CN105603739A - 一种有机无机复合多功能单向导湿整理剂及其应用 - Google Patents

一种有机无机复合多功能单向导湿整理剂及其应用 Download PDF

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CN105603739A
CN105603739A CN201510992658.XA CN201510992658A CN105603739A CN 105603739 A CN105603739 A CN 105603739A CN 201510992658 A CN201510992658 A CN 201510992658A CN 105603739 A CN105603739 A CN 105603739A
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CN105603739B (zh
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刘保江
姚金龙
黄长根
许小军
向中林
巨安奇
唐文君
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JIANGSU LIANFA TEXTILE CO Ltd
Donghua University
National Dong Hwa University
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Donghua University
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Abstract

本发明涉及一种有机无机复合多功能单向导湿整理剂及其应用，组分按重量百分比包括：10％～20％组分A、5％～10％组分B和70％～80％组分C；其中，A为重量比为1～2：4～6：2～3：0.5～1的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯，B为重量比为50:1～:20:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂组成，C为重量比1～3：4～5：1～2：0.5～1的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素组成。所述整理剂应用于纤维制品。本发明克服了现有产品的不足，易于工业化生产，应用方法简单，成本低，具有良好的应用前景和经济效益。

Description

一种有机无机复合多功能单向导湿整理剂及其应用
技术领域
本发明属于整理剂及其应用领域，特别涉及一种有机无机复合多功能单向导湿整理剂及其应用。
背景技术
随着生活水平的日益提高，人们对服装面料各方面的要求也越来越高，个性化、高档化及吸湿、透气、排汗、快干、防臭抗菌、抗紫外线等功能性纺织品己成为纺织服装面料的发展趋势。为了生产出功能性各异的材料，需要在纺织品后整理中注入许多高新整理技术，如三拒一抗整理、单向导湿整理、抗菌除臭整理、等离子体刻蚀整理、新型纳米颗粒整理等新型整理技术。UV紫外光固化整理剂由于具有固化速度快、对环境污染小、节省能源、对基材的适用范围广以及适合于高速自动化生产等优点而日益受到重视。但以往UV固化整理剂使用的低聚物主要为线形聚合物，存在粘度大、氧阻聚较严重等问题。为得到应用所需的粘度和流变性能，需要加入大量的稀释剂来调节，但使用的稀释剂大多有刺激性气味且易挥发，容易对人体健康和周围环境造成伤害，限制了其应用。而超支化聚合物这种具有高度支化分子拓扑结构的树形高分子，由于具有分子间链缠结少、溶解性好、粘度低、易成膜和反应活性高等特点，因此制备具有光敏性能的超支化聚合物用作单向导湿多功能整理剂，可以改善线形低聚物在应用性能上的缺点。
发明内容
本发明所要解决的技术问题是提供一种有机无机复合多功能单向导湿整理剂及其应用，该整理剂克服了现有产品的不足，能实现纤维制品单向导湿性能、抗菌除臭能力，易于工业化生产，应用方法简单，成本低，具有良好的应用前景和经济效益。
本发明的一种有机无机复合多功能单向导湿整理剂，组分按重量百分比包括：10％～20％组分A、5％～10％组分B和70％～80％组分C；其中，A为重量比为1～2：4～6：2～3：0.5～1的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯，B为重量比为50:1～:20:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂组成，C为重量比1～3：4～5：1～2：0.5～1的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素组成。
所述γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶中γ-甲基丙烯酰氧基丙基三甲氧基硅烷与SiO2溶胶的摩尔比为1:16。
所述光引发剂为德国巴斯夫光引发剂DAROCUR1173。
所述的增稠剂为浙江传化股份有限公司的增稠剂TF-313。
所述的粘合剂为成都茵地乐电源科技有限公司LA132粘合剂。
所述的有机无机复合多功能单向导湿整理剂的应用，应用于纤维制品。
所述纤维制品为由纤维素纤维、蛋白质纤维、合成纤维和纯纤维中的至少一种制得的机织物、针织物或非织造布。
所述应用于纤维制品包括：
(1)按重量比1～2：4～6：2～3：0.5～1的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯组分A、重量比为50:1～:20:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂与组分B和重量比1～3：4～5：1～2：0.5～1的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素重混合，制得含有重量百分比10％～20％组分A、重量百分比5％～10％组分B和重量百分比70％～80％组分C的有机无机复合多功能单向导湿整理剂；
(2)将步骤(1)中有机无机复合多功能单向导湿整理剂配制成印花浆料，单面拒水丝网印花，紫外光固化。
所述步骤(2)中印花为单面印花；紫外光固化的时间为1～3min。
有益效果
本发明克服了现有产品的不足，既能提高纤维制品抗光氧化降解能力，固化能力，又能降保护剂成本，易于工业化生产，应用方法简单，成本低，具有良好的应用前景和经济效益。
具体实施方式
下面结合具体实施例，进一步阐述本发明。应理解，这些实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解，在阅读了本发明讲授的内容之后，本领域技术人员可以对本发明作各种改动或修改，这些等价形式同样落于本申请所附权利要求书所限定的范围。
实施例1
有机无机复合多功能单向导湿整理剂组成：重量百分比15％组分A、重量百分比5％组分B、和80％组分C，其中A为重量比为1：4：2：1的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯，其中组分B重量比为50:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂组成，其中C为重量比1：4：1：0.5的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素组成。
其中，光引发剂为德国巴斯夫光引发剂DAROCUR1173，增稠剂为浙江传化股份有限公司的增稠剂TF-313，粘合剂为成都茵地乐电源科技有限公司LA132粘合剂，γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶中γ-甲基丙烯酰氧基丙基三甲氧基硅烷与SiO2溶胶的摩尔比为1:16。
整理织物：棉：涤(比例70：30)混纺面料。
整理工艺流程：印花浆料→单面印花→紫外光固化(3min)。
实施例2
有机无机复合多功能单向导湿整理剂组成：重量百分比10％组分A、重量百分比10％组分B、和重量百分比80％组分C，其中A为重量比为1.5：5：2.5：0.75的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯，其中组分B重量比为35:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂组成，其中C为重量比2：4：2：0.8的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素组成。
其中，光引发剂为德国巴斯夫光引发剂DAROCUR1173，增稠剂为浙江传化股份有限公司的增稠剂TF-313，粘合剂为成都茵地乐电源科技有限公司LA132粘合剂，γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶中γ-甲基丙烯酰氧基丙基三甲氧基硅烷与SiO2溶胶的的摩尔比为1:16。
整理织物：羊毛：涤(比例60：40)混纺面料。
整理工艺流程：印花浆料→单面印花→紫外光固化(2min)。
实施例3
有机无机复合多功能单向导湿整理剂组成：重量百分比20％组分A、重量百分比8％组分B、和重量百分比72％组分C，其中A为重量比为2：6：3：1的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯，其中组分B重量比为20:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂组成，其中C为重量比3：5：2：1的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素组成。
其中，光引发剂为德国巴斯夫光引发剂DAROCUR1173，增稠剂为浙江传化股份有限公司的增稠剂TF-313，粘合剂为成都茵地乐电源科技有限公司LA132粘合剂，γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶中γ-甲基丙烯酰氧基丙基三甲氧基硅烷与SiO2溶胶的的摩尔比为1:16。
整理织物：麻：棉(比例30：70)混纺面料。
整理工艺流程：印花浆料→单面印花→紫外光固化(1min)。
目前对织物单向导湿性能的测试主要是通过测试织物表、里层吸湿及快干性能的差异。本试验为探讨织物表、里层组织结构对其吸湿快干性能的影响，对各试样的表、里层分别进行滴液平铺测试，同时测试织物表、里层的快干时间。在温度(20±2)℃、相对湿度(65±2)％的条件下，将试样铺平，在离布面2cm处对织物不同位置进行滴液试验，滴液质量为(0.1±0.02)g。记录液滴在织物上由珠状扩展直到平铺的时间，测试5次求平均值。为减少测试误差，滴管应与织物平面保持垂直，测试数据见表1。将试样在温度(20±2)℃、相对湿度(65±2)％的条件下平衡24h后进行测试。用圆盘取样器裁剪出面积为100cm2的待测织物，称重；将质量为(0.01±0.005)g的水滴滴在圆形织物试样的圆心处，开始计时，记录每隔2min织物试样质量的变化情况；当织物质量恢复为原始质量时，停止测试，测试5次求平均值，测试数据见表1。
表1滴液平铺与快干测试结果
其中，表格1中所述织物样品1,2,3分别对应实施例1、实施例2和实施例3中得到的织物。
织物抗菌性能参照FZ/T73023-2006《抗菌针织品》，以振荡法测定织物的抗菌性能。所用菌种为大肠杆菌,试样的抗菌性能以抗菌效率表示，按式(1)计算取100μL涂布于琼脂培养皿中，在37℃下培养24h后，用平板计数法记录菌落数.织物抗菌性用公式R＝[(B－A)/B]×100％(公式1)计算，其中R代表抗菌率，A和B分别为样品和对照组的细菌浓度。抗菌性能数据如表2所示。
表2经整理剂整理后织物抗菌性能
样品 活菌数 抑菌率
1 <10 99.99
2 <10 99.99
3 <10 99.99
其中，表格1中所述织物样品1,2,3分别对应实施例1、实施例2和实施例3中得到的织物。

Claims (9)

1.一种有机无机复合多功能单向导湿整理剂，组分按重量百分比包括：10％～20％组分A、5％～10％组分B和70％～80％组分C；其中，A为重量比为1～2：4～6：2～3：0.5～1的超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯，B为重量比为50:1～:20:1的γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂组成，C为重量比1～3：4～5：1～2：0.5～1的增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素组成。
2.根据权利要求1所述的一种有机无机复合多功能单向导湿整理剂，其特征在于，所述γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶中γ-甲基丙烯酰氧基丙基三甲氧基硅烷与SiO2溶胶的质量摩尔比为1:16。
3.根据权利要求1所述的一种有机无机复合多功能单向导湿整理剂，其特征在于，所述光引发剂为DAROCUR1173。
4.根据权利要求1所述的一种有机无机复合多功能单向导湿整理剂，其特征在于，所述增稠剂为TF-313。
5.根据权利要求1所述的一种有机无机复合多功能单向导湿整理剂，其特征在于，所述粘合剂为LA132粘合剂。
6.一种如权利要求1所述的有机无机复合多功能单向导湿整理剂的应用，其特征在于，应用于纤维制品。
7.根据权利要求6所述的一种有机无机复合多功能单向导湿整理剂的应用，其特征在于，所述纤维制品为由纤维素纤维、蛋白质纤维、合成纤维和纯纤维中的至少一种制得的机织物、针织物或非织造布。
8.根据权利要求6所述的一种有机无机复合多功能单向导湿整理剂的应用，其特征在于，所述应用于纤维制品包括：
(1)将超支化聚氨酯丙烯酸酯、羧基化壳聚糖、正己醇和超支化聚酯丙烯酸酯组分A、γ-甲基丙烯酰氧基丙基三甲氧基硅烷/SiO2溶胶和光引发剂与组分B和增稠剂、粘合剂、十二烷基硫酸钠、羟基纤维素重混合，制得有机无机复合多功能单向导湿整理剂；
(2)将步骤(1)中有机无机复合多功能单向导湿整理剂配制成印花浆料，单面拒水丝网印花，紫外光固化。
9.根据权利要求8所述的一种有机无机复合多功能单向导湿整理剂的应用，其特征在于，所述步骤(2)中印花为单面印花；紫外光固化的时间为1～3min。
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