CN105609847A - Apparatus for realizing surplus sludge disposal and membrane filtration through coupled single-chamber inclined-plate multi-positive-electrode microbial fuel cell - Google Patents

Apparatus for realizing surplus sludge disposal and membrane filtration through coupled single-chamber inclined-plate multi-positive-electrode microbial fuel cell Download PDF

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Publication number
CN105609847A
CN105609847A CN201610116381.9A CN201610116381A CN105609847A CN 105609847 A CN105609847 A CN 105609847A CN 201610116381 A CN201610116381 A CN 201610116381A CN 105609847 A CN105609847 A CN 105609847A
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China
Prior art keywords
swash plate
positive
anode
fuel cell
negative electrode
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CN201610116381.9A
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CN105609847B (en
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张捍民
笪宗扬
王月竹
杨凤林
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Dalian University of Technology
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Dalian University of Technology
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/16Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention provides an apparatus for realizing surplus sludge disposal and membrane filtration through a coupled single-chamber inclined-plate multi-positive-electrode microbial fuel cell, and belongs to the technical field of environmental engineering. Anaerobic zone sludge is arranged at the bottom of the apparatus; a carbon felt positive electrode is arranged in the anaerobic zone sludge; inclined-plate positive electrodes are arranged in the middle part; the carbon felt positive electrode and the inclined-plate positive electrodes are connected through wires to form the multiple positive electrodes; a carbon felt negative electrode is suspended in a supernatant liquor; the upper layer is exposed in the air to be used as an air negative electrode; the positive electrodes and the air negative electrode are connected through an external electric wire, and are connected with an external resistor; and a hollow fiber membrane module is arranged in the supernatant liquor close to the position of the negative electrode. Due to the additional inclined-plate positive electrodes of the cell, the positive electrode area can be enlarged, so that rich organic matters in the middle of a sedimentation basin can be fully utilized to improve power generation efficiency, effectively prevent sludge from floating upwardly, and slow down membrane pollution; positive-electrode electricity-generating bacteria can utilize the organic matters in the middle and at the bottom of the sedimentation basin, so that the surplus sludge in the sedimentation basin can be reduced while extra electric energy can be generated as well; and therefore, the cost for disposing, conveying and landfilling of the surplus sludge can be lowered, and the generated electric energy can be stored and utilized.

Description

Membrane filtration coupling single chamber swash plate multianode excess sludge microbial fuel cell unit
Technical field
The invention belongs to field of environment engineering technology, relate to excess sludge and process and technology of middle water recycle, particularly shouldSynchronously realize sludge reduction and energy recovery with single chamber swash plate multianode microbiological fuel cell, and complete the residue of membrane filtrationMud and sewage water treatment method.
Background technology
At present, exceed in the world 90% municipal sewage plant Bian activated sludge process or biomembrance process, processingIn process, produce a large amount of excess sludges. Existing sewage treatment plant lignin-sludge practices well is through concentrated, dehydration and stabilisationAfter be used further to fill out sea, burning or soil utilization etc. But sludge of sewage treatment plant amount is large, moisture content is high, complicated component and perishable,Sludge handling process energy consumption is high, have high input, and causes a large amount of undressed mud to be stacked arbitrarily or simple landfill, not only to environmentPollute, also waste the useful resources in mud. Excess sludge content of organics is high, is a kind of potential biomass energy,Can adopt anaerobic digestion process from mud, to extract biomass energy produces after biogas for generating. But digester need to be controlled temperatureScope is at 30-35 DEG C, and energy consumption is higher, and biogas changes into the higher energy loss of existence in electric energy process. So, at normal temperatureUnder condition of normal pressure, directly from mud, utilizing organic electrogenesis, will be a kind of more efficiently energy utilization patterns.
Excess sludge microbiological fuel cell (SMFC) can directly extract biomass energy from excess sludge, single chamber fortuneOK, without PEM, in producing electric energy, complete mud decrement. The anode of SMFC is immersed in conventionally at the bottom of reactorIn the mud of portion, negative electrode is placed in reactor top supernatant. Electrogenesis microorganism produces the organic matter in oxidatesElectronics is delivered to anode, and electronics arrives negative electrode by external circuit, with cathodic region dissolved oxygen be delivered to the matter of negative electrode from anode regionSon combination generates water, thereby organic pollutant removal and energy recovery are synchronously completed. If therefore excess sludge microorganism is firedMaterial battery is combined with sedimentation basin, can, under normal temperature and pressure conditions, reduce excess sludge production and produce electric energy.
The anode of SMFC is placed in bottom conventionally, but also has abundant biomass energy at the middle part of sedimentation basin. Sedimentation basin simultaneouslyMajor function be after sewage treatment plant's biological processing unit for Separation of Solid and Liquid, inclined-plate clarifying basin utilizes shallow pool theory passableImprove solid-liquid separation efficiency and usefulness. If utilize sedimentation basin bottom anaerobic environment, according to excess sludge microbiological fuel cellElectrogenesis principle is transformed sedimentation basin, and at sedimentation basin, swash plate anode is set according to shallow pool theory, can synchronously complete mudSeparation of Solid and Liquid, minimizing also utilize sedimentation basin bottom and the organic production capacity in middle part simultaneously, are expected significantly to reduce excess sludge placeReason complexity, reduces sewage treatment plant's floor space, investment and operating cost.
Second pond effluent quality cannot meet " urban wastewater treatment firm pollutant emission standard " (GB18918-conventionally2002) one-level A standard, municipal sewage plant need separately establish advanced treatment process. Membrane filtration technique can provide reliable good water outletWater quality, reduces product water efficiency but film pollutes meeting, increases operation complexity. At the excess sludge microorganism fuel by Modification of Secondary Settling TankCell cathode arranges membrane module and filters water outlet, will not only can improve effluent quality, can also utilize negative electrode to repel bear electroactiveMud, can effectively alleviate film and pollute, and membrane component and prolong service life, reduces maintenance cost.
Summary of the invention
The present invention seeks to design film separation coupling single chamber swash plate multianode microbiological fuel cell, synchronously complete sewage placeReason factory mud Separation of Solid and Liquid, minimizing production capacity improve effluent quality of sedimentation tank simultaneously. In the mud of sedimentation basin bottom, carbon is setFelt anode, utilizes organic electrogenesis in mud; Sedimentation basin middle part arranges swash plate anode, when improving deposition efficiency, in utilizationThe organic electrogenesis of clear liquid. At sedimentation basin liquid level, negative electrode is set, near negative electrode, settles membrane filtration module, improve sedimentation basin water outlet waterMatter, and the repulsive interaction for bear electropollution thing by negative electrode, and the barrier effect of swash plate, can stop part mudGrain floating, can alleviate film and pollute.
Swash plate multianode microbiological fuel cell is that the inclined-plate clarifying basin being designed by shallow pool theory carries out upgrading. TiltedlyPlate sedimentation basin can significantly improve deposition efficiency, and plate is apart from being the upward flow sloping plate sedimentation basin of 30-50mm, and its theoretical efficiency can reach advectionDoubly, because the current between swash plate are laminar condition, hydraulic radius is little, is more conducive to precipitate and separate for the 7-10 of sedimentation basin. ThisSwash plate anode in bright not only can increase deposition efficiency, can also increase annode area, utilizes sedimentation basin middle part to enrich organicMatter, improves electrogenesis usefulness and effectively stops mud floating, improves effluent quality. Swash plate anode utilizes plate face deposition produce simultaneouslyElectricity, also the synchronous swash plate surface deposition problem that solves, avoids stopping up and hindering current and proton transfer between swash plate.
Effluent quality of sedimentation tank cannot meet more and more stricter water standard. Membrane bioreactor is by membrane filtrationCan obtain reliable effluent quality, but membrane module is placed in activated sludge, film is seriously polluted, need frequently backwash orAeration washes away, and energy consumption is higher. In the application, membrane module is placed near negative electrode position, repels bear by the elecrtonegativity of negative electrodeElectroactive mud, can effectively alleviate film and pollute. The swash plate anode of installing in sedimentation basin can effectively stop mud granule simultaneouslyFloating, also can alleviate film and pollute, and is not therefore increasing under the condition of energy consumption, is expected to obtain reliable and stable effluent quality.
Technical scheme of the present invention:
A kind of membrane filtration coupling single chamber swash plate multianode excess sludge microbial fuel cell unit, membrane filtration coupling single chamberSwash plate multianode excess sludge microbial fuel cell unit bottom is anaerobic zone mud 2, and carbon felt anode 3 is placed in anaerobic zone mudIn 2, swash plate anode 4 is placed at middle part, and carbon felt anode 3 is connected and is formed multianode by wire with swash plate anode 4; Carbon felt negative electrode 9 is outstandingFloat in supernatant, upper strata is exposed in air as air cathode; Anode be connected by external cord 7 with air cathode andConnect an external resistance 6, hollow fiber film assembly 10 is placed in supernatant, near negative electrode position.
Described swash plate anode 4 is arranged with 60 ° of overturning angles.
Sewage disposal plant aeration tank is discharged mud mixed liquid, after simple and stable, from single chamber swash plate multianode excess sludgeMicrobiological fuel cell swash plate anode bottom end vicinity enters. Mud mixed liquid upward flow is through swash plate anode, and swash plate anode promotes dirtyMud precipitates and stops lighter pollutant floating, makes most of sludge settling to battery bottom, and the anode surface of anaerobic zone, bottom is attachedElectrogenesis bacterium, utilize organic matter in precipitating sludge as anode fuel, when electrogenesis, complete mud decrement. Except precipitating sludgeOutward, all the other mixed liquors are flowed through in the process of swash plate anode, and swash plate anode further extracts biomass energy in mixed liquor, reduce and mixOrganic matter produce electric energy in liquid. The electronics being produced by electrogenesis bacterium is delivered to anode and is delivered to air cathode by external circuit,Be combined and generate water with cathodic region dissolved oxygen and the proton that is delivered to negative electrode from anode region. Supernatant, after membrane module filters, entersMembrane module cavity, suction water outlet.
Effect of the present invention and benefit:
(1) the film separation coupling single chamber swash plate microbiological fuel cell of the application's design can be for city domestic sewage placeManage the transformation of factory's sedimentation basin, make it have the ability of excess sludge processing and resource. It is heavy that anode electrogenesis bacterium can utilize simultaneouslyThe organic matter at bottom, pond, shallow lake and middle part, produces additional electrical energy when reducing sedimentation basin excess sludge, reduced residusal Treatment of Sludge,The expense of transport and landfill, the electric energy of generation can be stored and utilize.
(2) it is heavy that the swash plate anode in the film separation coupling single chamber swash plate microbiological fuel cell that the application designs can improveShallow lake efficiency also effectively stops mud granule floating, improves supernatant water quality, effectively alleviates film and pollutes; Membrane module is near cloudy simultaneouslyThe utmost point, near negative electrode, electric field repulsive interaction also can alleviate film pollution.
(3) hollow fiber film assembly in the film separation coupling single chamber swash plate microbiological fuel cell of the application's design can beWhole system provides the effluent quality of good stable, and water outlet can direct reuse. Solve the poor problem of effluent quality of sedimentation tank, contractingThe expense of Jian Liao sewage treatment plant advanced treating water outlet.
(4) the improved sedimentation basin structure of the membrane filtration coupling single chamber swash plate microbiological fuel cell letter of the application's designSingle, easy to maintenance, service life of equipment is long, has higher application potential and practical value.
Brief description of the drawings
Accompanying drawing is membrane filtration coupling single chamber swash plate multianode microbiological fuel cell schematic diagram.
In figure: 1 mud inlet; 2 anaerobic zone mud; 3 carbon felt anodes; 4 swash plate anodes; 5 conduction titanium silks; 6 outer meeting resistances; Outside 7Connect wires; 8 supervisory control comuters; 9 carbon felt negative electrodes; 10 hollow fiber film assemblies; 11 outlet pipes; 12 vavuum pumps; 13 effluent troughs.
Detailed description of the invention
Describe the specific embodiment of the present invention in detail below in conjunction with technical scheme and accompanying drawing.
Embodiment
A kind of film separation coupling single chamber swash plate multianode excess sludge microbiological fuel cell, the long 226mm of analogue means, wide200mm, high 250mm, there is anaerobic sludge anaerobic zone, bottom, is directly exposed to above in air, and anode carbon felt is placed in anaerobic zone dirtIn mud, long 200mm, wide 180mm, area is 360cm2. Swash plate anode carbon felt, long 200mm, wide 100mm, have four swash plates with60 ° tilting, and at device middle part, level interval is 50mm, and vertical interval is 43mm. Hollow fiber film assembly is placed in supernatant,Above membrane module, place a carbon felt negative electrode at liquid level, be exposed to above in air as air cathode, long 200mm, wide90mm, effective area is 180cm2
Activated sludge enters anaerobic zone dirt from single chamber swash plate multianode excess sludge microbiological fuel cell bottom mud inlet 1In mud 2, upwards stream is through swash plate anode 4, and the organic matter in the mixed liquor of in mud and middle part is at bottom anode and swash plate anode tableFace is degraded by electrogenesis bacterium and is produced electronics and passes through outer meeting resistance 6 by external circuit and arrive carbon felt negative electrode 9, the H of generation+Along with currentArrive air cathode and combination with oxygen and generate water, the voltage of generation is measured and record by voltmeter and supervisory control comuter 8. SupernatantLiquid enters hollow fiber film assembly 10 cavitys, and suction water outlet, finally flows to effluent trough 13 by outlet pipe 11.

Claims (2)

1. a membrane filtration coupling single chamber swash plate multianode excess sludge microbial fuel cell unit, is characterized in that film mistakeFilter coupling single chamber swash plate multianode excess sludge microbial fuel cell unit bottom is anaerobic zone mud (2), carbon felt anode (3)Be placed in anaerobic zone mud (2), swash plate anode (4) is placed at middle part, and carbon felt anode (3) is connected by wire with swash plate anode (4)Form multianode; Carbon felt negative electrode (9) is suspended in supernatant, and upper strata is exposed in air as air cathode; Anode and airNegative electrode is connected by external cord (7) and connects an external resistance (6), and hollow fiber film assembly (10) is placed on supernatantIn, near negative electrode position.
2. a kind of membrane filtration coupling single chamber swash plate multianode excess sludge microbiological fuel cell dress according to claim 1Put, it is characterized in that, described swash plate anode (4) is arranged with 60 ° of overturning angles.
CN201610116381.9A 2016-03-01 2016-03-01 Membrane filtration couples single chamber swash plate multianode excess sludge microbial fuel cell unit Expired - Fee Related CN105609847B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109378508A (en) * 2018-09-30 2019-02-22 天津大学 A kind of single-chamber microbial fuel cell and its application method adding degradation class bacterium
CN110137552A (en) * 2019-04-23 2019-08-16 西安建筑科技大学 One kind having both NOxThe more cathode microbial fuel cells and method of removal and production capacity
CN110148771A (en) * 2019-05-17 2019-08-20 天津大学 A kind of appositional pattern microbiological fuel cell for oil-sludge treatment
CN111252871A (en) * 2020-02-28 2020-06-09 广东工业大学 Device for removing colloid impurities under action of static field force coupled with multistage partition plates and water power
CN112939195A (en) * 2021-02-05 2021-06-11 郑州轻工业大学 Multi-anode microbial fuel cell artificial wetland system, operation method and application
TWI826170B (en) * 2022-12-07 2023-12-11 蘇忠楨 Upright benthic microbial fuel cell module

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CN103351093A (en) * 2013-07-28 2013-10-16 桂林理工大学 Method for excess sludge anerobic fermentation and electricity generation

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109378508A (en) * 2018-09-30 2019-02-22 天津大学 A kind of single-chamber microbial fuel cell and its application method adding degradation class bacterium
CN110137552A (en) * 2019-04-23 2019-08-16 西安建筑科技大学 One kind having both NOxThe more cathode microbial fuel cells and method of removal and production capacity
CN110148771A (en) * 2019-05-17 2019-08-20 天津大学 A kind of appositional pattern microbiological fuel cell for oil-sludge treatment
CN111252871A (en) * 2020-02-28 2020-06-09 广东工业大学 Device for removing colloid impurities under action of static field force coupled with multistage partition plates and water power
CN111252871B (en) * 2020-02-28 2022-06-03 广东工业大学 Device for removing colloid impurities under action of static field force coupled with multistage partition plates and water power
CN112939195A (en) * 2021-02-05 2021-06-11 郑州轻工业大学 Multi-anode microbial fuel cell artificial wetland system, operation method and application
TWI826170B (en) * 2022-12-07 2023-12-11 蘇忠楨 Upright benthic microbial fuel cell module

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