CN105642185A - Anionic-cationic-nonionic surfactant, preparation method therefor and application of anionic-cationic-nonionic surfactant - Google Patents

Abstract

The invention relates to an anionic-cationic-nonionic surfactant which is substantially represented by a following formula (I) shown in the description, a preparation method therefor and an application of the anionic-cationic-nonionic surfactant. The anionic-cationic-nonionic surfactant disclosed by the invention shows remarkably-improved interfacial activity and stability compared with surfactants in the prior art. By using the anionic-cationic-nonionic surfactant disclosed by the invention, an oil displacement composition for tertiary oil recovery, which has improved oil displacement efficiency and oil washing capability compared with oil displacement compositions in the prior art, can be prepared. The formula (I) is as shown in the description, wherein each group is as defined in the description.

Description

A kind of anionic-cationic-nonionic surfactant, its manufacture method and application thereof

Technical field

The present invention relates to a kind of anionic-cationic-nonionic surfactant. Specifically, the present invention relates to and a kind of can be used for the anionic-cationic-nonionic surfactant of tertiary oil recovery, its manufacture method and the application in tertiary oil recovery thereof.

Background technology

Along with the increase of world energy sources demand, the rational exploitation and utilization of oil has caused the very big attention of people, and the yield of oil and the requirement of production efficiency is also more and more higher. The 1/3 of conventional oil production method (once with secondary method) normally only extraction oil in-place, there is also about the crude oil of 2/3 and fails extraction, therefore when energy day is becoming tight, improve tar productivity and become the key subjects of oil exploitation research.

Tertiary oil recovery technology is then a kind of method of effective raising tar productivity. Wherein, chemical displacement of reservoir oil technology is technology that is extremely important in tertiary oil recovery and that implement on a large scale, including polymer displacement of reservoir oil tech, surfactant flooding technology, caustic flooding technology etc. and polymer, alkali, surfactant multiple combination technology. The chemical displacement of reservoir oil is the common results of physical action and chemical action, and physical action make use of the effect that involves of displacing fluid, and chemical action then make use of the microcosmic oil drive effect of displacing fluid. The core of chemical action is the interfacial tension reducing displacing fluid with crude oil. Surfactant is owing to having oleophylic (hydrophobic) and hydrophilic (oleophobic) character concurrently, and when surfactant is dissolved in water, molecule is mainly distributed on oil-water interfaces, it is possible to significantly reduce oil water interfacial tension. The reduction of oil water interfacial tension means that surfactant system can overcome the cohesiveness between crude oil, and larger oil droplet is dispersed into little oil droplet, thus improving percent of pass when crude oil flows through pore throat. The effects such as the oil displacement efficiency of surfactant is also manifested by making the wettability of rock surface of oleophylic to reverse, emulsification of crude oil, raising surface charge density and oil droplet coalescence, this is the reason that surfactant can become in displacing fluid the component playing very important effect.

But, there is more problem in the displacing fluid used for tertiary oil recovery of prior art, mainly the interfacial activity of surface active agent composition is poor, cause that the oil displacement efficiency of displacing fluid being produced from is low, simultaneously because the system of displacing fluid is excessively complicated, thus Produced Liquid breakdown of emulsion is difficult, and sewage disposal difficulty is big;Owing to displacing fluid is containing inorganic base, injury is brought on stratum and oil well, causes the problem such as etching apparatus and pipeline, and owing to inorganic base can seriously reduce the viscosity of polymer, have to be greatly improved the working concentration of polymer for reaching required viscosity, make oil recovery integrated cost improve; The high temperature resistance of surface active agent composition, high salt tolerance, anti-high salinity limited in one's ability; Surface active agent composition is poor stability when composite, it is easy to produce precipitation.

Therefore, current present situation is, is still required for a kind of surfactant, and it can overcome the foregoing problems that prior art exists, and demonstrates the interfacial activity and stability compared with prior art improved.

Summary of the invention

The present inventor is on the basis of existing technology through diligent research, it is found that a kind of novel anionic-cationic-nonionic surfactant, and be further discovered that, by using this surfactant to manufacture displacement composition used for tertiary oil recovery (displacing fluid), just can solve the foregoing problems that prior art exists, and this completes the present invention.

Specifically, the present invention relates to the content of following aspect.

1. anionic-cationic-nonionic surfactant, it is characterised in that at least one in substantially compound as shown in following formula (I),

In formula (I), group N⁺It it is quaternary nitrogen cation; Group R₁To R₃It is same to each other or different to each other, is each independently selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted C_6-50(preferred C_6-20) aryl and by formulaThe group represented, premise is group R₁To R₃In at least one be by formulaThe group represented, so-called " optionally substituted " herein, refer to optionally by one or more selected from oxo, hydroxyl, by formulaThe group of representative, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X-is selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-); Group Link is selected from optionally substituted x+1 valency C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted x+1 valency C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted x+1 valency C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted x+1 valency C_6-50(preferred C_6-20) aryl and optionally substituted x+1 valency C_3-50(preferred C_3-20) the assorted alkyl of straight or branched; Each group Poly is same to each other or different to each other, and is each independently selected from formulaThe group represented; Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-);X is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Between each group Poly, each numerical value y is same to each other or different to each other, and is each independently selected from any number (preferably any number between 0 to 100) between 0 to 200, and premise is that x numerical value y sum is more than 0; Between each group Poly, each group Ru is same to each other or different to each other, and is each independently selected from C_2-6Straight or branched alkylidene (is preferably each independently selected from-CH₂-CH₂-and-CH₂-CH(CH₃)-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Wherein, when not clear and definite especially, so-called " optionally substituted ", refer to optionally by one or more selected from oxo, hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) substituent group of aryl replaces, and, the assorted alkyl of described straight or branched is selected from one or more group-CH of straight or branched alkyl molecule inside configuration₂-be selected from-O-,-S-,-NR '-(wherein, group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl) and(wherein, group N⁺It it is quaternary nitrogen cation; Group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) one of the group that substitutes directly substitute and the group that obtains; And one or more groups of straight or branched alkyl molecule inside configurationSubstituted groupOr(wherein, group N⁺It it is quaternary nitrogen cation; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) directly substitute and the group that obtains,

Premise is, described group R₁, described group R₂, described group R₃In its structure, C is comprised with at least one in described group Rh₈Straight-chain part.

2. anionic-cationic-the nonionic surfactant described in any preceding aspect, wherein each group Poly is each independently selected from formulaThe ether segment represented; Between each group Poly, each numerical value m is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50;Between each group Poly, each numerical value n is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50, and premise is whole numerical value m with whole numerical value n sums more than 0; Preferably, whole numerical value m sums more than 0 and less than 100 (preferably more than 50) and/or all numerical value n sum more than 0 and less than 100 (preferably more than 50).

3. anionic-cationic-the nonionic surfactant described in any preceding aspect, selected from substantially compound as shown in following formula (I-1), substantially compound as shown in following formula (I-2), substantially compound as shown in following formula (I-3) and the substantially at least one in compound as shown in following formula (I-4), and additional conditions are: at least one atom N in these molecular structure of compounds is bonded with other group Rh and group X and is rendered as formula(wherein, group N⁺It it is the quaternary nitrogen cationic form of at least one atom N described; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) shown in quaternary ammonium salt and/or the form of quaternary ammonium base,

In formula (I-1), each group Ra is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-10Aryl; Each group Ra ' is same to each other or different to each other, and is each independently selected from singly-bound, optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, carbonyl, optionally substituted C_1-10Straight or branched alkylenecarbonyl and optionally substituted C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from singly-bound and optionally substituted C_1-6Straight or branched alkylidene; B is the arbitrary integer between 1 to 3, it is preferable that 1; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a=1, when group Y is 0, and a=0, and at least one group Y is N; X ' is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 5; Each group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp₁It it is formulaThe group represented; Each group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ', whole numerical value m ", " sum is more than 0 and less than 200 (being preferably greater than 0 and less than 100) with whole numerical value n for whole numerical value n ',Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Ra and at least one in described group Rh comprise C in its structure₈Straight-chain part,

In formula (I-2), group Rb is selected from optionally substituted C_1-49Straight or branched alkyl, optionally substituted C_5-49Monocycle or polycyclic naphthene base and optionally substituted C_2-49Straight or branched thiazolinyl (is preferably selected from optionally substituted C_1-29Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base and optionally substituted C_2-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-29Straight or branched alkyl, optionally substituted C_5-8Monocycle or polycyclic naphthene base and optionally substituted C_8-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-19Straight or branched alkyl, optionally substituted C_5-7Monocyclic cycloalkyl (such as cyclohexyl) and optionally substituted C_8-19Straight or branched thiazolinyl); Each group Rb ' is same to each other or different to each other, and is each independently selected from singly-bound and carbonyl; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a=1, when group Y is O, and a=0, and at least one group Y is N; X " is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp₁It it is formulaThe group represented; Each group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ', whole numerical value m ", " sum is more than 0 and less than 200 (being preferably greater than 0 and less than 100) with whole numerical value n for whole numerical value n ', each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene);Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Rb and at least one in described group Rh comprise C in its structure₈Straight-chain part,

In formula (I-3), each group Rc is same to each other or different to each other, and is each independently selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl); Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); X " ' it is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp is same to each other or different to each other, and is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp is formulaThe group represented; Each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ' with whole numerical value n ' sums more than 0 and less than 200 (being preferably greater than 0 and less than 100); Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Rc and at least one in described group Rh comprise C in its structure₈Straight-chain part,

In formula (I-4), group Rc is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl);Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); Group Y is N or O, and premise is when group Y is N, a=1, when group Y is O, and a=0; X " " is arbitrary integer between 1 to 9 (the preferably arbitrary integer between 1 to 3, more preferably 1 or 2); Each group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp₁It it is formulaThe group represented; Each group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Each group Rp₃It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " ' be same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " ' be same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ', whole numerical value m ", whole numerical value m " ', whole numerical value n ', whole numerical value n " with whole numerical value n " ' sum is more than 0 and less than 200 (being preferably greater than 0 and less than 100), each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-);Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Rc and at least one in described group Rh comprise C in its structure₈Straight-chain part,

Wherein, described optionally substituted refer to optionally by one or more selected from hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace.

4. anionic-cationic-the nonionic surfactant described in any preceding aspect, wherein said group X^-With described group (M)_r ⁺In at least some of with (M)_r ⁺X^-Form exist independent of described anionic-cationic-nonionic surfactant, it is preferred that in the whole molecular structure of described anionic-cationic-nonionic surfactant, if described group X^-Total number be e1, described group N⁺Total number be e2, described group A^-Total number be e3, described group (M)_r ⁺Total number be e4, as e2=e3,0��e1��e2,0��e4��e3, as e2 > e3,0 < e1��e2,0��e4��e3, as e2 < e3,0��e1��e2,0 < e4��e3, but premise is e1+e3=e2+e4, or, e2=e3, e1=0, e4=0.

5. the manufacture method of anionic-cationic-nonionic surfactant, it is characterised in that comprise the following steps:

Step (1): make one or more nitrogenous and with one or more selected from-OH ,-NH₂React under the existence of base catalyst (preferred alkali metal hydroxide) with the alkylene oxide shown in one or more following formulas (Y) with the polyfunctional compound of the functional group of-NH-, it is thus achieved that etherification product,

In formula (Y), group Ru ' is selected from C_2-6Straight or branched alkylidene (is preferably selected from-CH₂-CH₂-and-CH₂-CH(CH₃)-),

Step (2): make described etherification product and the quaternizing agent shown in following formula (A) react, it is derived from cation-nonionic surfactant, the consumption of wherein said quaternizing agent makes at least one atom N in described etherification product molecular structure form quaternary ammonium salt group

Rh-X��(A)

In formula (A), group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X ' selected from halogen (preferred fluorine, chlorine, bromine and iodine, more preferably chlorine),

Premise is, described polyfunctional compound comprises C with at least one in described quaternizing agent in its molecular structure₈Straight-chain part,

Step (3): make described cation-nonionic surfactant and the compound shown in one or more following formulas (Z) react under the existence of base catalyst (preferred alkali metal hydroxide), it is derived from anionic-cationic-nonionic surfactant

G-L-AS(Z)

In formula (Z), group G is selected from halogen (preferred fluorine, chlorine, bromine and iodine, more preferably chlorine) and hydroxyl; Group L is selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably selected from optionally substituted C_1-5Straight or branched alkylidene); Group AS choosing freely-A^-(M��)_r ⁺The group represented; Group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-);Group M ' is selected from hydrogen, alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M ' be hydrogen, alkali metal or during ammonium root, r=1; When group M ' is for alkaline-earth metal, r=0.5,

Optionally, step (4): at least some of quaternary ammonium salt group in the anionic-cationic-nonionic surfactant obtained by the arbitrary steps of described manufacture method is converted to corresponding quaternary ammonium base group, and/or, at least some of quaternary ammonium base group in described anionic-cationic-nonionic surfactant is converted to corresponding quaternary ammonium salt group

Optionally, step (5): isolate the compound (M ') that at least some of (preferably whole) exist in a free form from anionic-cationic-nonionic surfactant that the arbitrary steps of described manufacture method obtains_rX ',

Wherein, described optionally substituted refer to optionally by one or more selected from hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace.

6. the manufacture method described in any preceding aspect, wherein said polyfunctional compound at least one in the compound shown in following formula (X),

In formula (X), group R '₁To R '₃It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted C_6-50(preferred C_6-20) aryl and by formulaThe group represented, premise is group R '₁To R '₃In at least one be hydrogen or by formulaThe group represented, so-called " optionally substituted " herein, refer to optionally by one or more selected from oxo, hydroxyl, by formulaThe group of representative, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace; Group LA is selected from optionally substituted x0+1 valency C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted x0+1 valency C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted x0+1 valency C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted x0+1 valency C_6-50(preferred C_6-20) aryl and optionally substituted x0+1 valency C_3-50(preferred C_3-20) the assorted alkyl of straight or branched; X0 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Func is same to each other or different to each other, and is each independently selected from-OH, > NH and-NH₂, and, the assorted alkyl of described straight or branched is selected from one or more group-CH of straight or branched alkyl molecule inside configuration₂-be selected from-O-,-S-,-NR '-(wherein, group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl) and(wherein, group N⁺It it is quaternary nitrogen cation; Group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl;Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) one of the group that substitutes directly substitute and the group that obtains; And one or more groups of straight or branched alkyl molecule inside configurationSubstituted groupOr(wherein, group N⁺It it is quaternary nitrogen cation; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) directly substitute and the group that obtains,

Described polyfunctional compound is preferably selected from the compound shown in the compound shown in the compound shown in following formula (X-1), following formula (X-2), following formula (X-3) and at least one in the compound shown in following formula (X-4)

In formula (X-1), each group Ra is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-20Aryl; Each group Ra ' is same to each other or different to each other, and is each independently selected from singly-bound, optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, carbonyl, optionally substituted C_1-10Straight or branched alkylenecarbonyl and optionally substituted C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from singly-bound and optionally substituted C_1-6Straight or branched alkylidene; B is the arbitrary integer between 1 to 3, it is preferable that 1; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a1=1, when group Y is O, and a1=0, and at least one group Y is N; X1 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 5; Each group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp '₁It is hydrogen; Each group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl,

In formula (X-2), group Rb is selected from optionally substituted C_1-49Straight or branched alkyl, optionally substituted C_5-49Monocycle or polycyclic naphthene base and optionally substituted C_2-49Straight or branched thiazolinyl (is preferably selected from optionally substituted C_1-29Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base and optionally substituted C_2-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-29Straight or branched alkyl, optionally substituted C_5-8Monocycle or polycyclic naphthene base and optionally substituted C_8-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-19Straight or branched alkyl, optionally substituted C_5-7Monocyclic cycloalkyl (such as cyclohexyl) and optionally substituted C_8-19Straight or branched thiazolinyl);Each group Rb ' is same to each other or different to each other, and is each independently selected from singly-bound and carbonyl; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a2=1, when group Y is O, and a2=0, and at least one group Y is N; X2 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp '₁It is hydrogen; Each group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl,

In formula (X-3), each group Rc is same to each other or different to each other, and is each independently selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl); Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); X3 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp ' is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp ' is hydrogen,

In formula (X-4), group Rc is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl);Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); Group Y is N or O, and premise is when group Y is N, a4=1, when group Y is O, and a4=0; X4 is arbitrary integer between 1 to 9 (the preferably arbitrary integer between 1 to 3, more preferably 1 or 2); Each group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp '₁It is hydrogen; Each group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Each group Rp '₃It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl,

Wherein, when not clear and definite especially, so-called " optionally substituted ", refer to optionally by one or more selected from oxo, hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace.

7. the mol ratio of the manufacture method described in any preceding aspect, wherein said polyfunctional compound and described alkylene oxide is 1: 0-200 (preferably 1: 0-100), but does not include 0; The mol ratio of described polyfunctional compound and the compound shown in described formula (Z) is 1: 1-10 (preferably 1: 1-3); The reaction condition of described step (1) including: reaction temperature be room temperature to 300 DEG C (preferred 100-200 DEG C), the response time is 1-20 hour (preferred 1-10 hour); The reaction condition of described step (2) including: reaction temperature is 0-300 DEG C (preferred 50-150 DEG C), and the response time is 1-20 hour (preferred 4-15 hour); The reaction condition of described step (3) including: reaction temperature is 0-300 DEG C (preferred 50-200 DEG C), and the response time is 1-20 hour (preferred 4-10 hour).

8. the manufacture method described in any preceding aspect, wherein said alkylene oxide at least includes expoxy propane, and makes described polyfunctional compound first and described propylene oxide reaction.

9. a displacement composition used for tertiary oil recovery, it is characterized in that, comprise the anionic-cationic-nonionic surfactant described in any preceding aspect or the anionic-cationic-nonionic surfactant of the manufacture of the manufacture method described in any preceding aspect, and water, wherein count with the gross weight of described displacement composition used for tertiary oil recovery for 100wt%, the weight percentage of described anionic-cationic-nonionic surfactant is 0.001-10wt%, preferred 0.005-5wt%, more preferably 0.02-1wt%.

10. the displacement composition used for tertiary oil recovery described in any preceding aspect, does not wherein comprise inorganic base.

11. the manufacture method of a displacement composition used for tertiary oil recovery, it is characterized in that, anionic-cationic-nonionic surfactant that the anionic-cationic-nonionic surfactant described in any preceding aspect or the manufacture method described in any preceding aspect manufacture is made at least to mix with water, wherein count with the gross weight of described displacement composition used for tertiary oil recovery for 100wt%, the weight percentage of described anionic-cationic-nonionic surfactant is 0.001-10wt%, preferred 0.005-5wt%, more preferably 0.02-1wt%.

12. a tertiary oil recovery method, it is characterized in that, carry out the step of tertiary oil recovery including the displacement composition used for tertiary oil recovery of the anionic-cationic-nonionic surfactant used described in any preceding aspect, the anionic-cationic-nonionic surfactant of manufacture method manufacture described in any preceding aspect, the displacement composition used for tertiary oil recovery described in any preceding aspect or the manufacture method manufacture described in any preceding aspect as displacing fluid.

13. the tertiary oil recovery method described in any preceding aspect, wherein do not use inorganic base.

Technique effect

Anionic-cationic-nonionic surfactant according to the present invention, it is shown that the interfacial activity compared with prior art significantly improved. Such as, remain to when the consumption of this surfactant is low to moderate 0.01��0.05wt% form 10 with underground crude oil^-3-10^-4MN/m ultralow interfacial tension.

Anionic-cationic-nonionic surfactant according to the present invention or displacement composition used for tertiary oil recovery, even at high temperature, water also is able to form stable and transparent aqueous solution, and in the preferred case, even across long-term (particularly at high temperature) storage, its chemical composition and interfacial activity also keep excellent stability.

Anionic-cationic-nonionic surfactant according to the present invention or displacement composition used for tertiary oil recovery, in use do not have chromatographic isolation phenomenon, and stability in use is excellent.

Displacement composition used for tertiary oil recovery according to the present invention, owing to employing the anionic-cationic-nonionic surfactant of the present invention as surface active agent composition, demonstrate the oil displacement efficiency compared with prior art improved and washing oil ability (such as can more than 40% to the washing oil rate of crude oil), it is possible to significantly improve oil recovery factor.

Displacement composition used for tertiary oil recovery according to the present invention, system is simple, without there being inorganic base, stratum and oil well are not injured, it is to avoid the corrosion of equipment and pipeline, and does not result in breakdown of emulsion difficulty.

Detailed description of the invention

Below the specific embodiment of the present invention is described in detail, it should be noted however that protection scope of the present invention is not limited to these specific embodiments, but is determined by claims of annex.

All publications, patent application, patent and other list of references that this specification is mentioned all draw in this for reference. Unless otherwise defined, all technology used by this specification and scientific terminology all have the implication that those skilled in the art's routine is understood. In case of conflict, it is as the criterion with the definition of this specification.

When this specification comes derived materials, material, method, step, device or parts etc. with prefix " as well known to those skilled in the art ", " prior art " or its similar term, the object that this prefix is derived contains commonly used in the art those when the application proposes, but also include also being of little use at present, but will become art-recognized for suitable in those of similar purpose.

In the context of the present specification, except the content clearly stated, anything not mentioning should or item all directly be suitable for known in the art those without carrying out any change.And, any embodiment described herein all freely can combine with one or more other embodiments described herein, the technical scheme formed therefrom or technological thought are accordingly to be regarded as that the present invention is original open or a part for original description, and be not considered as the new content not disclosing herein or expecting, unless those skilled in the art think that this combination is substantially irrational.

In the context of the present invention, statement " halogen " refers to fluorine, chlorine, bromine or iodine.

In the context of the present invention, so-called " the assorted alkyl of straight or branched ", refers to one or more (such as 1 to 4,1 to 3,1 to 2 or 1) group-CH of straight or branched alkyl molecule inside configuration (not including the end of main chain or any side chain in this alkyl molecule structure)₂-be selected from-O-,-S-,-NR '-andOne of the group that substitutes directly substitute and one or more (such as 1 to 3,1 to 2 or 1) group of the group that obtains or straight or branched alkyl molecule inside configuration (not including the end of main chain or any side chain in this alkyl molecule structure)Substituted groupOrThe group directly substituted and obtain. As described replacement group, it is preferable that-NR '-orMore preferably-NR '-. At this, group R ' is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-20Aryl. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, specifically such as methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl. As described group R ', it is preferable that C_1-20Straight or branched alkyl or C_5-7Monocyclic cycloalkyl, specifically such as methyl, ethyl or cyclohexyl. Group N⁺It it is quaternary nitrogen cation. Group Rh is selected from optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. In the definition of group Rh, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. Group X^-Selected from halide ion (including fluorion, chloride ion, bromide ion and iodide ion) and hydroxide ion (0H^-), wherein preferred halide ion, more preferably chloride ion.This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl. It is apparent that from the angle of structural stability, when existing multiple, these substitute between groups not Direct Bonding. Although it addition, the carbon number of this straight or branched alkyl is because of group-CH₂-or groupReduced accordingly by replacement, but in order to state simplicity, still refer to the carbon number of the assorted alkyl of described straight or branched instead of the carbon number of front described straight or branched alkyl with this. As the assorted alkyl of described straight or branched, concrete example, C₄Straight chained alkyl is such as(in formula, the group indicated by arrow is not in inside molecular structure, and is in the end of main chain) is substituted group-O-by one and directly substitutes acquisition-CH₂-O-CH₂-CH₃Or-CH₂-CH₂-O-CH₃, it is referred to as C₄Linear heteroalkyl group. Or, C₄Branched alkyl is such as(in formula, the group indicated by arrow is not in inside molecular structure, and is in the end of main chain and side chain) is substituted group by oneDirectly substitute and will obtainIt is referred to as C₄Branched heteroalkyl groups. According to the present invention, as the assorted alkyl of described straight or branched, C such as can be enumerated_3-50The assorted alkyl of straight or branched, specifically such as C_8-50The assorted alkyl of straight or branched, C_8-30The assorted alkyl of straight or branched or C_8-20The assorted alkyl of straight or branched, or C_3-20The assorted alkyl of straight or branched, C_3-10The assorted alkyl of straight or branched or C_3-6The assorted alkyl of straight or branched.

In the context of the present specification, expression way " numeral+valency+group " or its similar term refer to the group obtained after removing the hydrogen atom of the quantity representated by this numeral the base structure (such as chain, ring or its combination etc.) corresponding to this group, it is preferable that refer to the group obtained after removing the hydrogen atom of the quantity representated by this numeral from the carbon atom (preferred saturated carbon atom and/or non-same carbon atom) contained by this structure. For example, " 3 valency straight or branched alkyl " refers to the group removing 3 hydrogen atoms from this straight or branched alkane (i.e. basic chain corresponding to this straight or branched alkyl) and obtain, " the assorted alkyl of divalent straight or branched " then refers to from the assorted alkane of this straight or branched (preferably from the carbon atom contained by this assorted alkane, or further, from non-same carbon atom) remove 2 hydrogen atoms and the group that obtains. Obviously, expression way " 0 valency+group " represents described base structure, and such as 0 valency alkyl refers to alkane.

In the context of the present specification, what is called " comprises C in structure₈Straight-chain part ", refer to involved compound or group comprises the structure fragment that (such as one or more) are bonded by straight chain mode in succession by 8 carbon atoms in the chemical constitution of its entirety.Depending on being specifically defined or replacement situation of described chemical constitution, these 8 carbon atoms can be rendered as replacement state or unsubstituted state independently of one another. And, this C₈Straight-chain part may be at the inside (such as constituting the main chain of this chemical constitution) of described chemical constitution, the end (such as constituting end group or the side chain of this chemical constitution) of described chemical constitution can also be in, be not particularly limited. Concrete example, if group R1 (as mentioned below) comprises C in its structure₈Straight-chain part, if setting this group R₁It is optionally substituted C₁₀Straight or branched alkyl, then this group R₁It is probably-CH₂-CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH₂-CH₃��

-CH₂-CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH(CH ₃ )-CH₃��

-CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH(CH ₃ )-CH(CH ₃ )-CH₃��

-CH ₂ -CH(OH)-CH ₂ -CH ₂ -CH ₂ -CH(CH ₃ )-CH(CH ₃ )-CH₃��

-CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -C(OH)(CH ₃ )-CH(CH ₃ )-CH₃��

-CH ₂ -CH ₂ -C (=O)-CH ₂ -CH ₂ -CH(CH ₃ )-CH(CH ₃ )-CH₃Or

-CH ₂ -CH(CH ₃ )-CH ₂ -C (=O)-CH ₂ -CH ₂ -CH(CH ₃ )-CH₃(in these alkyl, shown in each underscore, it is described C by 8 carbon atoms by the structure fragment that straight chain mode is bonded in succession₈Straight-chain part) etc., but cannot be

-CH(CH₃)-CH₂-CH₂-CH₂-CH(CH₃)-CH(CH₃)-CH₃Or

-CH(CH₂CH₂CH₂CH₃)-CH(CH₃)-CH(CH₃)-CH₃Deng (being absent from the structure fragment being in succession bonded by 8 carbon atoms by straight chain mode). As shown in this example, if this group R₁Its structure comprises C₈Straight-chain is partly as a part (fragment) for its structure, and to this C₈Straight-chain part location does not limit, it may be possible to main chain, end group or side chain, and does not obviously also limit described group R₁Only it is made up of or this C 8 carbon atoms₈Straight-chain part is merely presented as-CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -CH ₂ -��

When not clearly indicating, all percents of being previously mentioned in this specification, number, ratio etc. are all with weight for benchmark, unless do not met the conventional understanding of those skilled in the art during with weight for benchmark.

According to the present invention, relating to a kind of anionic-cationic-nonionic surfactant, this anionic-cationic-nonionic surfactant is substantially compound as shown in following formula (I). Compound shown in this formula (I) can only use one, it is also possible to two or more combine use.

According to the present invention, in formula (I), group N⁺It is quaternary nitrogen cation, so that quaternary ammonium type compound should be become the compound shown in (I).

According to the present invention, in formula (I), group R₁To R₃It is same to each other or different to each other, is each independently selected from optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl, optionally substituted C_6-50Aryl and by formulaThe group represented. At this, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from oxo (namely), hydroxyl, by formulaThe group of representative, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I), it is desirable to group R₁To R₃In at least one (such as at most two) be by formulaThe group represented.

According to the present invention, in formula (I), group Rh is selected from optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl.

According to the present invention, in formula (I), at group Rh and group R₁To R₃Definition in, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I), group X^-Selected from halide ion (including fluorion, chloride ion, bromide ion and iodide ion) and hydroxide ion (OH^-), wherein preferred halide ion, more preferably chloride ion.

According to the present invention, in formula (I), by formulaIn the group represented, group Link is selected from optionally substituted x+1 valency C_1-50Straight or branched alkyl, optionally substituted x+1 valency C_5-50Monocycle or polycyclic naphthene base, optionally substituted x+1 valency C_2-50Straight or branched thiazolinyl, optionally substituted x+1 valency C_6-50Aryl and optionally substituted x+1 valency C_3-50The assorted alkyl of straight or branched. As described optionally substituted x+1 valency C_1-50Straight or branched alkyl, it is preferable that optionally substituted x+1 valency C_1-20Straight or branched alkyl. As described optionally substituted x+1 valency C_5-50Monocycle or polycyclic naphthene base, such as can enumerate optionally substituted x+1 valency C_5-10Monocycle or polycyclic naphthene base, optionally substituted x+1 valency C_5-8Monocycle or polycyclic naphthene base or optionally substituted x+1 valency C_5-7Monocycle or polycyclic naphthene base, especially optionally substituted x+1 valency C_5-7Monocyclic cycloalkyl, such as cyclohexyl. As described optionally substituted x+1 valency C_2-50Straight or branched thiazolinyl, it is preferable that optionally substituted x+1 valency C_2-20Straight or branched thiazolinyl. As described optionally substituted x+1 valency C_6-50Aryl, it is preferable that optionally substituted x+1 valency C_6-20Aryl, such as phenyl or naphthyl. The x+1 valency C optionally replaced_3-50The assorted alkyl of straight or branched, it is preferable that optionally substituted x+1 valency C_3-20The assorted alkyl of straight or branched.

According to the present invention, in formula (I), by formulaIn the group represented, each group Poly is same to each other or different to each other, and is formula independently of one anotherThe group represented.

According to the present invention, in formula (I), by formulaIn the group represented, between each group Poly, each numerical value y is same to each other or different to each other, and is each independently selected from any number between 0 to 200, it is preferable that any number between 0 to 100. Now, described numerical value y represents unit-O-Ru-in formulaAverage number in the group represented, therefore can be non-integer. As described numerical value y, can be such as 0,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I), it is desirable to x numerical value y sum is (namely by formulaIn the overall molecule structure of the compound shown in the group represented or formula (I), the population mean number of unit-O-Ru-) more than 0, but it is usually no more than 200, it is preferable that less than 100. In consideration of it, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, it is necessary to containing (a number of) unit-O-Ru-, so that the compound shown in formula (I) is rendered as non-ionic nature. Now, by formulaIn the overall molecule structure of the group represented or in the overall molecule structure of the compound shown in formula (I), as the population mean number of described unit-O-Ru-, can be such as 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I), between each group Poly, each group Ru is same to each other or different to each other, and is each independently selected from C_2-6Straight or branched alkylidene, it is preferable that-CH₂-CH₂-��-CH₂-CH(CH₃)-or its combination, especially-CH₂-CH(CH₃)-or-CH₂-CH(CH₃)-and other C_2-6The combination of straight or branched alkylidene.

According to the present invention, in formula (I), in formulaIn the group represented, when group Ru is selected from C_2-6During two or more in straight or branched alkylidene, respectively between (different) unit-O-Ru-can according to random, (two or many) block or alternately etc. mode be mutually bonded with the ratio arbitrarily determined as required, but the population mean number of these unit is y. For example, when group Ru is-CH₂-CH₂-and-CH₂-CH(CH₃)-combination, and when y is 2.2, unit-O-CH₂-CH₂-and unitBetween can according to (two or many) block, alternately or the any-mode such as random be mutually bonded with the ratio (such as mol ratio therebetween can for 1: 99 to 99: 1) arbitrarily determined as required, but the population mean number of both unit is 2.2.

According to the present invention, there is one or more group Poly, it is preferred that at least one group Poly (preferably all of group Poly), the group Ru of at least some of (at least one determined number) is selected from C_3-6Straight or branched alkylidene is (corresponding to non-O-CH₂-CH₂-unit), wherein preferred-CH₂-CH(CH₃)-(is corresponding to unit), so that this group Poly preferably comprises, (some, its upper limit is y) non-O-CH₂-CH₂-unit (such as unit) as Component units.

According to an embodiment of the invention, in formula (I), each group Poly is independently of one another or (two blocks) ether segment of representing selected from following formula (I-A) of at least one of which group Poly. Now, as shown in formula (I-A), unit-O-CH₂-CH₂-and unitBetween be bonded according to the mode of (two) block.

This embodiment according to the present invention, it is preferred that described ether segment is bonded in such a way with group Link.

This embodiment according to the present invention, between each group Poly (or in this group Poly), each numerical value m is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m represents unitAverage number in formula (I-A), therefore can be non-integer. As described numerical value m, can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

This embodiment according to the present invention, between each group Poly (or in this group Poly), each numerical value n is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n represents unitAverage number in formula (I-A), therefore can be non-integer. As described numerical value n, can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

This embodiment according to the present invention, in formula (I) or by formulaIn the group represented, it is preferred that when x group Poly is all each independently selected from (two blocks) ether segment that formula (I-A) represents, x numerical value m sum is (namely at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, unitPopulation mean number) more than 0, but be usually no more than 100, it is preferable that less than 50. In consideration of it, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, it is preferable that containing (a number of) unitNow, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, as described unitPopulation mean number, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

This embodiment according to the present invention, in formula (I) or by formulaIn the group represented, it is preferred that when x group Poly is all each independently selected from (two blocks) ether segment that formula (I-A) represents, x numerical value n sum is (namely at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, unit-O-CH₂-CH₂-population mean number) less than 100, it is preferable that less than 50. In consideration of it, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, optional containing (a number of) unit-O-CH₂-CH₂-. Now, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, as described unit-O-CH₂-CH₂-population mean number, can be such as 0,0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 49.5 etc.

This embodiment according to the present invention, it is preferred that in formula (I) or by formulaIn the group represented, when x group Poly is all each independently selected from (two blocks) ether segment that formula (I-A) represents, x numerical value n sum is (namely at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, unit-O-CH₂-CH₂-population mean number) more than 0. In consideration of it, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, it is preferable that containing (a number of) unit-O-CH₂-CH₂-. Now, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, as described unit-O-CH₂-CH₂-population mean number, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

This embodiment according to the present invention, it is preferred that in formula (I) or by formulaIn the group represented, when x group Poly is all each independently selected from (two blocks) ether segment that formula (I-A) represents, x numerical value n sum is (namely at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, unit-O-CH₂-CH₂-population mean number) with x numerical value m sum (namely at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, unitPopulation mean number) summation more than 0, but be usually no more than 200, it is preferable that less than 100.In consideration of it, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, it is preferable that containing (a number of) unit-O-CH₂-CH₂-and/orNow, at the compound shown in formula (I) or by formulaIn the overall molecule structure of the group represented, as the population mean number of these unit, can be such as 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I), by formulaIn the group represented, each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene.

According to the present invention, in formula (I), by formulaIn the group represented, each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5.

According to an embodiment of the invention, in formula (I), by formulaIn the group represented, depend on the number of group Salt, group A^-It can be one, it is also possible to be x, it is preferable that at least one of which group A^-It is carboxylate radical (COO^-). In consideration of it, in the overall molecule structure of the compound shown in formula (I), it is preferable that there is at least one carboxylate radical (COO^-)��

According to the present invention, in formula (I), by formulaIn the group represented, x+1 represents the valence state value of group Link. Now, x is the arbitrary integer between 1 to 10, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (I), it is desirable to described group R₁, described group R₂, described group R₃(one or more) C must be comprised in its structure with at least one in described group Rh₈Straight-chain part, so that the anionic-cationic-nonionic surfactant of the present invention shows intended surface-active property.

According to the present invention, in formula (I), under there is no other clearly defined situations, so-called optionally substituted, refer to optionally by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1) selected from oxo (namely), hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I), when there is oxo alternatively base, an oxo substituent is preferably at least had to be positioned at atom N (if any, the assorted alkyl of such as straight or branched is likely to the atom N comprised) on the carbon atom of Direct Bonding, make described carbon atom be rendered as carbonyl (namely) form, in the molecular structure of the compound shown in formula (I), thus introduce the structure (such as acylimino) of carbonyl and atom N Direct Bonding.Additionally, in order to obtain better stability to hydrolysis resistance or chemical stability, preferably, at least partially (preferably whole) and the carbon atom of O or S atom (if any) Direct Bonding are absent from this oxo substituent, and/or, (preferably whole) are on the carbon atom of the end of the chain (refer to the free end of strand and/or treat the end with other atomic linkages) position and are absent from this oxo substituent at least partially, and/or, replaced by oxo during the carbon atom difference of two Direct Bonding. By so, it is possible to avoid introducing the chemical activity such as ester group or aldehyde radical or unstable group in the molecular structure of the compound shown in formula (I). Concrete example, group Link is the divalent straight chained alkyl replaced by 1 oxo substituentTime (it includes two carbon atoms being in chain end position, in formula shown in arrow), then according to aforementioned principle, this group Link is such as preferablyOrDeng. Or, group Link is the divalent branched heteroalkyl groups replaced by 1 oxo substituentTime (it includes three carbon atoms being in chain end position, in formula shown in arrow, also includes the carbon atom of three and atom N Direct Bonding), then according to aforementioned principle, this group Link is such as preferablyOrDeng.

According to the present invention, as the compound shown in described anionic-cationic-nonionic surfactant or described formula (I), substantially compound as shown in following formula (I-1), substantially compound as shown in following formula (I-2), substantially compound as shown in following formula (I-3) or substantially compound as shown in following formula (I-4) such as specifically can be enumerated. These compounds can only use one, it is also possible to two or more combine use.

This embodiment according to the present invention, it is desirable to contained at least one in these molecular structure of compounds atom N such as (such as 1,2,3 or 4) and other group Rh and group X (these groups are not shown in below formula (I-1), formula (I-2), formula (I-3) or formula (I-4)) are bonded and are rendered as formulaThe form of shown quaternary ammonium salt (alkali). In formulaIn, group N⁺Being the quaternary nitrogen cationic form of at least one atom N described, group Rh is selected from optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. In the definition of group Rh, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. Group X^-Selected from halide ion (including fluorion, chloride ion, bromide ion and iodide ion) and hydroxide ion (OH^-), wherein preferred halide ion, more preferably chloride ion.This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-1), each group Ra is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-10Aryl, it is preferable that hydrogen, optionally substituted C_8-20Straight or branched alkyl and optionally substituted C_6-10Aryl.

According to the present invention, in formula (I-1), each group Ra ' is same to each other or different to each other, and is each independently selected from singly-bound, optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, carbonyl, optionally substituted C_1-10Straight or branched alkylenecarbonyl and optionally substituted C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from singly-bound and optionally substituted C_1-6Straight or branched alkylidene.

According to the present invention, in formula (I-1), b is the arbitrary integer between 1 to 3, it is preferable that 1.

According to the present invention, in formula (I-1), x ' represents groupNumber, be the arbitrary integer between 1 to 5, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3. It is apparent that b+x '��6.

According to the present invention, in formula (I-1), each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a=1, when group Y is O, and a=0. Further, at least one group Y is N.

According to the present invention, in formula (I-1), each (namely x ' is individual) group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise (such as one or two) the group Rp that is at least one₁It it is formulaThe group represented. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc.As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-1), each (namely x ' �� a) group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-1), each numerical value m ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m ' represents unitAverage number, therefore can be non-integer.As described numerical value m ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-1), each numerical value n ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n ' represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-1), each numerical value m " is same to each other or different to each other, is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m " represents unitAverage number, therefore can be non-integer. As described numerical value m ", can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-1), each numerical value n " is same to each other or different to each other, is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n " represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ", can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-1), preferably, all (namely x ' is individual) numerical value m ' and all (namely x ' �� a) numerical value m " sum (namely in the overall molecule structure of the compound shown in formula (I-1), unitPopulation mean number) more than 0, but be usually no more than 100, it is preferable that less than 50. In consideration of it, in the overall molecule structure of the compound shown in formula (I-1), it is preferable that containing (a number of) unitNow, in the overall molecule structure of the compound shown in formula (I-1), as described unitPopulation mean number, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-1), preferably, all (namely x ' is individual) numerical value n ' and all (namely x ' �� a) numerical value n " sum (namely in the overall molecule structure of the compound shown in formula (I-1), unit-CH₂-CH₂The population mean number of-O-) less than 100, it is preferable that less than 50. As described unit-CH₂-CH₂The population mean number of-O-, can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to an embodiment of the invention, preferably, in formula (I-1), all (namely x ' is individual) numerical value n ' and all (namely x ' �� a) numerical value n " and sum (namely in the overall molecule structure of the compound shown in formula (I-1), unit-CH₂-CH₂The population mean number of-O-) more than 0. In consideration of it, in the overall molecule structure of the compound shown in formula (I-1), it is preferable that containing (a number of) unit-CH₂-CH₂-O-.Now, in the overall molecule structure of the compound shown in formula (I-1), as described unit-CH₂-CH₂The population mean number of-O-, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-1), all (namely x ' is individual) numerical value n ' and all (namely x ' �� a) numerical value n " and sum (namely in the overall molecule structure of the compound shown in formula (I-1), unit-CH₂-CH₂The population mean number of-O-) and all (namely x ' is individual) numerical value m ' and all (namely x ' �� a) numerical value m " sum (namely in the overall molecule structure of the compound shown in formula (I-1), unitPopulation mean number) summation more than 0, but be usually no more than 200, it is preferable that less than 100. In consideration of it, in the overall molecule structure of the compound shown in formula (I-1), it is necessary to containing (a number of) unit-O-CH₂-CH₂-and/orNow, in the overall molecule structure of the compound shown in formula (I-1), as the population mean number of these unit, can be such as 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I-1), each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene.

According to the present invention, in formula (I-1), each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄). When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5.

According to the present invention, in formula (I-1), group Ra and group Rh (contain whole group Ra and group Rh that the compound shown in described formula (I-1) comprises, it is clear that also include the group Rh that aforesaid quaternary ammonium salt (alkali) comprises) at least one (such as 1,2 or 3 etc.) (one or more) C must be comprised in its structure₈Straight-chain part, so that the compound shown in this formula (I-1) shows intended some surface active property.

According to an embodiment of the invention, in formula (I-1), depend on the number of group Salt, group A^-Can be one, it is also possible to be multiple, at least one of which group A^-It is carboxylate radical (COO^-). In consideration of it, in the overall molecule structure of the compound shown in formula (I-1), it is preferable that there is at least one carboxylate radical (COO^-)��

According to the present invention, in formula (I-2), group Rb is selected from optionally substituted C_1-49Straight or branched alkyl, optionally substituted C_5-49Monocycle or polycyclic naphthene base and optionally substituted C_2-49Straight or branched thiazolinyl, it is preferable that selected from optionally substituted C_1-29Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base and optionally substituted C_2-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-29Straight or branched alkyl, optionally substituted C_5-8Monocycle or polycyclic naphthene base and optionally substituted C_8-29Straight or branched thiazolinyl, it is preferable that selected from optionally substituted C_8-19Straight or branched alkyl, optionally substituted C_5-7Monocyclic cycloalkyl (such as cyclohexyl) and optionally substituted C_8-19Straight or branched thiazolinyl.

According to the present invention, in formula (I-2), each group Rb ' is same to each other or different to each other, and is each independently selected from singly-bound and carbonyl.

According to the present invention, in formula (I-2), each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a=1, when group Y is O, and a=0. Further, at least one group Y is N.

According to the present invention, in formula (I-2), x " represents groupNumber, be the arbitrary integer between 1 to 10, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (I-2), each (i.e. x " is individual) group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise (such as one or two) the group Rp that is at least one₁It it is formulaThe group represented. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-2), each (i.e. x " �� a) group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-2), each numerical value m ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m ' represents unitAverage number, therefore can be non-integer. As described numerical value m ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-2), each numerical value n ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n ' represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-2), each numerical value m " is same to each other or different to each other, is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m " represents unitAverage number, therefore can be non-integer. As described numerical value m ", can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-2), each numerical value n " is same to each other or different to each other, is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n " represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ", can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-2), preferably, all (i.e. x " individual) numerical value m ' is individual with all (i.e. x " �� a) numerical value m " sum (namely in the overall molecule structure of the compound shown in formula (I-2), unitPopulation mean number) more than 0, but be usually no more than 100, it is preferable that less than 50.In consideration of it, in the overall molecule structure of the compound shown in formula (I-2), it is preferable that containing (a number of) unitNow, in the overall molecule structure of the compound shown in formula (I-2), as described unitPopulation mean number, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-2), preferably, all (i.e. x " individual) numerical value n ' is individual with all (i.e. x " �� a) numerical value n " sum (namely in the overall molecule structure of the compound shown in formula (I-2), unit-CH₂-CH₂The population mean number of-O-) less than 100, it is preferable that less than 50. As described unit-CH₂-CH₂The population mean number of-O-, can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to an embodiment of the invention, preferably, in formula (I-2), all (i.e. x " individual) numerical value n ' is individual with all (i.e. x " �� a) numerical value n " sum (namely in the overall molecule structure of the compound shown in formula (I-2), unit-CH₂-CH₂The population mean number of-O-) more than 0. In consideration of it, in the overall molecule structure of the compound shown in formula (I-2), it is preferable that containing (a number of) unit-CH₂-CH₂-O-. Now, in the overall molecule structure of the compound shown in formula (I-2), as described unit-CH₂-CH₂The population mean number of-O-, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-2), all (i.e. x " individual) numerical value n ' is individual with all (i.e. x " �� a) numerical value n " sum (namely in the overall molecule structure of the compound shown in formula (I-2), unit-CH₂-CH₂The population mean number of-O-) individual with all (i.e. x " �� a with all (i.e. x " individual) numerical value m ') numerical value m " sum (namely in the overall molecule structure of the compound shown in formula (I-2), unitPopulation mean number) summation more than 0, but be usually no more than 200, it is preferable that less than 100. In consideration of it, in the overall molecule structure of the compound shown in formula (I-2), it is necessary to containing (a number of) unit-O-CH₂-CH₂-and/orNow, in the overall molecule structure of the compound shown in formula (I-2), as the population mean number of these unit, can be such as 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I-2), each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene.

According to the present invention, in formula (I-2), each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH4). When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5.

According to an embodiment of the invention, in formula (I-2), depend on the number of group Salt, group A^-Can be one, it is also possible to be multiple, at least one of which group A^-It is carboxylate radical (COO^-). In consideration of it, in the overall molecule structure of the compound shown in formula (I-2), it is preferable that there is at least one carboxylate radical (COO^-)��

According to the present invention, in formula (I-2), group Rb and group Rh (contain whole group Rb and group Rh that the compound shown in described formula (I-2) comprises, it is clear that also include the group Rh that aforesaid quaternary ammonium salt (alkali) comprises) at least one (such as 1,2 or 3 etc.) (one or more) C must be comprised in its structure₈Straight-chain part, so that the compound shown in this formula (I-2) shows intended some surface active property.

According to the present invention, in formula (I-3), each group Rc is same to each other or different to each other, and is each independently selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl.

According to the present invention, in formula (I-3), each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl.

According to the present invention, in formula (I-3), x " ' representative unitNumber, be the arbitrary integer between 1 to 10, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (I-3), each (i.e. x " ' individual) group Rp is same to each other or different to each other, and is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise is at least one (such as one or two) group Rp is formulaThe group represented. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc.As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-3), each numerical value m ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m ' represents unitAverage number, therefore can be non-integer. As described numerical value m ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-3), each numerical value n ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n ' represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-3), it is preferred that whole (i.e. x " ' individual) numerical value m ' sum (namely in the overall molecule structure of the compound shown in formula (I-3), unitPopulation mean number) more than 0, but be usually no more than 100, it is preferable that less than 50. In consideration of it, in the overall molecule structure of the compound shown in formula (I-3), it is preferable that containing (a number of) unitNow, in the overall molecule structure of the compound shown in formula (I-3), as described unitPopulation mean number, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-3), it is preferred that whole (i.e. x " ' individual) numerical value n ' sum (namely in the overall molecule structure of the compound shown in formula (I-3), unit-CH₂-CH₂The population mean number of-O-) less than 100, it is preferable that less than 50. As described unit-CH₂-CH₂The population mean number of-O-, can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to an embodiment of the invention, it is preferred that in formula (I-3), whole (i.e. x " ' individual) numerical value n ' sum (namely in the overall molecule structure of the compound shown in formula (I-3), unit-CH₂-CH₂The population mean number of-O-) more than 0.In consideration of it, in the overall molecule structure of the compound shown in formula (I-3), it is preferable that containing (a number of) unit-CH₂-CH₂-O-. Now, in the overall molecule structure of the compound shown in formula (I-3), as described unit-CH₂-CH₂The population mean number of-O-, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-3), whole (i.e. x " ' individual) numerical value n ' sum (namely in the overall molecule structure of the compound shown in formula (I-3), unit-CH₂-CH₂The population mean number of-O-) and whole (i.e. x " ' individual) numerical value m ' sum (namely in the overall molecule structure of the compound shown in formula (I-3), unitPopulation mean number) summation more than 0, but be usually no more than 200, it is preferable that less than 100. In consideration of it, in the overall molecule structure of the compound shown in formula (I-3), it is necessary to containing (a number of) unit-O-CH₂-CH₂-and/orNow, in the overall molecule structure of the compound shown in formula (I-3), as the population mean number of these unit, can be such as 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I-3), each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene.

According to the present invention, in formula (I-3), each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄). When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5.

According to an embodiment of the invention, in formula (I-3), depend on the number of group Salt, group A^-Can be one, it is also possible to be multiple, at least one of which group A^-It is carboxylate radical (COO^-). In consideration of it, in the overall molecule structure of the compound shown in formula (I-3), it is preferable that there is at least one carboxylate radical (COO^-)��

According to the present invention, in formula (I-3), group Rc and group Rh (contain whole group Rc and group Rh that the compound shown in described formula (I-3) comprises, it is clear that also include the group Rh that aforesaid quaternary ammonium salt (alkali) comprises) at least one (such as 1,2 or 3 etc.) (one or more) C must be comprised in its structure₈Straight-chain part, so that the compound shown in this formula (I-3) shows intended some surface active property.

According to the present invention, in formula (I-4), group Rc is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl.

According to the present invention, in formula (I-4), each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl.

According to the present invention, in formula (I-4), group Y is N or O, and premise is when group Y is N, a=1, when group Y is O, and a=0.

According to the present invention, in formula (I-4), x " " representative unitNumber, be the arbitrary integer between 1 to 9, it is preferable that the arbitrary integer between 1 to 3, more preferably 1 or 2.

According to the present invention, in formula (I-4), each (namely x " " is individual) group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise (such as one or two) the group Rp that is at least one₁It it is formulaThe group represented. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-4), group Rp2 is selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc.As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-4), each (namely a) group Rp₃It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc.As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (I-4), each numerical value m ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m ' represents unitAverage number, therefore can be non-integer. As described numerical value m ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), each numerical value n ' is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n ' represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), each numerical value m " is same to each other or different to each other, is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m " represents unitAverage number, therefore can be non-integer. As described numerical value m ", can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), each numerical value n " is same to each other or different to each other, is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n " represents unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n ", can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), each numerical value m " ' be same to each other or different to each other, it is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value m " ' represent unitAverage number, therefore can be non-integer. As described numerical value m " ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), each numerical value n " ' be same to each other or different to each other, it is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50. Now, described numerical value n " ' represent unit-CH₂-CH₂The average number of-O-, therefore can be non-integer. As described numerical value n " ', can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), preferably, all (x " " is individual) and numerical value m ', all (1) numerical value m " with all (a) numerical value m " ' sum (namely in the overall molecule structure of the compound shown in formula (I-4), unitPopulation mean number) more than 0, but be usually no more than 100, it is preferable that less than 50.In consideration of it, in the overall molecule structure of the compound shown in formula (I-4), it is preferable that containing (a number of) unitNow, in the overall molecule structure of the compound shown in formula (I-4), as described unitPopulation mean number, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), preferably, all (x " " is individual) and numerical value n ', all (1) numerical value n " with all (a) numerical value n " ' sum (namely in the overall molecule structure of the compound shown in formula (I-4), unit-CH₂-CH₂The population mean number of-O-) less than 100, it is preferable that less than 50. As described unit-CH₂-CH₂The population mean number of-O-, can be such as 0,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to an embodiment of the invention, preferably, in formula (I-4), all (x " " is individual) and numerical value n ', all (1) numerical value n " with all (a) numerical value n " ' sum (namely in the overall molecule structure of the compound shown in formula (I-4), unit-CH₂-CH₂The population mean number of-O-) more than 0. In consideration of it, in the overall molecule structure of the compound shown in formula (I-4), it is preferable that containing (a number of) unit-CH₂-CH₂-O-. Now, in the overall molecule structure of the compound shown in formula (I-4), as described unit-CH₂-CH₂The population mean number of-O-, can be such as 0.1,0.5,1.2,2.0,2.5,3.0,3.5,5.4,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5 or 50.5 etc.

According to the present invention, in formula (I-4), all (x " " is individual) and numerical value n ', all (1) numerical value n " with all (a) numerical value n " ' sum (namely in the overall molecule structure of the compound shown in formula (I-4), unit-CH₂-CH₂The population mean number of-O-) individual with all (x " ") numerical value m ', all (1) numerical value m " with all (a) numerical value m " ' sum (namely in the overall molecule structure of the compound shown in formula (I-4), unitPopulation mean number) summation more than 0, but be usually no more than 200, it is preferable that less than 100. In consideration of it, in the overall molecule structure of the compound shown in formula (I-4), it is preferable that containing (a number of) unit-O-CH₂-CH₂-and/orNow, in the overall molecule structure of the compound shown in formula (I-4), as the population mean number of these unit, can be such as 0.1,0.5,1.5,2.0,3.0,3.5,7.5,10.0,15.0,25.0,30.2,35.0,40.0,45.5,50.5,55.2,60.0,75.5,80.5,85.0,90.5 or 95.7 etc.

According to the present invention, in formula (I-4), each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene.

According to the present invention, in formula (I-4), each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH4).When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5.

According to an embodiment of the invention, in formula (I-4), depend on the number of group Salt, group A^-Can be one, it is also possible to be multiple, at least one of which group A^-It is carboxylate radical (COO^-). In consideration of it, in the overall molecule structure of the compound shown in formula (I-4), it is preferable that there is at least one carboxylate radical (COO^-)��

According to the present invention, in formula (I-4), group Rc and group Rh (contain whole group Rc and group Rh that the compound shown in described formula (I-4) comprises, it is clear that also include the group Rh that aforesaid quaternary ammonium salt (alkali) comprises) at least one (such as 1,2 or 3 etc.) (one or more) C must be comprised in its structure₈Straight-chain part, so that the compound shown in this formula (I-4) shows intended some surface active property.

According to the present invention, in aforesaid formula (I-1), formula (I-2), formula (I-3) and formula (I-4), under there is no other clearly defined situations, so-called optionally substituted, refer to optionally by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, shown in anionic-cationic-nonionic surfactant structural formula as respective in it of the aforementioned various shown present invention, specify that and its respective molecular structure must contain ionic group (M) simultaneously_r ⁺With group X^-(sometimes it is likely to writing (M) respectively_rAnd X). However, it is known that both ionic groups are to demonstrating higher reactivity each other, if therefore the two coexists in same system, such as coexist in same molecular structure, will tend to react with each other and production (M)_r ⁺X^-(sometimes it is likely to writing (M)_rX) inorganic compound shown in. This inorganic compound (even such as precipitates out or forms independent thing phase) sometimes in a free form to be existed independent of the anionic-cationic-nonionic surfactant of the present invention, thus causing these groups (i.e. group (M)_r ⁺With group X^-) at least some of (being whole sometimes) cannot clear and definite as these structural formulas, become the ingredient of the molecular structure of the anionic-cationic-nonionic surfactant of the present invention. In this case, the anionic-cationic-nonionic surfactant of the present invention is substantially (such as to lose whole groups (M)_r ⁺Or group X^-) or at least partly (such as to lose a part of group (M)_r ⁺Or group X^-) betaine form exist. Now, contained in the molecular structure of this anionic-cationic-nonionic surfactant group A^-With group N⁺Become new counter ion counterionsl gegenions each other.In consideration of it, in the whole molecular structure of the anionic-cationic-nonionic surfactant of the present invention, if described group X^-Total number be e1, described group N⁺Total number be e2, described group A^-Total number be e3, described group (M)_r ⁺Total number be e4, as e2=e3,0��e1��e2,0��e4��e3. Or, as e2 > e3,0 < e1��e2,0��e4��e3. Or, as e2 < e3,0��e1��e2,0 < e4��e3. Premise is, e1+e3=e2+e4. Or, it is preferred that e2=e3, e1=0, e4=0. Therefore, depend on the generation degree of described inorganic compound, especially anionic-cationic-the nonionic surfactant of present invention group (M) in its whole molecular structure_r ⁺With group X^-Number ratio, or whether have and be beneficial to the reaction condition that this inorganic compound generates, the anionic-cationic-nonionic surfactant of the present invention contains described group (M) time sometimes different in its molecular structure_r ⁺With group X^-, sometimes even simultaneously without there being described group (M)_r ⁺With group X^-. Due to this inorganic compound generation whether, or the number of its content, or its existence form is how, the various performances (such as interfacial activity and stability) of the anionic-cationic-nonionic surfactant of the present invention are not produced substantial effect, and therefore the present invention is not intended to provide any special regulation for this inorganic compound. In consideration of it, in the context of the present specification, in order to more precisely describe or define the anionic-cationic-nonionic surfactant of the present invention, " substantially as shown in formula ## " or its similar statement are employed. At this, so-called " substantially as shown in formula ## " (than as the aforementioned substantially as Suo Shi formula (I), substantially as Suo Shi formula (I-1), substantially as Suo Shi formula (I-2), substantially as Suo Shi formula (I-3) or substantially as Suo Shi formula (I-4) etc.) or its similar statement, refer to the anionic-cationic-nonionic surfactant of the present invention, both as clear and definite in this formula, contain group (M) simultaneously_r ⁺With group X^-, also as explained before like that, lose at least some of (even whole) group (M)_r ⁺And/or group X^-, even do not contain (or being absent from) group (M)_r ⁺And/or group X^-. To those skilled in the art, these representatives are the different existence forms of anionic-cationic-nonionic surfactant of the present invention, are all necessarily encompassed within protection scope of the present invention.

According to the present invention, aforementioned various shown anionic-cationic-nonionic surfactant such as can manufacture according to following manufacture method, and wherein this manufacture method such as includes the steps (1) to (5).

Step (1): make one or more nitrogenous and with one or more selected from-OH ,-NH₂React under the existence of base catalyst with the alkylene oxide shown in one or more formulas (Y) with the polyfunctional compound of the functional group of-NH-, it is thus achieved that etherification product.

According to the present invention, in step (1), as described polyfunctional compound, it is possible to use any with one or more (such as 1 to 10, it is preferable that 1 to 4, such as 2,3 or 4) selected from-OH ,-NH₂With the compound of the functional group of-NH-, be not particularly limited. These functional groups, owing to containing active hydrogen, therefore can make alkylene oxide generation open loop (polymerization) reactions such as oxirane, thus introduce (gathering) ether segment in the molecular structure of this polyfunctional compound.These polyfunctional compounds can only use one, it is also possible to two or more combine use. It addition, these polyfunctional compounds can directly use commercially available prod, it is also possible to manufacture according to any of method.

According to the present invention, in step (1), described polyfunctional compound must nitrogen atom. This nitrogen-atoms may be from this polyfunctional compound be likely to containing primary amine group, tertiary amine group or secondary amine group.

According to the present invention, in step (1), as described polyfunctional compound, the amines shown in following formula (X) specifically such as can be enumerated. These compounds can only use one, it is also possible to two or more combine use.

According to the present invention, in formula (X), group R '₁To R '₃It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl, optionally substituted C_6-50Aryl and by formulaThe group represented. At this, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from oxo (namely), hydroxyl, by formulaThe group of representative, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X), it is desirable to group R '₁To R '₃In to have at least one (such as at most two) be hydrogen or by formulaThe group represented.

According to the present invention, in formula (X), at group R '₁To R '₃Definition in, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X), by formulaIn the group represented, group L_ASelected from optionally substituted x0+1 valency C_1-50Straight or branched alkyl, optionally substituted x0+1 valency C_5-50Monocycle or polycyclic naphthene base, optionally substituted x0+1 valency C_2-50Straight or branched thiazolinyl, optionally substituted x0+1 valency C_6-50Aryl and optionally substituted x0+1 valency C_3-50The assorted alkyl of straight or branched.As described optionally substituted x0+1 valency C_1-50Straight or branched alkyl, it is preferable that optionally substituted x0+1 valency C_1-20Straight or branched alkyl. As described optionally substituted x0+1 valency C_5-50Monocycle or polycyclic naphthene base, such as can enumerate optionally substituted x0+1 valency C_5-10Monocycle or polycyclic naphthene base, optionally substituted x0+1 valency C_5-8Monocycle or polycyclic naphthene base or optionally substituted x0+1 valency C_5-7Monocycle or polycyclic naphthene base, especially optionally substituted x0+1 valency C_5-7Monocyclic cycloalkyl, such as cyclohexyl. As described optionally substituted x0+1 valency C_2-50Straight or branched thiazolinyl, it is preferable that optionally substituted x0+1 valency C_2-20Straight or branched thiazolinyl. As described optionally substituted x0+1 valency C_6-50Aryl, it is preferable that optionally substituted x0+1 valency C_6-20Aryl, such as phenyl or naphthyl. The x0+1 valency C optionally replaced_3-50The assorted alkyl of straight or branched, it is preferable that optionally substituted x0+1 valency C_3-20The assorted alkyl of straight or branched.

According to the present invention, in formula (X), each group Func is same to each other or different to each other, and is each independently selected from-OH ,-NH-and-NH₂, it is preferable that it is each independently selected from-OH and-NH₂��

According to the present invention, in formula (X), x0+1 general proxy group L_AValence state value, wherein x0 is the arbitrary integer between 1 to 10, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3. But, artisans will appreciate that, when group Func is-NH-, group L_AInterrupted in arbitrarily (acceptable) position by this-NH-. Now, x0 (or its at least some of, this depends on the number of-NH-) represents the number of times of this interruption, without so representing group L_AValence state value (its valence state value is minimum be likely 1, when such as x0 group Func is-NH-). When there is multiple-NH-, group L_ARepeatedly interrupted accordingly in arbitrarily (acceptable) position by these-NH-. Here so-called interruption, refers to this-NH-to group L_AMolecular structure internal insert, and be not in its molecular structure the end of main chain or any side chain. Preferably, not Direct Bonding between each-NH-. Concrete example, is 1 (interruption times is 1) when group Func is-NH-, x0, and group L_AIt is 1 valency (being no longer divalent) C₈Straight chained alkyl is namelyTime (in formula, the position indicated by arrow is the end of main chain in molecular structure), group L_AIt is probablyOrDeng.

According to the present invention, in formula (X), under there is no other clearly defined situations, so-called optionally substituted, refer to optionally by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1) selected from oxo, hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to an embodiment of the invention (being called embodiment A), in formula (X), there is oxo as a certain group (such as group L_A) substituent group time, it is preferable that have at least an oxo substituent to be positioned at and on the carbon atom of atom N (if any, the assorted alkyl of such as straight or branched is likely to the atom N comprised) Direct Bonding, make described carbon atom be rendered as carbonyl (namely) form, in this group, thus introduce the structure (such as acylimino) of carbonyl and atom N Direct Bonding.Additionally, in order to obtain better stability to hydrolysis resistance or chemical stability, preferably, at least partially (preferably whole) and the carbon atom of O or S atom (if any) Direct Bonding are absent from this oxo substituent, and/or, at least some of (preferably whole) are in the carbon atom of the end of the chain (refer to the free end of strand and/or treat the end with other atomic linkages) position (if group Func is-NH-or-NH₂, this group such as group L_AIn with the chain end carbon atom of this group Func Direct Bonding except, the embodiment B seen below) on be absent from this oxo substituent, and/or, replaced by oxo during the carbon atom difference of two Direct Bonding. By so, it is possible to avoid introducing the chemical activity such as ester group or aldehyde radical or unstable group in this group. Concrete example, group L_AFor the divalent straight chained alkyl replaced by 1 oxo substituentTime (it includes two carbon atoms being in chain end position, in formula shown in arrow), then according to aforementioned principle, this group is such as preferablyOrDeng. Or, group L_AFor the divalent branched heteroalkyl groups replaced by 1 oxo substituentTime (it includes three carbon atoms being in chain end position, in formula shown in arrow, also includes the carbon atom of three and atom N Direct Bonding), then according to aforementioned principle, this group is such as preferablyOrDeng.

According to an embodiment of the invention (being called embodiment B), when group Func is-NH-or-NH₂Time, in formula (X), when there is oxo alternatively base, preferably at least have an oxo substituent be positioned at on the carbon atom of this group Func Direct Bonding, in other words, there is oxo substituent with at least one in the carbon atom of this group Func Direct Bonding, thus at group L_AThe structure (such as acylamino-) of middle introducing carbonyl and atom N Direct Bonding. Concrete example, group L_AFor the divalent straight chained alkyl replaced by 1 oxo substituentAnd group Func is-NH₂Time, formulaThe group represented is preferred except embodiment A instituteOutside, it is also possible to it is

According to the present invention, it is desirable to described polyfunctional compound must comprise (one or more) C with at least one in the quaternizing agent shown in formula (A) hereinafter described in its molecular structure₈Straight-chain part (hereinafter sometimes referred to regulation (1)). In consideration of it, according to this regulation (1), it is also desirable to the amines shown in described formula (X) must comprise (one or more) C with at least one in described quaternizing agent in its molecular structure₈Straight-chain part. Specifically, according to this regulation (1), group R '₁To R '₃At least one (such as 1,2 or 3 etc.) in (coming from the amines shown in described formula (X)) and group Rh (referring to hereafter, coming from described quaternizing agent) must comprise (one or more) C in its structure₈Straight-chain part.

According to the present invention, in step (1), as the amines shown in described formula (X), the compound shown in the compound shown in the compound shown in following formula (X-1), following formula (X-2), following formula (X-3) and the compound shown in following formula (X-4) more specifically such as can be enumerated. These compounds can only use one, it is also possible to two or more combine use.

According to the present invention, in formula (X-1), each group Ra is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-20Aryl, it is preferable that optionally substituted C_8-20Straight or branched alkyl and optionally substituted C_6-10Aryl.

According to the present invention, in formula (X-1), each group Ra ' is same to each other or different to each other, and is each independently selected from singly-bound, optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, carbonyl, optionally substituted C_1-10Straight or branched alkylenecarbonyl and optionally substituted C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from singly-bound and optionally substituted C_1-6Straight or branched alkylidene.

According to the present invention, in formula (X-1), b is the arbitrary integer between 1 to 3, it is preferable that 1.

According to the present invention, in formula (X-1), x1 represents groupNumber, be the arbitrary integer between 1 to 5, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3. It is apparent that b+x1��6.

According to the present invention, in formula (X-1), each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a1=1, when group Y is O, and a1=0. Further, at least one group Y is N.

According to the present invention, in formula (X-1), each (namely x1) group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise is at least one group Rp '₁It is hydrogen. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-1), each (namely x1 �� a1) group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl.At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-1), according to aforesaid regulation (1), it is desirable to group Ra and group Rh (contain whole group Ra that the compound shown in described formula (X-1) comprises whole group Rh comprised with the quaternizing agent shown in formula (A) hereinafter described) at least one (such as 1,2 or 3 etc.) (one or more) described C must be comprised in its structure₈Straight-chain part.

According to the present invention, in formula (X-2), group Rb is selected from optionally substituted C_1-49Straight or branched alkyl, optionally substituted C_5-49Monocycle or polycyclic naphthene base and optionally substituted C_2-49Straight or branched thiazolinyl, it is preferable that selected from optionally substituted C_1-29Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base and optionally substituted C_2-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-29Straight or branched alkyl, optionally substituted C_5-8Monocycle or polycyclic naphthene base and optionally substituted C_8-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-19Straight or branched alkyl, optionally substituted C_5-7Monocyclic cycloalkyl (such as cyclohexyl) and optionally substituted C_8-19Straight or branched thiazolinyl.

According to the present invention, in formula (X-2), each group Rb ' is same to each other or different to each other, and is each independently selected from singly-bound and carbonyl.

According to the present invention, in formula (X-2), each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a2=1, when group Y is O, and a2=0. Further, at least one group Y is N.

According to the present invention, in formula (X-2), x2 represents groupNumber, be the arbitrary integer between 1 to 10, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (X-2), each (namely x2) group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise is at least one group Rp '₁It is hydrogen. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-2), each (namely x2 �� a2) group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces.As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-2), according to aforesaid regulation (1), it is desirable to group Rb and group Rh (contain whole group Rb that the compound shown in described formula (X-2) comprises whole group Rh comprised with the quaternizing agent shown in formula (A) hereinafter described) at least one (such as 1,2 or 3 etc.) (one or more) described C must be comprised in its structure₈Straight-chain part.

According to the present invention, in formula (X-3), each group Rc is same to each other or different to each other, and is each independently selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl.

According to the present invention, in formula (X-3), each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl.

According to the present invention, in formula (X-3), x3 representative unitNumber, be the arbitrary integer between 1 to 10, it is preferable that the arbitrary integer between 1 to 4, such as 1,2 or 3.

According to the present invention, in formula (X-3), each (namely x3) group Rp ' is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise is at least one group Rp ' is hydrogen. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc.As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-3), according to aforesaid regulation (1), it is desirable to group Rc and group Rh (contain whole group Rc that the compound shown in described formula (X-3) comprises whole group Rh comprised with the quaternizing agent shown in formula (A) hereinafter described) at least one (such as 1,2 or 3 etc.) (one or more) described C must be comprised in its structure₈Straight-chain part.

According to the present invention, in formula (X-4), group Rc is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl.

According to the present invention, in formula (X-4), each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl.

According to the present invention, in formula (X-4), group Y is N or O, and premise is when group Y is N, a4=1, when group Y is O, and a4=0.

According to the present invention, in formula (X-4), x4 representative unitNumber, be the arbitrary integer between 1 to 9, it is preferable that the arbitrary integer between 1 to 3, more preferably 1 or 2.

According to the present invention, in formula (X-4), each (namely x4) group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl, premise is at least one group Rp '₁It is hydrogen.At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-4), group Rp '₂Selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-4), each (namely a4) group Rp '₃It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. At this, as described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (X-4), according to aforesaid regulation (1), it is desirable to group Rc and group Rh (contain whole group Rc that the compound shown in described formula (X-4) comprises whole group Rh comprised with the quaternizing agent shown in formula (A) hereinafter described) at least one (such as 1,2 or 3 etc.) (one or more) described C must be comprised in its structure₈Straight-chain part.

According to the present invention, in formula (X-1), formula (X-2), formula (X-3) and formula (X-4), under there is no other clearly defined situations, so-called optionally substituted, refer to optionally by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1) selected from oxo, hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl.As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, as the compound shown in the amines shown in aforesaid polyfunctional compound, formula (X), the compound shown in formula (X-1), formula (X-2), the compound shown in formula (X-3) and the compound etc. shown in formula (X-4), can directly use commercially available product, it is also possible to manufactured by any method known in the art. For example, as the compound shown in described formula (X-2), (wherein, Y=N, Rb ' is carbonyl, group Rp '₁With group Rp '₂It is hydrogen), namely(being called amidation step) can be obtained by making the compound shown in following formula (X-2-1) and amidating agent (such as diisopropanolamine (DIPA)) react under the existence of base catalyst.

In formula, group Rb and numerical value x2 is identical with the definition in formula (X-2), group R_acIt is H or C_1-4Straight or branched alkyl.

According to the present invention, this amidation step can carry out according to any mode known in the art, but reaction temperature is generally 100-200 DEG C, and the response time is generally 1-10 hour, and reaction pressure can be normal pressure or any be suitable for the pressure that this reaction carries out.

According to the present invention, in described amidation step, as described base catalyst, it is possible to directly use prior art conventional use of any base catalyst for this purpose, wherein preferred alkali metal hydroxide, especially sodium hydroxide or potassium hydroxide. These base catalysts can only use one, it is also possible to two or more combine use. Consumption as described base catalyst, can directly be suitable for the conventional amount used of this area, but generally make described base catalyst reach the 0.2-20wt% of the compound shown in described formula (X-2-1) and described amidating agent gross weight, it is preferable that 0.5-15wt%.

According to the present invention, in described amidation step, the mol ratio of the compound shown in described formula (X-2-1) and described amidating agent is generally 1: 1-15,1: 1-10,1: 1-8,1: 1-5 or 1: 2-4, but is sometimes not limited to this, it is possible to be able to x2 group-COOR_acIt is completely converted into any mol ratio of amide groups.

According to the present invention, after described amidation step terminates, from mixture of reaction products, unreacted amidating agent is removed by conventionally known separate mode (such as vacuum draw), the compound shown in formula (X-2) can be obtained (such as, Y=N, Rb ' are carbonyl, group Rp '₁With group Rp '₂It is hydrogen), without further purification or separation.

According to the present invention, in formula (Y), group Ru ' is selected from C_2-6Straight or branched alkylidene, wherein preferred-CH₂-CH₂-and/or-CH₂-CH(CH₃)-, be-CH more preferably₂-CH₂-and-CH₂-CH(CH₃)-combination.

According to the present invention, in step (1), as the alkylene oxide shown in described formula (Y), oxirane, expoxy propane, epoxy butane, oxepane etc. such as can be enumerated. These alkylene oxides can only use one, it is also possible to two or more combine use, the combination of such as oxirane and expoxy propane.

According to the present invention, use the alkylene oxide shown in one or more formulas (Y), it is preferable that at least one of which alkylene oxide is expoxy propane. This expoxy propane can as required with shown in other formulas (Y) alkylene oxide (especially oxirane) combination use.When combination uses, shown in expoxy propane and other formulas (Y) the mol ratio of alkylene oxide (especially oxirane) can be such as 1: 0.1-10, but be not limited to this.

According to the present invention, in step (1), as described base catalyst, it is possible to directly use prior art conventional use of any base catalyst for this purpose, wherein preferred alkali metal hydroxide, especially potassium hydroxide. These base catalysts can only use one, it is also possible to two or more combine use.

According to the present invention, in step (1), consumption as described base catalyst, can directly be suitable for the conventional amount used of this area, but the mol ratio generally making described polyfunctional compound (such as the amines shown in formula (X)) and described base catalyst reaches 1: 1-10, it is preferable that reach 1: 1-5.

According to the present invention, in step (1), the mol ratio of described polyfunctional compound (such as the amines shown in formula (X)) and described alkylene oxide is generally 1: 0-200, it is preferable that 1: 0-100, but do not include 0, more preferably 1: 0.1-50.

According to the present invention, in step (1), reaction temperature is generally room temperature to 300 DEG C, it is preferable that 100-200 DEG C, the response time is generally 1-20 hour, it is preferable that 1-10 hour, and reaction pressure can be any pressure that this reaction carries out that is suitable for, such as normal pressure.

According to a preferred embodiment of the present invention, in step (1), as the alkylene oxide shown in described formula (Y), two or more if (at least including expoxy propane preferably wherein) combination uses, make described polyfunctional compound (such as the amines shown in formula (X)) first with (at least some of amount or whole amount) propylene oxide reaction, then react with other alkylene oxide (such as oxirane) again (preferably in the reaction with described expoxy propane at least partly or after being fully completed).

According to the present invention, after step (1) terminates, the mixture of reaction products obtained can carry out step (2) subsequently directly as etherification product, without through any isolated or purified, or only need to isolate (as by washing) described base catalyst.

Step (2): make described etherification product and the quaternizing agent shown in following formula (A) react, be derived from described cation-nonionic surfactant.

Rh-X��(A)

According to the present invention, in formula (A), group Rh is selected from optionally substituted C_1-50Straight or branched alkyl, optionally substituted C_5-50Monocycle or polycyclic naphthene base, optionally substituted C_2-50Straight or branched thiazolinyl and optionally substituted C_6-50Aryl. As described C_1-50Straight or branched alkyl, such as can enumerate C_1-20Straight or branched alkyl or C_8-20Straight or branched alkyl, specifically such as octadecyl, lauryl, octyl group, cetyl, hexyl, methyl or ethyl etc. As described C_5-50Monocycle or polycyclic naphthene base, such as can enumerate C_5-10Monocycle or polycyclic naphthene base, C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-50Straight or branched thiazolinyl, such as can enumerate C_2-20Straight or branched thiazolinyl or C_8-20Straight or branched thiazolinyl, specifically such as vaccenic acid base, dodecenyl succinic, sub-oil base, vinyl, acrylic or pi-allyl etc. As described C_6-50Aryl, such as can enumerate C_6-20Aryl or C_6-10Aryl, specifically such as phenyl or naphthyl. This, so-called " optionally substituted ", refer to optionally by one or more (such as 1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces.As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in formula (A), group X ' is selected from halogen, including fluorine, chlorine, bromine and iodine, and wherein preferred chlorine.

According to the present invention, in step (2), the mol ratio making described polyfunctional compound (such as the amines shown in formula (X)) and the quaternizing agent shown in described formula (A) commonly reaches 1: 0.1-200, preferably 1: 0.1-50, but sometimes it is not limited to this, as long as the consumption of described quaternizing agent makes at least one atom N in described etherification product molecular structure form quaternary ammonium salt group.

According to the present invention, in step (2), reaction temperature is generally 0 to 300 DEG C, it is preferable that 50-150 DEG C, and the response time is generally 1-20 hour, it is preferable that 4-15 hour, and reaction pressure can be any pressure that this reaction carries out that is suitable for, such as normal pressure.

According to the present invention, described step (2) can carry out in the presence of a catalyst, it is also possible to does not use catalyst. As described catalyst, it is possible to directly use this area conventional use of catalyst for this purpose, specifically such as can enumerate potassium iodide. Consumption as described catalyst, it is possible to be directly suitable for the conventional amount used of this area, specifically such as can enumerate 0.5-3.0wt%, especially 1.0-2.0wt%.

According to the present invention, after step (2) terminates, it is possible to mixture of reaction products step (2) obtained by conventional separate mode is processed, and thus isolates described cation-nonionic surfactant. As described separate mode, such as can enumerate and extract in the basic conditions.

Step (3): make described cation-nonionic surfactant and the compound shown in one or more following formulas (Z) react under the existence of base catalyst, is derived from the anionic-cationic-nonionic surfactant (include substantially compound as shown in previously described formula (I), substantially compound as shown in previously described formula (I-1), substantially compound as shown in previously described formula (I-2), substantially compound as shown in previously described formula (I-3) or substantially compound etc. as shown in previously described formula (I-4)) of the present invention.

According to the present invention, in step (3), as described base catalyst, it is possible to directly use prior art conventional use of any base catalyst for this purpose, wherein preferred alkali metal hydroxide, especially sodium hydroxide or potassium hydroxide. These base catalysts can only use one, it is also possible to two or more combine use.

According to the present invention, in step (3), consumption as described base catalyst, can directly be suitable for the conventional amount used of this area, but the mol ratio generally making described polyfunctional compound (such as the amines shown in formula (X)) and described base catalyst reaches 1: 1-10, it is preferable that reach 1: 1-5.

G-L-AS(Z)

According to the present invention, in formula (Z), group G is selected from halogen and hydroxyl, it is preferable that halogen.As described halogen, fluorine, chlorine, bromine and iodine such as can be enumerated, it is preferable that chlorine.

According to the present invention, in formula (Z), group L is selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene, it is preferable that selected from optionally substituted C_1-5Straight or branched alkylidene.

According to the present invention, in formula (Z), group AS choosing freely-A^-(M��)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-), group M ' is selected from hydrogen, alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄), it is preferable that alkali metal (preferred Li, Na and K) and alkaline-earth metal (preferred Mg and Ca).

According to the present invention, when group M ' be hydrogen, alkali metal or during ammonium root, r=1; When group M ' is for alkaline-earth metal, r=0.5.

According to an embodiment of the invention, in formula (Z), as group A^-It is carboxylate radical (COO^-) time, group G is halogen, and as group A^-It is sulfonate radical (SO₃ ^-) time, group G is halogen or hydroxyl.

According to an embodiment of the invention, use the compound shown in one or more formulas (Z), wherein in the compound shown at least one formula (Z), group A^-It is carboxylate radical (COO^-). In consideration of it, when carrying out described step (3), it is preferable that at least use with carboxylate radical (COO^-) the compound shown in formula (Z).

According to the present invention, in formula (Z), so-called optionally substituted, refer to optionally by one or more (such as 1 to 5,1 to 4,1 to 3,1 to 2 or 1) selected from hydroxyl, C_1-20Straight or branched alkyl, C_5-10Monocycle or polycyclic naphthene base, C_2-20Straight or branched thiazolinyl and C_6-20The substituent group of aryl replaces. As described C_1-20Straight or branched alkyl, such as can enumerate C_1-10Straight or branched alkyl or C_1-6Straight or branched alkyl, or methyl or ethyl etc. As described C_5-10Monocycle or polycyclic naphthene base, such as can enumerate C_5-8Monocycle or polycyclic naphthene base or C_5-7Monocycle or polycyclic naphthene base, especially C_5-7Monocyclic cycloalkyl, specifically such as cyclopenta or cyclohexyl. As described C_2-20Straight or branched thiazolinyl, such as can enumerate C_2-10Straight or branched thiazolinyl, specifically such as vinyl, acrylic or pi-allyl etc. As described C_6-20Aryl, such as can enumerate C_6-10Aryl, specifically such as phenyl or naphthyl.

According to the present invention, in step (3), the mol ratio generally making described polyfunctional compound (such as the amines shown in formula (X)) and the compound shown in described formula (Z) reaches 1: 1-10, it is preferable that 1: 1-3.

According to the present invention, in step (3), reaction temperature is generally 0-300 DEG C, it is preferable that 50-200 DEG C, and the response time is generally 1-20 hour, it is preferable that 4-10 hour, and reaction pressure can be any pressure that this reaction carries out that is suitable for, such as normal pressure.

According to the present invention, after step (3) terminates, it is possible to mixture of reaction products step (3) obtained by conventional separate mode is processed, and thus isolates described surfactant. As described separate mode, such as can enumerate and the mixture of reaction products first obtained to step (3) adds acidic aqueous solution (such as aqueous hydrochloric acid solution, aqueous sulfuric acid, phosphate aqueous solution, sodium bisulphate solution, aqueous potassium hydrogen sulfate etc.), its pH value is regulated to 1-3, then oil-water separation is carried out, the method thus obtaining the anionic-cationic-nonionic surfactant of the present invention with the form of oil phase.

According to the present invention, after step (3) terminates, as required, anionic-cationic-the nonionic surfactant obtained as previously mentioned can be made to contact with nertralizer further, thus by this surfactant is likely to containing free acid groups (such as free carboxyl or sulfonic group) be converted into the form (hereinafter referred to as neutralization procedure) of its salt. As described nertralizer, alkali metal (preferred Li, Na and K) hydroxide, alkaline-earth metal (preferred Mg and Ca) hydroxide or ammonia such as can be enumerated. These nertralizers can only use one, it is also possible to two or more combine use. Ways of carrying out as described neutralization procedure, such as can enumerate in described anionic-cationic-nonionic surfactant, add a certain amount of described nertralizer aqueous solution or aqueous suspension, being neutralized to pH value is 7-9 or 8-10, then the method removing moisture (as by the method such as heating evaporation, vacuum removal), but it is not limited to this.

Step (4): as required, the either step of the manufacture method of the present invention (is included aforesaid step (3) and neutralization procedure, and step (5) etc. hereinafter described) at least some of (or all) quaternary ammonium salt group in anionic-cationic-nonionic surfactant molecular structure of obtaining is converted to corresponding quaternary ammonium base group, and/or, at least some of (or whole) the quaternary ammonium base group in the anionic-cationic of described acquisition-nonionic surfactant molecular structure is converted to corresponding quaternary ammonium salt group.

According to the present invention, this step (4) is optional step, rather than steps necessary.

According to the present invention, any mode that described step (4) can be conventionally known carries out, and such as can enumerate electrolysis or ion exchange etc., be not particularly limited.

Step (5): isolate the compound (M ') that at least some of (preferably whole) exist in a free form from anionic-cationic-nonionic surfactant that the arbitrary steps (including aforesaid step (3), step (4) and neutralization procedure) of the manufacture method of the present invention obtains_rX ' is (corresponding to previously described formula (M)_r ⁺X^-Shown inorganic compound). This, group (M ')_rDerived from the compound shown in previously described formula (Z), group X ' is derived from the quaternizing agent shown in previously described formula (A). This compound (M ')_rMain the carrying out in process because of the ionic group (M ') that reactivity is higher each other in abovementioned steps (3) or step (4) etc. of X '_r ⁺With ionic group X '^-Meet and generate. By this separation, as mentioned before, it is thus achieved that substantially with or at least partly within anionic-cationic-nonionic surfactant of the present invention of existing of ammonium salts. It is of course also possible to do not isolate this compound (M ')_rX ' (even if it is present in described anionic-cationic-nonionic surfactant in a free form), and make it as the constituent (blending ingredients or innocuous impurities) of the anionic-cationic-nonionic surfactant of the present invention. Regardless of whether through this separation; all anionic-cationic-nonionic surfactant of aforementioned acquisition are all referred to as the anionic-cationic-nonionic surfactant of the present invention and are not distinguish between, and all include within protection scope of the present invention.

According to the present invention, this step (5) is optional step, rather than steps necessary, nor is considered as the purification step of the anionic-cationic-nonionic surfactant to the present invention.

According to the present invention, as described compound (M ')_rThe separation method of X ', such as can enumerate and the anionic-cationic-nonionic surfactant obtained from the arbitrary steps (including aforesaid step (3), step (4) and neutralization procedure etc.) of the manufacture method of the present invention is dissolved in substantial amounts of dehydrated alcohol, then pass through the method etc. being filtered to remove this compound, but the present invention is not limited to this. Due to described compound (M ')_rX ' has stronger water solublity, therefore its be likely at least partially in the manufacture process (such as in step (3)) of the anionic-cationic-nonionic surfactant of the present invention by being dissolved in water and separated removing. Due to this compound (M ')_rThe various performances (such as interfacial activity and stability) of described anionic-cationic-nonionic surfactant that the how many couples of present invention of the presence or absence of X ' or content manufacture do not have substantial effect, and therefore the present invention is not intended to this compound (M ') in the specific anionic-cationic-nonionic surfactant obtained by this manufacture method_rThe content of X ' or existence form etc., be also absent from certainly by this compound (M ')_rThe necessity that X ' removes from the aforementioned any anionic-cationic-nonionic surfactant obtained of the present invention.

According to the present invention, as described anionic-cationic-nonionic surfactant (include substantially compound as shown in previously described formula (I), substantially compound as shown in previously described formula (I-1), substantially compound as shown in previously described formula (I-2), substantially compound as shown in previously described formula (I-3) or substantially compound etc. as shown in previously described formula (I-4)), it can be single a kind of compound, can also be the mixture comprising multiple compounds, even further comprise aforesaid compound (M ')_rX ', these are all desired by the present invention. Given this, according to the present invention, and be absent from being further purified described anionic-cationic-nonionic surfactant, or from the described anionic-cationic-nonionic surfactant (mixture) obtained, it is further separated out the necessity of the compound of a certain ad hoc structure. Even so, as described purification or separation method, the method such as column chromatography method or preparative hplc such as can be enumerated.

According to the present invention, in the anionic-cationic-nonionic surfactant of the present invention, can be respective individualism between different anionic-cationics-nonionic surfactant molecule, it is also possible to be zwitterion associate because of attracting each other even occur chemical reaction (as by eliminate compound (M)_r ⁺X^-Or compound (M ')_rX ' etc.) and form new compound, not special restriction. These existences belong to protection scope of the present invention, and are not limited to this literal statement.

In the anionic-cationic-nonionic surfactant of the present invention, on the one hand due to electrostatic attraction effect strong between anions and canons surfactant opposite charges polar group, surfactant molecule is increased in adsorbed on interfaces amount, critical micelle concentration significantly reduces, thus having the high surface that single surfactant is incomparable; Simultaneously because the interfacial activity of this surfactant superelevation, its aqueous solution can form ultralow interfacial tension with crude oil, thus effectively overcoming the cohesiveness between crude oil, being conducive to former oil-out, and then oil displacement efficiency is greatly improved.On the other hand, this surfactant can change oil reservoir wettability of the surface, such as cationic moiety therein by with absorption electronegative Interaction of substituents on a solid surface, its desorption is made to get off, glossy wet structure is made to change into neutral wetting or water-wet surface, reduce the crude oil adhesion work at the surface of solids, thus being conducive to the stripping of crude oil. Meanwhile, crude oil is had solubilization by the mixing of anions and canons part, it is possible to washed down by the crude oil sticked on the sandstone of rock stratum further, improves oil recovery factor. In consideration of it, the anionic-cationic-nonionic surfactant of the present invention is particularly suitable for manufacturing displacement composition used for tertiary oil recovery (displacing fluid).

According to an embodiment of the invention, further relating to a kind of displacement composition used for tertiary oil recovery, it comprises the aforesaid anionic-cationic-nonionic surfactant of the present invention, Yi Jishui.

According to the present invention, in described displacement composition used for tertiary oil recovery, anionic-cationic-the nonionic surfactant of the present invention accounts for the gross weight (in 100wt%) of described displacement composition used for tertiary oil recovery and is generally 0.001-10wt%, preferred 0.005-5wt%, more preferably 0.02-1wt%.

According to the present invention, described displacement composition used for tertiary oil recovery can also include this area conventional use of various additive during fabrication as required, include but not limited to cationic water-soluble polymer, anionic water-soluble polymer or fatty alcohol ether solvent etc. These additives can only use one, it is also possible to two or more combine use, and its consumption can also directly with reference to the conventional amount used of this area.

According to the present invention, as described cationic water-soluble polymer, polyacrylamide such as can be enumerated. The number-average molecular weight of this polyacrylamide is generally 1,000 ten thousand to 4,000 ten thousand, it is preferable that 1,000 ten thousand to 3,000 ten thousand, and its consumption is generally the 0.05-5.0wt% of described displacement composition gross weight used for tertiary oil recovery, it is preferable that 0.1-0.5wt%, but is sometimes not limited to this.

According to the present invention, even if described displacement composition used for tertiary oil recovery does not comprise inorganic base as component, it is also possible to obtain high oil displacement efficiency and washing oil ability. Therefore, according to one preferred embodiment of the invention, described displacement composition used for tertiary oil recovery does not comprise (or not intentionally adding) inorganic base as component. As described inorganic base, this area conventional use of inorganic alkaline compound in displacement composition used for tertiary oil recovery, especially alkali-metal carbonate such as sodium carbonate, sodium bicarbonate etc. such as can be enumerated.

According to the present invention, described displacement composition used for tertiary oil recovery can be manufactured by following manufacture method.

According to the present invention, the manufacture method of described displacement composition used for tertiary oil recovery includes the step making the aforesaid anionic-cationic-nonionic surfactant of the present invention mix (to uniformly) with water (and the additive used as required). Now, the consumption of described anionic-cationic-nonionic surfactant and described additive regulation in the past.

According to the present invention, described anionic-cationic-nonionic surfactant or described displacement composition used for tertiary oil recovery may be used for tertiary oil recovery method, and demonstrate the oil displacement efficiency compared with prior art improved and washing oil ability (such as can more than 40% to the washing oil rate of crude oil), thus can significantly improve oil recovery factor. In consideration of it, the invention still further relates to a kind of tertiary oil recovery method, including the step using the aforesaid anionic-cationic-nonionic surfactant of the present invention or the aforesaid displacement composition used for tertiary oil recovery of the present invention to carry out tertiary oil recovery as displacing fluid.

According to a preferred embodiment of the present invention, when carrying out described tertiary oil recovery method, do not use or do not intentionally add inorganic base. Therefore, stratum and oil well are not injured by the tertiary oil recovery method of the present invention, it is to avoid the corrosion of equipment and pipeline, and do not result in breakdown of emulsion difficulty.

According to the present invention, described anionic-cationic-nonionic surfactant or displacement composition used for tertiary oil recovery are soluble in water, even at high temperature, water also is able to formed and stablizes and the aqueous solution of clear, and do not precipitate the excellent in stability of generation, chemical composition and interfacial activity. It addition, the clear state of this aqueous solution can (even at high temperature) keep steadily in the long term, thus show the long-term chemical composition stability of excellence. And, according to currently preferred it is, described anionic-cationic-nonionic surfactant, displacement composition used for tertiary oil recovery or its aqueous solution are even across long-term (particularly at high temperature) storage, its interfacial activity is also kept substantially stable, thus shows the long-term interfacial activity stability of excellence.

According to the present invention, (namely described anionic-cationic-nonionic surfactant in use (substantially) does not have chromatographic isolation phenomenon, do not have Component seperation phenomenon), use the excellent in stability of middle chemical composition and interfacial activity.

Embodiment

Hereinafter adopt embodiment and comparative example that the present invention is described in further detail, but the present invention is not limited to these embodiments.

[embodiment 1]

20 moles of dodecyl polyanilines and 2 moles of chloromethanes being added utilizes chromatographic technique to purify (4-dodecylphenyl) methyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of (4-dodecylphenyl) methyl amine and 0.1 molar potassium hydroxide are added in reactor and is warming up to 80 DEG C, it is decompressed to vacuum 0.9, stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. the temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 mol propylenoxy is added in reactor, after reacting 5 hours, obtain etherification product. the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, 1.1 moles of quaternizing agent chloromethanes are added with the nitrogen of 0.8MPa pressure, react 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chloromethanes and etoh solvent obtains quaternized products (namely cation-nonionic surfactant, as follows). by 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C, it is stirred continuously, utilize the moisture being azeotroped off in reaction system that quaternized products changes into corresponding potassium salt, it is subsequently adding after 1.1 moles of carboxylating agent sodium chloroacetates react 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt, then product is dissolved in a large amount of dehydrated alcohol, it is filtered to remove the inorganic salt in product, decompression obtains anionic-cationic-nonionic surfactant after etoh solvent is distilled off, its particular chemical is in the 1-1 in Table 1, its proton nmr spectra is in Table 5.

[embodiment 2]

20 moles of 4-nonyl aniline and 2 moles of chloromethanes being added utilizes chromatographic technique to purify (4-nonyl phenyl) methyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours.1 mole of (4-nonyl phenyl) methyl amine and 0.1 molar potassium hydroxide are added in reactor and is warming up to 80 DEG C, it is decompressed to vacuum 0.9, stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 moles of ethylene oxide is added in reactor, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chloromethanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chloromethanes and etoh solvent obtains quaternized products. Then by 1 mole of quaternized products and 10 liters of solvent benzols and 1.1 molar potassium hydroxide addition reactor, it is warming up to 80 DEG C to be stirred continuously, azeotropic is utilized to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate, 1.1 moles of carboxylating agent sodium chloroacetates are added in reactor, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with ammonia, product is changed into corresponding ammonium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-2 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 3]

20 moles of 9-oleyl amines and 2 moles of allyl chlorides being added utilizes chromatographic technique to purify (9-vaccenic acid base) allyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. It is decompressed to vacuum 0.9 by 1 mole of (9-vaccenic acid base) allyl amine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 49 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 37 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-3 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 4]

20 moles of isotridecyl aniline and 2 moles of benzyl chlorides being added utilizes chromatographic technique to purify isotridecyl benzyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours.1 mole of isotridecyl benzyl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 39 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 41 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent benzyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent benzyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with calcium hydroxide aqueous solution, product changed into corresponding calcium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-4 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 5]

20 moles of dinonyl benzylamines and 2 moles of 2 cbloropropane isopropyl chlorides being added utilizes chromatographic technique to purify different (dinonyl benzyl) isopropylamine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of dinonyl benzylamine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 39 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of 2 cbloropropane isopropyl chlorides of quaternizing agent with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent 2 cbloropropane isopropyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with magnesium hydroxide aqueous solution, product changed into corresponding magnesium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-5 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 6]

20 moles of dodecyl benzylamines and 2 moles of ethyl chloride being added utilizes chromatographic technique to purify (dodecylbenzyl) ethylamine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of (dodecylbenzyl) ethylamine and 0.1 molar potassium hydroxide are added in reactor and is warming up to 80 DEG C, it is decompressed to vacuum 0.9, stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 21 moles of ethylene oxide is added in reactor, with the nitrogen of 0.8MPa pressure, 17 mol propylenoxy are added reaction kettle for reaction after reacting 5 hours and obtain etherification product in 5 hours. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent ethyl chloride with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent ethyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-6 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 7]

1 mole of dodecyl-3-Methyl anthranilate, 2 moles of isopropanolamines and 0.1 molar potassium hydroxide are added in reactor, is warmed up to 180 DEG C, after reacting 5 hours, utilize chromatographic technique to purify dodecyl-3-amino benzoyl isopropyl alcohol radical amine. 1 mole of dodecyl-3-amino benzoyl isopropyl alcohol radical amine and 0.1 molar potassium hydroxide are added reactor and is decompressed to vacuum 0.9; stir 30 minutes and remove volatile components; with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 11 mol propylenoxy is added in reactor, after 27 moles of ethylene oxide being added reaction kettle for reaction 5 hours with the nitrogen of 0.8MPa pressure again after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with ammonia, product changed into corresponding ammonium salt.Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-7 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 8]

10 moles of 5-eicosyl m-diaminobenzene .s and 20 moles of benzyl chlorides being added utilizes chromatographic technique to purify N, N after being warming up to 80 DEG C of reactions in reactor 5 hours '-dibenzyl-5-eicosyl m-diaminobenzene.. By 1 mole of N, N '-dibenzyl-5-eicosyl m-diaminobenzene. and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C, are decompressed to vacuum 0.9, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 2 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 48 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent benzyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent benzyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of sulfonating agent chloromethylsulfonic acid sodium are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 1-8 in Table 1, and its proton nmr spectra is in Table 5.

[embodiment 9]

20 moles of lauryl amines and 2 moles of chloromethanes being added utilizes chromatographic technique to purify dodecyl methyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of dodecyl methyl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 mol propylenoxy is added in reactor, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chloromethanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chloromethanes and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt.Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-1 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 10]

20 moles of oleyl amines and 2 moles of chloromethanes being added utilizes chromatographic technique to purify 9-vaccenic acid ylmethyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of 9-vaccenic acid ylmethyl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 moles of ethylene oxide is added in reactor, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chloromethanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chloromethanes and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with ammonia, product changed into corresponding ammonium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-2 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 11]

20 moles of rosin amines and 2 moles of 1-chloro octanes being added utilizes chromatographic technique to purify abietyl octyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of abietyl octyl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 49 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 37 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1 mole of quaternizing agent 1-chloro octane with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary etoh solvent and obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with magnesium hydroxide aqueous solution, product changed into corresponding magnesium salt.Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-3 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 12]

20 moles of isotridecyl amine and 2 moles of allyl chlorides being added utilizes chromatographic technique to purify isotridecyl allyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of isotridecyl allyl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 25 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 17 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with calcium hydroxide aqueous solution, product changed into corresponding calcium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-4 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 13]

5 moles of lysine methyl esters and 10 moles of monoethanolamine being added utilizes chromatographic technique purification to obtain lysine single ethanol amide after being warmed up to 180 DEG C of reactions in reactor 5 hours. 5 moles of lysine single ethanol amides and 10 moles of 1-chloro octanes being added utilizes chromatographic technique purification to obtain N, N after being warming up to 80 DEG C of reactions in reactor 5 hours '-dioctyl lysine single ethanol amide. By 1 mole of N, N '-dioctyl lysine single ethanol amide and potassium hydroxide addition reactor are warming up to 80 DEG C, are decompressed to vacuum 0.9, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 39 moles of ethylene oxide is added in reactor, with the nitrogen of 0.8MPa pressure, 15 mol propylenoxy are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2 moles of quaternizing agent 1-chloro octanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, removal of solvent under reduced pressure ethanol obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate.3.3 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with magnesium hydroxide aqueous solution, product changed into corresponding magnesium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic surfactant, and its particular chemical is in the 2-5 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 14]

20 moles of 18-amine. and 2 moles of benzyl chlorides being added utilizes chromatographic technique purification to obtain octadecyl benzyl amine after being warming up to 80 DEG C of reactions in reactor 5 hours. 1 mole of octadecyl benzyl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 25 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 17 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent benzyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes excess of solvent ethanol and obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with sodium hydroxide, product changed into corresponding ammonium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-6 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 15]

1 mole of lauryl amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 39 moles of ethylene oxide is added in reactor, with the nitrogen of 0.8MPa pressure, 1 mol propylenoxy is added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chlorocyclohexanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chlorocyclohexane and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt.Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-7 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 16]

1 mole of palmitin amine and 0.1 molar potassium hydroxide being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 mol propylenoxy is added in reactor, with the nitrogen of 0.8MPa pressure, 39 moles of ethylene oxide are added in reactor after reacting 5 hours, after reacting 5 hours, obtain etherification product. The solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of sulfonating agent chloromethylsulfonic acid sodium are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with calcium hydroxide aqueous solution, product changed into corresponding calcium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 2-8 in Table 2, and its proton nmr spectra is in Table 6.

[embodiment 17]

10 moles of 1-chlorinated dodecanes and 5 moles of ammonia are added in reactor and is warming up to 80 DEG C, chromatographic technique is utilized to purify two (dodecyl) amine after reacting 5 hours, then 1 mole of two (dodecyl) amine and 0.1 molar potassium hydroxide are added in reactor and be warming up to 80 DEG C, it is decompressed to vacuum 0.9, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 14 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 9 moles of ethylene oxide are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chloromethanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chloromethanes and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-1 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 18]

2 moles of 1-chlorooctadecanes and 20 moles of diethanolamine are added in reactor and is warming up to 80 DEG C, after reacting 5 hours, chromatographic technique is utilized to purify octadecyl diethanolamine, then 1 mole of octadecyl diethanolamine and 0.1 molar potassium hydroxide are added reactor and be warming up to 80 DEG C, it is decompressed to vacuum 0.9, stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 4 moles of ethylene oxide are added in reactor, with the nitrogen of 0.8MPa pressure, 22 mol propylenoxy are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1 mole of quaternizing agent 1-chlorinated dodecane with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes excess of solvent ethanol and obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-2 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 19]

20 moles of oleyl amines and 2 moles of 1-chlorinated dodecanes are added in reactor and is warming up to 80 DEG C, chromatographic technique is utilized to purify 1-(9-vaccenic acid base) lauryl amine after reacting 5 hours, then it is decompressed to vacuum 0.9 by 1 mole of 1-(9-vaccenic acid base) lauryl amine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 17 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 38 moles of ethylene oxide are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chlorocyclohexanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chlorocyclohexane and etoh solvent obtains quaternized products. Then by season 1 molar ammonium product, 10 liters of solvent benzols and 1.1 molar potassium hydroxide add in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away moisture content that reaction produces is until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with calcium hydroxide aqueous solution, product changed into corresponding calcium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-3 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 20]

2 moles of 1-chloro-9-vaccenic acids and 20 moles of diethanolamine are added in reactor and is warming up to 80 DEG C, after reacting 5 hours, chromatographic technique is utilized to purify (9-vaccenic acid base) diethanolamine, then it is decompressed to vacuum 0.9 by 1 mole of (9-vaccenic acid base) diethanolamine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 16 moles of ethylene oxide are added in reactor, with the nitrogen of 0.8MPa pressure, 49 mol propylenoxy are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1 mole of quaternizing agent 1-chlorinated dodecane with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary etoh solvent and obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-4 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 21]

11 mole of oleic acid methyl ester and 100 moles of ethylene diamine are added in reactor and is warming up to 180 DEG C; chromatographic technique is utilized to purify to obtain oleoyl ethylenediamine after reacting 5 hours; then 10 moles of oleoyl ethylenediamines and 1 mole of 1-chlorinated dodecane are added in reactor and be warming up to 80 DEG C, after reacting 5 hours, utilize chromatographic technique to purify 1-oleoyl-4-lauryl ethylenediamine. It is decompressed to vacuum 0.9 by 1 mole of 1-oleoyl-4-lauryl ethylenediamine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C; stir 30 minutes and remove volatile components; with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 2 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 39 moles of ethylene oxide are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chlorocyclohexanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chlorocyclohexane and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt.Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-5 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 22]

15 moles of methyl laurates and 150 moles of ethylene diamine are added in reactor and is warming up to 180 DEG C; after reacting 5 hours; chromatographic technique is utilized to purify 1-lauroyl ethylenediamine; then 12 moles of 1-lauroyl ethylenediamines and 1 mole of 1-chlorinated dodecane base are added in reactor and be warming up to 80 DEG C; after reacting 5 hours, chromatographic technique is utilized to purify 1-lauroyl-4-dodecyl ethylenediamine. It is decompressed to vacuum 0.9 by 1 mole of 1-lauroyl-4-dodecyl ethylenediamine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C; stir 30 minutes and remove volatile components; with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. Temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 16 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 22 moles of ethylene oxide are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent ethyl chloride with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent ethyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-6 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 23]

20 moles of methyl laurates and 200 moles of diethylenetriamines are added in reactor and is warming up to 180 DEG C; after reacting 5 hours; chromatographic technique is utilized to purify 1-lauroyl diethylenetriamine; then 2 moles of methyl laurates and 10 moles of 1-lauroyl diethylenetriamines are added in reactor and be warming up to 180 DEG C; after reacting 5 hours; chromatographic technique is utilized to purify 1,7-dilauroyl diethylenetriamine. By 1 mole 1; 7-dilauroyl diethylenetriamine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C and are decompressed to vacuum 0.9; stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 16 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 37 moles of ethylene oxide are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent ethyl chloride with the nitrogen of 0.8MPa pressure.Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent ethyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 1.1 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 1.1 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with ammonia, product changed into corresponding ammonium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-7 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 24]

30 moles of 1-chlorinated dodecanes and 300 moles of triethylene tetramines are added in reactor and is warming up to 80 DEG C; after reacting 5 hours; chromatographic technique is utilized to purify 1-lauryl triethylene tetramine; then 2 moles of methyl laurates and 20 moles of 1-lauryl triethylene tetramines are added in reactor and be warming up to 180 DEG C; after reacting 5 hours, chromatographic technique is utilized to purify 1-lauroyl-10-lauryl triethylene tetramine. 1 mole of 1-lauroyl-10-lauryl triethylene tetramine and potassium hydroxide are added in reactor and is warming up to 80 DEG C; it is decompressed to vacuum 0.9; stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 31 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 9 moles of ethylene oxide are added in reactor after reacting 5 hours, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 3.3 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 3.3 moles of sulfonating agent 2-chloroethyl sodium sulfonates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with calcium hydroxide aqueous solution, product changed into corresponding calcium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 3-8 in Table 3, and its proton nmr spectra is in Table 7.

[embodiment 25]

2 moles of 1-chlorinated dodecanes and 20 moles of ethylene diamine are added in reactor and is warming up to 80 DEG C, after reacting 5 hours, utilize chromatographic technique to purify 1-lauryl ethylenediamine. Then 1 mole of 1-lauryl ethylenediamine and 0.1 molar potassium hydroxide being added and be warming up to 80 DEG C in reactor and be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa.The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 23 mol propylenoxy are added in reactor, etherification product is obtained after 19 moles of ethylene oxide being added reaction kettle for reaction 5 hours with the nitrogen of 0.8MPa pressure after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 3.3 moles of quaternizing agent ethyl chloride with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent ethyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 3.3 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-1 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 26]

2 moles of 1-chloro-9-vaccenic acids and 20 moles of ethylene diamine are added in reactor and is warming up to 80 DEG C, after reacting 5 hours, utilize chromatographic technique to purify (9-vaccenic acid base) ethylenediamine. Then it is decompressed to vacuum 0.9 by 1 mole of (9-vaccenic acid base) ethylenediamine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C, stir 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 11 mol propylenoxy are added in reactor, after reacting 5 hours, 9 moles of ethylene oxide addition reaction kettle for reaction are obtained etherification product in 5 hours by the nitrogen of 0.8MPa pressure, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 3.3 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 3.3 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-2 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 27]

2 moles of methyl laurates and 20 moles of ethylene diamine are added in reactor and is warming up to 180 DEG C, after reacting 5 hours, utilize chromatographic technique to purify lauroyl ethylenediamine.Then 1 mole of lauroyl ethylenediamine being added in reactor and be warming up to 80 DEG C, be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 1 mol propylenoxy is added in reactor, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent benzyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent benzyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with ammonia, product changed into corresponding ammonium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-3 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 28]

2 mole of oleic acid methyl ester and 20 moles of ethylene diamine are added in reactor and is warming up to 80 DEG C, after reacting 5 hours, utilize chromatographic technique to purify 1-oleoyl ethylenediamine. Then 1 mole of 1-oleoyl base ethylenediamine and 0.1 molar potassium hydroxide being added and be warming up to 80 DEG C in reactor and be decompressed to vacuum 0.9, stir 30 minutes removing volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 47 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 32 moles of ethylene oxide are added reaction kettle for reaction after reacting 5 hours and obtain etherification product in 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 1.1 moles of quaternizing agent chlorocyclohexanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chlorocyclohexane and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 2010 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-4 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 29]

2 moles of 1-chlorinated dodecanes and 20 moles of monoethanolamine are added in reactor and is warming up to 180 DEG C, after reacting 5 hours, utilize chromatographic technique to purify N-lauryl monoethanolamine.Then 1 mole of N-lauryl monoethanolamine and 0.1 molar potassium hydroxide are added in reactor and be warming up to 80 DEG C, it is decompressed to vacuum 0.9, stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 41 mol propylenoxy are added in reactor, with the nitrogen of 0.8MPa pressure, 21 moles of ethylene oxide are added reaction kettle for reaction after reacting 5 hours and obtain etherification product in 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent allyl chlorides with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent allyl chloride and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 20 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with magnesium hydroxide aqueous solution, product changed into corresponding magnesium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-5 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 30]

2 moles of 1-chloro-9-vaccenic acids and 20 moles of monoethanolamine are added in reactor and is warming up to 180 DEG C, after reacting 5 hours, utilize chromatographic technique to purify N-vaccenic acid base monoethanolamine. Then 1 mole of N-vaccenic acid base monoethanolamine and 0.1 molar potassium hydroxide are added in reactor and be warming up to 80 DEG C, it is decompressed to vacuum 0.9, stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 31 mol propylenoxy are added in reactor, etherification product is obtained after 11 moles of ethylene oxide being added reaction kettle for reaction 5 hours with the nitrogen of 0.8MPa pressure after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent chlorocyclohexanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chlorocyclohexane and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaBr saline washing reaction product twice, with calcium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-6 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 31]

2 moles of methyl laurates and 20 moles of hydroxyethylethylene diamine are added in reactor and is warming up to 180 DEG C, after reacting 5 hours, utilize chromatographic technique to purify N-lauroyl-N '-hydroxyethylethylene diamine. Then 1 mole of N-lauroyl-N'-hydroxyethylethylene diamine and 0.1 molar potassium hydroxide are added in reactor and be warming up to 80 DEG C; it is decompressed to vacuum 0.9; stirring 30 minutes and remove volatile components, with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 42 mol propylenoxy are added in reactor, etherification product is obtained after 17 moles of ethylene oxide being added reaction kettle for reaction 5 hours with the nitrogen of 0.8MPa pressure after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent chlorocyclohexanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chlorocyclohexane and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 20 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of carboxylating agent sodium chloroacetates are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaI saline washing reaction product twice, with potassium hydroxide aqueous solution, product changed into corresponding potassium salt. Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-7 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 32]

2 mole of oleic acid methyl ester and 20 moles of hydroxyethylethylene diamine are added in reactor and is warming up to 180 DEG C, after reacting 5 hours, utilize chromatographic technique to purify N-oleoyl-N '-hydroxyethylethylene diamine. Then it is decompressed to vacuum 0.9 by 1 mole of N-oleoyl-N '-hydroxyethylethylene diamine and 0.1 molar potassium hydroxide addition reactor are warming up to 80 DEG C; stir 30 minutes and remove volatile components; with nitrogen displacement reaction gas reactor 4 times, adjustment reacting kettle inner pressure is 0.2MPa. The temperature of reaction system is risen to 220 DEG C, with the nitrogen of 0.8MPa pressure, 2 mol propylenoxy are added in reactor, etherification product is obtained after reacting 5 hours, the solution being dissolved in dehydrated alcohol by all etherification products being configured to 40% joins in reactor, adds 2.2 moles of quaternizing agent chloromethanes with the nitrogen of 0.8MPa pressure. Reacting 3��10 hours after reaction system is warming up to 80 DEG C, decompression removes unnecessary quaternizing agent chloromethanes and etoh solvent obtains quaternized products. Then 1 mole of quaternized products, 10 liters of solvent benzols and 2.2 molar potassium hydroxide are added in reactor, be warming up to 80 DEG C and be stirred continuously, utilize azeotropic to take away the moisture content of reaction generation until quaternized products changes into corresponding potassium alcoholate. 2.2 moles of sulfonating agent chloromethylsulfonic acid sodium are added in reactors, after reacting 5 hours, with hydrochloric acid, reactant is adjusted to acidity, with 15%NaCl saline washing reaction product twice, with sodium hydrate aqueous solution, product changed into corresponding sodium salt.Product being dissolved in a large amount of dehydrated alcohol, be filtered to remove the inorganic salt in product, decompression is distilled off solvent and obtains anionic-cationic-nonionic surfactant, and its particular chemical is in the 4-8 in Table 4, and its proton nmr spectra is in Table 8.

[embodiment 33]

Anionic-cationic-nonionic surfactant 0.30wt% embodiment 19 prepared is uniform with 0.15wt% polyacrylamide (molecular weight 26,000,000) aqueous solution, obtains displacement composition used for tertiary oil recovery.

Table 5 anionic-cationics-nonionic surfactant proton nmr spectra

Table 6 anionic-cationics-nonionic surfactant proton nmr spectra

Table 7 anionic-cationics-nonionic surfactant proton nmr spectra

Table 8 anionic-cationics-nonionic surfactant proton nmr spectra

[embodiment 34] surfactant interface active testing

Rotate with TX-500C and drip interfacial tensimeter mensuration surfactant and Shuanghe Oil Field IV5-11 series of strata oil water interfacial tension. Measuring temperature is 81 DEG C, and formation water is NaHCO₃Type, salinity is 7947mg/L, chloride ion content 2002mg/L, Ca²⁺Content 20mg/L, Mg²⁺Content 12.2mg/L, dosage of surfactant is 0.3wt%.

Table 9 surfactant and Shuan He oil field IV5-11 series of strata oil water interfacial tension

Embodiment is numbered	Interfacial tension (mN/m)
		1	0.01
2	0.02
		3	0.0006
4	0.0004
		5	0.0007
6	0.004
		7	0.0007
8	0.0006
		9	0.009
10	0.0009
		11	0.0004
12	0.0005
		13	0.0006
14	0.0007
		15	0.005
16	0.0007
		17	0.0004
18	0.005
		19	0.0003
20	0.006
		21	0.0007
22	0.0005
		23	0.0006
24	0.0007
		25	0.0006
26	0.0004
		27	0.04
28	0.0008
		29	0.0007
30	0.0006
		31	0.0005
32	0.08
		33	0.0003

As shown in Table 9, the surfactant except 1,2,27,32 embodiments all has good interfacial activity for Henan Oil Field. Embodiment 33 shows, after surfactant prepared by the present invention is composite with polymer, its interfacial activity is still good.

Surfactant formulatory prepared by embodiment 33 being become variable concentrations, respectively test and Shuanghe Oil Field IV5-11 series of strata oil water interfacial tension, result is in Table 10.

Table 10 variable concentrations surfactant 19 and Shuanghe Oil Field IV5-11 series of strata oil water interfacial tension

Dosage of surfactant (wt%)	0.01	0.02	0.05	0.1	0.2	0.3
							Interfacial tension (MN/m)	0.006	0.003	0.0009	0.0004	0.0003	0.0003

The above results shows, surfactant of the present invention has significantly high interfacial activity for Henan Oil Field crude oil.

Rotate with TX-500C and drip an interfacial tensimeter and again measure the embodiment 1-4 compound surfactant prepared and Zhongyuan Oil Field and recover the oil three factory's oil water interfacial tensions. Measuring temperature is 80 DEG C, and formation water salinity is 79439mg/L, Ca²⁺Content 592mg/L, Mg²⁺Content 2871mg/L, dosage of surfactant is 0.3wt%. Oil water interfacial tension is 0.003mN/m, it was shown that the surfactant of the present invention, not only for low mineralization oil reservoir, still has good interfacial activity, has the advantage that the scope of application is wide simultaneously for high temperature and high salt oil deposit.

[embodiment 35] surfactant washing oil aptitude tests

Take Shuanghe Oil Field IV5-11 series of strata oil-sand, according to oil: sand=1: 4 (weight ratios) are aging 7 days at 81 DEG C, within every 2 hours, stir 5 minutes; Then take out above-mentioned aging after oil-sand 5g, with the surfactant solution of 0.3wt% by oil-sand: solution weight is mixed homogeneously than=1: 10, under reservoir temperature after aging 48 hours, with the crude oil in petroleum ether extraction solution, with 50ml color comparison tube constant volume, spectrophotometer is in wavelength 430nm place's colorimetric analysis. Utilize standard curve gauging surface activator solution Crude Oil concentration.

Table 11 surfactant washing oil result

Embodiment is numbered	Washing oil rate %
		1	39%
2	31%
		3	68%
4	77%
		5	66%
6	51%
		7	65%
8	67%
		9	49%
10	61%
		11	73%
12	71%
		13	66%
14	64%

15	49%
		16	65%
17	73%
		18	46%
19	81%
		20	48%
21	63%
		22	73%
23	67%
		24	66%
25	69%
		26	78%
27	28%
		28	60%
29	63%
		30	66%
31	74%
		32	25%
33	81%

[embodiment 36] surfactant flooding performance study

Being 30 centimetres in length, diameter is 2.5 centimetres, and permeability is 1.5 microns²Rock core on carry out oil displacement test.First being driven to oil-free with Shuanghe Oil Field IV5-11 series of strata formation water to produce, after the surfactant of tuberculosis 0.3PV (rock pore volume), then water drive produces to oil-free, improves oil recovery factor result in Table 7.

Table 12 surfactant flooding result of the test

Embodiment is numbered	Improve recovery ratio %
		1	2.8%
2	2.5%
		3	4.9%
4	8.9%
		5	4.7%
6	4.1%
		7	5.5%
8	5.6%
		9	4.0%
10	5.0%
		11	7.5%
12	7.1%

13	6.7%
		14	6.4%
15	4.0%
		16	6.5%
17	7.1%
		18	4.2%
19	9.7%
		20	4.1%
21	6.4%
		22	7.0%
23	5.6%
		24	6.7%
25	6.9%
		26	9.0%
27	1.8%
		28	6.1%
29	6.5%
		30	6.8%
31	7.2%
		32	1.2%
33	10.9%

The Journal of Sex Research steady in a long-term of [embodiment 37] surfactant

Surfactant Henan Oil Field in embodiment double; two rivers IV5-11 series of strata formation water is configured to the solution of 0.3%wt, being positioned in constant temperature oven, 81 DEG C of difference take out the interfacial tension of outward appearance the test solution observing solution from calorstat after aging 1 day, 1 month, 2 months, 3 months. The ability dripping interfacial tensimeter mensuration surfactant reduction Shuanghe Oil Field IV5-11 series of strata oil/water interfacial tension is rotated with TX-500C. Measuring temperature is 81 DEG C, and formation water is NaHCO₃Type, salinity is 7947mg/L, chloride ion content 2002mg/L, Ca²⁺Content 20mg/L, Mg²⁺Content 12.2mg/L result is in Table 13, and wherein the unit of interfacial tension is mN/m.

The long-term stable experiment result of table 13 surfactant

Even according to these experimental datas it can be seen that the anionic-cationic-nonionic surfactant of the present invention at high temperature, also has good dissolubility in water, and in situations where it is preferred, demonstrating the long-term interfacial activity stability of excellence.

The chromatograph effect study of [embodiment 38] anionic-cationic-nonionic surfactant

Surfactant Henan Oil Field in embodiment double; two rivers IV5-11 series of strata formation water is configured to the solution of 0.3%wt. Filling thin tube model with IV5-11 series of strata oil-sand+70% quartz sand mixing of 30% Henan Oil Field double; two rivers, capillary inside diameter is 0.4cm, and length is 4.5 meters. Mixed sand model has carried out following chromatograph effect experiment: 1) (1# experiment) inject preparation surfactant solution 2PV; 2) compound system (paper mill wastewater: NaOH, 2000mg/L) of (2# experiment) injection surfactant solution+alkali; 3) (3# experiment) first inject the formation water 1PV of 2000mg/lNaOH, reinject compound system (paper mill wastewater: the NaOH of surfactant solution+alkali; 2000mg/L), flow velocity: 0.2mL/min is injected. After the compound system injecting certain slug, carry out water drive with the formation water of same flow, collect effluent. With the change long-pending along with injecting liquid of surfactant concentration in high performance liquid chromatography (HPLC) and total organic carbon analyzer (TOC) simultaneous determination effluent. If there is separated surface active agent composition, calculate the response rate of each surface active agent composition respectively according to injection rate and quantum of output. Formula is as follows

If there is multiple surface active agent compositions, then with one of them for standard, other all of component all with compared with the surfactant component of standard. Experimental result is in Table 14.

The chromatograph effect experiment result of table 14 anionic-cationics-nonionic surfactant

According to these experimental results it can be seen that the anionic-cationic-nonionic surfactant of the present invention does not have chromatographic isolation phenomenon.

[comparative example 1]

According to Northwest University's journal (natural science edition) volume the 1st phase February the 30th in 2000, cetyl trimethylammonium bromide (CTAB) and sodium lauryl sulphate (SDS) are configured to mixed system (mol ratio 1: 1.5) by the methods such as 28��31 Gong Yu armies, test respectively its when 0.3wt% consumption with Shuanghe Oil Field IV5-11 series of strata crude oil oil water interfacial tension, washing oil rate and Oil Displacing Capacity, result is as follows:

Table 15 reference oil displacement agent performance

Interfacial tension (MN/m)	Washing oil rate % improves recovery ratio %
		0.03	45.62.8

[comparative example 2]

According to petroleum gas journal volume the 4th phase August the 29th in 2007, (101��104) method such as Huang Hong degree etc. is by 0.01wt% cetyl trimethylammonium bromide and 0.02wt% anion surfactant petroleum sulfonate and 1.8wt%Na₂CO₃Be configured to mixed system, test respectively its when 0.3wt% consumption with Shuanghe Oil Field IV5-11 series of strata crude oil oil water interfacial tension, washing oil rate and Oil Displacing Capacity, result is as follows:

Table 16 reference oil displacement agent performance

Interfacial tension (MN/m)	Washing oil rate %	Improve recovery ratio %
			0.008	56.3	4.2

Although the specific embodiment of the present invention has been described in detail above in conjunction with the embodiments, it should be noted however that protection scope of the present invention is not limited to these specific embodiments, but determined by claims of annex. These embodiments can be carried out suitable change in without departing from the technological thought of the present invention and the scope of purport by those skilled in the art, and these change after embodiment be obviously also included within protection scope of the present invention.

Claims (13)

1. anionic-cationic-nonionic surfactant, it is characterised in that at least one in substantially compound as shown in following formula (I),

In formula (I), group N⁺It it is quaternary nitrogen cation; Group R₁To R₃It is same to each other or different to each other, is each independently selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted C_6-50(preferred C_6-20) aryl and by formulaThe group represented, premise is group R₁To R₃In at least one be by formulaThe group represented, so-called " optionally substituted " herein, refer to optionally by one or more selected from oxo, hydroxyl, by formulaThe group of representative, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-); Group Link is selected from optionally substituted x+1 valency C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted x+1 valency C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted x+1 valency C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted x+1 valency C_6-50(preferred C_6-20) aryl and optionally substituted x+1 valency C_3-50(preferred C_3-20) the assorted alkyl of straight or branched;Each group Poly is same to each other or different to each other, and is each independently selected from formulaThe group represented; Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); X is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Between each group Poly, each numerical value y is same to each other or different to each other, and is each independently selected from any number (preferably any number between 0 to 100) between 0 to 200, and premise is that x numerical value y sum is more than 0; Between each group Poly, each group Ru is same to each other or different to each other, and is each independently selected from C_2-6Straight or branched alkylidene (is preferably each independently selected from-CH₂-CH₂-and-CH₂-CH(CH₃)-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Wherein, when not clear and definite especially, so-called " optionally substituted ", refer to optionally by one or more selected from oxo, hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) substituent group of aryl replaces, and, the assorted alkyl of described straight or branched is selected from one or more group-CH of straight or branched alkyl molecule inside configuration₂-be selected from-O-,-S-,-NR '-(wherein, group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl) and(wherein, group N⁺It it is quaternary nitrogen cation; Group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) one of the group that substitutes directly substitute and the group that obtains; And one or more groups of straight or branched alkyl molecule inside configurationSubstituted groupOr(wherein, group N⁺It it is quaternary nitrogen cation; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) directly substitute and the group that obtains,

Premise is, described group R₁, described group R₂, described group R₃In its structure, C is comprised with at least one in described group Rh₈Straight-chain part.

2. anionic-cationic-the nonionic surfactant described in claim 1, wherein each group Poly is each independently selected from formulaThe ether segment represented; Between each group Poly, each numerical value m is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50; Between each group Poly, each numerical value n is same to each other or different to each other, and is each independently selected from any number between 0 to 100, it is preferable that any number between 0 to 50, and premise is whole numerical value m with whole numerical value n sums more than 0; Preferably, whole numerical value m sums more than 0 and less than 100 (preferably more than 50) and/or all numerical value n sum more than 0 and less than 100 (preferably more than 50).

3. anionic-cationic-the nonionic surfactant described in claim 1, selected from substantially compound as shown in following formula (I-1), substantially compound as shown in following formula (I-2), substantially compound as shown in following formula (I-3) and the substantially at least one in compound as shown in following formula (I-4), and additional conditions are: at least one atom N in these molecular structure of compounds is bonded with other group Rh and group X and is rendered as formula(wherein, group N⁺It it is the quaternary nitrogen cationic form of at least one atom N described; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) shown in quaternary ammonium salt and/or the form of quaternary ammonium base,

In formula (I-1), each group Ra is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-10Aryl; Each group Ra ' is same to each other or different to each other, and is each independently selected from singly-bound, optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, carbonyl, optionally substituted C_1-10Straight or branched alkylenecarbonyl and optionally substituted C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from singly-bound and optionally substituted C_1-6Straight or branched alkylidene; B is the arbitrary integer between 1 to 3, it is preferable that 1; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a=1, when group Y is O, and a=0, and at least one group Y is N; X ' is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 5; Each group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp₁It it is formulaThe group represented; Each group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl;Each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ', whole numerical value m ", " sum is more than 0 and less than 200 (being preferably greater than 0 and less than 100) with whole numerical value n for whole numerical value n ', each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Ra and at least one in described group Rh comprise C in its structure₈Straight-chain part,

In formula (I-2), group Rb is selected from optionally substituted C_1-49Straight or branched alkyl, optionally substituted C_5-49Monocycle or polycyclic naphthene base and optionally substituted C_2-49Straight or branched thiazolinyl (is preferably selected from optionally substituted C_1-29Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base and optionally substituted C_2-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-29Straight or branched alkyl, optionally substituted C_5-8Monocycle or polycyclic naphthene base and optionally substituted C_8-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-19Straight or branched alkyl, optionally substituted C_5-7Monocyclic cycloalkyl (such as cyclohexyl) and optionally substituted C_8-19Straight or branched thiazolinyl); Each group Rb ' is same to each other or different to each other, and is each independently selected from singly-bound and carbonyl; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a=1, when group Y is O, and a=0, and at least one group Y is N; X " is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp₁It it is formulaThe group represented; Each group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ', whole numerical value m ", " sum is more than 0 and less than 200 (being preferably greater than 0 and less than 100) with whole numerical value n for whole numerical value n ',Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Rb and at least one in described group Rh comprise C in its structure₈Straight-chain part,

In formula (I-3), each group Rc is same to each other or different to each other, and is each independently selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl); Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); X " ' it is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp is same to each other or different to each other, and is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp is formulaThe group represented; Each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ' with whole numerical value n ' sums more than 0 and less than 200 (being preferably greater than 0 and less than 100); Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-);Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Rc and at least one in described group Rh comprise C in its structure₈Straight-chain part,

In formula (I-4), group Rc is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl); Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); Group Y is N or O, and premise is when group Y is N, a=1, when group Y is O, and a=0; X " " is arbitrary integer between 1 to 9 (the preferably arbitrary integer between 1 to 3, more preferably 1 or 2); Each group Rp₁It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp₁It it is formulaThe group represented; Each group Rp₂It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Each group Rp₃It is same to each other or different to each other, is each independently selected from formulaThe group of representative, hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, each numerical value m ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n ' is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " is same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value m " ' be same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, each numerical value n " ' be same to each other or different to each other, it is each independently selected from any number between 0 to 100, the preferably any number between 0 to 50, premise is whole numerical value m ', whole numerical value m ", whole numerical value m " ', whole numerical value n ', whole numerical value n " with whole numerical value n " ' sum is more than 0 and less than 200 (being preferably greater than 0 and less than 100),Each group L is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene); Each group Salt is same to each other or different to each other, and is each independently selected from by-A^-(M)_r ⁺The group represented, wherein group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M is selected from alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M is alkali metal or ammonium root, r=1; When group M is alkaline-earth metal, r=0.5,

Premise is, described group Rc and at least one in described group Rh comprise C in its structure₈Straight-chain part,

Wherein, described optionally substituted refer to optionally by one or more selected from hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace.

4. anionic-cationic-the nonionic surfactant described in claim 1, wherein said group X^-With described group (M)_r ⁺In at least some of with (M)_r ⁺X^-Form exist independent of described anionic-cationic-nonionic surfactant, it is preferred that in the whole molecular structure of described anionic-cationic-nonionic surfactant, if described group X^-Total number be e1, described group N⁺Total number be e2, described group A^-Total number be e3, described group (M)_r ⁺Total number be e4, as e2=e3,0��e1��e2,0��e4��e3, as e2 > e3,0 < e1��e2,0��e4��e3, as e2 < e3,0��e1��e2,0 < e4��e3, but premise is e1+e3=e2+e4, or, e2=e3, e1=0, e4=0.

5. the manufacture method of anionic-cationic-nonionic surfactant, it is characterised in that comprise the following steps:

Step (1): make one or more nitrogenous and with one or more selected from-OH ,-NH₂React under the existence of base catalyst (preferred alkali metal hydroxide) with the alkylene oxide shown in one or more following formulas (Y) with the polyfunctional compound of the functional group of-NH-, it is thus achieved that etherification product,

In formula (Y), group Ru ' is selected from C_2-6Straight or branched alkylidene (is preferably selected from-CH₂-CH₂-and-CH₂-CH(CH₃)-),

Step (2): make described etherification product and the quaternizing agent shown in following formula (A) react, it is derived from cation-nonionic surfactant, the consumption of wherein said quaternizing agent makes at least one atom N in described etherification product molecular structure form quaternary ammonium salt group

Rh-X��(A)

In formula (A), group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X ' selected from halogen (preferred fluorine, chlorine, bromine and iodine, more preferably chlorine),

Premise is, described polyfunctional compound comprises C with at least one in described quaternizing agent in its molecular structure₈Straight-chain part,

Step (3): make described cation-nonionic surfactant and the compound shown in one or more following formulas (Z) react under the existence of base catalyst (preferred alkali metal hydroxide), it is derived from anionic-cationic-nonionic surfactant

G-L-AS(Z)

In formula (Z), group G is selected from halogen (preferred fluorine, chlorine, bromine and iodine, more preferably chlorine) and hydroxyl;Group L is selected from optionally substituted C_1-10Straight or branched alkylidene and optionally substituted C_2-10Straight or branched alkenylene (is preferably selected from optionally substituted C_1-5Straight or branched alkylidene); Group AS choosing freely-A^-(M��)_r ⁺The group represented; Group A^-Selected from carboxylate radical (COO^-) and sulfonate radical (SO₃ ^-); Group M ' is selected from hydrogen, alkali metal (preferred Li, Na and K), alkaline-earth metal (preferred Mg and Ca) and ammonium root (NH₄); When group M ' be hydrogen, alkali metal or during ammonium root, r=1; When group M ' is for alkaline-earth metal, r=0.5,

Optionally, step (4): at least some of quaternary ammonium salt group in the anionic-cationic-nonionic surfactant obtained by the arbitrary steps of described manufacture method is converted to corresponding quaternary ammonium base group, and/or, at least some of quaternary ammonium base group in described anionic-cationic-nonionic surfactant is converted to corresponding quaternary ammonium salt group

Optionally, step (5): isolate the compound (M ') that at least some of (preferably whole) exist in a free form from anionic-cationic-nonionic surfactant that the arbitrary steps of described manufacture method obtains_rX ',

Wherein, described optionally substituted refer to optionally by one or more selected from hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace.

6. the manufacture method described in claim 5, wherein said polyfunctional compound at least one in the compound shown in following formula (X),

In formula (X), group R '₁To R '₃It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted C_6-50(preferred C_6-20) aryl and by formulaThe group represented, premise is group R '₁To R '₃In at least one be hydrogen or by formulaThe group represented, so-called " optionally substituted " herein, refer to optionally by one or more selected from oxo, hydroxyl, by formulaThe group of representative, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace; Group L_ASelected from optionally substituted x0+1 valency C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted x0+1 valency C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (preferred C_5-7Monocyclic cycloalkyl is cyclohexyl such as), optionally substituted x0+1 valency C_2-50(preferred C_2-20) straight or branched thiazolinyl, optionally substituted x0+1 valency C_6-50(preferred C_6-20) aryl and optionally substituted x0+1 valency C_3-50(preferred C_3-20) the assorted alkyl of straight or branched; X0 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Func is same to each other or different to each other, and is each independently selected from-OH, > NH and-NH₂, and, the assorted alkyl of described straight or branched is selected from one or more group-CH of straight or branched alkyl molecule inside configuration₂-be selected from-O-,-S-,-NR '-(wherein, group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl) and(wherein, group N⁺It it is quaternary nitrogen cation;Group R ' is selected from optionally substituted C_1-20(preferred C_1-10) straight or branched alkyl, optionally substituted C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base, optionally substituted C_2-20(preferred C_2-10) straight or branched thiazolinyl and optionally substituted C_6-20(preferred C_6-10) aryl; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) one of the group that substitutes directly substitute and the group that obtains; And one or more groups of straight or branched alkyl molecule inside configurationSubstituted groupOr(wherein, group N⁺It it is quaternary nitrogen cation; Group Rh is selected from optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Group X^-Selected from halide ion (preferred fluorion, chloride ion, bromide ion and iodide ion, more preferably chloride ion) and hydroxide ion (OH^-)) directly substitute and the group that obtains,

Described polyfunctional compound is preferably selected from the compound shown in the compound shown in the compound shown in following formula (X-1), following formula (X-2), following formula (X-3) and at least one in the compound shown in following formula (X-4)

In formula (X-1), each group Ra is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl and optionally substituted C_6-20Aryl; Each group Ra ' is same to each other or different to each other, and is each independently selected from singly-bound, optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, carbonyl, optionally substituted C_1-10Straight or branched alkylenecarbonyl and optionally substituted C_2-10Straight or branched alkenylene carbonyl, it is preferable that be each independently selected from singly-bound and optionally substituted C_1-6Straight or branched alkylidene; B is the arbitrary integer between 1 to 3, it is preferable that 1; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a1=1, when group Y is O, and a1=0, and at least one group Y is N; X1 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 5; Each group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp '₁It is hydrogen; Each group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl,

In formula (X-2), group Rb is selected from optionally substituted C_1-49Straight or branched alkyl, optionally substituted C_5-49Monocycle or polycyclic naphthene base and optionally substituted C_2-49Straight or branched thiazolinyl (is preferably selected from optionally substituted C_1-29Straight or branched alkyl, optionally substituted C_5-10Monocycle or polycyclic naphthene base and optionally substituted C_2-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-29Straight or branched alkyl, optionally substituted C_5-8Monocycle or polycyclic naphthene base and optionally substituted C_8-29Straight or branched thiazolinyl, or selected from optionally substituted C_8-19Straight or branched alkyl, optionally substituted C_5-7Monocyclic cycloalkyl (such as cyclohexyl) and optionally substituted C_8-19Straight or branched thiazolinyl);Each group Rb ' is same to each other or different to each other, and is each independently selected from singly-bound and carbonyl; Each group Y is same to each other or different to each other, and is each independently selected from N and O, and premise is when group Y is N, a2=1, when group Y is O, and a2=0, and at least one group Y is N; X2 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp '₁It is hydrogen; Each group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl,

In formula (X-3), each group Rc is same to each other or different to each other, and is each independently selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl); Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); X3 is the arbitrary integer (the preferably arbitrary integer between 1 to 4, such as 1,2 or 3) between 1 to 10; Each group Rp ' is same to each other or different to each other, and is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp ' is hydrogen,

In formula (X-4), group Rc is selected from optionally substituted C_1-20Straight or branched alkyl, optionally substituted C_2-20Straight or branched thiazolinyl, optionally substituted C_1-20Straight or branched alkyl-carbonyl and optionally substituted C_2-20Straight or branched alkenyl carbonyl (or it is each independently selected from optionally substituted C_1-10Straight or branched alkyl, optionally substituted C_2-10Straight or branched thiazolinyl, optionally substituted C_1-10Straight or branched alkyl-carbonyl and optionally substituted C_2-10Straight or branched alkenyl carbonyl, or it is each independently selected from optionally substituted C_8-20Straight or branched alkyl, optionally substituted C_8-20Straight or branched thiazolinyl, optionally substituted C_8-20Straight or branched alkyl-carbonyl and optionally substituted C_8-20Straight or branched alkenyl carbonyl);Each group Rd is same to each other or different to each other, and is each independently selected from optionally substituted C_1-10Straight or branched alkylidene, optionally substituted C_2-10Straight or branched alkenylene, optionally substituted C_1-10Straight or branched alkylenecarbonyl, optionally substituted C_2-10Straight or branched alkenylene carbonyl, optionally substituted carbonyl C_1-10Straight or branched alkylenecarbonyl and optionally substituted carbonyl C_2-10Straight or branched alkenylene carbonyl (is preferably each independently selected from optionally substituted C_1-5Straight or branched alkylidene and optionally substituted C_1-5Straight or branched alkylenecarbonyl); Group Y is N or O, and premise is when group Y is N, a4=1, when group Y is O, and a4=0; X4 is arbitrary integer between 1 to 9 (the preferably arbitrary integer between 1 to 3, more preferably 1 or 2); Each group Rp '₁It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl, premise is at least one group Rp '₁It is hydrogen; Each group Rp '₂It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl; Each group Rp '₃It is same to each other or different to each other, is each independently selected from hydrogen, optionally substituted C_1-50(preferred C_1-20) straight or branched alkyl, optionally substituted C_5-50(preferred C_5-10Or C_5-8) monocycle or polycyclic naphthene base (such as cyclohexyl), optionally substituted C_2-50(preferred C_2-20) straight or branched thiazolinyl and optionally substituted C_6-50(preferred C_6-20) aryl,

Wherein, when not clear and definite especially, so-called " optionally substituted ", refer to optionally by one or more selected from oxo, hydroxyl, C_1-20(preferred C_1-10) straight or branched alkyl, C_5-10(preferred C_5-8Or C_5-7) monocycle or polycyclic naphthene base (such as cyclohexyl), C_2-20(preferred C_2-10) straight or branched thiazolinyl and C_6-20(preferred C_6-10) aryl substituent group replace.

7. the mol ratio of the manufacture method described in claim 5, wherein said polyfunctional compound and described alkylene oxide is 1: 0-200 (preferably 1: 0-100), but does not include 0; The mol ratio of described polyfunctional compound and the compound shown in described formula (Z) is 1: 1-10 (preferably 1: 1-3); The reaction condition of described step (1) including: reaction temperature be room temperature to 300 DEG C (preferred 100-200 DEG C), the response time is 1-20 hour (preferred 1-10 hour); The reaction condition of described step (2) including: reaction temperature is 0-300 DEG C (preferred 50-150 DEG C), and the response time is 1-20 hour (preferred 4-15 hour); The reaction condition of described step (3) including: reaction temperature is 0-300 DEG C (preferred 50-200 DEG C), and the response time is 1-20 hour (preferred 4-10 hour).

8. the manufacture method described in claim 5, wherein said alkylene oxide at least includes expoxy propane, and makes described polyfunctional compound first and described propylene oxide reaction.

9. a displacement composition used for tertiary oil recovery, it is characterized in that, comprise the anionic-cationic-nonionic surfactant described in any one of Claims 1-4 or the anionic-cationic-nonionic surfactant of the manufacture of the manufacture method described in any one of claim 5 to 8, and water, wherein count with the gross weight of described displacement composition used for tertiary oil recovery for 100wt%, the weight percentage of described anionic-cationic-nonionic surfactant is 0.001-10wt%, preferred 0.005-5wt%, more preferably 0.02-1wt%.

10. the displacement composition used for tertiary oil recovery described in claim 9, does not wherein comprise inorganic base.

11. the manufacture method of a displacement composition used for tertiary oil recovery, it is characterized in that, anionic-cationic-nonionic surfactant that the anionic-cationic-nonionic surfactant described in any one of Claims 1-4 or the manufacture method described in any one of claim 5 to 8 manufacture is made at least to mix with water, wherein count with the gross weight of described displacement composition used for tertiary oil recovery for 100wt%, the weight percentage of described anionic-cationic-nonionic surfactant is 0.001-10wt%, preferred 0.005-5wt%, more preferably 0.02-1wt%.

12. a tertiary oil recovery method, it is characterized in that, carry out the step of tertiary oil recovery including the displacement composition used for tertiary oil recovery of the anionic-cationic-nonionic surfactant used described in any one of claim 1 to 4, the anionic-cationic-nonionic surfactant of manufacture method manufacture described in any one of claim 5 to 8, the displacement composition used for tertiary oil recovery described in claim 9 or 10 or the manufacture method manufacture described in claim 11 as displacing fluid.

13. the tertiary oil recovery method described in claim 12, wherein do not use inorganic base.