CN105603727A - Novel anti-ultraviolet antibacterial finishing agent and preparing method thereof - Google Patents

Novel anti-ultraviolet antibacterial finishing agent and preparing method thereof Download PDF

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Publication number
CN105603727A
CN105603727A CN201610015306.3A CN201610015306A CN105603727A CN 105603727 A CN105603727 A CN 105603727A CN 201610015306 A CN201610015306 A CN 201610015306A CN 105603727 A CN105603727 A CN 105603727A
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parts
finishing agent
antibacterial finishing
nano
antiultraviolet
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CN201610015306.3A
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王锦江
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HUZHOU QIANJIN SILK Co Ltd
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HUZHOU QIANJIN SILK Co Ltd
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Priority to CN201610015306.3A priority Critical patent/CN105603727A/en
Publication of CN105603727A publication Critical patent/CN105603727A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D—TEXTILES; PAPER
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
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    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

The invention discloses a novel anti-ultraviolet antibacterial finishing agent. The finishing agent is prepared from nanometer oxide, oligomeric sodium acrylate, a silane coupling agent, diphenyl acetone, phenyl triazine, sorbitan monooleate polyoxyethylene ether, sodium carbonate, an initiating agent, a guanidine antibacterial agent, copper 8-hydroxyquinoline and water. The anti-ultraviolet antibacterial finishing agent enables fabric to have antibacterial and anti-ultraviolet functions, thoroughly eradicates repeated pollution, and is good in effect and nontoxic.

Description

A kind of novel anti-ultraviolet antibacterial finishing agent and preparation method thereof
Technical field
The present invention relates to a kind of textile finshing agent. More particularly, the present invention relates to a kind of novelUvioresistant antibacterial finishing agent and preparation method thereof.
Background technology
Since twentieth century, along with a large amount of uses in carbon fluorine series solvent and fluorine Lyons, make the earth largeIn gas-bearing formation, ozone layer suffers serious destruction, and the ultraviolet ray that arrives earth surface constantly increases, and makesThe harm of health is more troubling in pairs. Ultraviolet ray is that wavelength is the electromagnetism of 180～400nmRipple, appropriate ultraviolet radiation has bactericidal action and can promote the synthetic, favourable of vitamin DIn health, but under burning sun prolonged exposure, human body skin can lose defensive ability/resistance ability, Yi Fa, there is erythema or blister in raw burning, excessive ultraviolet ray is irradiated also can bring out skin disease, can leadCause cutaneum carcinoma, cataract, suppress human immune system. Therefore, in order to protect human body to exempt fromMeasure ultraviolet radiation, the product of research and development ultra-violet radiation resisting is extremely urgent.
The textile of some and human body close contact in use, inevitably can be stained thinBacterium. Because common textile there is no bactericidal action, therefore that itself also can become various pathogenic bacteria is large" hotbed " of amount breeding, plays and adds fuel to the flames the flora imbalance on human body skin surface converselyEffect. Finance, stain the bacterium on textile, obtain the same of the rapid breeding of nutrition at itTime, can metabolism or decomposite the volatilization of various lower fatty acids, ammonia or other irritant stinksProperty article, add the secretion of bacterium itself and the corrupt smell of the dead bones of the body, textile is produced eachPlant disgusting smell, affect health.
Therefore, exploitation one has antiultraviolet and antibacterial simultaneously, and is safety non-toxic, againThe antiultraviolet antibacterial finishing agent with excellent durability becomes important research direction.
Summary of the invention
The object of the invention is to provide a kind of unioresistant antibacterial finishing agent. Of the present invention wholeAntibacterial fabric and anti-ultraviolet function are given in reason agent, thoroughly stop repeated contamination, effective, andNon-toxic.
The technical solution used in the present invention is:
A kind of novel antiultraviolet antibacterial finishing agent, comprises the component of following weight portion:
Nano-oxide: 0.1～2 part; Sodium low polyacrylate: 3～6 parts;
Silane coupler: 1～3 part; Two propiophenones: 5～15 parts; Phenyl triazine: 2～12 parts;
Sorbitan monooleate APEO: 5～20 parts; Soda ash: 1～8 part;
Initator: 2～4 parts; Guanidine class antiseptic: 0.1～5 part;
Copper 8-quinolinolate: 1～8 part; Water: 60～80 parts.
Preferably, described nano-oxide be nano zine oxide, titanium dioxide, silica,One in magnesia.
Preferably, the number-average molecular weight of described sodium low polyacrylate is 2000～3000. Preferably, described initator is selected from sodium peroxydisulfate, potassium peroxydisulfate, ammonium persulfate, benzoyl peroxide firstOne in acyl.
Preferably, described guanidine class antiseptic is selected from dodine, 1,6-bis-(4 '-chlorobenzenesBiguanides) hexane or hexamethylene.
Another object of the present invention is to provide a kind of preparation side of antiultraviolet antibacterial finishing agentMethod, comprises the steps:
Step 1: by the proportioning of claim 1 by sorbitan monooleate APEO,Soda ash, silane coupler join in reaction vessel and stir, and are heated to 58～65 DEG C;
Step 2: vessel temp is down to 55 DEG C, adding oligomeric acrylic acid in reaction vesselSodium, nano-oxide, two propiophenones, phenyl triazine, copper 8-quinolinolate, guanidine class antiseptic,Continue to stir;
Step 3: get initator and be dissolved in water, after dissolving, to entering in container, stir,Obtain mixing material;
Step 4: mixing material is cooled to room temperature, uses cutter shear treatment after being down to room temperature,Cutter rotating speed is 6000rpm, and shear time is 10min～15min, shears and finishes rear preparationObtain uvioresistant antibacterial finishing agent.
The present invention at least comprises following beneficial effect:
(1) finishing agent of the present invention is given antibacterial fabric and anti-ultraviolet function, thoroughly stops heavilyMultiple pollution, effective, and non-toxic;
(2) finishing agent of the present invention can also be given the good washability of fabric and soft feel.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, whereby to thisInvent how application technology means solve technical problem, and reach the implementation procedure of technique effectCan fully understand and implement according to this.
If do not specialize, the technological means adopting in embodiment is those skilled in the art instituteThe conventional means of knowing, the raw material adopting is also and can business obtains. Do not describe in detailVarious processes and method are conventional methods as known in the art.
Embodiment 1
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: nano-oxide 0.1Part; 3 parts of the sodium low polyacrylates that the amount that number all divides is 2000; 1 part of silane coupler; Two5 parts of propiophenones; 2 parts of phenyl triazines; 5 parts of sorbitan monooleate APEOs;1 part of soda ash; 2 parts of initators; 0.1 part of guanidine class antiseptic; 1 part of copper 8-quinolinolate; Water60 parts.
Embodiment 2
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: 1 part of nano-oxide;4 parts of the sodium low polyacrylates that the amount that number all divides is 3000; 2 parts of silane couplers; Two phenylpropyl alcohols8 parts of ketone; 8 parts of phenyl triazines; 10 parts of sorbitan monooleate APEOs; Pure6 parts, alkali; 3 parts of initators; 3 parts of guanidine class antiseptics; 6 parts of copper 8-quinolinolates; Water 70Part.
Embodiment 3
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: 2 parts of nano-oxides;6 parts of the sodium low polyacrylates that the amount that number all divides is 2500; 3 parts of silane couplers; Two phenylpropyl alcohols15 parts of ketone; 12 parts of phenyl triazines; 20 parts of sorbitan monooleate APEOs;8 parts of soda ash; 4 parts of initators; 5 parts of guanidine class antiseptics; 8 parts of copper 8-quinolinolates; Water80 parts.
Comparative example 1
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: nano-oxide 0.06Part; 2 parts of the sodium low polyacrylates that the amount that number all divides is 2000; 0.5 part of silane coupler;Two 4 parts of propiophenones; 1 part of phenyl triazine; 4 parts of sorbitan monooleate APEOs;0.1 part of soda ash; 1 part of initator; 0.05 part of guanidine class antiseptic; Copper 8-quinolinolate 0.6Part; 20 parts, water.
Comparative example 2
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: 3 parts of nano-oxides;8 parts of the sodium low polyacrylates that the amount that number all divides is 3000; 4 parts of silane couplers; Two phenylpropyl alcohols20 parts of ketone; 15 parts of phenyl triazines; 25 parts of sorbitan monooleate APEOs;9 parts of soda ash; 5 parts of initators; 7 parts of guanidine class antiseptics; 9 parts of copper 8-quinolinolates; Water100 parts.
Comparative example 3
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: nano-oxide 0.1Part; 3 parts of the sodium low polyacrylates that the amount that number all divides is 500; 1 part of silane coupler; Hexichol5 parts, acetone; 2 parts of phenyl triazines; 5 parts of sorbitan monooleate APEOs; Pure1 part, alkali; 2 parts of initators; 0.1 part of guanidine class antiseptic; 1 part of copper 8-quinolinolate; Water60 parts.
Comparative example 4
Antiultraviolet antibacterial finishing agent, comprises the component of following weight portion: nano-oxide 0.1Part; 3 parts of the sodium low polyacrylates that the amount that number all divides is 5000; 1 part of silane coupler; Two5 parts of propiophenones; 2 parts of phenyl triazines; 5 parts of sorbitan monooleate APEOs;1 part of soda ash; 2 parts of initators; 0.1 part of guanidine class antiseptic; 1 part of copper 8-quinolinolate; Water60 parts.
The preparation method of the antiultraviolet antibacterial finishing agent of embodiment 1～3 and comparative example 1～4, bagDraw together following steps:
Step 1: by the proportioning of claim 1 by sorbitan monooleate APEO,Soda ash, silane coupler join in reaction vessel and stir, and are heated to 58～65 DEG C;
Step 2: vessel temp is down to 55 DEG C, adding oligomeric acrylic acid in reaction vesselSodium, nano-oxide, two propiophenones, phenyl triazine, copper 8-quinolinolate, guanidine class antiseptic,Continue to stir;
Step 3: get initator and be dissolved in water, after dissolving, to entering in container, stir,Obtain mixing material;
Step 4: mixing material is cooled to room temperature, uses cutter shear treatment after being down to room temperature,Cutter rotating speed is 6000rpm, and shear time is 10min～15min, shears and finishes rear preparationObtain uvioresistant antibacterial finishing agent.
Finishing technique: fabric, by groove, is added simultaneously and contains uvioresistant at 80 DEG CThe maceration extract of antibacterial finishing agent, pads the speed of a motor vehicle and is controlled at 50 ms/min; Then fabric is existedConstant temperature 0.5 hour between 130 DEG C; Being down to and being washed to pH value with nertralizer after normal temperature is 6.8,Dry and obtain described antiultraviolet antibiotic facing material.
Performance test
Antibacterial test adopts commenting of standard GB/T/T20944.3-2008 antibacterial textile performanceValency the 3rd part: succusion is carried out antibiotic property quantitative test, and test result is in table 1;
Uvioresistant test adopts standard GB/T-T18830-2002 textile uviolresistanceThe method of testing of the evaluation of energy is measured the anti-ultraviolet property of fabric under different wash conditions, surveysTest result is in table 1.
Although embodiment of the present invention are open as above, its be not restricted to description andListed utilization in embodiment, it can be applied to various applicable the field of the invention completely,For those skilled in the art, can easily realize other amendment, therefore do not carrying on the backUnder the universal limiting from claim and equivalency range, the present invention is not limited to specificallyDetails.

Claims (6)

1. a novel antiultraviolet antibacterial finishing agent, is characterized in that, comprises following weightThe component of part:
Nano-oxide: 0.1～2 part; Sodium low polyacrylate: 3～6 parts;
Silane coupler: 1～3 part; Two propiophenones: 5～15 parts; Phenyl triazine: 2～12 parts;
Sorbitan monooleate APEO: 5～20 parts; Soda ash: 1～8 part;
Initator: 2～4 parts; Guanidine class antiseptic: 0.1～5 part;
Copper 8-quinolinolate: 1～8 part; Water: 60～80 parts.
2. antiultraviolet antibacterial finishing agent as claimed in claim 1, is characterized in that, instituteStating nano-oxide is the one in nano zine oxide, titanium dioxide, silica, magnesia.
3. antiultraviolet antibacterial finishing agent as claimed in claim 1, is characterized in that, instituteThe number-average molecular weight of stating sodium low polyacrylate is 2000～3000.
4. antiultraviolet antibacterial finishing agent as claimed in claim 1, is characterized in that, instituteState initator and be selected from one in sodium peroxydisulfate, potassium peroxydisulfate, ammonium persulfate, benzoyl peroxideKind.
5. antiultraviolet antibacterial finishing agent as claimed in claim 1, is characterized in that, instituteState guanidine class antiseptic and be selected from dodine, 1,6-bis-(4 '-chlorobenzene biguanides) hexane or poly-sixMethylene biguanide hydrochloride.
6. a preparation method for antiultraviolet antibacterial finishing agent as claimed in claim 1,It is characterized in that, comprise the steps:
Step 1: by the proportioning of claim 1 by sorbitan monooleate APEO,Soda ash, silane coupler join in reaction vessel and stir, and are heated to 58～65 DEG C;
Step 2: vessel temp is down to 55 DEG C, adding oligomeric acrylic acid in reaction vesselSodium, nano-oxide, two propiophenones, phenyl triazine, copper 8-quinolinolate, guanidine class antiseptic,Continue to stir;
Step 3: get initator and be dissolved in water, after dissolving, to entering in container, stir,Obtain mixing material;
Step 4: mixing material is cooled to room temperature, uses cutter shear treatment after being down to room temperature,Cutter rotating speed is 6000rpm, and shear time is 10min～15min, shears and finishes rear preparationObtain uvioresistant antibacterial finishing agent.
CN201610015306.3A 2016-01-08 2016-01-08 Novel anti-ultraviolet antibacterial finishing agent and preparing method thereof Pending CN105603727A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106435944A (en) * 2016-11-28 2017-02-22 江西服装学院 Novel antibacterial fabric and preparation method thereof
CN106521691A (en) * 2016-11-16 2017-03-22 揭阳市腾晟科技咨询有限公司 Polyester fiber with flame resistance and antibacterial properties, and applications thereof
CN106592233A (en) * 2016-11-28 2017-04-26 江西服装学院 Preparation process for a fiber
CN107338650A (en) * 2016-11-28 2017-11-10 江西服装学院 A kind of New Regenerated Cellulosic Fibers and preparation method thereof
CN107724083A (en) * 2017-10-09 2018-02-23 马多浩 A kind of fire-retardant anti-ultraviolet finishing agent of polyester cotton
CN109235023A (en) * 2018-08-31 2019-01-18 黄勇 A kind of preparation method of high-affinity Anti-ultraviolet true silk textile finishing agent material

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CN103938451A (en) * 2014-03-25 2014-07-23 福州大学 Fluorine-silicon-containing core-shell type fabric finishing agent and preparation method thereof
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CN102199238A (en) * 2011-04-14 2011-09-28 武汉纺织大学 Environmentally-friendly nonionic cotton fabric finishing agent and preparation method thereof
CN103469558A (en) * 2013-08-21 2013-12-25 昆山铁牛衬衫厂 Method for preparing ultraviolet-proof antibacterial finishing agent
CN103469557A (en) * 2013-08-21 2013-12-25 昆山铁牛衬衫厂 Method for finishing ultraviolet-proof antibacterial fabric
CN103469556A (en) * 2013-08-21 2013-12-25 昆山铁牛衬衫厂 Ultraviolet-proof antibacterial finishing agent
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106521691A (en) * 2016-11-16 2017-03-22 揭阳市腾晟科技咨询有限公司 Polyester fiber with flame resistance and antibacterial properties, and applications thereof
CN106435944A (en) * 2016-11-28 2017-02-22 江西服装学院 Novel antibacterial fabric and preparation method thereof
CN106592233A (en) * 2016-11-28 2017-04-26 江西服装学院 Preparation process for a fiber
CN107338650A (en) * 2016-11-28 2017-11-10 江西服装学院 A kind of New Regenerated Cellulosic Fibers and preparation method thereof
CN106435944B (en) * 2016-11-28 2018-04-03 江西服装学院 A kind of novel antibacterial fabric and preparation method thereof
CN107724083A (en) * 2017-10-09 2018-02-23 马多浩 A kind of fire-retardant anti-ultraviolet finishing agent of polyester cotton
CN109235023A (en) * 2018-08-31 2019-01-18 黄勇 A kind of preparation method of high-affinity Anti-ultraviolet true silk textile finishing agent material

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Application publication date: 20160525