CN105604293B - A kind of energy saving and environment friendly nanometer heating floor - Google Patents
A kind of energy saving and environment friendly nanometer heating floor Download PDFInfo
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- CN105604293B CN105604293B CN201610075469.0A CN201610075469A CN105604293B CN 105604293 B CN105604293 B CN 105604293B CN 201610075469 A CN201610075469 A CN 201610075469A CN 105604293 B CN105604293 B CN 105604293B
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Classifications
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
- E04F15/181—Insulating layers integrally formed with the flooring or the flooring elements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D13/00—Electric heating systems
- F24D13/02—Electric heating systems solely using resistance heating, e.g. underfloor heating
- F24D13/022—Electric heating systems solely using resistance heating, e.g. underfloor heating resistances incorporated in construction elements
- F24D13/024—Electric heating systems solely using resistance heating, e.g. underfloor heating resistances incorporated in construction elements in walls, floors, ceilings
Abstract
The invention belongs to floor panel structure technical field, more particularly, to a kind of heating floor.The energy saving and environment friendly nanometer heating floor of the present invention includes substrate layer, and multilayer speed heat overlay is provided with above its described substrate layer；The speed heat coating layer material includes graphene nano material and paint, and graphene nano material and the mass ratio painted are 1:10000‑1:1200；Waterproofing membrane layer is provided with below the substrate layer；MUF adhesive layers are provided between the substrate layer and speed heat overlay；Also include photo-catalytic antibacterial material in the speed heat overlay；The photo-catalytic antibacterial material is nanoscale TiO2Photocatalyst material and Nano Silver in mass ratio 10 20：The mixture of 24 mixing compositions.Using heating floor made of specific structure of the present invention and material, there is high heating rate, reduction heat build-up and the advantage for reducing energy resource consumption.
Description
Technical field
The invention belongs to floor panel structure technical field, more particularly, to a kind of heating floor.
Background technology
Floor heating full name is floor panel heating, is the heat radiated by the heating source heating floor laid in below ground
Amount, stimulation is produced to human body skin, makes one the heating system to bask.Compared with traditional convection current heating system, floor heating can
To improve indoor air quality, reduce indoor air convection and then reduce airborne dust, flcating germ is reduced, and is advantageous to build health
Indoor environment；It is comfortable to be more beneficial for health.Different from traditional heating system, floor heating makes indoor temperature gradually drop from bottom to top
Low, the temperature of floor surface is higher than the respiratory system temperature of people, gives people a kind of pin and warms up a cool comfort；And due to thermal source
（Such as warm oneself pipe, carbon fibre electrothermal wire）Laying under floor, effectively saves the space for placing warming sheet, facilitates indoor furniture
And that decorates puts.
The floor species of traditional floor heating is various, but structure by existing floor and material are limited, these floors
The time for reaching expected design temperature is very long（It is more than hour to generally require 3）, the room effect of floor heating has been had a strong impact on, and
Easily form heat build-up and form potential safety hazard.
The content of the invention
It is an object of the invention to provide a kind of energy saving and environment friendly nanometer heating floor, compared with existing heating floor, this hair
The bright advantage with performance environmental protection, heating rate height, reduction heat build-up and reduction energy resource consumption.
The present invention above-mentioned technical purpose technical scheme is that：
A kind of energy saving and environment friendly nanometer heating floor, including substrate layer, its described substrate layer top are provided with multilayer speed heat
Overlay；The speed heat coating layer material includes the quality of graphene nano material and paint, graphene nano material and paint
Than 1:10000-1:1200；Waterproofing membrane layer is provided with below the substrate layer；Set between the substrate layer and speed heat overlay
There are MUF adhesive layers；
Also include photo-catalytic antibacterial material in the speed heat overlay；
The photo-catalytic antibacterial material is nanoscale TiO2Photocatalyst material and Nano Silver 10-20 in mass ratio：2-4 is mixed
The mixture of composition.
Graphene is a kind of material of layer structure, and thickness is about less than 1 nanometer, equivalent to the 200000 of a hair thickness
/ mono-, by what is stacked and formed with the planar carbon atom of honeycomb-patterned ordered arrangement from level to level.Graphene has perfect crystal
Structure and excellent heat conducting performance（Thermal conductivity factor is up to 5300 W/m K）Etc. physical property.With function graphene nano material pair
After common heating floor is processed, the heating rate of floor surface can be effectively improved（Improve 30%-75% liter
Warm speed）, save the time for reaching design temperature（Less than 1 hour）, heat conduction efficiency is up to 13 DEG C/h, and because graphene is good
Good heat diffusivity can accumulate uniformity of temperature profile empty calory, eliminate safe hidden trouble.MUF adhesive layers mainly with urea,
Melamine, formaldehyde are matrix, and the floor burst size of methanal handled using MUF adhesives of the present invention is less than 0.2mg/L.
Using heating floor made of specific structure of the present invention and material, have heating rate is high, reduce heat build-up and
Reduce the advantage of energy resource consumption.
Preferably, the speed heat overlay coating method is specially：
（1）It is prepared by graphene nano material：By graphite powder and glucose solids with mass ratio 1：10-15 is in ball grinder cavity
Middle mixing, grinding 15-18h obtain powder；Then solvent is used（Water or organic solvent）The powder is transferred out of, centrifugation is disperseed
Liquid, dialysis obtain the Sheet Graphite alkene nano material that thickness is less than 1nm until in neutrality；
（2）It is prepared by graphene nano material dispersion liquid：Gained graphene nano material is prepared in water or organic solvent
Into uniform translucent graphene nano material dispersion liquid, concentration 0.008-0.08mg/mL；
（3）It is prepared by speed heat coating layer material：Gained graphene nano material dispersion liquid is well mixed with finish paint, graphite
The mass ratio 1 of alkene nano material and paint:10000-1:1200；
（4）Coating；
（5）Dry.
When preparing graphene nano material using particular step method of the present invention, using normal-temperature solid-phase ball milling method, with anti-
The progress answered, graphite flake layer spacing strut, and graphite flake layer bond energy reduces.Under ball milling stress, graphene is smoothly separated
Nanometer sheet, the removal of impurity and the complete graphite powder of unreacted and polymer are gone when being then centrifuged for, obtain the lamella stone that thickness is less than 1nm
Black alkene nano material.
Preferably, the step（1）The graphene purity of preparation is high（99.99%）；The solid-phase grinding is using planetary
Drive manner, ball milling speed 200-350r/min.
Preferably, also include photo-catalytic antibacterial material in the speed heat overlay；
The photo-catalytic antibacterial material is nanoscale TiO2Photocatalyst material and Nano Silver 10-20 in mass ratio：2-4 is mixed
The mixture of composition.
Nanoscale TiO2Photocatalyst material, it is anti-that similar photosynthetic catalysis is produced under the irradiation of sunshine or visible ray
Should, the oxygen in air and hydrone are excited, form oxidability extremely strong hydroxyl free radical and active oxygen.These energy of oxidations
The extremely strong free radical of power can catch and kill the planktonic bacteria in air, and remove that cigarette is smelly, rubbish is smelly, sludge is smelly, and organic contamination
Thing is constantly degraded into free of contamination water and carbon dioxide etc., so as to reach the purpose of environment purification and air.To improve TiO2Light
The photocatalytic activity of catalyst, using Nano Silver as active catalyst.Silver in inorganic nano-silver is noble metal, is sunk by surface
Area method can improve nanoscale TiO2The photocatalytic activity of photocatalyst material, improve the effect of its antibacterial.Nano Silver has anti-in itself
Bacterium acts on, while silver ion has raising nanoscale TiO2The photocatalysis of photocatalyst material, makes TiO2Photocatalyst material can be
Stronger activity just can be produced under longer wavelengths of visible ray, improves the utilization rate of luminous energy.Also, inventor has found, in speed heat
Overlay includes the speed heat performance that photo-catalytic antibacterial material can further improve heating floor, and this is probably nanoscale TiO2
Photocatalyst material has synergistic function with Nano Silver and graphene.
Preferably, the substrate layer is solid wood layer.
Preferably, the substrate layer is solid wood multi-layer harden structure；Plate is prepared during the substrate layer uses, and is specifically
Biomass rubber made from soybean cake is used by middle plate cloth glue-cold pressing-core finishing-combination-hot pressing-cutting edge-sanding, during the cloth glue；The biology
Matter rubber made from soybean cake includes in mass ratio 1：The mixture that 1.5-2.5 bean powder mixes with auxiliary agent；
The auxiliary agent includes water, alkali, polyvinyl alcohol, hexamethyl-epoxy chlorobutane, kaolin and isocyanates；
The biomass rubber made from soybean cake preparation method is included the bean powder and auxiliary agent in the bar that rotating speed is 300-2000r/min
5-20min is stirred under part, is stirred, viscosity is controlled in 30000-100000cps.
By the specific substrate layer of the present invention, help to play the overall anti-microbial property of composite floor board.By using biology
Matter rubber made from soybean cake is as special adhesive, it is ensured that high-environmental, intensity and the antibiotic property of ground laminin plate.Biomass rubber made from soybean cake is by auxiliary agent
With bean powder through stirring, the main component of auxiliary agent is water, alkali, polyvinyl alcohol, hexamethyl-epoxy chlorobutane, kaolin,
Isocyanates etc., bean powder are that soybean grease processed side product forms through processing such as degreasing, grindings.
Preferably, include balance layer below the substrate layer；The balance layer be thickness 0.3-1.2mm veneer, institute
It is rotary-cut material to state balance layer.
Preferably, the upper and lower surface of the balance layer is equipped with thermal trough and thermal hole；The thermal hole passes through
Balance layer is worn, its both ends open is respectively in the thermal trough of balance layer upper and lower surface.
Underfloor heat, which need to pass through floor, to be conducted into room air, and the present invention is provided with floor balance layer and led
Heat channel and thermal hole, the heat energy of base material lower floor are flowed by thermal trough and are delivered to substrate layer lower surface by thermal hole.This is big
Energy transfer rate is accelerated greatly, the heating-up temperature for reaching setting needed for indoor temperature is reduced, saves the energy, while will not
Cause floor problems of crack caused by excessive dehydration.
Preferably, a diameter of 1-3cm of the thermal trough；A diameter of 0.4-1cm of the thermal hole.
The thermal trough and thermal hole of proper ratio are set, thermal loss can be reduced, heating rate is improved, reduces heat heap
Product and reduction energy resource consumption.
Preferably, partly it is provided with thermal conductive cavity between the two neighboring thermal hole of balance layer；It is provided with the thermal conductive cavity
Metallic supports and semiconductor heating piece.Metallic supports can strengthen floor anti-pressure ability, it is ensured that thermal conductive cavity is indeformable.
Preferably, the semiconductor heating piece include for absorb heat cold end, the hot junction for radiating, be arranged on it is described
The metal of N-type semiconductor and P-type semiconductor, the connection N-type semiconductor and the P-type semiconductor between cold end and hot junction is led
Body, power supply；The metallic conductor is provided for electrically connecting the positive and negative electrode of the power supply；The N-type semiconductor sets graphene
Layer, either the P-type semiconductor setting graphene layer or the N-type semiconductor and the P-type semiconductor are respectively provided with graphene
Layer.
Graphene in semiconductor has the high electron mobility and conductance of high thermal conductivity, can promote described
Stable P poles or N poles are more quickly formed with smaller energy consumption for P-type semiconductor and the N-type semiconductor；Meanwhile graphene pole
High heat conductivility can improve heat transfer velocity and ability in the heating and cooling semiconductor chip.So that the semiconductor
The cold end of heating and cooling chip persistently produces cold, and the hot junction of the heating and cooling semiconductor chip persistently produces heat, improves
The temperature difference of the hot cold end of heating and cooling semiconductor chip.Even if the hot junction is simultaneously not provided with semiconductor refrigerating described in heat abstractor
Heating piece can also protect it from burning, and ensure its normal work.
Preferably, it is additionally provided with drier in the thermal trough；
The drier is connected with external control box；Blower fan, heater are provided with the drier and for accommodating and
Protect the elastic protecting sleeve of the blower fan and heater；Controller, time switch and attaching plug are mounted with the control box.
When needing work, plug in, open time switch timing, drier is started working, and blower fan makes in thermal trough
Moisture discharge；When temperature is relatively low or humidity is larger, start heater, condensing drip is heated as vapor discharge, together
When, when running into rainy weather, floor be easier to make moist in itself breed bacteria when, start heater, it is former according to pasteurization
Reason, heated by heater and dry and kept for a period of time, most harmful bacteria in floor can be killed.In summary,
The invention has the advantages that：
1st, heating floor of the present invention is provided with thermal trough, thermal hole and thermal conductive cavity, can effectively lift thermal energy conduction efficiency, together
When also have sound insulation and noise reduction effect.Metallic supports are provided with thermal conductive cavity, floor anti-pressure ability can be lifted.
2nd, heating floor heat conducting nano dope layer of the present invention is graphene heat conducting nano dope layer, effectively can improve ground
The heating rate of plate surface, the time for reaching design temperature is saved, and because the good heat diffusivity of graphene can make temperature
The empty calory accumulation that is evenly distributed is spent, is eliminated safe hidden trouble.
3rd, nanoscale TiO2Photocatalyst material, similar photosynthetic catalysis is produced under the irradiation of sunshine or visible ray
Reaction, the oxygen in air and hydrone are excited, and form oxidability extremely strong hydroxyl free radical and active oxygen.These oxidations
Very competent free radical can catch and kill the planktonic bacteria in air, and remove that cigarette is smelly, rubbish is smelly, sludge is smelly, and organic dirt
Dye thing is constantly degraded into free of contamination water and carbon dioxide etc., so as to reach the purpose of environment purification and air.To improve TiO2
The photocatalytic activity of photocatalyst, using Nano Silver as active catalyst.Silver in inorganic nano-silver is noble metal, passes through surface
Sedimentation can improve nanoscale TiO2The photocatalytic activity of photocatalyst material, improve the effect of its antibacterial.Nano Silver has in itself
Antibacterial action, while silver ion has raising nanoscale TiO2The photocatalysis of photocatalyst material, makes TiO2Photocatalyst material energy
Stronger activity just can be produced under longer wavelengths of visible ray, improves the utilization rate of luminous energy.Also, inventor has found, in speed
Hot overlay includes the speed heat performance that photo-catalytic antibacterial material can further improve heating floor, and this is probably nanoscale
TiO2Photocatalyst material has synergistic function with Nano Silver and graphene.
Brief description of the drawings
Fig. 1 is quick-heating type nanometer heating floor schematic diagram of the present invention；
Fig. 2 is semiconductor heating piece schematic diagram of the present invention；
Fig. 3 is common heating floor and colleges and universities' quick-heating type nanometer heating floor heat-transfer effect comparison diagram of the present invention；
Fig. 4 is drier schematic diagram of the present invention.
Embodiment
Embodiment one
As shown in figure 1, energy saving and environment friendly nanometer heating floor includes substrate layer 1, the top of substrate layer 1 is provided with multilayer speed heat
Overlay 2；Speed heat coating layer material includes the mass ratio 1 of graphene nano material and paint, graphene nano material and paint:
10000.Substrate layer 1 is solid wood layer.The lower section of substrate layer 1 is provided with waterproofing membrane layer 4；Set between substrate layer 1 and speed heat overlay 2
There are MUF adhesive layers.Also include photo-catalytic antibacterial material in speed heat overlay 2；Photo-catalytic antibacterial material is nanoscale TiO2Light
Catalyst material and Nano Silver in mass ratio 15：The mixture of 3 mixing compositions.
Speed heat overlay coating method is specially：
（1）It is prepared by graphene nano material：By graphite powder and glucose solids with certain proportion（Mass ratio 1：10）In ball
Mixed in grinding jar cavity, with certain speed（200r/min）Solid-phase grinding 18h, solid-phase grinding use planetary drive manner,
Ball milling speed is 200r/min, obtains powder；Then solvent is used（Water or organic solvent）The powder is transferred out of, centrifugation goes to clean
Matter（The complete graphite powder of unreacted and polymer）Dispersion liquid is obtained, dialysis obtains the lamella that thickness is less than 1nm until in neutrality
Graphene nano material；
（2）It is prepared by graphene nano material dispersion liquid：Gained graphene nano material is prepared in water or organic solvent
Into uniform translucent graphene nano material dispersion liquid, concentration 0.008mg/mL；
（3）It is prepared by speed heat coating layer material：Gained graphene nano material dispersion liquid is well mixed with finish paint；
（4）Coating；
(5) dry.
Common paint floor and energy saving and environment friendly nanometer heating floor use identical base material and paint raw materials, 42 DEG C of thermals source
Equal conditions under, room temperature starts to conduct heat, if sets target temperature be 32.3 DEG C（The relatively comfortable temperature of floor heating）, it can be seen that this
The energy saving and environment friendly nanometer heating floor that invention heating floor provides reaches the heat transfer time of setting compared with common heating floor
Shorten 44%, it was confirmed that energy saving and environment friendly nanometer heating floor provided by the invention has high rate of heat transfer and splendid led
Thermal efficiency（The detection of national authority testing agency is up to 13 DEG C/h）, it is specifically shown in Fig. 3.
Embodiment two
Energy saving and environment friendly nanometer heating floor includes substrate layer 1, and the top of substrate layer 1 is provided with multilayer speed heat overlay 2；Speed
Heat coating layer material includes the mass ratio 1 of graphene nano material and paint, graphene nano material and paint:5000.Base material
Layer 1 is solid wood layer.The lower section of substrate layer 1 is provided with waterproofing membrane layer 4；MUF gluings are provided between substrate layer 1 and speed heat overlay 2
Oxidant layer.Also include photo-catalytic antibacterial material in speed heat overlay 2；Photo-catalytic antibacterial material is nanoscale TiO2Photocatalyst material with
Nano Silver in mass ratio 10：The mixture of 4 mixing compositions.
Speed heat overlay coating method is specially：
（1）It is prepared by graphene nano material：By graphite powder and glucose solids with certain proportion（Mass ratio 1：15）In ball
Mixed in grinding jar cavity, with certain speed（350r/min）Solid-phase grinding 15h, solid-phase grinding use planetary drive manner,
Ball milling speed is 350r/min, obtains powder；Then solvent is used（Water or organic solvent）The powder is transferred out of, centrifugation goes to clean
Matter（The complete graphite powder of unreacted and polymer）Dispersion liquid is obtained, dialysis obtains the lamella that thickness is less than 1nm until in neutrality
Graphene nano material；
（2）It is prepared by graphene nano material dispersion liquid：Gained graphene nano material is prepared in water or organic solvent
Into uniform translucent graphene nano material dispersion liquid, concentration 0.08mg/mL；
（3）It is prepared by speed heat coating layer material：Gained graphene nano material dispersion liquid is well mixed with finish paint；
（4）Coating；
(5) dry.
Embodiment three
Energy saving and environment friendly nanometer heating floor includes substrate layer 1, and the top of substrate layer 1 is provided with multilayer speed heat overlay 2；Speed
Heat coating layer material includes the mass ratio 1 of graphene nano material and paint, graphene nano material and paint:1200.Base material
Layer 1 is solid wood layer.Also include photo-catalytic antibacterial material in speed heat overlay 2；Photo-catalytic antibacterial material is nanoscale TiO2Light touches
Catalytic material and Nano Silver in mass ratio 20：The mixture of 2 mixing compositions.
Speed heat overlay coating method is specially：
（1）It is prepared by graphene nano material：By graphite powder and glucose solids with certain proportion（Mass ratio 1：12）In ball
Mixed in grinding jar cavity, with certain speed（250r/min）Solid-phase grinding 16h, solid-phase grinding use planetary drive manner,
Ball milling speed is 250r/min, obtains powder；Then solvent is used（Water or organic solvent）The powder is transferred out of, centrifugation goes to clean
Matter（The complete graphite powder of unreacted and polymer）Dispersion liquid is obtained, dialysis obtains the lamella that thickness is less than 1nm until in neutrality
Graphene nano material；
（2）It is prepared by graphene nano material dispersion liquid：Gained graphene nano material is prepared in water or organic solvent
Into uniform translucent graphene nano material dispersion liquid, concentration 0.02mg/mL；
（3）It is prepared by speed heat coating layer material：Gained graphene nano material dispersion liquid is well mixed with finish paint；
（4）Coating；
(5) dry.
Example IV
With embodiment one, the difference is that substrate layer 1 is solid wood multi-layer harden structure；Plate is prepared during substrate layer 1 uses, and has
Body is by middle plate cloth glue-cold pressing-core finishing-combination-hot pressing-cutting edge-sanding, uses biomass rubber made from soybean cake during cloth glue；Biomass is big
Bean gum includes in mass ratio 1：The mixture that 1.5 bean powder mixes with auxiliary agent；Auxiliary agent includes water, alkali, polyvinyl alcohol, pregnancy
Base-epoxy chlorobutane, kaolin and isocyanates；Biomass rubber made from soybean cake preparation method is included bean powder
5-20min is stirred under conditions of 300r/min, is stirred, viscosity is controlled in 30000cps.The lower section of substrate layer 1 includes balance layer
3；Balance layer 3 is thickness 0.3mm veneer, and balance layer is rotary-cut material.
Embodiment five
With embodiment two, the difference is that substrate layer 1 is solid wood multi-layer harden structure；Plate is prepared during substrate layer 1 uses, and has
Body is by middle plate cloth glue-cold pressing-core finishing-combination-hot pressing-cutting edge-sanding, uses biomass rubber made from soybean cake during cloth glue；Biomass is big
Bean gum includes in mass ratio 1：The mixture that 2.5 bean powder mixes with auxiliary agent；Auxiliary agent includes water, alkali, polyvinyl alcohol, pregnancy
Base-epoxy chlorobutane, kaolin and isocyanates；Biomass rubber made from soybean cake preparation method is included bean powder
20min is stirred under conditions of 2000r/min, is stirred, viscosity is controlled in 100000cps.The lower section of substrate layer 1 includes balance layer
3；Balance layer 3 is thickness 1.2mm veneer, and balance layer is rotary-cut material.
Embodiment six
With embodiment three, the difference is that substrate layer 1 is solid wood multi-layer harden structure；Plate is prepared during substrate layer 1 uses, and has
Body is by middle plate cloth glue-cold pressing-core finishing-combination-hot pressing-cutting edge-sanding, uses biomass rubber made from soybean cake during cloth glue；Biomass is big
Bean gum includes in mass ratio 1：The mixture that 2 bean powder mixes with auxiliary agent；Auxiliary agent includes water, alkali, polyvinyl alcohol, pregnancy
Base-epoxy chlorobutane, kaolin and isocyanates；Biomass rubber made from soybean cake preparation method is included bean powder
10min is stirred under conditions of 1000r/min, is stirred, viscosity is controlled in 70000cps.The lower section of substrate layer 1 includes balance layer
3；Balance layer 3 is thickness 0.9mm veneer, and balance layer is rotary-cut material.
Embodiment seven
With embodiment six, the difference is that as shown in figure 1, the upper and lower surface of balance layer 3 is equipped with the He of thermal trough 31
Thermal hole 32；Thermal hole 32 runs through balance layer 3, and its both ends open is respectively in the thermal trough 31 of the upper and lower surface of balance layer 3.It is flat
Thermal conductive cavity 33 is partly provided between the weighing apparatus two neighboring thermal hole 32 of layer 3；Metallic supports 34 and semiconductor are provided with thermal conductive cavity 33
Heat piece 35.
Semiconductor heating piece 35 includes the cold end 21 for heat absorption, the hot junction 22 for radiating, is arranged on cold end 21 and heat
The metallic conductor 25 of N-type semiconductor 23 and P-type semiconductor 24, connection N-type semiconductor 23 and P-type semiconductor 24 between end 22,
Power supply 26；Metallic conductor 25 is provided for the positive and negative electrode of electric connection of power supply 26；N-type semiconductor 23 sets graphene layer 27, or
Person's P-type semiconductor 24 sets graphene layer 27, or N-type semiconductor 23 and P-type semiconductor 24 to be respectively provided with graphene layer 27.
Embodiment eight
With embodiment six, unlike as shown in figure 4, in order to tackle that temperature is relatively low or humidity is larger or the spy such as rainy weather
Different climatic environment, inventor expects setting in thermal trough 31 or connection drier 26, drier 26 connect external control box；When
When needing work, plug in, open time switch timing, drier is started working, and blower fan 262 arranges the moisture in thermal trough
Go out；Start heater 262, condensing drip is heated as vapor discharge, such as when running into rainy weather, floor is compared in itself
During breed bacteria of easily making moist, start heater 262, according to pasteurization principle, heated by heater and dry and keep
For a period of time, most harmful bacteria in floor can be killed.Blower fan 261, heater 262 are provided with drier 26 and is used
In the accommodating and elastic protecting sleeve 263 of protection blower fan 261 and heater 262；Be mounted with control box controller, time switch and
Attaching plug.
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, people in the art
Member can make the modification of no creative contribution to the present embodiment as needed after this specification is read, but as long as at this
All protected in the right of invention by Patent Law.
Claims (4)
1. a kind of energy saving and environment friendly nanometer heating floor, including substrate layer（1）, it is characterised in that：The substrate layer（1）Top is set
It is equipped with multilayer speed heat overlay（2）；The speed heat coating layer material includes graphene nano material and paint, graphene nano material
The mass ratio of material and paint is 1:10000-1:1200；The substrate layer（1）Lower section is provided with waterproofing membrane layer（4）；The base material
Layer（1）With speed heat overlay（2）Between be provided with MUF adhesive layers；
The speed heat overlay（2）In also include photo-catalytic antibacterial material；
The photo-catalytic antibacterial material is nanoscale TiO2Photocatalyst material and Nano Silver 10-20 in mass ratio：2-4 mixing compositions
Mixture；
The speed heat overlay coating method is specially：
（1）It is prepared by graphene nano material：By graphite powder and glucose solids with mass ratio 1：10-15 is mixed in ball grinder cavity
Close, solid-phase grinding 15-18h obtains powder；Then the powder is transferred out of with water or organic solvent, centrifugation obtains dispersion liquid, thoroughly
Analysis obtains the Sheet Graphite alkene nano material that thickness is less than 1nm until in neutrality；
（2）It is prepared by graphene nano material dispersion liquid：Gained graphene nano material is prepared into water or organic solvent
Even translucent graphene nano material dispersion liquid, concentration 0.008-0.08mg/mL；
（3）It is prepared by speed heat coating layer material：Gained graphene nano material dispersion liquid is well mixed with paint, graphene nano
The mass ratio 1 of material and paint:10000-1:1200；
（4）Coating；
（5）Dry；
The step（1）The graphene purity of preparation is more than 99.99%；The solid-phase grinding uses planetary drive manner, ball
Mill speed is 200-350r/min；
The substrate layer（1）Lower section includes balance layer（3）；The balance layer（3）It is described flat for thickness 0.3-1.2mm veneer
Weighing apparatus layer is rotary-cut material；
The balance layer（3）Upper and lower surface be equipped with thermal trough（31）And thermal hole（32）；The thermal hole（32）
Through balance layer（3）, its both ends open is located at balance layer respectively（3）The thermal trough of upper and lower surface（31）It is interior；
The balance layer（3）Two neighboring thermal hole（32）Between be partly provided with thermal conductive cavity（33）；The thermal conductive cavity（33）Inside set
There are metallic supports（34）With semiconductor heating piece（35）；
The semiconductor heating piece（35）Including the cold end for heat absorption（21 ）, hot junction for radiating（22 ）, be arranged on institute
State cold end（21 ）And hot junction（22 ）Between N-type semiconductor（23 ）And P-type semiconductor（24 ）, the connection N-type semiconductor
（23 ）With the P-type semiconductor（24 ）Metallic conductor（25 ）, power supply（26 ）；The metallic conductor（25 ）It is provided for
Electrically connect the power supply（26 ）Positive and negative electrode；The N-type semiconductor（23 ）Graphene layer is set（2 7 ）, or the P
Type semiconductor（24 ）Graphene layer is set（27 ）, or the N-type semiconductor（23 ）With the P-type semiconductor（24 ）It is all provided with
Put graphene layer（27 ）.
A kind of 2. energy saving and environment friendly nanometer heating floor according to claim 1, it is characterised in that：The substrate layer（1）
For solid wood layer.
A kind of 3. energy saving and environment friendly nanometer heating floor according to claim 1, it is characterised in that：The substrate layer（1）
For solid wood multi-layer harden structure；The substrate layer（1）Plate is prepared in, specifically by middle plate cloth glue-cold pressing-core finishing-group
Conjunction-hot pressing-cutting edge-sanding, biomass rubber made from soybean cake is used during the cloth glue；The biomass rubber made from soybean cake includes in mass ratio 1：
The mixture that 1.5-2.5 bean powder mixes with auxiliary agent；
The auxiliary agent includes water, alkali, polyvinyl alcohol, hexamethyl-epoxy chlorobutane, kaolin and isocyanates；
The biomass rubber made from soybean cake preparation method is included the bean powder and auxiliary agent under conditions of rotating speed is 300-2000r/min
5-20min is stirred, is stirred, viscosity is controlled in 30000-100000cps.
A kind of 4. energy saving and environment friendly nanometer heating floor according to claim 1, it is characterised in that：The thermal trough（31）
Inside it is additionally provided with drier（26）；The drier（26）It is connected with external control box；The drier（26）Inside it is provided with blower fan
（261）, heater（262）With for housing and protecting the blower fan（261）And heater（262）Elastic protecting sleeve（263）；
Controller, time switch and attaching plug are mounted with the control box.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610075469.0A CN105604293B (en) | 2016-02-03 | 2016-02-03 | A kind of energy saving and environment friendly nanometer heating floor |
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| CN106051897B (en) * | 2016-06-17 | 2019-03-12 | 浙江暖诚智能科技有限公司 | A kind of semiconductor temp.-regulating floor based on Internet of Things |
| CN112391033A (en) * | 2020-11-16 | 2021-02-23 | 青岛德通纳米技术有限公司 | Efficient antibacterial heat-conducting wear-resistant layer for floor and preparation method thereof |
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