Active carbon by chemical method produces purification and the recovery system of tail gas
Technical field
The present invention relates to a kind of purifications and recovery method and purification and recovery system, more particularly to a kind of active carbon by chemical method
The purification of production tail gas and recovery method and purification and recovery system.
Background technology
Chemical method (phosphoric acid method and zinc chloride process) process for preparing activated carbon be by certain density chemical activating agent (phosphoric acid and
Zinc chloride) solution mixed with wooden class raw material fully after, be conveyed into internal heat type converter, and using high-temperature flue gas as heat source, directly add
Thermal material, the tail gas that production process generates can contain a certain amount of chemical activating agent, a concentration of 500-2000ppm, direct emission
Not only pollution air causes the waste of chemical activating agent simultaneously.Currently, common exhaust gas treating method has spray process and electric demisting
Method, spray process especially work as recovered liquid since recovered liquid powdered carbon, wood tar content height cause filtration difficulty, evaporation and concentration difficult
When volume is larger, equipment requirement and operation difficulty are required all larger.Electric demister pattern recycles tail gas chemical activating agent, although subtracting
Recovered liquid volume is lacked, but power consumption is big, equipment technology requires height, hardly results in extensive popularization.
A kind of chemical activating agent recovery method is disclosed in the prior art, including is contained first using what spray process recycled
Then the solution of chemical activating agent with chemical activation agent solution uniformly mix and by further adding using wooden class raw material
Heated drying, it is final that chemical activating agent in solution is rested in wooden class raw material, achieve the purpose that recycle chemical activating agent.
Although the part chemical activating agent in solution can in this way utilized by wooden class raw materials recovery, due to existing
The solution chemistry activator concentration of spray process processing chemical activating agent exhaust gas not exclusively, after spray is relatively low to be unfavorable for absorption, wooden
Class raw material easily causes part chemical activating agent in drying steps after being mixed with chemical activation agent solution and is asked by steam entrainment discharge etc.
Topic so that this method chemical activating agent organic efficiency is not high.Simultaneously as this method need to use sprinkling equipment, mixing apparatus with
And drying equipment, the steam of complex process high energy consumption, the trapped chemical activator generated in drying process cause secondary pollution etc.
Problem, it is more difficult in industry promote.
Invention content
For this purpose, the technical problem to be solved in the present invention is to provide a kind of purify and rate of recovery height, purification and recovery process
Simply, the more environmentally friendly pollutant purification that active carbon by chemical method produces in tail gas lower-cost with recovery process is purified
And recovery method, and purification and recovery system.
The present invention is purification and the recovery method of a kind of active carbon by chemical method production tail gas, is included the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for active carbon by chemical method production in tail gas is adsorbed and is recycled.
The above method, the initial temperature of the tail gas be 30~250 DEG C, and described can be used for active carbon by chemical method production
Pollutant includes at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar.
The above method further includes:By temperature holding meanss to the tail gas that is given off from the active carbon production equipment
Carry out temperature holding step so that the tail gas exported from the temperature holding meanss and the entrance temperature holding meanss
Temperature drop between the tail gas is less than 30%.
The above method further includes:The tail gas given off in the active carbon production equipment is added by heating device
The step of heat;Wherein, mode of heating can be jacket type indirectly heat or directly provide directly heating for hot gas.
The above method, wherein the exhaust temperature being passed into the absorber is 60-240 DEG C.
The above method, the Activated Carbon Production raw material are carbon containing plant crushed material.
The above method, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell crushed material
At least one of with sawdust etc..
The above method, wherein the exhaust temperature being passed into the absorber is 100-230 DEG C.
The initial temperature of the above method, the Activated Carbon Production tail gas is 30-90 DEG C, will be described by the heating device
Tail gas heating heating at least 20%.
The chemical method preferably comprises phosphoric acid method and zinc chloride process, and the initial concentration of chemical activating agent is preferably in tail gas
In 500-2000ppm.
A kind of purification and recovery system using any of the above-described kind of method, including:Absorber has for accommodating activated carbon
The accommodation space of raw materials for production, absorber gas access and absorber gas vent, the absorber gas access and activated carbon
The offgas outlet of production equipment is connected to.
Above-mentioned purification and recovery system further include:Temperature holding meanss have holding meanss gas access and holding meanss
Gas vent, be set between the active carbon production equipment and the absorber, wherein the holding meanss gas access with it is described
The offgas outlet of active carbon production equipment is connected to, and the holding meanss gas vent is connected to the absorber gas access, is used
It is dropped in the gas for export from the temperature holding meanss and into the temperature between the tail gas of the temperature holding meanss
Less than 30%.
Above-mentioned purification and recovery system further include:Heating device is set to the active carbon production equipment and the absorber
Between, for being heated to being passed into the pervious tail gas of the absorber, wherein the heating device includes indirect heating apparatus
And direct heater, the indirect heating apparatus is equipped with heating device gas access and heating device gas vent, described straight
It connects heating device and is equipped with heater gas inlet port.
Above-mentioned purification and recovery system further include:Wind turbine is set between the active carbon production equipment and the absorber,
For the Activated Carbon Production tail gas to be driven in the absorber;Or it is set to the absorber rear end, it is used for the tail gas
Discharge after being introduced into the absorber.
Above-mentioned purification and recovery system, including at least two wind turbines, be respectively arranged on the active carbon production equipment with
Between the absorber and it is set to the absorber rear end, for keeping pressure balance before and after the absorber.
Above-mentioned purification and recovery system further include:Controller of fan carries out constant for the output power to the wind turbine
Control.
Above-mentioned purification and recovery system further include:Temperature-detecting device is provided close to the heating device gas access
Locate, temperature information is obtained for carrying out temperature detection to the Activated Carbon Production tail gas for entering the heating device, it is described to add
Thermal controls the heating power of the heating device according to the temperature information that the temperature-detecting device detects, adds when described
Thermal is preferably when the initial temperature of the tail gas is 30-90 DEG C, by the heating device by the tail gas heating liter
Temperature at least 20%.
Above-mentioned purification and recovery system, the absorber include absorber ontology, and the accommodation space is located at the absorption
Device body interior, the absorber gas access and the absorber gas vent are set on the absorber ontology, institute
It states and is additionally provided with inlet port and outlet port on absorber ontology;Further include the belt conveyer with conveyer belt, is set to the absorption
Device body interior;Wherein, the belt conveyer is used to receive the Activated Carbon Production raw material entered from the feed inlet, and
The absorber ontology is discharged in the Activated Carbon Production feedstock transportation to the discharge outlet, the Activated Carbon Production raw material exists
It is contacted with the tail gas of entrance during conveying, and the flowing of the tail gas is obstructed.
Above-mentioned purification and recovery system, the absorber further include feeding warehouse, are set at the feed inlet;Limiting device,
At the feeding warehouse or the feed inlet, for being coordinated with the belt conveyer, it is defeated that limitation is located at the belt
The thickness of the Activated Carbon Production raw material on the conveyer belt of material machine.
Above-mentioned purification and recovery system, the limits device are coordinated with the belt conveyer, for that will be located at institute
The thickness for stating the Activated Carbon Production raw material on the conveyer belt of belt conveyer is limited to 100-1000mm;The belt is defeated
Described conveyer belt one end of material machine is located at the feed inlet, and the other end is located at the discharge outlet, the belt conveyer root
Conveying speed is controlled at a distance from the discharge port according to the feed inlet so that the Activated Carbon Production raw material is conveying
Taking the residence time is:1-5h, and the controller of fan is suitable for that the flow control of the tail gas of the absorber will be entered
For:0.1-0.8m/s.
A kind of absorber of purification and recycling for above-mentioned active carbon by chemical method production tail gas, including:With for holding
Receive accommodation space, absorber gas access and the absorber gas vent of Activated Carbon Production raw material, the absorber gas access
It is connected to the offgas outlet of active carbon production equipment, for make to give off in Activated Carbon Production raw material and active carbon production equipment
Tail gas is contacted.
Above-mentioned absorber, the absorber include absorber ontology, and the accommodation space is located at the absorber ontology
Inside, the absorber gas access and the absorber gas vent are set on the absorber ontology, the absorption
It is additionally provided with inlet port and outlet port on device ontology;Further include the belt conveyer with conveyer belt, is set to the absorber ontology
The accommodation space in;Wherein, the belt conveyer is for receiving the Activated Carbon Production entered from the feed inlet
Raw material, and the absorber ontology, the activated carbon life is discharged in the Activated Carbon Production feedstock transportation to the discharge outlet
Production raw material is contacted during conveying with the tail gas of entrance, and is obstructed to the flowing of the tail gas.
Above-mentioned absorber, the absorber further include feeding warehouse, are set at the feed inlet;Limiting device is set to institute
It states at feeding warehouse or the feed inlet, for being coordinated with the belt conveyer, limitation is positioned at the belt conveyer
The thickness of the Activated Carbon Production raw material on the conveyer belt.
Above-mentioned absorber, the limits device are coordinated with the belt conveyer, for that will be located at the belt
The thickness of the Activated Carbon Production raw material is limited to 100-1000mm on the conveyer belt of conveyer;The belt conveyer
Described conveyer belt one end is located at the feed inlet, and the other end is located at the discharge outlet, and the belt conveyer is according to
Feed inlet controls conveying speed at a distance from the discharge port so that the Activated Carbon Production raw material stops on the conveyor belt
The time is stayed to be:1-5h.
Above-mentioned absorber further includes spiral discharging machine, is located at the discharge outlet, the work for that will adsorb pollutant
Property charcoal raw materials for production the absorber ontology is discharged.
The present invention has the following advantages compared with the prior art:
1. the present invention is a kind of method of purification and the comprehensive utilization of active carbon by chemical method production tail gas, including following step
Suddenly:Activated Carbon Production raw material is contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production
Raw material is adsorbed and is recycled to the pollutant that can be used for Activated Carbon Production in the tail gas.Due to the tail gas, i.e. exhaust gas
The middle major part pollutant be in aerosol state or by steam carry secretly etc. unstable states, it is straight using Activated Carbon Production raw material
Connecing the technique contacted with gas can make the purification of pollutant described in the tail gas and the rate of recovery higher, i.e., finally inhaled
Be attached to the pollutant on Activated Carbon Production raw material with from the pollutant in the tail gas being discharged in active carbon production equipment
Ratio between amount is larger.
At least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar contained in pollutant pollutant passes through this
After method is recycled, obtained Activated Carbon Production raw material can be directly used for the production of consequent activities charcoal, will not cause the pollution
Object wastes, while will not cause secondary pollution, wherein is adsorbed at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar
The Activated Carbon Production raw material of pollutant, can be used in process for preparing activated carbon;And the wood adsorbed by Activated Carbon Production raw material is burnt
It is oily then can be further used as Activated Carbon Production raw material for consequent activities charcoal production.
Meanwhile this method is simple for process, equipment is uncomplicated, operating cost is low, is easy to promote in activated carbon industry.
2. the initial temperature of the Activated Carbon Production tail gas is 30~250 DEG C, active carbon by chemical method production can be conducive to
Absorption of the raw material at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar pollutant.
3. the exhaust temperature being passed into the absorber is 60-240 DEG C, it can directly be conducive to high temperature production tail gas pair one
A little moist Activated Carbon Production raw materials are dried, and reduce the moisture contained in Activated Carbon Production raw material, so that dry
And Activated Carbon Production raw material that adsorbed at least one of phosphoric acid, hydrogen chloride, zinc chloride and wood tar pollutant can be direct
It is applied in consequent activities charcoal producing technique, i.e., the present invention purifies the pollutant in the tail gas and recycling tail gas for subsequently living
Property charcoal production reduce pair relative to vent gas treatment and consequent activities charcoal producing technique is carried out using spray process in the prior art
Activated Carbon Production raw material drying technique saves production cost to simplify entire processing step.
4. the usual volume of active carbon production equipment in the prior art is larger, and the volume of absorber is generally also larger, inhales
Adnexa would generally be arranged far from the active carbon production equipment, and Activated Carbon Production tail gas needs to transmit by pipeline, existing skill
The device that tail gas is used for transmission in art is usually metallic conduit, and this pipeline can lead to gas during exporting high-temperature gas
Temperature rapid drawdown.The tail gas given off from the active carbon production equipment is kept into trip temperature by temperature holding meanss
The step of so that from the tail gas of temperature holding meanss output and between the tail gas of the temperature holding meanss
Temperature drop be less than 30%.It can be effectively prevented from because being exported tail gas to the process of absorber from active carbon production equipment
In, because exhaust temperature rapid drawdown causes to be cooled to liquid, Wu Fatong by pollutants such as chemical activating agents that steam is carried secretly in tail gas
It crosses steam to be brought into the absorber, compares from activated carbon and give birth to so as to cause the chemical activation dosage that absorber is touched
The amount being discharged in production equipment has larger reduction, closely leads to the rate of recovery for carrying out chemical activating agent recycling to tail gas using absorber
The technical issues of being greatly reduced.By the way that temperature drop control in the numberical range less than 30%, can be avoided this significantly
Kind technical problem, it is ensured that the rate of recovery is allowed to be in a higher level.
5. being heated to the tail gas given off from the active carbon production equipment by heating device, on the one hand
Can to avoid mentioning in the 4th point in tail gas transmission process, because of technical problem caused by temperature decrease, can also improve into
The temperature for entering the tail gas into absorber, so as to which further moist Activated Carbon Production raw material is dried,
Promote subsequently directly obtain the preferably dry Activated Carbon Production raw material for being adsorbed with chemical activating agent.
It, can be more efficiently to Activated Carbon Production original 6. the exhaust temperature being passed into the absorber is 60-240 DEG C
Material is dried, and promotes subsequently directly obtain the preferably dry Activated Carbon Production raw material for being adsorbed with chemical activating agent.
7. being passed into 100-230 DEG C of the exhaust temperature in the absorber, the above-mentioned 4th can be more effectively avoided
Technical problem in point can also more effectively be dried Activated Carbon Production raw material, promote subsequently directly obtain
The preferably dry Activated Carbon Production raw material for being adsorbed with the pollutant that can be used for Activated Carbon Production.
8. the initial temperature of the tail gas is 30-90 DEG C, the tail gas heating is heated up at least by the heating device
20%, it can be effectively prevented from the technical problem in above-mentioned 4th point as a kind of more preferably embodiment, it can also be more
Effectively Activated Carbon Production raw material is dried, promotes subsequently directly obtain being adsorbed with including institute for preferably drying
State the Activated Carbon Production raw material for the pollutant that can be used for Activated Carbon Production.
9. the recovery system of the present invention, including:Absorber is equipped with Activated Carbon Production raw material, has absorber gas access
With absorber gas vent, the absorber gas access is connected to the offgas outlet of active carbon production equipment, for making activity
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment.This design can improve to tail gas in can
While the rate of recovery for the pollutant of Activated Carbon Production, equipment is greatly simplified, reduces process costs, and environmental protection can be reached
Effect.
10. the absorber includes absorber ontology, the absorber gas access and the absorber gas vent are set
In on the absorber ontology, inlet port and outlet port are additionally provided on the absorber ontology;Further include with conveyer belt
Belt conveyer, be set to the absorber body interior;Wherein, the belt conveyer for receive from the feed inlet into
The Activated Carbon Production raw material entered, and the absorber is discharged in the Activated Carbon Production feedstock transportation to the discharge outlet
Ontology, the Activated Carbon Production raw material are contacted during conveying with the tail gas of entrance, and to the tail gas
Flowing is obstructed.It can be designed so that pollutant described in the tail gas being passed on the Activated Carbon Production raw material above
It is intercepted and is adsorbed by the Activated Carbon Production raw material.
11. the recovery system of the present invention, wherein be located at the thickness of the Activated Carbon Production raw material on the conveyer belt
For:100-1000mm;Flow velocity into the tail gas of the absorber is:0.1-0.8m/s;The material is on the conveyor belt
Residence time is:1-5h.It not only can be effectively so that the Activated Carbon Production raw material be to the pollutant in the tail gas
It is obstructed and is adsorbed, and more Activated Carbon Production raw material can be made to be adsorbed with the pollutant, obtain more having
The Activated Carbon Production raw material of adsorbate is used for subsequent Activated Carbon Production.
Description of the drawings
In order to make the content of the present invention more clearly understood, it below according to specific embodiments of the present invention and combines
Attached drawing, the present invention is described in further detail, wherein
Fig. 1 is the schematic diagram of the recovery system of one of which embodiment of the present invention;
Fig. 2 is a kind of schematic diagram of the recovery system of preferred embodiment of the present invention;
Fig. 3 is a kind of schematic diagram of the recovery system of more preferable embodiment of the present invention;
Fig. 4 is a kind of schematic diagram of the recovery system of more preferable embodiment of the present invention.
Fig. 5 is the schematic diagram of absorber of the present invention;
1- active carbon production equipments;2- absorbers;3- temperature holding meanss;4- Activated Carbon Production raw materials;5- wind turbines;6- adds
Thermal;7- feeding warehouses;8- absorbers gas access;9- belt conveyers;10- spiral discharging machines;11- conveyer belts;12- is accommodated
Space 13- feed inlets, 14- slag-drip openings;15- absorber ontologies.
Specific implementation mode
Embodiment 1
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
It can be used for being adsorbed and being recycled for the pollutant of Activated Carbon Production in tail gas, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 30 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..
Embodiment 2
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail
Gas is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 40 DEG C.The Activated Carbon Production is former
Material is preferably carbon containing plant crushed material, and the carbon containing plant crushed material includes furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell
At least one of crushed material and sawdust etc..
Embodiment 3
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 50 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..
Embodiment 4
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 60 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..
Embodiment 5
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 70 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 60 DEG C.
Embodiment 6
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 80 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 70 DEG C.
Embodiment 7
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 90 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 80 DEG C.
Embodiment 8
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 100 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 90 DEG C.
Embodiment 9
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 105 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 100 DEG C.
Embodiment 10
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 110 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 100 DEG C.
Embodiment 11
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 120 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 110 DEG C.
Embodiment 12
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 150 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 130 DEG C.
Embodiment 13
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 160 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 150 DEG C.
Embodiment 14
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 180 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 160 DEG C.
Embodiment 15
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 240 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 230 DEG C.
Embodiment 16
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method, include the following steps:It will be active
Charcoal raw materials for production are contacted with the tail gas given off in active carbon production equipment, so that Activated Carbon Production raw material is to described
The pollutant that can be used for Activated Carbon Production in tail gas is adsorbed and is recycled, wherein the pollutant includes phosphoric acid, chlorination
At least one of hydrogen, zinc chloride and wood tar.The Activated Carbon Production raw material is preferably placed in absorber, the tail gas
It is input into the absorber and is adsorbed.The initial temperature of the tail gas is preferably 250 DEG C.The Activated Carbon Production raw material
Preferably carbon containing plant crushed material, the carbon containing plant crushed material include furfural dregs, bagasse, tangerine bar crushed material, fruit stone shell powder
At least one of mince with sawdust etc..The exhaust temperature being passed into the absorber is 240 DEG C.
Embodiment 17
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method are in any of the above-described kind of embodiment
On the basis of, further include to the tail gas that is given off from the active carbon production equipment by temperature holding meanss into trip temperature
The step of holding so that the tail gas exported from the temperature holding meanss and the tail for entering the temperature holding meanss
Temperature drop between gas is less than 30%.The temperature drop=(temperature of the tail gas of temperature value-output of the tail gas of input
Value)/input the tail gas temperature value, the unit of the temperature value is degree Celsius.The thickness of the Activated Carbon Production raw material
For:100-1000mm;Flow velocity into the tail gas of the absorber is:0.1-0.8m/s;The material is on the conveyor belt
Residence time is:1-5h.The thickness of the Activated Carbon Production raw material, the flow velocity of the tail gas stop on the conveyor belt with the material
Staying time coordination that the pollutant in tail gas may be implemented can be obstructed by the Activated Carbon Production raw material, and other gases can
To pass through the Activated Carbon Production raw material to be discharged.
Embodiment 18
A kind of purification of active carbon by chemical method production tail gas of the present invention and recovery method are in any one implementation of embodiment 1-3
On the basis of example, further include:The tail gas given off from the active carbon production equipment is added by heating device
Heat.The tail gas heating is more preferably preferably heated to 100-230 DEG C to 60-240 DEG C.
When the initial temperature of the tail gas is 30-90 DEG C, as another more preferable embodiment, pass through the heating
Device by the tail gas heating heat up at least 20%.The percentage calculation mode is:(the temperature value-of the tail gas after heating
The temperature value of the tail gas before heating) tail gas before/heating temperature value, the unit of the temperature value is degree Celsius.
Embodiment 19
As shown in Figure 1, purification and the recovery system of a kind of active carbon by chemical method production tail gas of the present invention, including:Absorption
Device 2 is equipped with Activated Carbon Production raw material 4, and there is absorber gas access and absorber gas vent, 2 gas of the absorber to enter
Mouth is connected to the offgas outlet of active carbon production equipment 1.It preferably comprises:There is temperature holding meanss 3 holding meanss gas to enter
Mouth and holding meanss gas vent are set between the active carbon production equipment 1 and the absorber 2, wherein the holding meanss
Gas access is connected to the offgas outlet of the active carbon production equipment 1, the holding meanss gas vent and the absorber
Gas access is connected to;The tail gas for export from the temperature holding meanss and the entrance temperature holding meanss
Temperature drop between the tail gas is less than 30%.The temperature drop=(tail gas of temperature value-output of the tail gas of input
Temperature value)/input the tail gas temperature value, the unit of the temperature value is degree Celsius.
Preferably, as shown in Fig. 2, can also include:Wind turbine 5, be set to the active carbon production equipment 1 with
It between the absorber 2, is preferably set between the active carbon production equipment and the temperature holding meanss, is used for the tail gas
It drives in the absorber 2.As another alternative embodiments, after the wind turbine can also be set to the absorber
End, for discharge after the tail gas is introduced into the absorber.
In addition, as an improvement embodiment, can also include:Further include controller of fan, for the wind
The output power of machine carries out constant control.
Embodiment 20
As shown in figure 3, purification and the recovery system of a kind of active carbon by chemical method production tail gas of the present invention, including:Absorption
Device 2 is equipped with Activated Carbon Production raw material 4, has absorber gas access and absorber gas vent, the absorber gas access
It is connected to the offgas outlet of active carbon production equipment 1.Preferably further include:Heating device 6, have heating device gas access and
Heating device gas vent is set between the active carbon production equipment 1 and the absorber 2, for being passed into the absorption
2 pervious tail gas of device is heated.Can also include:Wind turbine 5 is set to the active carbon production equipment 1 and the absorber 2
Between, it is preferably set between heating device 6 and the absorber 2, for driving in the tail gas in the absorber 2.As another
A kind of alternative embodiments, the wind turbine can also be set to the rear end of the absorber, described in introducing the tail gas
Discharge after in absorber.
Preferably further include temperature-detecting device (not shown), is provided close at the heating device gas access, is used for
The tail gas to entering the heating device carries out temperature detection and obtains temperature information, and the heating device is according to the temperature
The temperature information that detection device detects controls the heating power of the heating device, when the heating device is preferably when described
The initial temperature of tail gas be 30-90 DEG C when, by the heating device by the tail gas heating heat up at least 20%.
In addition, as an improvement embodiment, can also include:Controller of fan, for the defeated of the wind turbine
Go out power and carries out constant control.
Embodiment 21
As shown in figure 4, purification and the recovery system of a kind of active carbon by chemical method production tail gas of the present invention, including:Absorption
Device 2 has the accommodation space 12 for accommodating Activated Carbon Production raw material 4, and there is absorber gas access to go out with absorber gas
Mouthful, the absorber gas access is connected to the offgas outlet of active carbon production equipment, for making Activated Carbon Production raw material and work
The tail gas given off in property charcoal production equipment is contacted.It preferably comprises:Heating device 6 has heating device gas access
With heating device gas vent, it is set between the active carbon production equipment and the absorber, for being passed into the absorption
2 pervious tail gas of device is heated.
Preferably further include:Temperature holding meanss 4 have holding meanss gas access and holding meanss gas vent, if
Between the active carbon production equipment 1 and the absorber 2, wherein given birth to the activated carbon holding meanss gas access
Produce the offgas outlet connection of equipment 1, the holding meanss gas vent be connected to the absorber gas access, be used to make from
Temperature drop between the tail gas and the tail gas for entering the temperature holding meanss of the temperature holding meanss output is less than
30%.
Can also include:At least two wind turbines 5, are respectively arranged between the active carbon production equipment and the absorber and set
In the absorber rear end, for keeping pressure balance before and after the absorber.
Preferably further include temperature-detecting device (not shown), is provided close at the heating device gas access, is used for
The tail gas to entering the heating device carries out temperature detection and obtains temperature information, and the heating device is according to the temperature
The temperature information that detection device detects controls the heating power of the heating device, when the heating device is preferably when described
The initial temperature of tail gas be 30-90 DEG C when, by the heating device by the tail gas heating heat up at least 20%.The percentage
Calculation is:The tail before (temperature value of the tail gas before temperature value-heating of the tail gas after heating)/heating
The unit of the temperature value of gas, the temperature value is degree Celsius.
In addition, as an improvement embodiment, can also include:Controller of fan, for the defeated of the wind turbine
Go out power and carries out constant control.
As another improved embodiment, as shown in figure 5, the purification and recovery system of the present embodiment, wherein described
Absorber includes absorber ontology 15, and the accommodation space 12 is located at the inside of the absorber ontology 15, the absorber gas
Body entrance 8 and the absorber gas vent (not marking herein) are set on the absorber ontology 15, the absorber
Feed inlet 13 and discharge port (not shown) are additionally provided on ontology 15;Further include the belt conveyer 9 with conveyer belt 11, is set to institute
It states in the accommodation space 12 of absorber ontology 15;Wherein, the belt conveyer 9 for receive from the feed inlet 13 into
The Activated Carbon Production raw material 4 entered, and the Activated Carbon Production raw material 4 is delivered to the discharge outlet, the absorption is discharged
Device ontology 15, the Activated Carbon Production raw material 13 are contacted during conveying with the tail gas of entrance, wherein in order to
Realize contact, the tail gas enter the absorber flow direction can the relatively described Activated Carbon Production raw material movement it is flat
Row is vertical;Preferably, the Activated Carbon Production raw material can realize that the flowing to the tail gas obstructs, to tail gas described in this
It is the direction of motion perpendicular to the Activated Carbon Production raw material into the preferable flow rate direction of the absorber, and flows to the work
Property charcoal raw materials for production, more preferably, the absorber gas access is set to right over the absorber ontology, and the tail gas is from upper
The Activated Carbon Production raw material is flowed under.In addition, it includes feeding warehouse 7 that the absorber, which is also preferably, it is set to the feed inlet
At 13;Limiting device (does not mark) herein, is set at the feeding warehouse 7 or the feed inlet, is used for and the belt conveyer 9
Coordinated, the thickness of limitation Activated Carbon Production raw material 4 on the conveyer belt 11 of the belt conveyer.
Present invention purification and recovery system, the limits device are coordinated with the belt conveyer, being used for will
The thickness of the Activated Carbon Production raw material is limited to 100-1000mm on the conveyer belt of the belt conveyer;It is described
Described conveyer belt one end of belt conveyer is located at the feed inlet, and the other end is located at the discharge outlet, and the belt is defeated
Material machine controls conveying speed at a distance from the discharge port according to the feed inlet so that the Activated Carbon Production raw material
The residence time is on the conveyor belt:1-5h, the controller of fan are suitable for that the flow velocity of the tail gas of the absorber will be entered
Control is:0.1-0.8m/s.
The residence time matches on the conveyor belt with the material for the thickness of the Activated Carbon Production raw material, the flow velocity of the tail gas
Closing the pollutant that may be implemented in tail gas can be obstructed by the Activated Carbon Production raw material, and other gases can pass through institute
Activated Carbon Production raw material is stated to be discharged.The discharge outlet is also further provided with spiral discharging machine 10, described for that will be adsorbed with
The discharge port is discharged in the Activated Carbon Production raw material of pollutant.The absorber bottoms are additionally provided with slag-drip opening 14.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.