CN105602236B - 新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体 - Google Patents

新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体 Download PDF

Info

Publication number
CN105602236B
CN105602236B CN201610146079.8A CN201610146079A CN105602236B CN 105602236 B CN105602236 B CN 105602236B CN 201610146079 A CN201610146079 A CN 201610146079A CN 105602236 B CN105602236 B CN 105602236B
Authority
CN
China
Prior art keywords
parts
pvc
tpu
retardant
plasticizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610146079.8A
Other languages
English (en)
Other versions
CN105602236A (zh
Inventor
邓之俊
唐铮
戴红兵
陈敏
张丽本
王兴宁
顾金云
栾珊珊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU DEWEI ADVANCED MATERIALS CO Ltd
Original Assignee
JIANGSU DEWEI ADVANCED MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU DEWEI ADVANCED MATERIALS CO Ltd filed Critical JIANGSU DEWEI ADVANCED MATERIALS CO Ltd
Priority to CN201610146079.8A priority Critical patent/CN105602236B/zh
Publication of CN105602236A publication Critical patent/CN105602236A/zh
Application granted granted Critical
Publication of CN105602236B publication Critical patent/CN105602236B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58—Component parts, details or accessories; Auxiliary operations
    • B29B7/72—Measuring, controlling or regulating
    • B29B7/726—Measuring properties of mixture, e.g. temperature or density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/302—Polyurethanes or polythiourethanes; Polyurea or polythiourea
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92904—Die; Nozzle zone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92952—Drive section, e.g. gearbox, motor or drive fluids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明涉及一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：它是由PVC阻燃母粒和改性TPU混合造粒而成，所述PVC阻燃母粒和所述改性TPU的质量比为1：1~3：7；所述PVC母粒的原料配方包括下列重量份数的组分：聚氯乙烯树脂100份；增塑剂70~85份；稳定剂3~6份；润滑剂5~10份；无机填料150~250份；阻燃剂150~250份；抗氧剂3~7份；所述增塑剂由低粘度聚酯增塑剂和超耐寒固体增塑剂按15：1~11：3的质量比组成。这样的电缆料具有良好的大截面挤出性能，表面光滑无颗粒，良好的耐磨耐油阻燃性能在户外的恶劣环境中长期运行而不出现故障。

Description

新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体
技术领域
本发明属于电缆线材料领域，涉及一种热塑性弹性体，具体涉及一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料。
背景技术
面对全球日益严重的环境危机及能源枯竭，特别是目前国内能源分布不均且日益枯竭、雾霾天气日益严重，大力发展新能源已提升至全球各国战略位置。根据美国能源信息署EIA发布的国际能源展望，世界能源市场消耗量2005年到2030年预计增加50％。随着能源消耗的逐年增加，二氧化碳的排放量也将增加，目前二氧化碳排放中，25％来自于汽车。至2030年，将由2005年的281亿吨增至423亿吨。在我国，汽车排放的污染已经成为城市大气污染的重要因素，我国的二氧化碳排放目前已居全球第二，减排二氧化碳的压力将越来越大。
新能源电动汽车与传统汽车相比，具有运行平稳、无噪声、无污染、低碳排放、高安全等特性，而具有广阔的市场应用前景，已列入《国家中长期科学和技术发展规划纲要》和《国家“十二五”科学和技术发展规划》，随着电动汽车的大范围推广及产业化应用，电动汽车充电桩电缆需求量也随之倍增。由于充电桩用电缆负荷电流值较大(最大约达400A)，电缆通电运行中导体易发热，以及在使用过程中频繁拖拽移动，长期暴露于室外环境，易受汽车碾压、日光照射、空气氧化、湿水环境以及酸碱化合物等因数的破坏腐蚀，因此，需对充电桩用电缆的性能指标提出了更高的要求。
现有技术中，新能源汽车充电桩电缆用材料多为TPE材料，TPU由于其高昂的价格使其优异的性能受到一定的限制性使用，而TPE虽具有一定的耐磨性能，但是其耐油性能却难以合格。越来越多的新能源充电桩厂家希望取得一种即具有良好的耐磨阻燃性能，又能满足良好的耐油性能，且性价比优异的新能源材料。
发明内容
本发明目的是为了克服现有技术的不足而提供一种高性价比新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，结合了PVC和TPU的综合优异性能。
为达到上述目的，本发明所采用的技术方案为：一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：它是由PVC阻燃母粒和改性TPU混合造粒而成，所述PVC阻燃母粒和所述改性TPU的质量比为1：1～3：7；所述PVC母粒的原料配方包括下列重量份数的组分：
聚氯乙烯树脂 100份；
增塑剂 70～85份；
稳定剂 3～6份；
润滑剂 5～10份；
无机填料 150～250份；
阻燃剂 150～250份；
抗氧剂 3～7份；
所述增塑剂由低粘度聚酯增塑剂和超耐寒固体增塑剂按15：1～11：3的质量比组成。
优化地，所述改性TPU由以下步骤制得：将TPU加入由硅烷偶联剂和钛酸酯偶联剂中的一种和无水乙醇组成的混合溶液中，浸渍5～15分钟后真空抽干即可，所述硅烷偶联剂或钛酸酯偶联剂与所述无水乙醇的体积比为1～2：1。
优化地，所选阻燃剂为氧化锑、十溴二苯乙烷和氢氧化镁种的一种或多种组成的混合物。
优化地，所述改性TPU的邵氏硬度分别为75～90A。
优化地，所述PVC阻燃母粒和所述改性TPU的质量比为1：2；所述PVC母粒的原料配方包括下列重量份数的组分：
聚氯乙烯树脂 100份；
增塑剂 85份，其中低粘度聚酯增塑剂 70份，超耐寒固体增塑剂 15份；
稳定剂 5份；
润滑剂 6份；
无机填料 150份；
阻燃剂 150份，其中氧化锑 50份，氢氧化镁 100份；
抗氧剂 7份。
本发明中低粘度聚酯增塑剂采用常规的那些即可，如己二酸类聚酯，具体为W-1550、W-1750、W8000、W2050等；超耐寒固体增塑剂采用常规的那些即可，如杜邦的HP441、HP731、HP751等；稳定剂采用常规的那些即可，如RUP151NB、RUP144等；润滑剂采用硬脂酸和硬脂酸钙，以及聚乙烯蜡、半精炼石蜡、ACR401、M-80、316A中的任意两种，按照一定质量比混合而成；无机填料为超微细碳酸钙，其目数为2500～3000目；抗氧剂采用常规的那些即可，如抗氧剂1010、抗氧剂DLTP和抗氧剂DSTP中的一种或多种组成的混合物。
优化地，它的制备方法包括以下步骤：
(a)称取配方量的PVC树脂粉、稳定剂和增塑剂加入高速混合机中，在70～80℃、450～700转/分钟的条件下混合3～5分钟，再加入配方量的润滑剂、抗氧化剂、无机填料和阻燃剂，在100～120℃、550～700转/分钟的条件下混合5～15分钟得第一混合物料；
(b)将所述第一混合物料投入双辊混炼机混炼，再进入双螺杆挤出机进行挤出造粒，即得PVC阻燃母粒；所述双辊混炼机的机身各段温度依次为：120℃～130℃、130℃～140℃、140℃～150℃、150℃～160℃、160℃～165℃、165℃～175℃，双螺杆挤出机的机头温度为175℃～180℃，主机转速为30～40转/分钟，喂料转速为40～45转/分钟；
(c)将PVC阻燃母粒和改性TPU按配方比例再依次投入双辊混炼机、双螺杆挤出机中挤出造粒，双辊混炼机的机身温度为110℃～170℃，机头温度130℃～140℃；双螺杆挤出机主机转速为40～45转/分，喂料转速为55～60转/分。
由于上述技术方案运用，本发明与现有技术相比具有下列优点：本发明新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，采用特定配方的PVC阻燃母粒和改性TPU的按质量比为1：1～3：7进行混合，这样的电缆料具有良好的大截面挤出性能，表面光滑无颗粒，良好的耐磨耐油阻燃性能在户外的恶劣环境中长期运行而不出现故障；并结合了PVC和TPU的优异性能：具有高机械性能、耐水解性能、耐油耐寒性、分散均匀性，保证电缆在多次拖链中不会受损。
具体实施方式
下面对本发明优选实施方案进行详细说明。
实施例1
本实施例提供一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其原料配方如表1和表2所示，使用的原料具体为：
聚氯乙烯(PVC)树脂：聚合度为800、1300和聚合度为2500的树脂粉按重量比1：2：7组成的混合物；
增塑剂：低粘度聚酯增塑剂和超耐寒固体增塑剂按重量比11：3组成的混合物；
稳定剂：钙锌复合稳定剂(RUP151NB)；
润滑剂：硬脂酸、硬脂酸钙、聚乙烯蜡、半精炼石蜡按重量比1：2：1.2：1.5组成的混合物；
无机填料：超微细碳酸钙150份(3000目)；
阻燃剂：氧化锑；
抗氧剂：抗氧剂1010；
其制备方法包括以下步骤：
(a)按照表1中的重量份数称取PVC树脂粉(PVC-800、PVC-1300和SH-200)，钙锌复合稳定剂RUP151NB、增塑剂加入高速混合机中，在70℃、450转/分钟的条件下混合5分钟，再加入配方量的润滑剂、抗氧化剂、无机填料和阻燃剂，在120℃、600转/分钟的条件下混合5分钟得第一混合物料；
(b)将所述第一混合物料投入双辊混炼机混炼，再进入双螺杆挤出机进行挤出造粒，即得PVC阻燃母粒；双辊混炼机的机身各段温度依次为：120℃、130℃、140℃、150℃、160℃、165℃，双螺杆挤出机的机头温度为175℃，主机转速为30转/分钟，喂料转速为40转/分钟；
(c)将PVC阻燃母粒和改性TPU按配方比例投入双辊混炼机中挤出造粒，双辊混炼机机身各段温度依次为：120℃、130℃、140℃、150℃、160℃、165℃；双螺杆挤出机的机头温度130℃,主机转速为40转/分，喂料转速为55转/分。
实施例2
本实施例提供一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其原料配方如表1和表2所示，使用的原料具体为：
聚氯乙烯(PVC)树脂：聚合度为800和聚合度为2500的树脂粉按重量比1：5组成的混合物；
增塑剂：低粘度聚酯增塑剂和超耐寒固体增塑剂按重量比6：1组成的混合物；
稳定剂：钙锌复合稳定剂(RUP144)
润滑剂：硬脂酸、硬脂酸钙、聚乙烯蜡、ACR401按重量比1：2：:1.2：1.5组成的混合物；
无机填料：超微细碳酸钙150份(2500目)；
阻燃剂：氧化锑与十溴二苯乙烷按比例1：2组成的混合物：
抗氧剂：抗氧剂DLTP
其制备方法与实施例1中的基本一致。
实施例3
本实施例提供一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其原料配方如表1和表2所示，使用的原料具体为：
聚氯乙烯(PVC)树脂：聚合度为800、1300和聚合度为3000的树脂粉按重量比1：2：7组成的混合物；
增塑剂：低粘度聚酯增塑剂和超耐寒固体增塑剂按重量比15：1组成的混合物；
稳定剂：钙锌复合稳定剂(RUP144)；
润滑剂：硬脂酸、硬脂酸钡、M-80、半精炼石蜡按重量比1：2：1.4：1.5混合物；
无机填料：超微细碳酸钙150份(3000目)；
阻燃剂：十溴二苯乙烷和氢氧化镁按重量比1：2组成的混合物；
抗氧剂：抗氧剂1010和抗氧剂DLTP按质量比1：1混合；
其制备方法与实施例1中的基本一致。
实施例4
本实施例提供一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其原料配方如表1和表2所示，使用的原料具体为：
聚氯乙烯(PVC)树脂：聚合度为800、1300和聚合度为3000的树脂粉按重量比2：4：4组成的混合物；
增塑剂：低粘度聚酯增塑剂和超耐寒固体增塑剂按重量比14：3组成的混合物；
稳定剂：钙锌复合稳定剂(RUP151NB)；
润滑剂：硬脂酸、硬脂酸钡、M-80、316A按重量比2：1：0.5：1组成的混合物；
无机填料：超微细碳酸钙150(2500目)；
阻燃剂：氧化锑和氢氧化镁按重量比1：2组成的混合物；
抗氧剂：抗氧剂DSTP和抗氧剂1010按质量比1：1混合；
其制备方法与实施例1中的基本一致。
表1为实施例1至实施例4的PVC母粒的原料配方(单位：重量份)
表2为实施例1至实施例4中PVC母粒和TPU母粒的混合配方(单位：重量比)
对实施例1至4所得的高性价比新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料的机械性能进行测试，结果见表3。
表3实施例1至4中塑性弹性体材料的机械物理性能及电性能指标
根据表3结果可知，本发明所制备的种高性价比新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，强度，伸率和耐油，耐水解等众多性能优异，氧指数高，加工性能，抗冲击性能优良，满足新能源充电桩电缆的应用要求，目前已为多家客户提供稳定的供货，具有良好的高性价比和社会效益。尤其是，实施例4中制得的热塑性弹性体材料具有最优的耐碱、耐酸、耐油、耐水解、抗撕特性，产生了意想不到的效果。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。

Claims (6)

1.一种新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：它是由PVC阻燃母粒和改性TPU混合造粒而成，所述PVC阻燃母粒和所述改性TPU的质量比为1：1~3：7；所述PVC母粒的原料配方包括下列重量份数的组分：
聚氯乙烯树脂100份；
增塑剂70~85份；
稳定剂3~6份；
润滑剂5~10份；
无机填料150~250份；
阻燃剂150~250份；
抗氧剂3~7份；
所述增塑剂由低粘度聚酯增塑剂和超耐寒固体增塑剂按15：1~11：3的质量比组成。
2.根据权利要求1所述的新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于，所述改性TPU由以下步骤制得：将TPU加入由硅烷偶联剂和钛酸酯偶联剂中的一种和无水乙醇组成的混合溶液中，浸渍5~15分钟后真空抽干即可，所述硅烷偶联剂或钛酸酯偶联剂与所述无水乙醇的体积比为1~2：1。
3.根据权利要求1所述的新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：所选阻燃剂为氧化锑、十溴二苯乙烷和氢氧化镁种的一种或多种组成的混合物。
4.根据权利要求1所述的新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：所述改性TPU的邵氏硬度分别为75~90A。
5.根据权利要求1所述的新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：所述PVC阻燃母粒和所述改性TPU的质量比为1：2；所述PVC母粒的原料配方包括下列重量份数的组分：
聚氯乙烯树脂100份；
增塑剂85份，其中低粘度聚酯增塑剂70份，超耐寒固体增塑剂15份；
稳定剂5份；
润滑剂6份；
无机填料150份；
阻燃剂150份，其中氧化锑50份，氢氧化镁100份；
抗氧剂7份。
6.权利要求1至5中任一所述新能源汽车充电桩电缆用PVC/TPU耐油阻燃热塑性弹性体材料，其特征在于：它的制备方法包括以下步骤：
（a）称取配方量的PVC树脂粉、稳定剂和增塑剂加入高速混合机中，在70~80℃、450~700转/分钟的条件下混合3~5分钟，再加入配方量的润滑剂、抗氧化剂、无机填料和阻燃剂，在100~120℃、550~700转/分钟的条件下混合5~15分钟得第一混合物料；
（b）将所述第一混合物料投入双辊混炼机混炼，再进入双螺杆挤出机进行挤出造粒，即得PVC阻燃母粒；所述双辊混炼机的机身各段温度依次为：120℃~130℃、130℃~140℃、140℃~150℃、150℃~160℃、160℃~165℃、165℃~175℃，双螺杆挤出机的机头温度为175℃~180℃，主机转速为30~40转/分钟，喂料转速为40~45转/分钟；
（c）将PVC阻燃母粒和改性TPU按配方比例再依次投入双辊混炼机、双螺杆挤出机中挤出造粒，双辊混炼机的机身温度为110℃~170℃，机头温度130℃~140℃；双螺杆挤出机主机转速为40~45转/分，喂料转速为55~60转/分。
CN201610146079.8A 2016-03-15 2016-03-15 新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体 Active CN105602236B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610146079.8A CN105602236B (zh) 2016-03-15 2016-03-15 新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610146079.8A CN105602236B (zh) 2016-03-15 2016-03-15 新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体

Publications (2)

Publication Number Publication Date
CN105602236A CN105602236A (zh) 2016-05-25
CN105602236B true CN105602236B (zh) 2018-06-19

Family

ID=55982612

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610146079.8A Active CN105602236B (zh) 2016-03-15 2016-03-15 新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体

Country Status (1)

Country Link
CN (1) CN105602236B (zh)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108070175A (zh) * 2016-11-11 2018-05-25 深圳市帝源新材料科技股份有限公司 电缆复合材料及其制造方法、充电电缆和充电桩
CN107286524A (zh) * 2017-08-01 2017-10-24 深圳市海特高分子材料有限公司 电动汽车充电桩电缆用pvc电缆料及其制备方法
CN107266829A (zh) * 2017-08-04 2017-10-20 苏州亨利通信材料有限公司 一种充电桩电缆用聚氯乙烯弹性体电缆料及其制备方法
CN107556645B (zh) * 2017-08-15 2020-12-08 东莞海铂新材料科技有限公司 一种用于充电桩电缆的弹性体绝缘包覆材料及其制备方法
CN110746714A (zh) * 2018-07-24 2020-02-04 广东领航新材料有限公司 Pvc改性拖链料及其制作方法
CN109473219A (zh) * 2018-09-03 2019-03-15 航天瑞奇电缆有限公司 超柔耐高温改性聚氯乙烯阻燃环保道路车辆用高压电缆及制备方法
CN111849189A (zh) * 2020-06-22 2020-10-30 安徽滁州德威新材料有限公司 一种防水卷材颗粒及其制备方法和应用
CN111995826B (zh) * 2020-08-13 2021-04-30 安徽滁州德威新材料有限公司 一种耐油耐高温阻燃pvc组合物及其制备方法和应用
CN115678183B (zh) * 2022-11-08 2023-11-24 无锡洪汇新材料科技股份有限公司 一种充电桩电缆用环保阻燃高强度复合材料及其制备方法
CN117924855B (zh) * 2024-03-25 2024-06-28 广州领音航复合材料有限公司 一种用于汽车的透气型遮黑膜及其制备方法

Also Published As

Publication number Publication date
CN105602236A (zh) 2016-05-25

Similar Documents

Publication Publication Date Title
CN105602236B (zh) 新能源汽车充电桩电缆用pvc/tpu耐油阻燃热塑性弹性体
CN102492191B (zh) 环保型耐高低温耐油耐磨阻燃橡塑组合物
CN102964724B (zh) 一种汽车用薄壁绝缘电线料及其制备方法
CN101857707B (zh) Pvc/abs塑料合金材料及其制备方法
CN101864141B (zh) 一种改性的abs抗静电材料及其制备方法
CN102911462B (zh) 一种废旧pvc和粉煤灰复合材料及其制备方法
CN110669259B (zh) 一种高效阻燃抑烟环保双功能助剂及由其制备的pvc-u材料
CN101768313A (zh) 一种透明阻燃聚氯乙烯组合物及其制备方法
CN101280097A (zh) 纳米阻燃聚对苯二甲酸乙二醇酯工程塑料及其制备方法
CN103819866B (zh) 一种高性能永久抗静电阻燃abs材料及制备方法和应用
CN103087380B (zh) 微胶囊化红磷阻燃的抗静电聚乙烯管材组合物
CN110591335B (zh) 一种高阻燃低烟气毒性耐候电缆护套料及其制备方法
CN104004224A (zh) 一种稀土配合物橡胶防老剂及其制备方法与应用
CN102002199A (zh) 90℃高阻燃聚乙烯护套料
CN104341709A (zh) 乌钢炭改性聚甲醛/聚氨酯合金海洋电缆护套料及其生产方法
CN108727697A (zh) 一种高流动性阻燃母料
CN111674130A (zh) 一种煤矿井下用pvc防静电增韧改性材料及其制备方法
CN105647100B (zh) 一种高黑高亮abs阻燃色母粒及其制备方法和应用方法
CN109096608B (zh) 一种抗菌耐粉尘吸附免喷涂pp材料及其制备方法
CN106497117A (zh) 一种环保阻燃木塑地板及其制备方法
CN102775681B (zh) 高温耐析出无卤阻燃聚丙烯组合物及其制备方法
CN107201049A (zh) 一种木塑复合材料
CN109651733B (zh) 阻燃、抗冲击印刷基膜的制备方法
CN110591336B (zh) 一种热塑性聚氨酯改性专用阻燃增效功能母粒及其制备方法
CN107236217A (zh) 一种高阻燃高耐候电缆料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PP01 Preservation of patent right

Effective date of registration: 20210122

Granted publication date: 20180619

PP01 Preservation of patent right
PD01 Discharge of preservation of patent

Date of cancellation: 20240122

Granted publication date: 20180619

PD01 Discharge of preservation of patent