CN105585977B - It is a kind of to improve gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof - Google Patents
It is a kind of to improve gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof Download PDFInfo
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- CN105585977B CN105585977B CN201510967319.6A CN201510967319A CN105585977B CN 105585977 B CN105585977 B CN 105585977B CN 201510967319 A CN201510967319 A CN 201510967319A CN 105585977 B CN105585977 B CN 105585977B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
Gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof is improved the invention discloses a kind of, adhesive Formulation Ingredients mainly include：EPDM elastomeric compounds, phenolic resin, isocyanates, gasoline.EPDM elastomeric compounds are formed by ethylene propylene diene rubber 4045, DCP, sulphur, altax, accelerator TT, zinc oxide ZnO, stearic acid StA, carbon black, white carbon, paraffin oil, anti-aging agent RD mixing.It is 100 by EPDM elastomeric compounds, phenolic resin, isocyanates and gasoline weight ratio：5‑10：0‑3：1000 are made adhesive, can effectively improve the bonding strength of EPDM rubber and polyester line, environmental pollution is small, and preparation technology is simple, practical.
Description
Technical field
The present invention relates to a kind of gluing agent prescription, and in particular to the adhesive that a kind of raising EPDM rubber is bonded with polyester line
Formula and preparation method thereof.
Background technology
EPDM rubber is by the non-polar rubber of ethene, propylene and a small amount of non-conjugated diene hydrocarbon copolymerization.Because of its master
Chain is made up of chemically stable saturated hydrocarbons, only contains unsaturated double-bond in side chain, therefore its resistance to ozone, heat-resisting, weather-proof etc. are resistance to
Ageing properties are excellent, can be widely used for the fields such as auto parts and components, electric wire and cable jacket, sebific duct, adhesive tape.But EPDM rubber point
Nonpolarity substituent in sub, intermolecular cohesive energy is low, causes the tack and mutual viscosity of EPDM rubber poor, with other skeletons
Bonding force is also very poor.At present, people are made corresponding metal salt, are then added in rubber by acrylic acid modified, in vulcanization
In play a part of metal adhesion promoters, this auxiliary agent can realize the direct bonding of EPDM rubber and metal, but bonding
Effect is poor.There is document report to add RS/A adhesives in EPDM rubber, select suitable vulcanizing system, EPDM can be solved
With vinylon line adhesion problem, but the bonding for polyester line not yet has been reported that.
The content of the invention
The invention aims to the adhesion problem for solving EPDM rubber and polyester line, there is provided one kind raising EPDM rubbers
Gluing agent prescription that glue is bonded with polyester line and preparation method thereof, by adding phenolic resin, isocyanates in adhesive,
Coordinate appropriate vulcanizing system, improve the bonding force of EPDM rubber and polyester line.
It is a kind of to improve gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof, adhesive Formulation Ingredients bag
Include following parts by weight component：
EPDM elastomeric compounds：100；
Phenolic resin：3-10；
Isocyanates：0-5；
Gasoline：1000.
Described EPDM elastomeric compounds are formed by the mixing of following percentage by weight raw material：
Ethylene propylene diene rubber 4045：100；
Vulcanizing agent DCP：0.5-4.0；
Sulphur：0.5-2.0；
Altax：0.6-1.8；
Accelerator TT：0.5-2.0；
Zinc oxide ZnO：5-10；
Stearic acid StA：1.0-2.5；
Carbon black：40-80；
White carbon：10-20；
Paraffin oil：5-20；
Anti-aging agent RD：1.0-2.0.
Described phenolic resin is resorcinol-formaldehyde resin；Described vulcanizing agent DCP is cumyl peroxide；Institute
The altax stated is two thio benzothiazoles；Described accelerator TT is two thio tetra methylthiurams；Described age resistor
RD is 4- trimethyl -1,2- dihyaroquinolines；Described carbon black be N330, N550, spray carbon black, N990, N774 any one
Or several compositions.
It is a kind of to improve gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof, including EPDM elastomeric compound systems
Preparation Method and adhesive preparation method, be specially：
EPDM elastomeric compound preparation methods, comprise the following steps:
Step one：The auxiliary agent and vulcanizing agent in ethylene propylene diene rubber 4045, formula, the auxiliary agent are weighed by ratio of weight and the number of copies
For zinc oxide ZnO, stearic acid StA, carbon black, white carbon, paraffin oil, anti-aging agent RD；The vulcanizing agent is DCP, sulphur, accelerator
DM, accelerator TT, auxiliary agent and vulcanizing agent are well mixed respectively.
Step 2：Ethylene propylene diene rubber is plasticated in banbury, then added well mixed auxiliary agent in banbury
Banburying, finally adds back mixing after vulcanizing agent thin logical 6-12 times on a mill.
Adhesive preparation method, comprises the following steps:
EPDM elastomeric compounds are dissolved in gasoline and stir 24-48h, phenolic resin and isocyanates stirring 6-12h are added extremely
Uniform state.
Embodiment
With reference to embodiment, the present invention is described in further detail, but this should not be interpreted as to the present invention
The scope of above-mentioned theme is only limitted to following embodiments.
Embodiment 1：
4,045 100 parts of ethylene propylene diene rubber is first weighed by ratio of weight and the number of copies；Auxiliary agent：5 parts of zinc oxide ZnO, stearic acid StA
1 part, 60 parts of carbon black, 10 parts of white carbon, 5 parts of paraffin oil, 1 part of anti-aging agent RD；Vulcanizing agent：2 parts of DCP, 0.5 part of sulphur, promotion
0.6 part of agent DM, 1.5 parts of accelerator TT；Auxiliary agent and vulcanizing agent are well mixed respectively.Then by ethylene propylene diene rubber in banburying
Plasticated in machine, well mixed auxiliary agent is then added into banburying in banbury, back mixing after vulcanizing agent is finally added on a mill
It is thin logical 6-12 times.
EPDM elastomeric compound 200g are taken, 2000g gasoline stirring and dissolving 24h are added, phenolic resin 10g are added, stirring 6h is extremely
Uniformly.
Embodiment 2：
4,045 100 parts of ethylene propylene diene rubber is first weighed by ratio of weight and the number of copies；Auxiliary agent：5 parts of zinc oxide ZnO, stearic acid StA
1 part, 60 parts of carbon black, 10 parts of white carbon, 5 parts of paraffin oil, 1 part of anti-aging agent RD；Vulcanizing agent：2 parts of DCP, 0.5 part of sulphur, promotion
0.6 part of agent DM, 1.5 parts of accelerator TT；Auxiliary agent and vulcanizing agent are well mixed respectively.Then by ethylene propylene diene rubber in banburying
Plasticated in machine, well mixed auxiliary agent is then added into banburying in banbury, back mixing after vulcanizing agent is finally added on a mill
It is thin logical 6-12 times.
EPDM elastomeric compound 200g are taken, 2000g gasoline stirring and dissolving 24h is added, adds phenolic resin 10g, isocyanates
1g, 6h is to uniform for stirring.
Embodiment 3：
4,045 100 parts of ethylene propylene diene rubber is first weighed by ratio of weight and the number of copies；Auxiliary agent：10 parts of zinc oxide ZnO, stearic acid
1 part of StA, 60 parts of carbon black, 20 parts of white carbon, 5 parts of paraffin oil, 1 part of anti-aging agent RD；Vulcanizing agent：4 parts of DCP, 0.5 part of sulphur,
0.6 part of altax, 1.5 parts of accelerator TT；Auxiliary agent and vulcanizing agent are well mixed respectively.Then ethylene propylene diene rubber is existed
Plasticated in banbury, well mixed auxiliary agent is then added into banburying in banbury, finally added on a mill after vulcanizing agent
Back mixing is thin logical 6-12 times.
EPDM elastomeric compound 200g are taken, 2000g gasoline stirring and dissolving 24h is added, adds phenolic resin 10g, isocyanates
1g, 6h is to uniform for stirring.
Embodiment 4：
4,045 100 parts of ethylene propylene diene rubber is first weighed by ratio of weight and the number of copies；Auxiliary agent：5 parts of zinc oxide ZnO, stearic acid StA
1 part, 60 parts of carbon black, 10 parts of white carbon, 5 parts of paraffin oil, 1 part of anti-aging agent RD；Vulcanizing agent：2 parts of DCP, 0.5 part of sulphur, promotion
0.6 part of agent DM, 1.5 parts of accelerator TT；Auxiliary agent and vulcanizing agent are well mixed respectively.Then by ethylene propylene diene rubber in banburying
Plasticated in machine, well mixed auxiliary agent is then added into banburying in banbury, back mixing after vulcanizing agent is finally added on a mill
It is thin logical 6-12 times.
EPDM elastomeric compound 200g are taken, 2000g gasoline stirring and dissolving 24h is added, adds phenolic resin 10g, isocyanates
6g, 6h is to uniform for stirring.
The H that adhesive prepared by embodiment 1-4 is used for EPDM rubber and polyester line extracts experiment, experimental result such as table 1 out
It is shown.
Comparative example 1 is that the H of the EPDM rubber and polyester line that are not added with adhesive extracts experimental result out.
The embodiment 1-4 of table 1 and the H extraction forces of comparative example 1
The above-described embodiments are merely illustrative of preferred embodiments of the present invention, not to the structure of the present invention
Think and scope is defined, under the premise of design concept of the present invention is not departed from, ordinary skill technical staff is to this hair in this area
The all variations and modifications that bright technical scheme is made, all should fall into protection scope of the present invention, claimed skill of the invention
Art content has all been recorded in detail in the claims.
Claims (3)
1. a kind of improve the adhesive that EPDM rubber is bonded with polyester line, it is characterised in that adhesive
Composition includes following parts by weight component：
EPDM elastomeric compounds：100 parts；
Phenolic resin：3-10；
Isocyanates：0-5；
Gasoline：1000；
Described EPDM elastomeric compounds are formed by the mixing of following parts by weight raw material；
Ethylene propylene diene rubber 4045：100
Vulcanizing agent DCP：0.5-4.0；
Sulphur：0.5-2.0；
Altax：0.6-1.8；
Accelerator TT：0.5-2.0；
Zinc oxide ZnO：5-10；
Stearic acid StA：1.0-2.5；
Carbon black：40-80；
White carbon：10-20；
Paraffin oil：5-20；
Anti-aging agent RD：1.0-2.0.
2. a kind of adhesive for improving EPDM rubber and the bonding of polyester line according to claim 1, it is characterised in that described
Phenolic resin be resorcinol-formaldehyde resin.
3. a kind of method for preparing the adhesive any one of claim 1 and 2, it is characterised in that including EPDM mixings
Glue preparation method and adhesive preparation method, specifically include following steps：
(1) EPDM elastomeric compounds preparation method, comprises the following steps:
Step one：The auxiliary agent and vulcanizing agent in ethylene propylene diene rubber 4045, formula are weighed by ratio of weight and the number of copies, and the auxiliary agent is oxygen
Change zinc ZnO, stearic acid StA, carbon black, white carbon, paraffin oil, anti-aging agent RD；The vulcanizing agent be DCP, sulphur, altax,
Accelerator TT, auxiliary agent and vulcanizing agent are well mixed respectively；
Step 2：Ethylene propylene diene rubber is plasticated in banbury, well mixed auxiliary agent is then added into banburying in banbury,
It is thin logical 6-12 times that back mixing after vulcanizing agent is finally added on a mill；
(2) adhesive preparation method, comprises the following steps:
EPDM elastomeric compounds are dissolved in gasoline and stir 24-48h, phenolic resin and isocyanates is added and stirs 6-12h to uniform
State.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510967319.6A CN105585977B (en) | 2015-12-21 | 2015-12-21 | It is a kind of to improve gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510967319.6A CN105585977B (en) | 2015-12-21 | 2015-12-21 | It is a kind of to improve gluing agent prescription that EPDM rubber is bonded with polyester line and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105585977A CN105585977A (en) | 2016-05-18 |
| CN105585977B true CN105585977B (en) | 2017-10-13 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318268B (en) * | 2016-10-18 | 2018-09-18 | 南京利德东方橡塑科技有限公司 | A kind of adhesive and preparation method thereof improving neoprene and the bonding of polyester line |
| CN108659744B (en) * | 2018-06-04 | 2021-02-02 | 南京利德东方橡塑科技有限公司 | Environment-friendly EPDM adhesive for improving adhesion between ethylene propylene diene monomer and cord thread |
| CN115304869A (en) * | 2022-07-26 | 2022-11-08 | 高科橡塑工业有限公司 | Ethylene propylene diene monomer rubber compound for high-adhesion and high-tear-resistance rubber roll and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008034591A1 (en) * | 2006-09-20 | 2008-03-27 | Arizona Chemical Company | Rubber compositions with building tack |
| CN102337092A (en) * | 2011-07-22 | 2012-02-01 | 北京化工大学 | Adhesive layer rubber material for high-temperature-resistant canvas conveyor belt and using method thereof |
| CN103467862A (en) * | 2013-08-22 | 2013-12-25 | 浙江双箭橡胶股份有限公司 | Formula of environment-friendly high-temperature-resisting fabric core rubber conveyer belt and processing technology |
| CN104650766A (en) * | 2014-12-17 | 2015-05-27 | 浙江科达利实业有限公司 | Reactive adhesive sizing material and preparation process thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5420386B2 (en) * | 2009-12-04 | 2014-02-19 | 日東電工株式会社 | EPDM foam, manufacturing method thereof and sealing material |
-
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- 2015-12-21 CN CN201510967319.6A patent/CN105585977B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008034591A1 (en) * | 2006-09-20 | 2008-03-27 | Arizona Chemical Company | Rubber compositions with building tack |
| CN102337092A (en) * | 2011-07-22 | 2012-02-01 | 北京化工大学 | Adhesive layer rubber material for high-temperature-resistant canvas conveyor belt and using method thereof |
| CN103467862A (en) * | 2013-08-22 | 2013-12-25 | 浙江双箭橡胶股份有限公司 | Formula of environment-friendly high-temperature-resisting fabric core rubber conveyer belt and processing technology |
| CN104650766A (en) * | 2014-12-17 | 2015-05-27 | 浙江科达利实业有限公司 | Reactive adhesive sizing material and preparation process thereof |
Non-Patent Citations (2)
| Title |
|---|
| 橡胶和纤维的粘合――耐热输送带;张虹;《世界橡胶工业》;20020630;第29卷(第3期);第30-34页 * |
| 浅谈橡胶与纤维骨架材料的粘合;李璐等;《中国胶粘剂》;20070831;第16卷(第8期);第36-40页 * |
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