CN105551555B - A kind of method that animals and plants extraction combines diatomite processing radioactive wastewater - Google Patents

A kind of method that animals and plants extraction combines diatomite processing radioactive wastewater Download PDF

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CN105551555B
CN105551555B CN201510920483.1A CN201510920483A CN105551555B CN 105551555 B CN105551555 B CN 105551555B CN 201510920483 A CN201510920483 A CN 201510920483A CN 105551555 B CN105551555 B CN 105551555B
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parts
lard
clear water
powder
mixed
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CN105551555A (en
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陈毅忠
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Zhuzhou Jianghai Environmental Protection Technology Co Ltd
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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04Treating liquids
    • G21F9/06Processing
    • G21F9/12Processing by absorption; by adsorption; by ion-exchange

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
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  • Activated Sludge Processes (AREA)

Abstract

The invention discloses a kind of animals and plants to extract the method for combining diatomite processing radioactive wastewater, belongs to technical field of waste water processing.After peanut, rape, sunflower seeds, olive, soybean, sesame, oil tea, castor-oil plant are carried out clean dirt by the present invention, it is ground into powder, it is put into fermentor later, clear water is added and carries out fermentation process, obtains fermentation liquid, then pig fat meat lard is squeezed into mix with fermentation liquid, diatomite powder is added, after mixing evenly, adds PAC, after lasting stirring a period of time, standing.Example proves that not only operation is simple by the present invention, at low cost, does not have any secondary pollution in treatment process, and Spent Radioactive water activity removal rate is up to 90% or more after processing.

Description

A kind of method that animals and plants extraction combines diatomite processing radioactive wastewater
Technical field
The invention discloses a kind of animals and plants to extract the method for combining diatomite processing radioactive wastewater, belongs to wastewater treatment Technical field.
Background technique
Radioactive wastewater refers to nuclear fuel pre-treatment and post-processing, and atomic power station is ground using radioisotopic Study carefully, hospital, the discharges such as factory waste water.Radioactive wastewater is big to humans and animals harmfulness.It can only be reduced by natural decay And eliminate its radioactivity.In addition, in nuclear power plant reactor, the hydrometallurgy factory of uranium thorium, hospital, isotope test reactor and production Heap etc. can all generate radioactive wastewater.Nuclear power station will form the different waste water of radioactive activity during operation or stoppage in transit.This The characteristics of a little waste water is complicated components, contains radioactive element or fission product in waste water, seriously damages health of human body, enters Human body deposits in organ, life threatening, it is therefore necessary to which stringent processing could discharge.
Currently, the method that the radioactive wastewater generated to nuclear power station is handled mainly includes chemical precipitation method, ion friendship Change method, evaporation concentration method, membrane separation process, absorption method.
(1) it is insoluble heavy mainly to convert hydroxide, carbonate, phosphate etc. for radioactive element for chemical precipitation method It forms sediment and shifts concentration into mud, it is suitable for the low level waste waters of less demanding to purification.However, this method is during processing More demanding to the pH value of waste water, treatment effect is influenced significant, generated radioactivity after processing by impurities in waste water Mud quality is larger (usually the 1~5% of raw water amount), easily causes secondary pollution in subsequent dehydration decrement.In addition, using When cement immobilizes the radioactive sludge of formation, radioactive sludge easily damages the mechanical property of cement, thus It reduces immobilization effect and easily forms secondary pollution;(2) ion-exchange be will be in waste water in radioactivity existing for ionic condition Element exchanges to the polymer rack of ion-exchanger and carries out enrichment concentration, though removal rate is higher, however operation is relative complex, Operating cost is high, furthermore needs to be frequent regenerating ion exchanger when handling high slat-containing wastewater, at present to being formed after processing The processing of isotopic ion exchanger there is also certain difficulties;(3) evaporation concentration method is to make moisture evaporative condenser by heating, To separate with the radioactive element of hardly possible volatilization, though decontamination factor and enrichment factor are high, energy consumption is high, and operating cost is high;(4) Membrane separation process, with pressure difference, temperature difference or potential difference etc. for power, is realized to radioactive element by selective penetrated property film Separation concentration not yet realizes large-scale industrialization though good purification, higher with operating cost there is also building at present Using;(5) absorption method is that radioactive element is transferred to solid phase using adsorbent to carry out enrichment concentration, and common adsorbent includes Active carbon, zeolite, montmorillonite etc., however these adsorbents are affected by the pH value of waste water, adsorption effect is unstable, and right The solidification effect being formed by when radioactivity adsorbent immobilizes processing is bad, and radioactive element easily discharges and forms environment Secondary pollution.
Summary of the invention
Present invention mainly solves the technical issues of: in the method for current conventional radioactive wastewater treatment, ion exchange Although method, evaporation and membrane separation process removal rate are high, at high cost, energy consumption is high, and chemical precipitation method and absorption method are to useless The pH value of water it is more demanding, and the drawbacks of will lead to secondary pollution, provide a kind of animals and plants and extract and combine at diatomite The method for managing radioactive wastewater.This method cleans peanut, rape, sunflower seeds, olive, soybean, sesame, oil tea, castor-oil plant After decontamination, it is ground into powder, is put into fermentor later, clear water is added and carries out fermentation process, fermentation liquid is obtained, then by pig fat meat It is squeezed into lard to mix with fermentation liquid, adds diatomite powder, after mixing evenly, add PAC, persistently stir one section After time, standing.Not only operation is simple by the present invention, at low cost, does not have any secondary pollution in treatment process, and Spent Radioactive water activity removal rate is up to 90% or more after processing.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
(1) according to the mass fraction, 5~15 parts of peanut, 3~9 parts of rape, 2~10 parts of sunflower seeds, 5~10 parts of olive, big is taken 5~12 parts of beans, 6~12 parts of sesame, 5~10 parts of oil tea, 5~10 parts of castor-oil plant, are cleaned 1~3 time repeatedly with clear water, and removal surface is dirty Object is put into airslide disintegrating mill and is crushed, and crosses 130~140 meshes later, obtains mixed-powder, the mixed powder that will then obtain End is put into fermentor, adds 3~5 times of peanut weight of clear water, is sufficiently mixed and is carried out fermentation process after mixing evenly, setting Temperature is 38~58 DEG C, ferments 8~12 days, obtains fermentation mixed liquor;
(2) mixed liquor obtained above being moved into supercentrifuge, setting centrifugal rotational speed is 800~1200r/min, from After the heart handles 15~20min, supernatant liquor is taken;
(3) the pig fat meat that 300~500g is fresh is taken, is cleaned repeatedly with clear water until surface is without dirt, is cut into long 4~7cm, The vertical cutlet of wide 3~5cm, later pours into the cutlet cut in the pot equipped with 300~400mL clear water, and setting temperature is 80 ~110 DEG C, then constantly stir-frying, until pulling lard stearin out when pig fat meat whole yellowly lard stearin, while hot pouring into lard dry Only not in the basin of moisture content;
(4) supernatant liquor for obtaining lard obtained above and above-mentioned steps (2) is uniformly mixed, then pig is added thereto The diatomite powder of oil quality 50~60% is put into 1~3t radioactive wastewater to be processed, later again after mixing It adds PAC and persistently stirs 45~50min, stand 30min, wherein the PAC additional amount is 200~300mg/L.
Application method of the invention is: lard and fermentation mixed liquor that the present invention obtains being uniformly mixed, then added thereto Enter the diatomite powder of lard quality 50~60%, again after mixing, put into 1~3t radioactive wastewater to be processed, The PAC for adding 200~300mg/L later persistently stirs 45~50min, stands 30min.Not only operation is simple, Cost is relatively low, and does not have any secondary pollution in treatment process, and Spent Radioactive water activity is from 1000~2000Bq/ after processing L is reduced to 100~150Bq/L, and removal rate is up to 90% or more.
The beneficial effects of the present invention are:
(1) operation of the present invention is simple and easy, and raw material are pure natural, so that it is at low cost, do not have in treatment process any secondary Pollution;
(2) obvious processing effect, so that Spent Radioactive water activity removal rate is up to 90% or more after processing.
Specific embodiment
First according to the mass fraction, take 5~15 parts of peanut, 3~9 parts of rape, 2~10 parts of sunflower seeds, 5~10 parts of olive, 5~12 parts of soybean, 6~12 parts of sesame, 5~10 parts of oil tea, 5~10 parts of castor-oil plant, are cleaned 1~3 time repeatedly with clear water, remove surface Dirt is put into airslide disintegrating mill and is crushed, and crosses 130~140 meshes later, obtains mixed-powder, the mixing that will then obtain Powder is put into fermentor, is added 3~5 times of peanut weight of clear water, is sufficiently mixed and carries out fermentation process after mixing evenly, if Setting temperature is 38~58 DEG C, ferments 8~12 days, obtains fermentation mixed liquor;Then mixed liquor obtained above is moved into high speed centrifugation In machine, setting centrifugal rotational speed is 800~1200r/min, after 15~20min of centrifugal treating, takes supernatant liquor;Next 300 are taken ~500g fresh pig fat meat is cleaned with clear water repeatedly until long 4~7cm, the vertical meat of wide 3~5cm are cut into without dirt in surface Item later pours into the cutlet cut in the pot equipped with 300~400mL clear water, and setting temperature is 80~110 DEG C, then constantly Lard is poured into the basin of clean not moisture content until pulling lard stearin out when pig fat meat whole yellowly lard stearin by stir-frying while hot In;Finally the supernatant liquor that lard obtained above and above-mentioned steps obtain is uniformly mixed, then lard quality is added thereto 50~60% diatomite powder puts into 1~3t radioactive wastewater to be processed, adds later again after mixing PAC persistently stirs 45~50min, stands 30min, wherein the PAC additional amount is 200~300mg/L.
Example 1
First according to the mass fraction, take 5 parts of peanut, 3 parts of rape, 2 parts of sunflower seeds, 5 parts of olive, 5 parts of soybean, 6 parts of sesame, 5 parts of oil tea, 5 parts of castor-oil plant, are cleaned 1 time repeatedly with clear water, are removed surface contaminants, are put into airslide disintegrating mill and are crushed, later 130 meshes are crossed, mixed-powder is obtained, the mixed powder that will then obtain
End is put into fermentor, is added 3 times of peanut weight of clear water, is sufficiently mixed and carries out at fermentation after mixing evenly Reason, setting temperature are 38 DEG C, ferment 8 days, obtain fermentation mixed liquor;Then mixed liquor obtained above is moved into supercentrifuge In, setting centrifugal rotational speed is 800r/min, after centrifugal treating 15min, takes supernatant liquor;Next the pig fertilizer that 300g is fresh is taken Meat, cleaned repeatedly with clear water until surface without dirt, be cut into long 4cm, the vertical cutlet of wide 3cm later falls the cutlet cut Enter in the pot equipped with 300mL clear water, setting temperature is 80 DEG C, then constantly stir-frying, until pig fat meat whole yellowly lard stearin When, it pulls lard stearin out, while hot pours into lard in the clean not basin of moisture content;Finally by lard obtained above and above-mentioned step Suddenly the supernatant liquor obtained is uniformly mixed, then the diatomite powder of lard quality 50% is added thereto, again after mixing, PAC is added and persistently stirs 45min, stands 30min, wherein the PAC additional amount is 200mg/L.
This example operation is simple and easy, and when operation, lard and fermentation mixed liquor that the present invention obtains are uniformly mixed, then to The diatomite powder that lard quality 50% is wherein added is put into 1t radioactive wastewater to be processed again after mixing, it The PAC for adding 200mg/L afterwards persistently stirs 45min, stands 30min.Not only operation is simple, and cost is relatively low, And there is no any secondary pollution in treatment process, Spent Radioactive water activity is reduced to 100Bq/L from 1000Bq/L after processing, Removal rate is up to 90%.
Example 2
First according to the mass fraction, 10 parts of peanut, 6 parts of rape, 8 parts of sunflower seeds, 7 parts of olive, 10 parts of soybean, sesame 11 are taken Part, 8 parts of oil tea, 7 parts of castor-oil plant, are cleaned 2 times repeatedly with clear water, are removed surface contaminants, are put into airslide disintegrating mill and are crushed, it 135 meshes are crossed afterwards, obtain mixed-powder, then obtained mixed-powder is put into fermentor, add 4 times of peanut weight clear Water is sufficiently mixed and carries out fermentation process after mixing evenly, and setting temperature is 45 DEG C, ferments 10 days, obtains fermentation mixed liquor;Then will Mixed liquor obtained above moves into supercentrifuge, and setting centrifugal rotational speed is 1050r/min, after centrifugal treating 18min, takes Layer clear liquid;Next 400g fresh pig fat meat clean up to surface is without dirt repeatedly with clear water, is cut into long 6cm, wide 4cm's Vertical cutlet later pours into the cutlet cut in the pot equipped with 350mL clear water, and setting temperature is 95 DEG C, then constantly stir-frying, Until pulling lard stearin out when pig fat meat whole yellowly lard stearin, lard is poured into the clean not basin of moisture content while hot;Most The supernatant liquor that lard obtained above and above-mentioned steps obtain is uniformly mixed afterwards, then lard quality 55% is added thereto Diatomite powder is added PAC and persistently stirs 48min, stand 30min again after mixing, wherein the PAC adds Entering amount is 250mg/L.
This example operation is simple and easy, and when operation, lard and fermentation mixed liquor that the present invention obtains are uniformly mixed, then to The diatomite powder that lard quality 55% is wherein added is put into 2t radioactive wastewater to be processed again after mixing, it The PAC for adding 250mg/L afterwards persistently stirs 47min, stands 30min.Not only operation is simple, and cost is relatively low, And there is no any secondary pollution in treatment process, Spent Radioactive water activity is reduced to 130Bq/L from 1500Bq/L after processing, Removal rate is up to 91.3%.
Example 3
First according to the mass fraction, 15 parts of peanut, 9 parts of rape, 10 parts of sunflower seeds, 10 parts of olive, 12 parts of soybean, sesame are taken 12 parts, 10 parts of oil tea, 10 parts of castor-oil plant, are cleaned 3 times repeatedly with clear water, are removed surface contaminants, are put into airslide disintegrating mill and carry out powder It is broken, 140 meshes are crossed later, obtain mixed-powder, then obtained mixed-powder is put into fermentor, add peanut weight 5 Clear water again, is sufficiently mixed and carries out fermentation process after mixing evenly, and setting temperature is 58 DEG C, ferments 12 days, obtains fermentation mixed liquor; Then mixed liquor obtained above is moved into supercentrifuge, setting centrifugal rotational speed is 1200r/min, centrifugal treating 20min Afterwards, supernatant liquor is taken;Next take 500g fresh pig fat meat, clean repeatedly with clear water up to surface without dirt, be cut into length The vertical cutlet of 7cm, wide 5cm, later pour into the cutlet cut in the pot equipped with 400mL clear water, and setting temperature is 110 DEG C, Then constantly stir-frying while hot pours into lard completely without water until pulling lard stearin out when pig fat meat whole yellowly lard stearin In the basin of part;Finally the supernatant liquor that lard obtained above and above-mentioned steps obtain is uniformly mixed, then is added thereto The diatomite powder of lard quality 60% is added PAC and persistently stirs 50min, stand 30min again after mixing, Wherein the PAC additional amount is 300mg/L.
This example operation is simple and easy, and when operation, lard and fermentation mixed liquor that the present invention obtains are uniformly mixed, then to The diatomite powder that lard quality 60% is wherein added is put into 3t radioactive wastewater to be processed again after mixing, it The PAC for adding 300mg/L afterwards persistently stirs 50min, stands 30min.Not only operation is simple, and cost is relatively low, And there is no any secondary pollution in treatment process, Spent Radioactive water activity is reduced to 150Bq/L from 2000Bq/L after processing, Removal rate is up to 92.5%.

Claims (1)

1. a kind of animals and plants extract the method for combining diatomite processing radioactive wastewater, it is characterised in that concrete operation step are as follows:
(1) according to the mass fraction, 5~15 parts of peanut, 3~9 parts of rape, 2~10 parts of sunflower seeds, 5~10 parts of olive, soybean 5 are taken ~12 parts, 6~12 parts of sesame, 5~10 parts of oil tea, 5~10 parts of castor-oil plant, are cleaned 1~3 time repeatedly with clear water, remove surface contaminants, It is put into airslide disintegrating mill and is crushed, cross 130~140 meshes later, obtain mixed-powder, then put obtained mixed-powder Enter in fermentor, add 3~5 times of peanut weight of clear water, be sufficiently mixed and carry out fermentation process after mixing evenly, temperature is set It is 38~58 DEG C, ferments 8~12 days, obtain fermentation mixed liquor;
(2) mixed liquor obtained above is moved into supercentrifuge, setting centrifugal rotational speed is 800~1200r/min, at centrifugation After managing 15~20min, supernatant liquor is taken;
(3) the pig fat meat that 300~500g is fresh is taken, is cleaned repeatedly with clear water until surface is without dirt, is cut into long 4~7cm, it is wide by 3 The vertical cutlet of~5cm, later pours into the cutlet cut in the pot equipped with 300~400mL clear water, setting temperature be 80~ 110 DEG C, then constantly stir-frying, until pulling lard stearin out when pig fat meat whole yellowly lard stearin, while hot pouring into lard completely Do not have in the basin of moisture content;
(4) supernatant liquor for obtaining lard obtained above and above-mentioned steps (2) is uniformly mixed, then lard matter is added thereto The diatomite powder of amount 50~60% is put into 1~3t radioactive wastewater to be processed again after mixing, is added again later Enter PAC and persistently stir 45~50min, stands 30min, wherein the PAC additional amount is 200~300mg/L.
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CN101894597B (en) * 2010-06-04 2013-04-03 清华大学 Pretreatment method for radioactive wastewater
CN102328974B (en) * 2011-05-31 2013-07-24 厦门建霖工业有限公司 Water purification material and preparation method thereof
CN202438323U (en) * 2011-11-14 2012-09-19 大理学院 Plant volatile oil-containing alkaline carbon composite column type adsorbing device
JP2014200722A (en) * 2013-04-03 2014-10-27 Dowaエコシステム株式会社 Agglomeration deposition method of ferrocyanide and removal method of soluble cesium
CN103816862B (en) * 2014-03-12 2016-01-06 福州大学 Diatomite-nickel slag the composite adsorbing material of recyclable heavy metal ion and preparation thereof
KR101551233B1 (en) * 2014-09-16 2015-09-10 한국원자력연구원 Treatment method for radioactive wastewater generated in severe accident in nuclear power plant
CN104826584A (en) * 2015-04-22 2015-08-12 芜湖市鸿坤汽车零部件有限公司 Multi-plant modified composite active carbon particle with devulcanization effect and preparation method thereof
CN105107458A (en) * 2015-09-11 2015-12-02 中山大学 Kieselguhr/coal ash particle adsorbent and preparing method and application of kieselguhr/coal ash particle adsorbent

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