CN105565405A - Vertical type rapid water purifying device and water purifying method thereof - Google Patents

Vertical type rapid water purifying device and water purifying method thereof Download PDF

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Publication number
CN105565405A
CN105565405A CN201610107380.8A CN201610107380A CN105565405A CN 105565405 A CN105565405 A CN 105565405A CN 201610107380 A CN201610107380 A CN 201610107380A CN 105565405 A CN105565405 A CN 105565405A
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water
filter tank
parts
controlling system
acid
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CN105565405B (en
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梁峙
梁骁
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Xuzhou University of Technology
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Xuzhou University of Technology
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/008—Control or steering systems not provided for elsewhere in subclass C02F
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C08G16/0212—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
    • C08G16/0218—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
    • C08G16/0225—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/003—Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/02—Temperature
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/14—Maintenance of water treatment installations
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Filtration Of Liquid (AREA)

Abstract

The invention discloses a vertical type rapid water purifying device and a water purifying method thereof. The vertical type rapid water purifying device consists of a raw water tank, a water feeding device, a filter tank, a water outlet pipe, a backwashing device, a clean water tank, a sludge discharge pipe, a bracket, a sludge collecting tank, a stirring water distribution device and a control system; raw water in the raw water tank is conveyed to the upper part of the front of the filter tank by the water feeding device, enters the filter tank, then, is subjected to dispersed flowing from top to bottom by the stirring water distribution device and finally is drained into the clean water tank from the water outlet pipe located at the left side of the bottom of the filter tank; after a system runs for two hours, valves on the water feeding device and the water outlet pipe are manually closed, then, clean water is conveyed to the bottom of the filter tank from the clean water tank by the backwashing device, slowly rises from the bottom of the filter tank and finally is drained through the sludge discharge pipe; twenty minutes later, valves on the backwashing device and the sludge discharge pipe are closed, the valves on the water feeding device and the water outlet pipe are opened again, and the device is in cycle operation in this way. The vertical type rapid water purifying device and the water purifying method thereof, disclosed by the invention, are reasonable in design and good in treatment effect and are applicable to the refiltering treatment of water treated by various sedimentation devices.

Description

A kind of vertical Quick purifying device and process for purifying water thereof
Technical field
The invention belongs to water-purification plant field, be specifically related to a kind of vertical Quick purifying device.
Background technology
Filtration is requisite key link in water technology.Filtration is in the common process of coagulation, precipitation, filtration, sterilization, and the obstruction produced the suspended impurity in water by particulate filter layer (quartz sand, hard coal) etc., adhesive attraction make water obtain the technological process of purification further.Filter tank in the surface water water purification plant being water source with river or Lake Water etc., after being placed in settling tank or settling pond, as last procedure of suspended substance removal.The vital role in filter tank is embodied in the removal to suspended substance in water and colloidalmaterial, filter tank can reduce turbidity in water effectively, this means a part of bacterium in water, virus, two worms, organic effective removal, a small amount of virus that simultaneously can not be retained by filtrate and bacterium lose colloidalmaterial to its parcel with depend on, thus more easily remove by lower sterilization process together.Therefore, filter tank is checking on property link that is indispensable, that ensure effluent quality safety in water-purifying process really, is the important measures ensureing water hygiene safety.Therefore Water purification worker attaches great importance to the effect of filtration process in link of purifying water and how better to be played.
Filtration theory and technique have passed through exploration and the research of last 100 years, constantly improve and development process in, filter progressively become be widely used, the drinking water treatment link of technology maturation.In depth probe into along with the progress of science and technology and scholars in last century, all there is larger breakthrough the inherent theory and technology aspect of coagulation, depositing technology, and filtering technique seems some stagnation.On the other hand, the drinking water quality of the source quality situation that mouth benefit is complicated and higher standard requires to also become a principal contradiction, this promotes water treatment research workers and is devoted to the exploration of filtering technique and perfect, therefore scholars still to conduct a research work to filtration process and theory, seek more economically filtering technique efficiently.
In prior art, Water treatment filtration speed is slow, and filter tank design is too short and small, and the flow having blocked filtration unit increases, filter tank actual motion poor effect.In prior art, the design place water yield in filter tank is little, effluent quality is not up to standard, with front end structures bridging mode unreasonable, the form in filter tank is single, after running, processing parameter (as filter tank single pool area, filtering velocity, filtrate grating etc.) can not adjust, and can not ensure in the sewage of change, give full play to its effect.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of vertical Quick purifying device, comprising: former pond 1, water feed apparatus 2, filter tank 3, rising pipe 4, back-purge system 5, clean water basin 6, shore pipe 7, support 8, mud-collecting slot 9, stirs water-distributing device 10, Controlling System 11; Be positioned at the former pond 1 bottom support 8 and clean water basin 6, be positioned at the filter tank 3 above support 8, with the water feed apparatus 2 be connected with filter tank 3 front upper bottom former pond 1, be positioned at the rising pipe 4 of lower left, filter tank 3, connect bottom clean water basin 6 and the back-purge system 5 of rising pipe 4 near one end, filter tank 3, be positioned at the shore pipe 7 of filter tank 3 front upper, be positioned at the stirring water-distributing device 10 of filter tank 3 inner upper, be positioned at the mud-collecting slot 9 be connected above shore pipe 7 and with filter tank 3, be positioned at the Controlling System 11 on the right side of water feed apparatus 2.
Further, described filter tank 3 comprises: filtering layer 3-1, supporting plate 3-2, and catchment frid 3-3, filtering layer inductance gauge 3-4, water level sensor 3-5; Described filtering layer 3-1 is positioned in the middle part of the body of pond, filter tank 3, supporting plate 3-2 is positioned at below filtering layer 3-1, supporting plate 3-2 tetra-limit and seamless welding vertical with filter tank 3 wall, supporting plate 3-2 there is the cell body of the up/down perforation be arranged in parallel, the quantity of cell body is no less than 60, it is inner that described filtering layer inductance gauge 3-4 inserts filtering layer 3-1 from outside, filter tank 3, and filtering layer inductance gauge 3-4 is connected with Controlling System 11 wire; The frid 3-3 that catchments is positioned at bottom the body of pond, filter tank 3, and the quantity of the frid 3-3 that catchments is 2 and front and back are symmetrical, and catchment frid 3-3 tetra-limit and filter tank 3 wall seamless welding, and the frid 3-3 that catchments is manganese steel material; Described water level sensor 3-5 is positioned at filter tank 3 inside upper part, and water level sensor 3-5 is connected with Controlling System 11 wire.
Further, the frid 3-3 that catchments described in comprises: taper slide 3-3-1, arc 3-3-2, vertical plate 3-3-3; The angle of described taper slide 3-3-1 and horizontal plane is 20 ° ~ 40 °, and welds with filter tank 3 left and right sides wall seamless; Vertical plate 3-3-3 is vertically welded in bottom filter tank 3, and left and right vertical plate 3-3-3 spacing is 10cm ~ 60cm; Arc 3-3-2 two ends respectively with taper slide 3-3-1 and vertical plate 3-3-3 seamless welding, arc 3-3-2 arc angle radius is 20cm ~ 40cm.
Further, described stirring water-distributing device 10 comprises: turning axle 10-1, rolling bearing 10-2, stirs water distribution board 10-3, and rotating shaft temperature surveys instrument 10-4; Described turning axle 10-1 one end is fixed on pool wall position, side, filter tank 3, and the turning axle 10-1 the other end drives with external motor and is connected; Described rotating shaft temperature surveys one end that instrument 10-4 is socketed in turning axle 10-1, and rotating shaft temperature is surveyed instrument 10-4 and is connected with Controlling System 11 wire; Described rolling bearing 10-2 is fixed on turning axle about 10-1 two ends and central position; Described stirring water distribution board 10-3 is screwed on rolling bearing 10-2, and stirring water distribution board 10-3 quantity is 2 ~ 4, and multiple stirring water distribution board 10-3 rotational symmetry layout, adjacent stirring water distribution board 10-3 angle is 45 ° ~ 90 °.
Further, described stirring water distribution board 10-3 comprises: long slab 10-3-1, short slab 10-3-2; Long slab 10-3-1, short slab 10-3-2 form " day " character form structure jointly, the two vertical and seamless welding; Described long slab 10-3-1 quantity is 2 ~ 4, and each long slab 10-3-1 is parallel evenly distributed, and adjacent long slab 10-3-1 spacing is 5cm ~ 15cm; Described short slab 10-3-2 quantity is 2 ~ 4, and each short slab 10-3-2 is parallel evenly distributed, and adjacent short slab 10-3-2 spacing is 15cm ~ 20cm.
Further, described Controlling System 11 and water feed apparatus 2, back-purge system 5 and stir water-distributing device 10 and be connected with wire.
Further, described long slab 10-3-1 is by macromolecular material moulded section, and moiety and the manufacturing processed of long slab 10-3-1 are as follows:
One, long slab 10-3-1 moiety:
Count by weight, 2 ~ 25 parts, base n-octyl ether, DMG ester 1 ~ 30 part, ethyl chloride 1 ~ 18 part, 3,3', 4,4'-tetramethyl diphenyl ethane 8 ~ 20 parts, Pyromellitic Acid phthalic anhydride 4 ~ 18 parts, 2,2-Dimethyl-propionic acid acid anhydride 15 ~ 25 parts, concentration is the ethyl propionate 300 ~ 500 parts of 10ppm ~ 250ppm, octadecanoic acid cetyl ester 3 ~ 19 parts, 1 ~ 17 part, lindane formic acid, linking agent 5 ~ 34 parts, Chlorodracylic acid 7 ~ 18 parts, vinylacrylic acid 3 ~ 14 parts, dimethyl tellurium 3 ~ 15 parts, the methaldehyde 7 ~ 19 parts;
Described linking agent is to any one in bromo SULPHURYL CHLORIDE, butyl disulfide tin, ethylene glycol dilaurate;
Two, the manufacturing processed of long slab 10-3-1, comprises following steps:
1st step: add the ultrapure water 300 ~ 1000 parts that specific conductivity is 0.0005 μ S/cm ~ 0.02 μ S/cm in a kettle., start agitator in reactor, rotating speed is 120rpm ~ 191rpm, starts heat pump, makes reactor temperature rise to 30 DEG C ~ 70 DEG C; Add base n-octyl ether, DMG ester, ethyl chloride successively, be stirred to and dissolve completely, adjust ph is 4.0 ~ 9.0, and agitator speed is adjusted to 70rpm ~ 95rpm, and temperature is 60 DEG C ~ 80 DEG C, esterification 2 ~ 11 hours;
2nd step: get 3,3', 4,4'-tetramethyl diphenyl ethane, Pyromellitic Acid phthalic anhydride are pulverized, and powder diameter is 500 ~ 600 orders; Add 2,2-Dimethyl-propionic acid acid anhydride to mix, be laid in pallet, tiling thickness is 30mm ~ 40mm, and employing dosage is 2.5kGy ~ 5.5kGy, gamma-ray irradiation that energy is 3.0MeV ~ 12MeV 20 ~ 45 minutes;
3rd step: the mixed powder through the 2nd step process is dissolved in ethyl propionate, add reactor, agitator speed is 70rpm ~ 95rpm, and temperature is 70 DEG C ~ 85 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.02MPa ~-0.07MPa, keeps this state response 3 ~ 9 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.007MPa ~ 0.015MPa, and insulation leaves standstill 1 ~ 8 hour; Agitator speed is promoted to 95rpm ~ 155rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add octadecanoic acid cetyl ester successively, after lindane formic acid dissolves completely, add linking agent and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 4.3 ~ 8.5, insulation leaves standstill 1 ~ 3 hour;
4th step: when agitator speed is 80rpm ~ 150rpm, add Chlorodracylic acid, vinylacrylic acid, dimethyl tellurium and the methaldehyde successively, promote reactor pressure, make it reach 0.07MPa ~ 0.15MPa, temperature is 120 DEG C ~ 130 DEG C, polyreaction 2 ~ 20 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 30 DEG C ~ 45 DEG C, discharging, enter press molding machine and can obtain long slab 10-3-1.
Further, described short slab 10-3-2 is by macromolecular material moulded section, and moiety and the manufacturing processed of long slab short slab 10-3-2 are as follows:
One, short slab 10-3-2 moiety:
Count by weight, 5 ~ 20 parts, base n-octyl ether, sweet Pu acid methyl esters 4 ~ 18 parts, ethyl chloride 3 ~ 15 parts, equal tetraphenylethane 7 ~ 19 parts, Pyromellitic Acid phthalic anhydride 8 ~ 16 parts, methyl chloride carbic anhydride 7 ~ 22 parts, concentration is the ethyl propionate 400 ~ 600 parts of 15ppm ~ 250ppm, ethyl palmitate 2 ~ 11 parts, 1 ~ 19 part, lindane formic acid, linking agent 1 ~ 14 part, Chlorodracylic acid 3 ~ 11 parts, vinylacrylic acid 4 ~ 17 parts, dimethyl tellurium 2 ~ 10 parts, the methaldehyde 9 ~ 13 parts;
Described linking agent is to any one in bromo SULPHURYL CHLORIDE, butyl disulfide tin, ethylene glycol dilaurate;
Two, the manufacturing processed of short slab 10-3-2, comprises following steps:
1st step: add the ultrapure water 200 ~ 900 parts that specific conductivity is 0.0003 μ S/cm ~ 0.025 μ S/cm in a kettle., start agitator in reactor, rotating speed is 125rpm ~ 210rpm, starts heat pump, makes reactor temperature rise to 35 DEG C ~ 80 DEG C; Add base n-octyl ether, the acid of sweet Pu methyl esters, ethyl chloride successively, be stirred to and dissolve completely, adjust ph is 3.0 ~ 9.0, and agitator speed is adjusted to 80rpm ~ 100rpm, and temperature is 60 DEG C ~ 90 DEG C, esterification 3 ~ 9 hours;
2nd step: get equal tetraphenylethane, Pyromellitic Acid phthalic anhydride is pulverized, powder diameter is 400 ~ 550 orders; Add methyl chloride carbic anhydride to mix, be laid in pallet, tiling thickness is 20mm ~ 55mm, and employing dosage is 4.0kGy ~ 6.5kGy, alpha-ray irradiation that energy is 1.0MeV ~ 12MeV 10 ~ 45 minutes;
3rd step: the mixed powder through the 2nd step process is dissolved in ethyl propionate, add reactor, agitator speed is 90rpm ~ 105rpm, and temperature is 60 DEG C ~ 85 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.015MPa ~-0.09MPa, keeps this state response 2 ~ 7 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.0065MPa ~ 0.018MPa, and insulation leaves standstill 3 ~ 10 hours; Agitator speed is promoted to 100rpm ~ 175rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add ethyl palmitate successively, after lindane formic acid dissolves completely, add linking agent and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 3.7 ~ 7.8, insulation leaves standstill 2 ~ 5 hours;
4th step: when agitator speed is 90rpm ~ 130rpm, add Chlorodracylic acid, vinylacrylic acid, dimethyl tellurium and the methaldehyde successively, promote reactor pressure, make it reach 0.055MPa ~ 0.20MPa, temperature is 140 DEG C ~ 160 DEG C, polyreaction 2 ~ 15 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 20 DEG C ~ 35 DEG C, discharging, enter press molding machine and can obtain short slab 10-3-2.
Further, the invention also discloses a kind of process for purifying water of vertical Quick purifying device, this process for purifying water comprises following step:
1st step: first use Controlling System 11 starts the motor in water feed apparatus 2, and after the sewage in former pond 1 being squeezed into filter tank 3,10min, Controlling System 11 starts the motor stirred in water-distributing device 10, carries out stirring precipitation process to sewage;
2nd step: the sewage after preliminary treatment, in filter tank 3, by the filteration of filtering layer 3-1, produces clear water by supporting plate 3-2, is finally pooled to and catchments in frid 3-3, then enter in clean water basin 6 by rising pipe 4;
3rd step: the filtering layer inductance gauge 3-4 in system detects the filter effect of filtering layer 3-1 in real time, when filtering layer 3-1 filter effect lower than 20% time, filtering layer inductance gauge 3-4 feeds back signal to Controlling System 11, Controlling System 11 shut-off device power supply, equipment is quit work, and sends sound signal and notify to safeguard before serviceman; When the filter effect of filtering layer 3-1 returns to standard, filtering layer inductance gauge 3-4 feeds back signal to Controlling System 11, and Controlling System 11 switching on device power supply, makes equipment resume work;
4th step: when in filter tank 3, mud impurity increases, supervisory system sends signal to Controlling System 11, Controlling System 11 stops the sewage treatment works of this device, and start back-purge system 5 pairs of filter tanks 3 simultaneously and carry out back flushing, backwashing sewage water is discharged by shore pipe 7;
5th step: when the water level sensor 3-5 being arranged in filter tank 3 perceives filter tank 3 water level decreasing to lowest water level, generation feeds back signal to Controlling System 11, Controlling System 11 impels the water pump enlargement discharge in water feed apparatus 2 to carry, to input in filter tank 3 bottom water feed apparatus 2 with being stored in the sewage large discharge in former pond 1, to maintain the normal work of this device; When water level sensor 3-5 perceive filter tank 3 water level exceed early warning value water level time, produce feed back signal to Controlling System 11, Controlling System 11 is cut off the electricity supply and single unit system is quit work, and sends sound signal simultaneously, notifies that Administrator safeguards equipment; When water level sensor 3-5 perceives filter tank 3 water level rezime to normal value, produce and feed back signal to Controlling System 11, Controlling System 11 switches on power and makes this device recover normal processing work;
6th step: rotating shaft temperature is surveyed instrument 10-4 and detected the axle temperature of rolling bearing 10-2 in real time, when rotating shaft temperature survey instrument 10-4 monitor rolling bearing 10-2 temperature exceed safety range time; Generation feeds back signal to Controlling System 11, and Controlling System 11 is cut off the electricity supply and this device is quit work, and sends sound signal simultaneously, notifies that Administrator safeguards equipment; When rotating shaft temperature survey instrument 10-4 monitors rolling bearing 10-2 temperature return to normal value, produce and feed back signal to Controlling System 11, Controlling System 11 switches on power and makes this device recover normal processing work.
A kind of vertical Quick purifying device and process for purifying water thereof disclosed in patent of the present invention, its advantage is:
(1) this device adopts water distribution whipping appts structure, makes former water distribution more releive evenly;
(2) this device catchments frid modern design, makes current transition more steady;
(3) this apparatus structure is reasonable, and perfect technology, processing efficiency is high.
A kind of vertical Quick purifying apparatus design of the present invention is reasonable, and structure is simple, and treatment effect is good, and after being applicable to all kinds of sedimentation device process, water refilters process.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of a kind of vertical Quick purifying device described in the present invention.
Fig. 2 is the schematic diagram in the filter tank described in the present invention.
Fig. 3 is the schematic diagram of the frid that catchments described in the present invention.
Fig. 4 is the schematic diagram of the stirring water-distributing device described in the present invention.
Fig. 5 is the schematic diagram of the stirring water distribution board described in the present invention.
Fig. 6 is that the long slab described in the present invention and short slab are to the settling efficiency of sewage.
In above Fig. 1 ~ Fig. 5, former pond 1, water feed apparatus 2, filter tank 3, filtering layer 3-1, supporting plate 3-2, catchment frid 3-3, taper slide 3-3-1, arc 3-3-2, vertical plate 3-3-3, filtering layer inductance gauge 3-4, water level sensor 3-5, rising pipe 4, back-purge system 5, clean water basin 6, shore pipe 7, support 8, mud-collecting slot 9, stirs water-distributing device 10, turning axle 10-1, rolling bearing 10-2, stirs water distribution board 10-3, and rotating shaft temperature surveys instrument 10-4, Controlling System 11.
Embodiment
Below in conjunction with accompanying drawing and example, a kind of vertical Quick purifying device provided by the invention is further described.
As shown in Figure 1, be the schematic diagram of a kind of vertical Quick purifying device described in the present invention.Find out in figure, comprising: former pond 1, water feed apparatus 2, filter tank 3, rising pipe 4, back-purge system 5, clean water basin 6, shore pipe 7, support 8, mud-collecting slot 9, stir water-distributing device 10, Controlling System 11; Be positioned at the former pond 1 bottom support 8 and clean water basin 6, be positioned at the filter tank 3 above support 8, with the water feed apparatus 2 be connected with filter tank 3 front upper bottom former pond 1, be positioned at the rising pipe 4 of lower left, filter tank 3, connect bottom clean water basin 6 and the back-purge system 5 of rising pipe 4 near one end, filter tank 3, be positioned at the shore pipe 7 of filter tank 3 front upper, be positioned at the stirring water-distributing device 10 of filter tank 3 inner upper, be positioned at the mud-collecting slot 9 be connected above shore pipe 7 and with filter tank 3, be positioned at the Controlling System 11 on the right side of water feed apparatus 2.
As shown in Figure 2, be the schematic diagram in the filter tank described in the present invention.Find out in Fig. 2 or Fig. 1, filter tank 3 comprises: filtering layer 3-1, supporting plate 3-2, and catchment frid 3-3, filtering layer inductance gauge 3-4, water level sensor 3-5; Filtering layer 3-1 is positioned in the middle part of the body of pond, filter tank 3, supporting plate 3-2 is positioned at below filtering layer 3-1, supporting plate 3-2 tetra-limit and seamless welding vertical with filter tank 3 wall, supporting plate 3-2 there is the cell body of the up/down perforation be arranged in parallel, the quantity of cell body is no less than 60, it is inner that filtering layer inductance gauge 3-4 inserts filtering layer 3-1 from outside, filter tank 3, and filtering layer inductance gauge 3-4 is connected with Controlling System 11 wire; The frid 3-3 that catchments is positioned at bottom the body of pond, filter tank 3, and the quantity of the frid 3-3 that catchments is 2 and front and back are symmetrical, and catchment frid 3-3 tetra-limit and filter tank 3 wall seamless welding, and the frid 3-3 that catchments is manganese steel material; Water level sensor 3-5 is positioned at filter tank 3 inside upper part, and water level sensor 3-5 is connected with Controlling System 11 wire.
As shown in Figure 3, be the schematic diagram of the frid that catchments described in the present invention.Find out in Fig. 3 or Fig. 1, the frid 3-3 that catchments comprises: taper slide 3-3-1, arc 3-3-2, vertical plate 3-3-3; The angle of taper slide 3-3-1 and horizontal plane is 20 ° ~ 40 °, and welds with filter tank 3 left and right sides wall seamless; Vertical plate 3-3-3 is vertically welded in bottom filter tank 3, and left and right vertical plate 3-3-3 spacing is 10cm ~ 60cm; Arc 3-3-2 two ends respectively with taper slide 3-3-1 and vertical plate 3-3-3 seamless welding, arc 3-3-2 arc angle radius is 20cm ~ 40cm.
As shown in Figure 4, be the schematic diagram of the stirring water-distributing device described in the present invention.Find out in Fig. 4 or Fig. 1, stir water-distributing device 10 and comprise: turning axle 10-1, rolling bearing 10-2, stir water distribution board 10-3, rotating shaft temperature surveys instrument 10-4; Turning axle 10-1 one end is fixed on pool wall position, side, filter tank 3, and the turning axle 10-1 the other end drives with external motor and is connected; Rotating shaft temperature surveys one end that instrument 10-4 is socketed in turning axle 10-1, and rotating shaft temperature is surveyed instrument 10-4 and is connected with Controlling System 11 wire; Rolling bearing 10-2 is fixed on turning axle about 10-1 two ends and central position; Stirring water distribution board 10-3 is screwed on rolling bearing 10-2, and stirring water distribution board 10-3 quantity is 2 ~ 4, and multiple stirring water distribution board 10-3 rotational symmetry layout, adjacent stirring water distribution board 10-3 angle is 45 ° ~ 90 °.
As shown in Figure 5, be the schematic diagram of the stirring water distribution board described in the present invention.Find out in Fig. 5 or Fig. 1, stir water distribution board 10-3 and comprise: long slab 10-3-1, short slab 10-3-2; Long slab 10-3-1, short slab 10-3-2 form " day " character form structure jointly, the two vertical and seamless welding; Long slab 10-3-1 quantity is 2 ~ 4, and each long slab 10-3-1 is parallel evenly distributed, and adjacent long slab 10-3-1 spacing is 5cm ~ 15cm; Short slab 10-3-2 quantity is 2 ~ 4, and each short slab 10-3-2 is parallel evenly distributed, and adjacent short slab 10-3-2 spacing is 15cm ~ 20cm.
Controlling System 11 and water feed apparatus 2, back-purge system 5 and stir water-distributing device 10 and be connected with wire.
Be below the embodiment of the manufacturing processed of long slab 10-3-1 of the present invention and short slab 10-3-2, embodiment is to further illustrate content of the present invention, but should not be construed as limitation of the present invention.Without departing from the spirit and substance of the case in the present invention, the amendment do the inventive method, step or condition and replacement, all belong to scope of the present invention.
If do not specialize, the conventional means that technique means used in embodiment is well known to those skilled in the art.
Embodiment 1
One, according to following steps, and meter manufactures long slab 10-3-1 of the present invention by weight:
1st step: add the ultrapure water 300 parts that specific conductivity is 0.0005 μ S/cm in a kettle., start agitator in reactor, rotating speed is 120rpm, starts heat pump, makes reactor temperature rise to 30 DEG C; Add 2 parts, base n-octyl ether successively, DMG ester 1 part, ethyl chloride 1 part, is stirred to and dissolves completely, and adjust ph is 4.0, and agitator speed is adjusted to 70rpm, and temperature is 60 DEG C, esterification 2 hours;
2nd step: get 3,3', 4,4'-tetramethyl diphenyl ethane 8 parts, Pyromellitic Acid phthalic anhydride 4 parts is pulverized, and powder diameter is 500 orders; Add 2,2-Dimethyl-propionic acid acid anhydride 15 parts to mix, be laid in pallet, tiling thickness is 30mm, and employing dosage is 2.5kGy, gamma-ray irradiation that energy is 3.0MeV 20 minutes;
3rd step: it is in the ethyl propionate 300 parts of 10ppm that the mixed powder through the 2nd step process is dissolved in concentration, and add reactor, agitator speed is 70rpm, and temperature is 70 DEG C, starts vacuum pump and makes the vacuum tightness of reactor reach-0.02MPa, when keeping this state response 3; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.007MPa, and insulation leaves standstill 1 hour; Agitator speed is promoted to 95rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add octadecanoic acid cetyl ester 3 parts successively, after 1 part, lindane formic acid dissolves completely, add linking agent 5 parts and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 4.3, insulation leaves standstill 1 hour;
4th step: when agitator speed is 80rpm, adds Chlorodracylic acid 7 parts successively, vinylacrylic acid 3 parts, dimethyl tellurium 3 parts, the methaldehyde 7 parts, and promote reactor pressure, make it reach 0.07MPa, temperature is 120 DEG C, polyreaction 2 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 30 DEG C, discharging, enter press molding machine and can obtain long slab 10-3-1.
Described linking agent is to bromo SULPHURYL CHLORIDE.
Two, according to following steps, and meter manufactures short slab 10-3-2 of the present invention by weight:
1st step: add the ultrapure water 200 parts that specific conductivity is 0.0003 μ S/cm in a kettle., start agitator in reactor, rotating speed is 125rpm, starts heat pump, makes reactor temperature rise to 35 DEG C; Add 5 parts, base n-octyl ether successively, sweet Pu acid methyl esters 4 parts, ethyl chloride 3 parts, is stirred to and dissolves completely, and adjust ph is 3.0, and agitator speed is adjusted to 80rpm, and temperature is 60 DEG C, esterification 3 hours;
2nd step: get all tetraphenylethanes 7 parts, Pyromellitic Acid phthalic anhydride 8 parts is pulverized, and powder diameter is 400 orders; Add methyl chloride carbic anhydride 7 parts to mix, be laid in pallet, tiling thickness is 20mm, and employing dosage is 4.0kGy, alpha-ray irradiation that energy is 1.0MeV 10 minutes;
3rd step: it is in the ethyl propionate 400 parts of 15ppm that the mixed powder through the 2nd step process is dissolved in concentration, add reactor, agitator speed is 90rpm, and temperature is 60 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.015MPa, keeps this state response 2 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.0065MPa, and insulation leaves standstill 3 hours; Agitator speed is promoted to 100rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add ethyl palmitate 2 parts successively, after 1 part, lindane formic acid dissolves completely, add linking agent 1 part and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 3.7, insulation leaves standstill 2 hours;
4th step: when agitator speed is 90rpm, adds Chlorodracylic acid 3 parts successively, vinylacrylic acid 4 parts, dimethyl tellurium 2 parts, the methaldehyde 9 parts, and promote reactor pressure, make it reach 0.055MPa, temperature is 140 DEG C, polyreaction 2 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 20 DEG C, discharging, enter press molding machine and can obtain short slab 10-3-2.
Described linking agent is to bromo SULPHURYL CHLORIDE.
Embodiment 2
One, according to following steps, and meter manufactures long slab 10-3-1 of the present invention by weight:
1st step: add the ultrapure water 1000 parts that specific conductivity is 0.02 μ S/cm in a kettle., start agitator in reactor, rotating speed is 191rpm, starts heat pump, makes reactor temperature rise to 70 DEG C; Add 25 parts, base n-octyl ether successively, DMG ester 30 parts, ethyl chloride 18 parts, is stirred to and dissolves completely, and adjust ph is 9.0, and agitator speed is adjusted to 95rpm, and temperature is 80 DEG C, esterification 11 hours;
2nd step: get 3,3', 4,4'-tetramethyl diphenyl ethane 20 parts, Pyromellitic Acid phthalic anhydride 18 parts is pulverized, and powder diameter is 600 orders; Add 2,2-Dimethyl-propionic acid acid anhydride 25 parts to mix, be laid in pallet, tiling thickness is 40mm, and employing dosage is 5.5kGy, gamma-ray irradiation that energy is 12MeV 45 minutes;
3rd step: it is in the ethyl propionate 500 parts of 250ppm that the mixed powder through the 2nd step process is dissolved in concentration, add reactor, agitator speed is 95rpm, and temperature is 85 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.07MPa, keeps this state response 9 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.015MPa, and insulation leaves standstill 8 hours; Agitator speed is promoted to 155rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add octadecanoic acid cetyl ester 19 parts successively, after 17 parts, lindane formic acid dissolves completely, add linking agent 34 parts and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 8.5, insulation leaves standstill 3 hours;
4th step: when agitator speed is 150rpm, adds Chlorodracylic acid 18 parts successively, vinylacrylic acid 14 parts, dimethyl tellurium 15 parts, the methaldehyde 19 parts, and promote reactor pressure, make it reach 0.15MPa, temperature is 130 DEG C, polyreaction 20 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 45 DEG C, discharging, enter press molding machine and can obtain long slab 10-3-1.
Described linking agent is ethylene glycol dilaurate.
Two, according to following steps, and meter manufactures short slab 10-3-2 of the present invention by weight:
1st step: add the ultrapure water 900 parts that specific conductivity is 0.025 μ S/cm in a kettle., start agitator in reactor, rotating speed is 210rpm, starts heat pump, makes reactor temperature rise to 80 DEG C; Add 20 parts, base n-octyl ether successively, sweet Pu acid methyl esters 18 parts, ethyl chloride 15 parts, is stirred to and dissolves completely, and adjust ph is 9.0, and agitator speed is adjusted to 100rpm, and temperature is 90 DEG C, esterification 9 hours;
2nd step: get all tetraphenylethanes 19 parts, Pyromellitic Acid phthalic anhydride 16 parts is pulverized, and powder diameter is 550 orders; Add methyl chloride carbic anhydride 22 parts to mix, be laid in pallet, tiling thickness is 55mm, and employing dosage is 6.5kGy, alpha-ray irradiation that energy is 12MeV 45 minutes;
3rd step: it is in the ethyl propionate 600 parts of 250ppm that the mixed powder through the 2nd step process is dissolved in concentration, add reactor, agitator speed is 105rpm, and temperature is 85 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.09MPa, keeps this state response 7 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.018MPa, and insulation leaves standstill 10 hours; Agitator speed is promoted to 175rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add ethyl palmitate 11 parts successively, after 19 parts, lindane formic acid dissolves completely, add linking agent 14 parts and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 7.8, insulation leaves standstill 5 hours;
4th step: when agitator speed is 130rpm, adds Chlorodracylic acid 11 parts successively, vinylacrylic acid 17 parts, dimethyl tellurium 10 parts, the methaldehyde 13 parts, and promote reactor pressure, make it reach 0.20MPa, temperature is 160 DEG C, polyreaction 15 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 35 DEG C, discharging, enter press molding machine and can obtain short slab 10-3-2.
Described linking agent is ethylene glycol dilaurate.
Embodiment 3
One, according to following steps, and meter manufactures long slab 10-3-1 of the present invention by weight:
1st step: add the ultrapure water 378 parts that specific conductivity is 0.000785 μ S/cm in a kettle., start agitator in reactor, rotating speed is 145rpm, starts heat pump, makes reactor temperature rise to 37 DEG C; Add 12 parts, base n-octyl ether successively, DMG ester 12 parts, ethyl chloride 12 parts, is stirred to and dissolves completely, and adjust ph is 5.0, and agitator speed is adjusted to 78rpm, and temperature is 78 DEG C, esterification 10 hours;
2nd step: get 3,3', 4,4'-tetramethyl diphenyl ethane 10 parts, Pyromellitic Acid phthalic anhydride 10 parts is pulverized, and powder diameter is 550 orders; Add 2,2-Dimethyl-propionic acid acid anhydride 20 parts to mix, be laid in pallet, tiling thickness is 35mm, and employing dosage is 2.9kGy, gamma-ray irradiation that energy is 3.9MeV 25 minutes;
3rd step: it is in the ethyl propionate 345 parts of 20ppm that the mixed powder through the 2nd step process is dissolved in concentration, add reactor, agitator speed is 80rpm, and temperature is 78 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.021MPa, keeps this state response 8 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.0078MPa, and insulation leaves standstill 7 hours; Agitator speed is promoted to 100rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add octadecanoic acid cetyl ester 10 parts successively, after 10 parts, lindane formic acid dissolves completely, add linking agent 10 parts and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 5.5, insulation leaves standstill 2 hours;
4th step: when agitator speed is 90rpm, adds Chlorodracylic acid 10 parts successively, vinylacrylic acid 10 parts, dimethyl tellurium 10 parts, the methaldehyde 10 parts, and promote reactor pressure, make it reach 0.078MPa, temperature is 125 DEG C, polyreaction 10 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 35 DEG C, discharging, enter press molding machine and can obtain long slab 10-3-1.
Described linking agent is butyl disulfide tin.
Two, according to following steps, and meter manufactures short slab 10-3-2 of the present invention by weight:
1st step: add the ultrapure water 230 parts that specific conductivity is 0.00038 μ S/cm in a kettle., start agitator in reactor, rotating speed is 145rpm, starts heat pump, makes reactor temperature rise to 39 DEG C; Add 15 parts, base n-octyl ether successively, sweet Pu acid methyl esters 14 parts, ethyl chloride 10 parts, is stirred to and dissolves completely, and adjust ph is 4.5, and agitator speed is adjusted to 90rpm, and temperature is 70 DEG C, esterification 4 hours;
2nd step: get all tetraphenylethanes 8 parts, Pyromellitic Acid phthalic anhydride 10 parts is pulverized, and powder diameter is 440 orders; Add methyl chloride carbic anhydride 10 parts to mix, be laid in pallet, tiling thickness is 30mm, and employing dosage is 4.5kGy, alpha-ray irradiation that energy is 1.5MeV 20 minutes;
3rd step: it is in the ethyl propionate 450 parts of 20ppm that the mixed powder through the 2nd step process is dissolved in concentration, add reactor, agitator speed is 99rpm, and temperature is 68 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.0151MPa, keeps this state response 8 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.00651MPa, and insulation leaves standstill 5 hours; Agitator speed is promoted to 150rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add ethyl palmitate 8 parts successively, after 10 parts, lindane formic acid dissolves completely, add linking agent 10 parts and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 3.8, insulation leaves standstill 3 hours;
4th step: when agitator speed is 100rpm, adds Chlorodracylic acid 10 parts successively, vinylacrylic acid 10 parts, dimethyl tellurium 8 parts, the methaldehyde 10 parts, and promote reactor pressure, make it reach 0.0555MPa, temperature is 150 DEG C, polyreaction 10 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 25 DEG C, discharging, enter press molding machine and can obtain short slab 10-3-2.
Described linking agent is butyl disulfide tin.
Reference examples
Reference examples is the treating processes of agitating plate for sewage of certain brand commercially available.
Embodiment 4
Long slab 10-3-1 embodiment 1 ~ 3 prepared and short slab 10-3-2, the treatment effect being used for sewage with the agitating plate described in reference examples contrasts.Process terminates the rear character respectively sewage being promoted to degraded, carries out detection contrast.Table 1 embodiment 1 ~ 3 and reference examples agitating plate are to the promotion degraded contrast of sewage.
As seen from Table 1, the present invention prepares long slab 10-3-1 and short slab 10-3-2, and it promotes that degree of degradation, degraded strength enhancing rate, throw out output enhancing rate, water purification rate are all higher than the product that prior art is produced.
In addition, as shown in Figure 6, be that long slab 10-3-1 of the present invention and short slab 10-3-2 is to the settling efficiency of particulate.Find out in figure, the long slab 10-3-1 manufactured by macromolecular material and short slab 10-3-2 material are evenly distributed, and material surface is long-pending comparatively large with volume ratio, and Dispersion on surface is good, and the relative concentration reference examples of dispersible carrier free in external phase is high.Use long slab 10-3-1 of the present invention and short slab 10-3-2, depositing particles is assembled agglomerating little, form the precipitation body of dispersed texture, the long slab 10-3-1 manufactured by macromolecular material and short slab 10-3-2 has particulate in sewage and well promotes settling property; Its product settling efficiency is better than currently available products.

Claims (9)

1. a vertical Quick purifying device, comprise: former pond (1), water feed apparatus (2), filter tank (3), rising pipe (4), back-purge system (5), clean water basin (6), shore pipe (7), support (8), mud-collecting slot (9), stirs water-distributing device (10), Controlling System (11), it is characterized in that, be positioned at former pond (1) and the clean water basin (6) of support (8) bottom, be positioned at the filter tank (3) of support (8) top, the water feed apparatus (2) be connected with filter tank (3) front upper with former pond (1) bottom, be positioned at the rising pipe (4) of filter tank (3) lower left, connect clean water basin (6) bottom and the back-purge system (5) of rising pipe (4) near filter tank (3) one end, be positioned at the shore pipe (7) of filter tank (3) front upper, be positioned at the stirring water-distributing device (10) of filter tank (3) inner upper, be positioned at shore pipe (7) top and the mud-collecting slot (9) be connected with filter tank (3), be positioned at the Controlling System (11) on water feed apparatus (2) right side.
2. a kind of vertical Quick purifying device according to claim 1, it is characterized in that, described filter tank (3) comprising: filtering layer (3-1), supporting plate (3-2), catchment frid (3-3), filtering layer inductance gauge (3-4), water level sensor (3-5); Described filtering layer (3-1) is positioned in the middle part of the body of filter tank (3) pond, supporting plate (3-2) is positioned at filtering layer (3-1) below, supporting plate (3-2) four limit and seamless welding vertical with filter tank (3) wall, supporting plate (3-2) there is the cell body of the up/down perforation be arranged in parallel, the quantity of cell body is no less than 60, it is inner that described filtering layer inductance gauge (3-4) inserts filtering layer (3-1) from filter tank (3) outside, and filtering layer inductance gauge (3-4) is connected with Controlling System (11) wire; The frid (3-3) that catchments is positioned at bottom the body of filter tank (3) pond, the quantity of frid (3-3) of catchmenting is 2 and front and back are symmetrical, catchment frid (3-3) four limit and filter tank (3) wall seamless welding, and the frid that catchments (3-3) is manganese steel material; Described water level sensor (3-5) is positioned at filter tank (3) inside upper part, and water level sensor (3-5) is connected with Controlling System (11) wire.
3. a kind of vertical Quick purifying device according to claim 2, is characterized in that, described in the frid (3-3) that catchments comprising: taper slide (3-3-1), arc (3-3-2), vertical plate (3-3-3); Described taper slide (3-3-1) is 20 ° ~ 40 ° with the angle of horizontal plane, and welds with filter tank (3) left and right sides wall seamless; Vertical plate (3-3-3) is vertically welded in bottom, filter tank (3), and left and right vertical plate (3-3-3) spacing is 10cm ~ 60cm; Arc (3-3-2) two ends respectively with taper slide (3-3-1) and vertical plate (3-3-3) seamless welding, arc (3-3-2) arc angle radius is 20cm ~ 40cm.
4. a kind of vertical Quick purifying device according to claim 1, it is characterized in that, described stirring water-distributing device (10) comprising: turning axle (10-1), rolling bearing (10-2), stir water distribution board (10-3), rotating shaft temperature surveys instrument (10-4); Described turning axle (10-1) one end is fixed on pool wall position, filter tank (3) side, and turning axle (10-1) the other end drives with external motor and is connected; Described rotating shaft temperature surveys one end that instrument (10-4) is socketed in turning axle (10-1), and rotating shaft temperature is surveyed instrument (10-4) and is connected with Controlling System (11) wire; Described rolling bearing (10-2) is fixed on turning axle (10-1) two ends, left and right and central position; Described stirring water distribution board (10-3) is screwed on rolling bearing (10-2), stirring water distribution board (10-3) quantity is 2 ~ 4, multiple stirring water distribution board (10-3) rotational symmetry layout, adjacent stirring water distribution board (10-3) angle is 45 ° ~ 90 °.
5. a kind of vertical Quick purifying device according to claim 4, is characterized in that, described stirring water distribution board (10-3) comprising: long slab (10-3-1), short slab (10-3-2); Long slab (10-3-1), short slab (10-3-2) be composition " day " character form structure jointly, the two vertical and seamless welding; Described long slab (10-3-1) quantity is 2 ~ 4, and each long slab (10-3-1) is parallel evenly distributed, and adjacent long slab (10-3-1) spacing is 5cm ~ 15cm; Described short slab (10-3-2) quantity is 2 ~ 4, and each short slab (10-3-2) is parallel evenly distributed, and adjacent short slab (10-3-2) spacing is 15cm ~ 20cm.
6. a kind of vertical Quick purifying device according to claim 1, it is characterized in that, described Controlling System (11) and water feed apparatus (2), back-purge system (5) and stir water-distributing device (10) and be connected with wire.
7. a kind of vertical Quick purifying device according to claim 5, is characterized in that, described long slab (10-3-1) is by macromolecular material moulded section, and moiety and the manufacturing processed of long slab (10-3-1) are as follows:
One, long slab (10-3-1) moiety:
Count by weight, 2 ~ 25 parts, base n-octyl ether, DMG ester 1 ~ 30 part, ethyl chloride 1 ~ 18 part, 3,3', 4,4'-tetramethyl diphenyl ethane 8 ~ 20 parts, Pyromellitic Acid phthalic anhydride 4 ~ 18 parts, 2,2-Dimethyl-propionic acid acid anhydride 15 ~ 25 parts, concentration is the ethyl propionate 300 ~ 500 parts of 10ppm ~ 250ppm, octadecanoic acid cetyl ester 3 ~ 19 parts, 1 ~ 17 part, lindane formic acid, linking agent 5 ~ 34 parts, Chlorodracylic acid 7 ~ 18 parts, vinylacrylic acid 3 ~ 14 parts, dimethyl tellurium 3 ~ 15 parts, the methaldehyde 7 ~ 19 parts;
Described linking agent is to any one in bromo SULPHURYL CHLORIDE, butyl disulfide tin, ethylene glycol dilaurate;
Two, the manufacturing processed of long slab (10-3-1), comprises following steps:
1st step: add the ultrapure water 300 ~ 1000 parts that specific conductivity is 0.0005 μ S/cm ~ 0.02 μ S/cm in a kettle., start agitator in reactor, rotating speed is 120rpm ~ 191rpm, starts heat pump, makes reactor temperature rise to 30 DEG C ~ 70 DEG C; Add base n-octyl ether, DMG ester, ethyl chloride successively, be stirred to and dissolve completely, adjust ph is 4.0 ~ 9.0, and agitator speed is adjusted to 70rpm ~ 95rpm, and temperature is 60 DEG C ~ 80 DEG C, esterification 2 ~ 11 hours;
2nd step: get 3,3', 4,4'-tetramethyl diphenyl ethane, Pyromellitic Acid phthalic anhydride are pulverized, and powder diameter is 500 ~ 600 orders; Add 2,2-Dimethyl-propionic acid acid anhydride to mix, be laid in pallet, tiling thickness is 30mm ~ 40mm, and employing dosage is 2.5kGy ~ 5.5kGy, gamma-ray irradiation that energy is 3.0MeV ~ 12MeV 20 ~ 45 minutes;
3rd step: the mixed powder through the 2nd step process is dissolved in ethyl propionate, add reactor, agitator speed is 70rpm ~ 95rpm, and temperature is 70 DEG C ~ 85 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.02MPa ~-0.07MPa, keeps this state response 3 ~ 9 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.007MPa ~ 0.015MPa, and insulation leaves standstill 1 ~ 8 hour; Agitator speed is promoted to 95rpm ~ 155rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add octadecanoic acid cetyl ester successively, after lindane formic acid dissolves completely, add linking agent and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 4.3 ~ 8.5, insulation leaves standstill 1 ~ 3 hour;
4th step: when agitator speed is 80rpm ~ 150rpm, add Chlorodracylic acid, vinylacrylic acid, dimethyl tellurium and the methaldehyde successively, promote reactor pressure, make it reach 0.07MPa ~ 0.15MPa, temperature is 120 DEG C ~ 130 DEG C, polyreaction 2 ~ 20 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 30 DEG C ~ 45 DEG C, discharging, enter press molding machine and can obtain long slab (10-3-1).
8. a kind of vertical Quick purifying device according to claim 5, is characterized in that, described short slab (10-3-2) is by macromolecular material moulded section, and moiety and the manufacturing processed of long slab short slab (10-3-2) are as follows:
One, short slab (10-3-2) moiety:
Count by weight, 5 ~ 20 parts, base n-octyl ether, sweet Pu acid methyl esters 4 ~ 18 parts, ethyl chloride 3 ~ 15 parts, equal tetraphenylethane 7 ~ 19 parts, Pyromellitic Acid phthalic anhydride 8 ~ 16 parts, methyl chloride carbic anhydride 7 ~ 22 parts, concentration is the ethyl propionate 400 ~ 600 parts of 15ppm ~ 250ppm, ethyl palmitate 2 ~ 11 parts, 1 ~ 19 part, lindane formic acid, linking agent 1 ~ 14 part, Chlorodracylic acid 3 ~ 11 parts, vinylacrylic acid 4 ~ 17 parts, dimethyl tellurium 2 ~ 10 parts, the methaldehyde 9 ~ 13 parts;
Described linking agent is to any one in bromo SULPHURYL CHLORIDE, butyl disulfide tin, ethylene glycol dilaurate;
Two, the manufacturing processed of short slab (10-3-2), comprises following steps:
1st step: add the ultrapure water 200 ~ 900 parts that specific conductivity is 0.0003 μ S/cm ~ 0.025 μ S/cm in a kettle., start agitator in reactor, rotating speed is 125rpm ~ 210rpm, starts heat pump, makes reactor temperature rise to 35 DEG C ~ 80 DEG C; Add base n-octyl ether, the acid of sweet Pu methyl esters, ethyl chloride successively, be stirred to and dissolve completely, adjust ph is 3.0 ~ 9.0, and agitator speed is adjusted to 80rpm ~ 100rpm, and temperature is 60 DEG C ~ 90 DEG C, esterification 3 ~ 9 hours;
2nd step: get equal tetraphenylethane, Pyromellitic Acid phthalic anhydride is pulverized, powder diameter is 400 ~ 550 orders; Add methyl chloride carbic anhydride to mix, be laid in pallet, tiling thickness is 20mm ~ 55mm, and employing dosage is 4.0kGy ~ 6.5kGy, alpha-ray irradiation that energy is 1.0MeV ~ 12MeV 10 ~ 45 minutes;
3rd step: the mixed powder through the 2nd step process is dissolved in ethyl propionate, add reactor, agitator speed is 90rpm ~ 105rpm, and temperature is 60 DEG C ~ 85 DEG C, starting vacuum pump makes the vacuum tightness of reactor reach-0.015MPa ~-0.09MPa, keeps this state response 2 ~ 7 hours; Pressure release also passes into nitrogen, makes reacting kettle inner pressure be 0.0065MPa ~ 0.018MPa, and insulation leaves standstill 3 ~ 10 hours; Agitator speed is promoted to 100rpm ~ 175rpm, and the pressure release of simultaneous reactions still is to 0MPa; Add ethyl palmitate successively, after lindane formic acid dissolves completely, add linking agent and be uniformly mixed, make the hydrophile-lipophile balance value of reactor solution be 3.7 ~ 7.8, insulation leaves standstill 2 ~ 5 hours;
4th step: when agitator speed is 90rpm ~ 130rpm, add Chlorodracylic acid, vinylacrylic acid, dimethyl tellurium and the methaldehyde successively, promote reactor pressure, make it reach 0.055MPa ~ 0.20MPa, temperature is 140 DEG C ~ 160 DEG C, polyreaction 2 ~ 15 hours; After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 20 DEG C ~ 35 DEG C, discharging, enter press molding machine and can obtain short slab (10-3-2).
9. a process for purifying water for vertical Quick purifying device, is characterized in that, this process for purifying water comprises following step:
1st step: use the motor in Controlling System (11) startup water feed apparatus (2) for the first time, sewage in former pond (1) is squeezed into filter tank (3), after 10min, Controlling System (11) starts the motor stirred in water-distributing device (10), carries out stirring precipitation process to sewage;
2nd step: the sewage after preliminary treatment is in filter tank (3), by the filteration of filtering layer (3-1), produce clear water by supporting plate (3-2), finally be pooled in the frid that catchments (3-3), then enter in clean water basin (6) by rising pipe (4);
3rd step: the filtering layer inductance gauge (3-4) in system detects the filter effect of filtering layer (3-1) in real time, when filtering layer (3-1) filter effect lower than 20% time, filtering layer inductance gauge (3-4) feeds back signal to Controlling System (11), Controlling System (11) shut-off device power supply, equipment is quit work, and sends sound signal and notify to safeguard before serviceman; When the filter effect of filtering layer (3-1) returns to standard, filtering layer inductance gauge (3-4) feeds back signal to Controlling System (11), and Controlling System (11) switching on device power supply, makes equipment resume work;
4th step: when in filter tank (3), mud impurity increases, supervisory system sends signal to Controlling System (11), Controlling System (11) then stops the sewage treatment works of this device, start back-purge system (5) simultaneously and carry out back flushing to filter tank (3), backwashing sewage water is discharged by shore pipe (7);
5th step: when the water level sensor (3-5) being arranged in filter tank (3) perceives filter tank (3) water level decreasing to lowest water level, generation feeds back signal to Controlling System (11), Controlling System (11) impels the water pump enlargement discharge in water feed apparatus (2) to carry, the sewage large discharge ground that will be stored in former pond (1) inputs in filter tank (3), to maintain the normal work of this device through water feed apparatus (2) bottom; When water level sensor (3-5) perceive filter tank (3) water level exceed early warning value water level time, generation feeds back signal to Controlling System (11), Controlling System (11) is cut off the electricity supply and single unit system is quit work, send sound signal simultaneously, notify that Administrator safeguards equipment; When water level sensor (3-5) perceives filter tank (3) water level rezime to normal value, generation feeds back signal to Controlling System (11), and Controlling System (11) switches on power and makes this device recover normal processing work;
6th step: rotating shaft temperature survey instrument (10-4) in real time the axle temperature of rolling bearing (10-2) is detected, when rotating shaft temperature survey instrument (10-4) monitor rolling bearing (10-2) temperature exceed safety range time; Generation feeds back signal to Controlling System (11), and Controlling System (11) is cut off the electricity supply and this device is quit work, and sends sound signal simultaneously, notifies that Administrator safeguards equipment; When rotating shaft temperature survey instrument (10-4) monitors rolling bearing (10-2) temperature return to normal value, generation feeds back signal to Controlling System (11), and Controlling System (11) switches on power and makes this device recover normal processing work.
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CN106707931A (en) * 2016-12-22 2017-05-24 徐州工程学院 Automatic building control system based on Agent and working method of automatic building control system
CN106946410A (en) * 2017-04-13 2017-07-14 徐州工程学院 A kind of quartzy sand filter purifier and process for purifying water based on WinCC control programs
CN107098407A (en) * 2017-05-15 2017-08-29 安徽安科余良卿药业有限公司 The water for extracting water circulation vavuum pump collects reuse means
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CN109588279A (en) * 2018-12-14 2019-04-09 陈蕾伊 A kind of small-sized landscape ecology system based on water circulation
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CN106707931A (en) * 2016-12-22 2017-05-24 徐州工程学院 Automatic building control system based on Agent and working method of automatic building control system
CN106946410A (en) * 2017-04-13 2017-07-14 徐州工程学院 A kind of quartzy sand filter purifier and process for purifying water based on WinCC control programs
CN107098407A (en) * 2017-05-15 2017-08-29 安徽安科余良卿药业有限公司 The water for extracting water circulation vavuum pump collects reuse means
CN107839276A (en) * 2017-09-21 2018-03-27 黄鸿珊 A kind of refuse compression treater
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CN109588279A (en) * 2018-12-14 2019-04-09 陈蕾伊 A kind of small-sized landscape ecology system based on water circulation
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