CN105621903A - LED light-emitting glass used for outdoor curtain wall and preparation method of LED light-emitting glass - Google Patents

LED light-emitting glass used for outdoor curtain wall and preparation method of LED light-emitting glass Download PDF

Info

Publication number
CN105621903A
CN105621903A CN201510996316.5A CN201510996316A CN105621903A CN 105621903 A CN105621903 A CN 105621903A CN 201510996316 A CN201510996316 A CN 201510996316A CN 105621903 A CN105621903 A CN 105621903A
Authority
CN
China
Prior art keywords
layer
glass
glass coating
curtain wall
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510996316.5A
Other languages
Chinese (zh)
Other versions
CN105621903B (en
Inventor
顾黎明
徐峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAICANG YAOHUA GLASS CO Ltd
Original Assignee
TAICANG YAOHUA GLASS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAICANG YAOHUA GLASS CO Ltd filed Critical TAICANG YAOHUA GLASS CO Ltd
Priority to CN201510996316.5A priority Critical patent/CN105621903B/en
Publication of CN105621903A publication Critical patent/CN105621903A/en
Application granted granted Critical
Publication of CN105621903B publication Critical patent/CN105621903B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B32B37/1018Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using only vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V33/00Structural combinations of lighting devices with other articles, not otherwise provided for
    • F21V33/006General building constructions or finishing work for buildings, e.g. roofs, gutters, stairs or floors; Garden equipment; Sunshades or parasols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/28Multiple coating on one surface
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/73Anti-reflective coatings with specific characteristics
    • C03C2217/734Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/15Deposition methods from the vapour phase
    • C03C2218/154Deposition methods from the vapour phase by sputtering
    • C03C2218/156Deposition methods from the vapour phase by sputtering by magnetron sputtering
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21WINDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO USES OR APPLICATIONS OF LIGHTING DEVICES OR SYSTEMS
    • F21W2131/00Use or application of lighting devices or systems not provided for in codes F21W2102/00-F21W2121/00
    • F21W2131/10Outdoor lighting
    • F21W2131/107Outdoor lighting of the exterior of buildings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention provides LED light-emitting glass used for an outdoor curtain wall and a preparation method of the LED light-emitting glass. The LED light-emitting glass comprises glass layers, a glue clamping layer, an infrared inflection layer, an electric conduction layer, LED lamps, sealing layers and a protection layer. The glass layers include the first glass layer, the second glass layer and the third glass layer which are stacked from top to bottom. The glue clamping layer is arranged between the first glass layer and the second glass layer. The infrared reflection layer is arranged on the lower surface of the second glass layer. The electric conduction layer is arranged on the upper surface of the third glass layer, and circuit grooves are etched in the electric conduction layer. The LED lamps adhere to the circuit grooves through electric conduction silver glue. The seams of the glass layers are filled with the sealing layers. The peripheries of the glass layers are coated with the protection layer. By means of the LED light-emitting glass, the characteristics of LED glass and vacuum glass can be effectively combined, the anti-explosion performance and the heat preservation and thermal insulation property of the LED light-emitting glass are enhanced, and the LED light-emitting glass is suitable for the outdoor curtain wall.

Description

A kind of outdoor curtain wall LED fluorescent glass and its preparation method
Technical field
The invention belongs to building material technical field, specifically, it relates to a kind of outdoor curtain wall LED fluorescent glass and its preparation method.
Background technology
Glass is the material that a kind of transparency, intensity and hardness are all very high, in unreactiveness in surroundings, also can not work with biology. Therefore, its purposes is widely. The features such as LED glass is a kind of New Building Materials, and it has penetrating, anti-riot, waterproof, antiultraviolet, can design. It is widely used in interior/exterior decoration, furniture design, fluorescent tube illumination Design, the outdoor field such as cladding glass, the design of sunlight room. But, its heat insulating effect is poor. Vacuum glass has the unrivaled advantage of other glass in sound insulation, insulation, and thinner, and weight is relatively light. By physical knowledge it will be seen that heat transmission usually occurs between contactant, two sheet glass up and down of vacuum glass do not contact each other, and the support in the sealing material of circumference of vacuum glass and vacuum chamber all adopts thermal insulation material, and the composition of thermal conduction is very little; Meanwhile, the annular seal space in the middle of levels glass is vacuum state, and vacuum tightness is more high, and gas molecule number is more few, and the convection action of gas molecule is more little, and heat insulation effect is more good. But, due to technical limitation, vacuum glass cannot be accomplished to vacuumize completely, have impact on its heat insulation effect to a certain extent. In prior art, lack the means combined by this two kinds of glass, while giving full play to LED glass advantage, retain and strengthen the insulative properties of vacuum glass.
To this, mainly there is following patent in China at present.
Patent publication No.: CN104791730A, disclose a kind of folder glue fluorescent glass, comprise doubling glass and it is located at conducting film and the LED on described doubling glass surface, described doubling glass is two layers or multiple glazing has been bondd by interlayer film, described conducting film is located on the bonding plane of described glass, described conducting film is carved with circuit groove by laser or engraving machine, and described circuit groove is connected with power supply, and described LED is pasted onto on described circuit groove by conductive silver glue; Described glass is toughened glass, and its surface shape is plane or curved surface; Described interlayer film is PVB, SGP, EVA or PU; Described power supply is 12V direct supply. Glass of the present invention is provided with luminous LED, can send the different light of color at night, have the effect of beautifying and decorating and exploitation. But, the fluorescent glass heat insulation and preservation effect that this invention provides is poor.
Summary of the invention
For solving above-mentioned Problems existing, it is an object of the invention to provide a kind of outdoor curtain wall LED fluorescent glass and its preparation method.
For achieving the above object, the technical solution used in the present invention is: provides a kind of outdoor curtain wall LED fluorescent glass and its preparation method, comprising: glass coating, comprising: the first glass coating of the setting of stacking from top to bottom, the 2nd glass coating, the 3rd glass coating; Folder glue-line, is arranged between the first glass coating and the 2nd glass coating; Infrared reflecting layer, is arranged at the 2nd glass coating lower surface; Conductive layer, is arranged at described 3rd glass coating upper surface, it is carved with circuit groove; LED, is pasted onto on described circuit groove by conductive silver glue; Sealing ply, is filled in described glass coating gap; Protective layer, is coated on described glass coating surrounding.
Further, described glass coating is the bend glass that central authorities arch upward, and wherein, the convex surface of described first glass coating, the 2nd glass coating and the 3rd glass coating is positioned at same side.
Separately, described folder glue-line material is PVB or EVA.
Separately having, described infrared reflecting layer comprises: base layer, is arranged at described 2nd glass coating lower surface; Metal level is layer gold, silver layer, layers of copper or gold, silver and bronze alloy layer; First high refractive index layer, is arranged between described metal level and base layer, be selected from following oxide skin one or more: indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer; 2nd high refractive index layer, is arranged at described metal level lower surface, be selected from following oxide skin one or more: indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer.
Again, described sealing ply is refractory seals glue-line.
Having, described conductive layer is water white transparency layer, its transmitance >=80% again.
And, described protective layer is teflon layer.
Also, described base layer is PET film matrix, PC matrix, PI matrix, PP matrix, PTFE matrix or PA matrix.
Further, the preparation method of a kind of outdoor curtain wall LED fluorescent glass, comprises the steps: 1) get the first glass coating, the 2nd glass coating, the 3rd glass coating; 2) PVB or EVA is chosen, by twin screw extruder granulation, then by the obtained required folder glue-line of the method for extrusion moulding; 3) cleaning clean by the first glass coating and the 2nd glass coating, then sequentially stacking, is followed successively by from top to down: the first glass coating, folder glue-line, the 2nd glass coating; Under negative pressure of vacuum, heating, applying and keep pressure, folder glue is thoroughly melted and described first glass coating and the 2nd glass coating is bonded together and complete excluding air, described Heating temperature is 152-158 DEG C, and the pressure of described applying is 2.5-4.5kg/cm2, the time that described pressure maintains is 25-30min; 4) adopt showering means to form the base layer of infrared reflecting layer at the 2nd glass coating lower surface, and then deposit the first high refractor, metal level and the 2nd high refractor from bottom to top successively at base layer, form four Rotating fields films; 5) adopt magnetron sputtering coating method, form conductive layer at the 3rd glass coating upper surface, and conductive layer is carried out yellow photoetch and forms circuit groove; 6) choose LED, described LED is arranged on described circuit groove; 7) place the 2nd glass coating to carry out closing sheet, form sealing ply at glass coating surrounding gap filling refractory seals glue; Glass after closing sheet is put into process furnace, enters stove and be warming up to 100oC-500oC; 8) vacuumize in stove, or vacuumize outside stove, be evacuated to below 0.1Pa, then be cooled to below the melt temperature of refractory seals glue; 9) at the outer showering protective layer of glass coating surrounding i.e. obtained outdoor curtain wall LED fluorescent glass.
The useful effect of the present invention is: be combined with vacuum glass by LED glass, while retaining the LED glass characteristics of luminescence, strengthens its heat insulating effect, is applicable to outdoor curtain wall. Adopt bend glass, it is possible to can outdoor curtain wall be divergent shape to the reflected light of sunlight, alleviate the light pollution of glass curtain wall. By adding folder glue-line, the explosion-resistance characteristic of the outer glass curtain wall of enhanced room, even if glass breaking, fragment also can not splashes, enhance the security that outdoor glass curtain wall uses; By adding infrared reflecting layer, can the ir radiation of usable reflection glass both sides, avoid outdoor glass curtain wall both sides to carry out heat exchange, strengthen the heat insulation and preservation effect of curtain wall, natural light can be allowed simultaneously incident, ensure the transparency of outdoor glass curtain wall; Sealing ply, by whole for glass coating sealing, not only ensure that vacuum-tightness, it is possible to prevents from infiltrating in the middle of infrared reflecting layer and glass coating air, to cause infrared reflecting layer to be oxidized; Outside sealing ply, add layer protective layer, sealing ply can be avoided to cause breakage because of unexpected or friction, extend curtain wall work-ing life.
Accompanying drawing explanation
Fig. 1 is a kind of outdoor curtain wall LED fluorescent glass provided by the present invention and the structural representation of its preparation method.
Fig. 2 is the structural representation of the infrared reflecting layer of a kind of outdoor curtain wall LED fluorescent glass provided by the present invention and its preparation method.
Embodiment
Following examples are for illustration of the present invention, but can not be used for limiting the scope of the invention.
With reference to Fig. 1 ~ Fig. 2, a kind of outdoor curtain wall LED fluorescent glass provided by the present invention and its preparation method, comprising: glass coating 1, comprising: the first glass coating 11 of the setting of stacking from top to bottom, the 2nd glass coating 12, the 3rd glass coating 13; Folder glue-line 2, is arranged between the first glass coating 11 and the 2nd glass coating 12; Infrared reflecting layer 3, is arranged at the 2nd glass coating 12 lower surface; Conductive layer 4, is arranged at described 3rd glass coating 13 upper surface, it is carved with circuit groove; LED 5, is pasted onto on described circuit groove by conductive silver glue; Sealing ply 6, is filled in described glass coating 1 gap; Protective layer 7, is coated on described glass coating 1 surrounding.
Further, described glass coating 1 is the bend glass that central authorities arch upward, and wherein, the convex surface of described first glass coating 11, the 2nd glass coating 12 and the 3rd glass coating 13 is positioned at same side.
Separately, described folder glue-line 2 material is PVB or EVA.
Separately having, described infrared reflecting layer 3 comprises: base layer 31, is arranged at described 2nd glass coating lower surface; Metal level 33 is layer gold, silver layer, layers of copper or gold, silver and bronze alloy layer; First high refractive index layer 32, is arranged between described metal level 33 and base layer 31, be selected from following oxide skin one or more: indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer; 2nd high refractive index layer 34, is arranged at described metal level lower surface, be selected from following oxide skin one or more: indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer.
Again, described sealing ply 6 is refractory seals glue-line.
Having, described conductive layer 4 is water white transparency layer, its transmitance >=80% again.
And, described protective layer 7 is teflon layer.
Also, described base layer 31 is PET film matrix, PC matrix, PI matrix, PP matrix, PTFE matrix or PA matrix.
Further, the preparation method of a kind of outdoor curtain wall LED fluorescent glass, comprises the steps: 1) get the first glass coating 11, the 2nd glass coating 12, the 3rd glass coating 13; 2) PVB or EVA is chosen, by twin screw extruder granulation, then by the obtained required folder glue-line 2 of the method for extrusion moulding; 3) cleaning totally by the first glass coating 11 and the 2nd glass coating 12, then sequentially stacking, is followed successively by from top to down: the first glass coating 11, folder glue-line 2, the 2nd glass coating 12; Under negative pressure of vacuum, heating, applying and keep pressure, folder glue is thoroughly melted and described first glass coating 11 and the 2nd glass coating 12 is bonded together and complete excluding air, described Heating temperature is 152-158 DEG C, and the pressure of described applying is 2.5-4.5kg/cm2, the time that described pressure maintains is 25-30min; 4) adopt showering means to form the base layer 31 of infrared reflecting layer at the 2nd glass coating lower surface, and then deposit the first high refractor 32, metal level 33 and the 2nd high refractor 34 from bottom to top successively at base layer 31, form four Rotating fields films; 5) adopt magnetron sputtering coating method, form conductive layer 4 at the 3rd glass coating upper surface, and conductive layer is carried out yellow photoetch and forms circuit groove; 6) choose LED 5, described LED 5 is arranged on described circuit groove; 7) place the 2nd glass coating 12 to carry out closing sheet, form sealing ply 6 at glass coating surrounding gap filling refractory seals glue; Glass after closing sheet is put into process furnace, enters stove and be warming up to 100oC-500oC; 8) vacuumize in stove, or vacuumize outside stove, be evacuated to below 0.1Pa, then be cooled to below the melt temperature of refractory seals glue; 9) at the outer showering protective layer 7 of glass coating 1 surrounding i.e. obtained outdoor curtain wall LED fluorescent glass.
It should be noted that, above embodiment is only in order to illustrate the technical scheme of the present invention and unrestricted. Although with reference to better embodiment to invention has been detailed explanation, it will be understood by those within the art that, the technical scheme of invention can being modified or equivalent replacement, and not depart from the scope of technical solution of the present invention, it all should be encompassed in the right of the present invention.

Claims (9)

1. an outdoor curtain wall LED fluorescent glass and its preparation method, it is characterised in that, comprising: glass coating, comprising: the first glass coating of the setting of stacking from top to bottom, the 2nd glass coating, the 3rd glass coating; Folder glue-line, is arranged between the first glass coating and the 2nd glass coating; Infrared reflecting layer, is arranged at the 2nd glass coating lower surface; Conductive layer, is arranged at described 3rd glass coating upper surface, it is carved with circuit groove; LED, is pasted onto on described circuit groove by conductive silver glue; Sealing ply, is filled in described glass coating gap; Protective layer, is coated on described glass coating surrounding.
2. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterized in that, described glass coating is the bend glass that central authorities arch upward, and wherein, the convex surface of described first glass coating, the 2nd glass coating and the 3rd glass coating is positioned at same side.
3. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterised in that, described folder glue-line material is PVB or EVA.
4. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterised in that, described infrared reflecting layer comprises: base layer, is arranged at described 2nd glass coating lower surface; Metal level is layer gold, silver layer, layers of copper or gold, silver and bronze alloy layer; First high refractive index layer, is arranged between described metal level and base layer, be selected from following oxide skin one or more: indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer; 2nd high refractive index layer, is arranged at described metal level lower surface, be selected from following oxide skin one or more: indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer.
5. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterised in that, described sealing ply is refractory seals glue-line.
6. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterised in that, described conductive layer is water white transparency layer, its transmitance >=80%.
7. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterised in that, described protective layer is teflon layer.
8. a kind of outdoor curtain wall LED fluorescent glass according to claim 1 and its preparation method, it is characterised in that, described base layer is PET film matrix, PC matrix, PI matrix, PP matrix, PTFE matrix or PA matrix.
9. the preparation method of a kind of outdoor curtain wall LED fluorescent glass according to claim 1, comprises the steps: 1) get the first glass coating, the 2nd glass coating, the 3rd glass coating; 2) PVB or EVA is chosen, by twin screw extruder granulation, then by the obtained required folder glue-line of the method for extrusion moulding; 3) cleaning clean by the first glass coating and the 2nd glass coating, then sequentially stacking, is followed successively by from top to down: the first glass coating, folder glue-line, the 2nd glass coating; Under negative pressure of vacuum, heating, applying and keep pressure, folder glue is thoroughly melted and described first glass coating and the 2nd glass coating is bonded together and complete excluding air, described Heating temperature is 152-158 DEG C, and the pressure of described applying is 2.5-4.5kg/cm2, the time that described pressure maintains is 25-30min; 4) adopt showering means to form the base layer of infrared reflecting layer at the 2nd glass coating lower surface, and then deposit the first high refractor, metal level and the 2nd high refractor from bottom to top successively at base layer, form four Rotating fields films; 5) adopt magnetron sputtering coating method, form conductive layer at the 3rd glass coating upper surface, and conductive layer is carried out yellow photoetch and forms circuit groove; 6) choose LED, described LED is arranged on described circuit groove; 7) place the 2nd glass coating to carry out closing sheet, form sealing ply at glass coating surrounding gap filling refractory seals glue; Glass after closing sheet is put into process furnace, enters stove and be warming up to 100oC-500oC; 8) vacuumize in stove, or vacuumize outside stove, be evacuated to below 0.1Pa, then be cooled to below the melt temperature of refractory seals glue; 9) at the outer showering protective layer of glass coating surrounding i.e. obtained outdoor curtain wall LED fluorescent glass.
CN201510996316.5A 2015-12-28 2015-12-28 A kind of outdoor curtain wall LED fluorescent glasses and preparation method thereof Active CN105621903B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510996316.5A CN105621903B (en) 2015-12-28 2015-12-28 A kind of outdoor curtain wall LED fluorescent glasses and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510996316.5A CN105621903B (en) 2015-12-28 2015-12-28 A kind of outdoor curtain wall LED fluorescent glasses and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105621903A true CN105621903A (en) 2016-06-01
CN105621903B CN105621903B (en) 2018-09-04

Family

ID=56037303

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510996316.5A Active CN105621903B (en) 2015-12-28 2015-12-28 A kind of outdoor curtain wall LED fluorescent glasses and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105621903B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106927698A (en) * 2016-09-18 2017-07-07 深圳市致竑光电有限公司 The manufacture method and LED transparent luminescent glass of LED transparent luminescent glass
CN108257527A (en) * 2018-02-05 2018-07-06 深圳市睿帘智造科技有限公司 Flexible advertisement film and preparation method thereof
CN110777986A (en) * 2019-10-21 2020-02-11 南宁职业技术学院 Assembly type combined frame of decorative component and mounting method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1559950A (en) * 2004-02-23 2005-01-05 扬州大学 Bulletproof explosion-proof complex layer vacuum galss and mfg. method thereof
CN101320698A (en) * 2008-07-07 2008-12-10 上海耀皮建筑玻璃有限公司 Production technique of LED luminous laminated glass
CN103383472A (en) * 2006-12-14 2013-11-06 圣戈班性能塑料谢纳有限公司 A solar control film
CN104608439A (en) * 2015-01-14 2015-05-13 太仓市其盛化纤厂 Thermal insulation glass

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1559950A (en) * 2004-02-23 2005-01-05 扬州大学 Bulletproof explosion-proof complex layer vacuum galss and mfg. method thereof
CN103383472A (en) * 2006-12-14 2013-11-06 圣戈班性能塑料谢纳有限公司 A solar control film
CN101320698A (en) * 2008-07-07 2008-12-10 上海耀皮建筑玻璃有限公司 Production technique of LED luminous laminated glass
CN104608439A (en) * 2015-01-14 2015-05-13 太仓市其盛化纤厂 Thermal insulation glass

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106927698A (en) * 2016-09-18 2017-07-07 深圳市致竑光电有限公司 The manufacture method and LED transparent luminescent glass of LED transparent luminescent glass
CN108257527A (en) * 2018-02-05 2018-07-06 深圳市睿帘智造科技有限公司 Flexible advertisement film and preparation method thereof
CN110777986A (en) * 2019-10-21 2020-02-11 南宁职业技术学院 Assembly type combined frame of decorative component and mounting method thereof
CN110777986B (en) * 2019-10-21 2021-04-23 南宁职业技术学院 Assembly type combined frame of decorative component and mounting method thereof

Also Published As

Publication number Publication date
CN105621903B (en) 2018-09-04

Similar Documents

Publication Publication Date Title
CN105541135B (en) A kind of double-layer vacuum LED glass and preparation method thereof
US9568659B2 (en) Luminous glazing unit
US9059378B2 (en) Luminous glazing unit
CN206635233U (en) Led transparent luminescent glass
CN105599398B (en) A kind of LED luminous laminated glass and preparation method thereof
KR20150024816A (en) Organic light-emitting diode device comprising a substrate including a transparent layered element
CN105621903A (en) LED light-emitting glass used for outdoor curtain wall and preparation method of LED light-emitting glass
CN104995152A (en) Multilayer glass and production method for same
CN105818493A (en) Fireproof smart switchable glass
CN105291789A (en) Vehicle skylight assembly with adjustable glowing effect
CN208753333U (en) A kind of solar power generation watt substrate and solar power generation watt
CN103420593A (en) Convex double-vacuum-layer glass mounting holes with sealing strips and grooves and manufacturing method of convex double-vacuum-layer glass mounting holes
CN101201152A (en) LED light-embedding artistic glass and method of manufacturing the same
CN201933017U (en) Low-emissivity toughened vacuum glass
CN105599383B (en) A kind of metal mesh explosion-proof vacuum heat insulation glass and preparation method thereof
CN104742446B (en) High-transmittance high-reflectivity, high-efficiency and energy-saving single-silver LOW-E film-plated glass
CN203979961U (en) The great power LED of the high light efficiency low light attenuation of a kind of high heat radiation
CN2892516Y (en) Luminescent floor glazed tile
CN105541134B (en) A kind of doubling explosion-proof vacuum heat insulation glass and preparation method thereof
CN202125740U (en) Lamp with excellent radiation effect
CN207732718U (en) A kind of solar energy power generating body protection tempered glass
CN103928452A (en) Novel solar photoelectric glass
CN104446012A (en) Hollow glass
CN211286187U (en) Novel porcelain aluminum plate
CN105599365A (en) Dimming composite vacuum glass and preparing method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant