-O-) it is no more than 100, preferably more than 50.As the unit-CH₂-CH₂The population mean number of-O-, for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to embodiment of the present invention, it is preferred that in formula (I-3), the sum of whole (i.e. x " ' is a) numerical value n ' (i.e. in the overall molecule structure of formula (I-3) compound represented, unit-CH₂-CH₂The population mean number of-O-) it is more than 0. In consideration of it, in the overall molecule structure of formula (I-3) compound represented, (a certain number of) unit-CH is preferably comprised₂-CH₂- O-.At this point, in the overall molecule structure of formula (I-3) compound represented, as the unit-CH₂-CH₂The totality of-O- is flat Equal number, for example, can be 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2, 35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-3), the sum of whole (i.e. x " ' is a) numerical value n ' (i.e. chemical combination shown in formula (I-3) In the overall molecule structure of object, unit-CH₂-CH₂The population mean number of-O-) with all the sum of (i.e. x " ' is a) numerical value m ' (i.e. In the overall molecule structure of formula (I-3) compound represented, unitPopulation average Mesh) summation be more than 0, but be usually no more than 200, preferably more than 100.In consideration of it, in the whole of formula (I-3) compound represented In body molecular structure, it is necessary to contain (a certain number of) unit-O-CH₂-CH₂And/orThis When, in the overall molecule structure of formula (I-3) compound represented, as the population mean number of these units, such as can be with 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2, 60.0,75.5,80.5,85.0,90.5 or 95.7 etc..

According to the present invention, in formula (I-3), each group L is same or different to each other, and is each independently selected from and optionally replaces C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene is preferably each independently selected from and optionally takes The C in generation_1-5Linear chain or branched chain alkylidene.

According to the present invention, in formula (I-3), each group Salt is same or different to each other, and is each independently selected from by-A^- (M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH₄).When group M is alkali metal or ammonium root, r=1；Work as group When M is alkaline-earth metal, r=0.5.

According to embodiment of the present invention, in formula (I-3), the number of group Salt, group A are depended on^-It can be with It is one, can also be multiple, wherein at least one group A^-It is carboxylate radical (COO^-).In consideration of it, changing shown in formula (I-3) In the overall molecule structure for closing object, preferably there is at least one carboxylate radical (COO^-)。

According to the present invention, in formula (I-3), group Rc and group Rh (cover the formula (I-3) compound represented to be wrapped At least one of the whole group Rc and group Rh contained, it is clear that further include the group Rh that quaternary ammonium salt above-mentioned (alkali) is included) (such as 1,2 or 3 etc.) must include (one or more) C in its structure₈Straight-chain part, so that the formula (I-3) compound represented shows expected some surface active property.

According to the present invention, in formula (I-4), group Rc is selected from the C optionally replaced_1-20Linear or branched alkyl group optionally takes The C in generation_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and the C optionally replaced_2-20Straight chain or Branched-chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_1-10Linear or branched alkyl group, the C optionally replaced_2-10Straight chain Or branched-chain alkenyl, the C that optionally replaces_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenyl carbonyl, Or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkenyl is appointed Choose the C in generation_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Linear chain or branched chain alkenyl carbonyl.

According to the present invention, in formula (I-4), each group Rd is same or different to each other, and is each independently selected from optional substitution C_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain Alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylene Base carbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl is preferably each independently selected from and optionally replaces C_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl.

According to the present invention, in formula (I-4), group Y is N or O, on condition that when group Y is N, a=1, when group Y is O When, a=0.

According to the present invention, in formula (I-4), x " " representative unitNumber, be arbitrary whole between 1 to 9 It counts, the arbitrary integer between preferably 1 to 3, more preferable 1 or 2.

According to the present invention, in formula (I-4), each (i.e. x " " is a) group Rp₁It is same or different to each other, selects each independently From formulaThe group of representative, optionally takes hydrogen The C in generation_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain Alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one (such as one or two) group Rp₁It is formulaThe group of representative.Here, as described C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group is specific to compare Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl.As the C_5-50Monocycle or polycyclic ring Alkyl, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic ring Alkyl, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, than C can such as be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecylene Base, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refer to optionally by it is one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example can lift Go out C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle Or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7 Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10 Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example can lift Go out C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-4), group Rp2 is selected from formula The group of representative, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally Substituted C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, For example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, Octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocycle Naphthenic base, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Straight chain Or branched-chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, Acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as Phenyl or naphthalene.Here, so-called " optionally substitution ", refer to optionally by it is one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl And C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear chain or branched chain alkane Base or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, such as C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, it is specific to compare Such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, tool Body such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as Phenyl or naphthalene.

According to the present invention, in formula (I-4), each (i.e. a) group Rp₃It is same or different to each other, is each independently selected from FormulaThe group of representative, optionally takes hydrogen The C in generation_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain Alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Straight chain Or branched alkyl or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, cetyl, hexyl, Methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta Or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Straight chain Or branched-chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or allyl etc..Make For the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) be selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl takes Generation.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear chain or branched chain Alkyl either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle is more Ring naphthenic base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.Make For the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic Or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (I-4), each numerical value m ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m ' represents unit's Average number, therefore can be non-integer.As the numerical value m ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), each numerical value n ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n ' represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), each numerical value m " is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m " represents unit Average number, therefore can be non-integer.As the numerical value m ", for example, can be 0,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), each numerical value n " is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n " represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n ", for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), each numerical value m " ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value m " ' represents unit Average number, therefore can be non-integer.As the numerical value m " ', for example, can be 0,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), each numerical value n " ' is same or different to each other, be each independently selected from 0 to 100 it Between any number, any number between preferably 0 to 50.At this point, the numerical value n " ' represents unit-CH₂-CH₂- O-'s is flat Equal number, therefore can be non-integer.As the numerical value n " ', for example, can be 0,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), it is preferred that all (x " " is a) numerical value m ', all (1) numerical value m " with it is complete The sum of portion (a) numerical value m " ' (i.e. in the overall molecule structure of formula (I-4) compound represented, unitPopulation mean number) be more than 0, but be usually no more than 100, preferably more than 50.In view of This preferably comprises (a certain number of) unit in the overall molecule structure of formula (I-4) compound representedAt this point, in the overall molecule structure of formula (I-4) compound represented, as the list MemberPopulation mean number, such as can be 0.1,0.5,1.2,2.0,2.5,3.0,3.5, 5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), it is preferred that all (x " " is a) numerical value n ', all (1) numerical value n " with it is complete The sum of portion (a) numerical value n " ' (i.e. in the overall molecule structure of formula (I-4) compound represented, unit-CH₂-CH₂- O-'s is total Body average number) it is no more than 100, preferably more than 50.As the unit-CH₂-CH₂The population mean number of-O-, such as can Be 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

Numerical value n ', whole according to embodiment of the present invention, it is preferred that in formula (I-4), whole (x " " is a) The sum of (1) numerical value n " with all (a) numerical value n " ' is (single i.e. in the overall molecule structure of formula (I-4) compound represented Member-CH₂-CH₂The population mean number of-O-) it is more than 0.In consideration of it, in the overall molecule structure of formula (I-4) compound represented In, preferably comprise (a certain number of) unit-CH₂-CH₂-O-.At this point, in the overall molecule knot of formula (I-4) compound represented In structure, as the unit-CH₂-CH₂The population mean number of-O-, for example, can be 0.1,0.5,1.2,2.0,2.5,3.0, 3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc..

According to the present invention, in formula (I-4), all (x " " is a) numerical value n ', all (1) numerical value n " and all (a) numbers The sum of value n " ' (i.e. in the overall molecule structure of formula (I-4) compound represented, unit-CH₂-CH₂The population average of-O- Mesh) a with all (x " ") numerical value m ', all the sum of (1) numerical value m " with all (a) numerical value m " ' is (i.e. shown in formula (I-4) Compound overall molecule structure in, unitPopulation mean number) summation be more than 0, but 200 are usually no more than, preferably more than 100.In consideration of it, in the overall molecule structure of formula (I-4) compound represented, Preferably comprise (a certain number of) unit-O-CH₂-CH₂And/orAt this point, at formula (I-4) In the overall molecule structure of compound represented, as the population mean number of these units, such as can be 0.1,0.5, 1.5、2.0、3.0、3.5、7.5、10.0、15.0、25.0、30.2、35.0、40.0、45.5、50.5、55.2、60.0、75.5、 80.5,85.0,90.5 or 95.7 etc..

According to the present invention, in formula (I-4), each group L is same or different to each other, and is each independently selected from and optionally replaces C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene is preferably each independently selected from and optionally takes The C in generation_1-5Linear chain or branched chain alkylidene.

According to the present invention, in formula (I-4), each group Salt is same or different to each other, and is each independently selected from by-A^- (M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and Ca) and ammonium root (NH4).When group M is alkali metal or ammonium root, r=1；Work as group When M is alkaline-earth metal, r=0.5.

According to embodiment of the present invention, in formula (I-4), the number of group Salt, group A are depended on^-It can be with It is one, can also be multiple, wherein at least one group A^-It is carboxylate radical (COO^-).In consideration of it, changing shown in formula (I-4) In the overall molecule structure for closing object, preferably there is at least one carboxylate radical (COO^-)。

According to the present invention, in formula (I-4), group Rc and group Rh (cover the formula (I-4) compound represented to be wrapped At least one of the whole group Rc and group Rh contained, it is clear that further include the group Rh that quaternary ammonium salt above-mentioned (alkali) is included) (such as 1,2 or 3 etc.) must include (one or more) C in its structure₈Straight-chain part, so that the formula (I-4) compound represented shows expected some surface active property.

According to the present invention, in formula above-mentioned (I-1), formula (I-2), formula (I-3) and formula (I-4), defined in no other In the case of definition, so-called optional substitution, refer to optionally by it is one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl And C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear chain or branched chain alkane Base or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, such as C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, it is specific to compare Such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, tool Body such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as Phenyl or naphthalene.

According to the present invention, it is aforementioned it is various shown in anionic-cationic-nonionic surface active agent of the invention such as its Shown in respective structural formula, ionic group (M) must be contained simultaneously by specifying in its respective molecular structure_r ⁺With group X^- It (may also write respectively sometimes (M)_rAnd X).However, it is known that both ionic groups to showing higher reaction each other Activity, therefore the two is if coexisting in the same system, for example coexist in the same molecular structure, it will tend to It reacts with each other and production (M)_r ⁺X^-It (may also write sometimes (M)_rX inorganic compound shown in).The inorganic compound Sometimes (or even being such as precipitated or formed independent object phase) is non-independently of the anionic-cationic-of the present invention in a free form Ionic surfactant and exist, so as to cause these group (i.e. groups (M)_r ⁺With group X^-) at least part (have When be all) anionic-cationic-non-ionic surface of the invention can not be become as defining these structural formulas The component part of the molecular structure of activating agent.In this case, anionic-cationic of the invention-non-ionic surface is lived Property agent is substantially (for example to lose whole group (M)_r ⁺Or group X^-) or at least partly (for example to lose a part of group (M)_r ⁺Or group X^-) betaine form exist.At this point, the molecule knot of the anionic-cationic-nonionic surface active agent Group A contained in structure^-With group N⁺As mutual new counter ion counterionsl gegenions.In consideration of it, the anionic-cationic-in the present invention is non- In the entire molecular structure of ionic surfactant, if the group X^-Total number be e1, the group N⁺Total number be E2, the group A^-Total number be e3, the group (M)_r ⁺Total number be e4, as e2=e3,0≤e1≤e2,0≤e4 ≤e3.Alternatively, as e2 ＞ e3,0 ＜ e1≤e2,0≤e4≤e3.Alternatively, as e2 ＜ e3,0≤e1≤e2,0 ＜ e4≤e3. On condition that e1+e3=e2+e4.Or, it is preferred that e2=e3, e1=0, e4=0.Therefore, the inorganic chemical is depended on The generation degree of object, especially anionic-cationic-nonionic surface active agent of the invention is in its entire molecular structure Group (M)_r ⁺With group X^-Number ratio, or whether there are the reaction condition generated conducive to the inorganic compound, this Anionic-cationic-nonionic surface active agent of invention contains the group when sometimes different in its molecular structure (M)_r ⁺With group X^-, do not contain the group (M) simultaneously even sometimes_r ⁺With group X^-.Due to the generation of the inorganic compound Whether either its content number or its existence form be how, to the present invention anionic-cationic-nonionic table The various performances (such as interfacial activity and stability) of face activating agent do not generate substantial effect, therefore the present invention is not intended to be directed to The inorganic compound provides any special regulation.In consideration of it, in the context of the present specification, in order to more precisely describe Or anionic-cationic-nonionic surface active agent of the definition present invention, it has used " substantially as shown in formula ## " or its class Like statement.Here, so-called " substantially as shown in formula ## " (than as the aforementioned substantially as shown in formula (I), substantially such as formula (I- 1) shown in, substantially such as shown in formula (I-2), substantially as shown in formula (I-3) or substantially as shown in formula (I-4)) or its Similar statement, refers to anionic-cationic-nonionic surface active agent of the present invention, both as the formula defines, Contain group (M) simultaneously_r ⁺With group X^-, also as explained before like that, lose at least part (or even whole) group (M)_r ⁺And/or group X^-, or even do not contain (or being not present) group (M)_r ⁺And/or group X^-.For those skilled in the art Speech, what these were represented is the different existence forms of anionic-cationic-nonionic surface active agent of the present invention, all necessarily It is included within the scope of the present invention.

According to the present invention, it is aforementioned it is various shown in anionic-cationic-nonionic surface active agent such as can be according to Following manufacturing method is manufactured, and wherein the manufacturing method such as includes following step (1) to (5).

Step (1)：Make one or more nitrogenous and is selected from-OH ,-NH with one or more₂With the functional group of-NH- Polyfunctional compound reacts with alkylene oxide shown in one or more formulas (Y) in the presence of basic catalyst, obtains etherificate production Object.

According to the present invention, in step (1), as the polyfunctional compound, can use there are one any bands or more A (such as 1 to 10, preferably 1 to 4, such as 2,3 or 4) it is selected from-OH ,-NH₂With the compound of the functional group of-NH-, It is not particularly limited.These functional groups can make the alkylene oxides such as ethylene oxide that open loop occur due to containing active hydrogen (polymerization) is reacted, and (poly-) ether segment is thus introduced in the molecular structure of the polyfunctional compound.These polyfunctional compounds can It, can also combination of two or more use one kind is used only.In addition, these polyfunctional compounds can directly use commercially available production Product can also be manufactured according to any of method.

According to the present invention, in step (1), the polyfunctional compound must nitrogen atom.The nitrogen-atoms may be from Primary amine group, tertiary amine group or the secondary amine group that the polyfunctional compound may be contained.

According to the present invention, in step (1), as the polyfunctional compound, lower formula (X) institute specifically can be such as enumerated The amine compounds shown.One kind can be used only in these compounds, can also combination of two or more use.

According to the present invention, in formula (X), group R '₁To R '₃Be same or different to each other, be each independently selected from hydrogen, optionally Substituted C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Straight chain or branch Alkenyl, the C optionally replaced_6-50Aryl and by formulaThe group of representative.Here, so-called " optionally take In generation ", refers to optionally being selected from oxo (i.e. by one or more (such as 1 to 4,1 to 3,1 to 2 or 1)), hydroxyl Base, by formulaGroup, the C of representative_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example can lift Go out C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle Or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7 Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10 Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example can lift Go out C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (X), it is desirable that group R '₁To R '₃In at least one (such as at most two) be hydrogen or Person is by formulaThe group of representative.

According to the present invention, in formula (X), in group R '₁To R '₃Definition in, as the C_1-50Linear chain or branched chain alkane Base, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, bay Base, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example can lift Go out C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7It is single Ring naphthenic base, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Directly Chain or branched-chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, ethylene Base, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, it is specific to compare Such as phenyl or naphthalene.

According to the present invention, in formula (X), by formulaIn the group of representative, group L_AIt is selected from The x0+1 valences C optionally replaced_1-50Linear or branched alkyl group, the x0+1 valences C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally take The x0+1 valences C in generation_2-50Linear chain or branched chain alkenyl, the x0+1 valences C optionally replaced_6-50Aryl and the x0+1 valences C optionally replaced_3-50Directly Chain or branched heteroalkyl groups.As the x0+1 valences C optionally replaced_1-50Linear or branched alkyl group, the x0+1 preferably optionally replaced Valence C_1-20Linear or branched alkyl group.As the x0+1 valences C optionally replaced_5-50Monocycle or polycyclic naphthene base, for example can enumerate The x0+1 valences C optionally replaced_5-10Monocycle or polycyclic naphthene base, the x0+1 valences C optionally replaced_5-8Monocycle or polycyclic naphthene base or The x0+1 valences C optionally replaced_5-7Monocycle or polycyclic naphthene base, the x0+1 valences C especially optionally replaced_5-7Monocyclic cycloalkyl, such as Cyclohexyl.As the x0+1 valences C optionally replaced_2-50Linear chain or branched chain alkenyl, the x0+1 valences C preferably optionally replaced_2-20Straight chain Or branched-chain alkenyl.As the x0+1 valences C optionally replaced_6-50Aryl, the x0+1 valences C preferably optionally replaced_6-20Aryl, such as Phenyl or naphthalene.As the x0+1 valences C optionally replaced_3-50Linear chain or branched chain miscellaneous alkyl, the x0+1 valences C preferably optionally replaced_3-20 Linear chain or branched chain miscellaneous alkyl.

According to the present invention, in formula (X), each group Func is same or different to each other, and is each independently selected from-OH ,-NH- With-NH₂, preferably it is each independently selected from-OH and-NH₂。

According to the present invention, in formula (X), x0+1 general proxy groups L_AValence state value, wherein x0 is appointing between 1 to 10 It anticipates integer, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.But technical staff is it is understood that work as group Func For-NH- when, group L_AIt is interrupted at arbitrary (acceptable) position by the-NH-.At this point, x0 (or its at least part, this Number depending on-NH-) number that represents the interruption, without necessarily representing group L_AValence state value (its minimum possibility of valence state value It is 1, such as when x0 group Func is-NH-).When there are multiple-NH-, group L_ABy these-NH- it is arbitrary (can be with Receive) it accordingly repeatedly interrupts at position.Here so-called interruption refers to the-NH- to group L_AMolecular structure inside insert Enter, and is not at the end of main chain or any side chain in its molecular structure.Preferably, not Direct Bonding between each-NH-.Tool For example, when group Func is-NH-, x0 is 1 (interruption times 1) to body, and group L_AFor 1 valence (being no longer divalent) C₈Straight chain Alkyl isWhen (position in formula indicated by arrow is the end of main chain in molecular structure), base Group L_AMay beOrDeng.

According to the present invention, in formula (X), in the case where no other explicitly define, so-called optional substitution refers to appointing Choosing is selected from oxo, hydroxyl, C by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1)_1-20Straight chain Or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As The C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group, or Person's methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base Or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As described C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or alkene Propyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to embodiment of the present invention (be known as embodiment A), in formula (X), there are oxos as a certain Group (such as group L_A) substituent group when, preferably at least there are one oxo substituent be located at N atoms (if any, than The N atoms that may include such as linear chain or branched chain miscellaneous alkyl) Direct Bonding carbon atom on, so that the carbon atom is rendered as carbonyl (i.e.) form, structure (such as the imide of carbonyl and N atom Direct Bondings is thus introduced in the group Base).In addition, in order to obtain better stability to hydrolysis resistance or chemical stability, it is preferred that at least part is (preferably complete Portion) with the oxo substituent is not present on the carbon atom of O or S atom (if any) Direct Bonding, and/or, at least one Divide the carbon for (preferably all) (referring to the free end of strand and/or wait for the end with other atomistic bindings) position in the end of the chain Atom is (if group Func is-NH- or-NH₂, the group such as group L_AIn end of the chain carbon with group Func Direct Bondings Except atom, the embodiment B that sees below) on the oxo substituent is not present, and/or, the carbon atom of two Direct Bondings is not Replaced simultaneously by oxo.By in this way, can be to avoid the introducing chemical activities such as ester group or aldehyde radical or shakiness in the group Determine group.For concrete example, group L_AFor the divalent straight chained alkyl replaced by 1 oxo substituent When (it includes two carbon atoms for being in chain end position, as shown in arrow in formula), then according to aforementioned principle, the group is such as excellent Choosing isOrDeng.Alternatively, Group L_AFor the divalent branched heteroalkyl groups replaced by 1 oxo substituent(its The carbon atom for being in chain end position including three further includes three former with the carbon of N atom Direct Bondings as shown in arrow in formula Son) when, then according to aforementioned principle, which is such as preferably OrDeng.

(it is known as embodiment B) according to embodiment of the present invention, when group Func is-NH- or-NH₂When, In formula (X), when there are oxos as substituent group, preferably at least there are one oxo substituents to be located at and group Func direct keys On the carbon atom of conjunction, in other words, at least one of the carbon atom of group Func Direct Bondings there are oxo substituent, Thus in group L_AThe middle structure (such as acylamino-) for introducing carbonyl and N atom Direct Bondings.For concrete example, group L_AFor The divalent straight chained alkyl replaced by 1 oxo substituentAnd group Func is-NH₂When, FormulaThe group of representative is preferred in addition to embodiment A institutes Except, it can also be

According to the present invention, it is desirable in quaternizing agent shown in the polyfunctional compound and formula (A) described below extremely Few one must include (one or more) C in its molecular structure₈Straight-chain part (hereinafter sometimes referred to provides (1)).Mirror In this, according to the regulation (1), it is also desirable to which at least one of amine compounds and the quaternizing agent exist shown in the formula (X) Must include (one or more) C in its molecular structure₈Straight-chain part.Specifically, according to the regulation (1), group R '₁Extremely R′₃(coming from amine compounds shown in the formula (X)) in group Rh (see below, come from the quaternizing agent) extremely Few one (such as 1,2 or 3 etc.) must include (one or more) C in its structure₈Straight-chain part.

According to the present invention, in step (1), as amine compounds shown in the formula (X), more specifically can such as enumerate Following formula (X-1) compound represented, following formula (X-2) compound represented, following formula (X-3) compound represented and following formula (X-4) Compound represented.One kind can be used only in these compounds, can also combination of two or more use.

According to the present invention, in formula (X-1), each group Ra is same or different to each other, and is each independently selected from hydrogen, optionally takes The C in generation_1-20Linear or branched alkyl group, the C optionally replaced_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-20Aryl is preferably appointed Choose the C in generation_8-20Linear or branched alkyl group and the C optionally replaced_6-10Aryl.

According to the present invention, in formula (X-1), each group Ra ' is same or different to each other, and is each independently selected from singly-bound, appoints Choose the C in generation_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, optionally replaces carbonyl C_1-10Linear chain or branched chain alkylenecarbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, is preferably selected each independently The C from singly-bound and optionally replaced_1-6Linear chain or branched chain alkylidene.

According to the present invention, in formula (X-1), b is the arbitrary integer between 1 to 3, preferably 1.

According to the present invention, in formula (X-1), x1 represents groupNumber, be 1 to 5 it Between arbitrary integer, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.It is apparent that b+x1≤6.

According to the present invention, in formula (X-1), each group Y is same or different to each other, and is each independently selected from N and O, premise It is the a1=1 when group Y is N, when group Y is O, a1=0.Also, at least one group Y is N.

According to the present invention, in formula (X-1), each (i.e. x1) group Rp '₁It is same or different to each other, selects each independently The C from hydrogen, optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally replace C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp '₁It is hydrogen.Here, as institute State C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle is polycyclic Naphthenic base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle is polycyclic Naphthenic base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, For example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, 12 carbon Alkenyl, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or Person C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refers to optionally by one or more (ratios Such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene Base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, such as can To enumerate C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10 Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially It is C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example can lift Go out C_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, such as can To enumerate C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (X-1), each (i.e. x1 × a1) group Rp '₂It is same or different to each other, it is respectively independent The C that ground is selected from hydrogen, optionally replaces_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally substitution C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, such as C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, Cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle Or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, Specific such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkene Base or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or Person's allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or Naphthalene.Here, so-called " optionally substitution ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1 It is a) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Virtue The substituent group of base replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example can lift Go out C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as ring penta Base or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as Vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or Person's naphthalene.

According to the present invention, in formula (X-1), according to regulation (1) above-mentioned, it is desirable to which group Ra and group Rh (are covered described Whole group Ra that formula (X-1) compound represented is included are included with quaternizing agent shown in formula (A) described below Whole group Rh) at least one of (such as 1,2 or 3 etc.) in its structure must include (one or more) described in C₈Straight-chain part.

According to the present invention, in formula (X-2), group Rb is selected from the C optionally replaced_1-49Linear or branched alkyl group optionally takes The C in generation_5-49Monocycle or polycyclic naphthene base and the C optionally replaced_2-49Linear chain or branched chain alkenyl is preferably selected from the C optionally replaced_1-29 Linear or branched alkyl group, the C optionally replaced_5-10Monocycle or polycyclic naphthene base and the C optionally replaced_2-29Linear chain or branched chain alkenyl, or Person is selected from the C optionally replaced_8-29Linear or branched alkyl group, the C optionally replaced_5-8Monocycle or polycyclic naphthene base and optionally replace C_8-29Linear chain or branched chain alkenyl, or selected from the C optionally replaced_8-19Linear or branched alkyl group, the C optionally replaced_5-7Monocycle cycloalkanes C base (such as cyclohexyl) and optionally replaced_8-19Linear chain or branched chain alkenyl.

According to the present invention, in formula (X-2), each group Rb ' is same or different to each other, and is each independently selected from singly-bound and carbonyl Base.

According to the present invention, in formula (X-2), each group Y is same or different to each other, and is each independently selected from N and O, premise It is the a2=1 when group Y is N, when group Y is O, a2=0.Also, at least one group Y is N.

According to the present invention, in formula (X-2), x2 represents groupNumber, be between 1 to 10 Arbitrary integer, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (X-2), each (i.e. x2) group Rp '₁It is same or different to each other, selects each independently The C from hydrogen, optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally replace C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp '₁It is hydrogen.Here, as institute State C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle is polycyclic Naphthenic base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle is polycyclic Naphthenic base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, For example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, 12 carbon Alkenyl, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or Person C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refers to optionally by one or more (ratios Such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene Base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, such as can To enumerate C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10 Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially It is C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example can lift Go out C_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, such as can To enumerate C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (X-2), each (i.e. x2 × a2) group Rp '₂It is same or different to each other, it is respectively independent The C that ground is selected from hydrogen, optionally replaces_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally substitution C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, such as C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, Cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle Or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, Specific such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkene Base or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or Person's allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or Naphthalene.Here, so-called " optionally substitution ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1 It is a) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Virtue The substituent group of base replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example can lift Go out C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as ring penta Base or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as Vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or Person's naphthalene.

According to the present invention, in formula (X-2), according to regulation (1) above-mentioned, it is desirable to which group Rb and group Rh (are covered described Whole group Rb that formula (X-2) compound represented is included are included with quaternizing agent shown in formula (A) described below Whole group Rh) at least one of (such as 1,2 or 3 etc.) in its structure must include (one or more) described in C₈Straight-chain part.

According to the present invention, in formula (X-3), each group Rc is same or different to each other, and is each independently selected from optional substitution C_1-20Linear or branched alkyl group, the C optionally replaced_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group Carbonyl and the C optionally replaced_2-20Linear chain or branched chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_1-10Straight chain or Branched alkyl, the C optionally replaced_2-10Linear chain or branched chain alkenyl, the C optionally replaced_1-10It linear or branched alkyl group carbonyl and optionally takes The C in generation_2-10Linear chain or branched chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, optionally Substituted C_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Straight chain Or branched-chain alkenyl carbonyl.

According to the present invention, in formula (X-3), each group Rd is same or different to each other, and is each independently selected from optional substitution C_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain Alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylene Base carbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl is preferably each independently selected from and optionally replaces C_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl.

According to the present invention, in formula (X-3), x3 representative unitsNumber, be arbitrary whole between 1 to 10 It counts, the arbitrary integer between preferably 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (X-3), each (i.e. x3) group Rp ' is same or different to each other, is each independently selected from Hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50 Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp ' is hydrogen.Here, as the C_1-50 Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as ten Eight alkyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, For example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, Especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, such as can To enumerate C_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, Sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10 Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refer to optionally by one or more (such as 1 to 4 It is a, 1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20 Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example can enumerate C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or Polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7It is single Ring naphthenic base, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Directly Chain or branched-chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example can enumerate C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (X-3), according to regulation (1) above-mentioned, it is desirable to which group Rc and group Rh (are covered described Whole group Rc that formula (X-3) compound represented is included are included with quaternizing agent shown in formula (A) described below Whole group Rh) at least one of (such as 1,2 or 3 etc.) in its structure must include (one or more) described in C₈Straight-chain part.

According to the present invention, in formula (X-4), group Rc is selected from the C optionally replaced_1-20Linear or branched alkyl group optionally takes The C in generation_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and the C optionally replaced_2-20Straight chain or Branched-chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_1-10Linear or branched alkyl group, the C optionally replaced_2-10Straight chain Or branched-chain alkenyl, the C that optionally replaces_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenyl carbonyl, Or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkenyl is appointed Choose the C in generation_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Linear chain or branched chain alkenyl carbonyl.

According to the present invention, in formula (X-4), each group Rd is same or different to each other, and is each independently selected from optional substitution C_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain Alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylene Base carbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl is preferably each independently selected from and optionally replaces C_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl.

According to the present invention, in formula (X-4), group Y is N or O, on condition that when group Y is N, a4=1, when group Y is When O, a4=0.

According to the present invention, in formula (X-4), x4 representative unitsNumber, be arbitrary whole between 1 to 9 It counts, the arbitrary integer between preferably 1 to 3, more preferable 1 or 2.

According to the present invention, in formula (X-4), each (i.e. x4) group Rp '₁It is same or different to each other, selects each independently The C from hydrogen, optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally replace C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp '₁It is hydrogen.Here, as institute State C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle is polycyclic Naphthenic base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle is polycyclic Naphthenic base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, For example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, 12 carbon Alkenyl, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or Person C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refers to optionally by one or more (ratios Such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene Base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, such as can To enumerate C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10 Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially It is C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example can lift Go out C_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, such as can To enumerate C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (X-4), group Rp '₂The C selected from hydrogen, optionally replaced_1-50Linear or branched alkyl group is appointed Choose the C in generation_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl. Here, as the C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Straight chain or branch Alkyl group, specifically such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50 Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7 Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Straight chain Or branched-chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as 18 carbon Alkenyl, dodecenyl succinic, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example can lift Go out C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refers to optionally by one A or multiple (such as 1 to 4,1 to 3,1 to 2 or 1) is selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle Or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear chain or branched chain alkane Base, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..Make For the C_5-10Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic ring Alkyl, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, than C can such as be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Virtue Base, for example C can be enumerated_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (X-4), each (i.e. a4) group Rp '₃It is same or different to each other, selects each independently The C from hydrogen, optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally replace C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.Here, as the C_1-50Linear or branched alkyl group, such as can To enumerate C_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically such as octadecyl, lauryl, octyl, ten Six alkyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle or polycyclic naphthene base, for example C can be enumerated_5-10Monocycle or Polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, tool Body such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, for example C can be enumerated_2-20Linear chain or branched chain alkenyl Or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, dodecenyl succinic, sub- oil base, vinyl, acrylic or Allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthalene Base.Here, so-called " optionally substitution ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1 It is a) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Virtue The substituent group of base replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, for example can lift Go out C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as ring penta Base or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, specifically such as Vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as phenyl or Person's naphthalene.

According to the present invention, in formula (X-4), according to regulation (1) above-mentioned, it is desirable to which group Rc and group Rh (are covered described Whole group Rc that formula (X-4) compound represented is included are included with quaternizing agent shown in formula (A) described below Whole group Rh) at least one of (such as 1,2 or 3 etc.) in its structure must include (one or more) described in C₈Straight-chain part.

According to the present invention, in formula (X-1), formula (X-2), formula (X-3) and formula (X-4), there is no other clearly defined In the case of, so-called optional substitution, refer to optionally by it is one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or Person 1) selected from oxo, hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl And C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example C can be enumerated_1-10Linear chain or branched chain alkane Base or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle or polycyclic naphthene base, such as C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, it is specific to compare Such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10Linear chain or branched chain alkenyl, tool Body such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example C can be enumerated_6-10Aryl, specifically such as Phenyl or naphthalene.

According to the present invention, as chemical combination shown in amine compounds, formula (X-1) shown in polyfunctional compound above-mentioned, formula (X) Object, formula (X-2) compound represented, formula (X-3) compound represented and formula (X-4) compound represented etc., can directly use city The product sold can also be manufactured by any method known in the art.For example, as shown in the formula (X-2) Compound (wherein, Y=N, Rb ' be carbonyl, group Rp '₁With group Rp '₂It is hydrogen), i.e.,It can With by making following formula (X-2-1) compound represented with amidating agent (such as diisopropanolamine (DIPA)) in the presence of basic catalyst It reacts and obtains and (be known as amidation step).

In formula, group Rb and numerical value x2 are identical as the definition in formula (X-2), group R_acIt is H or C_1-4Linear chain or branched chain alkane Base.

According to the present invention, which can carry out according to any mode known in the art, but reaction temperature one As be 100-200 DEG C, the reaction time is generally 1-10 hour, reaction pressure can be normal pressure or it is any suitable for the reaction progress Pressure.

According to the present invention, in the amidation step, as the basic catalyst, the prior art can be directly used Conventional use of any basic catalyst, wherein preferred alkali metal hydroxide for this purpose, especially sodium hydroxide or Potassium hydroxide.One kind can be used only in these basic catalysts, can also combination of two or more use.It is urged as the alkalinity The dosage of agent can directly be applicable in the conventional amount used of this field, but generally so that the basic catalyst reaches the formula (X- 2-1) the 0.2-20wt% of compound represented and the amidating agent total weight, preferably 0.5-15wt%.

According to the present invention, in the amidation step, formula (X-2-1) compound represented and the amidating agent Molar ratio be generally 1: 1-15,1: 1-10,1: 1-8,1: 1-5 or 1: 2-4, but is not limited thereto, and can be can By x2 group-COOR_acIt is completely converted into any molar ratio of amide groups.

According to the present invention, after the amidation step, by conventionally known separate mode, (for example vacuum is taken out Inhale) unreacted amidating agent is removed from mixture of reaction products, you can formula (X-2) compound represented is obtained (for example, Y =N, Rb ' are carbonyl, group Rp '₁With group Rp '₂It is hydrogen), without further purifying or detaching.

According to the present invention, in formula (Y), group Ru ' is selected from C_2-6Linear chain or branched chain alkylidene, wherein it is preferred that-CH₂-CH₂- And/or-CH₂-CH(CH₃)-, more preferably-CH₂-CH₂With-CH₂-CH(CH₃)-combination.

According to the present invention, in step (1), as alkylene oxide shown in the formula (Y), for example epoxy second can be enumerated Alkane, propylene oxide, epoxy butane, oxepane etc..One kind can be used only in these alkylene oxides, can also combination of two or more Use, for example, ethylene oxide and propylene oxide combination.

According to the present invention, using alkylene oxide shown in one or more formulas (Y), at least one alkylene oxide is ring preferably wherein Ethylene Oxide.The propylene oxide can be combined with the alkylene oxide (especially ethylene oxide) shown in other formulas (Y) as needed to be made With.When being applied in combination, the molar ratio of the alkylene oxide (especially ethylene oxide) shown in propylene oxide and other formulas (Y) is such as Can be 1: 0.1-10, but it is not limited to this.

According to the present invention, in step (1), as the basic catalyst, prior art mesh thus can be directly used And conventional use of any basic catalyst, wherein preferred alkali metal hydroxide, especially potassium hydroxide.These alkalinity are urged One kind can be used only in agent, can also combination of two or more use.

According to the present invention, in step (1), as the dosage of the basic catalyst, it can directly be applicable in this field Conventional amount used, but generally so that polyfunctional compound's (such as amine compounds shown in formula (X)) and the basic catalyst Molar ratio reach 1: 1-10, preferably reach 1: 1-5.

According to the present invention, in step (1), polyfunctional compound's (such as amine compounds shown in formula (X)) and institute The molar ratio for stating alkylene oxide is generally 1: 0-200, preferably 1: 0-100, but does not include 0, more preferable 1: 0.1-50.

According to the present invention, in step (1), reaction temperature is generally room temperature to 300 DEG C, preferably 100-200 DEG C, when reaction Between generally 1-20 hour, preferably 1-10 hour, and reaction pressure can be the pressure of any suitable reaction progress, than as usual Pressure.

A preferred embodiment according to the present invention, in step (1), as alkylene oxide shown in the formula (Y), such as When fruit two or more (preferably wherein include at least propylene oxide) is applied in combination, make the polyfunctional compound (such as formula (X) institute The amine compounds shown) first reacted with (at least part measure or whole amount) propylene oxide, then (preferably with the epoxy The reaction of propane is at least partly or after being fully completed) it is reacted again with other alkylene oxides (such as ethylene oxide).

According to the present invention, after step (1) terminates, the mixture of reaction products obtained can be produced directly as etherificate Object carries out subsequent step (2), without passing through any isolated or purified, or only need to isolate (for example pass through water Wash) basic catalyst.

Step (2)：The etherification product is set to be reacted with quaternizing agent shown in following formula (A), thus to obtain the sun Ion-nonionic surfactant.

Rh-X′ (A)

According to the present invention, in formula (A), group Rh is selected from the C optionally replaced_1-50Linear or branched alkyl group, optionally substitution C_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl.As institute State C_1-50Linear or branched alkyl group, for example C can be enumerated_1-20Linear or branched alkyl group or C_8-20Linear or branched alkyl group, specifically Such as octadecyl, lauryl, octyl, cetyl, hexyl, methyl or ethyl etc..As the C_5-50Monocycle is polycyclic Naphthenic base, for example C can be enumerated_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle is polycyclic Naphthenic base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-50Linear chain or branched chain alkenyl, For example C can be enumerated_2-20Linear chain or branched chain alkenyl or C_8-20Linear chain or branched chain alkenyl, specifically such as octadecene base, 12 carbon Alkenyl, sub- oil base, vinyl, acrylic or allyl etc..As the C_6-50Aryl, for example C can be enumerated_6-20Aryl or Person C_6-10Aryl, specifically such as phenyl or naphthalene.Here, so-called " optionally substitution ", refers to optionally by one or more (ratios Such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene Base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, such as can To enumerate C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10 Monocycle or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially It is C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example can lift Go out C_2-10Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, such as can To enumerate C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in formula (A), group X ' is selected from halogen, including fluorine, chlorine, bromine and iodine, wherein it is preferred that chlorine.

According to the present invention, in step (2) so that polyfunctional compound's (such as amine compounds shown in formula (X)) 1: 0.1-200, preferably 1: 0.1-50 are commonly reached with the molar ratio of quaternizing agent shown in the formula (A), but sometimes and unlimited In this, as long as the dosage of the quaternizing agent makes at least one of etherification product molecular structure N atoms form quaternary ammonium Salt groups.

According to the present invention, in step (2), reaction temperature is generally 0 to 300 DEG C, preferably 50-150 DEG C, reaction time one As be 1-20 hour, preferably 4-15 hour, and reaction pressure can be the pressure of any suitable reaction progress, such as normal pressure.

According to the present invention, the step (2) can carry out in the presence of a catalyst, can not also use catalyst.Make For the catalyst, iodine specifically can be such as enumerated directly using this field conventional use of catalyst for this purpose Change potassium.As the dosage of the catalyst, it can be directly applicable in the conventional amount used of this field, specifically can such as enumerate 0.5- 3.0wt%, especially 1.0-2.0wt%.

According to the present invention, after step (2), the reaction that step (2) can be obtained by conventional separate mode Product mixtures are handled, and the cation-nonionic surfactant is thus isolated.As the separate mode, than It can such as enumerate and extract under alkaline condition.

Step (3)：Make the cation-nonionic surfactant and one or more following formulas (Z) compound represented It is reacted in the presence of basic catalyst, thus to obtain anionic-cationic-nonionic surface active agent (packet of the present invention It includes substantially such as aforementioned formula (I) compound represented, substantially such as previously described formula (I-1) compound represented, substantially as aforementioned Formula (I-2) compound represented, substantially such as previously described formula (I-3) compound represented or substantially such as previously described formula (I-4) institute The compound etc. shown).

According to the present invention, in step (3), as the basic catalyst, prior art mesh thus can be directly used And conventional use of any basic catalyst, wherein preferred alkali metal hydroxide, especially sodium hydroxide or hydroxide Potassium.One kind can be used only in these basic catalysts, can also combination of two or more use.

According to the present invention, in step (3), as the dosage of the basic catalyst, it can directly be applicable in this field Conventional amount used, but generally so that polyfunctional compound's (such as amine compounds shown in formula (X)) and the basic catalyst Molar ratio reach 1: 1-10, preferably reach 1: 1-5.

G-L-AS (Z)

According to the present invention, in formula (Z), group G is selected from halogen and hydroxyl, preferably halogen.As the halogen, such as can To enumerate fluorine, chlorine, bromine and iodine, preferably chlorine.

According to the present invention, in formula (Z), group L is selected from the C optionally replaced_1-10It linear chain or branched chain alkylidene and optionally takes The C in generation_2-10Linear chain or branched chain alkenylene is preferably selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene.

According to the present invention, in formula (Z), group AS is selected from by-A^-(M′)_r ⁺The group of representative, wherein group A^-Selected from carboxylic Acid group (COO^-) and sulfonate radical (SO₃ ^-), group M ' be selected from hydrogen, alkali metal (preferably Li, Na and K), alkaline-earth metal (preferably Mg and ) and ammonium root (NH Ca₄), preferred as alkali (preferably Li, Na and K) and alkaline-earth metal (preferably Mg and Ca).

According to the present invention, when group M ' is hydrogen, alkali metal or ammonium root, r=1；When group M ' is alkaline-earth metal, r= 0.5。

According to embodiment of the present invention, in formula (Z), as group A^-It is carboxylate radical (COO^-) when, group G is halogen Element, and work as group A^-It is sulfonate radical (SO₃ ^-) when, group G is halogen or hydroxyl.

According to embodiment of the present invention, using one or more formulas (Z) compound represented, wherein at least one In kind formula (Z) compound represented, group A^-It is carboxylate radical (COO^-).In consideration of it, when carrying out step (3), preferably at least Using with carboxylate radical (COO^-) formula (Z) compound represented.

According to the present invention, in formula (Z), so-called optional substitution, refer to optionally by it is one or more (such as 1 to 5,1 To 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.As the C_1-20Linear or branched alkyl group, for example can lift Go out C_1-10Linear or branched alkyl group or C_1-6Linear or branched alkyl group either methyl or ethyl etc..As the C_5-10Monocycle Or polycyclic naphthene base, for example C can be enumerated_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7 Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As the C_2-20Linear chain or branched chain alkenyl, for example C can be enumerated_2-10 Linear chain or branched chain alkenyl, specifically such as vinyl, acrylic or allyl etc..As the C_6-20Aryl, for example can lift Go out C_6-10Aryl, specifically such as phenyl or naphthalene.

According to the present invention, in step (3), general (such as amine compounds shown in formula (X) so that the polyfunctional compound Object) with the molar ratio of the formula (Z) compound represented reach 1: 1-10, preferably 1: 1-3.

According to the present invention, in step (3), reaction temperature is generally 0-300 DEG C, preferably 50-200 DEG C, reaction time one As be 1-20 hour, preferably 4-10 hour, and reaction pressure can be the pressure of any suitable reaction progress, such as normal pressure.

According to the present invention, after step (3), the reaction that step (3) can be obtained by conventional separate mode Product mixtures are handled, and the surfactant is thus isolated.As the separate mode, for example, can enumerate first to Acidic aqueous solution (such as aqueous hydrochloric acid solution, aqueous sulfuric acid, phosphoric acid water are added in the mixture of reaction products that step (3) obtains Solution, sodium bisulphate solution, aqueous potassium hydrogen sulfate etc.), its pH value is adjusted to 1-3, then carries out water-oil separating, thus The method that anionic-cationic-nonionic surface active agent of the present invention is obtained in the form of oil phase.

According to the present invention, after step (3), as needed, can make the anion-sun obtained as previously described from Son-nonionic surface active agent is further contacted with neutralizer, the free acid that thus will may contain in the surfactant Property group (such as free carboxyl or sulfonic group) be converted into the form (hereinafter referred to as neutralization procedure) of its salt.In described And agent, such as can enumerate alkali metal (preferably Li, Na and K) hydroxide, alkaline-earth metal (preferably Mg and Ca) hydroxide or Person's ammonium hydroxide.One kind can be used only in these neutralizers, can also combination of two or more use.As the neutralization procedure into Line mode, for example, can enumerate be added into the anionic-cationic-nonionic surface active agent it is a certain amount of it is described in With the aqueous solution or aqueous suspension of agent, it is 7-9 or 8-10 to be neutralized to pH value, then removes moisture and (for example passes through heating Evaporation, the methods of vacuum removal) method, but it is not limited to this.

Step (4)：As needed, by the either step of the manufacturing method of the present invention (including aforementioned step (3) and neutralize Step and step described below (5) etc.) anionic-cationic-nonionic surface active agent molecular structure for being obtained In at least part (or all) quaternary ammonium salt group be converted to corresponding quaternary ammonium base groups, and/or, by the moon of the acquisition At least part (or whole) quaternary ammonium base groups conversion in ion-cation-nonionic surface active agent molecular structure For corresponding quaternary ammonium salt group.

According to the present invention, which is optional step, rather than steps necessary.

According to the present invention, the step (4) can carry out according to conventionally known any mode, for example can enumerate electrolysis Method or ion-exchange etc., are not particularly limited.

Step (5)：It (including aforementioned step (3), step (4) and is neutralized from the arbitrary steps of the manufacturing method of the present invention Step) at least part (preferably all) is isolated with trip in anionic-cationic-nonionic surface active agent for being obtained From compound (M ') existing for form_rX ' (corresponds to previously described formula (M)_r ⁺X^-Shown in inorganic compound).Here, group (M′)_rDerived from previously described formula (Z) compound represented, group X ' is derived from quaternizing agent shown in previously described formula (A).The compound (M′)_rX ' is mainly because react with each other the higher ionic base of activity during the progress of abovementioned steps (3) or step (4) etc. Group (M ')_r ⁺With ionic group X '^-It meets and generates.By the separation, as it was noted above, obtain substantially with or at least portion Anionic-cationic-nonionic surface active agent of the present invention existing for ammonium salts within point.It is of course also possible to not detach Go out the compound (M ')_rX ' is (even if it is present in the anionic-cationic-nonionic surface active agent in a free form In), and make it as constituent (blending ingredients or the nothing of anionic-cationic-nonionic surface active agent of the present invention Evil impurity).Regardless of whether by the separation, all anionic-cationic-nonionic surface active agent of aforementioned acquisition are all united Referred to as anionic-cationic-nonionic surface active agent of the invention is included in the present invention's without being distinguish Within protection domain.

According to the present invention, which is optional step, rather than steps necessary, nor is considered as to the present invention's The purification step of anionic-cationic-nonionic surface active agent.

According to the present invention, as the compound (M ')_rThe separation method of X ', for example, can enumerate by from the present invention system Make the anionic-cationic-that the arbitrary steps (including aforementioned step (3), step (4) and neutralization procedure etc.) of method are obtained Nonionic surface active agent is dissolved in a large amount of absolute ethyl alcohol, the method etc. that the compound is then removed by filtration, but The present invention is not limited thereto.Due to the compound (M ')_rX ' has stronger water solubility, therefore its at least part may be Through passing through in the manufacturing process (such as in step (3)) of anionic-cationic-nonionic surface active agent of the present invention It is dissolved in water and is separated off.Due to the compound (M ')_rThe presence or absence of X ' or how many pairs of content it is produced by the present invention The various performances (such as interfacial activity and stability) of the anionic-cationic-nonionic surface active agent are without essence Property influence, therefore the present invention is not intended to the specific anionic-cationic-non-ionic surfactant obtained by the manufacturing method The compound (M ') in agent_rContent or existence form of X ' etc. are also not present the compound (M ') certainly_rX ' is from the present invention The necessity removed in any anionic-cationic-nonionic surface active agent of aforementioned acquisition.

According to the present invention, as the anionic-cationic-nonionic surface active agent (including substantially as aforementioned Formula (I) compound represented is changed substantially such as previously described formula (I-1) compound represented, substantially as shown in previously described formula (I-2) Close object, substantially such as previously described formula (I-3) compound represented or substantially such as previously described formula (I-4) compound represented), it can Can also be the mixture comprising multiple compounds, or even further comprise chemical combination above-mentioned to be a kind of single compound Object (M ')_rX ', these are all desired by the present invention.In consideration of it, according to the present invention, and there is no be further purified it is described it is cloudy from Son-cation-nonionic surface active agent, or from the anionic-cationic-nonionic surface active agent obtained The necessity of the compound of a certain specific structure is further separated out in (mixture).Even so, as it is described purifying or point The methods of from method, for example column chromatography method can be enumerated or prepare chromatography.

According to the present invention, in anionic-cationic-nonionic surface active agent of the present invention, different anion- It can be respective individualism between cation-nonionic surface active agent molecule, can also be zwitterion because of phase Mutually attract and associate even occur chemical reaction (such as pass through eliminate compound (M)_r ⁺X^-Or compound (M ')_rX ' etc.) and formed New compound, is not particularly limited.These existences all belong to the scope of protection of the present invention, and without being limited thereto literal Statement.

In anionic-cationic-nonionic surface active agent of the present invention, on the one hand due to anions and canons surface Strong electrostatic attraction effect between activating agent opposite charges polar group so that surfactant molecule increases in adsorbed on interfaces amount Greatly, critical micelle concentration significantly reduces, to the incomparable high surface of single surfactant；Simultaneously because should The interfacial activity of surfactant superelevation, aqueous solution can form ultralow interfacial tension with crude oil, thus between effectively overcoming crude oil Cohesive force, be conducive to the outflow of crude oil, and then greatly improve oil displacement efficiency.On the other hand, which can change Oil reservoir wettability of the surface, for example, cationic portion therein pass through it is mutual with absorption electronegative group on a solid surface Effect, makes it be desorbed, and so that glossy wet structure is changed into neutral wetting or water wetting surface, reduces crude oil in the surface of solids Adhesion work, to be conducive to the stripping of crude oil.Meanwhile the mixing of anions and canons part has solubilization to crude oil, it can be into one Step washes down the crude oil being adhered on the sandstone of rock stratum, improves oil recovery factor.In consideration of it, the anionic-cationic-of the present invention is non- Ionic surfactant is particularly suitable for manufacturing displacement composition (displacing fluid) used for tertiary oil recovery.

According to embodiment of the present invention, a kind of displacement composition used for tertiary oil recovery is further related to, it includes the present invention Anionic-cationic-nonionic surface active agent above-mentioned, Yi Jishui.

According to the present invention, in the displacement composition used for tertiary oil recovery, anionic-cationic-nonionic of the invention The total weight that type surfactant accounts for the displacement composition used for tertiary oil recovery is generally 0.001- (in terms of 100wt%) 10wt%, preferably 0.005-5wt%, more preferable 0.02-1wt%.

According to the present invention, in the displacement composition used for tertiary oil recovery can also as needed include this field during fabrication Conventional use of various additives, including but not limited to cationic water-soluble polymer, anionic water-soluble polymer or fat Fat alcohol ether solvents etc..These additives can be used only one kind, can also combination of two or more use, dosage can also be straight Connect the conventional amount used with reference to this field.

According to the present invention, as the cationic water-soluble polymer, for example polyacrylamide can be enumerated.The polypropylene The number-average molecular weight of amide is generally 10,000,000 to 40,000,000, preferably 10,000,000 to 30,000,000, dosage generally it is described three times The 0.05-5.0wt% to recover the oil with displacement composition total weight, preferably 0.1-0.5wt%, but is not limited thereto.

It can also be obtained according to the present invention even if the displacement composition used for tertiary oil recovery does not include inorganic base as component Obtain high oil displacement efficiency and washing oil ability.Therefore, according to a preferred embodiment of the present invention, the displacement of reservoir oil used for tertiary oil recovery Composition does not include (or not intentionally adding) inorganic base as component.As the inorganic base, for example this field can be enumerated and existed The carbonate of conventional use of inorganic alkaline compound, especially alkali metal such as carbonic acid in displacement composition used for tertiary oil recovery Sodium, sodium bicarbonate etc..

According to the present invention, the displacement composition used for tertiary oil recovery can be manufactured by following manufacturing method.

According to the present invention, the manufacturing method of the displacement composition used for tertiary oil recovery include make the present invention it is above-mentioned it is cloudy from Son-cation-nonionic surface active agent mixes the step of (to uniformly) with water (and additive used as needed). At this point, the dosage of the anionic-cationic-nonionic surface active agent and the additive provides in the past.

According to the present invention, the anionic-cationic-nonionic surface active agent or the displacement of reservoir oil used for tertiary oil recovery Composition can be used for tertiary oil recovery method, and show the oil displacement efficiency improved compared with prior art and washing oil ability (ratio Can be more than such as 40%), it is possible thereby to significantly improve oil recovery factor to the washing oil rate of crude oil.In consideration of it, the invention further relates to A kind of tertiary oil recovery method, including use anionic-cationic-nonionic surface active agent above-mentioned of the invention or this hair The step of bright displacement composition used for tertiary oil recovery above-mentioned carries out tertiary oil recovery as displacing fluid.

A preferred embodiment according to the present invention does not use or does not have when carrying out the tertiary oil recovery method Meaning addition inorganic base.Therefore, tertiary oil recovery method of the invention does not injure stratum and oil well, avoids equipment and pipeline Corrosion, and demulsification will not be caused difficult.

According to the present invention, the anionic-cationic-nonionic surface active agent or displacement composition used for tertiary oil recovery It is soluble easily in water, even at high temperature, it can also be formed stablize and the aqueous solution of clear in water, and without precipitating production It is raw, the excellent in stability of chemical composition and interfacial activity.In addition, the clear state of the aqueous solution can be (even in height Under temperature) it keeps steadily in the long term, thus show excellent long-term chemical composition stability.Moreover, according to currently preferred Be, though the anionic-cationic-nonionic surface active agent, displacement composition used for tertiary oil recovery or its aqueous solution through Long-term (especially at high temperature) storage is crossed, interfacial activity is also kept substantially stabilization, thus shows excellent long-term boundary Face activity stability.

According to the present invention, the anionic-cationic-nonionic surface active agent is in use (substantially) no It will appear chromatographic isolation phenomenon (that is, being not in component segregation phenomenon), the stability of chemical composition and interfacial activity in use It is excellent.

Embodiment

Embodiment and comparative example is used to illustrate the present invention in further detail below, but the present invention is not limited to these implementations Example.

【Embodiment 1】

20 moles of dodecyl polyanilines and 2 moles of chloromethanes are added in reaction kettles to profit after being warming up to 80 DEG C of reactions 5 hours (4- dodecylphenyls) methyl amine is purified with chromatographic technique.By 1 mole of (4- dodecylphenyls) methyl amine and 0.1 moles of hydrogen Potassium oxide is added in reaction kettle and is warming up to 80 DEG C, is decompressed to vacuum degree 0.9, stirs 30 minutes and removes volatile components, uses nitrogen Gas 4 times in replacement reaction kettle, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, is used 1 mol propylenoxy is added in reaction kettle the nitrogen of 0.8MPa pressure, and reaction obtains etherification product after 5 hours.By all ethers Change product and be dissolved in and be configured to 40% solution in absolute ethyl alcohol and be added in reaction kettle, 1.1 are added with the nitrogen of 0.8MPa pressure Mole quaternizing agent chloromethanes, reacts 3~10 hours after reaction system is warming up to 80 DEG C, is removed under reduced pressure extra quaternized Reagent chloromethanes and etoh solvent obtain quaternized products (i.e. cation-nonionic surface active agent, the same below).1 is rubbed Your quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides, which are added in reaction kettle, is warming up to 80 DEG C, is stirred continuously, profit Quaternized products are converted to corresponding sylvite with the moisture being azeotroped off in reaction system, 1.1 moles of carboxylating agents are then added Reactant with hydrochloric acid is adjusted to acidity by sodium chloroacetate after reacting 5 hours, twice with 15%NaCl brine washing reactions product, is used Product is converted to corresponding sodium salt by sodium hydrate aqueous solution, and then reaction product is dissolved in a large amount of absolute ethyl alcohols, is crossed and is filtered out Anionic-cationic-nonionic surface active agent is obtained after going the inorganic salts in product, vacuum distillation to remove etoh solvent, Its particular chemical is shown in Table the 1-1 in 1, and nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 2】

20 moles of 4- nonyls aniline and 2 moles of chloromethanes are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours and are utilized Chromatographic technique purifies (4- nonyls phenyl) methyl amine.1 mole of (4- nonyls phenyl) methyl amine and 0.1 molar potassium hydroxide are added It is warming up to 80 DEG C in reaction kettle, is decompressed to vacuum degree 0.9, stirs 30 minutes and removes volatile components, with nitrogen replacement reaction kettle Interior gas 4 times, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure 1 moles of ethylene oxide is added in reaction kettle gas, and reaction obtains etherification product after 5 hours.All etherification products are dissolved in anhydrous It is configured to 40% solution in ethyl alcohol to be added in reaction kettle, 1.1 moles of quaternizing agents are added with the nitrogen of 0.8MPa pressure Chloromethanes.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra quaternizing agent chloromethanes and molten is removed under reduced pressure Agent ethyl alcohol obtains quaternized products.Then 1 mole of quaternized products and 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added It in reaction kettle, is warming up to 80 DEG C and is stirred continuously, take away the moisture content of reaction generation using azeotropic until quaternized products are converted to phase 1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle the potassium alcoholate answered, and after reacting 5 hours, are adjusted to reactant with hydrochloric acid Product twice with 15%NaBr brine washing reactions product is converted to corresponding ammonium salt by acidity with ammonium hydroxide.Reaction product is molten In a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, it is non-that vacuum distillation removing solvent obtains anionic-cationic- Ionic surfactant, particular chemical are shown in Table the 1-2 in 1, and nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 3】

20 moles of 9- oleyl amines and 2 moles of allyl chlorides are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours (9- octadecenes base) allyl amine is purified using chromatographic technique.By 1 mole of (9- octadecenes base) allyl amine and 0.1 mole It is warming up to 80 DEG C in potassium hydroxide addition reaction kettle and is decompressed to vacuum degree 0.9, stirs 30 minutes and remove volatile components, use nitrogen Gas 4 times in replacement reaction kettle, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, is used 49 mol propylenoxies are added in reaction kettle the nitrogen of 0.8MPa pressure, and reaction uses the nitrogen of 0.8MPa pressure will after 5 hours 37 moles of ethylene oxide are added in reaction kettle, and reaction obtains etherification product after 5 hours.All etherification products are dissolved in absolute ethyl alcohol In be configured to 40% solution and be added in reaction kettle, 1.1 moles of quaternizing agent allyls are added with the nitrogen of 0.8MPa pressure Base chlorine.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra quaternizing agent allyl chloride and molten is removed under reduced pressure Agent ethyl alcohol obtains quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added It in reaction kettle, is warming up to 80 DEG C and is stirred continuously, take away the moisture content of reaction generation using azeotropic until quaternized products are converted to phase The potassium alcoholate answered.1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, are adjusted to reactant with hydrochloric acid Product twice with 15%NaI brine washing reactions product is converted to corresponding sylvite by acidity with potassium hydroxide aqueous solution.It will Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, and vacuum distillation removes solvent and obtains anion- Cation-nonionic surface active agent, particular chemical are shown in Table the 1-3 in 1, and nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 4】

20 moles of isotridecyl aniline and 2 moles of benzyl chlorides are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours Isotridecyl benzyl amine is purified using chromatographic technique.1 mole of isotridecyl benzyl amine and 0.1 molar potassium hydroxide are added It is warming up to 80 DEG C in reaction kettle, is decompressed to vacuum degree 0.9, stirs 30 minutes and removes volatile components, with nitrogen replacement reaction kettle Interior gas 4 times, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure 39 mol propylenoxies are added in reaction kettle gas, with the nitrogen of 0.8MPa pressure by 41 moles of ethylene oxide after reaction 5 hours It is added in reaction kettle, reaction obtains etherification product after 5 hours.All etherification products are dissolved in absolute ethyl alcohol and are configured to 40% Solution is added in reaction kettle, and 1.1 moles of quaternizing agent benzyl chlorides are added with the nitrogen of 0.8MPa pressure.By reaction system liter Temperature is removed under reduced pressure extra quaternizing agent benzyl chloride and etoh solvent obtains quaternized production to reacting 3~10 hours after 80 DEG C Object.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C It is stirred continuously, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate.By 1.1 moles of carboxylics Agent sodium chloroacetate is added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, with 15%NaCl brine Product is converted to corresponding calcium salt by washing reaction product twice, with calcium hydroxide aqueous solution.Reaction product is dissolved in a large amount of nothings In water-ethanol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-nonionic table Face activating agent, particular chemical are shown in Table the 1-4 in 1, and nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 5】

20 moles of dinonyl benzylamines and 2 moles of 2 cbloropropane isopropyl chlorides are added in reaction kettles to profit after being warming up to 80 DEG C of reactions 5 hours Different (dinonyl benzyl) isopropylamine is purified with chromatographic technique.1 mole of dinonyl benzylamine and 0.1 molar potassium hydroxide are added anti- It answers and is warming up to 80 DEG C in kettle, be decompressed to vacuum degree 0.9, stir 30 minutes and remove volatile components, in nitrogen replacement reaction kettle Gas 4 times, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure 1 mol propylenoxy is added in reaction kettle, 39 moles of ethylene oxide are added with the nitrogen of 0.8MPa pressure after 5 hours for reaction In reaction kettle, reaction obtains etherification product after 5 hours.All etherification products are dissolved in be configured in absolute ethyl alcohol 40% solution It is added in reaction kettle, 1.1 moles of 2 cbloropropane isopropyl chlorides of quaternizing agent is added with the nitrogen of 0.8MPa pressure.Reaction system is heated up It is reacted 3~10 hours after to 80 DEG C, extra quaternizing agent 2 cbloropropane isopropyl chloride is removed under reduced pressure and etoh solvent obtains quaternized production Object.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C It is stirred continuously, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate.By 1.1 moles of carboxylics Agent sodium chloroacetate is added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, with 15%NaBr brine Product is converted to corresponding magnesium salts by washing reaction product twice, with magnesium hydroxide aqueous solution.Reaction product is dissolved in a large amount of nothings In water-ethanol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-nonionic table Face activating agent, particular chemical are shown in Table the 1-5 in 1, and nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 6】

20 moles of dodecyl benzylamines and 2 moles of chloroethanes are added in reaction kettles to profit after being warming up to 80 DEG C of reactions 5 hours (dodecylbenzyl) ethylamine is purified with chromatographic technique.By 1 mole of (dodecylbenzyl) ethylamine and 0.1 mole of hydroxide Potassium is added in reaction kettle and is warming up to 80 DEG C, is decompressed to vacuum degree 0.9, stirs 30 minutes and removes volatile components, is replaced with nitrogen React gas reactor 4 times, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, is pressed with 0.8MPa 21 moles of ethylene oxide are added in reaction kettle the nitrogen of power, with the nitrogen of 0.8MPa pressure by 17 moles of rings after reaction 5 hours Ethylene Oxide, which is added in reaction kettle to react 5 hours, obtains etherification product.All etherification products are dissolved in absolute ethyl alcohol and are configured to 40% solution is added in reaction kettle, and 1.1 moles of quaternizing agent chloroethanes are added with the nitrogen of 0.8MPa pressure.It will reaction System is reacted 3~10 hours after being warming up to 80 DEG C, and extra quaternizing agent chloroethanes is removed under reduced pressure and etoh solvent obtains season Ammonium product.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, heating It is stirred continuously to 80 DEG C, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate.By 1.1 Mole carboxylating agent sodium chloroacetate is added in reaction kettle, after reaction 5 hours, reactant is adjusted to acidity with hydrochloric acid, uses 15%NaI Product is converted to corresponding sylvite by brine washing reaction product twice, with potassium hydroxide aqueous solution.Reaction product is dissolved in greatly It measures in absolute ethyl alcohol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-nonionic Type surfactant, particular chemical are shown in Table the 1-6 in 1, and nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 7】

1 mole of dodecyl -3- Methyl anthranilate, 2 moles of isopropanolamines and 0.1 molar potassium hydroxide are added In reaction kettle, 180 DEG C are warming up to, reaction utilizes chromatographic technique purification dodecyl -3- amino benzoyl isopropanols after 5 hours Base amine.Reaction kettle is added in 1 mole of dodecyl -3- amino benzoyls isopropyl alcohol radical amine and 0.1 molar potassium hydroxide and is subtracted It is depressed into vacuum degree 0.9, stirs 30 minutes and remove volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjust in reaction kettle Pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 11 mol propylenoxies are added with the nitrogen of 0.8MPa pressure In reaction kettle, reaction uses the nitrogen of 0.8MPa pressure that will be reacted 5 hours in 27 moles of ethylene oxide addition reaction kettle again after 5 hours After obtain etherification product.All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added in reaction kettle, are used 1.1 moles of quaternizing agent allyl chlorides are added in the nitrogen of 0.8MPa pressure.3~10 are reacted after reaction system is warming up to 80 DEG C Hour, extra quaternizing agent allyl chloride is removed under reduced pressure and etoh solvent obtains quaternized products.Then by 1 mole of quaternary ammonium Change product, 10 liters of solvent benzols and 1.1 molar potassium hydroxides to be added in reaction kettle, is warming up to 80 DEG C and is stirred continuously, utilize azeotropic The moisture content that reaction generates is taken away until quaternized products are converted to corresponding potassium alcoholate.1.1 moles of carboxylating agent sodium chloroacetates are added In reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, twice with 15%NaBr brine washing reactions product, Product is converted to corresponding ammonium salt with ammonium hydroxide.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the nothing being filtered to remove in product Machine salt, vacuum distillation remove solvent and obtain anionic-cationic-nonionic surface active agent, and particular chemical is shown in Table 1 In 1-7, nuclear magnetic resonance spectroscopy is shown in Table 5.

【Embodiment 8】

It is small by 80 DEG C of reactions 5 are warming up in 10 moles of 5- eicosyls m-phenylene diamine (MPD)s and 20 moles of benzyl chlorides addition reaction kettles When after using chromatographic technique purify N, N '-dibenzyl -5- eicosyl m-phenylene diamine (MPD)s.By 1 mole of N, N '-dibenzyl -5- 20 Alkyl resorsinols diamines and 0.1 molar potassium hydroxide, which are added in reaction kettle, is warming up to 80 DEG C, is decompressed to vacuum degree 0.9, stirs 30 points Clock removes volatile components, and with gas in nitrogen replacement reaction kettle 4 times, adjustings reacting kettle inner pressure is 0.2MPa.By reactant The temperature of system rises to 220 DEG C, 2 mol propylenoxies is added in reaction kettle with the nitrogen of 0.8MPa pressure, reaction is used after 5 hours 48 moles of ethylene oxide are added in reaction kettle the nitrogen of 0.8MPa pressure, and reaction obtains etherification product after 5 hours.By all ethers Change product and be dissolved in and be configured to 40% solution in absolute ethyl alcohol and be added in reaction kettle, 2.2 are added with the nitrogen of 0.8MPa pressure Mole quaternizing agent benzyl chloride.It reacts 3~10 hours, is removed under reduced pressure extra quaternized after reaction system is warming up to 80 DEG C Reagent benzyl chloride and etoh solvent obtain quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 are rubbed You are added in reaction kettle potassium hydroxide, are warming up to 80 DEG C and are stirred continuously, and the moisture content of reaction generation is taken away until quaternary ammonium using azeotropic Change product and is converted to corresponding potassium alcoholate.2.2 moles of sulfonating agent chloromethylsulfonic acid sodium are added in reaction kettle, after reacting 5 hours, are used Reactant is adjusted to acidity by hydrochloric acid, twice with 15%NaI brine washing reactions product, is turned product with potassium hydroxide aqueous solution It is melted into corresponding sylvite.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation removes Solvent is gone to obtain anionic-cationic-nonionic surface active agent, particular chemical is shown in Table the 1-8 in 1, nuclear-magnetism Resonance hydrogen spectrum is shown in Table 5.

【Embodiment 9】

20 moles of lauryl amines and 2 moles of chloromethanes are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours and are utilized Chromatographic technique purifies dodecyl methyl amine.1 mole of dodecyl methyl amine and 0.1 molar potassium hydroxide are added in reaction kettle 80 DEG C are warming up to, vacuum degree 0.9 is decompressed to, stirs 30 minutes and removes volatile components, with gas 4 in nitrogen replacement reaction kettle Secondary, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 1 is rubbed with the nitrogen of 0.8MPa pressure You are added in reaction kettle propylene oxide, and reaction obtains etherification product after 5 hours.All etherification products are dissolved in absolute ethyl alcohol and are matched 40% solution is made to be added in reaction kettle, 1.1 moles of quaternizing agent chloromethanes are added with the nitrogen of 0.8MPa pressure.It will Reaction system is reacted 3~10 hours after being warming up to 80 DEG C, and extra quaternizing agent chloromethanes is removed under reduced pressure and etoh solvent obtains To quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, It is warming up to 80 DEG C to be stirred continuously, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, are used Product is converted to corresponding sodium salt by 15%NaCl brine washing reactions product twice, with sodium hydrate aqueous solution.Reaction is produced Object is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation remove solvent obtain anion-sun from Son-nonionic surface active agent, particular chemical are shown in Table the 2-1 in 2, and nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 10】

20 moles of oleyl amines and 2 moles of chloromethanes are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours and utilize chromatography skill Art purifies 9- octadecene ylmethyl amine.Reaction kettle is added in 1 mole of 9- octadecene ylmethyl amine and 0.1 molar potassium hydroxide In be warming up to 80 DEG C, be decompressed to vacuum degree 0.9, stir 30 minutes and remove volatile components, with gas 4 in nitrogen replacement reaction kettle Secondary, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 1 is rubbed with the nitrogen of 0.8MPa pressure You are added in reaction kettle ethylene oxide, and reaction obtains etherification product after 5 hours.All etherification products are dissolved in absolute ethyl alcohol and are matched 40% solution is made to be added in reaction kettle, 1.1 moles of quaternizing agent chloromethanes are added with the nitrogen of 0.8MPa pressure.It will Reaction system is reacted 3~10 hours after being warming up to 80 DEG C, and extra quaternizing agent chloromethanes is removed under reduced pressure and etoh solvent obtains To quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, It is warming up to 80 DEG C to be stirred continuously, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, are used Product is converted to corresponding ammonium salt by 15%NaBr brine washing reactions product twice, with ammonium hydroxide.Reaction product is dissolved in largely In absolute ethyl alcohol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-nonionic Surfactant, particular chemical are shown in Table the 2-2 in 2, and nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 11】

20 moles of rosin amines and 2 moles of 1- chloro octanes are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours and are utilized Chromatographic technique purifies abietyl octyl amine.1 mole of abietyl octyl amine and 0.1 molar potassium hydroxide are added in reaction kettle and heated up To 80 DEG C, it is decompressed to vacuum degree 0.9, stirs 30 minutes and remove volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjusts Section reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure by 49 moles of rings Ethylene Oxide is added in reaction kettle, and 37 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure after 5 hours for reaction, Reaction obtains etherification product after 5 hours.All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added to instead It answers in kettle, 1 mole of quaternizing agent 1- chloro octane is added with the nitrogen of 0.8MPa pressure.After reaction system is warming up to 80 DEG C Reaction 3~10 hours, is removed under reduced pressure extra etoh solvent and obtains quaternized products.Then by 1 mole of quaternized products, 10 liters Solvent benzol and 1.1 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C and are stirred continuously, and taking away reaction using azeotropic generates Moisture content until quaternized products be converted to corresponding potassium alcoholate.1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, reaction After 5 hours, reactant is adjusted to acidity with hydrochloric acid, twice with 15%NaBr brine washing reactions product, with magnesium hydroxide water Product is converted to corresponding magnesium salts by solution.Reaction product is dissolved in a large amount of absolute ethyl alcohols, is filtered to remove inorganic in product Salt, vacuum distillation remove solvent and obtain anionic-cationic-nonionic surface active agent, and particular chemical is shown in Table in 2 2-3, nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 12】

20 moles of isotridecyl amine and 2 moles of allyl chlorides are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours Isotridecyl allyl amine is purified using chromatographic technique.By 1 mole of isotridecyl allyl amine and 0.1 molar potassium hydroxide It is added in reaction kettle and is warming up to 80 DEG C, be decompressed to vacuum degree 0.9, stir 30 minutes and remove volatile components, replaced with nitrogen anti- Answer gas reactor 4 times, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with 0.8MPa pressure Nitrogen 25 mol propylenoxies are added in reaction kettle, with the nitrogen of 0.8MPa pressure by 17 moles of epoxies after reaction 5 hours Ethane is added in reaction kettle, and reaction obtains etherification product after 5 hours.All etherification products are dissolved in absolute ethyl alcohol and are configured to 40% solution is added in reaction kettle, and 1.1 moles of quaternizing agent allyl chlorides are added with the nitrogen of 0.8MPa pressure.It will be anti- It is reacted 3~10 hours after answering system to be warming up to 80 DEG C, extra quaternizing agent allyl chloride is removed under reduced pressure and etoh solvent obtains To quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, It is warming up to 80 DEG C to be stirred continuously, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, are used Product is converted to corresponding calcium salt by 15%NaI brine washing reactions product twice, with calcium hydroxide aqueous solution.By reaction product It is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic- Nonionic surface active agent, particular chemical are shown in Table the 2-4 in 2, and nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 13】

5 moles of lysine methyl esters and 10 moles of monoethanolamine are added in reaction kettles to profit after being warming up to 180 DEG C of reactions 5 hours It is purified to obtain lysine single ethanol amide with chromatographic technique.By 5 moles of lysine single ethanol amides and 10 moles of 1- chloro octanes Be added reaction kettle in be warming up to 80 DEG C reaction 5 hours after purify to obtain N, N '-dioctyl lysine monoethanols using chromatographic technique Amide.By 1 mole of N, N '-dioctyl lysine single ethanol amides and potassium hydroxide are added in reaction kettle and are warming up to 80 DEG C, decompression It to vacuum degree 0.9, stirs 30 minutes and removes volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjust reaction kettle internal pressure Power is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 39 moles of ethylene oxide are added instead with the nitrogen of 0.8MPa pressure It answers in kettle, 15 mol propylenoxies are added in reaction kettle with the nitrogen of 0.8MPa pressure after 5 hours for reaction, after reacting 5 hours Obtain etherification product.All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added in reaction kettle, are used 2 moles of quaternizing agent 1- chloro octanes are added in the nitrogen of 0.8MPa pressure.3~10 are reacted after reaction system is warming up to 80 DEG C Hour, etoh solvent is removed under reduced pressure and obtains quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 are rubbed You are added in reaction kettle potassium hydroxide, are warming up to 80 DEG C and are stirred continuously, and the moisture content of reaction generation is taken away until quaternary ammonium using azeotropic Change product and is converted to corresponding potassium alcoholate.3.3 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, use hydrochloric acid Reactant is adjusted to acidity, twice with 15%NaBr brine washing reactions product, is converted product with magnesium hydroxide aqueous solution At corresponding magnesium salts.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation removes Solvent obtains anionic-cationic surfactant, and particular chemical is shown in Table the 2-5 in 2, and nuclear magnetic resonance spectroscopy is shown in Table 6。

【Embodiment 14】

20 moles of octadecylamines and 2 moles of benzyl chlorides are added in reaction kettles after being warming up to 80 DEG C of reactions 5 hours and utilize chromatography Technology purifies to obtain octadecyl benzyl amine.1 mole of octadecyl benzyl amine and 0.1 molar potassium hydroxide are added in reaction kettle 80 DEG C are warming up to, vacuum degree 0.9 is decompressed to, stirs 30 minutes and removes volatile components, with gas 4 in nitrogen replacement reaction kettle Secondary, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure by 25 Mol propylenoxy is added in reaction kettle, and 17 moles of ethylene oxide are added instead with the nitrogen of 0.8MPa pressure after 5 hours for reaction It answers in kettle, reaction obtains etherification product after 5 hours.All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and adds Enter into reaction kettle, 1.1 moles of quaternizing agent benzyl chlorides are added with the nitrogen of 0.8MPa pressure.Reaction system is warming up to 80 It is reacted 3~10 hours after DEG C, excess of solvent ethyl alcohol is removed under reduced pressure and obtains quaternized products.Then by 1 mole of quaternized products, 10 It rises solvent benzol and 1.1 molar potassium hydroxides is added in reaction kettle, be warming up to 80 DEG C and be stirred continuously, reaction production is taken away using azeotropic Raw moisture content is until quaternized products are converted to corresponding potassium alcoholate.1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, instead After answering 5 hours, reactant is adjusted to acidity with hydrochloric acid, it twice with 15%NaI brine washing reactions product, will with sodium hydroxide Product is converted to corresponding ammonium salt.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, is depressurized Solvent is distilled off and obtains anionic-cationic-nonionic surface active agent, particular chemical is shown in Table the 2-6 in 2, Its nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 15】

1 mole of lauryl amine and 0.1 molar potassium hydroxide are added in reaction kettle and are warming up to 80 DEG C, is decompressed to vacuum degree 0.9, Stirring removes volatile components in 30 minutes, and with gas in nitrogen replacement reaction kettle 4 times, adjustings reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, 39 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure, reaction 1 mol propylenoxy is added in reaction kettle with the nitrogen of 0.8MPa pressure after 5 hours, reaction obtains etherification product after 5 hours. All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added in reaction kettle, with the nitrogen of 0.8MPa pressure 1.1 moles of quaternizing agent chlorocyclohexanes are added.It reacts 3~10 hours, is removed under reduced pressure after reaction system is warming up to 80 DEG C Extra quaternizing agent chlorocyclohexane and etoh solvent obtain quaternized products.Then by 1 mole of quaternized products, 10 liters Solvent benzol and 2.2 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C and are stirred continuously, and taking away reaction using azeotropic generates Moisture content until quaternized products be converted to corresponding potassium alcoholate.2.2 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, reaction After 5 hours, reactant is adjusted to acidity with hydrochloric acid, twice with 15%NaCl brine washing reactions product, with sodium hydroxide water Product is converted to corresponding sodium salt by solution.Reaction product is dissolved in a large amount of absolute ethyl alcohols, is filtered to remove inorganic in product Salt, vacuum distillation remove solvent and obtain anionic-cationic-nonionic surface active agent, and particular chemical is shown in Table in 2 2-7, nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 16】

1 mole of palmitin amine and 0.1 molar potassium hydroxide are added in reaction kettle and are warming up to 80 DEG C, is decompressed to vacuum degree 0.9, Stirring removes volatile components in 30 minutes, and with gas in nitrogen replacement reaction kettle 4 times, adjustings reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, 1 mol propylenoxy is added in reaction kettle with the nitrogen of 0.8MPa pressure, reaction 5 39 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure after hour, reaction obtains etherification product after 5 hours. All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added in reaction kettle, with the nitrogen of 0.8MPa pressure 1.1 moles of quaternizing agent allyl chlorides are added.It reacts 3~10 hours, is removed under reduced pressure more after reaction system is warming up to 80 DEG C Remaining quaternizing agent allyl chloride and etoh solvent obtain quaternized products.Then by 1 mole of quaternized products, 10 liters of solvents Benzene and 2.2 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C and are stirred continuously, and the water that reaction generates is taken away using azeotropic Part is until quaternized products are converted to corresponding potassium alcoholate.2.2 moles of sulfonating agent chloromethylsulfonic acid sodium are added in reaction kettle, reaction After 5 hours, reactant is adjusted to acidity with hydrochloric acid, twice with 15%NaCl brine washing reactions product, with calcium hydroxide water Product is converted to corresponding calcium salt by solution.Reaction product is dissolved in a large amount of absolute ethyl alcohols, is filtered to remove inorganic in product Salt, vacuum distillation remove solvent and obtain anionic-cationic-nonionic surface active agent, and particular chemical is shown in Table in 2 2-8, nuclear magnetic resonance spectroscopy is shown in Table 6.

【Embodiment 17】

10 moles of 1- chlorinated dodecanes and 5 moles of ammonia are added in reaction kettle and are warming up to 80 DEG C, reaction utilizes layer after 5 hours Analysis technology purifies two (dodecyl) amine, and reaction kettle then is added in 1 mole of two (dodecyl) amine and 0.1 molar potassium hydroxide In be warming up to 80 DEG C, be decompressed to vacuum degree 0.9, stir 30 minutes and remove volatile components, with gas 4 in nitrogen replacement reaction kettle Secondary, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure by 14 Mol propylenoxy is added in reaction kettle, and 9 moles of ethylene oxide, which are added, with the nitrogen of 0.8MPa pressure after 5 hours for reaction reacts In kettle, reaction 5 hours after obtain etherification product, all etherification products are dissolved in be configured in absolute ethyl alcohol 40% solution be added Into reaction kettle, 1.1 moles of quaternizing agent chloromethanes are added with the nitrogen of 0.8MPa pressure.Reaction system is warming up to 80 DEG C It reacts 3~10 hours afterwards, extra quaternizing agent chloromethanes is removed under reduced pressure and etoh solvent obtains quaternized products.Then will 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C and are stirred continuously, The moisture content of reaction generation is taken away using azeotropic until quaternized products are converted to corresponding potassium alcoholate.By 1.1 moles of carboxylating agent chloroethenes Sour sodium is added in reaction kettle, and after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, is produced with 15%NaI brine washing reactions Product is converted to corresponding sodium salt by object twice, with sodium hydrate aqueous solution.Reaction product is dissolved in a large amount of absolute ethyl alcohols, mistake The inorganic salts in product are filtered out, vacuum distillation removes solvent and obtains anionic-cationic-nonionic surface active agent, Particular chemical is shown in Table the 3-1 in 3, and nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 18】

2 moles of 1- chlorooctadecanes and 20 moles of diethanol amine are added in reaction kettle and are warming up to 80 DEG C, are reacted 5 hours Afterwards, octadecyl diethanolamine is purified using chromatographic technique, then by 1 mole of octadecyl diethanolamine and 0.1 mole Potassium hydroxide is added reaction kettle and is warming up to 80 DEG C, is decompressed to vacuum degree 0.9, stirs 30 minutes and removes volatile components, uses nitrogen Gas 4 times in replacement reaction kettle, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, is used 4 moles of ethylene oxide are added in reaction kettle the nitrogen of 0.8MPa pressure, with the nitrogen of 0.8MPa pressure by 22 after reaction 5 hours Mol propylenoxy is added in reaction kettle, and reaction obtains etherification product after 5 hours, and all etherification products are dissolved in absolute ethyl alcohol It is configured to 40% solution to be added in reaction kettle, 1 mole of quaternizing agent 1- chloro ten is added with the nitrogen of 0.8MPa pressure Dioxane.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, excess of solvent ethyl alcohol is removed under reduced pressure and obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C not Disconnected stirring takes away the moisture content of reaction generation until quaternized products are converted to corresponding potassium alcoholate using azeotropic.By 2.2 moles of carboxylations Agent sodium chloroacetate is added in reaction kettle, and after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, is washed with 15%NaCl salt It washs reaction product twice, product is converted to corresponding sylvite with potassium hydroxide aqueous solution.Reaction product is dissolved in a large amount of anhydrous In ethyl alcohol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-non-ionic surface Activating agent, particular chemical are shown in Table the 3-2 in 3, and nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 19】

20 moles of oleyl amines and 2 moles of 1- chlorinated dodecanes are added in reaction kettle and are warming up to 80 DEG C, reaction utilizes after 5 hours Chromatographic technique purifies 1- (9- octadecenes base) lauryl amine, then by 1 mole of 1- (9- octadecenes base) lauryl amine It is decompressed to vacuum degree 0.9 with being warming up to 80 DEG C in 0.1 molar potassium hydroxide addition reaction kettle, stirring removes volatile group in 30 minutes Point, with gas in nitrogen replacement reaction kettle 4 times, adjustings reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 17 mol propylenoxies are added in reaction kettle with the nitrogen of 0.8MPa pressure, the nitrogen of 0.8MPa pressure is used in reaction after 5 hours 38 moles of ethylene oxide are added in reaction kettle gas, and reaction obtains etherification product after 5 hours, all etherification products is dissolved in anhydrous It is configured to 40% solution in ethyl alcohol to be added in reaction kettle, 1.1 moles of quaternizing agents are added with the nitrogen of 0.8MPa pressure Chlorocyclohexane.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra quaternizing agent chloro ring is removed under reduced pressure Hexane and etoh solvent obtain quaternized products.Then by 1 molar ammonium product of season, 10 liters of solvent benzols and 1.1 moles of hydrogen-oxygens Change potassium to be added in reaction kettle, be warming up to 80 DEG C and be stirred continuously, the moisture content of reaction generation is taken away until quaternized products using azeotropic It is converted to corresponding potassium alcoholate.1.1 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, will be reacted with hydrochloric acid Object is adjusted to acidity, twice with 15%NaBr brine washing reactions product, is converted to product accordingly with calcium hydroxide aqueous solution Calcium salt.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains To anionic-cationic-nonionic surface active agent, particular chemical is shown in Table the 3-3 in 3, nuclear magnetic resonance spectroscopy It is shown in Table 7.

【Embodiment 20】

2 moles of 1- chloro -9- octadecenes and 20 moles of diethanol amine are added in reaction kettle and are warming up to 80 DEG C, reaction 5 After hour, (9- octadecenes base) diethanolamine is purified using chromatographic technique, then by 1 mole of (9- octadecenes base) dihydroxy It is warming up to 80 DEG C in ethylamine and 0.1 molar potassium hydroxide addition reaction kettle and is decompressed to vacuum degree 0.9, stirs 30 minutes and remove easily Volatile component, with gas in nitrogen replacement reaction kettle 4 times, adjusting reacting kettle inner pressure is 0.2MPa.By the temperature of reaction system 220 DEG C are risen to, 16 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure, reaction uses 0.8MPa after 5 hours 49 mol propylenoxies are added in reaction kettle the nitrogen of pressure, and reaction obtains etherification product after 5 hours, by all etherification products It is dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added in reaction kettle, 1 mole of quaternary ammonium is added with the nitrogen of 0.8MPa pressure Change reagent 1- chlorinated dodecanes.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra etoh solvent is removed under reduced pressure Obtain quaternized products.Then reaction kettle is added in 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxides In, it is warming up to 80 DEG C and is stirred continuously, take away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding alcohol Potassium.2.2 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, Twice with 15%NaCl brine washing reactions product, product is converted to corresponding sylvite with potassium hydroxide aqueous solution.It will reaction Product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation remove solvent obtain anion-sun from Son-nonionic surface active agent, particular chemical are shown in Table the 3-4 in 3, and nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 21】

11 mole of oleic acid methyl esters and 100 moles of ethylene diamine are added in reaction kettle and are warming up to 180 DEG C, profit after reaction 5 hours Oleoyl ethylenediamine is purified to obtain with chromatographic technique, then 10 moles of oleoyl ethylenediamines and 1 mole of 1- chlorinated dodecane are added 80 DEG C are warming up in reaction kettle, reaction utilizes chromatographic technique purification 1- oleoyl -4- lauryl ethylenediamines after 5 hours.By 1 mole It is warming up to 80 DEG C in 1- oleoyls -4- lauryls ethylenediamine and 0.1 molar potassium hydroxide addition reaction kettle and is decompressed to vacuum degree 0.9, it stirs 30 minutes and removes volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, reaction kettle is added in 2 mol propylenoxies with the nitrogen of 0.8MPa pressure In, 39 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure after 5 hours for reaction, and reaction obtains after 5 hours All etherification products are dissolved in and are configured to 40% solution in absolute ethyl alcohol and are added in reaction kettle, use 0.8MPa by etherification product 1.1 moles of quaternizing agent chlorocyclohexanes are added in the nitrogen of pressure.Reaction 3~10 is small after reaction system is warming up to 80 DEG C When, extra quaternizing agent chlorocyclohexane is removed under reduced pressure and etoh solvent obtains quaternized products.Then by 1 mole of quaternary ammonium Change product, 10 liters of solvent benzols and 1.1 molar potassium hydroxides to be added in reaction kettle, is warming up to 80 DEG C and is stirred continuously, utilize azeotropic The moisture content that reaction generates is taken away until quaternized products are converted to corresponding potassium alcoholate.1.1 moles of carboxylating agent sodium chloroacetates are added In reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, twice with 15%NaCl brine washing reactions product, Product is converted to corresponding sodium salt with sodium hydrate aqueous solution.Reaction product is dissolved in a large amount of absolute ethyl alcohols, is filtered to remove Inorganic salts in product, vacuum distillation remove solvent and obtain anionic-cationic-nonionic surface active agent, embody It learns structure and is shown in Table the 3-5 in 3, nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 22】

15 moles of methyl laurates and 150 moles of ethylene diamine are added in reaction kettle and are warming up to 180 DEG C, after reacting 5 hours, 1- lauroyl ethylenediamines are purified using chromatographic technique, then by 12 moles of 1- lauroyls ethylenediamines and 1 mole of 1- chloro ten Dialkyl group, which is added in reaction kettle, is warming up to 80 DEG C, after reacting 5 hours, chromatographic technique is utilized to purify 1- lauroyl -4- dodecanes Base ethylenediamine.1 mole of 1- lauroyls -4- dodecyls ethylenediamine and 0.1 molar potassium hydroxide are added in reaction kettle and heated up It is decompressed to vacuum degree 0.9 to 80 DEG C, stirs 30 minutes and remove volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjusts Reacting kettle inner pressure is 0.2MPa.Temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure by 16 moles of epoxies third Alkane is added in reaction kettle, and 22 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure after 5 hours for reaction, reaction Etherification product is obtained after 5 hours, all etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added to reaction kettle In, 1.1 moles of quaternizing agent chloroethanes are added with the nitrogen of 0.8MPa pressure.3 are reacted after reaction system is warming up to 80 DEG C ~10 hours, extra quaternizing agent chloroethanes is removed under reduced pressure and etoh solvent obtains quaternized products.Then by 1 mole of season Ammonium product, 10 liters of solvent benzols and 1.1 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C and are stirred continuously, using altogether The moisture content that reaction generates is taken away in boiling until quaternized products are converted to corresponding potassium alcoholate.1.1 moles of carboxylating agent sodium chloroacetates are added Enter in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, with 15%NaI brine washing reactions product two It is secondary, product is converted to corresponding sylvite with potassium hydroxide aqueous solution.Reaction product is dissolved in a large amount of absolute ethyl alcohols, crosses and filters out The inorganic salts in product, vacuum distillation are gone to remove solvent and obtain anionic-cationic-nonionic surface active agent, it is specific Chemical constitution is shown in Table the 3-6 in 3, and nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 23】

20 moles of methyl laurates and 200 moles of diethylenetriamines are added in reaction kettle and are warming up to 180 DEG C, reaction 5 is small Shi Hou purifies 1- lauroyl diethylenetriamines, then by 2 moles of methyl laurates and 10 moles of 1- bays using chromatographic technique Acyl group diethylenetriamine, which is added in reaction kettle, is warming up to 180 DEG C, after reacting 5 hours, chromatographic technique is utilized to purify 1,7-, bis- bays Acyl group diethylenetriamine.1 mole of 1,7- dilauroyls diethylenetriamine and 0.1 molar potassium hydroxide are added in reaction kettle and risen Temperature is decompressed to vacuum degree 0.9 to 80 DEG C, stirs 30 minutes and removes volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjusts Section reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure by 16 moles of rings Ethylene Oxide is added in reaction kettle, and 37 moles of ethylene oxide are added in reaction kettle with the nitrogen of 0.8MPa pressure after 5 hours for reaction, Reaction obtains etherification product after 5 hours, and all etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added to instead It answers in kettle, 1.1 moles of quaternizing agent chloroethanes is added with the nitrogen of 0.8MPa pressure.It is anti-after reaction system is warming up to 80 DEG C It answers 3~10 hours, extra quaternizing agent chloroethanes is removed under reduced pressure and etoh solvent obtains quaternized products.Then 1 is rubbed You are added in reaction kettle quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxides, are warming up to 80 DEG C and are stirred continuously, profit The moisture content of reaction generation is taken away with azeotropic until quaternized products are converted to corresponding potassium alcoholate.By 1.1 moles of carboxylating agent monoxones Sodium is added in reaction kettle, and after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, is produced with 15%NaBr brine washing reactions Product is converted to corresponding ammonium salt by object twice, with ammonium hydroxide.Reaction product is dissolved in a large amount of absolute ethyl alcohols, product is filtered to remove In inorganic salts, vacuum distillation removes solvent and obtains anionic-cationic-nonionic surface active agent, specific chemistry knot Structure is shown in Table the 3-7 in 3, and nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 24】

30 moles of 1- chlorinated dodecanes and 300 moles of triethylene tetramines are added in reaction kettle and are warming up to 80 DEG C, reaction 5 is small Shi Hou purifies 1- lauryl triethylene tetramines, then by 2 moles of methyl laurates and 20 moles of 1- lauryls using chromatographic technique Triethylene tetramine, which is added in reaction kettle, is warming up to 180 DEG C, after reacting 5 hours, utilizes chromatographic technique purification 1- lauroyls -10- Lauryl triethylene tetramine.1 mole of 1- lauroyls -10- lauryls triethylene tetramine and potassium hydroxide are added in reaction kettle 80 DEG C are warming up to, vacuum degree 0.9 is decompressed to, stirs 30 minutes and removes volatile components, with gas 4 in nitrogen replacement reaction kettle Secondary, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure by 31 Mol propylenoxy is added in reaction kettle, and 9 moles of ethylene oxide, which are added, with the nitrogen of 0.8MPa pressure after 5 hours for reaction reacts In kettle, reaction 5 hours after obtain etherification product, all etherification products are dissolved in be configured in absolute ethyl alcohol 40% solution be added Into reaction kettle, 3.3 moles of quaternizing agent allyl chlorides are added with the nitrogen of 0.8MPa pressure.Reaction system is warming up to 80 It is reacted 3~10 hours after DEG C, extra quaternizing agent allyl chloride is removed under reduced pressure and etoh solvent obtains quaternized products.So 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxides are added in reaction kettle afterwards, are warming up to 80 DEG C constantly Stirring takes away the moisture content of reaction generation until quaternized products are converted to corresponding potassium alcoholate using azeotropic.By 3.3 moles of sulfonating agents 2- chloroethyl sodium sulfonates are added in reaction kettle, after reacting 5 hours, reactant are adjusted to acidity with hydrochloric acid, with 15%NaI brine Product is converted to corresponding calcium salt by washing reaction product twice, with calcium hydroxide aqueous solution.Reaction product is dissolved in a large amount of nothings In water-ethanol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-nonionic table Face activating agent, particular chemical are shown in Table the 3-8 in 3, and nuclear magnetic resonance spectroscopy is shown in Table 7.

【Embodiment 25】

2 moles of 1- chlorinated dodecanes and 20 moles of ethylene diamine are added in reaction kettle and are warming up to 80 DEG C, after reacting 5 hours, 1- lauryl ethylenediamines are purified using chromatographic technique.Then 1 mole of 1- lauryls ethylenediamine and 0.1 molar potassium hydroxide are added It is warming up to 80 DEG C in reaction kettle and is decompressed to vacuum degree 0.9, stirs 30 minutes and removes volatile components, in nitrogen replacement reaction kettle Gas 4 times, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure 23 mol propylenoxies are added in reaction kettle, reaction was added 19 moles of ethylene oxide with the nitrogen of 0.8MPa pressure after 5 hours Enter and obtain etherification product after being reacted 5 hours in reaction kettle, all etherification products are dissolved in be configured in absolute ethyl alcohol 40% it is molten Liquid is added in reaction kettle, and 3.3 moles of quaternizing agent chloroethanes are added with the nitrogen of 0.8MPa pressure.Reaction system is heated up It is reacted 3~10 hours after to 80 DEG C, extra quaternizing agent chloroethanes is removed under reduced pressure and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C not Disconnected stirring takes away the moisture content of reaction generation until quaternized products are converted to corresponding potassium alcoholate using azeotropic.By 3.3 moles of carboxylations Agent sodium chloroacetate is added in reaction kettle, and after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, is washed with 15%NaCl salt It washs reaction product twice, product is converted to corresponding sodium salt with sodium hydrate aqueous solution.Reaction product is dissolved in a large amount of anhydrous In ethyl alcohol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-non-ionic surface Activating agent, particular chemical are shown in Table the 4-1 in 4, and nuclear magnetic resonance spectroscopy is shown in Table 8.

【Embodiment 26】

2 moles of 1- chloro -9- octadecenes and 20 moles of ethylene diamine are added in reaction kettle and are warming up to 80 DEG C, reaction 5 is small Shi Hou purifies (9- octadecenes base) ethylenediamine using chromatographic technique.Then by 1 mole of (9- octadecenes base) ethylenediamine and It is warming up to 80 DEG C in 0.1 molar potassium hydroxide addition reaction kettle and is decompressed to vacuum degree 0.9, stirring removes volatile group in 30 minutes Point, with gas in nitrogen replacement reaction kettle 4 times, adjustings reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 11 mol propylenoxies are added in reaction kettle with the nitrogen of 0.8MPa pressure, the nitrogen of 0.8MPa pressure after reaction 5 hours 9 moles of ethylene oxide are added in reaction kettle to react 5 hours and obtain etherification product, all etherification products are dissolved in absolute ethyl alcohol It is configured to 40% solution to be added in reaction kettle, 2.2 moles of quaternizing agent allyls is added with the nitrogen of 0.8MPa pressure Chlorine.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra quaternizing agent allyl chloride and solvent is removed under reduced pressure Ethyl alcohol obtains quaternized products.Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxides are added anti- It answers in kettle, is warming up to 80 DEG C and is stirred continuously, take away the moisture content of reaction generation using azeotropic until quaternized products are converted to accordingly Potassium alcoholate.3.3 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, reactant is adjusted to acid with hydrochloric acid Property, twice with 15%NaI brine washing reactions product, product is converted to corresponding sylvite with potassium hydroxide aqueous solution.It will be anti- Product is answered to be dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anion-sun Ion-nonionic surface active agent, particular chemical are shown in Table the 4-2 in 4, and nuclear magnetic resonance spectroscopy is shown in Table 8.

【Embodiment 27】

2 moles of methyl laurates and 20 moles of ethylene diamine are added in reaction kettle and are warming up to 180 DEG C, after reacting 5 hours, profit Lauroyl ethylenediamine is purified with chromatographic technique.Then 1 mole of lauroyl ethylenediamine is added in reaction kettle and is warming up to 80 DEG C, It is decompressed to vacuum degree 0.9, stirs 30 minutes and remove volatile components, with gas in nitrogen replacement reaction kettle 4 times, adjust reaction kettle Interior pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, is added 1 mol propylenoxy with the nitrogen of 0.8MPa pressure Enter in reaction kettle, reaction 5 hours after obtain etherification product, all etherification products are dissolved in be configured in absolute ethyl alcohol 40% it is molten Liquid is added in reaction kettle, and 2.2 moles of quaternizing agent benzyl chlorides are added with the nitrogen of 0.8MPa pressure.Reaction system is heated up It is reacted 3~10 hours after to 80 DEG C, extra quaternizing agent benzyl chloride is removed under reduced pressure and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C not Disconnected stirring takes away the moisture content of reaction generation until quaternized products are converted to corresponding potassium alcoholate using azeotropic.By 2.2 moles of carboxylations Agent sodium chloroacetate is added in reaction kettle, and after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, is washed with 15%NaBr salt It washs reaction product twice, product is converted to corresponding ammonium salt with ammonium hydroxide.Reaction product is dissolved in a large amount of absolute ethyl alcohols, is filtered The inorganic salts in product are removed, vacuum distillation removes solvent and obtains anionic-cationic-nonionic surface active agent, has Body chemical constitution is shown in Table the 4-3 in 4, and nuclear magnetic resonance spectroscopy is shown in Table 8.

【Embodiment 28】

2 mole of oleic acid methyl esters and 20 moles of ethylene diamine are added in reaction kettle and are warming up to 80 DEG C, after reacting 5 hours, are utilized Chromatographic technique purifies 1- oleoyl ethylenediamines.Then 1 mole of 1- oleoyl base ethylenediamine and 0.1 molar potassium hydroxide are added anti- It answers and is warming up to 80 DEG C in kettle and is decompressed to vacuum degree 0.9, stir 30 minutes and remove volatile components, with gas in nitrogen replacement reaction kettle Body 4 times, adjusting reacting kettle inner pressure are 0.2MPa.The temperature of reaction system is risen to 220 DEG C, it will with the nitrogen of 0.8MPa pressure 47 mol propylenoxies are added in reaction kettle, and 32 moles of ethylene oxide are added with the nitrogen of 0.8MPa pressure after 5 hours for reaction It is reacted 5 hours in reaction kettle and obtains etherification product, all etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and adds Enter into reaction kettle, 1.1 moles of quaternizing agent chlorocyclohexanes are added with the nitrogen of 0.8MPa pressure.Reaction system is heated up Reacted 3~10 hours after to 80 DEG C, be removed under reduced pressure extra quaternizing agent chlorocyclohexane and etoh solvent obtain it is quaternized Product.Then 1 mole of quaternized products, 2010 liters of solvent benzols and 2.2 molar potassium hydroxides are added in reaction kettle, are warming up to 80 DEG C are stirred continuously, and take away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate.2.2 are rubbed You are added in reaction kettle carboxylating agent sodium chloroacetate, after reacting 5 hours, reactant are adjusted to acidity with hydrochloric acid, with 15%NaI salt Product is converted to corresponding sodium salt by water washing reaction product twice, with sodium hydrate aqueous solution.Reaction product is dissolved in largely In absolute ethyl alcohol, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains anionic-cationic-nonionic Surfactant, particular chemical are shown in Table the 4-4 in 4, and nuclear magnetic resonance spectroscopy is shown in Table 8.

【Embodiment 29】

2 moles of 1- chlorinated dodecanes and 20 moles of monoethanolamine are added in reaction kettle and are warming up to 180 DEG C, are reacted 5 hours Afterwards, N- lauryl monoethanolamine is purified using chromatographic technique.Then by 1 mole of N- lauryls monoethanolamine and 0.1 mole of hydrogen-oxygen Change in potassium addition reaction kettle and be warming up to 80 DEG C, be decompressed to vacuum degree 0.9, stirs 30 minutes and remove volatile components, set with nitrogen Change reaction gas reactor 4 times, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, uses 0.8MPa 41 mol propylenoxies are added in reaction kettle the nitrogen of pressure, and reaction uses the nitrogen of 0.8MPa pressure by 21 moles after 5 hours Ethylene oxide, which is added in reaction kettle to react 5 hours, obtains etherification product, and all etherification products are dissolved in absolute ethyl alcohol and are configured to 40% solution is added in reaction kettle, and 2.2 moles of quaternizing agent allyl chlorides are added with the nitrogen of 0.8MPa pressure.It will be anti- It is reacted 3~10 hours after answering system to be warming up to 80 DEG C, extra quaternizing agent allyl chloride is removed under reduced pressure and etoh solvent obtains To quaternized products.Then 1 mole of quaternized products, 20 liters of solvent benzols and 2.2 molar potassium hydroxides are added in reaction kettle, It is warming up to 80 DEG C to be stirred continuously, takes away the moisture content of reaction generation using azeotropic until quaternized products are converted to corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, reactant is adjusted to acidity with hydrochloric acid, are used Product is converted to corresponding magnesium salts by 15%NaCl brine washing reactions product twice, with magnesium hydroxide aqueous solution.Reaction is produced Object is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation remove solvent obtain anion-sun from Son-nonionic surface active agent, particular chemical are shown in Table the 4-5 in 4, and nuclear magnetic resonance spectroscopy is shown in Table 8.

【Embodiment 30】

2 moles of 1- chloro -9- octadecenes and 20 moles of monoethanolamine are added in reaction kettle and are warming up to 180 DEG C, reaction 5 After hour, N- octadecene base monoethanolamine is purified using chromatographic technique.Then by 1 mole of N- octadecene base monoethanolamine and 0.1 molar potassium hydroxide is added in reaction kettle and is warming up to 80 DEG C, is decompressed to vacuum degree 0.9, and stirring removes volatile group in 30 minutes Point, with gas in nitrogen replacement reaction kettle 4 times, adjustings reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 31 mol propylenoxies are added in reaction kettle with the nitrogen of 0.8MPa pressure, the nitrogen of 0.8MPa pressure is used in reaction after 5 hours Gas obtains etherification product after being reacted 5 hours in 11 moles of ethylene oxide addition reaction kettle, all etherification products is dissolved in anhydrous It is configured to 40% solution in ethyl alcohol to be added in reaction kettle, 2.2 moles of quaternizing agents are added with the nitrogen of 0.8MPa pressure Chlorocyclohexane.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra quaternizing agent chloro ring is removed under reduced pressure Hexane and etoh solvent obtain quaternized products.Then by 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 moles of hydrogen-oxygens Change potassium to be added in reaction kettle, be warming up to 80 DEG C and be stirred continuously, the moisture content of reaction generation is taken away until quaternized products using azeotropic It is converted to corresponding potassium alcoholate.2.2 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, will be reacted with hydrochloric acid Object is adjusted to acidity, twice with 15%NaBr brine washing reactions product, is converted to product accordingly with calcium hydroxide aqueous solution Sylvite.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, vacuum distillation removes solvent and obtains To anionic-cationic-nonionic surface active agent, particular chemical is shown in Table the 4-6 in 4, nuclear magnetic resonance spectroscopy It is shown in Table 8.

【Embodiment 31】

2 moles of methyl laurates and 20 moles of hydroxyethyl ethylenediamine are added in reaction kettle and are warming up to 180 DEG C, reaction 5 is small Shi Hou utilizes chromatographic technique purification N- lauroyls-N '-hydroxyethyl ethylenediamine.Then by 1 mole of N- lauroyl-N'- hydroxyl second Base ethylenediamine and 0.1 molar potassium hydroxide, which are added in reaction kettle, is warming up to 80 DEG C, is decompressed to vacuum degree 0.9, and stirring removes for 30 minutes Volatile components are removed, with gas in nitrogen replacement reaction kettle 4 times, adjusting reacting kettle inner pressure is 0.2MPa.By reaction system Temperature rises to 220 DEG C, 42 mol propylenoxies is added in reaction kettle with the nitrogen of 0.8MPa pressure, reaction is used after 5 hours The nitrogen of 0.8MPa pressure obtains etherification product after being reacted 5 hours in 17 moles of ethylene oxide addition reaction kettle, by all ethers Change product and be dissolved in and be configured to 40% solution in absolute ethyl alcohol and be added in reaction kettle, 2.2 are added with the nitrogen of 0.8MPa pressure Mole quaternizing agent chlorocyclohexane.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, extra season is removed under reduced pressure Ammonium reagent chlorocyclohexane and etoh solvent obtain quaternized products.Then by 1 mole of quaternized products, 20 liters of solvent benzols with And 2.2 molar potassium hydroxide be added reaction kettle in, be warming up to 80 DEG C and be stirred continuously, using azeotropic take away reaction generate moisture content it is straight It is converted to corresponding potassium alcoholate to quaternized products.2.2 moles of carboxylating agent sodium chloroacetates are added in reaction kettle, after reacting 5 hours, Reactant is adjusted to acidity with hydrochloric acid, twice with 15%NaI brine washing reactions product, with potassium hydroxide aqueous solution by product It is converted to corresponding sylvite.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product, is evaporated under reduced pressure It removes solvent and obtains anionic-cationic-nonionic surface active agent, particular chemical is shown in Table the 4-7 in 4, core Magnetic resonance hydrogen spectrum is shown in Table 8.

【Embodiment 32】

2 mole of oleic acid methyl esters and 20 moles of hydroxyethyl ethylenediamine are added in reaction kettle and are warming up to 180 DEG C, are reacted 5 hours Afterwards, chromatographic technique purification N- oleoyls-N '-hydroxyethyl ethylenediamine is utilized.Then by 1 mole of N- oleoyls-N '-ethoxy second two It is warming up to 80 DEG C in amine and 0.1 molar potassium hydroxide addition reaction kettle and is decompressed to vacuum degree 0.9, it is volatile to stir removing in 30 minutes Component, with gas in nitrogen replacement reaction kettle 4 times, adjusting reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, 2 mol propylenoxies being added in reaction kettle with the nitrogen of 0.8MPa pressure, reaction obtains etherification product after 5 hours, All etherification products are dissolved in and is configured to 40% solution in absolute ethyl alcohol and is added in reaction kettle, with the nitrogen of 0.8MPa pressure 2.2 moles of quaternizing agent chloromethanes are added.It is reacted 3~10 hours after reaction system is warming up to 80 DEG C, it is extra to be removed under reduced pressure Quaternizing agent chloromethanes and etoh solvent obtain quaternized products.Then by 1 mole of quaternized products, 10 liters of solvent benzols with And 2.2 molar potassium hydroxide be added reaction kettle in, be warming up to 80 DEG C and be stirred continuously, using azeotropic take away reaction generate moisture content it is straight It is converted to corresponding potassium alcoholate to quaternized products.2.2 moles of sulfonating agent chloromethylsulfonic acid sodium are added in reaction kettle, reaction 5 is small Reactant is adjusted to acidity by Shi Hou with hydrochloric acid, twice with 15%NaCl brine washing reactions product, uses sodium hydrate aqueous solution Product is converted to corresponding sodium salt.Reaction product is dissolved in a large amount of absolute ethyl alcohols, the inorganic salts being filtered to remove in product subtract Pressure is distilled off solvent and obtains anionic-cationic-nonionic surface active agent, and particular chemical is shown in Table the 4- in 4 8, nuclear magnetic resonance spectroscopy is shown in Table 8.

【Embodiment 33】

Anionic-cationic-nonionic surface active agent prepared by 0.30wt% embodiments 19 is gathered with 0.15wt% Acrylamide (molecular weight 26,000,000) aqueous solution is uniformly mixed, and obtains displacement composition used for tertiary oil recovery.

5 anionic-cationics of table-nonionic surface active agent nuclear magnetic resonance spectroscopy

6 anionic-cationics of table-nonionic surface active agent nuclear magnetic resonance spectroscopy

7 anionic-cationics of table-nonionic surface active agent nuclear magnetic resonance spectroscopy

8 anionic-cationics of table-nonionic surface active agent nuclear magnetic resonance spectroscopy

【Embodiment 34】Surfactant interface active testing

Surfactant and Shuanghe Oil Field IV5-11 series of strata greases circle are measured with TX-500C rotating interfacial tensimeters Face tension.Measuring temperature is 81 DEG C, water flooding NaHCO₃Type, salinity 7947mg/L, chloride ion content 2002mg/L, Ca² ⁺Content 20mg/L, Mg²⁺Content 12.2mg/L, dosage of surfactant 0.3wt%.

9 surfactant of table and the oil fields Shuan He IV5-11 series of strata oil water interfacial tensions

Embodiment is numbered	Interfacial tension (mN/m)
		1	0.01
2	0.02
		3	0.0006
4	0.0004
		5	0.0007
6	0.004
		7	0.0007
8	0.0006
		9	0.009
10	0.0009
		11	0.0004
12	0.0005
		13	0.0006
14	0.0007
		15	0.005
16	0.0007
		17	0.0004
18	0.005
		19	0.0003
20	0.006
		21	0.0007
22	0.0005
		23	0.0006
24	0.0007
		25	0.0006
26	0.0004
		27	0.04
28	0.0008
		29	0.0007
30	0.0006
		31	0.0005
32	0.08
		33	0.0003

As shown in Table 9, the surfactant other than 1,2,27,32 embodiments all has Henan Oil Field good Interfacial activity.After embodiment 33 shows that surfactant prepared by the present invention is compounded with polymer, interfacial activity is still good It is good.

Surfactant formulatory prepared by embodiment 33 is tested and Shuanghe Oil Field IV5-11 respectively at various concentration Series of strata oil water interfacial tension, the results are shown in Table 10.

10 various concentration surfactant 19 of table and Shuanghe Oil Field IV5-11 series of strata oil water interfacial tensions

Dosage of surfactant (wt%)	0.01	0.02	0.05	0.1	0.2	0.3
							Interfacial tension (MN/m)	0.006	0.003	0.0009	0.0004	0.0003	0.0003

The above results show that surfactant of the present invention has very high interfacial activity for Henan Oil Field crude oil.

The compound surfactant of embodiment 1-4 preparations is measured again in TX-500C rotating interfacial tensimeters Three factory's oil water interfacial tension of former oil extraction in oil field.Measuring temperature is 80 DEG C, formation water salinity 79439mg/L, Ca²⁺Content 592mg/L, Mg²⁺Content 2871mg/L, dosage of surfactant 0.3wt%.Oil water interfacial tension is 0.003mN/m, is shown The surfactant of the present invention still has good interface not only for low mineralization oil reservoir, simultaneously for high temperature and high salt oil deposit Activity has the advantages that the scope of application is wide.

【Embodiment 35】Surfactant washing oil aptitude tests

Shuanghe Oil Field IV5-11 series of strata oil-sands are taken, according to oil: sand=1: 4 (weight ratios) were in 81 DEG C of agings 7 days, every 2 Hour stirring 5 minutes；The oil-sand 5g after above-mentioned aging is then taken out, oil-sand: solution is pressed with the surfactant solution of 0.3wt% Weight ratio=1: 10 are uniformly mixed, and under reservoir temperature after aging 48 hours, with the crude oil in petroleum ether extraction solution, use 50ml Colorimetric cylinder constant volume, spectrophotometer colorimetric analysis at wavelength 430nm.Utilize standard curve gauging surface activator solution Central Plains Oil concentration.

11 surfactant washing oil result of table

Embodiment is numbered	Washing oil rate %
		1	39%
2	31%
		3	68%
4	77%
		5	66%
6	51%
		7	65%
8	67%
		9	49%
10	61%
		11	73%
12	71%
		13	66%
14	64%

15	49%
		16	65%
17	73%
		18	46%
19	81%
		20	48%
21	63%
		22	73%
23	67%
		24	66%
25	69%
		26	78%
27	28%
		28	60%
29	63%
		30	66%
31	74%
		32	25%
33	81%

【Embodiment 36】Surfactant flooding performance study

It it is 30 centimetres in length, a diameter of 2.5 centimetres, permeability is 1.5 microns²Rock core on carry out oil displacement test.First Oil-free is driven to Shuanghe Oil Field IV5-11 series of strata water floodings to generate, the surface-active of metaideophone 0.3PV (rock pore volume) After agent, then water drive to oil-free generates, and improves oil recovery factor and the results are shown in Table 7.

12 surfactant flooding test result of table

Embodiment is numbered	Improve recovery ratio %
		1	2.8%
2	2.5%
		3	4.9%
4	8.9%
		5	4.7%
6	4.1%
		7	5.5%
8	5.6%
		9	4.0%
10	5.0%
		11	7.5%
12	7.1%

13	6.7%
		14	6.4%
15	4.0%
		16	6.5%
17	7.1%
		18	4.2%
19	9.7%
		20	4.1%
21	6.4%
		22	7.0%
23	5.6%
		24	6.7%
25	6.9%
		26	9.0%
27	1.8%
		28	6.1%
29	6.5%
		30	6.8%
31	7.2%
		32	1.2%
33	10.9%

【Embodiment 37】The Journal of Sex Research steady in a long-term of surfactant

Surfactant in embodiment is configured to the molten of 0.3%wt with the double river IV5-11 series of strata water floodings of Henan Oil Field Liquid is positioned in constant temperature oven, after 81 DEG C of difference agings 1 day, 1 month, 2 months, 3 months from being taken out in insulating box solution Appearance and test the interfacial tension of solution.Measuring surfactant with TX-500C rotating interfacial tensimeters reduces Henan pair The ability of river oil field IV5-11 series of strata oil/water interfacial tensions.Measuring temperature is 81 DEG C, water flooding NaHCO₃Type, salinity are 7947mg/L, chloride ion content 2002mg/L, Ca²⁺Content 20mg/L, Mg²⁺Content 12.2mg/L the results are shown in Table 13, median surface The unit of tension is mN/m.

The long-term stable experiment result of 13 surfactant of table

Even can be seen that anionic-cationic-nonionic surfactant of the present invention according to these experimental datas At high temperature, also there is good dissolubility in water, and in situations where it is preferred, show excellent long-term interfacial activity Stability.

【Embodiment 38】The chromatography effect study of anionic-cationic-nonionic surfactant

Surfactant in embodiment is configured to the molten of 0.3%wt with the double river IV5-11 series of strata water floodings of Henan Oil Field Liquid.With double+70% quartz sand mixing filling thin tube models of river IV5-11 series of strata oil-sand of 30% Henan Oil Field, capillary inside diameter is 0.4cm, length are 4.5 meters.Following chromatography effect experiment has been carried out on mixed sand model：1) table that (1# experiments) injection is prepared Face activator solution 2PV；2) compound system (concentration of alkali of (2# experiments) injection surfactant solution+alkali：NaOH, 2000mg/L)；3) (3# experiments) first injects the formation water 1PV of 2000mg/l NaOH, reinject surfactant solution+ Compound system (the concentration of alkali of alkali：NaOH；2000mg/L), flow velocity is injected：0.2mL/min.In the compounding for injecting certain slug Water drive is carried out with the water flooding of same flow after system, collects efflux.With high performance liquid chromatography (HPLC) and total organic carbon point The variation that surfactant concentration is accumulated with injection liquid in analyzer (TOC) simultaneous determination efflux.If there is by separated Surface active agent composition calculates separately the rate of recovery of each surface active agent composition according to injection rate and quantum of output.Formula is as follows

If there is multiple surface active agent compositions, then using one of them as standard, other all components all with conduct The surfactant component of standard compares.Experimental result is shown in Table 14.

The chromatography effect experiment result of 14 anionic-cationics of table-nonionic surfactant

According to these experimental results it is found that anionic-cationic-nonionic surfactant of the present invention is not in color Compose segregation phenomenon.

【Comparative example 1】

According to Northwest University's journal (natural science edition) 2 months the 1st phases of volume 30 in 2000, the methods of 28~31 Gong Yu armies will Cetyl trimethylammonium bromide (CTAB) is configured to mixed system (molar ratio 1: 1.5) with lauryl sodium sulfate (SDS), point Do not test its in 0.3wt% dosages with Shuanghe Oil Field IV5-11 series of strata crude oil oil water interfacial tension, washing oil rate and the displacement of reservoir oil Performance is as a result as follows：

15 reference oil displacement agent performance of table

Interfacial tension (MN/m)	Washing oil rate % improves recovery ratio %
		0.03	45.62.8

【Comparative example 2】

According to petroleum gas journal in August, 2007 the 4th phase of volume 29, Huang Hong degree etc. (101~104) method etc. will 0.01wt% cetyl trimethylammonium bromides and 0.02wt% anion surfactants petroleum sulfonate and 1.8wt% Na₂CO₃Be configured to mixed system, test respectively its in 0.3wt% dosages with Shuanghe Oil Field IV5-11 series of strata crude oil greases Interfacial tension, washing oil rate and Oil Displacing Capacity, it is as a result as follows：

16 reference oil displacement agent performance of table

Interfacial tension (MN/m)	Washing oil rate %	Improve recovery ratio %
			0.008	56.3	4.2

Although the specific implementation mode of the present invention is described in detail above in conjunction with the embodiments, need to refer to Go out, the scope of protection of the present invention is not limited by these specific embodiments, but by claims of annex Lai It determines.Those skilled in the art can carry out these embodiments in the range of not departing from the technological thought and purport of the present invention Change appropriate, and the embodiment after these changes is obviously also included within protection scope of the present invention.

Claims

1. a kind of anionic-cationic-nonionic surface active agent, which is characterized in that selected from substantially such as following formula (I) is shown At least one of compound,

In formula (I), group N⁺It is quaternary nitrogen cation；Group R₁To R₃It is same or different to each other, is each independently selected from optional substitution C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkene Base, the C optionally replaced_6-50Aryl and by formulaThe group of representative, on condition that group R₁Extremely R₃At least one of be by formulaThe group of representative, it is so-called herein " optionally substitution ", refer to Be optionally by one or more selected from oxo, hydroxyl, by formulaThe group of representative, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl takes Generation；Group Rh is selected from the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally Substituted C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl；Group X^-Selected from halide ion and hydroxide ion (OH^-)；Group Link is selected from the x+1 valences C optionally replaced_1-50Linear or branched alkyl group, the x+1 valences C optionally replaced_5-50Monocycle or Polycyclic naphthene base, the x+1 valences C optionally replaced_2-50Linear chain or branched chain alkenyl, the x+1 valences C optionally replaced_6-50Aryl and optionally substitution X+1 valences C_3-50Linear chain or branched chain miscellaneous alkyl；Each group Poly is same or different to each other, and is each independently selected from formulaThe group of representative；Each group L is same or different to each other, and is each independently selected from optional substitution C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene；Each group Salt is mutually the same or not Together, it is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)； X is the arbitrary integer between 1 to 10；Between each group Poly, each numerical value y is same or different to each other, and is each independently selected from 0 Any number between to 200, on condition that the sum of x numerical value y is more than 0；Between each group Poly, each group Ru is mutually the same Or it is different, it is each independently selected from C_2-6Linear chain or branched chain alkylidene；Group M is selected from alkali metal, alkaline-earth metal and ammonium root (NH₄)； When group M is alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5,

Wherein, so-called " optionally substitution " in the case that especially specific, it refers to optionally being selected from oxygen by one or more Generation, hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Aryl Substituent group replaces, also, the linear chain or branched chain miscellaneous alkyl is selected from one or more inside linear or branched alkyl group molecular structure A group-CH₂By selected from-O- ,-S- ,-NR '-andOne of substituting group directly substitute and the group that obtains, Wherein group N⁺It is quaternary nitrogen cation；Group R ' is selected from the C optionally replaced_1-20Linear or branched alkyl group, the C optionally replaced_5-10It is single Ring or polycyclic naphthene base, the C optionally replaced_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-20Aryl；Group Rh is selected from optional Substituted C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Straight chain or branch Alkenyl and the C optionally replaced_6-50Aryl；Group X- is selected from halide ion and hydroxide ion (OH^-)；And linear chain or branched chain One or more groups of alkyl molecule inside configurationBy substituting group The group for directly substituting and obtaining, wherein group N⁺It is quaternary nitrogen cation；Group Rh is selected from the C optionally replaced_1-50Linear chain or branched chain Alkyl, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and optionally replace C_6-50Aryl；Group X^-Selected from halide ion and hydroxide ion (OH^-),

On condition that the group R₁, the group R₂, the group R₃In its structure at least one of the group Rh Including C₈Straight-chain part,

So-called " substantially as shown in formula (I) ", refers to the anionic-cationic-nonionic surface active agent, both as being somebody's turn to do As formula defines, contain group (M) simultaneously_r ⁺With group X^-, at least part group (M) can also be lost_r ⁺And/or group X^-, or do not contain group (M)_r ⁺And/or group X^-。

2. anionic-cationic-nonionic surface active agent described in claim 1, wherein x is arbitrary whole between 1 to 4 Number；Between each group Poly, each numerical value y is same or different to each other, any number being each independently selected between 0 to 100, On condition that the sum of x numerical value y is more than 0；Between each group Poly, each group Ru is same or different to each other, and selects each independently From-CH₂-CH₂And-CH₂-CH(CH₃)-；Group Link is selected from the x+1 valences C optionally replaced_1-20Linear or branched alkyl group optionally takes The x+1 valences C in generation_5-8Monocycle or polycyclic naphthene base, the x+1 valences C optionally replaced_2-20Linear chain or branched chain alkenyl, the x+1 optionally replaced Valence C_6-20Aryl and the x+1 valences C optionally replaced_3-20Linear chain or branched chain miscellaneous alkyl；The group L is same or different to each other, respectively solely On the spot it is selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene；The halide ion be fluorine ion, chlorion, bromide ion or Iodide ion；The C_1-20Linear or branched alkyl group is C_1-10Linear or branched alkyl group, the C_5-10Monocycle or polycyclic naphthene base are C_5-7Monocycle or polycyclic naphthene base, the C_2-20Linear chain or branched chain alkenyl is C_2-10Linear chain or branched chain alkenyl, the C_6-20Aryl is C_6-10Aryl.

3. anionic-cationic-nonionic surface active agent described in claim 1, wherein the C_1-50Linear chain or branched chain alkane Base is C_1-20Linear or branched alkyl group, the C_5-50Monocycle or polycyclic naphthene base are C_5-8Monocycle or polycyclic naphthene base, the C_2-50 Linear chain or branched chain alkenyl is C_2-20Linear chain or branched chain alkenyl, the C_6-50Aryl is C_6-20Aryl.

4. anionic-cationic-nonionic surface active agent described in claim 1, wherein each group Poly is respectively independent Ground is selected from formulaThe ether segment of representative；In each group Between Poly, each numerical value m is same or different to each other, any number being each independently selected between 0 to 100；In each group Between Poly, each numerical value n is same or different to each other, and any number being each independently selected between 0 to 100 is on condition that whole numbers The sum of value m and whole numerical value n are more than 0.

5. anionic-cationic-nonionic surface active agent described in claim 4, wherein between each group Poly, respectively Numerical value m is same or different to each other, any number being each independently selected between 0 to 50, and between each group Poly, respectively Numerical value n is same or different to each other, any number being each independently selected between 0 to 50, on condition that the sum of whole numerical value m are more than 0 and no more than 50 and/or the sum of whole numerical value n is more than 0 and is no more than 50.

6. anionic-cationic-nonionic surface active agent described in claim 1, selected from substantially such as following formula (I-1) institute The compound shown, substantially such as following formula (I-2) compound represented, substantially such as following formula (I-3) compound represented and basic Upper at least one of such as following formula (I-4) compound represented, and additional conditions are：In these molecular structure of compounds extremely A few N atom is bonded with other group Rh and group X and is rendered as formulaShown in quaternary ammonium salt and/or quaternary ammonium The form of alkali, wherein group N⁺It is the quaternary nitrogen cationic form of at least one N atoms；Group Rh, which is selected from, optionally to be replaced C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl The C optionally replaced_6-50Aryl；Group X^-Selected from halide ion and hydroxide ion (OH^-),

In formula (I-1), each group Ra is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-20Linear chain or branched chain Alkyl, the C optionally replaced_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-10Aryl；Each group Ra ' is same or different to each other, The C for being each independently selected from singly-bound, optionally replacing_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain Asia alkene Base, carbonyl, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl Base；B is the arbitrary integer between 1 to 3；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that working as base When group Y is N, a=1, when group Y is O, a=0, and at least one group Y is N；X ' is the arbitrary integer between 1 to 5； Each group Rp₁It is same or different to each other, is each independently selected from formulaGeneration The group of table, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally take The C in generation_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp₁It is formulaThe group of representative；Each group Rp₂It is mutually the same or not Together, it is each independently selected from formulaThe group of representative, Hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50 Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl；Each numerical value m ' is same or different to each other, be each independently selected from 0 to Any number between 100, each numerical value n ' are same or different to each other, any number being each independently selected between 0 to 100, Each numerical value m " is same or different to each other, any number being each independently selected between 0 to 100, each numerical value n " it is mutually the same or Difference, any number being each independently selected between 0 to 100, on condition that whole numerical value m ', whole numerical value m ", whole numerical value The sum of n ' and whole numerical value n " are more than 0 and are no more than 200；Each group L is same or different to each other, and is each independently selected from and optionally takes The C in generation_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene；Each group Salt it is mutually the same or Difference is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal, alkaline-earth metal and ammonium root (NH₄)；When group M is alkali metal or ammonium root, r=1；Work as group When M is alkaline-earth metal, r=0.5,

In formula (I-2), group Rb is selected from the C optionally replaced_1-49Linear or branched alkyl group, the C optionally replaced_5-49Monocycle is polycyclic Naphthenic base and the C optionally replaced_2-49Linear chain or branched chain alkenyl；Each group Rb ' is same or different to each other, and is each independently selected from list Key and carbonyl；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that when group Y is N, a=1, when When group Y is O, a=0, and at least one group Y is N；X " is the arbitrary integer between 1 to 10；Each group Rp₁Phase each other It is same or different, it is each independently selected from formula The group of representative, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally Substituted C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp₁It is formulaThe group of representative；Each group Rp₂It is mutually the same or Difference is each independently selected from formulaIt represents Group, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally substitution C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl；Each numerical value m ' is same or different to each other, and is each independently selected from Any number between 0 to 100, each numerical value n ' are same or different to each other, the arbitrary number being each independently selected between 0 to 100 Value, each numerical value m " are same or different to each other, any number being each independently selected between 0 to 100, and each numerical value n is " mutually the same Or different, any number being each independently selected between 0 to 100, on condition that whole numerical value m ', whole numerical value m ", whole numbers The sum of value n ' and whole numerical value n " are more than 0 and are no more than 200；Each group L is same or different to each other, and is each independently selected from optionally Substituted C_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10Linear chain or branched chain alkenylene；Each group Salt is mutually the same Or it is different, it is each independently selected from by-A^-(M)_r ⁺The group of representative, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal, alkaline-earth metal and ammonium root (NH₄)；When group M is alkali metal or ammonium root, r=1；Work as group When M is alkaline-earth metal, r=0.5,

In formula (I-3), each group Rc is same or different to each other, and is each independently selected from the C optionally replaced_1-20Linear chain or branched chain alkane Base, the C optionally replaced_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and optionally replace C_2-20Linear chain or branched chain alkenyl carbonyl；Each group Rd is same or different to each other, and is each independently selected from the C optionally replaced_1-10Straight chain Or branched alkylidene, the C that optionally replaces_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain alkylidene carbonyl Base, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and The carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl；X " ' is the arbitrary integer between 1 to 10；Each group Rp is each other It is identical or different, it is each independently selected from formulaIt represents Group, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally substitution C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp is formulaThe group of representative；Each numerical value m ' is mutually the same Or it is different, any number being each independently selected between 0 to 100, each numerical value n ' is same or different to each other, selects each independently Any number between from 0 to 100, on condition that the sum of whole numerical value m ' and whole numerical value n ' are more than 0 and are no more than 200；Each base Group L is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and the C optionally replaced_2-10 Linear chain or branched chain alkenylene；Each group Salt is same or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group of representative, Wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal, alkaline-earth metal and ammonium root (NH₄)；When When group M is alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5,

In formula (I-4), group Rc is selected from the C optionally replaced_1-20Linear or branched alkyl group, the C optionally replaced_2-20Linear chain or branched chain alkenyl, The C optionally replaced_1-20Linear or branched alkyl group carbonyl and the C optionally replaced_2-20Linear chain or branched chain alkenyl carbonyl；Each group Rd phases each other It is same or different, it is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain is sub- Alkenyl, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, optionally Substituted carbonyl C_1-10Linear chain or branched chain alkylenecarbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl；Base Group Y is N or O, on condition that when group Y is N, a=1, when group Y is O, a=0；X " " is the arbitrary integer between 1 to 9； Each group Rp₁It is same or different to each other, is each independently selected from formula The group of representative, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, optionally Substituted C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp₁It is formulaThe group of representative；Each group Rp₂It is mutually the same or not Together, it is each independently selected from formulaThe base of representative Group, hydrogen, the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base optionally replace C_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl；Each group Rp₃It is same or different to each other, is each independently selected from FormulaThe group of representative, hydrogen, the C optionally replaced_1-50Directly Chain or branched alkyl, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and optionally Substituted C_6-50Aryl；Each numerical value m ' is same or different to each other, any number being each independently selected between 0 to 100, each number Value n ' is same or different to each other, any number being each independently selected between 0 to 100, and each numerical value m " is same or different to each other, Any number being each independently selected between 0 to 100, each numerical value n " are same or different to each other, be each independently selected from 0 to Any number between 100, each numerical value m " ' are same or different to each other, any number being each independently selected between 0 to 100, Each numerical value n " ' is same or different to each other, any number being each independently selected between 0 to 100, on condition that whole numerical value m ', The sum of whole numerical value m ", whole numerical value m " ', whole numerical value n ', whole numerical value n " with whole numerical value n " ' are more than 0 and are no more than 200；Each group L is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and optionally Substituted C_2-10Linear chain or branched chain alkenylene；Each group Salt is same or different to each other, and is each independently selected from by-A^-(M)_r ⁺Generation The group of table, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M is selected from alkali metal, alkaline-earth metal and ammonium Root (NH₄)；When group M is alkali metal or ammonium root, r=1；When group M is alkaline-earth metal, r=0.5,

Wherein, the optional substitution refers to optionally by one or more selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10It is single Ring or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces,

So-called " substantially as shown in formula (I-1) ", refers to the anionic-cationic-nonionic surface active agent, both such as As the formula defines, contain group (M) simultaneously_r ⁺With group X^-, at least part group (M) can also be lost_r ⁺And/or base Group X^-, or do not contain group (M)_r ⁺And/or group X^-,

So-called " substantially as shown in formula (I-2) ", refers to the anionic-cationic-nonionic surface active agent, both such as As the formula defines, contain group (M) simultaneously_r ⁺With group X^-, at least part group (M) can also be lost_r ⁺And/or base Group X^-, or do not contain group (M)_r ⁺And/or group X^-,

So-called " substantially as shown in formula (I-3) ", refers to the anionic-cationic-nonionic surface active agent, both such as As the formula defines, contain group (M) simultaneously_r ⁺With group X^-, at least part group (M) can also be lost_r ⁺And/or base Group X^-, or do not contain group (M)_r ⁺And/or group X^-,

So-called " substantially as shown in formula (I-4) ", refers to the anionic-cationic-nonionic surface active agent, both such as As the formula defines, contain group (M) simultaneously_r ⁺With group X^-, at least part group (M) can also be lost_r ⁺And/or base Group X^-, or do not contain group (M)_r ⁺And/or group X^-。

7. anionic-cationic-nonionic surface active agent described in claim 6, wherein

In formula (I-1), each group Ra ' is same or different to each other, the C for being each independently selected from singly-bound and optionally replacing_1-6Straight chain or Branched alkylidene；B is 1；X ' is the arbitrary integer between 1 to 4；Each numerical value m ' is same or different to each other, and is each independently selected from 0 Any number between to 50, each numerical value n ' are same or different to each other, any number being each independently selected between 0 to 50, Each numerical value m " is same or different to each other, any number being each independently selected between 0 to 50, and each numerical value n " is mutually the same or not Together, any number being each independently selected between 0 to 50, on condition that whole numerical value m ', whole numerical value m ", whole numerical value n ' and The sum of whole numerical value n " are more than 0 and no more than 100,

In formula (I-2), group Rb is selected from the C optionally replaced_1-29Linear or branched alkyl group, the C optionally replaced_5-10Monocycle is polycyclic Naphthenic base and the C optionally replaced_2-29Linear chain or branched chain alkenyl, or selected from the C optionally replaced_8-29Linear or branched alkyl group, optionally Substituted C_5-8Monocycle or polycyclic naphthene base and the C optionally replaced_8-29Linear chain or branched chain alkenyl, or selected from the C optionally replaced_8-19 Linear or branched alkyl group, the C optionally replaced_5-7Monocyclic cycloalkyl and the C optionally replaced_8-19Linear chain or branched chain alkenyl；X " is 1 to 4 Between arbitrary integer；Each numerical value m ' is same or different to each other, any number being each independently selected between 0 to 50, each number Value n ' is same or different to each other, any number being each independently selected between 0 to 50, and each numerical value m " is same or different to each other, Any number being each independently selected between 0 to 50, each numerical value n " are same or different to each other, and are each independently selected from 0 to 50 Between any number, on condition that the sum of whole numerical value m ', whole numerical value m ", whole numerical value n ' and whole numerical value n " more than 0 and No more than 100,

In formula (I-3), each group Rc is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkane Base, the C optionally replaced_2-10Linear chain or branched chain alkenyl, the C optionally replaced_1-10Linear or branched alkyl group carbonyl and optionally replace C_2-10Linear chain or branched chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, optionally substitution C_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Straight chain or branch Alkenyl carbonyl；Each group Rd is same or different to each other, and is each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene The C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl；X " ' is the arbitrary integer between 1 to 4；Each numerical value m ' is mutually the same Or it is different, any number being each independently selected between 0 to 50, each numerical value n ' is same or different to each other, selects each independently Any number between from 0 to 50, on condition that the sum of whole numerical value m ' and whole numerical value n ' are more than 0 and no more than 100,

In formula (I-4), group Rc is selected from the C optionally replaced_1-10Linear or branched alkyl group, the C optionally replaced_2-10Linear chain or branched chain Alkenyl, the C optionally replaced_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenyl carbonyl, Huo Zhexuan From the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Straight chain Or branched alkyl carbonyl and the C that optionally replaces_8-20Linear chain or branched chain alkenyl carbonyl；Each group Rd is same or different to each other, respectively Independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl； X " " is the arbitrary integer between 1 to 3；Each numerical value m ' is same or different to each other, and is each independently selected from arbitrary between 0 to 50 Numerical value, each numerical value n ' are same or different to each other, any number being each independently selected between 0 to 50, each numerical value m " phases each other Same or different, any number being each independently selected between 0 to 50, each numerical value n " is same or different to each other, each independently Any number between 0 to 50, each numerical value m " ' are same or different to each other, and are each independently selected from arbitrary between 0 to 50 Numerical value, each numerical value n " ' are same or different to each other, any number being each independently selected between 0 to 50, on condition that whole numerical value The sum of m ', whole numerical value m ", whole numerical value m " ', whole numerical value n ', whole numerical value n " with whole numerical value n " ' are more than 0 and are no more than 100,

The halide ion is fluorine ion, chlorion, bromide ion or iodide ion,

The group L is same or different to each other, and is each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene,

The C_1-20Linear or branched alkyl group is C_1-10Linear or branched alkyl group, the C_5-10Monocycle or polycyclic naphthene base are C_5-7It is single Ring or polycyclic naphthene base, the C_2-20Linear chain or branched chain alkenyl is C_2-10Linear chain or branched chain alkenyl, the C_6-20Aryl is C_6-10Virtue Base.

8. anionic-cationic-nonionic surface active agent described in claim 6, wherein the C_1-50Linear chain or branched chain alkane Base is C_1-20Linear or branched alkyl group, the C_5-50Monocycle or polycyclic naphthene base are C_5-8Monocycle or polycyclic naphthene base, the C_2-50 Linear chain or branched chain alkenyl is C_2-20Linear chain or branched chain alkenyl, the C_6-50Aryl is C_6-20Aryl.

9. anionic-cationic-nonionic surface active agent described in claim 1, wherein the group X^-With the group (M)_r ⁺In at least part with (M)_r ⁺X^-Form independently of the anionic-cationic-nonionic surface active agent and In the presence of.

10. anionic-cationic-nonionic surface active agent described in claim 1, wherein the anion-sun from In the entire molecular structure of son-nonionic surface active agent, if the group X^-Total number be e1, the group N⁺It is total Number is e2, the group A^-Total number be e3, the group (M)_r ⁺Total number be e4, as e2=e3,0≤e1≤ E2,0≤e4≤e3, as e2 ＞ e3,0 ＜ e1≤e2,0≤e4≤e3, as e2 ＜ e3,0≤e1≤e2,0 ＜ e4≤e3, but On condition that e1+e3=e2+e4, alternatively, e2=e3, e1=0, e4=0.

11. a kind of manufacturing method of anionic-cationic-nonionic surface active agent, which is characterized in that including following step Suddenly：

Step (1)：Make one or more nitrogenous and is selected from-OH ,-NH with one or more₂It is multifunctional with the functional group of-NH- Compound is reacted with alkylene oxide shown in one or more following formulas (Y) in the presence of basic catalyst, and etherification product is obtained,

In formula (Y), group Ru ' is selected from C_2-6Linear chain or branched chain alkylidene,

Step (2)：So that the etherification product is reacted with quaternizing agent shown in following formula (A), thus to obtain cation-it is non-from Subtype surfactant, wherein the dosage of the quaternizing agent so that at least one of etherification product molecular structure N is former Son forms quaternary ammonium salt group,

Rh-X′ (A)

In formula (A), group Rh is selected from the C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic ring Alkyl, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl；Group X ' is selected from halogen,

On condition that at least one of the polyfunctional compound and the quaternizing agent include C in its molecular structure₈Straight chain Shape part,

Step (3)：Cation-the nonionic surface active agent is set to exist with one or more following formulas (Z) compound represented It is reacted in the presence of basic catalyst, thus to obtain anionic-cationic-nonionic surface active agent,

G-L-AS (Z)

In formula (Z), group G is selected from halogen and hydroxyl；Group L is selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene and optionally Substituted C_2-10Linear chain or branched chain alkenylene；Group AS is selected from by-A^-(M′)_r ⁺The group of representative；Group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-)；Group M ' is selected from hydrogen, alkali metal, alkaline-earth metal and ammonium root (NH₄)；When group M ' is hydrogen, alkali gold When category or ammonium root, r=1；When group M ' is alkaline-earth metal, r=0.5,

Optionally, step (4)：The anionic-cationic that the arbitrary steps of the manufacturing method are obtained-non-ionic surface is lived At least part quaternary ammonium salt group in property agent is converted to corresponding quaternary ammonium base groups, and/or, by the anionic-cationic- At least part quaternary ammonium base groups in nonionic surface active agent are converted to corresponding quaternary ammonium salt group,

Optionally, step (5)：The anionic-cationic obtained from the arbitrary steps of the manufacturing method-non-ionic surface is lived Property agent in isolate at least part existing compound (M ') in a free form_rX ',

Wherein, the optional substitution refers to optionally by one or more selected from hydroxyl, C_1-20Linear or branched alkyl group, C_5-10It is single Ring or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces.

12. the manufacturing method described in claim 11, wherein the basic catalyst is alkali metal hydroxide；The group Ru ' is selected from-CH₂-CH₂And-CH₂-CH(CH₃)-；The halogen is fluorine, chlorine, bromine or iodine；The group L is selected from optionally substitution C_1-5Linear chain or branched chain alkylidene；The C_1-20Linear or branched alkyl group is C_1-10Linear or branched alkyl group, the C_5-10Monocycle Or polycyclic naphthene base is C_5-7Monocycle or polycyclic naphthene base, the C_2-20Linear chain or branched chain alkenyl is C_2-10Linear chain or branched chain alkenyl, The C_6-20Aryl is C_6-10Aryl.

13. the manufacturing method described in claim 11, wherein the polyfunctional compound is in lower formula (X) compound represented At least one,

In formula (X), group R '₁To R '₃It is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50Straight chain or branch Alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl optionally replaces C_6-50Aryl and by formulaThe group of representative, on condition that group R '₁To R '₃At least one of be hydrogen Or by formulaThe group of representative, it is so-called herein " optionally substitution ", it refers to optionally one or more Selected from oxo, hydroxyl, by formulaGroup, the C of representative_1-20Linear or branched alkyl group, C_5-10Monocycle or Polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20The substituent group of aryl replaces；Group L_ASelected from the x0+1 valences optionally replaced C_1-50Linear or branched alkyl group, the x0+1 valences C optionally replaced_5-50Monocycle or polycyclic naphthene base, the x0+1 valences C optionally replaced_2-50Directly Chain or branched-chain alkenyl, the x0+1 valences C optionally replaced_6-50Aryl and the x0+1 valences C optionally replaced_3-50Linear chain or branched chain miscellaneous alkyl；x0 It is the arbitrary integer between 1 to 10；Each group Func is same or different to each other, and is each independently selected from-OH, ＞ NH and-NH₂, Also, the linear chain or branched chain miscellaneous alkyl is selected from one or more group-CH inside linear or branched alkyl group molecular structure₂- By selected from-O- ,-S- ,-NR '-andOne of substituting group directly substitute and the group that obtains, wherein group R ' Selected from the C optionally replaced_1-20Linear or branched alkyl group, the C optionally replaced_5-10Monocycle or polycyclic naphthene base, the C optionally replaced_2-20 Linear chain or branched chain alkenyl and the C optionally replaced_6-20Aryl；Group N⁺It is quaternary nitrogen cation；Group Rh is selected from the C optionally replaced_1-50 Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and appoint Choose the C in generation_6-50Aryl；Group X^-Selected from halide ion and hydroxide ion (OH^-)；And linear or branched alkyl group molecule knot One or more groups inside structureBy substituting groupDirectly substitute and The group of acquisition, wherein group N⁺It is quaternary nitrogen cation；Group Rh is selected from the C optionally replaced_1-50Linear or branched alkyl group, optionally Substituted C_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl；Base Group X^-Selected from halide ion and hydroxide ion (OH^-)。

14. the manufacturing method described in claim 13, wherein the C_1-20Linear or branched alkyl group is C_1-10Linear chain or branched chain alkane Base, the C_5-10Monocycle or polycyclic naphthene base are C_5-7Monocycle or polycyclic naphthene base, the C_2-20Linear chain or branched chain alkenyl is C_2-10 Linear chain or branched chain alkenyl, the C_6-20Aryl is C_6-10Aryl；The group L_ASelected from the x0+1 valences C optionally replaced_1-20Straight chain or Branched alkyl, the x0+1 valences C optionally replaced_5-8Monocycle or polycyclic naphthene base, the x0+1 valences C optionally replaced_2-20Linear chain or branched chain alkene Base, the x0+1 valences C optionally replaced_6-20Aryl and the x0+1 valences C optionally replaced_3-20Linear chain or branched chain miscellaneous alkyl；X0 is between 1 to 4 Arbitrary integer；The halide ion is fluorine ion, chlorion, bromide ion or iodide ion.

15. the manufacturing method described in claim 11 or 13, wherein the C_1-50Linear or branched alkyl group is C_1-20Linear chain or branched chain Alkyl, the C_5-50Monocycle or polycyclic naphthene base are C_5-8Monocycle or polycyclic naphthene base, the C_2-50Linear chain or branched chain alkenyl is C_2-20Linear chain or branched chain alkenyl, the C_6-50Aryl is C_6-20Aryl.

16. the manufacturing method described in claim 11, wherein the polyfunctional compound is selected from chemical combination shown in following formula (X-1) In object, following formula (X-2) compound represented, following formula (X-3) compound represented and following formula (X-4) compound represented at least One kind,

In formula (X-1), each group Ra is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-20Linear chain or branched chain Alkyl, the C optionally replaced_2-20Linear chain or branched chain alkenyl and the C optionally replaced_6-20Aryl；Each group Ra ' is same or different to each other, The C for being each independently selected from singly-bound, optionally replacing_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Linear chain or branched chain Asia alkene Base, carbonyl, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl Base；B is the arbitrary integer between 1 to 3；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that working as base When group Y is N, a1=1, when group Y is O, a1=0, and at least one group Y is N；X1 is arbitrary whole between 1 to 5 Number；Each group Rp '₁It is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50Linear or branched alkyl group, optionally Substituted C_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, it is preceding It is at least one group Rp ' to carry₁It is hydrogen；Each group Rp '₂It is same or different to each other, is each independently selected from hydrogen, optionally replaces C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl The C optionally replaced_6-50Aryl,

In formula (X-2), group Rb is selected from the C optionally replaced_1-49Linear or branched alkyl group, the C optionally replaced_5-49Monocycle is polycyclic Naphthenic base and the C optionally replaced_2-49Linear chain or branched chain alkenyl；Each group Rb ' is same or different to each other, and is each independently selected from list Key and carbonyl；Each group Y is same or different to each other, and is each independently selected from N and O, on condition that when group Y is N, a2=1, when When group Y is O, a2=0, and at least one group Y is N；X2 is the arbitrary integer between 1 to 10；Each group Rp '₁Each other C that is identical or different, being each independently selected from hydrogen, optionally replace_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or Polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp′₁It is hydrogen；Each group Rp '₂It is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50Linear chain or branched chain alkane Base, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50 Aryl,

In formula (X-3), each group Rc is same or different to each other, and is each independently selected from the C optionally replaced_1-20Linear chain or branched chain alkane Base, the C optionally replaced_2-20Linear chain or branched chain alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and optionally replace C_2-20Linear chain or branched chain alkenyl carbonyl；Each group Rd is same or different to each other, and is each independently selected from the C optionally replaced_1-10Straight chain Or branched alkylidene, the C that optionally replaces_2-10Linear chain or branched chain alkenylene, the C optionally replaced_1-10Linear chain or branched chain alkylidene carbonyl Base, the C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and The carbonyl C optionally replaced_2-10Linear chain or branched chain alkenylene carbonyl；X3 is the arbitrary integer between 1 to 10；Each group Rp ' is each other C that is identical or different, being each independently selected from hydrogen, optionally replace_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or Polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and the C optionally replaced_6-50Aryl, on condition that at least one group Rp ' is hydrogen,

In formula (X-4), group Rc is selected from the C optionally replaced_1-20Linear or branched alkyl group, the C optionally replaced_2-20Linear chain or branched chain Alkenyl, the C optionally replaced_1-20Linear or branched alkyl group carbonyl and the C optionally replaced_2-20Linear chain or branched chain alkenyl carbonyl；Each group Rd is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkylidene, the C optionally replaced_2-10Directly Chain or branched alkenylene, the C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl, the C optionally replaced_2-10Linear chain or branched chain Asia alkene Base carbonyl, the carbonyl C optionally replaced_1-10Linear chain or branched chain alkylenecarbonyl and the carbonyl C optionally replaced_2-10Linear chain or branched chain is sub- Alkenyl carbonyl；Group Y is N or O, on condition that when group Y is N, a4=1, when group Y is O, a4=0；X4 is between 1 to 9 Arbitrary integer；Each group Rp '₁It is same or different to each other, the C for being each independently selected from hydrogen, optionally replacing_1-50Linear chain or branched chain Alkyl, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Linear chain or branched chain alkenyl and optionally replace C_6-50Aryl, on condition that at least one group Rp '₁It is hydrogen；Each group Rp '₂Be same or different to each other, be each independently selected from hydrogen, The C optionally replaced_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Straight chain Or branched-chain alkenyl and the C that optionally replaces_6-50Aryl；Each group Rp '₃Be same or different to each other, be each independently selected from hydrogen, optionally Substituted C_1-50Linear or branched alkyl group, the C optionally replaced_5-50Monocycle or polycyclic naphthene base, the C optionally replaced_2-50Straight chain or branch Alkenyl and the C optionally replaced_6-50Aryl,

Wherein, so-called " optionally substitution " in the case that especially specific, it refers to optionally being selected from oxygen by one or more Generation, hydroxyl, C_1-20Linear or branched alkyl group, C_5-10Monocycle or polycyclic naphthene base, C_2-20Linear chain or branched chain alkenyl and C_6-20Aryl Substituent group replaces.

17. the manufacturing method described in claim 16, wherein

In formula (X-1), each group Ra ' is same or different to each other, the C for being each independently selected from singly-bound and optionally replacing_1-6Straight chain or Branched alkylidene；X1 is the arbitrary integer between 1 to 4,

In formula (X-2), group Rb is selected from the C optionally replaced_1-29Linear or branched alkyl group, the C optionally replaced_5-10Monocycle is polycyclic Naphthenic base and the C optionally replaced_2-29Linear chain or branched chain alkenyl, or selected from the C optionally replaced_8-29Linear or branched alkyl group, optionally Substituted C_5-8Monocycle or polycyclic naphthene base and the C optionally replaced_8-29Linear chain or branched chain alkenyl, or selected from the C optionally replaced_8-19 Linear or branched alkyl group, the C optionally replaced_5-7Monocyclic cycloalkyl and the C optionally replaced_8-19Linear chain or branched chain alkenyl；X2 is 1 to 4 Between arbitrary integer,

In formula (X-3), each group Rc is same or different to each other, and is each independently selected from the C optionally replaced_1-10Linear chain or branched chain alkane Base, the C optionally replaced_2-10Linear chain or branched chain alkenyl, the C optionally replaced_1-10Linear or branched alkyl group carbonyl and optionally replace C_2-10Linear chain or branched chain alkenyl carbonyl, or it is each independently selected from the C optionally replaced_8-20Linear or branched alkyl group, optionally substitution C_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Linear or branched alkyl group carbonyl and the C optionally replaced_8-20Straight chain or branch Alkenyl carbonyl；Each group Rd is same or different to each other, and is each independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene The C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl；X3 is the arbitrary integer between 1 to 4,

In formula (X-4), group Rc is selected from the C optionally replaced_1-10Linear or branched alkyl group, the C optionally replaced_2-10Linear chain or branched chain Alkenyl, the C optionally replaced_1-10Linear or branched alkyl group carbonyl and the C optionally replaced_2-10Linear chain or branched chain alkenyl carbonyl, Huo Zhexuan From the C optionally replaced_8-20Linear or branched alkyl group, the C optionally replaced_8-20Linear chain or branched chain alkenyl, the C optionally replaced_8-20Straight chain Or branched alkyl carbonyl and the C that optionally replaces_8-20Linear chain or branched chain alkenyl carbonyl；Each group Rd is same or different to each other, respectively Independently selected from the C optionally replaced_1-5Linear chain or branched chain alkylidene and the C optionally replaced_1-5Linear chain or branched chain alkylenecarbonyl；x4 It is the arbitrary integer between 1 to 3,

18. the manufacturing method described in claim 16, wherein the C_1-50Linear or branched alkyl group is C_1-20Linear chain or branched chain alkane Base, the C_5-50Monocycle or polycyclic naphthene base are C_5-8Monocycle or polycyclic naphthene base, the C_2-50Linear chain or branched chain alkenyl is C_2-20 Linear chain or branched chain alkenyl, the C_6-50Aryl is C_6-20Aryl.

19. the manufacturing method described in claim 11, wherein the polyfunctional compound and the molar ratio of the alkylene oxide are 1: 0-200, but do not include 0；The molar ratio of the polyfunctional compound and the formula (Z) compound represented is 1: 1-10；It is described The reaction condition of step (1) includes：Reaction temperature is room temperature to 300 DEG C, and the reaction time is 1-20 hours；The step (2) Reaction condition includes：Reaction temperature is 0-300 DEG C, and the reaction time is 1-20 hours；The reaction condition of the step (3) includes： Reaction temperature is 0-300 DEG C, and the reaction time is 1-20 hours.

20. the manufacturing method described in claim 11, wherein the polyfunctional compound and the molar ratio of the alkylene oxide are 1: 0-100, but do not include 0；The molar ratio of the polyfunctional compound and the formula (Z) compound represented is 1: 1-3；The step Suddenly the reaction condition of (1) includes：Reaction temperature is 100-200 DEG C, and the reaction time is 1-10 hours；The reaction of the step (2) Condition includes：Reaction temperature is 50-150 DEG C, and the reaction time is 4-15 hours；The reaction condition of the step (3) includes：Reaction Temperature is 50-200 DEG C, and the reaction time is 4-10 hours.

21. the manufacturing method described in claim 11 wherein the alkylene oxide includes at least propylene oxide, and makes more officials Energy compound is first reacted with the propylene oxide.

22. a kind of displacement composition used for tertiary oil recovery, which is characterized in that comprising claims 1 to 10 any one of them the moon from Son-cation-nonionic surface active agent or according to claim 11 to 21 any one of them manufacturing method manufacture Anionic-cationic-nonionic surface active agent, Yi Jishui, wherein with the gross weight of the displacement composition used for tertiary oil recovery Amount is that 100wt% is counted, and the weight percentage of the anionic-cationic-nonionic surface active agent is 0.001- 10wt%.

23. the displacement composition used for tertiary oil recovery described in claim 22, wherein with the displacement composition used for tertiary oil recovery Total weight is counted for 100wt%, and the weight percentage of the anionic-cationic-nonionic surface active agent is 0.02- 1wt%.

24. the displacement composition used for tertiary oil recovery described in claim 22, wherein not including inorganic base.

25. a kind of manufacturing method of displacement composition used for tertiary oil recovery, which is characterized in that make any one of claims 1 to 10 institute Anionic-cationic-nonionic surface active agent for stating or according to claim 11 to 21 any one of them manufacturer Anionic-cationic-nonionic surface active agent of method manufacture is at least mixed with water, wherein with the displacement of reservoir oil used for tertiary oil recovery The total weight of composition is counted for 100wt%, the weight percentage of the anionic-cationic-nonionic surface active agent For 0.001-10wt%.

26. the manufacturing method of the displacement composition used for tertiary oil recovery described in claim 25, wherein with the drive used for tertiary oil recovery The total weight of fluid composition is counted for 100wt%, and the weight percent of the anionic-cationic-nonionic surface active agent contains Amount is 0.02-1wt%.

27. a kind of tertiary oil recovery method, which is characterized in that including using 10 any one of them anion of claims 1 to 10-sun Ion-nonionic surface active agent, the anion-sun manufactured according to claim 11 to 21 any one of them manufacturing method Ion-nonionic surface active agent, claim 22 to 24 any one of them displacement composition used for tertiary oil recovery are pressed It is adopted three times as displacing fluid according to the displacement composition used for tertiary oil recovery of the manufacturing method manufacture described in claim 25 or 26 The step of oil.

28. the tertiary oil recovery method described in claim 27, wherein not using inorganic base.