CN105597484B - Active carbon by chemical method produces purification and the recovery system of tail gas - Google Patents

Active carbon by chemical method produces purification and the recovery system of tail gas Download PDF

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Publication number
CN105597484B
CN105597484B CN201510651319.5A CN201510651319A CN105597484B CN 105597484 B CN105597484 B CN 105597484B CN 201510651319 A CN201510651319 A CN 201510651319A CN 105597484 B CN105597484 B CN 105597484B
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China
Prior art keywords
absorber
tail gas
carbon production
activated carbon
raw material
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CN105597484A (en
Inventor
周巾英
郑迅荟
郑晓红
郭昊
黄吉水
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Yushan Sanqing Activated Carbon Co ltd
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YUSHAN SANQING ACTIVATED CARBON FACTORY
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Abstract

The purification of the active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:Activated Carbon Production raw material is contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is adsorbed and recycled to the pollutant that can be used for active carbon by chemical method production in the tail gas.This recovery process rate of recovery is high, and recovery process is simple, and recovery process is lower-cost, more environmentally friendly.The invention also provides a kind of recovery systems using the recovery method.

Description

Active carbon by chemical method produces purification and the recovery system of tail gas
Technical field
The present invention relates to a kind of purifications and recovery method and purification and recovery system, more particularly to a kind of active carbon by chemical method The purification of production tail gas and recovery method and purification and recovery system.
Background technology
Chemical method (phosphoric acid method and zinc chloride process) process for preparing activated carbon be by certain density chemical activating agent (phosphoric acid and Zinc chloride) solution mixed with wooden class raw material fully after, be conveyed into internal heat type converter, and using high-temperature flue gas as heat source, directly add Thermal material, the tail gas that production process generates can contain a certain amount of chemical activating agent, a concentration of 500-2000ppm, direct emission Not only pollution air causes the waste of chemical activating agent simultaneously.Currently, common exhaust gas treating method has spray process and electric demisting Method, spray process especially work as recovered liquid since recovered liquid powdered carbon, wood tar content height cause filtration difficulty, evaporation and concentration difficult When volume is larger, equipment requirement and operation difficulty are required all larger.Electric demister pattern recycles tail gas chemical activating agent, although subtracting Recovered liquid volume is lacked, but power consumption is big, equipment technology requires height, hardly results in extensive popularization.
A kind of chemical activating agent recovery method is disclosed in the prior art, including is contained first using what spray process recycled Then the solution of chemical activating agent with chemical activation agent solution uniformly mix and by further adding using wooden class raw material Heated drying, it is final that chemical activating agent in solution is rested in wooden class raw material, achieve the purpose that recycle chemical activating agent. Although the part chemical activating agent in solution can in this way utilized by wooden class raw materials recovery, due to existing The solution chemistry activator concentration of spray process processing chemical activating agent exhaust gas not exclusively, after spray is relatively low to be unfavorable for absorption, wooden Class raw material easily causes part chemical activating agent in drying steps after being mixed with chemical activation agent solution and is asked by steam entrainment discharge etc. Topic so that this method chemical activating agent organic efficiency is not high.Simultaneously as this method need to use sprinkling equipment, mixing apparatus with And drying equipment, the steam of complex process high energy consumption, the trapped chemical activator generated in drying process cause secondary pollution etc. Problem, it is more difficult in industry promote.
Invention content
For this purpose, the technical problem to be solved in the present invention is to provide a kind of purify and rate of recovery height, purification and recovery process Simply, the more environmentally friendly pollutant purification that active carbon by chemical method produces in tail gas lower-cost with recovery process is purified And recovery method, and purification and recovery system.
The present invention is purification and the recovery method of a kind of active carbon by chemical method production tail gas, is included the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for active carbon by chemical method production in tail gas is adsorbed and is recycled.
The above method, the initial temperature of the tail gas be 30~250 DEG C, and described can be used for active carbon by chemical method production Pollutant includes at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar.
The above method further includes:By temperature holding meanss to the tail gas that is given off from the active carbon production equipment Carry out temperature holding step so that the tail gas exported from the temperature holding meanss and the entrance temperature holding meanss Temperature drop between the tail gas is less than 30%.
The above method further includes:The tail gas given off in the active carbon production equipment is added by heating device The step of heat;Wherein, mode of heating can be jacket type indirectly heat or directly provide directly heating for hot gas.
The above method, wherein the exhaust temperature being passed into the absorber is 60-240 DEG C.
The above method, the Activated Carbon Production raw material are carbon containing plant crushed material.
The above method, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell crushed material At least one of with sawdust etc..
The above method, wherein the exhaust temperature being passed into the absorber is 100-230 DEG C.
The initial temperature of the above method, the Activated Carbon Production tail gas is 30-90 DEG C, will be described by the heating device Tail gas heating heating at least 20%.
The chemical method preferably comprises phosphoric acid method and zinc chloride process, and the initial concentration of chemical activating agent is preferably in tail gas In 500-2000ppm.
A kind of purification and recovery system using any of the above-described kind of method, including:Absorber has for accommodating activated carbon The accommodation space of raw materials for production, absorber gas access and absorber gas vent, the absorber gas access and activated carbon The offgas outlet of production equipment is connected to.
Above-mentioned purification and recovery system further include:Temperature holding meanss have holding meanss gas access and holding meanss Gas vent, be set between the active carbon production equipment and the absorber, wherein the holding meanss gas access with it is described The offgas outlet of active carbon production equipment is connected to, and the holding meanss gas vent is connected to the absorber gas access, is used It is dropped in the gas for export from the temperature holding meanss and into the temperature between the tail gas of the temperature holding meanss Less than 30%.
Above-mentioned purification and recovery system further include:Heating device is set to the active carbon production equipment and the absorber Between, for being heated to being passed into the pervious tail gas of the absorber, wherein the heating device includes indirect heating apparatus And direct heater, the indirect heating apparatus is equipped with heating device gas access and heating device gas vent, described straight It connects heating device and is equipped with heater gas inlet port.
Above-mentioned purification and recovery system further include:Wind turbine is set between the active carbon production equipment and the absorber, For the Activated Carbon Production tail gas to be driven in the absorber;Or it is set to the absorber rear end, it is used for the tail gas Discharge after being introduced into the absorber.
Above-mentioned purification and recovery system, including at least two wind turbines, be respectively arranged on the active carbon production equipment with Between the absorber and it is set to the absorber rear end, for keeping pressure balance before and after the absorber.
Above-mentioned purification and recovery system further include:Controller of fan carries out constant for the output power to the wind turbine Control.
Above-mentioned purification and recovery system further include:Temperature-detecting device is provided close to the heating device gas access Locate, temperature information is obtained for carrying out temperature detection to the Activated Carbon Production tail gas for entering the heating device, it is described to add Thermal controls the heating power of the heating device according to the temperature information that the temperature-detecting device detects, adds when described Thermal is preferably when the initial temperature of the tail gas is 30-90 DEG C, by the heating device by the tail gas heating liter Temperature at least 20%.
Above-mentioned purification and recovery system, the absorber include absorber ontology, and the accommodation space is located at the absorption Device body interior, the absorber gas access and the absorber gas vent are set on the absorber ontology, institute It states and is additionally provided with inlet port and outlet port on absorber ontology;Further include the belt conveyer with conveyer belt, is set to the absorption Device body interior;Wherein, the belt conveyer is used to receive the Activated Carbon Production raw material entered from the feed inlet, and The absorber ontology is discharged in the Activated Carbon Production feedstock transportation to the discharge outlet, the Activated Carbon Production raw material exists It is contacted with the tail gas of entrance during conveying, and the flowing of the tail gas is obstructed.
Above-mentioned purification and recovery system, the absorber further include feeding warehouse, are set at the feed inlet;Limiting device, At the feeding warehouse or the feed inlet, for being coordinated with the belt conveyer, it is defeated that limitation is located at the belt The thickness of the Activated Carbon Production raw material on the conveyer belt of material machine.
Above-mentioned purification and recovery system, the limits device are coordinated with the belt conveyer, for that will be located at institute The thickness for stating the Activated Carbon Production raw material on the conveyer belt of belt conveyer is limited to 100-1000mm;The belt is defeated Described conveyer belt one end of material machine is located at the feed inlet, and the other end is located at the discharge outlet, the belt conveyer root Conveying speed is controlled at a distance from the discharge port according to the feed inlet so that the Activated Carbon Production raw material is conveying Taking the residence time is:1-5h, and the controller of fan is suitable for that the flow control of the tail gas of the absorber will be entered For:0.1-0.8m/s.
A kind of absorber of purification and recycling for above-mentioned active carbon by chemical method production tail gas, including:With for holding Receive accommodation space, absorber gas access and the absorber gas vent of Activated Carbon Production raw material, the absorber gas access It is connected to the offgas outlet of active carbon production equipment, for make to give off in Activated Carbon Production raw material and active carbon production equipment Tail gas is contacted.
Above-mentioned absorber, the absorber include absorber ontology, and the accommodation space is located at the absorber ontology Inside, the absorber gas access and the absorber gas vent are set on the absorber ontology, the absorption It is additionally provided with inlet port and outlet port on device ontology;Further include the belt conveyer with conveyer belt, is set to the absorber ontology The accommodation space in;Wherein, the belt conveyer is for receiving the Activated Carbon Production entered from the feed inlet Raw material, and the absorber ontology, the activated carbon life is discharged in the Activated Carbon Production feedstock transportation to the discharge outlet Production raw material is contacted during conveying with the tail gas of entrance, and is obstructed to the flowing of the tail gas.
Above-mentioned absorber, the absorber further include feeding warehouse, are set at the feed inlet;Limiting device is set to institute It states at feeding warehouse or the feed inlet, for being coordinated with the belt conveyer, limitation is positioned at the belt conveyer The thickness of the Activated Carbon Production raw material on the conveyer belt.
Above-mentioned absorber, the limits device are coordinated with the belt conveyer, for that will be located at the belt The thickness of the Activated Carbon Production raw material is limited to 100-1000mm on the conveyer belt of conveyer;The belt conveyer Described conveyer belt one end is located at the feed inlet, and the other end is located at the discharge outlet, and the belt conveyer is according to Feed inlet controls conveying speed at a distance from the discharge port so that the Activated Carbon Production raw material stops on the conveyor belt The time is stayed to be:1-5h.
Above-mentioned absorber further includes spiral discharging machine, is located at the discharge outlet, the work for that will adsorb pollutant Property charcoal raw materials for production the absorber ontology is discharged.
The present invention has the following advantages compared with the prior art:
1. the present invention is a kind of method of purification and the comprehensive utilization of active carbon by chemical method production tail gas, including following step Suddenly:Activated Carbon Production raw material is contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production Raw material is adsorbed and is recycled to the pollutant that can be used for Activated Carbon Production in the tail gas.Due to the tail gas, i.e. exhaust gas The middle major part pollutant be in aerosol state or by steam carry secretly etc. unstable states, it is straight using Activated Carbon Production raw material Connecing the technique contacted with gas can make the purification of pollutant described in the tail gas and the rate of recovery higher, i.e., finally inhaled Be attached to the pollutant on Activated Carbon Production raw material with from the pollutant in the tail gas being discharged in active carbon production equipment Ratio between amount is larger.
At least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar contained in pollutant pollutant passes through this After method is recycled, obtained Activated Carbon Production raw material can be directly used for the production of consequent activities charcoal, will not cause the pollution Object wastes, while will not cause secondary pollution, wherein is adsorbed at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar The Activated Carbon Production raw material of pollutant, can be used in process for preparing activated carbon;And the wood adsorbed by Activated Carbon Production raw material is burnt It is oily then can be further used as Activated Carbon Production raw material for consequent activities charcoal production.
Meanwhile this method is simple for process, equipment is uncomplicated, operating cost is low, is easy to promote in activated carbon industry.
2. the initial temperature of the Activated Carbon Production tail gas is 30~250 DEG C, active carbon by chemical method production can be conducive to Absorption of the raw material at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar pollutant.
3. the exhaust temperature being passed into the absorber is 60-240 DEG C, it can directly be conducive to high temperature production tail gas pair one A little moist Activated Carbon Production raw materials are dried, and reduce the moisture contained in Activated Carbon Production raw material, so that dry And Activated Carbon Production raw material that adsorbed at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar pollutant can be direct It is applied in consequent activities charcoal producing technique, i.e., the present invention purifies the pollutant in the tail gas and recycling tail gas for subsequently living Property charcoal production reduce pair relative to vent gas treatment and consequent activities charcoal producing technique is carried out using spray process in the prior art Activated Carbon Production raw material drying technique saves production cost to simplify entire processing step.
4. the usual volume of active carbon production equipment in the prior art is larger, and the volume of absorber is generally also larger, inhales Adnexa would generally be arranged far from the active carbon production equipment, and Activated Carbon Production tail gas needs to transmit by pipeline, existing skill The device that tail gas is used for transmission in art is usually metallic conduit, and this pipeline can lead to gas during exporting high-temperature gas Temperature rapid drawdown.The tail gas given off from the active carbon production equipment is kept into trip temperature by temperature holding meanss The step of so that from the tail gas of temperature holding meanss output and between the tail gas of the temperature holding meanss Temperature drop be less than 30%.It can be effectively prevented from because being exported tail gas to the process of absorber from active carbon production equipment In, because exhaust temperature rapid drawdown causes to be cooled to liquid, Wu Fatong by pollutants such as chemical activating agents that steam is carried secretly in tail gas It crosses steam to be brought into the absorber, compares from activated carbon and give birth to so as to cause the chemical activation dosage that absorber is touched The amount being discharged in production equipment has larger reduction, closely leads to the rate of recovery for carrying out chemical activating agent recycling to tail gas using absorber The technical issues of being greatly reduced.By the way that temperature drop control in the numberical range less than 30%, can be avoided this significantly Kind technical problem, it is ensured that the rate of recovery is allowed to be in a higher level.
5. being heated to the tail gas given off from the active carbon production equipment by heating device, on the one hand Can to avoid mentioning in the 4th point in tail gas transmission process, because of technical problem caused by temperature decrease, can also improve into The temperature for entering the tail gas into absorber, so as to which further moist Activated Carbon Production raw material is dried, Promote subsequently directly obtain the preferably dry Activated Carbon Production raw material for being adsorbed with chemical activating agent.
It, can be more efficiently to Activated Carbon Production original 6. the exhaust temperature being passed into the absorber is 60-240 DEG C Material is dried, and promotes subsequently directly obtain the preferably dry Activated Carbon Production raw material for being adsorbed with chemical activating agent.
7. being passed into 100-230 DEG C of the exhaust temperature in the absorber, the above-mentioned 4th can be more effectively avoided Technical problem in point can also more effectively be dried Activated Carbon Production raw material, promote subsequently directly obtain The preferably dry Activated Carbon Production raw material for being adsorbed with the pollutant that can be used for Activated Carbon Production.
8. the initial temperature of the tail gas is 30-90 DEG C, the tail gas heating is heated up at least by the heating device 20%, it can be effectively prevented from the technical problem in above-mentioned 4th point as a kind of more preferably embodiment, it can also be more Effectively Activated Carbon Production raw material is dried, promotes subsequently directly obtain being adsorbed with including institute for preferably drying State the Activated Carbon Production raw material for the pollutant that can be used for Activated Carbon Production.
9. the recovery system of the present invention, including:Absorber is equipped with Activated Carbon Production raw material, has absorber gas access With absorber gas vent, the absorber gas access is connected to the offgas outlet of active carbon production equipment, for making activity Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment.This design can improve to tail gas in can While the rate of recovery for the pollutant of Activated Carbon Production, equipment is greatly simplified, reduces process costs, and environmental protection can be reached Effect.
10. the absorber includes absorber ontology, the absorber gas access and the absorber gas vent are set In on the absorber ontology, inlet port and outlet port are additionally provided on the absorber ontology;Further include with conveyer belt Belt conveyer, be set to the absorber body interior;Wherein, the belt conveyer for receive from the feed inlet into The Activated Carbon Production raw material entered, and the absorber is discharged in the Activated Carbon Production feedstock transportation to the discharge outlet Ontology, the Activated Carbon Production raw material are contacted during conveying with the tail gas of entrance, and to the tail gas Flowing is obstructed.It can be designed so that pollutant described in the tail gas being passed on the Activated Carbon Production raw material above It is intercepted and is adsorbed by the Activated Carbon Production raw material.
11. the recovery system of the present invention, wherein be located at the thickness of the Activated Carbon Production raw material on the conveyer belt For:100-1000mm;Flow velocity into the tail gas of the absorber is:0.1-0.8m/s;The material is on the conveyor belt Residence time is:1-5h.It not only can be effectively so that the Activated Carbon Production raw material be to the pollutant in the tail gas It is obstructed and is adsorbed, and more Activated Carbon Production raw material can be made to be adsorbed with the pollutant, obtain more having The Activated Carbon Production raw material of adsorbate is used for subsequent Activated Carbon Production.
Description of the drawings
In order to make the content of the present invention more clearly understood, it below according to specific embodiments of the present invention and combines Attached drawing, the present invention is described in further detail, wherein
Fig. 1 is the schematic diagram of the recovery system of one of which embodiment of the present invention;
Fig. 2 is a kind of schematic diagram of the recovery system of preferred embodiment of the present invention;
Fig. 3 is a kind of schematic diagram of the recovery system of more preferable embodiment of the present invention;
Fig. 4 is a kind of schematic diagram of the recovery system of more preferable embodiment of the present invention.
Fig. 5 is the schematic diagram of absorber of the present invention;
1- active carbon production equipments;2- absorbers;3- temperature holding meanss;4- Activated Carbon Production raw materials;5- wind turbines;6- adds Thermal;7- feeding warehouses;8- absorbers gas access;9- belt conveyers;10- spiral discharging machines;11- conveyer belts;12- is accommodated Space 13- feed inlets, 14- slag-drip openings;15- absorber ontologies.
Specific implementation mode
Embodiment 1
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described It can be used for being adsorbed and being recycled for the pollutant of Activated Carbon Production in tail gas, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 30 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..
Embodiment 2
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail Gas is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 40 DEG C.The Activated Carbon Production is former Material is preferably carbon containing plant crushed material, and the carbon containing plant crushed material includes furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell At least one of crushed material and sawdust etc..
Embodiment 3
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 50 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..
Embodiment 4
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 60 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..
Embodiment 5
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 70 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 60 DEG C.
Embodiment 6
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 80 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 70 DEG C.
Embodiment 7
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 90 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 80 DEG C.
Embodiment 8
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 100 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 90 DEG C.
Embodiment 9
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 105 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 100 DEG C.
Embodiment 10
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 110 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 100 DEG C.
Embodiment 11
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 120 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 110 DEG C.
Embodiment 12
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 150 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 130 DEG C.
Embodiment 13
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 160 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 150 DEG C.
Embodiment 14
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 180 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 160 DEG C.
Embodiment 15
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 240 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 230 DEG C.
Embodiment 16
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 250 DEG C.The Activated Carbon Production raw material Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 240 DEG C.
Embodiment 17
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method are in any of the above-described kind of embodiment On the basis of, further include to the tail gas that is given off from the active carbon production equipment by temperature holding meanss into trip temperature The step of holding so that the tail gas exported from the temperature holding meanss and the tail for entering the temperature holding meanss Temperature drop between gas is less than 30%.The temperature drop=(temperature of the tail gas of temperature value-output of the tail gas of input Value)/input the tail gas temperature value, the unit of the temperature value is degree Celsius.The thickness of the Activated Carbon Production raw material For:100-1000mm;Flow velocity into the tail gas of the absorber is:0.1-0.8m/s;The material is on the conveyor belt Residence time is:1-5h.The thickness of the Activated Carbon Production raw material, the flow velocity of the tail gas stop on the conveyor belt with the material Staying time coordination that the pollutant in tail gas may be implemented can be obstructed by the Activated Carbon Production raw material, and other gases can To pass through the Activated Carbon Production raw material to be discharged.
Embodiment 18
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method are in any one implementation of embodiment 1-3 On the basis of example, further include:The tail gas given off from the active carbon production equipment is added by heating device Heat.The tail gas heating is more preferably preferably heated to 100-230 DEG C to 60-240 DEG C.
When the initial temperature of the tail gas is 30-90 DEG C, as another more preferable embodiment, pass through the heating Device by the tail gas heating heat up at least 20%.The percentage calculation mode is:(the temperature value-of the tail gas after heating The temperature value of the tail gas before heating) tail gas before/heating temperature value, the unit of the temperature value is degree Celsius.
Embodiment 19
As shown in Figure 1, purification and the recovery system of a kind of active carbon by chemical method production tail gas of the present invention, including:Absorption Device 2 is equipped with Activated Carbon Production raw material 4, and there is absorber gas access and absorber gas vent, 2 gas of the absorber to enter Mouth is connected to the offgas outlet of active carbon production equipment 1.It preferably comprises:There is temperature holding meanss 3 holding meanss gas to enter Mouth and holding meanss gas vent are set between the active carbon production equipment 1 and the absorber 2, wherein the holding meanss Gas access is connected to the offgas outlet of the active carbon production equipment 1, the holding meanss gas vent and the absorber Gas access is connected to;The tail gas for export from the temperature holding meanss and the entrance temperature holding meanss Temperature drop between the tail gas is less than 30%.The temperature drop=(tail gas of temperature value-output of the tail gas of input Temperature value)/input the tail gas temperature value, the unit of the temperature value is degree Celsius.
Preferably, as shown in Fig. 2, can also include:Wind turbine 5, be set to the active carbon production equipment 1 with It between the absorber 2, is preferably set between the active carbon production equipment and the temperature holding meanss, is used for the tail gas It drives in the absorber 2.As another alternative embodiments, after the wind turbine can also be set to the absorber End, for discharge after the tail gas is introduced into the absorber.
In addition, as an improvement embodiment, can also include:Further include controller of fan, for the wind The output power of machine carries out constant control.
Embodiment 20
As shown in figure 3, purification and the recovery system of a kind of active carbon by chemical method production tail gas of the present invention, including:Absorption Device 2 is equipped with Activated Carbon Production raw material 4, has absorber gas access and absorber gas vent, the absorber gas access It is connected to the offgas outlet of active carbon production equipment 1.Preferably further include:Heating device 6, have heating device gas access and Heating device gas vent is set between the active carbon production equipment 1 and the absorber 2, for being passed into the absorption 2 pervious tail gas of device is heated.Can also include:Wind turbine 5 is set to the active carbon production equipment 1 and the absorber 2 Between, it is preferably set between heating device 6 and the absorber 2, for driving in the tail gas in the absorber 2.As another A kind of alternative embodiments, the wind turbine can also be set to the rear end of the absorber, described in introducing the tail gas Discharge after in absorber.
Preferably further include temperature-detecting device (not shown), is provided close at the heating device gas access, is used for The tail gas to entering the heating device carries out temperature detection and obtains temperature information, and the heating device is according to the temperature The temperature information that detection device detects controls the heating power of the heating device, when the heating device is preferably when described The initial temperature of tail gas be 30-90 DEG C when, by the heating device by the tail gas heating heat up at least 20%.
In addition, as an improvement embodiment, can also include:Controller of fan, for the defeated of the wind turbine Go out power and carries out constant control.
Embodiment 21
As shown in figure 4, purification and the recovery system of a kind of active carbon by chemical method production tail gas of the present invention, including:Absorption Device 2 has the accommodation space 12 for accommodating Activated Carbon Production raw material 4, and there is absorber gas access to go out with absorber gas Mouthful, the absorber gas access is connected to the offgas outlet of active carbon production equipment, for making Activated Carbon Production raw material and work The tail gas given off in property charcoal production equipment is contacted.It preferably comprises:Heating device 6 has heating device gas access With heating device gas vent, it is set between the active carbon production equipment and the absorber, for being passed into the absorption 2 pervious tail gas of device is heated.
Preferably further include:Temperature holding meanss 4 have holding meanss gas access and holding meanss gas vent, if Between the active carbon production equipment 1 and the absorber 2, wherein given birth to the activated carbon holding meanss gas access Produce the offgas outlet connection of equipment 1, the holding meanss gas vent be connected to the absorber gas access, be used to make from Temperature drop between the tail gas and the tail gas for entering the temperature holding meanss of the temperature holding meanss output is less than 30%.
Can also include:At least two wind turbines 5, are respectively arranged between the active carbon production equipment and the absorber and set In the absorber rear end, for keeping pressure balance before and after the absorber.
Preferably further include temperature-detecting device (not shown), is provided close at the heating device gas access, is used for The tail gas to entering the heating device carries out temperature detection and obtains temperature information, and the heating device is according to the temperature The temperature information that detection device detects controls the heating power of the heating device, when the heating device is preferably when described The initial temperature of tail gas be 30-90 DEG C when, by the heating device by the tail gas heating heat up at least 20%.The percentage Calculation is:The tail before (temperature value of the tail gas before temperature value-heating of the tail gas after heating)/heating The unit of the temperature value of gas, the temperature value is degree Celsius.
In addition, as an improvement embodiment, can also include:Controller of fan, for the defeated of the wind turbine Go out power and carries out constant control.
As another improved embodiment, as shown in figure 5, the purification and recovery system of the present embodiment, wherein described Absorber includes absorber ontology 15, and the accommodation space 12 is located at the inside of the absorber ontology 15, the absorber gas Body entrance 8 and the absorber gas vent (not marking herein) are set on the absorber ontology 15, the absorber Feed inlet 13 and discharge port (not shown) are additionally provided on ontology 15;Further include the belt conveyer 9 with conveyer belt 11, is set to institute It states in the accommodation space 12 of absorber ontology 15;Wherein, the belt conveyer 9 for receive from the feed inlet 13 into The Activated Carbon Production raw material 4 entered, and the Activated Carbon Production raw material 4 is delivered to the discharge outlet, the absorption is discharged Device ontology 15, the Activated Carbon Production raw material 13 are contacted during conveying with the tail gas of entrance, wherein in order to Realize contact, the tail gas enter the absorber flow direction can the relatively described Activated Carbon Production raw material movement it is flat Row is vertical;Preferably, the Activated Carbon Production raw material can realize that the flowing to the tail gas obstructs, to tail gas described in this It is the direction of motion perpendicular to the Activated Carbon Production raw material into the preferable flow rate direction of the absorber, and flows to the work Property charcoal raw materials for production, more preferably, the absorber gas access is set to right over the absorber ontology, and the tail gas is from upper The Activated Carbon Production raw material is flowed under.In addition, it includes feeding warehouse 7 that the absorber, which is also preferably, it is set to the feed inlet At 13;Limiting device (does not mark) herein, is set at the feeding warehouse 7 or the feed inlet, is used for and the belt conveyer 9 Coordinated, the thickness of limitation Activated Carbon Production raw material 4 on the conveyer belt 11 of the belt conveyer.
Present invention purification and recovery system, the limits device are coordinated with the belt conveyer, being used for will The thickness of the Activated Carbon Production raw material is limited to 100-1000mm on the conveyer belt of the belt conveyer;It is described Described conveyer belt one end of belt conveyer is located at the feed inlet, and the other end is located at the discharge outlet, and the belt is defeated Material machine controls conveying speed at a distance from the discharge port according to the feed inlet so that the Activated Carbon Production raw material The residence time is on the conveyor belt:1-5h, the controller of fan are suitable for that the flow velocity of the tail gas of the absorber will be entered Control is:0.1-0.8m/s.
The residence time matches on the conveyor belt with the material for the thickness of the Activated Carbon Production raw material, the flow velocity of the tail gas Closing the pollutant that may be implemented in tail gas can be obstructed by the Activated Carbon Production raw material, and other gases can pass through institute Activated Carbon Production raw material is stated to be discharged.The discharge outlet is also further provided with spiral discharging machine 10, described for that will be adsorbed with The discharge port is discharged in the Activated Carbon Production raw material of pollutant.The absorber bottoms are additionally provided with slag-drip opening 14.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or It changes still within the protection scope of the invention.

Claims (1)

1. a kind of purification and recovery system, including:Absorber has for accommodating the accommodation space of Activated Carbon Production raw material, inhaling Adnexa gas access and absorber gas vent, the absorber gas access are suitable for the offgas outlet with active carbon production equipment Connection, for making Activated Carbon Production raw material be contacted with the tail gas given off in active carbon production equipment;
The absorber includes absorber ontology, and the accommodation space is located at the absorber body interior, the absorber gas Body entrance and the absorber gas vent are set on the absorber ontology, be additionally provided on the absorber ontology feed inlet and Discharge port;Further include the belt conveyer with conveyer belt, is set in the accommodation space of the absorber ontology;Wherein, The belt conveyer is for receiving the Activated Carbon Production raw material entered from the feed inlet, and by the Activated Carbon Production Feedstock transportation to the discharge outlet is discharged the absorber ontology, the Activated Carbon Production raw material during conveying with into The tail gas entered is contacted, and is obstructed to the flowing of the tail gas;
The absorber further includes feeding warehouse, is set at the feed inlet;Limiting device is set to the feeding warehouse or the charging At mouthful, for being coordinated with the belt conveyer, limitation work on the conveyer belt of the belt conveyer The thickness of property charcoal raw materials for production;
It is characterized in that:
The limiting device is coordinated with the belt conveyer, for that will be located at the conveyer belt of the belt conveyer The thickness of the upper Activated Carbon Production raw material limits 100-1000mm;Described conveyer belt one end of the belt conveyer is located at institute It states at feed inlet, the other end is located at the discharge outlet, and the belt conveyer is according to the feed inlet and the discharge port Distance controls conveying speed so that the residence time is the Activated Carbon Production raw material on the conveyor belt:1-5h;
Further include wind turbine, be set between the active carbon production equipment and the absorber, is used for the Activated Carbon Production tail gas It drives in the absorber;Or it is set to the absorber rear end, for discharge after the tail gas is introduced into the absorber;
Controller of fan carries out constant control for the output power to the wind turbine;And be suitable for will be into for the controller of fan The flow control for entering the tail gas of the absorber is:0.1-0.8m/s;
Heating device is set between the active carbon production equipment and the absorber, for being passed into before the absorber Tail gas heated;And when the initial temperature of the tail gas is 30-90 DEG C, the heating device heats up to the tail gas heating At least 20%;
Temperature holding meanss have holding meanss gas access and holding meanss gas vent, are set set on the Activated Carbon Production It is standby between the absorber, wherein the holding meanss gas access is connected to the offgas outlet of the active carbon production equipment, The holding meanss gas vent is connected to the absorber gas access, is used to make to export from the temperature holding meanss Temperature drop between tail gas and the tail gas for entering the temperature holding meanss is less than 30%.
CN201510651319.5A 2014-01-07 2014-01-07 Active carbon by chemical method produces purification and the recovery system of tail gas Expired - Fee Related CN105597484B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201228234Y (en) * 2008-03-13 2009-04-29 项缙农 Active carbon preparation apparatus by chemical method with purification exhaust and recovery activator function
CN101613101B (en) * 2008-03-06 2012-02-01 项瑞芳 Chemical method for preparing active carbon and simultaneously purifying self tail gas
CN102515163A (en) * 2011-12-21 2012-06-27 福建元力活性炭股份有限公司 Method for recycling phosphoric acid from tail gas produced in carbonization and activation of active carbon in phosphoric acid process
CN103112836A (en) * 2013-01-30 2013-05-22 项瑞芳 Method for recycling phosphoric acid in tail gas generated in process of producing activated carbon by phosphoric acid process and utilizing afterheat of tail gas
CN203264532U (en) * 2013-04-24 2013-11-06 浙江省林业科学研究院 Active tail gas purification treatment equipment for preparing active carbon through chemical method
CN103446851A (en) * 2013-08-21 2013-12-18 泉州市天龙环境工程有限公司 Recovery and purification device and method for phosphoric acid from tail gases generated in chemical method activated carbon production process

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009032810A1 (en) * 2009-07-10 2011-01-13 BLüCHER GMBH Plant and process for the production of activated carbon
CN201625490U (en) * 2010-03-19 2010-11-10 铜陵市陵阳化工有限责任公司 Exhaust gas purifying device
JP5566815B2 (en) * 2010-08-31 2014-08-06 大陽日酸株式会社 Gas purification method and gas purification apparatus
CN201840979U (en) * 2010-11-08 2011-05-25 深圳市翔宇环保科技有限公司 Smoke gas comprehensive treatment system
CN203803324U (en) * 2014-01-07 2014-09-03 上海康捷空气净化技术有限公司 Adsorber for purifying and recycling exhaust generated during chemical production of activated carbon
CN105582784B (en) * 2014-01-07 2018-02-23 上海三山炭业科技有限公司 The purification of active carbon by chemical method production tail gas and recovery system
CN203803329U (en) * 2014-01-07 2014-09-03 上海康捷空气净化技术有限公司 Purification and recovery system for tail gas discharged from activated carbon production by chemical method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613101B (en) * 2008-03-06 2012-02-01 项瑞芳 Chemical method for preparing active carbon and simultaneously purifying self tail gas
CN201228234Y (en) * 2008-03-13 2009-04-29 项缙农 Active carbon preparation apparatus by chemical method with purification exhaust and recovery activator function
CN102515163A (en) * 2011-12-21 2012-06-27 福建元力活性炭股份有限公司 Method for recycling phosphoric acid from tail gas produced in carbonization and activation of active carbon in phosphoric acid process
CN103112836A (en) * 2013-01-30 2013-05-22 项瑞芳 Method for recycling phosphoric acid in tail gas generated in process of producing activated carbon by phosphoric acid process and utilizing afterheat of tail gas
CN203264532U (en) * 2013-04-24 2013-11-06 浙江省林业科学研究院 Active tail gas purification treatment equipment for preparing active carbon through chemical method
CN103446851A (en) * 2013-08-21 2013-12-18 泉州市天龙环境工程有限公司 Recovery and purification device and method for phosphoric acid from tail gases generated in chemical method activated carbon production process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
关于氧化锌法活性炭废气中锌的回收利用的探讨;徐善海;《林化科技通讯》;19820829;第121-123页 *

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CN105381684A (en) 2016-03-09

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