CN105632592A - Inorganic mineral substance ceramic fireproof, fire-resistant and oxygen-isolating filling mud composition - Google Patents

Inorganic mineral substance ceramic fireproof, fire-resistant and oxygen-isolating filling mud composition Download PDF

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Publication number
CN105632592A
CN105632592A CN201610190762.1A CN201610190762A CN105632592A CN 105632592 A CN105632592 A CN 105632592A CN 201610190762 A CN201610190762 A CN 201610190762A CN 105632592 A CN105632592 A CN 105632592A
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Prior art keywords
fire
separation
inorganic mineral
mud composition
oxygen
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CN201610190762.1A
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Chinese (zh)
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赵源
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Tao Kai Polymer Materials Science And Technology Center (shanghai)
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Tao Kai Polymer Materials Science And Technology Center (shanghai)
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Priority to CN201610190762.1A priority Critical patent/CN105632592A/en
Publication of CN105632592A publication Critical patent/CN105632592A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/02Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
    • H01B3/12Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances ceramics
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Fireproofing Substances (AREA)

Abstract

The present invention discloses an inorganic mineral substance ceramic fireproof, fire-resistant and oxygen-isolating filling mud composition. The composition includes the following components in parts by weight: 5 to 28 parts of silicon dioxide, silicon dioxide-containing silica mineral substance or the mixture of the silicon dioxide and the silicon dioxide-containing silica mineral substance, 10 to 25 parts of room-temperature ceramic powder, 8 to 17 parts of inorganic filler, 3 to 18 parts of flame retardant, and 18 to 29 parts of curing agent, wherein the silicon dioxide is any one component selected from nano white carbon black, gas white carbon black and precipitated white carbon black, the silicon dioxide-containing silica mineral substance is wollastonite powder or silica powder, and the room-temperature ceramic powder is one component or a mixture of several components selected from powder-like calciborite, pyrophyllite, szaibelyite, datolite, ulexite, calcite and spodumene. The inorganic mineral substance ceramic fireproof, fire-resistance and oxygen-isolating filling mud composition provided by the invention has the advantages of excellent flame-retardant, fireproof and fire-resistant performance, high curing speed and high hardness, and can withstand spraying and vibration.

Description

A kind of inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition
Technical field
The present invention relates to a kind of inorganic mineral potteryization mixture, specifically, it relates to a kind of inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition.
Background technology
At present due to improving constantly that material of construction and fire resistant flame retardant of being prevented fires by cable and optical cable material are required, existing fire prevention fire resistant flame retardant material is difficult to meet actual requirement, particularly there is bigger defect in material cost, processing performance, safety, environmental protection and work-ing life etc.
Existing flame-retardant and fire-resistant wire and cable mostly adopts magnesium oxide mineral insulation or mica tape to be wound around and realizes fire-resistant function, but, there is following shortcoming in magnesium oxide mineral fireinsulation cable: first in Manufacture and application, equipment cost height, magnesium oxide mineral fireinsulation cable needs special manufacturing and processing equipment, expensive, equipment cost is higher; 2nd, production cost height, because the outer jacket of magnesium oxide mineral fireinsulation cable is full copper, the ratio of copper is great, price is high so that production cost is higher, in practical application, by restriction to a certain extent; The easy moisture absorption weathering of magnesium oxide; 3rd, the laying installation of process for processing, transport, circuit and in-convenience in use, owing to copper sheath magnesium oxide mineral fire prevention insulated cable has particular requirement in the laying installation and use procedure of process for processing, transport, circuit, as magnesium oxide mineral prevent fires insulated cable process for processing can not as macromolecular material easy making process, laying installation very complicated, material cost cost height, it is difficult to extensive popularization and application, particularly covil construction etc., could not obtain extensive, general application up to now.
And the fire-resistant wire and cable that mica tape is wound around, in process of production, need multiple wraps, due to the restriction of processing condition, often cause seam lap place that overlap joint defect occurs, add that after burning, mica tape is easily sent out crisp, come off, and reduces fire-resistant effect to a great extent, cause circuit short circuit, thus it is difficult to ensure electric power, communication line in the case of fire safe and smooth.
Therefore, the urgent mode needing a kind of prevent fires refractory materials replacement magnesium oxide mineral fireinsulation or mica tape winding, it is achieved fire-resistant function of preventing fires.
Summary of the invention
It is an object of the invention to provide a kind of inorganic mineral potteryization mixture for fire resistant flame retardant of preventing fires, there is extraordinary fire-retardant, fire prevention and resistivity against fire, and curing speed is fast, very hard, it is possible to bear spray and drench and vibrations.
In order to achieve the above object, the present invention provides a kind of inorganic mineral pottery chemoprevention fire fireproof oxygen-separation and fills mud composition, wherein, said composition comprises silicon-dioxide, silica containing mineral substance or its mixture, normal temperature Vitrified powder, mineral filler, fire retardant and solidifying agent.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, and wherein, described composition is counted by weight and comprised: silicon-dioxide, silica containing mineral substance or its mixture 5-28 part; Normal temperature Vitrified powder 10-25 part; Mineral filler 8-17 part; Fire retardant 3-18 part; Solidifying agent 18-29 part.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, and wherein, described silicon-dioxide adopts any one in Nano carbon white, gas-phase silica, precipitated silica; Described silica containing mineral substance is wollastonite powder or silicon powder. Wollastonite belongs to strand silicate minerals, triclinic(crystalline)system. Silicon powder is by natural quartz (SiO2) or fused quartz (the amorphous Si O of natural quartz after high-temperature fusion, cooling2) through broken, ball milling (or vibration, airflow milling), flotation, pickling purification, high purity water process Deng Duo road processes and micro-powder of becoming.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, wherein, described normal temperature Vitrified powder is any one or a few the mixture in pulverous calciborite, agalmatolite, szaibelyite, datolite, ulexite, calcite, triphane.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, wherein, described mineral filler is any one or a few the mixture in nano magnesia, nano aluminium oxide, nanometer Wingdale, nano kaoline, nanoclay, nano imvite.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, and wherein, described fire retardant is any one or a few the mixture in nano-sized magnesium hydroxide, nano-aluminum hydroxide, nano-zinc borate, weisspiessglanz.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, and wherein, described solidifying agent is pure aluminium silicate or Tai-Ace S 150 or both mixtures.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, wherein, the purposes of described composition includes but not limited to: as the oxygen barrier layer of mineral substance flame resistant cable and fire resistant flexible flame resistant cable, packing layer, flame retardant coating, fire-proof mud and bus groove insulation, prevent fires fire-resistant, fill mud.
Present invention also offers the preparation method that a kind of above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, wherein, described method is by the silicon-dioxide counting 5-28 part by weight, silica containing mineral substance or its mixture, the normal temperature Vitrified powder of 10-25 part, the mineral filler of 8-17 part, the fire retardant of 3-18 part, the solidifying agent of 18-29 part, and the deionized water of 30-46 part evenly obtains described inorganic mineral pottery chemoprevention fire fireproof oxygen-separation in stirrer for mixing and fills mud composition.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills the preparation method of mud composition, wherein, the described inorganic mineral pottery chemoprevention fire fireproof oxygen-separation obtained that mixes fills mud composition, direct extrusion molding on forcing machine, or in mould injection moulding.
Above-mentioned inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills the preparation method of mud composition, wherein, described inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, contacts with air in atmosphere and carry out reaction can obtain the hard mineral substance not fired ceramic mixture after 2-4 hour under normal temperature.
Inorganic mineral provided by the invention pottery chemoprevention fire fireproof oxygen-separation is filled mud composition and is had the following advantages:
Contacting with air in atmosphere under said composition normal temperature to carry out reacting obtains after 2-4 hour very hard, pure inorganic, and the ceramic mixture of the mineral substance not fired is pure inorganic hard material. Said composition is easy to processing, and price is low, technique is easy, security height, do not contain hazardous substance, for flame resistant cable of preventing fires, point not, not heat release, at the high temperatures of the flame, it does not have drip, prolong combustion phenomenon, objectionable impurities and gas can not be produced. The A level of GB31247 " cable and optical cable classification system for fire performance " and the requirement of the standard of GB/T31248 " cable and optical cable are in the test method being subject to propagation of flame under fire condition, Thermal release and product cigarette characteristic " can be reached, curing speed is fast, very hard, spray can be born drench and vibrations, warping resistance intensity can reach 50MPa, and ultimate compression strength can reach 90MPa, has very excellent fire-retardant, fire prevention, fire performance, can can direct extrusion molding on forcing machine, it is also possible to injection moulding in mould.
Embodiment
Hereinafter the specific embodiment of the present invention is further described.
Inorganic mineral provided by the invention pottery chemoprevention fire fireproof oxygen-separation fills mud composition, comprises silicon-dioxide, silica containing mineral substance or its mixture, normal temperature Vitrified powder, mineral filler, fire retardant and solidifying agent.
Said composition is counted by weight and is comprised: silicon-dioxide, silica containing mineral substance or its mixture 5-28 part; Normal temperature Vitrified powder 10-25 part; Mineral filler 8-17 part; Fire retardant 3-18 part; Solidifying agent 18-29 part.
Silicon-dioxide adopts any one in Nano carbon white, gas-phase silica, precipitated silica; Silica containing mineral substance is wollastonite powder or silicon powder. Wollastonite belongs to strand silicate minerals, triclinic(crystalline)system. Silicon powder is by natural quartz (SiO2) or fused quartz (the amorphous Si O of natural quartz after high-temperature fusion, cooling2) through broken, ball milling (or vibration, airflow milling), flotation, pickling purification, high purity water process Deng Duo road processes and micro-powder of becoming.
Normal temperature Vitrified powder is any one or a few the mixture in pulverous calciborite, agalmatolite, szaibelyite, datolite, ulexite, calcite, triphane.
Mineral filler is any one or a few the mixture in nano magnesia, nano aluminium oxide, nanometer Wingdale, nano kaoline, nanoclay, nano imvite.
Fire retardant is any one or a few the mixture in nano-sized magnesium hydroxide, nano-aluminum hydroxide, nano-zinc borate, weisspiessglanz.
Solidifying agent is pure aluminium silicate or Tai-Ace S 150 or both mixtures.
The purposes of said composition includes but not limited to: as the oxygen barrier layer of mineral substance flame resistant cable and fire resistant flexible flame resistant cable, packing layer, flame retardant coating, fire-proof mud and bus groove insulation, prevent fires fire-resistant, fill mud.
Present invention also offers the preparation method that this inorganic mineral pottery chemoprevention fire fireproof oxygen-separation a kind of fills mud composition, the silicon-dioxide of 5-28 part, silica containing mineral substance or its mixture will be counted by weight, the normal temperature Vitrified powder of 10-25 part, the mineral filler of 8-17 part, the fire retardant of 3-18 part, the solidifying agent of 18-29 part, and the deionized water of 30-46 part evenly obtains this inorganic mineral pottery chemoprevention fire fireproof oxygen-separation in stirrer for mixing and fills mud composition. Direct extrusion molding on forcing machine again, or in mould injection moulding.
This inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, contacts with air in atmosphere and carry out reaction can obtain the hard mineral substance not fired ceramic mixture after 2-4 hour under normal temperature.
Below in conjunction with embodiment the present invention done and further describe.
Each raw material is got in following ratio.
Embodiment 1
Nano carbon white 26 parts
Powder shape calciborite 15 parts
10 parts, the mixture of nano magnesia and nano aluminium oxide weight ratio 1:1
Nano-aluminum hydroxide 5 parts
Pure aluminium silicate 28 parts
Deionized water 30 parts.
Embodiment 2
Gas-phase silica 8 parts
Powder shape agalmatolite 10 parts
Nanometer 12 parts, Wingdale
Nano-sized magnesium hydroxide 18 parts
Pure aluminium silicate 25 parts
Deionized water 38 parts.
Embodiment 3
Silicon powder 15 parts
20 parts, powder shape calcite
Nano kaoline 16 parts
Nano-zinc borate 10 parts
20 parts, Tai-Ace S 150
Deionized water 45 parts.
Above composition is evenly obtained this inorganic mineral pottery chemoprevention fire fireproof oxygen-separation in stirrer for mixing and fills mud composition. Again at direct extrusion molding on forcing machine, or in mould injection moulding. This inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, contacts with air in atmosphere and carry out reaction can obtain the hard mineral substance not fired ceramic mixture after 2-4 hour under normal temperature.
The purposes of said composition includes but not limited to: as the oxygen barrier layer of mineral substance flame resistant cable and fire resistant flexible flame resistant cable, packing layer, flame retardant coating, fire-proof mud and bus groove insulation, prevent fires fire-resistant, fill mud.
Inorganic mineral provided by the invention pottery chemoprevention fire fireproof oxygen-separation fills mud composition, there is extraordinary fire-retardant, fire prevention and resistivity against fire, and curing speed is fast, very hard, spray can be born drench and vibrations, being easy to processing, price is low, technique is easy, security height, do not contain hazardous substance, for flame resistant cable of preventing fires, point not, not heat release, at the high temperatures of the flame, it does not have drip, prolong combustion phenomenon, objectionable impurities and gas can not be produced.
Although the content of the present invention has made detail by above preferred embodiment, but it should recognize that above-mentioned description is not considered as limitation of the present invention. After those skilled in the art have read foregoing, multiple amendment for the present invention and replacement will be all apparent. Therefore, protection scope of the present invention should be limited to the appended claims.

Claims (10)

1. an inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, it is characterised in that, said composition comprises silicon-dioxide, silica containing mineral substance or its mixture, normal temperature Vitrified powder, mineral filler, fire retardant and solidifying agent.
2. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 1 fills mud composition, it is characterised in that, described composition is counted by weight and is comprised:
Silicon-dioxide, silica containing mineral substance or its mixture 5-28 part;
Normal temperature Vitrified powder 10-25 part;
Mineral filler 8-17 part;
Fire retardant 3-18 part;
Solidifying agent 18-29 part.
3. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 2 fills mud composition, it is characterised in that, described silicon-dioxide adopts any one in Nano carbon white, gas-phase silica, precipitated silica; Described silica containing mineral substance is wollastonite powder or silicon powder.
4. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 2 fills mud composition, it is characterized in that, described normal temperature Vitrified powder is any one or a few the mixture in pulverous calciborite, agalmatolite, szaibelyite, datolite, ulexite, calcite, triphane.
5. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 2 fills mud composition, it is characterized in that, described mineral filler is any one or a few the mixture in nano magnesia, nano aluminium oxide, nanometer Wingdale, nano kaoline, nanoclay, nano imvite.
6. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 2 fills mud composition, it is characterised in that, described fire retardant is any one or a few the mixture in nano-sized magnesium hydroxide, nano-aluminum hydroxide, nano-zinc borate, weisspiessglanz.
7. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 2 fills mud composition, it is characterised in that, described solidifying agent is pure aluminium silicate or Tai-Ace S 150 or both mixtures.
8. one kind as in claim 1 ~ 7 as described in any one inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fill mud composition preparation method, it is characterized in that, described method is by the silicon-dioxide counting 5-28 part by weight, silica containing mineral substance or its mixture, the normal temperature Vitrified powder of 10-25 part, the mineral filler of 8-17 part, the fire retardant of 3-18 part, the solidifying agent of 18-29 part, and the deionized water of 30-46 part evenly obtains described inorganic mineral pottery chemoprevention fire fireproof oxygen-separation in stirrer for mixing and fills mud composition.
9. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 8 fills the preparation method of mud composition, it is characterized in that, the described inorganic mineral pottery chemoprevention fire fireproof oxygen-separation obtained that mixes fills mud composition, direct extrusion molding on forcing machine, or in mould injection moulding.
10. inorganic mineral pottery chemoprevention fire fireproof oxygen-separation as claimed in claim 9 fills the preparation method of mud composition, it is characterized in that, described inorganic mineral pottery chemoprevention fire fireproof oxygen-separation fills mud composition, contacts with air in atmosphere and carry out reaction can obtain the hard mineral substance not fired ceramic mixture after 2-4 hour under normal temperature.
CN201610190762.1A 2016-03-30 2016-03-30 Inorganic mineral substance ceramic fireproof, fire-resistant and oxygen-isolating filling mud composition Pending CN105632592A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106058660A (en) * 2016-08-05 2016-10-26 太仓宏光自控电器设备有限公司 Fireproof high-voltage AC power distribution cabinet
CN107123462A (en) * 2017-05-12 2017-09-01 罗碧贤 A kind of cable filling cream using glass powder as matrix and preparation method thereof
CN108218320A (en) * 2018-01-31 2018-06-29 上海腾瑞纳化工科技有限公司 A kind of flexible mineral insulation cable mineral oxygen barrier feed composition and preparation method thereof
CN110085359A (en) * 2019-03-29 2019-08-02 浙江中大元通特种电缆有限公司 Oxygen barrier layer cable
CN111489853A (en) * 2020-03-27 2020-08-04 衡阳师范学院 Low-cost anhydrous flexible ceramic fireproof cable filler
CN112174639A (en) * 2020-08-31 2021-01-05 浙江工业大学 Low-temperature sintering ceramic powder for ceramic high polymer material and application thereof
CN114822907A (en) * 2022-06-24 2022-07-29 西安宏星电子浆料科技股份有限公司 Sintering-resistant resistor slurry
US20220306532A1 (en) * 2019-06-06 2022-09-29 Eco Boron LLC Fire resistant compositions and articles and methods of preparation and use thereof

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JPH1166975A (en) * 1997-08-20 1999-03-09 Yazaki Corp Fire resistant electric wire
CN102040839A (en) * 2009-10-16 2011-05-04 青岛汉缆股份有限公司 Formula for ceramicized silicon rubber cable material
CN103065718A (en) * 2013-01-28 2013-04-24 深圳市沃尔核材股份有限公司 Fire-resistant power cable
CN103087531A (en) * 2013-01-22 2013-05-08 辽宁科瑞德电缆有限公司 Fire retardant foaming material for halogen-free flame retardant cable and preparation method of fire retardant foaming material
CN103102134A (en) * 2013-02-20 2013-05-15 上海宏胜电线电缆有限公司 Fireproof and flame retardant mineral compound filling material and cable containing the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1166975A (en) * 1997-08-20 1999-03-09 Yazaki Corp Fire resistant electric wire
CN102040839A (en) * 2009-10-16 2011-05-04 青岛汉缆股份有限公司 Formula for ceramicized silicon rubber cable material
CN103087531A (en) * 2013-01-22 2013-05-08 辽宁科瑞德电缆有限公司 Fire retardant foaming material for halogen-free flame retardant cable and preparation method of fire retardant foaming material
CN103065718A (en) * 2013-01-28 2013-04-24 深圳市沃尔核材股份有限公司 Fire-resistant power cable
CN103102134A (en) * 2013-02-20 2013-05-15 上海宏胜电线电缆有限公司 Fireproof and flame retardant mineral compound filling material and cable containing the same

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106058660A (en) * 2016-08-05 2016-10-26 太仓宏光自控电器设备有限公司 Fireproof high-voltage AC power distribution cabinet
CN107123462A (en) * 2017-05-12 2017-09-01 罗碧贤 A kind of cable filling cream using glass powder as matrix and preparation method thereof
CN108218320A (en) * 2018-01-31 2018-06-29 上海腾瑞纳化工科技有限公司 A kind of flexible mineral insulation cable mineral oxygen barrier feed composition and preparation method thereof
CN110085359A (en) * 2019-03-29 2019-08-02 浙江中大元通特种电缆有限公司 Oxygen barrier layer cable
US20220306532A1 (en) * 2019-06-06 2022-09-29 Eco Boron LLC Fire resistant compositions and articles and methods of preparation and use thereof
CN111489853A (en) * 2020-03-27 2020-08-04 衡阳师范学院 Low-cost anhydrous flexible ceramic fireproof cable filler
CN112174639A (en) * 2020-08-31 2021-01-05 浙江工业大学 Low-temperature sintering ceramic powder for ceramic high polymer material and application thereof
CN114822907A (en) * 2022-06-24 2022-07-29 西安宏星电子浆料科技股份有限公司 Sintering-resistant resistor slurry
CN114822907B (en) * 2022-06-24 2022-09-30 西安宏星电子浆料科技股份有限公司 Sintering-resistant resistor slurry

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Application publication date: 20160601