CN105585935A - Solvent-free high-solid ocean anti-fouling paint - Google Patents
Solvent-free high-solid ocean anti-fouling paint Download PDFInfo
- Publication number
- CN105585935A CN105585935A CN201510395089.0A CN201510395089A CN105585935A CN 105585935 A CN105585935 A CN 105585935A CN 201510395089 A CN201510395089 A CN 201510395089A CN 105585935 A CN105585935 A CN 105585935A
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- Prior art keywords
- solvent
- free high
- ocean
- high solid
- free
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Links
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 25
- 239000003973 paint Substances 0.000 title claims abstract description 24
- 239000007787 solid Substances 0.000 title claims abstract description 23
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 46
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 23
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229940112669 cuprous oxide Drugs 0.000 claims abstract description 23
- 239000003822 epoxy resin Substances 0.000 claims abstract description 23
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 23
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 23
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 23
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 23
- 239000011787 zinc oxide Substances 0.000 claims abstract description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 44
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 18
- 238000000576 coating method Methods 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 150000001261 hydroxy acids Chemical class 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 238000007689 inspection Methods 0.000 claims description 8
- 238000004806 packaging method and process Methods 0.000 claims description 8
- 238000012856 packing Methods 0.000 claims description 8
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 241000238586 Cirripedia Species 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 231100000614 poison Toxicity 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 239000002519 antifouling agent Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000251557 Ascidiacea Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241001269238 Data Species 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- 241001541122 Linguatula serrata Species 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides solvent-free high-solid ocean anti-fouling paint. The solvent-free high-solid ocean anti-fouling paint is characterized by being prepared from epoxy resin, cuprous oxide, sodium benzoate, glycidyl ether, zinc oxide, polyethylene wax and polyether amine according to the weight ratio of (40-60):(25-35):(2.5-10):(2.5-5):(5-10):(3-6):(20-30). The solvent-free high-solid ocean anti-fouling paint is low in manufacturing cost, free of a solvent, long in storage time, good in stability, free of VOC volatilization during use, resistant to water and abrasion, smooth and hard; ocean organisms can be hardly attached to the surface of a hull, and the advantages that contamination of the ocean organisms such as barnacle to a hull bottom is prevented for a long time, smoothness of the hull bottom is kept, the ocean organisms are not killed with poisons, and the ocean environment is protected.
Description
Technical field
The present invention relates to a kind of antifouling paint, relate in particular to a kind of solvent-free high solid marine antifouling coating.
Background technology
In marine environment, when object immerses after seawater, first its surface occurs miniature stained, and the miniature organism such as bacterium is attached on body surface, and grows thereon, breeds; Subsequently, the spore of macro and oceanic invertebrate are attached on body surface as the young of barnacle, mussel and Ascidian, and this process is called as large-scale stained. Large-scalely stainedly can be further divided into again soft stainedly and rigid stained, soft stained to refer to that the biologies such as algae, careless tongue worm, Ascidian, hydra cause stained, the rigid stained biology that refers to secretion calcium carbonate shell as barnacle and extra large oyster etc. cause stained. These marine fouling organisms are attached to hull facility surface, can strengthen ship resistance, blocking pipe and cultivation netting gear, affect the serious harms such as the normal use of acoustic instrument and other offshore set-ups, the burden that increases offshore oil and natural gas extraction platform, acceleration metal erosion, cause the massive losses of ocean military activity, sea transport, industry and aquaculture production.
Up to now, solving most economical, the effective and conventional method of marine biofouling is the coating containing marine antifoulant in marine equipment surface brushing, its Main Function is by the key component in coating---the mode such as the oozing out of marine antifoulant, diffusion or hydrolysis progressively discharges anti-fouling agent, reaches and prevents that marine fouling organism is attached to the object on marine Artificial facilities surface. Current marine antifoulant kind is most of containing heavy metal, the stronger toxicity of tool, Marine Pollution ecological environment, and spot ship antifouling paint preparation cost is high, to shortcomings such as large, the antifouling persistence of environmental hazard are poor.
Summary of the invention
For overcoming the deficiencies in the prior art; the invention provides a kind of new anti-fouling agent,, containing solvent, period of storage is not long; good stability; the volatilization of use VOC free, water-fast, wear-resisting, smooth hard, make the biology of ocean be difficult to be attached to hull surface; have and prevent for a long time stained to hull bottom of the marine organisms such as barnacle; keep hull bottom bright and clean, also to marine organisms without poisoning, protected the environment of ocean.
The technical scheme that the present invention deals with problems is, a kind of solvent-free high solid marine antifouling coating, it is characterized in that: be made up of epoxy resin, cuprous oxide, Sodium Benzoate, glycidol ether, zinc oxide, Tissuemat E and polyetheramine, the weight ratio of each component is 40-60:25-35:2.5-10:2.5-5:5-10:3-6:20-30.
Wherein add unsaturated polynary hydroxy acid polymer, its weight ratio of iron oxide red is 0.6-2:5-10, forms solvent-free high solid ocean ship bottom antifouling paint.
Wherein add unsaturated polynary hydroxy acid polymer, its weight ratio of titanium dioxide is 0.6-2:10-20, forms solvent-free high solid ocean shell antifouling paint.
Wherein adding unsaturated polynary hydroxy acid polymer, titanium dioxide, its weight ratio of mica powder is 0.6-2:10-20:15-25, forms solvent-free high solid marine steel and sets up and execute antifouling paint.
Its preparation method:
(1) technological process:
As shown in Figure 1.
(2) concrete preparation method:
First epoxy resin is added to Tissuemat E, glycidol ether again through dissolving, high speed dispersion, then add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stop stirring, seal, after standing 24H, stir paint, touch the mark through inspection viscosity, fineness, coating, packaging warehouse-in, polyetheramine packing.
Solvent-free high solid marine antifouling coating; do not add the non-stimulated smell of poisonous and hazardous material (as tributyltin oxide (TBTF) arsenic etc.) harmless to the biology of ocean; because of paint itself have water-fast, wear-resisting, smooth hard; make the biology of ocean be difficult to be attached to hull surface; product has and prevents that for a long time the marine organisms such as barnacle are bright and clean to the stained maintenance hull bottom of hull bottom; thereby do not kill by poisonous and harmful substance the marine organisms that are attached to hull, protected the also Marine Pollution useless of environment of ocean.
Below further illustrate beneficial effect of the present invention by two groups of experimental datas:
(1) the screening experiment of filling a prescription:
According to the different qualities of material, design 4 kinds of formulas:
1 carry out screening experiment (with 4 best results of filling a prescription) as index to fill a prescription
| Formula 1 | Formula 2 | Formula 3 | Formula 4 | |
| Viscosity | 80KU | 80KU | 80KU | 80KU |
| Alkali resistance | 160 hours | 200 hours | 200 hours | 400 hours |
| Salt spray resistance | 500 hours | 600 hours | 600 hours | 800 hours |
| Resistance to water | 360 hours | 400 hours | 400 hours | 600 hours |
| Solid content | 99％ | 99％ | 99％ | 99％ |
(2) contrast experiment:
Carry out contrast experiment's (the present invention has marked improvement) with following index and prior art
Useful effect of the present invention is; low cost of manufacture,, containing solvent, period of storage is not long; good stability; the volatilization of use VOC free, water-fast, wear-resisting, smooth hard, make the biology of ocean be difficult to be attached to hull surface; have and prevent for a long time stained to hull bottom of the marine organisms such as barnacle; keep hull bottom bright and clean, also to marine organisms without poisoning, protected the environment of ocean.
Brief description of the drawings
Fig. 1 is process chart of the present invention.
Detailed description of the invention:
Following embodiment is used for illustrating formula of the present invention and preparation technology, but it can not form any restriction to scope of the present invention.
Embodiment 1
With epoxy resin: the proportioning of cuprous oxide: Sodium Benzoate: glycidol ether: zinc oxide: Tissuemat E: polyetheramine=40:35:10:5:10:6:20, takes respectively: epoxy resin 40kg, cuprous oxide 35kg, Sodium Benzoate 10kg, glycidol ether 5kg, zinc oxide 10kg, Tissuemat E 6kg, polyetheramine 20kg are for subsequent use.
First epoxy resin is added to Tissuemat E, glycidol ether again through dissolving, high speed dispersion, then add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stop stirring, seal, after standing 24H, stir paint, touch the mark through inspection viscosity, fineness, obtain coating, packaging warehouse-in, polyetheramine packing
Products obtained therefrom is tested through laboratory, meets the technical requirements:
Embodiment 2
With epoxy resin: the proportioning of cuprous oxide: Sodium Benzoate: glycidol ether: zinc oxide: Tissuemat E: polyetheramine=50:30:5:3.5:7:5:25, take respectively: epoxy resin 50kg, cuprous oxide 30kg, Sodium Benzoate 5kg, glycidol ether 3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, for subsequent use.
First epoxy resin is added to Tissuemat E, glycidol ether, high speed dispersion again through dissolving, add again cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stops stirring, seal, leave standstill after 24H and stir paint, touch the mark through inspection viscosity, fineness, coating, packaging warehouse-in, polyetheramine packing.
Products obtained therefrom is tested through laboratory, meets technical indicator:
Embodiment 3
With epoxy resin: the proportioning of cuprous oxide: Sodium Benzoate: glycidol ether: zinc oxide: Tissuemat E: polyetheramine=60:25:2.5:2.5:5:3:30, take respectively: epoxy resin 60kg, cuprous oxide 25kg, Sodium Benzoate 2.5kg, glycidol ether 2.5kg, zinc oxide 5kg, Tissuemat E 3kg, polyetheramine 30kg, for subsequent use.
First epoxy resin is added to Tissuemat E, glycidol ether again through dissolving, high speed dispersion, then add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stop stirring, seal, after standing 24H, stir paint, touch the mark through inspection viscosity, fineness, coating, packaging warehouse-in, polyetheramine packing
Products obtained therefrom is tested through laboratory, meets technical indicator:
Embodiment 4
With epoxy resin: unsaturated polynary hydroxy acid polymer: the proportioning of iron oxide red: cuprous oxide: Sodium Benzoate: glycidol ether: zinc oxide: Tissuemat E: polyetheramine=50:2:8:30:5:3.5:7:5:25, take respectively: epoxy resin 50kg, unsaturated polynary hydroxy acid polymer 2kg, iron oxide red 8kg, cuprous oxide 30kg, Sodium Benzoate 5kg, glycidol ether 3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, for subsequent use.
First epoxy resin is added to unsaturated polynary hydroxy acid polymer, iron oxide red, Tissuemat E, glycidol ether again through dissolving, high speed dispersion, then add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stop stirring, seal, after standing 24H, stir paint, touch the mark through inspection viscosity, fineness, obtain coating, packaging warehouse-in, polyetheramine packing.
The test of novel ship bottom antifouling paint laboratory, the solvent-free high solid of products obtained therefrom ocean, meets the technical requirements:
Embodiment 5
With epoxy resin: unsaturated polynary hydroxy acid polymer: the proportioning of titanium dioxide: cuprous oxide: Sodium Benzoate: glycidol ether: zinc oxide: Tissuemat E: polyetheramine=50:2:15:30:5:3.5:7:5:25, take respectively: epoxy resin 50kg, unsaturated polynary hydroxy acid polymer 2kg, titanium dioxide 15kg, cuprous oxide 30kg, Sodium Benzoate 5kg, glycidol ether 3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, for subsequent use.
First epoxy resin is added to unsaturated polynary hydroxy acid polymer, titanium dioxide, Tissuemat E, glycidol ether again through dissolving, high speed dispersion, then add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stop stirring, seal, after standing 24H, stir paint, touch the mark through inspection viscosity, fineness, obtain coating, packaging warehouse-in, polyetheramine packing
The test of novel ship bottom antifouling paint laboratory, the solvent-free high solid of products obtained therefrom ocean, meets the technical requirements:
Embodiment 6
With epoxy resin: unsaturated polynary hydroxy acid polymer: titanium dioxide: mica powder: cuprous oxide: the proportioning of Sodium Benzoate, glycidol ether: zinc oxide: Tissuemat E: polyetheramine=50:2:15:20:30:5:3.5:7:5:25, take respectively: epoxy resin 50kg, unsaturated polynary hydroxy acid polymer 2kg, titanium dioxide 15kg, mica powder 20kg, cuprous oxide 30kg, Sodium Benzoate 5kg, glycidol ether 3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, for subsequent use.
First epoxy resin is added to unsaturated polynary hydroxy acid polymer, titanium dioxide, mica powder, Tissuemat E, glycidol ether again through dissolving, high speed dispersion, then add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain, stop stirring, seal, after standing 24H, stir paint, touch the mark through inspection viscosity, fineness, obtain coating, packaging warehouse-in, polyetheramine packing
The test of novel ship bottom antifouling paint laboratory, the solvent-free high solid of products obtained therefrom ocean, meets the technical requirements:
Claims (5)
1. a solvent-free high solid marine antifouling coating, it is characterized in that: be made up of epoxy resin, cuprous oxide, Sodium Benzoate, glycidol ether, zinc oxide, Tissuemat E and polyetheramine, the weight ratio of each component is 40-60:25-35:2.5-10:2.5-5:5-10:3-6:20-30.
2. so the solvent-free high solid marine antifouling coating of stating according to right 1, is characterized in that: wherein add unsaturated polynary hydroxy acid polymer, its weight ratio of iron oxide red is 0.6-2:5-10, forms solvent-free high solid ocean ship bottom antifouling paint.
3. so the solvent-free high solid marine antifouling coating of stating according to right 1, is characterized in that: wherein add unsaturated polynary hydroxy acid polymer, its weight ratio of titanium dioxide is 0.6-2:10-20, forms solvent-free high solid ocean shell antifouling paint.
4. so solvent-free high solid marine antifouling coating of stating according to right 1, it is characterized in that: wherein adding unsaturated polynary hydroxy acid polymer, titanium dioxide, its weight ratio of mica powder is 0.6-2:10-20:15-25, form solvent-free high solid marine steel and set up and execute antifouling paint.
5. according to solvent-free high solid marine antifouling coating claimed in claim 1, it is characterized in that: its preparation method:
First epoxy resin is added to Tissuemat E, glycidol ether, high speed dispersion again through dissolving; Add cuprous oxide, zinc oxide, Sodium Benzoate, in high speed dispersion tank diameter, high-speed stirred mixes after the fineness that reaches certain again, stops stirring, seal, leave standstill after 24H, stir paint, touch the mark through inspection viscosity, fineness, coating, packaging warehouse-in, polyetheramine packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510395089.0A CN105585935B (en) | 2015-07-07 | 2015-07-07 | A kind of solvent-free high solid marine antifouling coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510395089.0A CN105585935B (en) | 2015-07-07 | 2015-07-07 | A kind of solvent-free high solid marine antifouling coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105585935A true CN105585935A (en) | 2016-05-18 |
| CN105585935B CN105585935B (en) | 2017-12-08 |
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|---|---|---|---|
| CN201510395089.0A Active CN105585935B (en) | 2015-07-07 | 2015-07-07 | A kind of solvent-free high solid marine antifouling coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504083A (en) * | 2018-11-21 | 2019-03-22 | 杭州本松新材料技术股份有限公司 | Polyamide two-component eliminating smell agent and containing its polyamide resin composite material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967316A (en) * | 2010-09-08 | 2011-02-09 | 中国乐凯胶片集团公司 | Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint |
| CN103788811A (en) * | 2013-12-11 | 2014-05-14 | 青岛海洋新材料科技有限公司 | Environment-friendly marine antifouling coating |
| CN103805028A (en) * | 2014-02-20 | 2014-05-21 | 中国船舶重工集团公司第七二五研究所 | Preparation method of solvent-free antifouling paint for underwater construction |
-
2015
- 2015-07-07 CN CN201510395089.0A patent/CN105585935B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967316A (en) * | 2010-09-08 | 2011-02-09 | 中国乐凯胶片集团公司 | Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint |
| CN103788811A (en) * | 2013-12-11 | 2014-05-14 | 青岛海洋新材料科技有限公司 | Environment-friendly marine antifouling coating |
| CN103805028A (en) * | 2014-02-20 | 2014-05-21 | 中国船舶重工集团公司第七二五研究所 | Preparation method of solvent-free antifouling paint for underwater construction |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504083A (en) * | 2018-11-21 | 2019-03-22 | 杭州本松新材料技术股份有限公司 | Polyamide two-component eliminating smell agent and containing its polyamide resin composite material |
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| CN105585935B (en) | 2017-12-08 |
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Effective date of registration: 20200116 Address after: 332200 Building 8, Jinding famous city, south of Xunyang East Road and east of Donghuan Road, Ruichang City, Jiujiang City, Jiangxi Province Patentee after: Ruiyide new materials Co.,Ltd. Address before: 224600 Jiangsu Province, Yancheng City chemical industry park and the two Road North Patentee before: JIANGSU RUIHE NEW MATERIAL CO.,LTD. |
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Denomination of invention: A solvent-free high solid marine antifouling coating Effective date of registration: 20210722 Granted publication date: 20171208 Pledgee: Jiujiang Industrial Financing Guarantee Co.,Ltd. Pledgor: Ruiyide new materials Co.,Ltd. Registration number: Y2021980006642 |
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Date of cancellation: 20220805 Granted publication date: 20171208 Pledgee: Jiujiang Industrial Financing Guarantee Co.,Ltd. Pledgor: Ruiyide new materials Co.,Ltd. Registration number: Y2021980006642 |
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Denomination of invention: A solvent-free high solid marine antifouling coating Effective date of registration: 20230804 Granted publication date: 20171208 Pledgee: China Postal Savings Bank Co.,Ltd. Ruichang City Branch Pledgor: Ruiyide new materials Co.,Ltd. Registration number: Y2023980051102 |
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Granted publication date: 20171208 Pledgee: China Postal Savings Bank Co.,Ltd. Ruichang City Branch Pledgor: Ruiyide new materials Co.,Ltd. Registration number: Y2023980051102 |