CN105579817A - 用于量热测量的样品小瓶 - Google Patents

用于量热测量的样品小瓶 Download PDF

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CN105579817A
CN105579817A CN201480052957.9A CN201480052957A CN105579817A CN 105579817 A CN105579817 A CN 105579817A CN 201480052957 A CN201480052957 A CN 201480052957A CN 105579817 A CN105579817 A CN 105579817A
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bottle
infrared reflection
reflection coating
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马格努斯·简森
克里斯特·瓦林
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Symcel Sverige AB
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00—Investigating or analyzing materials by the use of thermal means
    • G01N25/20—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity
    • G01N25/48—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on solution, sorption, or a chemical reaction not involving combustion or catalytic oxidation
    • G01N25/4846—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on solution, sorption, or a chemical reaction not involving combustion or catalytic oxidation for a motionless, e.g. solid sample
    • G01N25/4853—Details
    • G01N25/486—Sample holders
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K17/00—Measuring quantity of heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
    • B01L3/50—Containers for the purpose of retaining a material to be analysed, e.g. test tubes
    • B01L3/508—Containers for the purpose of retaining a material to be analysed, e.g. test tubes rigid containers not provided for above
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
    • B01L3/50—Containers for the purpose of retaining a material to be analysed, e.g. test tubes
    • B01L3/508—Containers for the purpose of retaining a material to be analysed, e.g. test tubes rigid containers not provided for above
    • B01L3/5082—Test tubes per se
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00—Investigating or analyzing materials by the use of thermal means
    • G01N25/20—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity
    • G01N25/48—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on solution, sorption, or a chemical reaction not involving combustion or catalytic oxidation
    • G01N25/4806—Details not adapted to a particular type of sample
    • G01N25/484—Heat insulation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/04—Closures and closing means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/08—Geometry, shape and general structure
    • B01L2300/0832—Geometry, shape and general structure cylindrical, tube shaped
    • B01L2300/0835—Ampoules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/16—Surface properties and coatings
    • B01L2300/168—Specific optical properties, e.g. reflective coatings
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N2001/002—Devices for supplying or distributing samples to an analysing apparatus

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Abstract

本发明涉及用于量热测量的样品小瓶(1)。本发明教导了小瓶材料(1’)为质量轻的，以及在小瓶的外部，小瓶至少部分地涂覆有红外反射涂层。5本发明还涉及用于与小瓶(1)一起形成安瓿(5)的盖子(4)。

Description

用于量热测量的样品小瓶
技术领域
本发明涉及一种用于量热测量的样品小瓶和用于该样品小瓶的盖子。
背景技术
通常在使用独立隔离且处于热态的单样品室的设备中执行等温量热测量。为了增加样品的生产量从而应对并适应普通实验室库存，可以使用单板式多通道恒温量热器(等温量热仪)，其对于多个样品小瓶使用一个共同室。这允许在典型实验室环境下具有更快且更有效的样品生产量。
发明内容
问题
通过使用标准化微量滴定板布置(诸如ANSI/SBS1-2004标准中所述)而施加的尺寸限制使得生成热量的样品小瓶彼此紧靠并且使得样品小瓶与相邻的热流传感器紧靠。微量滴定板的各样品之间将由空气进行隔离。
样品之间的红外热辐射造成导致不期望的交叉样品加热和样品精度损失的风险。
解决方案
从用于量热测量的样品小瓶的观点出发并以解决上述问题中的一个或多个为目的，本发明教导了：小瓶材料是质量轻的；并且在该小瓶的外部，该小瓶至少部分地涂覆有红外反射涂层。
通过利用质量轻的样品小瓶材料，将发生从样品小瓶到热流传感器的快速热传递。用红外反射涂层涂覆样品小瓶将小瓶中生成的热量反射回小瓶中并且使邻近小瓶中生成的热量转向。最终结果是，增加多小瓶恒温量热器中特定样品信号的完整性。
本申请建议：小瓶材料包括但不限于钛合金；红外反射涂层包括但不限于氮化钛。
当利用以下原则(即，测量到传递能量的热量流通过样品小瓶的与安装有散热器的传感器相接触的侧面从该样品小瓶流到该传感器)时，本申请提出：小瓶的该侧面没有红外反射涂层以便增加传到热传感器的热量流。
本申请建议：小瓶的底部是该小瓶的与位于样品组件底部的传感器相接触的侧面。
红外反射涂层优选地物理性(mechanically，机械方面)稳定并且化学惰性高，例如，金(Au)或陶瓷复合物，所述陶瓷复合物包括但不限于氮化钛(TiN)，诸如来自欧瑞康巴尔查斯(OerliconBalzers)的A，并且建议使用在0.5μm与4μm之间的涂层厚度。
为了提供具有本发明的小瓶的有利特性的完整安瓿，本发明还涉及用于与本发明的小瓶一起形成安瓿的盖子。盖子材料为质量轻的，并且在盖子的外部，盖子至少部分地涂覆有红外反射涂层。
盖子材料包括但不限于钛合金；红外反射涂层包括但不限于氮化钛。
红外反射涂层物理性稳定并且化学惰性高，诸如金(Au)或陶瓷复合物，所述陶瓷复合物包括但不限于氮化钛，并且具有在0.5μm与4μm之间的涂层厚度。
优点
根据本发明的小瓶或方法的优点是，最终结果为，通过除了与传感器接触的小瓶侧面之外的小瓶侧面上的红外反射材料的选择性应用，增加了从样品到传感器的小瓶间热量传递。
本发明的样品小瓶特别有利于用在多通道量热测量中，因为通过尽可能地减少通过空气对邻近小瓶和传感器的热量辐射而降低内部样品红外辐射。
附图说明
现在将参照附图，详细描述本发明的样品小瓶，附图中：
图1是具有盖子的本发明的样品小瓶的横截面视图；
图2是具有涂层的小瓶的一部分的示意性简化横截面放大图；以及
图3是具有涂层的盖子的一部分的示意性简化横截面放大图。
具体实施方式
将参照图1描述本发明，图1示出了用于量热测量的样品小瓶1，其中，小瓶材料1’为质量轻的。图2示出了在小瓶1的外部，小瓶1至少部分地涂覆有红外反射涂层2。
该小瓶适用于这样的测量，其中测量到传递能量的热量流通过样品小瓶的与安装有散热器的传感器接触的侧面1a从该样品小瓶流到传感器，并且建议小瓶的该侧面1a没有红外反射涂层。图1示出了一实施例，其中小瓶1的底部是该小瓶的与传感器3接触的侧面1a。
本申请建议：小瓶材料1’包括但不限于钛合金；红外反射涂层2包括但不限于氮化钛。
优选地，红外反射涂层2物理性稳定并且化学惰性高，诸如金(Au)或陶瓷复合物，所述陶瓷复合物包括但不限于氮化钛。
本申请还建议红外反射涂层具有在0.5μm与4μm之间的涂层厚度A。
图1还示出了用于与本发明的小瓶1一起形成安瓿5的盖子4。盖子材料4’为质量轻的，并且图3示出了在盖子4的外部，盖子4至少部分地涂覆有红外反射涂层6。
盖子材料4’包括但不限于钛合金；红外反射涂层6包括但不限于氮化钛。
红外反射涂层6物理性稳定并且化学惰性高，诸如金(Au)或陶瓷复合物，所述陶瓷复合物包括但不限于氮化钛，并且具有在0.5μm与4μm之间的涂层厚度B。
应当理解，本发明不限于以上所述和示出的本发明的示例性实施例，可以在如由所附权利要求所限定的本发明的范围内做出修改。

Claims (14)

1.一种样品小瓶，所述样品小瓶用于量热测量，其特征在于，小瓶材料为质量轻的，并且在所述小瓶的外部，所述小瓶至少部分地涂覆有红外反射涂层。
2.根据权利要求1所述的小瓶，其特征在于，所述小瓶用于测量，其中对传递能量的热量流进行测量，所述热量流通过所述小瓶的与安装有散热器的传感器接触的一个侧面从所述小瓶流到所述传感器，所述小瓶的该侧面没有红外反射涂层。
3.根据权利要求2所述的小瓶，其特征在于，所述小瓶的底部是所述小瓶的与所述传感器接触的侧面。
4.根据任一前述权利要求所述的小瓶，其特征在于，所述小瓶材料包括但不限于钛合金。
5.根据任一前述权利要求所述的小瓶，其特征在于，所述红外反射涂层包括但不限于氮化钛。
6.根据任一前述权利要求所述的小瓶，其特征在于，所述红外反射涂层物理性稳定并且化学惰性高。
7.根据权利要求6所述的小瓶，其特征在于，所述红外反射涂层由金(Au)或陶瓷复合物制成，所述陶瓷复合物包括但不限于氮化钛。
8.根据任一前述权利要求所述的小瓶，其特征在于，所述红外反射涂层具有在0.5μm与4μm之间的涂层厚度。
9.一种盖子，所述盖子用于与根据任一前述权利要求所述的小瓶一起形成安瓿，其特征在于，盖子材料为质量轻的，在所述盖子的外部，所述盖子至少部分地涂覆有红外反射涂层。
10.根据权利要求9所述的盖子，其特征在于，所述盖子材料包括但不限于钛合金。
11.根据权利要求9或10所述的盖子，其特征在于，所述红外反射涂层包括但不限于氮化钛。
12.根据权利要求9至11中任一项所述的盖子，其特征在于，所述红外反射涂层物理性稳定并且化学惰性高。
13.根据权利要求12所述的盖子，其特征在于，所述红外反射涂层由金(Au)或陶瓷复合物制成，所述陶瓷复合物包括但不限于氮化钛。
14.根据权利要求9至13中任一项所述的盖子，其特征在于，所述红外反射涂层具有在0.5μm与4μm之间的涂层厚度。
CN201480052957.9A 2013-09-30 2014-08-20 用于量热测量的样品小瓶 Pending CN105579817A (zh)

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PCT/SE2014/050951 WO2015047156A1 (en) 2013-09-30 2014-08-20 Sample vial for calorimetric measurements

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EP3052914A1 (en) 2016-08-10
SE1351139A1 (sv) 2015-03-31
EP3052914A4 (en) 2017-05-03
KR20160063363A (ko) 2016-06-03
SE537326C2 (sv) 2015-04-07
US20160223480A1 (en) 2016-08-04
JP2016532089A (ja) 2016-10-13

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