CN105552451A - Explosion-proof lead-acid storage battery - Google Patents

Explosion-proof lead-acid storage battery Download PDF

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Publication number
CN105552451A
CN105552451A CN201610078832.4A CN201610078832A CN105552451A CN 105552451 A CN105552451 A CN 105552451A CN 201610078832 A CN201610078832 A CN 201610078832A CN 105552451 A CN105552451 A CN 105552451A
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CN
China
Prior art keywords
explosion
key
battery
lead acid
acid accumulator
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Granted
Application number
CN201610078832.4A
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Chinese (zh)
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CN105552451B (en
Inventor
魏立平
段喜春
宋艳龙
查立平
高凤英
张彦杰
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Fengfan Co Ltd
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Fengfan Co Ltd
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Priority to CN201610078832.4A priority Critical patent/CN105552451B/en
Publication of CN105552451A publication Critical patent/CN105552451A/en
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Publication of CN105552451B publication Critical patent/CN105552451B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/102Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/112Monobloc comprising multiple compartments
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • H01M50/155Lids or covers characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/308Detachable arrangements, e.g. detachable vent plugs or plug systems
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/383Flame arresting or ignition-preventing means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • H01M50/668Means for preventing spilling of liquid or electrolyte, e.g. when the battery is tilted or turned over
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Gas Exhaust Devices For Batteries (AREA)

Abstract

The invention discloses an explosion-proof lead-acid storage battery, which comprises a battery container, a battery cover, plate groups, an electrolyte, exhaust bolts and safety pads, wherein the battery cover is a single-layer cover; the battery container and the batter cover are formed by high-tenacity PP plastic in an injection molding manner and are bonded together in a heat sealing manner; the plate groups are connected with one another in series in a through the partition (TTP) welding manner; each exhaust bolt is hermetically fixed to a liquid filling hole of the battery cover via a thread; and each safety pad is arranged at the upper part of each plate group, and floats on the surface of the electrolyte under each liquid filling hole. The explosion-proof lead-acid storage battery can effectively filter an acid mist, and can prevent an external fire source from detonating the battery, and the damage degree to the battery caused by internal sparks is significantly lowered, and the explosion-proof lead-acid storage battery can prevent the electrolyte from overflowing, prevents external dust from affecting use of the storage battery, and can effectively prevent fragments formed after a storage battery housing detonates from hurting people.

Description

A kind of explosion-proof type lead acid accumulator
Technical field
The invention belongs to battery technology field, relating to a kind of automobile with safeguarding lead acid accumulator less.
Background technology
Safeguard that lead acid accumulator is the main lead acid accumulator of one that current automobile uses less, its battery case is made up of cell jar, battery cap and blow-cook, and blow-cook is fixed on battery cap by thread seal.Based on national environmental protection and updating and upgrading of a product requirement, the gas that regulation storage battery produces could be discharged after having to pass through filtration, and requires that battery external and internal pressure is inconsistent.For this problem, existing scheme is generally increase polytetrafluoroethylene filter vapour sheet to the blow-cook inside of lead acid accumulator, and gas after filter vapour sheet filters, then discharges battery.The hydrogen produced in battery operation and oxygen, a part is disposed to outside storage battery by blow-cook, and a part is then gathered in internal storage battery.The weak point of this solution is: safeguard that lead acid accumulator generally adopts lead-antimony alloy less, this battery gassing rate is large, and polytetrafluoroethylene filter vapour sheet is obviously deteriorated by the wetting rear venting capability of water vapour, inside battery hydrogen and oxygen mixed gas pressure is caused to raise, when inside battery or outside generation spark, produce accumulator explosion event, explosion time impulsive force can cause battery cell case and the exhaust cracked separation of fragments of stopper and acid solution to splash, and cause any property loss even personal injury.
Summary of the invention
Object of the present invention solves the above-mentioned problems in the prior art exactly, provides one effectively can filter acid mist, can prevent outside burning things which may cause a fire disaster and ignite battery, significantly reduces the explosion-proof type lead acid accumulator that inside spark ignites the extent of injury of battery.
For achieving the above object, technical solution of the present invention is: a kind of explosion-proof type lead acid accumulator, and it comprises cell jar, battery cap, pole group, electrolyte, blow-cook and safety pad; Battery cap is single-layer cover, and cell jar and battery cap adopt high tenacity PP injection molding, and both are connected together by hot-seal adhesive; Ge Ji group is connected by cross wall welding, and blow-cook thread seal is fixed on the liquid injection hole of battery cap; Safety pad is placed in above the group of pole, floats over the electrolyte surface immediately below liquid injection hole.
Blow-cook described above comprises key, stopper and filter vapour sheet; Key is the hollow structure having bottom surface and sidewall; Key and stopper are by chain connection, and stopper is fastened on key top, and with key tight fit; Its bottom center is provided with multiple venting of dust explosion hole, and middle and lower part is provided with buffer air chamber, and middle and lower part outer wall is provided with screw thread, and middle part is provided with the support rim installing filter vapour sheet, and filter vapour sheet is placed on support rim; Stopper bottom is provided with annular boss, and annular boss presses filter vapour sheet edge, and annular boss is provided with air vent hole, and key sidewall is provided with steam vent.
Steam vent described above is two, is symmetricly set on the key sidewall of key and hinge connection lower end; Described air vent hole is three, and three air vent holes are distributed in annular boss away from the semicircular ring of steam vent.
Key top inner wall described above is provided with draw-in groove, and stopper outer wall is provided with at least three chuck, and after stopper is fastened on key top, chuck is connected in draw-in groove.
The key outer wall of thread root described above is also provided with the rubber washer with key one.
Support rim described above and key inwall form annular dust-proof groove.
Filter vapour sheet described above is that the ultra-high molecular weight polyethylene dusty material being 60-105 μm by particle diameter forms through mold pressing, sintering.This material possesses good hydrophobicity performance and greasy property, can effectively prevent surperficial water droplet from being formed and dust blocking; Hydrophobicity performance appears without water droplet under can reaching 18cm water column pressure, therefore can ensure that storage battery is revealed without electrolyte when inclination 90 °; Simultaneously by controlling dusty material particle diameter to balance porosity and the aperture of air filter piece, even if still have certain venting capability after accomplishing to be soaked by water vapour, it is by under the state of water complete wetting, at 240mmH 2air permenbility>=0.08m under O water column pressure 3/ h, ensures that in use inside battery gas pressure is no more than 20mbar; Because ultra-high molecular weight polyethylene forms micropore cross-linked structure in mold pressing, sintering process, gas passage is tortuous, can acid mist effectively in filtering gas, while can stop that outside burning things which may cause a fire disaster enters inside battery, play good anti-backfire, filtration.
High tenacity PP plastics described above can adopt number of patent application to be the waste and old polypropylene regeneration toughening modifying composition announced in a kind of waste and old polypropylene regeneration toughening modifying composition and method of making the same patent of invention of 2015102011537, also other superhigh tenacity PP plastics can be adopted, as K8009 superhigh tenacity PP plastics etc.This high tenacity PP plastics toughness is higher, and performance is good in impact strength and high elongation at tear etc., can resist greater impact power and not produce fragmentation.
Safety pad described above is closed-cell foam PE cystosepiment, and apparent density is 0.3 ~ 0.5kg/L, and overall dimension is mated with cell negative terminal internal diameter, ensures that safety pad swims in electrolyte surface and can block battery cap liquid injection hole completely.
Beneficial effect of the present invention is: 1, blow-cook adopts the stopper retractable structure of particular design, once inside battery is blasted, gas venting of dust explosion hole bottom blow-cook of instantaneous expansion enters buffer air chamber, and then impacts filter vapour sheet, and stopper is opened fast and realizes venting of dust explosion; Cell jar, lid employing high tenacity PP plastics, being hit can not be broken, and storage battery can be avoided to produce the fragment of blast and blast generation to personal injury; 2, the filter vapour sheet adopting ultrahigh molecular weight polyethylene to become is that tortuous hole, aperture are little, has good anti-backfire performance, ensures that outside burning things which may cause a fire disaster cannot enter and ignite hydrogen and the oxygen of inside battery, avoids the blast of external source formula.3, electrolyte can be prevented excessive, automotive lead-acid battery carries out the vibration that pitches together along with vehicle, and electrolyte carries out vibrating and rocking thereupon.Safety pad swims in more than liquid level of electrolyte, effectively slow down the shaking amplitude of liquid level of electrolyte, acid liquor overflow when avoiding battery to vibrate.4, air filter piece self possesses good hydrophobicity performance, and hydrophobic height can reach 18cm water column, can effectively ensure battery tilt 90 ° time electrolyte do not produce leakage.5, can prevent external dust from affecting storage battery, blow-cook key inner chamber is provided with annular dust-proof groove, the key sidewall of key and hinge connection lower end arranges steam vent, and steam vent is away from the air vent hole on stopper boss.Stopped dust like this and vertically fallen into steam vent from top to bottom, the dust entered from the side is deposited on after entering key inside in dust-proof groove, can not contamination and plugging filter vapour sheet.
In a word, the present invention effectively can filter acid mist, can prevent outside burning things which may cause a fire disaster and ignite battery, significantly reduces the extent of injury that inside spark ignites battery, electrolyte can be prevented excessive, prevent external dust from affecting the use of storage battery; Form fragment after can effectively avoiding battery cell case to explode to hurt sb.'s feelings.
Accompanying drawing explanation
Fig. 1 is front view of the present invention; ;
Fig. 2 is vertical view of the present invention;
Fig. 3 is right view of the present invention;
Fig. 4 is the structural representation of blow-cook in the present invention;
Fig. 5 is the decomposition texture schematic diagram of blow-cook in the present invention;
Fig. 6 is the front view of blow-cook in the present invention;
Fig. 7 is the upward view of blow-cook in the present invention;
Fig. 8 is the front view of safety pad in the present invention;
Fig. 9 is the vertical view of safety pad in the present invention,
Figure 10 is the front view filtering vapour sheet in the present invention;
Figure 11 is the vertical view filtering vapour sheet in the present invention.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention will be further described.
As shown in Figure 1, Figure 2 with shown in Fig. 3, Fig. 4, Fig. 8 and Fig. 9, the present embodiment cell jar 8, battery cap 7, pole group 9, electrolyte 6, blow-cook 3 and safety pad 5.Battery cap 7 is single-layer cover, and cell jar 8 and battery cap 7 adopt high tenacity PP injection molding, and both are connected together by hot-seal adhesive.Blow-cook 3 thread seal is fixed on the liquid injection hole 2 of battery cap 7.Ge Ji group 9 is connected by cross wall welding, the positive plate of some, negative plate and dividing plate are contained in each pole group, and electrolyte 6 is injected by the liquid injection hole 2 on battery cap 7, and its main component is the sulfuric acid solution of dilution, between the battery normal operating period, electrolyte 6 liquid level is not less than through-wall welding hole.Further preferably, high tenacity PP plastics can adopt number of patent application to be the waste and old polypropylene regeneration toughening modifying composition announced in a kind of waste and old polypropylene regeneration toughening modifying composition and method of making the same patent of invention of 2015102011537, also other superhigh tenacity PP plastics can be adopted, as K8009 superhigh tenacity PP plastics.Safety pad 5 is placed in above pole group 9, floats over electrolyte 6 surface immediately below liquid injection hole 2.Further preferably, safety pad 5 is closed-cell foam PE cystosepiment, and apparent density is 0.3 ~ 0.5kg/L, and overall dimension is mated with cell negative terminal internal diameter, ensures that safety pad 5 swims in electrolyte 6 surface and can block battery cap liquid injection hole 2 completely.
As shown in Fig. 4, Fig. 5, Fig. 6, Fig. 7, Figure 10 and Figure 11, blow-cook 3 comprises key 15, stopper 10 and filter vapour sheet 14.Key 15 is for there being the hollow structure of bottom surface and sidewall.Key 15 is connected by hinge 11 with stopper 10, and when igniting from inside to avoid storage battery, stopper flies out.Key 15 top inner wall is provided with draw-in groove 12, and stopper 10 outer wall is provided with three chuck 21 such as (may also be four, five), after stopper 10 is fastened on key 15 top, and with key 15 tight fit, chuck 21 is connected in draw-in groove 12.Two steam vents 18 are symmetricly set on key 15 with on key 15 sidewall of lower end, hinge 11 junction.Key 15 bottom center is provided with multiple venting of dust explosion hole 22 can playing cushioning effect to electrolyte and gas, and single venting of dust explosion hole 22 cross-sectional area is not more than 7mm 2, the cross-sectional area sum in all venting of dust explosion holes is not less than 50mm 2.Key 15 middle and lower part is provided with buffer air chamber 23, middle and lower part outer wall is provided with screw thread 17.Key 15 outer wall of described screw thread 17 root is also provided with the rubber washer 16 with key 15 one.Be provided with the support rim installing filter vapour sheet 14 in the middle part of key 15, filter vapour sheet 14 is placed on support rim; Support rim and key 15 inwall form annular dust-proof groove 13.The dust entered in key 15 from steam vent 18 first accumulates at annular dust-proof groove 13 place, thus reduces contamination by dust filter vapour sheet 14 to greatest extent.Stopper 10 bottom is provided with annular boss 20, and annular boss 20 presses filter vapour sheet 14 edge, and annular boss 20 is provided with air vent hole 19; Air vent hole be three (may also be two, four etc.), three air vent holes 19 are distributed in the semicircular ring of annular boss 20 away from steam vent 18.Further preferably, described filter vapour sheet is that the ultra-high molecular weight polyethylene dusty material being 60-105 μm by particle diameter forms through mold pressing, sintering.
Above-described embodiment is only preferred and exemplary, and those skilled in the art can carry out the improvement of equivalent technologies according to the description of this patent, it is all in the protection range of this patent.

Claims (9)

1. an explosion-proof type lead acid accumulator, it comprises cell jar, battery cap, pole group, electrolyte and blow-cook; Ge Ji group is connected by cross wall welding; It is characterized in that: it also comprises safety pad; Battery cap is single-layer cover, and cell jar and battery cap adopt high tenacity PP injection molding, and both are connected together by hot-seal adhesive; Blow-cook thread seal is fixed on the liquid injection hole of battery cap; Safety pad is placed in above the group of pole, floats over the electrolyte surface immediately below liquid injection hole.
2. explosion-proof type lead acid accumulator according to claim 1, is characterized in that: described blow-cook comprises key, stopper and filter vapour sheet; Key is the hollow structure having bottom surface and sidewall; Key and stopper are by chain connection, and stopper is fastened on key top, and with key tight fit; Its bottom center is provided with multiple venting of dust explosion hole, and middle and lower part is provided with buffer air chamber, and middle and lower part outer wall is provided with screw thread, and middle part is provided with the support rim installing filter vapour sheet, and filter vapour sheet is placed on support rim; Stopper bottom is provided with annular boss, and annular boss presses filter vapour sheet edge, and annular boss is provided with air vent hole, and key sidewall is provided with steam vent.
3. explosion-proof type lead acid accumulator according to claim 2, is characterized in that: described steam vent is two, is symmetricly set on the key sidewall of key and hinge connection lower end; Described air vent hole is three, and three air vent holes are distributed in annular boss away from the semicircular ring of steam vent.
4. explosion-proof type lead acid accumulator according to claim 3, is characterized in that: described key top inner wall is provided with draw-in groove, and stopper outer wall is provided with at least three chuck, and after stopper is fastened on key top, chuck is connected in draw-in groove.
5. explosion-proof type lead acid accumulator according to claim 4, is characterized in that: the key outer wall of described thread root is also provided with the rubber washer with key one.
6. explosion-proof type lead acid accumulator according to claim 5, is characterized in that: described support rim and key inwall form annular dust-proof groove.
7. according to the explosion-proof type lead acid accumulator in claim 1 to 6 described in one of them, it is characterized in that: described filter vapour sheet is that the ultra-high molecular weight polyethylene dusty material being 60-105 μm by particle diameter forms through mold pressing, sintering; Filter vapour sheet by under the state of water complete wetting, at 240mmH 2air permenbility>=0.08m under O water column pressure 3/ h.
8. explosion-proof type lead acid accumulator according to claim 7, it is characterized in that: described safety pad is closed-cell foam PE cystosepiment, apparent density is 0.3 ~ 0.5kg/L, overall dimension is mated with cell negative terminal internal diameter, ensures that safety pad swims in electrolyte surface and can block battery cap liquid injection hole completely.
9. according to the explosion-proof type lead acid accumulator described in claim 1 to 6, it is characterized in that: described safety pad is closed-cell foam PE cystosepiment, apparent density is 0.3 ~ 0.5kg/L, overall dimension is mated with cell negative terminal internal diameter, ensures that safety pad swims in electrolyte surface and can block battery cap liquid injection hole completely.
CN201610078832.4A 2016-02-04 2016-02-04 A kind of explosion-proof type lead-acid accumulator Active CN105552451B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113258166A (en) * 2021-07-13 2021-08-13 北京智帮帮科技有限公司 Fire-proof and explosion-proof type new energy automobile storage battery structure
WO2022239828A1 (en) * 2021-05-14 2022-11-17 昭和電工マテリアルズ株式会社 Secondary battery
WO2023085016A1 (en) * 2021-11-10 2023-05-19 株式会社Gsユアサ Stopper for storage batteries, and storage battery

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0553430A1 (en) * 1992-01-30 1993-08-04 VARTA Batterie Aktiengesellschaft Process for the production of a lead accumulator having a gelled thixotropic electrolyte
CN101882695A (en) * 2010-07-20 2010-11-10 福州大学 Lead-acid storage battery forming anti-acid mist device
CN102544595A (en) * 2010-12-14 2012-07-04 骆驼集团襄樊蓄电池有限公司 Storage battery with puncturable thin film design
CN102780045A (en) * 2012-07-30 2012-11-14 徐金山 Valve controlled heat-preservation vacuum lead-acid storage battery
CN202695616U (en) * 2012-06-15 2013-01-23 浙江天能动力能源有限公司 Acid fluid pot used for acidification and inner formation of lead-acid storage batteries
CN205543123U (en) * 2016-02-04 2016-08-31 风帆有限责任公司 Explosion -proof type lead acid battery

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0553430A1 (en) * 1992-01-30 1993-08-04 VARTA Batterie Aktiengesellschaft Process for the production of a lead accumulator having a gelled thixotropic electrolyte
CN101882695A (en) * 2010-07-20 2010-11-10 福州大学 Lead-acid storage battery forming anti-acid mist device
CN102544595A (en) * 2010-12-14 2012-07-04 骆驼集团襄樊蓄电池有限公司 Storage battery with puncturable thin film design
CN202695616U (en) * 2012-06-15 2013-01-23 浙江天能动力能源有限公司 Acid fluid pot used for acidification and inner formation of lead-acid storage batteries
CN102780045A (en) * 2012-07-30 2012-11-14 徐金山 Valve controlled heat-preservation vacuum lead-acid storage battery
CN205543123U (en) * 2016-02-04 2016-08-31 风帆有限责任公司 Explosion -proof type lead acid battery

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022239828A1 (en) * 2021-05-14 2022-11-17 昭和電工マテリアルズ株式会社 Secondary battery
CN113258166A (en) * 2021-07-13 2021-08-13 北京智帮帮科技有限公司 Fire-proof and explosion-proof type new energy automobile storage battery structure
CN113258166B (en) * 2021-07-13 2021-11-05 北京智帮帮科技有限公司 Fire-proof and explosion-proof type new energy automobile storage battery structure
WO2023085016A1 (en) * 2021-11-10 2023-05-19 株式会社Gsユアサ Stopper for storage batteries, and storage battery

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