CN105602404B - Concrete surface carbonization-resistant nano coating and preparation process thereof - Google Patents
Concrete surface carbonization-resistant nano coating and preparation process thereof Download PDFInfo
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- CN105602404B CN105602404B CN201610069430.8A CN201610069430A CN105602404B CN 105602404 B CN105602404 B CN 105602404B CN 201610069430 A CN201610069430 A CN 201610069430A CN 105602404 B CN105602404 B CN 105602404B
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- concrete surface
- carbonization
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- nano paint
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- 238000003763 carbonization Methods 0.000 title claims abstract description 49
- 239000002103 nanocoating Substances 0.000 title abstract 6
- 238000002360 preparation method Methods 0.000 title description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- 239000000080 wetting agent Substances 0.000 claims abstract description 10
- 229920000768 polyamine Polymers 0.000 claims abstract description 9
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000003973 paint Substances 0.000 claims description 42
- 238000011049 filling Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 2
- 239000001569 carbon dioxide Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 239000011241 protective layer Substances 0.000 abstract description 2
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an anti-carbonization nano coating for concrete surface, which comprises the following formula (in parts by weight): the component A comprises: 50-60 parts of bisphenol A type resin; 20-30 parts of a dispersing agent; 20-30 parts of nano silicon dioxide; and B component: 10-12 parts of polyamine curing agent; 25-30 parts of water; precipitating 12-15% of barium sulfate; 15-18 parts of wax powder; 18-20 parts of titanium dioxide; 2-5% of a defoaming agent; 2-5 parts of a wetting agent. Meanwhile, the invention also discloses a process for preparing the anti-carbonization nano coating on the surface of the concrete. The nano coating can be widely applied to the surfaces of concrete structures such as buildings, bridges, tunnels, dams, retaining walls and the like, a compact and hard protective layer is formed on the surface of the concrete, and the nano coating plays a good role in isolating components such as carbon dioxide, oxygen and the like in the air, so that the effect of preventing carbonization of the surface of the concrete is achieved, and meanwhile, the nano coating has good weather resistance and stain resistance.
Description
Technical field
The present invention relates to a kind of nano paint, specifically a kind of concrete carbonization preventing nano paint and its making work
Skill.
Background technology
The carbonization of concrete is a kind of chemical attack suffered by concrete.CO in air2It penetrates into concrete, with it
Carbonate and water are generated after alkaline matter chemically reactive, the process that making concrete basicity reduces is known as concrete carbonization, also known as
Make neutralisation.Concrete carbonization is concrete durability research and its important content, and domestic and foreign scholars are from different perspectives
Deep studies concrete carbonization mechanism, and the principal element for obtaining influencing concrete carbonization includes material factor, environment
Factor and construction factor.And for much built concrete structures, concrete can not be prevented in terms of material and construction
Carbonization, so it is a kind of a kind of measure of economic and practical, anti-carbonization excellent to prevent carbonization in concrete surface brushing paint.
Nanometer technology is that 20 th century laters grow up, and becomes one of three big dominant technology of 21 century.Nanoparticle
Size is 1~100nm, since nanoparticle is that nanometer scale causes it to possess many unusual physics and chemical property, is such as measured
Sub- dimensional effect, small-size effect, skin effect and macro quanta tunnel effect.
Invention content
For above-mentioned deficiency in the prior art, there is very strong adhesive force, water resistance the present invention provides a kind of
Can be strong with chemical resistance, while there is the anti-carbonization nano paint of concrete surface of splendid anti-carbonation effect.
Meanwhile the present invention also provides a kind of techniques for preparing the anti-carbonization nano paint of concrete surface.
In order to solve the above-mentioned technical problem, present invention employs following technical solutions：
A kind of anti-carbonization nano paint of concrete surface, the nano paint mainly include following formula (parts by weight)：
Component A：Bisphenol A type resin 50~60；Dispersant 20~30；Nano silicon dioxide 20~30；
B component：Polyamine curing agent 10~12；Water 25~30；Blanc fixe 12~15；Wax powder 15~18；Titanium dioxide
18~20；Antifoaming agent 2~5；Wetting agent 2~5.
As a preferred embodiment of the present invention, the dispersant is Nuo Pu sections 5027.
As another preferred embodiment of the present invention, the wax powder is BASF AF-30.
A kind of technique for preparing the anti-carbonization nano paint of above-mentioned concrete surface, the technique include the following steps：
1) it is proportionally added into bisphenol A type resin and dispersant in a kettle, 580~620 revs/min are stirred 30 minutes
Afterwards, nano silicon dioxide is proportionally added into, 780~820 revs/min are stirred 60 minutes, and component A is made；
2) the anti-carbonization nano paint component A of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
3) it is proportionally added into water, blanc fixe and titanium dioxide in a kettle, 780~820 revs/min are stirred 20 points
Clock；
4) it adds in wax powder to reaction kettle in proportion, 580~620 revs/min of stirrings, while is proportionally added into polyamine and consolidates
B component is made in agent, antifoaming agent and wetting agent；
5) the anti-carbonization nano paint B component of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
6) component A obtained and B component are pressed 1:1 is mixed and can obtain the anti-carbonization nano paint of concrete surface.
The solution have the advantages that：The nano paint can be widely applied to building construction, bridge, tunnel, water
The surface of the concrete structures such as dam, retaining wall forms one layer of densification, hard protective layer, in air in concrete surface
The ingredients such as carbon dioxide, oxygen play fine insulating effect, so as to achieve the effect that the anti-carbonization of concrete surface, while have very
Good weatherability and resistance to soiling.
Specific embodiment
A kind of anti-carbonization nano paint of concrete surface, the coating include following formula (parts by weight)：
Component A：Bisphenol A type resin 50~60；Dispersant 20~30；Nano silicon dioxide 20~30；
B component：Polyamine curing agent 10~12；Water 25~30；Blanc fixe 12~15；Wax powder 15~18；Titanium dioxide
18~20；Antifoaming agent 2~5；Wetting agent 2~5.Wherein, dispersant is Nuo Pu sections 5027；Wax powder is BASF AF-30.
Embodiment 1
A kind of technique for preparing the anti-carbonization nano paint of concrete surface, the technique include the following steps：
1) bisphenol A type resin 50Kg and dispersant 20Kg are added in a kettle, after 580 revs/min are stirred 30 minutes, are added
Enter nano silicon dioxide 20Kg, 780 revs/min are stirred 60 minutes, and component A is made；
2) the anti-carbonization nano paint component A of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
3) water 25Kg, blanc fixe 12Kg and titanium dioxide 18Kg are added in a kettle, and 780 revs/min are stirred 20 points
Clock；
4) in addition wax powder 15Kg to reaction kettle, 580 revs/min of stirrings, while add in polyamine curing agent 10Kg, defoaming
B component is made in agent 5Kg and wetting agent 5Kg；
5) the anti-carbonization nano paint B component of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
6) component A obtained and B component are pressed 1:1 is mixed and can obtain the anti-carbonization nano paint of concrete surface.
By the anti-carbonization nano paint of the concrete surface of preparation for concrete surface, experiment test index：
| Project | Parameter | Standard |
| 28d carbonation depths, mm | <1 | GB/T 50082-2009 |
| Hubbing adhesive force is tested, MPa | 1 grade | GB/T 5210-2006 |
| Pencil hardness | 6H is not scratched | GB/T 6739-2006 |
| Water resistance (leaching 31 days) | It is unchanged | GB/T 1733-1993 |
| Alkali resistance (saturation Ca (OH) 10 days) | It is unchanged | GB/T 9274-1988 |
| Acid resistance ((0.1mol/L) HCI4 days) | It is unchanged | GB/T 9274-1988 |
Embodiment 2
A kind of technique for preparing the anti-carbonization nano paint of concrete surface, the technique include the following steps：
1) bisphenol A type resin 54Kg and dispersant 24Kg are added in a kettle, after 590 revs/min are stirred 30 minutes, are added
Enter nano silicon dioxide 24Kg, 790 revs/min are stirred 60 minutes, and component A is made；
2) the anti-carbonization nano paint component A of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
3) water 27Kg, blanc fixe 13Kg and titanium dioxide 19Kg are added in a kettle, and 790 revs/min are stirred 20 points
Clock；
4) in addition wax powder 18Kg to reaction kettle, 590 revs/min of stirrings, while add in polyamine curing agent 12Kg, defoaming
B component is made in agent 5Kg and wetting agent 5Kg；
5) the anti-carbonization nano paint B component of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
6) component A obtained and B component are pressed 1:1 is mixed and can obtain the anti-carbonization nano paint of concrete surface.
By the anti-carbonization nano paint of the concrete surface of preparation for concrete surface, experiment test index：
| Project | Parameter | Standard |
| 28d carbonation depths, mm | <1 | GB/T 50082-2009 |
| Hubbing adhesive force is tested, MPa | 1 grade | GB/T 5210-2006 |
| Pencil hardness | 6H is not scratched | GB/T 6739-2006 |
| Water resistance (leaching 32 days) | It is unchanged | GB/T 1733-1993 |
| Alkali resistance (saturation Ca (OH) 11 days) | It is unchanged | GB/T 9274-1988 |
| Acid resistance ((0.1mol/L) HCI5 days) | It is unchanged | GB/T 9274-1988 |
Embodiment 3
A kind of technique for preparing the anti-carbonization nano paint of concrete surface, the technique include the following steps：
1) bisphenol A type resin 60Kg and dispersant 30Kg are added in a kettle, after 600 revs/min are stirred 30 minutes, are added
Enter nano silicon dioxide 20Kg, 800 revs/min are stirred 60 minutes, and component A is made；
2) the anti-carbonization nano paint component A of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
3) water 30Kg, blanc fixe 15Kg and titanium dioxide 20Kg are added in a kettle, and 800 revs/min are stirred 20 points
Clock；
4) in addition wax powder 18Kg to reaction kettle, 600 revs/min of stirrings, while add in polyamine curing agent 12Kg, defoaming
B component is made in agent 2Kg and wetting agent 2Kg；
5) the anti-carbonization nano paint B component of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
6) component A obtained and B component are pressed 1:1 is mixed and can obtain the anti-carbonization nano paint of concrete surface.
By the anti-carbonization nano paint of the concrete surface of preparation for concrete surface, experiment test index：
| Project | Parameter | Standard |
| 28d carbonation depths, mm | <1 | GB/T 50082-2009 |
| Hubbing adhesive force is tested, MPa | 1 grade | GB/T 5210-2006 |
| Pencil hardness | 6H is not scratched | GB/T 6739-2006 |
| Water resistance (leaching 34 days) | It is unchanged | GB/T 1733-1993 |
| Alkali resistance (saturation Ca (OH) 13 days) | It is unchanged | GB/T 9274-1988 |
| Acid resistance ((0.1mol/L) HCI6 days) | It is unchanged | GB/T 9274-1988 |
Embodiment 4
A kind of technique for preparing the anti-carbonization nano paint of concrete surface, the technique include the following steps：
1) bisphenol A type resin 50Kg and dispersant 20Kg are added in a kettle, after 620 revs/min are stirred 30 minutes, are added
Enter nano silicon dioxide 30Kg, 820 revs/min are stirred 60 minutes, and component A is made；
2) the anti-carbonization nano paint component A of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
3) water 29Kg, blanc fixe 15Kg and titanium dioxide 19Kg are added in a kettle, and 820 revs/min are stirred 20 points
Clock；
4) in addition wax powder 17Kg to reaction kettle, 620 revs/min of stirrings, while add in polyamine curing agent 11Kg, defoaming
B component is made in agent 5Kg and wetting agent 5Kg；
5) the anti-carbonization nano paint B component of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
6) component A obtained and B component are pressed 1:1 is mixed and can obtain the anti-carbonization nano paint of concrete surface.
By the anti-carbonization nano paint of the concrete surface of preparation for concrete surface, experiment test index：
| Project | Parameter | Standard |
| 28d carbonation depths, mm | <1 | GB/T 50082-2009 |
| Hubbing adhesive force is tested, MPa | 1 grade | GB/T 5210-2006 |
| Pencil hardness | 6H is not scratched | GB/T 6739-2006 |
| Water resistance (leaching 31 days) | It is unchanged | GB/T 1733-1993 |
| Alkali resistance (saturation Ca (OH) 10 days) | It is unchanged | GB/T 9274-1988 |
| Acid resistance ((0.1mol/L) HCI1 days) | It is unchanged | GB/T 9274-1988 |
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, it can be to the skill of the present invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this
In the right of invention.
Claims (4)
1. a kind of anti-carbonization nano paint of concrete surface, which is characterized in that the nano paint mainly includes following formula (weight
Part)：
Component A：Bisphenol A type resin 50~60；Dispersant 20~30；Nano silicon dioxide 20~30；
B component：Polyamine curing agent 11~12；Water 27~30；Blanc fixe 13~15；Wax powder 17~18；Titanium dioxide 19~
20；Antifoaming agent 2~5；Wetting agent 2~5.
2. the anti-carbonization nano paint of a kind of concrete surface according to claim 1, which is characterized in that the dispersant is
Nuo Puke 5027.
3. the anti-carbonization nano paint of a kind of concrete surface according to claim 1, which is characterized in that the wax powder is bar
This husband AF-30.
4. a kind of work of the anti-carbonization nano paint of concrete surface prepared described in any one of claims 1 to 3 claim
Skill, which is characterized in that the technique includes the following steps：
1) it is proportionally added into bisphenol A type resin and dispersant in a kettle, after 580~620 revs/min are stirred 30 minutes, presses
Ratio adds in nano silicon dioxide, and 780~820 revs/min are stirred 60 minutes, and component A is made；
2) the anti-carbonization nano paint component A of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
3) it is proportionally added into water, blanc fixe and titanium dioxide in a kettle, 780~820 revs/min are stirred 20 minutes；
4) it adds in wax powder to reaction kettle in proportion, 580~620 revs/min of stirrings, while is proportionally added into polynary amine curing
B component is made in agent, antifoaming agent and wetting agent；
5) the anti-carbonization nano paint B component of filling concrete surface is sealed, it is necessary to it is filling that sealing was completed in 1 hour；
6) component A obtained and B component are pressed 1:1 is mixed and can obtain the anti-carbonization nano paint of concrete surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610069430.8A CN105602404B (en) | 2016-02-01 | 2016-02-01 | Concrete surface carbonization-resistant nano coating and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610069430.8A CN105602404B (en) | 2016-02-01 | 2016-02-01 | Concrete surface carbonization-resistant nano coating and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105602404A CN105602404A (en) | 2016-05-25 |
| CN105602404B true CN105602404B (en) | 2018-06-29 |
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| CN201610069430.8A Expired - Fee Related CN105602404B (en) | 2016-02-01 | 2016-02-01 | Concrete surface carbonization-resistant nano coating and preparation process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107011706B (en) * | 2017-04-13 | 2019-02-05 | 江苏大使同丰涂料有限公司 | A kind of anti-concrete neutralisation coating and its application method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1766019A (en) * | 2005-09-22 | 2006-05-03 | 长江水利委员会长江科学院 | Nano composite aqueous epoxide resin coating material and preparation method |
| CN101392142A (en) * | 2008-11-06 | 2009-03-25 | 同济大学 | Method for preparing environment-friendly type anti-corrosive and anti-fingerprint metal surface coating |
| CN102786280A (en) * | 2011-05-16 | 2012-11-21 | 秦明 | Novel concrete carbonization prevention coating material |
| CN103232267A (en) * | 2013-05-14 | 2013-08-07 | 中交第一公路勘察设计研究院有限公司 | Environment-friendly nanoscale bottom infiltrated layer material used for protecting concrete surface and preparation method of environment-friendly nanoscale bottom infiltrated layer material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100989942B1 (en) * | 2010-04-29 | 2010-10-26 | 태산엔지니어링 주식회사 | Eco-friendly aqueous epoxy resin composition and its uses |
-
2016
- 2016-02-01 CN CN201610069430.8A patent/CN105602404B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1766019A (en) * | 2005-09-22 | 2006-05-03 | 长江水利委员会长江科学院 | Nano composite aqueous epoxide resin coating material and preparation method |
| CN101392142A (en) * | 2008-11-06 | 2009-03-25 | 同济大学 | Method for preparing environment-friendly type anti-corrosive and anti-fingerprint metal surface coating |
| CN102786280A (en) * | 2011-05-16 | 2012-11-21 | 秦明 | Novel concrete carbonization prevention coating material |
| CN103232267A (en) * | 2013-05-14 | 2013-08-07 | 中交第一公路勘察设计研究院有限公司 | Environment-friendly nanoscale bottom infiltrated layer material used for protecting concrete surface and preparation method of environment-friendly nanoscale bottom infiltrated layer material |
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| CN105602404A (en) | 2016-05-25 |
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