CN105568737B - High anti-tensile white board and preparation method thereof - Google Patents

High anti-tensile white board and preparation method thereof Download PDF

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Publication number
CN105568737B
CN105568737B CN201510954015.6A CN201510954015A CN105568737B CN 105568737 B CN105568737 B CN 105568737B CN 201510954015 A CN201510954015 A CN 201510954015A CN 105568737 B CN105568737 B CN 105568737B
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composite fibre
white board
parts
high anti
bleaching
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CN105568737A (en
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周庆芬
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Ningbo Polygala Cubic Energy Technology Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/22Other features of pulping processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof

Abstract

It is made the invention discloses a kind of high anti-tensile white board and preparation method thereof, including the raw material of following parts by weight:100 105 parts of composite fibre, 68 parts of tea extracts and 10 15 parts of mango leaf extract;Wherein, it is 15 16 that 100 105 parts of the composite fibre, which includes mass ratio,:2‑3:The 10 wooden wood-fibred of willow wood-fibred, bamboo fibre and San Cheong, a length of 0.98mm of the willow wood-fibred, a width of 0.02mm.The high anti-tensile white board that the present invention is provided, its content of formaldehyde is low, solves the retractility drawback that existing high anti-tensile white board is present, and fluffing, smoothness height is difficult, while ink is easily attached on high anti-tensile white board.

Description

High anti-tensile white board and preparation method thereof
Technical field
The present invention relates to field of papermaking.It is more particularly related to a kind of production technology of high anti-tensile white board.
Background technology
White board is because fibr tissue is than more uniform, and superficial layer has the composition of filler and sizing material, and surface scribbles one Fixed coating, and by multi-roller rolling processing, so the quality of cardboard is closer, thickness is also than more uniform.Its paper is general In the case of it is all pure whiter and smooth, with more uniform absorbency, surface shedding and hair loss phenomenon are less, papery high-tenacity and have There is preferable folding strength, but its water content is higher, typically 10% or so, there is certain retractility, this can bring to printing Certain influence.Difference between white board and art paper, offset paper, typographic printing paper is that paper gram degree weight, paper are compared abundant And positive and negative face color is different, white board is the grey colourless of one side, and also referred to as grey primary coat cloth is white.
The content of the invention
It is an object of the invention to solve at least the above, and provide the advantage that at least will be described later.
It is a still further object of the present invention to provide a kind of high anti-tensile white board, its content of formaldehyde is low, solves existing high anti- The drawbacks of opening retractility and the low tensile factor that white board is present.The high anti-tensile white board of the present invention is difficult fluffing, smoothness height, Ink is easily attached on high anti-tensile white board simultaneously.
In order to realize according to object of the present invention and further advantage there is provided a kind of high anti-tensile white board, including with The raw material of lower parts by weight is made:
100-105 parts of composite fibre, 6-8 parts of tea extracts and 10-15 parts of mango leaf extract;
Wherein, it is 15-16 that 100-105 parts of the composite fibre, which includes mass ratio,:2-3:10 willow wood-fibred, bamboo are fine Peacekeeping San Cheong wood wood-fibred, a length of 0.98mm of the willow wood-fibred, a width of 0.02mm;
The preparation method of the tea extract is:Refluxing extraction in aqueous acetone solution is added after drying tea leaves are crushed, Filtered after extracting for the first time, filter residue is carried out to 2 refluxing extractions again, the filtrate of 3 refluxing extractions is merged, vacuum distillation is removed Acetone, is produced after concentration filtrate, freeze-drying;Wherein, the addition of each acetone is 3-5 times of tea quality.
Preferably, in addition to bleaching agent, the bleaching agent is gas catalyst.
Present invention also offers a kind of method for preparing high anti-tensile white board, comprise the following steps:
Step 1: size degradation will be added in the milk tree aqueous solution into composite fibre in the composite fibre of 100-105 parts by weight Mass fraction is 11%-12% composite fibre slurry;The preparation method of the milk tree aqueous solution is to cut milk tree bark It is 3-5 in mass ratio with water to open taking juice:Boiled after 100 mixing, cooling is produced;
Step 2: adding the mango leaf extract and 6-8 parts by weight of 10-15 parts by weight in the composite fibre slurry Tea extract, is stirred continuously, and stir speed (S.S.) is 350r/min, and is passed through temperature into composite fibre slurry for 100-110 DEG C Steam, continue 40-55min;
Step 3: the composite fibre slurry handled by step 2 is carried out into free beating method processing, material must be beaten, The freedom for making fiber is 810mL-820mL;
Step 4: mashing material is placed in bleaching system, bleaching agent is gas catalyst, wherein the bleaching system includes sealing Rectangular-shape case body, be provided with air inlet pipe above the case body, the case body is stretched into one end of the air inlet pipe Bottom surface internal and close to the case body, the other end of the air inlet pipe is connected with the gas tank equipped with gas catalyst, the air inlet It is provided with pipe above the first valve, the case body and is provided with escape pipe, the case sheet is stretched into one end of the escape pipe The top surface of body and the close case body, the other end of the escape pipe is connected with gas collector, set on the escape pipe It is equipped with vavuum pump and the second valve;
After mashing material is placed in bleaching system, gas catalyst is passed through into the air inlet pipe, its intake is every liter of mashing material 22-25mg gas catalyst is passed through, the first valve and the second valve is closed, the bleaching system is heated, makes the temperature of the mashing material It is maintained at after 46-48 DEG C, reaction 16-20min, opens the second valve and vavuum pump, repeat step four 3-5 times, mashing must be bleached Material;
Step 5: bleaching mashing material is carried out into papermaking, the high anti-tensile white board is dried to obtain.
Preferably, after repeat step four obtains bleaching mashing material for 3-5 times, talcum is also added into bleaching mashing material Powder, step 5 is carried out after being well mixed again;Wherein, the talcum powder added in every kilogram of bleaching mashing material is 40-49 grams.
Preferably, the composite fibre slurry has also carried out removal of impurities processing after step 2 is carried out, using 80 purposes Screen cloth stays screenings to composite fibre pulp separation, and the screenings is carried out into step 3.
Preferably, the intake of the gas catalyst is 24mg/L.
Preferably, the water content of the high anti-tensile white board is 5-8.8% after being dried in step 5.
The present invention at least includes following beneficial effect:
1st, general fibre length is maintained at more than 340 μm and would not had an impact to the intensity of paper, and the willow wood of use is fine Dimension, fibre length is 0.98mm, and the price than wastepaper as raw material and long fibre trees is low, and obtained white board harmful components are significantly Reduction;The quality that a small amount of bamboo fibre improves paper product is added in composite fibre, with the fungi-proofing effect of certain deodorization, is strengthened simultaneously The burst index of white board, adds the wooden wood-fibred of San Cheong as natural formaldehyde eliminating agent in composite fibre, can improve blank The environment protecting of paper.
2nd, with milk water aqueous solution size degradation composite fibre, it is possible to increase the tensile index of white board.
3rd, accelerate tea extract and mango leaf extract to be evenly distributed in composite fibre slurry using vapours, make tea Leaf extract and mango leaf extract are embedded in the fiber holes of slurry, make to contain tea extract and mango in the finished product in later stage Leaf extract, can adsorb the harmful substances such as the formaldehyde around white board while also having certain bactericidal effect.
4th, the consumption of paper pulp can be saved using free beating method, while obtained white board density is small, transparency is low, change The problem of being apt to existing white board retractility, while ink easily adheres to.
5th, talcum powder is added in bleaching mashing material has the effect for improving white board smoothness.
6th, bleaching agent uses gas catalyst, white board can not only be bleached, while can also remove formaldehyde, benzene homologues etc. has poison gas Body, the effect to paper with sterilization, the process for eliminating later stage sterilization finished paper reduces labor intensity.
Further advantage, target and the feature of the present invention embodies part by following explanation, and part will also be by this The research and practice of invention and be understood by the person skilled in the art.
Embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification Word can be implemented according to this.
Embodiment 1
A kind of high anti-tensile white board, including the raw material of following parts by weight are made:100 parts of composite fibre, 6 portions of tealeaves are carried Take thing and 10 parts of mango leaf extract.Wherein, it is 15 that 100 parts of the composite fibre, which includes mass ratio,:2:10 willow wood The wooden wood-fibred of fiber, bamboo fibre and San Cheong, a length of 0.98mm of the willow wood-fibred, a width of 0.02mm.
The preparation method of the tea extract is:Refluxing extraction in aqueous acetone solution is added after drying tea leaves are crushed, Filtered after extracting for the first time, filter residue is carried out to 2 refluxing extractions again, the filtrate of 3 refluxing extractions is merged, vacuum distillation is removed Acetone, is produced after concentration filtrate, freeze-drying;Wherein, the addition of each acetone is 3 times of tea quality.
The high anti-tensile white board also includes bleaching agent, and the bleaching agent is gas catalyst.
The method that high anti-tensile white board is prepared in the present embodiment, comprises the following steps:
Step 1: quality of the size degradation into composite fibre in the milk tree aqueous solution will be added in the composite fibre of 100 parts by weight Fraction is 11% composite fibre slurry;The preparation method of the milk tree aqueous solution be by milk tree bark cut taking juice and Water is 3 in mass ratio:Boiled after 100 mixing, cooling is produced.
Step 2: adding the mango leaf extract of 10 parts by weight and the tealeaves of 6 parts by weight in the composite fibre slurry Extract, is stirred continuously, and stir speed (S.S.) is 350r/min, and it is 100-110 DEG C of steaming to be passed through temperature into composite fibre slurry Vapour, continues 40min.
Step 3: the composite fibre slurry has also carried out removal of impurities processing after step 2 is carried out, using the sieve of 80 mesh Net stays screenings to composite fibre pulp separation.
Step 4: screenings is carried out into free beating method processing, material must be beaten, the freedom for making fiber is 810mL.
Step 5: mashing material is placed in bleaching system, bleaching agent is gas catalyst, wherein the bleaching system includes sealing Rectangular-shape case body, be provided with air inlet pipe above the case body, the case body is stretched into one end of the air inlet pipe Bottom surface internal and close to the case body, the other end of the air inlet pipe is connected with the gas tank equipped with gas catalyst, the air inlet It is provided with pipe above the first valve, the case body and is provided with escape pipe, the case sheet is stretched into one end of the escape pipe The top surface of body and the close case body, the other end of the escape pipe is connected with gas collector, set on the escape pipe It is equipped with vavuum pump and the second valve.
After mashing material is placed in bleaching system, gas catalyst is passed through into the air inlet pipe, its intake is every liter of mashing material 22mg gas catalyst is passed through, the first valve and the second valve is closed, the bleaching system is heated, the temperature of the mashing material is kept At 46 DEG C, after reaction 16min, the second valve and vavuum pump, repeat step 53 times are opened, mashing material must be bleached.
Step 6: adding talcum powder in bleaching mashing material, step 7 is carried out again after being well mixed;Wherein, every kilogram The talcum powder added in bleaching mashing material is 40 grams.
Step 7: the bleaching obtained in step 6 mashing material is subjected to papermaking, the high anti-tensile white board is dried to obtain, wherein The water content of the high anti-tensile white board is 5%.
Embodiment 2
A kind of high anti-tensile white board, including the raw material of following parts by weight are made:105 parts of composite fibre, 8 portions of tealeaves are carried Take thing and 15 parts of mango leaf extract.Wherein, it is 16 that 105 parts of the composite fibre, which includes mass ratio,:3:10 willow wood The wooden wood-fibred of fiber, bamboo fibre and San Cheong, a length of 0.98mm of the willow wood-fibred, a width of 0.02mm.
The preparation method of the tea extract is:Refluxing extraction in aqueous acetone solution is added after drying tea leaves are crushed, Filtered after extracting for the first time, filter residue is carried out to 2 refluxing extractions again, the filtrate of 3 refluxing extractions is merged, vacuum distillation is removed Acetone, is produced after concentration filtrate, freeze-drying;Wherein, the addition of each acetone is 5 times of tea quality.
The high anti-tensile white board also includes bleaching agent, and the bleaching agent is gas catalyst.
The method that high anti-tensile white board is prepared in the present embodiment, comprises the following steps:
Step 1: quality of the size degradation into composite fibre in the milk tree aqueous solution will be added in the composite fibre of 105 parts by weight Fraction is 12% composite fibre slurry;The preparation method of the milk tree aqueous solution be by milk tree bark cut taking juice and Water is 5 in mass ratio:Boiled after 100 mixing, cooling is produced.
Step 2: adding the mango leaf extract of 15 parts by weight and the tealeaves of 8 parts by weight in the composite fibre slurry Extract, is stirred continuously, and stir speed (S.S.) is 350r/min, and is passed through the steam that temperature is 110 DEG C into composite fibre slurry, holds Continuous 55min.
Step 3: the composite fibre slurry has also carried out removal of impurities processing after step 2 is carried out, using the sieve of 80 mesh Net stays screenings to composite fibre pulp separation.
Step 4: screenings is carried out into free beating method processing, material must be beaten, the freedom for making fiber is 820mL.
Step 5: mashing material is placed in bleaching system, bleaching agent is gas catalyst, wherein the bleaching system includes sealing Rectangular-shape case body, be provided with air inlet pipe above the case body, the case body is stretched into one end of the air inlet pipe Bottom surface internal and close to the case body, the other end of the air inlet pipe is connected with the gas tank equipped with gas catalyst, the air inlet It is provided with pipe above the first valve, the case body and is provided with escape pipe, the case sheet is stretched into one end of the escape pipe The top surface of body and the close case body, the other end of the escape pipe is connected with gas collector, set on the escape pipe It is equipped with vavuum pump and the second valve.
After mashing material is placed in bleaching system, gas catalyst is passed through into the air inlet pipe, its intake is every liter of mashing material 25mg gas catalyst is passed through, the first valve and the second valve is closed, the bleaching system is heated, the temperature of the mashing material is kept At 48 DEG C, after reaction 20min, the second valve and vavuum pump, repeat step 55 times are opened, mashing material must be bleached.
Step 6: adding talcum powder in bleaching mashing material, step 7 is carried out again after being well mixed;Wherein, every kilogram The talcum powder added in bleaching mashing material is 49 grams.
Step 7: the bleaching obtained in step 6 mashing material is subjected to papermaking, the high anti-tensile white board is dried to obtain, wherein The water content of the high anti-tensile white board is 8.8%.
Embodiment 3
A kind of high anti-tensile white board, including the raw material of following parts by weight are made:102 parts of composite fibre, 7 portions of tealeaves are carried Take thing and 12 parts of mango leaf extract.Wherein, it is 15 that 102 parts of the composite fibre, which includes mass ratio,:2:10 willow wood The wooden wood-fibred of fiber, bamboo fibre and San Cheong, a length of 0.98mm of the willow wood-fibred, a width of 0.02mm.
The preparation method of the tea extract is:Refluxing extraction in aqueous acetone solution is added after drying tea leaves are crushed, Filtered after extracting for the first time, filter residue is carried out to 2 refluxing extractions again, the filtrate of 3 refluxing extractions is merged, vacuum distillation is removed Acetone, is produced after concentration filtrate, freeze-drying;Wherein, the addition of each acetone is 4 times of tea quality.
The high anti-tensile white board also includes bleaching agent, and the bleaching agent is gas catalyst.
The method that high anti-tensile white board is prepared in the present embodiment, comprises the following steps:
Step 1: quality of the size degradation into composite fibre in the milk tree aqueous solution will be added in the composite fibre of 102 parts by weight Fraction is 11% composite fibre slurry;The preparation method of the milk tree aqueous solution be by milk tree bark cut taking juice and Water is 4 in mass ratio:Boiled after 100 mixing, cooling is produced.
Step 2: adding the mango leaf extract of 12 parts by weight and the tealeaves of 7 parts by weight in the composite fibre slurry Extract, is stirred continuously, and stir speed (S.S.) is 350r/min, and is passed through the steam that temperature is 105 DEG C into composite fibre slurry, holds Continuous 45min.
Step 3: the composite fibre slurry has also carried out removal of impurities processing after step 2 is carried out, using the sieve of 80 mesh Net stays screenings to composite fibre pulp separation.
Step 4: screenings is carried out into free beating method processing, material must be beaten, the freedom for making fiber is 815mL.
Step 5: mashing material is placed in bleaching system, bleaching agent is gas catalyst, wherein the bleaching system includes sealing Rectangular-shape case body, be provided with air inlet pipe above the case body, the case body is stretched into one end of the air inlet pipe Bottom surface internal and close to the case body, the other end of the air inlet pipe is connected with the gas tank equipped with gas catalyst, the air inlet It is provided with pipe above the first valve, the case body and is provided with escape pipe, the case sheet is stretched into one end of the escape pipe The top surface of body and the close case body, the other end of the escape pipe is connected with gas collector, set on the escape pipe It is equipped with vavuum pump and the second valve.
After mashing material is placed in bleaching system, gas catalyst is passed through into the air inlet pipe, its intake is every liter of mashing material 23mg gas catalyst is passed through, the first valve and the second valve is closed, the bleaching system is heated, the temperature of the mashing material is kept At 47 DEG C, after reaction 18min, the second valve and vavuum pump, repeat step 54 times are opened, mashing material must be bleached.
Step 6: adding talcum powder in bleaching mashing material, step 7 is carried out again after being well mixed;Wherein, every kilogram The talcum powder added in bleaching mashing material is 45 grams.
Step 7: the bleaching obtained in step 6 mashing material is subjected to papermaking, the high anti-tensile white board is dried to obtain, wherein The water content of the high anti-tensile white board is 7.8%.
Comparative example 1
White board in comparative example 1 is identical with the preparation method of embodiment 3, but in raw material only:102 parts of mixing is fine Dimension.There is no tea extract and mango extract both raw materials.
Comparative example 2
Comparative example 2 is raw materials used identical with embodiment 3, but uses in manufacturing process step one pure water progress Size degradation, does not carry out size degradation using the milk tree aqueous solution, and other steps are identical with embodiment 3.
The performance test results of embodiment 1-3 and comparative example 1-2 white board are shown in Table 1.
The performance test of the white board of table 1
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited In specific details and shown here as the embodiment with description.

Claims (5)

1. a kind of method for preparing high anti-tensile white board, it is characterised in that
Raw material including following parts by weight is made:100-105 parts of composite fibre, 6-8 parts of tea extracts and 10-15 parts Mango leaf extract;Wherein, it is 15-16 that 100-105 parts of the composite fibre, which includes mass ratio,:2-3:10 willow wood is fine The wooden wood-fibred of dimension, bamboo fibre and San Cheong, a length of 0.98mm of the willow wood-fibred, a width of 0.02mm;
The preparation method of the tea extract is:Refluxing extraction, first in aqueous acetone solution are added after drying tea leaves are crushed Filtered after secondary extraction, filter residue is carried out to 2 refluxing extractions again, the filtrate of 3 refluxing extractions is merged, vacuum distillation removes third Ketone, is produced after concentration filtrate, freeze-drying;Wherein, the addition of each acetone is 3-5 times of tea quality;
Also include bleaching agent, the bleaching agent is gas catalyst;
Comprise the following steps:
Step 1: quality of the size degradation into composite fibre in the milk tree aqueous solution will be added in the composite fibre of 100-105 parts by weight Fraction is 11%-12% composite fibre slurry;The preparation method of the milk tree aqueous solution is to cut milk tree bark to take Juice is 3-5 in mass ratio with water:Boiled after 100 mixing, cooling is produced;
Step 2: adding the mango leaf extract of 10-15 parts by weight and the tealeaves of 6-8 parts by weight in the composite fibre slurry Extract, is stirred continuously, and stir speed (S.S.) is 350r/min, and it is 100-110 DEG C of steaming to be passed through temperature into composite fibre slurry Vapour, continues 40-55min;
Step 3: the composite fibre slurry handled by step 2 is carried out into free beating method processing, material must be beaten, makes fibre The freedom of dimension is 810mL-820mL;
Step 4: mashing material is placed in bleaching system, bleaching agent is gas catalyst, wherein the bleaching system includes sealed length Air inlet pipe is provided with above the case body of cube shape, the case body, the case body interior is stretched into one end of the air inlet pipe And close to the bottom surface of the case body, the other end of the air inlet pipe is connected with the gas tank equipped with gas catalyst, in the air inlet pipe It is provided with above the first valve, the case body and is provided with escape pipe, the case body is stretched into simultaneously in one end of the escape pipe Close to the top surface of the case body, the other end of the escape pipe is connected with gas collector, is provided with the escape pipe Vavuum pump and the second valve;
After mashing material is placed in bleaching system, gas catalyst is passed through into the air inlet pipe, its intake is that every liter of mashing material is passed through 22-25mg gas catalyst, closes the first valve and the second valve, heats the bleaching system, keeps the temperature of the mashing material At 46-48 DEG C, after reaction 16-20min, the second valve and vavuum pump, repeat step four 3-5 times are opened, mashing material must be bleached;
Step 5: bleaching mashing material is carried out into papermaking, the high anti-tensile white board is dried to obtain.
2. prepare the method for high anti-tensile white board as claimed in claim 1, it is characterised in that in repeat step four 3-5 times It is beaten to bleaching after material, is also added into talcum powder in bleaching mashing material, step 5 is carried out again after being well mixed;Wherein, every thousand The talcum powder that adds is 40-49 grams in gram bleaching mashing material.
3. the method for high anti-tensile white board is prepared as claimed in claim 1, it is characterised in that the composite fibre slurry is entering Removal of impurities processing has also been carried out after row step 2, using the screen cloth of 80 mesh to composite fibre pulp separation, screenings has been stayed, will be described Screenings carries out step 3.
4. prepare the method for high anti-tensile white board as claimed in claim 1, it is characterised in that the intake of the gas catalyst is 24mg/L。
5. the method for high anti-tensile white board is prepared as claimed in claim 1, it is characterised in that the height after being dried in step 5 The water content of anti-tensile white board is 5-8.8%.
CN201510954015.6A 2015-12-19 2015-12-19 High anti-tensile white board and preparation method thereof Active CN105568737B (en)

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CN107724170A (en) * 2017-10-10 2018-02-23 枣庄市恒宇纸业有限公司 A kind of light paper and preparation method thereof

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CN1396342A (en) * 2002-08-08 2003-02-12 福建闽都纸业股份有限公司 Preparing and process for high-coated (500-1000g/sq.m) white paperhoard
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CN104195873A (en) * 2014-07-29 2014-12-10 安徽省三环纸业(集团)有限公司 Tipping paper with good paper property and spicy and pungent taste and preparation method thereof
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