CN105633510B - Flow-type zinc/air fuel cell - Google Patents
Flow-type zinc/air fuel cell Download PDFInfo
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- CN105633510B CN105633510B CN201410718050.3A CN201410718050A CN105633510B CN 105633510 B CN105633510 B CN 105633510B CN 201410718050 A CN201410718050 A CN 201410718050A CN 105633510 B CN105633510 B CN 105633510B
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- Prior art keywords
- zinc
- pipeline
- electrode
- metal
- air
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The present invention relates to a kind of flow-type zinc/air fuel cells, including：The charging pipeline that electric discharge pipeline is connected to by an electric discharge pipeline and one collectively forms a closed pipeline, wherein, the pipeline that discharges includes a zinc electrode that flowable pureed pattern is presented, by the periphery one metal collector tube of cladding of zinc electrode, periphery one isolation film of cladding of metal collector tube, periphery one air electrode of cladding of isolation film, in one shell with multiple through-holes for entering air electrode for air of periphery cladding of air electrode, it discharges and is equipped with an at least driving device between pipeline and charging pipeline, after zinc electrode aoxidizes in the pipeline that discharges, zinc electrode is pushed in charging pipeline by driving device, zinc electrode is gradually reduced in the pipeline that charges, zinc electrode is pushed in electric discharge pipeline by driving device again, accordingly, the present invention forms a duration and recycles the redox reaction produced electricl energy.
Description
Technical field
The present invention carries out the fuel cell of redox reaction about a kind of Zinc material and air, espespecially a kind of by cathode
(anode) Zinc material is designed as the zinc/air fuel cell that flowable pureed pattern is reacted with air, allows fuel cell not
It must supplement or replace cathode (anode) material or can routinely carry out redox reaction in the case of removing waste material.
Background technology
The energy is the power of the national economic development, and weighs overall national strength, Civilization development degree and people's lives
Horizontal important indicator, the history of social progress show development of the strategic structural of energy technology each time all to productivity and
Social progress brings important and far-reaching change, it was demonstrated that energy science and technology is very important, has to the following new industry important
Influence power.
For 21st century, environmental protection, which has become under premised on human society Sustainable Development, to be concerned about at once
The public project in the world, be the core of sustainable development strategy, be influence our times various countries energy decision making and science and technology be oriented to
Key factor, meanwhile, it is also the huge motive force for promoting energy science and technology development, the huge energy system set up in 20th century
System can not adapt to requirement of the future society to efficient, cleaning, economic, safety energy system, and energy development is faced with huge
Big challenge.
With macromolecule battery hair and, the exploitation of new technology so that different types of macromolecule battery increases.Simultaneously
Due to extending to for application 3C Product field so that thinner and lighter, smaller battery also will be as the mainstream in market.With solid-state height
Molecule is the battery of solid electrolyte, has extraordinary advantage in safety, processability and under applied at elevated temperature, because
Without worrying electrolyte because of encapsulation is incomplete, or because of the long reduction for leading to isolation film electrolyte inside of battery standing time
Battery performance is influenced, and at high temperature using that can possess preferable performance, this namely solid-state polymer battery will be
Future battery hair and critically important breakthrough.
The type of battery can generally be divided into chemical cell and physical battery two major classes, and chemical cell can be sub-divided into
Three kinds of one-shot battery, secondary cell and fuel cell, wherein fuel cell is also referred to as continuous battery, and characteristic is positive and negative electrode
The presence of active material is had no, and must be constantly provided by outside and just can continuously be discharged, the part of positive (cathode)
Oxidation reaction is carried out by air 14 or oxygen, accordingly, the fuel cell of the environmental issues such as nonhazardous is also referred to as efficient green
The energy.
Development of human civilization is until latter stage in the 1970's, and efficient zinc-air battery is by industrial mass production and can be wide
In the general electronic product using low-power, such as：Hearing aid and calculator etc..The 1980's so far, large-scale zinc-air battery
Gradually become mainstream applications in automobile, generation nineteen ninety is more applied in electric vehicle.
And in all types of battery kenels, wherein zinc-air battery is now to enable all battery systems based on electrolyte
Energy density soprano in system, other than safe and reliable, zinc-air battery has been also equipped with low material cost and easily recycling, low dirt
The advantages that dye.General zinc-air battery is using potassium hydroxide as electrolyte, in order to improve the solubility of zinc oxide in the electrolytic solution
To prevent battery polarization phenomenon, the potassium hydroxide mole concentration that general zinc-air battery uses to may be up to 8 moles (M).
Being developed to the more common type of the prior art mainly as cathode (anode) by the old-fashioned monoblock spelter of tradition can divide
Be all non-rechargeable primary battery for zine plate type electrode 1 and zinc granule subtype electrode 2, refering to Figure 1, zine plate type be by
Zinc metal is made plate 11, mainly includes the zinc anode plate 12 and cathode plate 13 of a plate 11, the wherein zinc anode
Plate 12 is as cathode (anode) while as the fuel of zinc-air battery.The zinc-air battery is using the oxygen in air 14 as hydrogen original
The battery depolarizer of son, air 14 are entered in the zinc-air battery structure by the side diffusion of cathode plate 13.The zinc anode plate 12 1
As be accommodated in one full of electrolyte battery case in.This pattern battery can coordinate electricity by the zinc electrode for exchanging card box
It solves liquid and regenerates.The zinc anode plate 12 and cathode plate 13 have protruded out a connection lug respectively, for connecting lead wire.
Wherein, zine plate type electrode 1 is other than can be made by a closely knit zinc metallic plate, additionally it is possible to by a porosity
Zinc metallic plate made by (not shown).The manufacture of the zinc metallic plate of previous porous can be high by sintering, coating, mixing one
Zinc particle is fixed on and is completed on a netted inert metal substrate by the modes such as molecule adhesive, bonding or plating, aforementioned more
The hole size and distribution for the anode that the zinc metallic plate of permeability is constituted can influence the anode performance and its capacitance
Loss.
In contrast, it please refers to shown in Fig. 2, zinc granule subtype electrode 2 is applied in zinc-air battery monomer, with what is filled in
Zinc particle 21 or zinc powder (not shown) are as anode using as fuel, operation principle and the work of aforementioned zinc anode plate 12 are former
Manage it is similar, air 14 be similarly by cathode plate 13 side diffusion enter the zinc-air battery structure in, when the zinc particle 21
Or after zinc powder has reacted, as long as the battery cell can be made to continue to supply required electric power again by filling appropriate.
The zinc-air battery of zinc granule subtype electrode 2 is usually applied to miniature button cell, has and is used as electronic hearing aid
The special-purpose of battery pack, the hearing aid include programmable type hearing aid.Such compact battery is usually disk like cylinder
Shape.
However, existing zinc granule subtype electrode 2 with being that multiple zinc metallics is directly made to be scattered in an electrolyte 22
(electrolyte) in, along with a current collector is as electrode, to constitute a zinc-air battery, and to avoid such zinc
Metallic is precipitated to the bottom of the electrolyte 22, and influences the stability of electric discharge, it will usually which the electrolyte 22 can be made by being added one
Gelatinous additive is formed, such as：Carboxylic acid methyl cellulose (carboxymethyl cellulose), so that such zinc metal
Particle can be dispersed in the electrolyte 22.
Summarizing the missing that aforementioned prior art zinc-air battery all has is：(I) fuel by that will generate after completion of the reaction
Complete oxidation must replace or supplement fuel and there may be pollution environment waste material, extra padding or replacement must be subject to again
It；(II) fuel of anode is the pattern of solid-state or semisolid, the limited area of ingress of air reaction.
Invention content
The zinc electrode of zinc/air fuel cell is designed as a flowable sample the main purpose of the present invention is to provide a kind of
State makes electric discharge pipeline of the zinc electrode in closed pipeline and is circulated between charging pipeline, and routinely aoxidized
It discharges and turns reacting for electric energy with the chemical energy of reduction charging, thereby needn't supplement or replace the material of its inside battery, also will not
Generate excess waste, both economic and environment-friendly and no pollution.
The secondary objective of the present invention is that zinc/air fuel cell coordinates flowable formula zinc electrode using tubular design, works as zinc
Electrode is driven device effect and generates flowing variation, and the gross area contacted with oxygen will be significantly increased in still unreacted zinc electrode
Than the discharge power for promoting fuel cell in turn.
It is separately designed with charging pipeline another object of the present invention is to driving device and for a pair of of zinc oxide restore instead
The positive and negative electrode answered uses the circuit design of simplified zinc/air fuel cell.
To reach the purpose, flow-type zinc/air fuel cell of the present invention is made of a closed pipeline, described closed
Pipeline is connected to the charging pipeline of the electric discharge pipeline with an electric discharge pipeline and one, and it is flowable that the closed pipeline is equipped with one
And it is rendered as the zinc electrode of pureed pattern, it is equipped with an at least driving device between the electric discharge pipeline and charging pipeline, by described
Driving device pond continue property push the zinc electrode in the electric discharge pipeline and charge pipeline in flow, and the electric discharge pipeline into
One step is equipped with a pressue device for accelerating the zinc electrode flowing displacement.
Wherein, it includes that the compound of zinc metal or mixture are constituted that the zinc electrode, which is set as one, and the zinc metal can
It is set as one of zinc particle or zinc powder or its mixing.
Moreover, the driving device is driven with single direction and carried out back and forth by the driving source equipped with a driving source and one
The screw rod of displacement action.
After the zinc electrode aoxidizes in the electric discharge pipeline, the zinc electrode is pushed to institute by the driving device
It states in charging pipeline, the zinc electrode is gradually reduced in the charging pipeline, then by the driving device that the zinc is electric
Pole, which is pushed in the electric discharge pipeline, forms the redox reaction that duration cycle produces electricl energy.
Furthermore by the periphery one metal collector tube of cladding of the zinc electrode, the material of the metal collector tube is set as by copper
Or made by one of nickel, periphery one isolation film of cladding of the metal collector tube, the periphery of the isolation film coats
Pneumoelectric pole has the shell of multiple through-holes for entering the air electrode for air in the periphery cladding one of the air electrode,
The present invention is designed as the pattern of pipeline and enables air or oxygen with the characteristics of this is from being completely coated on another layer for one layer
By the institute of the outside of the present invention it is angled enter contacted with internal zinc electrode, then illustrate it, since zinc electrode of the invention is set
For flowable material and replacement can be flowed by zinc electrode by driving device and pressue device and actually touch anode (the moon
Pole) air or oxygen chance, significantly promote cathode (anode) and contact the area that positive (cathode) carries out oxidation reaction.
In addition, the present invention, in a preferred embodiment, the charging pipeline has a metal mesh being connect with the shell,
One group is set as by the screw rod and the metal mesh zinc electrode after the oxidation in the charging pipeline restore instead
The positive and negative electrode answered.
In contrast, the present invention is described to charge what pipeline was connect with one with the shell in another preferred embodiment
Metal tubes, and a hollow metal rod is further provided in the metal tubes, by the metal tubes and the metal
Rod piece is set as one group of positive and negative electrode that the zinc electrode after being aoxidized in the charging pipeline can be carried out to reduction reaction, wherein
There are multiple stomatas, the oxygen that zinc electrode after oxidation generates after carrying out reduction will enter metal rod on the metal rod surface
Stomata guiding discharge.
By preceding description it is found that the method have the characteristics that：After zinc electrode (cathode) flows through electric discharge pipeline oxidation electric discharge,
By driving device by zinc electrode by electric discharge pipeline be pushed to charging pipeline in, zinc electrode in charge tube runs when be gradually reduced
Charging, then the zinc electrode after reduction is pushed to again in electric discharge pipeline by driving device, thus path forms duration cycle
The redox reaction produced electricl energy makes the present invention that needn't be supplemented or replace by hand the negative material of its fuel battery inside,
Also the waste material of possible hostile environment, service life not only economic and environment-friendly but also that fuel cell can be increased not will produce.
Description of the drawings
Fig. 1 is the stereogram of the existing zinc-air battery with plate zinc electrode；
Fig. 2 is the sectional view of the existing zinc-air battery monomer with zinc particle；
Fig. 3 is the structural schematic diagram of flow-type zinc/air fuel cell of the present invention；
Fig. 4 is the stereogram of charging valve road of the present invention partial section；
Fig. 5 is the sectional view of Fig. 4；
Fig. 6 is the schematic diagram that driving device of the present invention cooperation charging pipeline carries out reduction reaction；
Fig. 7 is the schematic diagram that present invention charging pipeline individually carries out reduction reaction.
Reference sign：1--- zine plate type electrodes；11---- plates；12--- zinc anode plates；13--- cathode plates；
14--- air；2--- zinc granule subtype electrodes；21--- zinc particles；22--- electrolyte；3--- flow-type zinc/air fuel cells；
The closed pipelines of 31---；32-- zinc electrodes；33--- collector tubes；4--- electric discharge pipelines；41--- metal collector tubes；42--- is isolated
Film；43--- air electrodes；44--- shells；441--- through-holes；5--- charging pipelines；51--- metal tubes；52--- metallic rods
Part；53--- metal meshes；6--- driving devices；61--- screw rods；7--- pressue devices.
Specific implementation mode
Hereby for ease of further having deeper one layer clear, full and accurate understanding to construction, use and its feature of the present invention
With understanding, preferred embodiment is hence enumerated, detailed description are as follows for cooperation diagram：
It please referring to shown in Fig. 3 and Fig. 4, flow-type zinc/air fuel cell 3 of the present invention is made of a closed pipeline 31, by
External air or oxygen (part of arrow in diagram) enters inside from all angles of circular arc tubulose, includes mainly one to put
Charge pipeline 5 and 6 three parts of an at least driving device on fulgurite road 4, one, and the charging pipeline 5 is connected to the electric discharge pipeline 4
Opposite end is respectively arranged on the electric discharge pipeline 4 and charging valve in present pre-ferred embodiments by two driving devices 6
Between road 5.
Since cathode (anode) electrode for being used in zinc/air fuel cell 3 of the present invention is one flowable and be rendered as pureed
The zinc electrode 32 of pattern, by the driving device 6 by the zinc electrode 32 by being elapsed to the charging in the electric discharge pipeline 4
In pipeline 5, when the zinc electrode 32 flows to the end of the charging pipeline 5, then by the driving device 6 by the zinc
Electrode 32 carries out passage by the charging pipeline 5 towards the electric discharge pipeline 4 makes its displacement.
Moreover, mobility and rate travel in order to ensure the zinc electrode 32 in the electric discharge pipeline 4, and it is further
A pressue device 7 is set in present invention electric discharge pipeline 4, the pressue device 7 can be set as releasing bubble formula device or pressurization side
Pu, and can be squeezed into the zinc electrode 32 bubble increase the zinc electrode 32 in it is described electric discharge pipeline 4 in mobility and
Uniformity, or when the zinc electrode 32 helps Pu by pressurization, help pressing to zinc electrode 32 for Pu to ensure to flow by pressurization
Dynamic property.
Wherein, it includes that the compound of zinc metal or mixture are constituted that the zinc electrode 32, which is set as one, the zinc metal
It can be set as one of zinc particle or zinc powder or its mixing.
In addition, referring again to shown in Fig. 4, in order to ensure the zinc electrode 32 in the electric discharge pipeline 4, the electric discharge pipeline 4
Opposite left and right ends extend and be respectively formed a collector tube 33 for collecting the present invention produced electric energy export.
It please refers to shown in Fig. 5, the electric discharge pipeline 4 is completely to coat a metal current collection by the periphery of the zinc electrode 32
The periphery of pipe 41, the metal collector tube 41 completely coats an isolation film 42 again, and the periphery of the isolation film 42 is completely wrapped
An air electrode 43 is covered, separately completely coats a shell 44 in the periphery of the air electrode 43, the shell 44 has multiple
Enter the through-hole 441 of the air electrode 43 for air or oxygen, the material of the metal collector tube 41 be set as by copper or nickel its
One of made by.
It please refers to shown in Fig. 6, for the present invention in a preferred embodiment, the charging pipeline 5 has one and the shell 44
The metal tubes 51 of connection, and a hollow metal rod 52 is further provided in the metal tubes 51, the driving device 6
Driven and carried out back and forth by the driving source screw rod 61 of displacement action, and the spiral shell with single direction equipped with a driving source and one
Bar 61 is set as being made of plastic material, and the metal tubes 51 and the metal rod 52 are set as one group and are carrying opposite-sign just
Negative electrode, by the metal tubes 51 of the charging pipeline 5 as positive (cathode), in contrast, by the gold of the charging pipeline 5
Belong to rod piece 52 as cathode (anode).
It is transformed into the zinc aoxidized electricity through air or oxygen reaction by the zinc electrode 32 is by electric discharge pipeline 4
The zinc electrode 32 of pole 32, the oxidation just can pass through the metal tubes 51 and metallic rod when by the charging pipeline 5
Part 52 jointly gradually restores the zinc electrode 32, and the zinc electrode 32 for finally leaving the charging pipeline 5 can be described in
The process that chemical energy is converted to electric energy is carried out with air or oxygen again in electric discharge pipeline 4, this is routinely in inventive closure
Redox reaction is carried out while cyclically flowing displacement in formula pipeline 31, can reach and avoid supplementing or replace its fuel electricity
The material of zinc electrode inside pond, long lasting for property self operating produce electricl energy, and are the green energy that meaning meets no pollution environmental protection
Source.
In addition, during zinc electrode 32 is carried out reduction reaction in the charging pipeline 5, due to the metal rod
There is the pattern that multiple stomatas while its center are set as hollow structure, the zinc electrode 32 after oxidation to be produced after carrying out reduction on 52 surfaces
Raw oxygen will enter the stomata of metal rod 52 again by hollow structure guiding discharge in the charging pipeline 5.
Shown in Fig. 7, the present invention charges pipeline 5 in another preferred embodiment, and the charging pipeline 5 has one
The metal mesh 53 being connect with the shell 44, the screw rod 61 of the driving device 6 is separately set as metal material and is made, by the metal
Net 53 and the screw rod 61 are set as one group of positive and negative electrode for carrying opposite-sign, in other words, by the metal of the charging pipeline 5
Net 53 is as the anode (cathode) with positive electron, in contrast, again by the screw rod 61 of the driving device 6 as with negative electricity
The cathode (anode) of son, by the zinc electrode 32 is by electric discharge pipeline 4 after air or oxygen is transformed into oxidation
The zinc electrode 32 of zinc electrode 32, the oxidation just can pass through the metal mesh 53 and screw rod when by the charging pipeline 5
61 are jointly gradually reduced the zinc electrode 32, and the zinc electrode 32 for finally leaving the charging pipeline 5 can be described in
In electric discharge pipeline 4 process that chemical energy is converted to electric energy is carried out with air or oxygen again.
Further illustrate, is set forth in the charging pipeline 5 during zinc electrode 32 is carried out reduction reaction, is produced
The charging pipeline 5 is discharged by the hole gap diffusion of the metal mesh 53 in raw oxygen.
In addition to this, the zinc granule subtype electrode 2 relative to the existing gelatinous electrolyte 22 for including zinc particle 21, glue
The electrolyte 22 of shape in zinc granule subtype electrode 2 and without mobility technical characteristic, compared to this, flow-type zinc of the present invention
The zinc electrode 32 of air fuel electrode 3 is set as mobile pureed, then the driving device 6 and pressue device 7 is coordinated to drive institute
It states 32 duration of zinc electrode to flow in the closed pipeline 31, flowing while can allow the surface of the zinc electrode 32
Really it is contacted with air or oxygen, and significantly promotes the area of reaction, be finally reached and promote flow-type zinc air combustion of the present invention
Expect the efficiency that battery 3 discharges.
Described above to be merely exemplary for the purpose of the present invention, and not restrictive, those of ordinary skill in the art understand,
In the case where not departing from spirit and scope defined by claim, can many modifications may be made, variation or equivalent, but will all fall
Enter within protection scope of the present invention.
Claims (8)
1. a kind of flow-type zinc/air fuel cell, it is characterised in that it includes：It is made of a closed pipeline, it is described closed
Pipeline is connected to the charging pipeline of the electric discharge pipeline with an electric discharge pipeline and one, and the electric discharge pipeline, which is equipped with one, to be flowed
And it is rendered as the zinc electrode of pureed pattern, a metal collector tube is coated by the periphery of the zinc electrode, the metal collector tube
Periphery one isolation film of cladding, periphery one air electrode of cladding of the isolation film, in one tool of periphery cladding of the air electrode
There is the shell of multiple through-holes for entering the air electrode for air；It is equipped at least between the electric discharge pipeline and charging pipeline again
One driving device is pushed the zinc electrode by the driving device after zinc electrode aoxidizes in the electric discharge pipeline
To in the charging pipeline, the zinc electrode is gradually reduced in the charging pipeline, then will be described by the driving device
Zinc electrode, which is pushed in the electric discharge pipeline, forms the redox reaction that duration cycle produces electricl energy.
2. flow-type zinc/air fuel cell according to claim 1, it is characterised in that：The zinc electrode is set as one
There is the mixture of zinc metal to be constituted, the zinc metal is set as one of zinc particle or zinc powder or its mixing.
3. flow-type zinc/air fuel cell according to claim 1, it is characterised in that：The material of the metal collector tube
It is set as made by one of copper or nickel.
4. flow-type zinc/air fuel cell according to claim 1, it is characterised in that：The driving device is equipped with one and drives
Dynamic source and one driven and carried out back and forth displacement action with single direction by the driving source screw rod.
5. flow-type zinc/air fuel cell according to claim 4, it is characterised in that：The charging pipeline have one with
The metal mesh of the shell connection, being set as one group by the screw rod and the metal mesh can be by the oxidation in the charging pipeline
Zinc electrode afterwards carries out the positive and negative electrode of reduction reaction.
6. flow-type zinc/air fuel cell according to claim 1, it is characterised in that：The charging pipeline have one with
Metal tubes of shell connection, an and metal rod is further provided in the metal tubes, by the metal tubes and
The metal rod is set as one group of positive negative electricity that the zinc electrode after the oxidation in the charging pipeline can be carried out to reduction reaction
Pole.
7. flow-type zinc/air fuel cell according to claim 6, it is characterised in that：The metal rod surface has
The stomata for entering the metal rod is guided discharge by multiple stomatas, the oxygen that zinc electrode after oxidation generates after carrying out reduction.
8. flow-type zinc/air fuel cell according to claim 1, it is characterised in that：The electric discharge pipeline is further set
There is the pressue device of the acceleration zinc electrode flowing displacement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410718050.3A CN105633510B (en) | 2014-12-01 | 2014-12-01 | Flow-type zinc/air fuel cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410718050.3A CN105633510B (en) | 2014-12-01 | 2014-12-01 | Flow-type zinc/air fuel cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105633510A CN105633510A (en) | 2016-06-01 |
| CN105633510B true CN105633510B (en) | 2018-09-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410718050.3A Expired - Fee Related CN105633510B (en) | 2014-12-01 | 2014-12-01 | Flow-type zinc/air fuel cell |
Country Status (1)
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| CN (1) | CN105633510B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113258173B (en) * | 2021-05-14 | 2023-06-20 | 黄兴国 | Integral zinc-air filled battery for automobile |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4957826A (en) * | 1989-04-25 | 1990-09-18 | Dreisbach Electromotive, Inc. | Rechargeable metal-air battery |
| TW487227U (en) * | 2001-04-24 | 2002-05-11 | Yung-Ren Lin | Fuel supply apparatus for electric vehicle by using zinc air battery |
| US6746509B2 (en) * | 2002-09-11 | 2004-06-08 | Mitsui Mining & Smelting Company, Ltd. | Process for producing zinc or zinc alloy powder for battery |
| CN1753243A (en) * | 2004-09-20 | 2006-03-29 | 北京长力联合能源技术有限公司 | Energy supplementing system of zinc air battery |
| CN101030664A (en) * | 2006-02-27 | 2007-09-05 | 合肥中大化学电子科技有限公司 | Directly chargeable zinc-air battery for electric vehicle |
| CN101783429A (en) * | 2009-01-16 | 2010-07-21 | 北京化工大学 | Zinc-oxygen single flow battery |
| CN101783428A (en) * | 2009-01-15 | 2010-07-21 | 宏达国际电池股份有限公司 | Low pressure molding package structure for fuel cell |
| CN204303948U (en) * | 2014-12-01 | 2015-04-29 | 廖文煌 | Flow-type zinc/air fuel cell |
-
2014
- 2014-12-01 CN CN201410718050.3A patent/CN105633510B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4957826A (en) * | 1989-04-25 | 1990-09-18 | Dreisbach Electromotive, Inc. | Rechargeable metal-air battery |
| TW487227U (en) * | 2001-04-24 | 2002-05-11 | Yung-Ren Lin | Fuel supply apparatus for electric vehicle by using zinc air battery |
| US6746509B2 (en) * | 2002-09-11 | 2004-06-08 | Mitsui Mining & Smelting Company, Ltd. | Process for producing zinc or zinc alloy powder for battery |
| CN1753243A (en) * | 2004-09-20 | 2006-03-29 | 北京长力联合能源技术有限公司 | Energy supplementing system of zinc air battery |
| CN101030664A (en) * | 2006-02-27 | 2007-09-05 | 合肥中大化学电子科技有限公司 | Directly chargeable zinc-air battery for electric vehicle |
| CN101783428A (en) * | 2009-01-15 | 2010-07-21 | 宏达国际电池股份有限公司 | Low pressure molding package structure for fuel cell |
| CN101783429A (en) * | 2009-01-16 | 2010-07-21 | 北京化工大学 | Zinc-oxygen single flow battery |
| CN204303948U (en) * | 2014-12-01 | 2015-04-29 | 廖文煌 | Flow-type zinc/air fuel cell |
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| CN105633510A (en) | 2016-06-01 |
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