CN105600940A - Preparation method and preparation device for self-collapsible type long-acting and sustained release water quality purifying filler brick - Google Patents
Preparation method and preparation device for self-collapsible type long-acting and sustained release water quality purifying filler brick Download PDFInfo
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- CN105600940A CN105600940A CN201610155185.2A CN201610155185A CN105600940A CN 105600940 A CN105600940 A CN 105600940A CN 201610155185 A CN201610155185 A CN 201610155185A CN 105600940 A CN105600940 A CN 105600940A
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- water quality
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- mold
- defeated
- filler brick
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
Abstract
The invention relates to a preparation device for a self-collapsible type long-acting and sustained release water quality purifying filler brick. The preparation device for the self-collapsible type long-acting and sustained release water quality purifying filler brick comprises a blank forming mould and a vibrating table, wherein the blank forming mould comprises an outer mould, core rods and a mould base, the outer mould is a hollow circular tube with the two ends open, five core rods are vertically arranged on the mould base, a limit slot is formed in the mould base, and the outer mould is connected with the mould base by virtue of the limit slot; and the vibrating table comprises a vibrating plate, supporting springs, a vibrating motor and a vibrating table support, wherein the vibrating motor is arranged below the vibrating plate, and the vibrating plate is connected with the vibrating table support by virtue of a plurality of supporting springs. The self-collapsible type long-acting and sustained release water quality purifying filler brick has the advantages that the self-collapsible type long-acting and sustained release water quality purifying filler brick can be slowly collapsed in water, the doped medicament is slowly released, and the self-collapsible type long-acting and sustained release water quality purifying filler brick is applicable to short-term emergency treatment of relatively seriously polluted water.
Description
Technical field
The present invention relates to a kind of preparation method and preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick, belong to environment-friendly materials technical field.
Background technology
Along with the further raising of the industrialized develop rapidly of China and intensive agriculture degree, the trade effluent producing, rural sewage and sanitary sewage have caused serious destruction to water environment. A large amount of unprocessed or process incomplete sewage and directly enter in the water body such as river, lake, cause comprehensive deterioration of rivers and lakes water quality. Meanwhile, in rural area, the excessive uses of agriculture input such as chemical fertilizer, agricultural chemicals, the unreasonable disposal of agricultural wastes such as feces of livestock and poultry, agricultural crop straw and farmland incomplete film, cause widespread pollution from the overuse of fertilizers and pesticides in rural area day by day serious, have aggravated soil and water pollution risk. China Large Or Medium Type Irrigation Areas is due to extensive farming mode, and applying quantity of chemical fertilizer is high, and livestock and poultry cultivation is intensive, and widespread pollution from the overuse of fertilizers and pesticides in rural area is even more serious, and in escape canal, nitrogen phosphorus and pesticide concentration are higher, after outer row, affects River water quality. In city, what the industrial wastewater of a large amount of discharges and sanitary sewage were serious affects river water environmental also and then the health of harm humans, along with the continuous propelling of modernization construction process, building the harmonious water environment of people's water becomes an Important Action that strengthens Urban Competitiveness, promotes city taste, sustainable economic development. Environmental pollution improvement also becomes modern society and faces one of major issue with urgently to be resolved hurrily.
The riverway water quality purification method using at city and country at present has more multiple, wherein building artificial swamp and ecological revetment is to use wider technology, utilize sewage after contacting with plant medium biomembrane, the maintenance of plant self function, the resource of fully purifying waste water, has the function of sewage disposal and landscape concurrently. But because this class biological purification method engineering construction cycle is long, investment is large, and onset is slow, for seriously polluted, burst Pollution thing exceeds standard, local should acute water environment treatment etc. occasion be not suitable for adopting said method. The traditional chemical reagent directly method of throwing in can reduce the water pollutant content in a certain region fast, be widely used in sewage treatment area, but because drug effect has just discharged in several hours, process range is limited, particularly for continuing moving water condition in river course, the medicine of throwing in cannot continue to play a role owing to discharging too fast, has brought difficulty to the environmental improvement of this class occasion. Therefore be badly in need of at present one can fast reducing water body in pollutant levels, can within one period, keep again the spacetabs type water quality purification material of stable purification efficiency, to expanding water environment treatment method, improve water environment processing horizontal and there is positive meaning simultaneously.
Summary of the invention
The present invention proposes a kind of preparation method and preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick, prepared filler brick can be slowly defeated and dispersed in water, the water quality treating chemicals of doping in brick is evenly slowly discharged in water body, thereby reach the effect of water body being carried out to long-acting stable purification. The advantages such as the present invention has that medicament rate of release is stable, long action time, production cost are low, are applicable to various water conditions, can carry out large-scale production.
Technical solution of the present invention: from the preparation facilities of defeated and dispersed type long-acting slow-release purification of water quality filler brick, its structure comprises blanking mold and shake table; Wherein blanking mold comprises external mold, plug and mold base, the hollow circular-tube that described external mold is both ends open, and 5 plug at right angle settings, on mold base, offer stopper slot on mold base, and external mold is connected with mold base by stopper slot; Described shake table involving vibrations plate, support spring, vibrating motor and shake table support, wherein vibrating motor is installed on oscillating plate below, and oscillating plate is connected with shake table support by some support springs.
From the preparation method of defeated and dispersed type long-acting slow-release purification of water quality filler brick, comprise the following steps:
(1) stalk that is 1cm ~ 3cm by strain footpath carries out nature or artificial processed, after removal lateral lobe, puts into pulverizer, is ground into the particle that length is 1 ~ 1.5cm;
(2) stalk particle crushing is put into the water glass solution that modulus is 3.0, Baume degrees is 50.0 and soaked 30 minutes, take out natural drying 24 hours;
(3) choose applicable solid state chemistry reagent treatment, drying for standby according to the kind of pollutant in staying water;
(4) by stalk particle, sawdust, cement, flyash, river sand, carboxymethyl cellulose, NaHCO3, citric acid, chemical treatment reagent drop in mixer and be dry mixed 5 minutes according to the mass ratio of 50:20:80:50:100:1:3:1:5;
(5) dry mash stirring, water, vegetalitas blowing agent are dropped into the processing of foaming in cement foam maker according to: the mass ratio of 80:120:15, then pour in blanking mold, elemental height is mold height 3/4;
(6) mould is positioned on shake table and vibrates 5 ~ 10 seconds, after filling evenly in mould, leave standstill 30 minutes until slurry;
The present invention has following beneficial effect:
1) prepared filler brick has porous, expanded structure, structural strength is low, the sawdust comprising and stalk particle can be removed by dilation and erosion in water, impel matrix material to occur slowly defeated and dispersed, thereby the water treatment reagent adulterating in material is discharged slowly in water, improve the effective acting time to water body of filler brick, not only rapid-action to reducing water pollution substrate concentration, and can keep before the deadline stable purification efficiency;
2) the sawdust water-swellable adulterating in material and be corroded after can make filler brick surface occur successively to come off, stalk particle soaks after dilation and erosion is removed and can make material be bulk to peel off in water, by adjusting the additional proportion of sawdust and stalk particle, the defeated and dispersed speed in water of capable of regulating filler brick and complete defeated and dispersed time;
3) mixed slurry that comprises cement blowing agent carries out mechanical foaming in foaming machine, simultaneously NaHCO3Also can in slurry, generate a large amount of CO with citric acid reactions2Bubble, this physics and chemistry is combined foaming processing method can improve the porosity in filler brick effectively, has significantly reduced the structural strength of material, and has alleviated the weight of filler brick;
4) the present invention adopts stalk, flyash, river sand etc. as matrix trunk material, can not form secondary pollution after defeated and dispersed, simultaneously also for recycling of waste resource provides a kind of new approach;
5) by adjusting kind and the doping of chemical treatment reagent in filling block, the present invention can use under different water pollution conditions, has stronger adaptability;
6) the present invention is cylindrical loose structure, has larger solid liquid interface, is conducive to improve medicament response area, is conducive to the serial connection of filler brick and the stability laying simultaneously, is suitable for various water body environments;
7) the present invention is simple in structure, with low cost, rapid-action, is suitable for the short-term Emergency management of all kinds of polluted water bodies.
Brief description of the drawings
Accompanying drawing 1 is constitutional diagram of the present invention.
Accompanying drawing 2 is filler brick monomer outline drawings.
Accompanying drawing 3 is filler brick manufacturing installation schematic diagrames.
Accompanying drawing 4 is blanking mold assembling schematic diagrames.
Accompanying drawing 5 is mold cores schematic diagrames.
In figure 1 is external mold, the 2nd, plug, the 3rd, mixed slurry, the 4th, mold base, the 5th, oscillating plate, the 6th, support spring, the 7th, shake table support, the 8th, vibrating motor, the 9th, ground, the 10th, filler brick, the 11st, permeable hole, the 12nd, straw rope, the 13rd, stopper slot.
Detailed description of the invention
Below in conjunction with embodiment and accompanying drawing, technical solution of the present invention is described in further detail, but protection scope of the present invention is not limited to described embodiment.
As shown in Fig. 1 ~ Fig. 5, a kind of from defeated and dispersed type long-acting slow-release purification of water quality filler brick device, comprise blanking mold and shake table.
The described blanking mold of stating comprises external mold 1, plug 2 and mold base 4.
The described hollow stainless pipe that external mold 1 is both ends open, internal diameter 200mm, height 350mm, the wall thickness 6mm of stating.
Described plug 2 diameters of stating are 15mm, and height 400mm, adopts stainless steel tube manufacture.
Described mold base 4 diameter 500mm, thickness 10mm, 5 plugs 2 are vertically fixed on mold base 4, for the permeable hole 11 of the filler brick 10 that is shaped. Mold base 4 surfaces also offer stopper slot 13, for being fixed by socket with external mold 1.
Described shake table involving vibrations plate 5, support spring 6, vibrating motor 8 and shake table support 7. Described oscillating plate 5 is square steel plate, and vibrating motor 8 is installed on oscillating plate 5 centers, below, power 400W, 3800 revs/min of rotating speeds.
Described oscillating plate 5 is connected with shake table support 7 by some support springs 6, and shake table support 7 is fixed on ground 9.
Its preparation method: comprise following processing step:
(1) stalk that is 1cm ~ 3cm by strain footpath carries out nature or artificial processed, after removal lateral lobe, puts into pulverizer, is ground into the particle that length is 1 ~ 1.5cm;
(2) stalk particle crushing is put into the water glass solution that modulus is 3.0, Baume degrees is 50.0 and soaked 30 minutes, take out natural drying 24 hours;
(3) choose applicable solid state chemistry reagent treatment, drying for standby according to the kind of pollutant in staying water;
(4) by stalk particle, sawdust, cement, flyash, river sand, carboxymethyl cellulose, NaHCO3, citric acid, chemical treatment reagent drop in mixer and be dry mixed 5 minutes according to the mass ratio of 50:20:80:50:100:1:3:1:5;
(5) dry mash stirring, water, vegetalitas blowing agent are dropped into the processing of foaming in cement foam maker according to: the mass ratio of 80:120:15, then pour in blanking mold, elemental height is mold height 3/4;
(6) mould is positioned on shake table and vibrates 5 ~ 10 seconds, after filling evenly in mould, leave standstill 30 minutes until slurry;
(7) mould is put into baking oven, 150 DEG C of insulations 30 minutes, take out and be cooled to normal temperature, remove mould, under nature, be dried 5 ~ 7 days, can obtain from defeated and dispersed filler brick.
Embodiment 1:
Using maize straw (strain footpath 1.8cm ~ 2.6cm), No. 425 portland cements do and river for building sand as matrix material, adopt the efficient ammonia nitrogen remover of commercially available LX-N501 type as doping treatment reagent, be applied to Liaohe irrigation area, Jiangxi agriculture drainage ditch engineering. Manufacture and engineering application process from defeated and dispersed type long-acting slow-release purification of water quality filler brick are as follows:
(1) stalk is carried out to natural-dehydration processing, after removal lateral lobe, put into pulverizer, be ground into the particle that length is 1cm ~ 1.5cm;
(2) stalk particle crushing is put into the water glass solution that modulus is 3.0, Baume degrees is 50.0 and soaked 30 minutes, take out natural drying 24 hours;
(3) by stalk particle, sawdust, cement, flyash, river sand, carboxymethyl cellulose, NaHCO3, citric acid, efficient ammonia nitrogen remover drop in mixer and be dry mixed 5 minutes according to the mass ratio of 50:20:80:50:100:1:3:1:5;
(4) dry mash stirring, water, vegetalitas blowing agent are dropped into the processing of foaming in cement foam maker according to: the mass ratio of 80:120:15, then pour in blanking mold, elemental height is mold height 3/4; (5) mould is positioned on shake table and vibrates 5 ~ 10 seconds, leaves standstill 30 minute after filling evenly until slurry in mould;
(6) mould is put into baking oven, 150 DEG C of insulations 30 minutes, then take out and be cooled to normal temperature, remove mould, under nature, be dried 5 ~ 7 days, can obtain from defeated and dispersed brick. After dried, be connected in series bunchiness from defeated and dispersed filler brick according to Fig. 1 mode with straw rope 12,15 ~ 20 filler bricks 10 of every a string serial connection, evenly render to the filler brick 10 being connected in series in drainage ditch, and throwing in density is 20 string/hundred meter. Before implementing, in drainage ditch, ammonia nitrogen concentration is 34.5 ~ 48.5mg/L, implements in latter 3 months, and ammonia nitrogen concentration is stabilized in 10.5 ~ 15.5mg/L, and that throws in is all defeated and dispersed after 3 months from defeated and dispersed filler brick, and Water quality has obtained obvious improvement.
Embodiment 2:
Using broomcorn straw (strain footpath 1cm ~ 1.2cm), No. 425 portland cements do and river for building sand as matrix material, adopt commercially available PCOD-2 type COD degradation agent as doping treatment reagent, be applied to river engineering in city, Nanjing, because this river course closes on multiple residence districts, water velocity is slow, and in water body, organic concentration is always higher. Manufacture and engineering application process from defeated and dispersed type long-acting slow-release purification of water quality filler brick are as follows:
(1) stalk is carried out to natural-dehydration processing, after removal lateral lobe, put into pulverizer, be ground into the particle that length is 1cm ~ 1.5cm;
(2) stalk particle crushing is put into the water glass solution that modulus is 3.0, Baume degrees is 50.0 and soaked 30 minutes, take out natural drying 24 hours;
(3) by stalk particle, sawdust, cement, flyash, river sand, carboxymethyl cellulose, NaHCO3, citric acid, efficient ammonia nitrogen remover drop in mixer and stir 5 minutes according to the mass ratio of 50:20:80:50:100:1:3:1:3;
(4) dry mash stirring, water, vegetalitas blowing agent are dropped into the processing of foaming in cement foam maker according to: the mass ratio of 80:120:15, then pour in blanking mold, elemental height is mold height 3/4; (6) mould is positioned on shake table and vibrates 5 ~ 10 seconds, leaves standstill 30 minute after filling evenly until slurry in mould;
(6) mould is put into baking oven, 150 DEG C of insulations 30 minutes, then take out and be cooled to normal temperature, remove mould, under nature, be dried 5 ~ 7 days, can obtain from defeated and dispersed brick. After dried, be connected in series bunchiness from defeated and dispersed filler brick according to Fig. 1 mode with straw rope 12,15 ~ 20 filler bricks 10 of every a string serial connection, evenly render to the filler brick 10 being connected in series in drainage ditch, and throwing in density is 20 string/hundred meter. Before implementing, in drainage ditch, COD concentration is 56 ~ 84mg/L, implements in latter 3 months, and COD concentration stabilize is at 18 ~ 25mg/L, and that throws in is all defeated and dispersed after 3 months from defeated and dispersed filler brick, and Water quality has obtained obvious improvement.
Above-described embodiment is preferably embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under Spirit Essence of the present invention and principle, substitutes, combination, simplify; all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (8)
1. from the preparation facilities of defeated and dispersed type long-acting slow-release purification of water quality filler brick, it is characterized in that: comprise blanking mold and shake table; Wherein blanking mold comprises external mold, plug and mold base, the hollow circular-tube that described external mold is both ends open, and 5 plug at right angle settings, on mold base, offer stopper slot on mold base, and external mold is connected with mold base by stopper slot; Described shake table involving vibrations plate, support spring, vibrating motor and shake table support, wherein vibrating motor is installed on oscillating plate below, and oscillating plate is connected with shake table support by some support springs.
2. the preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick according to claim 1, is characterized in that: described blanking mold comprises external mold, plug and mold base, and wherein external mold is on mold base, and plug is at external mold.
3. the preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick according to claim 1, is characterized in that: described hollow circular-tube, internal diameter 200mm, height 350mm, wall thickness 6mm.
4. the preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick according to claim 1, is characterized in that: stating diameter of mandrel is 15mm, and height 400mm, adopts stainless steel tube manufacture.
5. the preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick according to claim 1, is characterized in that: described mold base 4 diameter 500mm, and thickness 10mm, mold base surface also offers stopper slot, for being fixed by socket with external mold.
6. the preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick according to claim 1, it is characterized in that: described shake table involving vibrations plate, support spring, vibrating motor and shake table support, wherein oscillating plate is square steel plate, vibrating motor is installed on center, oscillating plate below, power 400W, 3800 revs/min of rotating speeds; Oscillating plate is connected with shake table support by some support springs, and shake table support is fixed on ground.
7. the preparation facilities from defeated and dispersed type long-acting slow-release purification of water quality filler brick according to claim 1, is characterized in that: described mold base surface also offers stopper slot, for being fixed by socket with external mold.
8. the preparation method from defeated and dispersed type long-acting slow-release purification of water quality filler brick as claimed in claim 1, is characterized in that: comprise the following steps:
(1) stalk that is 1cm ~ 3cm by strain footpath carries out nature or artificial processed, after removal lateral lobe, puts into pulverizer, is ground into the particle that length is 1 ~ 1.5cm;
(2) stalk particle crushing is put into the water glass solution that modulus is 3.0, Baume degrees is 50.0 and soaked 30 minutes, take out natural drying 24 hours;
(3) choose applicable solid state chemistry reagent treatment, drying for standby according to the kind of pollutant in staying water;
(4) by stalk particle, sawdust, cement, flyash, river sand, carboxymethyl cellulose, NaHCO3, citric acid, chemical treatment reagent drop in mixer and be dry mixed 5 minutes according to the mass ratio of 50:20:80:50:100:1:3:1:5;
(5) dry mash stirring, water, vegetalitas blowing agent are dropped into the processing of foaming in cement foam maker according to: the mass ratio of 80:120:15, then pour in blanking mold, elemental height is mold height 3/4;
(6) mould is positioned on shake table and vibrates 5 ~ 10 seconds, after filling evenly in mould, leave standstill 30 minutes until slurry;
(7) mould is put into baking oven, 150 DEG C of insulations 30 minutes, take out and be cooled to normal temperature, remove mould, under nature, be dried 5 ~ 7 days, obtain from defeated and dispersed type long-acting slow-release purification of water quality filler brick from defeated and dispersed filler brick.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610155185.2A CN105600940B (en) | 2016-03-18 | 2016-03-18 | From the preparation method and preparation facilities of defeated and dispersed type long-acting slow-release purification of water quality filler brick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610155185.2A CN105600940B (en) | 2016-03-18 | 2016-03-18 | From the preparation method and preparation facilities of defeated and dispersed type long-acting slow-release purification of water quality filler brick |
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| CN105600940A true CN105600940A (en) | 2016-05-25 |
| CN105600940B CN105600940B (en) | 2018-01-30 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101774244A (en) * | 2010-01-28 | 2010-07-14 | 黄庆森 | Method for preparing PVF sponge roller brush |
| CN201613610U (en) * | 2010-01-28 | 2010-10-27 | 黄庆森 | Device for producing polyvinyl formal sponge roll brush |
| CN102963548A (en) * | 2012-11-28 | 2013-03-13 | 杭州盛大高科技机电有限公司 | Vibration device for filling materials in container |
| US20140124420A1 (en) * | 2011-05-24 | 2014-05-08 | Korbi Co., Ltd. | Hybrid artificial wetland water purification system, sewage treatment device using same, and natural nonpoint purification device capable of simultaneously purifying river and lake water |
| CN104876635A (en) * | 2015-05-22 | 2015-09-02 | 蚌埠营军新型墙体材料有限公司 | Preparation method of hollow brick with high heat retaining property |
-
2016
- 2016-03-18 CN CN201610155185.2A patent/CN105600940B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101774244A (en) * | 2010-01-28 | 2010-07-14 | 黄庆森 | Method for preparing PVF sponge roller brush |
| CN201613610U (en) * | 2010-01-28 | 2010-10-27 | 黄庆森 | Device for producing polyvinyl formal sponge roll brush |
| US20140124420A1 (en) * | 2011-05-24 | 2014-05-08 | Korbi Co., Ltd. | Hybrid artificial wetland water purification system, sewage treatment device using same, and natural nonpoint purification device capable of simultaneously purifying river and lake water |
| CN102963548A (en) * | 2012-11-28 | 2013-03-13 | 杭州盛大高科技机电有限公司 | Vibration device for filling materials in container |
| CN104876635A (en) * | 2015-05-22 | 2015-09-02 | 蚌埠营军新型墙体材料有限公司 | Preparation method of hollow brick with high heat retaining property |
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| CN105600940B (en) | 2018-01-30 |
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