CN105624817A - Odorless eco-friendly fireproof display cloth - Google Patents
Odorless eco-friendly fireproof display cloth Download PDFInfo
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- CN105624817A CN105624817A CN201410618508.8A CN201410618508A CN105624817A CN 105624817 A CN105624817 A CN 105624817A CN 201410618508 A CN201410618508 A CN 201410618508A CN 105624817 A CN105624817 A CN 105624817A
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Abstract
The invention relates to an odorless eco-friendly fireproof display cloth. The odorless eco-friendly fireproof display cloth comprises, by mass, 2-4% of a nanometer polyester fiber master batch, 1-3% of a fire retardant and the balance chitosan fibers. High-deacetylation degree ultrahigh-viscosity high-quality chitosan fibers and polyester are woven through a mixing spinning method in the presence of the nanometer polyester fiber master batch as a catalyst so that a basic cloth is obtained, eco-friendly glue slurry and a special-purpose fire retardant are added into the basic cloth and the basic cloth is processed to form a stain-resistant eco-friendly cloth through a heat sublimation transfer printing method. An environmental protection technology is introduced into a display industry so that the odorless eco-friendly fireproof display cloth is odorless, nontoxic and colorless and does not produce pollution. The odorless eco-friendly fireproof display cloth has the advantages of energy saving, environmental protection and discoloration after repeated washing and repeated use. The nanometer cloth is light, can easily recover flatness after folding, is bright and colorful, can be washed without discoloration when the surface is dirty and greatly reduces various costs.
Description
Technical field
The present invention relates to a kind of displaying cloth, specifically a kind of odorlessness environment-friendly fireproof shows cloth.
Background technology
The displaying cloth of Present Domestic is all use PVC(polrvinyl chloride) warp knit is plus coating, and spray printing picture is all out be pungent not environmentally, ecological environment causes serious pollution, belongs to inflammable thing, and all can only disposable use, cause the great wasting of resources. More American-European developed countries do not allow PVC show cloth listing already, and the PVC that Korea S also formally prohibitted the use of contamination type comparatively serious in 2002 shows cloth.
Technical difficulty: be cloth printed picture of just having no idea all inflammable, incombustible, can printed picture again not environmentally. We think the not only environmental protection of invention one, but also have pliability, picture dazzle beautiful colorful, can also reuse, easy transportation and installation are fast integrated shows cloth to one fireproof again, domestic there is no precedent.
Summary of the invention
For above-mentioned situation, the present invention provides a kind of odorlessness environment-friendly fireproof to show cloth, adopts full-bodied high-quality chitin fiber high deacetylized, super and terylene to be weaved by blend spinning method under nano polyester fiber master batch catalysis, obtains basis cloth. Add environment-friendly type rubber cement and combustion inhibitor special, make employing heat sublimation transfer print patterned fashion, make the environment-friendlycloth cloth not staiing type. And its green technology is imported to displaying industry, colourless, nontoxic, tasteless, pollution-free to reach, solve energy-conserving and environment-protective in the lump, can wash that repeatedly use will not the great difficult problem of variable color, because nano-cloth is lighter, flatness is recovered after easily folding again, picture is bright and colourful, surface is dirty can also wash after will not become color, greatly save various cost.
To achieve these goals, technical scheme is as follows:
Odorlessness environment-friendly fireproof shows cloth, and raw material composition mass percent is: nano polyester fiber master batch 2-4%, fire retardant 1 ~ 3%, chitin fiber surplus.
Each raw materials by weight portion of described nano polyester fiber master batch is calculated as: nanometer inorganic filler 32 ~ 70, the first oil preparation 10��40, the second oil preparation 10��40, initiator 0.5��5.
The preparation method of described nano polyester fiber master batch is, after the first oil preparation, the second oil preparation and initiator are soaked swelling 30��120min at 20 DEG C, and stirring reaction 30��360min at 80 ~ 90 DEG C, then product vacuum is dried and obtain the Nano filling that organises.
Described first oil preparation includes one or more in maleic anhydride, itaconic acid, acrylic acid, acrylamide, n-methylolacrylamide.
Described second oil preparation includes one or more in styrene, methyl methacrylate, butyl acrylate, glycidyl methacrylate.
Described initiator is one or more in benzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, methyl ethyl ketone peroxide, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate.
Each raw materials by weight portion of affiliated fire retardant is calculated as: antimony trichloride 13%��14%; Amine sulfate 0.2%��0.3%; Magnesium hydroxide 10%��20%; Citric acid 10%��20%; Kieselguhr surplus.
Odorlessness environment-friendly fireproof shows the processing technology of cloth, comprises the following steps:
A, chip drying, B, nano polyester fiber master batch and fire retardant are respectively according to metering mixing, C, melt are carried, D, spinning moulding, E, post processing become cloth, F, bonding agent printing, it is characterised in that, step D spinning moulding step is after being impregnated in chitin fiber solution by the fiber prepared in step C, through dehydration, dries.
The solvent of described chitin fiber solution adopts formic acid, acetic acid, citric acid, malonic acid, lactic acid one of which or several mixed solvents.
The described printing mortar used by bonding agent printing technique comprises acrylic acid ester emulsion, antifouling net agent, antitack agent, thickening agent, filler, and in mass parts, the content of each component is as follows: acrylic acid ester emulsion 55-85, antifouling net agent 1-8, antitack agent 1.5-2, thickening agent 4-6, filler 0-30.
The invention have the advantage that employing full-bodied high-quality chitin fiber high deacetylized, super is weaved by blend spinning method with terylene under nano polyester fiber master batch catalysis, obtain basis cloth. Add environment-friendly type rubber cement and combustion inhibitor special, make employing heat sublimation transfer print patterned fashion, make the environment-friendlycloth cloth not staiing type. And its green technology is imported to displaying industry, colourless, nontoxic, tasteless, pollution-free to reach, solve energy-conserving and environment-protective in the lump, can wash that repeatedly use will not the great difficult problem of variable color, because nano-cloth is lighter, flatness is recovered after easily folding again, picture is bright and colourful, surface is dirty can also wash after will not become color, greatly save various cost.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be easy to understand.
Odorlessness environment-friendly fireproof shows cloth, and raw material composition mass percent is: nano polyester fiber master batch 2-4%, fire retardant 1 ~ 3%, chitin fiber surplus.
Each raw materials by weight portion of described nano polyester fiber master batch is calculated as: nanometer inorganic filler 32 ~ 70, the first oil preparation 10��40, the second oil preparation 10��40, initiator 0.5��5.
The preparation method of described nano polyester fiber master batch is, after the first oil preparation, the second oil preparation and initiator are soaked swelling 30��120min at 20 DEG C, and stirring reaction 30��360min at 80 ~ 90 DEG C, then product vacuum is dried and obtain the Nano filling that organises.
Described first oil preparation includes one or more in maleic anhydride, itaconic acid, acrylic acid, acrylamide, n-methylolacrylamide.
Described second oil preparation includes one or more in styrene, methyl methacrylate, butyl acrylate, glycidyl methacrylate.
Described initiator is one or more in benzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, methyl ethyl ketone peroxide, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate.
Each raw materials by weight portion of affiliated fire retardant is calculated as: antimony trichloride 13%��14%; Amine sulfate 0.2%��0.3%; Magnesium hydroxide 10%��20%; Citric acid 10%��20%; Kieselguhr surplus.
Odorlessness environment-friendly fireproof shows the processing technology of cloth, comprises the following steps:
A, chip drying, B, nano polyester fiber master batch and fire retardant are respectively according to metering mixing, C, melt are carried, D, chitin fiber and terylene are carried out spinning moulding by blend spinning method, E, post processing become cloth, F, bonding agent printing, it is characterised in that, after also including between step D and step C impregnating 10 ~ 20 minutes prepared chitin fiber in chitin fiber solution, through dehydration, dry.
The solvent of described chitin fiber solution adopts formic acid, acetic acid, citric acid, malonic acid, lactic acid one of which or several mixed solvents.
The described printing mortar used by bonding agent printing technique comprises acrylic acid ester emulsion, antifouling net agent, antitack agent, thickening agent, filler, and in mass parts, the content of each component is as follows: acrylic acid ester emulsion 55-85, antifouling net agent 1-8, antitack agent 1.5-2, thickening agent 4-6, filler 0-30.
If this invention is widely popularized, estimate to be subject to, in 5-10 Nian Nei China, degree decline 30-60 percentage point that common PVC shows that cloth pollutes, every year because of repeatable utilization saving energy 10-25%, workman's labour cost is about 20-40%, significantly decline 6-15% because of inflammable displaying cloth fire in saving, can save freight and be about 20-40%.
Natural environmental protection is the design focal point of advertising display cloth, and at former cloth printed material, and the aspect such as thermal transfer focuses on color patterned and word after exposing to wind and rain, equal nondiscoloration, do not fade, this kind of advertising display cloth, break the conventional ads and poster write on traditional wall with ink. Advertising display position is not specially required, easy to use, quick and environmental protection. In manufacturing, cost is preeminently low, and technique makes simple and is suitable for.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described. Skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; simply principles of the invention described in above-described embodiment and description; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements both fall within claimed the scope of the present invention. The protection domain of application claims is defined by appending claims and equivalent thereof.
Claims (7)
1. odorlessness environment-friendly fireproof shows cloth, and raw material composition mass percent is: nano polyester fiber master batch 2-4%, fire retardant 1 ~ 3%, chitin fiber surplus.
2. odorlessness environment-friendly fireproof according to claim 1 shows cloth, it is characterized in that, each raw materials by weight portion of described nano polyester fiber master batch is calculated as: nanometer inorganic filler 32 ~ 70, the first oil preparation 10��40, second oil preparation 10��40, initiator 0.5��5.
3. odorlessness environment-friendly fireproof according to claim 1 shows cloth, it is characterized in that, the preparation method of described nano polyester fiber master batch is, after first oil preparation, the second oil preparation and initiator are soaked swelling 30��120min at 20 DEG C, stirring reaction 30��360min at 80 ~ 90 DEG C, then dries product vacuum and obtains the Nano filling that organises.
4. odorlessness environment-friendly fireproof according to claim 1 shows cloth, it is characterized in that, described initiator is one or more in benzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, methyl ethyl ketone peroxide, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate.
5. odorlessness environment-friendly fireproof according to claim 1 shows cloth, it is characterised in that each raw materials by weight portion of affiliated fire retardant is calculated as: antimony trichloride 13%��14%; Amine sulfate 0.2%��0.3%; Magnesium hydroxide 10%��20%; Citric acid 10%��20%; Kieselguhr surplus.
6. odorlessness environment-friendly fireproof shows the processing technology of cloth, comprises the following steps:
A, chip drying, B, nano polyester fiber master batch and fire retardant are respectively according to metering mixing, C, melt are carried, D, chitin fiber and terylene are carried out spinning moulding by blend spinning method, E, post processing become cloth, F, bonding agent printing, it is characterised in that, after also including between step D and step C impregnating 10 ~ 20 minutes prepared chitin fiber in chitin fiber solution, through dehydration, dry.
7. odorlessness environment-friendly fireproof according to claim 6 shows the processing technology of cloth, it is characterised in that the solvent of described chitin fiber solution adopts formic acid, acetic acid, citric acid, malonic acid, lactic acid one of which or several mixed solvents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410618508.8A CN105624817A (en) | 2014-11-06 | 2014-11-06 | Odorless eco-friendly fireproof display cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410618508.8A CN105624817A (en) | 2014-11-06 | 2014-11-06 | Odorless eco-friendly fireproof display cloth |
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| Publication Number | Publication Date |
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| CN105624817A true CN105624817A (en) | 2016-06-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410618508.8A Pending CN105624817A (en) | 2014-11-06 | 2014-11-06 | Odorless eco-friendly fireproof display cloth |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111298284A (en) * | 2018-12-11 | 2020-06-19 | 天津市博丰兴电子技术有限公司 | Manufacturing method of printed non-woven fabric electrode slice |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1160092A (en) * | 1996-03-15 | 1997-09-24 | 山东淄博万通达工业技术研究所 | Method for making flame-retardant polyester fibre continuous filament |
| CN102585451A (en) * | 2012-02-17 | 2012-07-18 | 山东寿光神润发海洋化工有限公司 | Flame-retardant master batch, preparation method of flame-retardant master batch and method for preparing flame-retardant fiber by using flame-retardant master batch |
| CN103074080A (en) * | 2012-12-30 | 2013-05-01 | 胶州市富田化工有限公司 | Flame retardant |
| CN103085367A (en) * | 2012-12-12 | 2013-05-08 | 吴江麦道纺织有限公司 | Making process of chitosan health care fabric |
| CN103526384A (en) * | 2013-10-31 | 2014-01-22 | 上海婉静纺织科技有限公司 | Anti-acarid chitin fabric |
| CN103859908A (en) * | 2014-04-01 | 2014-06-18 | 上海婉静纺织科技有限公司 | Antibacterial pillow interior and preparing method thereof |
-
2014
- 2014-11-06 CN CN201410618508.8A patent/CN105624817A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1160092A (en) * | 1996-03-15 | 1997-09-24 | 山东淄博万通达工业技术研究所 | Method for making flame-retardant polyester fibre continuous filament |
| CN102585451A (en) * | 2012-02-17 | 2012-07-18 | 山东寿光神润发海洋化工有限公司 | Flame-retardant master batch, preparation method of flame-retardant master batch and method for preparing flame-retardant fiber by using flame-retardant master batch |
| CN103085367A (en) * | 2012-12-12 | 2013-05-08 | 吴江麦道纺织有限公司 | Making process of chitosan health care fabric |
| CN103074080A (en) * | 2012-12-30 | 2013-05-01 | 胶州市富田化工有限公司 | Flame retardant |
| CN103526384A (en) * | 2013-10-31 | 2014-01-22 | 上海婉静纺织科技有限公司 | Anti-acarid chitin fabric |
| CN103859908A (en) * | 2014-04-01 | 2014-06-18 | 上海婉静纺织科技有限公司 | Antibacterial pillow interior and preparing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111298284A (en) * | 2018-12-11 | 2020-06-19 | 天津市博丰兴电子技术有限公司 | Manufacturing method of printed non-woven fabric electrode slice |
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Application publication date: 20160601 |
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