CN105566827A - Wear-resistant 3D printer window glass and preparation method thereof - Google Patents
Wear-resistant 3D printer window glass and preparation method thereof Download PDFInfo
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- CN105566827A CN105566827A CN201510975572.6A CN201510975572A CN105566827A CN 105566827 A CN105566827 A CN 105566827A CN 201510975572 A CN201510975572 A CN 201510975572A CN 105566827 A CN105566827 A CN 105566827A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses wear-resistant 3D printer window glass and a preparation method thereof. The preparation method includes: 1), in the presence of ultraviolet rays, dissolving nano magnesia, a complex of a structure shown as a formula (I) and graphene in N, N-dimethyl formamide for ultrasonic stirring to form modifying liquid; 2), mixing polymethyl methacrylate, xylitol, aluminum hydroxide, silicone oxide, silver oxide, rare earth oxide and vinyl phenyl silicone oil with the modifying liquid, fusing, cooling and pelleting to obtain a 3D printer window glass material; 3), mixing the glass material for 3-4 h at 180-185 DEG C, injecting the glass material into a die cavity at 45-65 DEG C for forming for 40-50 min, and cooling at 25-35 DEG C to obtain the 3D printer window glass, wherein Mes is 2, 4, 6-trimethylphenyl. The 3D printer window glass prepared by the method has excellent mechanical performance and wear resistance.
Description
Technical field
The present invention relates to sight glass, particularly, relate to a kind of anti abrasive 3D printer sight glass and preparation method thereof.
Background technology
Sight glass divides from material, can be divided into unorganic glass and synthetic glass.Wherein, the main component of unorganic glass is silicate, and this kind of glass has excellent wear-resistant and heat-resisting performance, but this kind of glass has frangible defect.And synthetic glass has the advantage of excellent resistance to fracture, but its surface is to form cut, and thermotolerance is poor.
3D printer sight glass is an important assembly in 3D printer, for the ease of observing the process in printer, requirement sight glass is then needed to have excellent transmittance, tensile strength, thermotolerance and anti abrasive performance, but current glass is difficult to meet these several requirements, and especially abrasion resistance properties is poor simultaneously.
Summary of the invention
The object of this invention is to provide a kind of anti abrasive 3D printer sight glass and preparation method thereof, the 3D printer sight glass obtained by the method has excellent mechanical property and abrasion resistance properties.
To achieve these goals, the invention provides a kind of preparation method of anti abrasive 3D printer sight glass, comprising:
1) in the presence of uv light, by nanometer magnesia, be dissolved in ultrasonic agitation in DMF such as formula the complex compound of structure (I) Suo Shi and Graphene and form modification liquid;
2) polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide, vinyl phenyl silicone oil and modification liquid are mixed, then melting, cooling, granulation are with obtained 3D printer sight glass material;
3) by described 3D printer sight glass material mixing 3-4h at 180-185 DEG C, then in the shaping 40-50min of die cavity injecting 45-65 DEG C, finally cool with obtained described 3D printer sight glass at 25-35 DEG C;
Wherein, Mes is mesityl.
Present invention also offers a kind of anti abrasive 3D printer sight glass, this 3D printer sight glass is prepared from by above-mentioned method.
By technique scheme, preparation method provided by the invention first by nanometer magnesia, be dissolved in ultrasonic agitation in DMF such as formula the complex compound of structure (I) Suo Shi and Graphene and form modification liquid; Then polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide, vinyl phenyl silicone oil and modification liquid are mixed, then melting, cooling, granulation are with obtained 3D printer sight glass.In the process, by the synergy between each material, make the 3D printer sight glass obtained not only have excellent mechanical property, also there is excellent abrasion resistance properties simultaneously.In addition, this preparation method's raw material is easy to get, and step is simple.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of preparation method of anti abrasive 3D printer sight glass, comprising:
1) in the presence of uv light, by nanometer magnesia, be dissolved in ultrasonic agitation in DMF such as formula the complex compound of structure (I) Suo Shi and Graphene and form modification liquid;
2) polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide, vinyl phenyl silicone oil and modification liquid are mixed, then melting, cooling, granulation are with obtained 3D printer sight glass material;
3) by described 3D printer sight glass material mixing 3-4h at 180-185 DEG C, then in the shaping 40-50min of die cavity injecting 45-65 DEG C, finally cool with obtained described 3D printer sight glass at 25-35 DEG C;
Wherein, Mes is mesityl.
In step 1 of the present invention) in, ultraviolet wavelength can be selected in wide scope, but in order to make the 3D printer sight glass obtained have more excellent mechanical property and abrasion resistance properties, preferably, in step 1) in, ultraviolet wavelength is 150-200nm.
In step 1 of the present invention) in, the condition of ultrasonic agitation can be selected in wide scope, but in order to make the 3D printer sight glass obtained, there is more excellent mechanical property and abrasion resistance properties, preferably, in step 1) in, ultrasonic agitation at least meets the following conditions: hyperacoustic frequency is 25-30KHz, and whipping temp is 55-65 DEG C, and churning time is 4-6h.
In step 1 of the present invention) in, the particle diameter of nanometer magnesia can be selected in wide scope, but in order to make the 3D printer sight glass obtained have more excellent mechanical property and abrasion resistance properties, preferably, in step 1) in, the particle diameter of nanometer magnesia is 35-40nm.
In step 1 of the present invention) in, the consumption of each material can be selected in wide scope, but in order to make the 3D printer sight glass obtained, there is more excellent mechanical property and abrasion resistance properties, preferably, in step 1) in, relative to the nanometer magnesia of 100 weight parts, consumption such as formula the complex compound of structure (I) Suo Shi is 28-35 weight part, the consumption of Graphene is 3-3.5 weight part, and the consumption of DMF is 200-280 weight part.
In step 2 of the present invention) in, the consumption of each material can be selected in wide scope, but in order to make the 3D printer sight glass obtained, there is more excellent mechanical property and abrasion resistance properties, preferably, in step 2) in, relative to the polymethyl methacrylate of 100 weight parts, the consumption of Xylitol is 8-15 weight part, the consumption of aluminium hydroxide is 1-1.5 weight part, the consumption of silicon oxide is 3-7 weight part, the consumption of silver suboxide is 0.1-0.8 weight part, the consumption of rare earth oxide is 1.2-2 weight part, the consumption of vinyl phenyl silicone oil is 40-50 weight part, the consumption of modification liquid is 5-14 weight part.
In step 2 of the present invention) in, the concrete kind of rare earth oxide can be selected in wide scope, but in order to make the 3D printer sight glass obtained, there is more excellent mechanical property and abrasion resistance properties, preferably, rare earth oxide is selected from one or more in cerous oxide, cerium dioxide, Praseodymium trioxide and rubidium oxide.
In step 2 of the present invention) in, the condition of melting can be selected in wide scope, but in order to make the 3D printer sight glass obtained, there is more excellent mechanical property and abrasion resistance properties, preferably, in step 2) in, melting at least meets the following conditions: melt temperature is 175-185 DEG C, and the fusion time is 30-50min.
In step 2 of the present invention) in, the temperature of cooling can be selected in wide scope, but in order to make the 3D printer sight glass obtained have more excellent mechanical property and abrasion resistance properties, preferably, in step 2) in, the temperature of cooling is 5-15 DEG C.
Present invention also offers a kind of anti abrasive 3D printer sight glass, this 3D printer sight glass is prepared from by above-mentioned method.
Below will be described the present invention by embodiment.
Embodiment 1
1) under the existence of ultraviolet (wavelength is 180nm), by nanometer magnesia (particle diameter is 37nm), complex compound, Graphene, N such as formula structure (I) Suo Shi, dinethylformamide mixes according to the weight ratio of 100:30:3.3:250, and under the condition of ultrasonic (frequency is 27KHz) of 60 DEG C, stir 5h formation modification liquid;
2) polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide (cerous oxide), vinyl phenyl silicone oil and modification liquid are mixed according to the weight ratio of 100:10:1.2:5:0.5:1.7:45:9, then at 180 DEG C melting 40min, at 10 DEG C cooling, granulation with obtained 3D printer sight glass material;
3) by described 3D printer sight glass material mixing 3.5h at 183 DEG C, then in the shaping 45min of die cavity of injection 55 DEG C, finally cool with obtained described 3D printer sight glass A1 at 30 DEG C;
Wherein, Mes is mesityl.
Embodiment 2
1) under the existence of ultraviolet (wavelength is 150nm), by nanometer magnesia (particle diameter is 35nm), complex compound, Graphene, N such as formula structure (I) Suo Shi, dinethylformamide mixes according to the weight ratio of 100:28:3:200, and under the condition of ultrasonic (frequency is 25KHz) of 55 DEG C, stir 4h formation modification liquid;
2) polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide (Praseodymium trioxide), vinyl phenyl silicone oil and modification liquid are mixed according to the weight ratio of 100:8:1:3:0.1:1.2:40:5, then at 175 DEG C melting 30min, at 5 DEG C cooling, granulation with obtained 3D printer sight glass material;
3) by described 3D printer sight glass material mixing 3h at 180 DEG C, then in the shaping 40min of die cavity of injection 45 DEG C, finally cool with obtained described 3D printer sight glass A2 at 25 DEG C;
Wherein, Mes is mesityl.
Embodiment 3
1) under the existence of ultraviolet (wavelength is 200nm), by nanometer magnesia (particle diameter is 40nm), complex compound, Graphene, N such as formula structure (I) Suo Shi, dinethylformamide mixes according to the weight ratio of 100:35:3.5:280, and under the condition of ultrasonic (frequency is 30KHz) of 65 DEG C, stir 6h formation modification liquid;
2) polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide (rubidium oxide), vinyl phenyl silicone oil and modification liquid are mixed according to the weight ratio of 100:15:1.5:7:0.8:2:50:14, then at 185 DEG C melting 50min, at 15 DEG C cooling, granulation with obtained 3D printer sight glass material;
3) by described 3D printer sight glass material mixing 4h at 185 DEG C, then in the shaping 50min of die cavity of injection 65 DEG C, finally cool with obtained described 3D printer sight glass A3 at 35 DEG C;
Wherein, Mes is mesityl.
Comparative example 1
Carry out obtained 3D printer sight glass B1 according to the method for embodiment 1, unlike, step 1) in do not use Graphene.
Comparative example 2
Carry out obtained 3D printer sight glass B2 according to the method for embodiment 1, unlike, step 1) in do not use complex compound such as formula structure (I) Suo Shi.
Comparative example 3
Carry out obtained 3D printer sight glass B3 according to the method for embodiment 1, unlike, step 1) in do not use nanometer magnesia.
Test example 1
Detect the tensile strength of above-mentioned 3D printer sight glass, transmittance and Rockwell hardness, concrete outcome is in table 1.
Table 1
Known by above-described embodiment, comparative example and test example, anti abrasive 3D printer sight glass provided by the invention has excellent tensile strength, transmittance and hardness.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. a preparation method for anti abrasive 3D printer sight glass, is characterized in that, comprising:
1) in the presence of uv light, by nanometer magnesia, be dissolved in ultrasonic agitation in DMF such as formula the complex compound of structure (I) Suo Shi and Graphene and form modification liquid;
2) polymethyl methacrylate, Xylitol, aluminium hydroxide, silicon oxide, silver suboxide, rare earth oxide, vinyl phenyl silicone oil and described modification liquid are mixed, then melting, cooling, granulation are with obtained 3D printer sight glass material;
3) by described 3D printer sight glass material mixing 3-4h at 180-185 DEG C, then in the shaping 40-50min of die cavity injecting 45-65 DEG C, finally cool with obtained described 3D printer sight glass at 25-35 DEG C;
Wherein, Mes is mesityl.
2. preparation method according to claim 1, wherein, in step 1) in, described ultraviolet wavelength is 150-200nm.
3. preparation method according to claim 1, wherein, in step 1) in, described ultrasonic agitation at least meets the following conditions: hyperacoustic frequency is 25-30KHz, and whipping temp is 55-65 DEG C, and churning time is 4-6h.
4. preparation method according to claim 1, wherein, in step 1) in, the particle diameter of described nanometer magnesia is 35-40nm.
5. according to the preparation method in claim 1-4 described in any one, wherein, in step 1) in, relative to the described nanometer magnesia of 100 weight parts, the consumption of the described complex compound such as formula structure (I) Suo Shi is 28-35 weight part, the consumption of described Graphene is 3-3.5 weight part, and the consumption of described DMF is 200-280 weight part.
6. preparation method according to claim 5, wherein, in step 2) in, relative to the described polymethyl methacrylate of 100 weight parts, the consumption of described Xylitol is 8-15 weight part, the consumption of described aluminium hydroxide is 1-1.5 weight part, the consumption of described silicon oxide is 3-7 weight part, the consumption of described silver suboxide is 0.1-0.8 weight part, the consumption of described rare earth oxide is 1.2-2 weight part, the consumption of described vinyl phenyl silicone oil is 40-50 weight part, and the consumption of described modification liquid is 5-14 weight part.
7. preparation method according to claim 6, wherein, described rare earth oxide be selected from cerous oxide, cerium dioxide, Praseodymium trioxide and rubidium oxide one or more.
8. preparation method according to claim 6, wherein, in step 2) in, described melting at least meets the following conditions: melt temperature is 175-185 DEG C, and the fusion time is 30-50min.
9. preparation method according to claim 6, wherein, in step 2) in, the temperature of described cooling is 5-15 DEG C.
10. an anti abrasive 3D printer sight glass, is characterized in that, described 3D printer sight glass is prepared from by the method in claim 1-9 described in any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510975572.6A CN105566827A (en) | 2015-12-22 | 2015-12-22 | Wear-resistant 3D printer window glass and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510975572.6A CN105566827A (en) | 2015-12-22 | 2015-12-22 | Wear-resistant 3D printer window glass and preparation method thereof |
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| CN105566827A true CN105566827A (en) | 2016-05-11 |
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| CN201510975572.6A Pending CN105566827A (en) | 2015-12-22 | 2015-12-22 | Wear-resistant 3D printer window glass and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825019A (en) * | 2019-02-25 | 2019-05-31 | 安徽迈明亚克力科技有限公司 | A kind of multi-functional acryl plates |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446850A (en) * | 2002-03-22 | 2003-10-08 | 中国人民解放军海军工程大学 | Compound nano organic glass of protecting against X ray |
| CN101633740A (en) * | 2008-07-22 | 2010-01-27 | 上海杰事杰新材料股份有限公司 | Method for preparing transparent heat-resistant polymethyl methacrylate nano-composite membrane |
| CN102408658A (en) * | 2011-10-21 | 2012-04-11 | 上海交通大学 | Graphene modified poly-methyl methacrylate composite and preparation method thereof |
| CN103333449A (en) * | 2013-07-25 | 2013-10-02 | 中国科学院合肥物质科学研究院 | Polymethyl methacrylate-zinc hydroxide nanocomposite and preparation method thereof |
-
2015
- 2015-12-22 CN CN201510975572.6A patent/CN105566827A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446850A (en) * | 2002-03-22 | 2003-10-08 | 中国人民解放军海军工程大学 | Compound nano organic glass of protecting against X ray |
| CN101633740A (en) * | 2008-07-22 | 2010-01-27 | 上海杰事杰新材料股份有限公司 | Method for preparing transparent heat-resistant polymethyl methacrylate nano-composite membrane |
| CN102408658A (en) * | 2011-10-21 | 2012-04-11 | 上海交通大学 | Graphene modified poly-methyl methacrylate composite and preparation method thereof |
| CN103333449A (en) * | 2013-07-25 | 2013-10-02 | 中国科学院合肥物质科学研究院 | Polymethyl methacrylate-zinc hydroxide nanocomposite and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825019A (en) * | 2019-02-25 | 2019-05-31 | 安徽迈明亚克力科技有限公司 | A kind of multi-functional acryl plates |
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Application publication date: 20160511 |