CN105549254A - 液晶面板及其制造方法 - Google Patents

液晶面板及其制造方法 Download PDF

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CN105549254A
CN105549254A CN201610090348.3A CN201610090348A CN105549254A CN 105549254 A CN105549254 A CN 105549254A CN 201610090348 A CN201610090348 A CN 201610090348A CN 105549254 A CN105549254 A CN 105549254A
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liquid crystal
photo
alignment layer
crystal panel
layer
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CN105549254B (zh
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陈兴武
马小龙
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TCL China Star Optoelectronics Technology Co Ltd
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Shenzhen China Star Optoelectronics Technology Co Ltd
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Priority to US15/113,734 priority patent/US20170371188A1/en
Priority to PCT/CN2016/078025 priority patent/WO2017140016A1/zh
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Abstract

本发明公开一种液晶面板及其制造方法,所述液晶面板通过对光配向层预先进行偏振紫外光照射的光配向处理,以便在进行聚合步骤时,使多个液晶分子的倾倒方向会相同,从而解决现有技术所存在的光线穿透率降低的问题。

Description

液晶面板及其制造方法
技术领域
本发明是有关于一种显示器结构及其制造方法,特别是有关于一种液晶面板及其制造方法。
背景技术
纳米相分离液晶(Nano-Phase-SeparatedLiquidCrystals,NPSLCs)技术,是指一液晶组合物层包含多个液晶分子及多个可聚合单体,在输入电压时通过紫外光照射所述多个可聚合单体,以形成多个聚合物网络。这些聚合物网络可以促使所述多个液晶分子的响应速度达到1毫秒内。
然而,纳米相分离液晶技术具有光线穿透率较低的缺点,这是因为纳米相分离液晶技术通常采用完全透明导电膜(FullITO)的技术,亦即在上基板及下基板上皆形成一个完整的透明导电膜。这种透明导电膜无法利用现有技术的方式(例如制作多个凸起物(Bump)或蚀刻多个沟槽(slit)等)来使所述多个液晶分子产生一预倾角。所以,在进行输入电压时通过紫外光照射所述多个可聚合单体的步骤时,若是相邻的液晶分子的倾倒方向不一致时,光线穿透率会降低。
故,有必要提供一种液晶面板及其制造方法,以解决现有技术所存在的问题。
发明内容
有鉴于此,本发明提供一种液晶面板及其制造方法,以解决现有技术所存在的光线穿透率降低的问题。
本发明的主要目的在于提供一种液晶面板及其制造方法,其可以透过对第一光配向层及第二光配向层进行光配向,以便在进行聚合步骤时,使多个液晶分子的倾倒方向会相同,从而解决现有技术所存在的光线穿透率降低的问题。
为达成本发明的前述目的,本发明一实施例提供一种液晶面板,其中所述液晶面板包含︰一第一基板、一第二透明导电膜、一第一光配向层、一液晶组合物层、一第二光配向层、一第二透明导电层及一第二基板。所述第一透明导电膜设在所述第一基板上。所述第一光配向层设在所述第一透明导电膜上。所述液晶组合物层设在所述第一光配向层上,并包含:多个液晶分子;及由多个反应单体聚合形成的多个聚合物网络,其中所述多个液晶分子与所述多个聚合物网络是分离的二个相。所述第二光配向层设在所述液晶组合物层上。所述第二透明导电层设在所述第二光配向层上。所述第二基板设在所述第二透明导电层上。
在本发明的一实施例中,所述第一基板是一薄膜晶体管阵列基板。
在本发明的一实施例中,所述第二基板是一彩膜基板。
在本发明的一实施例中,所述多个液晶分子是多个负型液晶分子;及所述第一光配向层及所述第二光配向层皆是受偏振紫外光照射过的垂直光配向材料。
在本发明的一实施例中,所述多个液晶分子是多个正型液晶分子;及所述第一光配向层及所述第二光配向层皆是受偏振紫外光照射过的水平光配向材料。
再者,本发明另一实施例提供一种液晶面板的制造方法,其中所述液晶面板的制造方法包含步骤:提供一第一基板及一第二基板;形成一第一透明导电膜在所述第一基板上,并形成一第二透明导电膜在所述第二基板上;形成一第一光配向层在所述第一透明导电膜上,并形成一第二光配向层在所述第二透明导电膜上;进行一光配向步骤,提供一第一偏振紫外光予所述第一光配向层,其中所述第一偏振紫外光相对于所述第一光配向层的垂直方向的一第一预倾角度在0至90度之间,并提供一第二偏振紫外光予所述第二光配向层,其中所述第二偏振紫外光相对于所述第二光配向层的垂直方向的一第二预倾角度在0至90度之间;提供一混合物层,夹设在所述第一光配向层及所述第二光配向层之间,其中所述混合物层包含多个液晶分子及多个反应单体;及进行一聚合步骤,提供一紫外光予所述混合物层以形成一液晶组合物层,其中所述液晶组合物层包含所述多个液晶分子及由所述多个反应单体聚合形成的多个聚合物网络,及所述多个液晶分子与所述多个聚合物网络是分离的二个相。
在本发明的一实施例中,在进行所述聚合步骤中,所述紫外光的一主反应波长是313纳米或365纳米,及所述聚合步骤的一反应温度是摄氏30度至摄氏60度。
在本发明的一实施例中,在进行所述光配向步骤中,更包含提供一第一光掩膜在所述第一偏振紫外光及所述第一光配向层之间;及一第二光掩膜在所述第二偏振紫外光及所述第二光配向层之间。
在本发明的一实施例中,所述多个液晶分子是多个负型液晶分子;及所述第一光配向层及所述第二光配向层皆是垂直光配向材料。
在本发明的一实施例中,所述多个液晶分子是多个正型液晶分子;及所述第一光配向层及所述第二光配向层皆是水平光配向材料。
与现有技术相比较,本发明的液晶面板及其制造方法是通过对第一光配向层及第二光配向层进行光配向,以便在进行聚合步骤时,使多个液晶分子的倾倒方向会相同,从而解决现有技术所存在的光线穿透率降低的问题。
为让本发明的上述内容能更明显易懂,下文特举优选实施例,并配合所附图式,作详细说明如下:
附图说明
图1是本发明实施例的液晶面板的剖面示意图。
图2A至2D是本发明实施例的液晶面板的各个制造阶段的剖面示意图。
图3是本发明实施例的液晶面板的制造方法的流程图。
具体实施方式
以下各实施例的说明是参考附加的图式,用以例示本发明可用以实施的特定实施例。再者,本发明所提到的方向用语,例如上、下、顶、底、前、后、左、右、内、外、侧面、周围、中央、水平、横向、垂直、纵向、轴向、径向、最上层或最下层等,仅是参考附加图式的方向。因此,使用的方向用语是用以说明及理解本发明,而非用以限制本发明。
请参照图1,图1是本发明实施例的液晶面板10的剖面示意图。所述液晶面板10包含一第一基板11、一第二透明导电膜12、一第一光配向层13、一液晶组合物层14、一第二光配向层15、一第二透明导电层16及一第二基板17。在一实施例中,第一基板11是一薄膜晶体管阵列基板。
在液晶面板10中,所述第一透明导电膜12设在所述第一基板11上。在一实施例中,所述第一透明导电膜12是整面式的沉积在所述第一基板11上。在又一实施例中,所述第一透明导电膜12的材质是氧化铟锡。
在液晶面板10中,所述第一光配向层13设在所述第一透明导电膜上。在一实施例中,所述第一光配向层13沉积在所述第一透明导电膜12上。在另一实施例中,所述第一光配向层13可以是受偏振紫外光(倾斜)照射过的垂直光配向材料或水平光配向材料。
在液晶面板10中,所述液晶组合物层14设在所述第一光配向层13上。所述液晶组合物层14包含多个液晶分子141及由多个反应单体142聚合形成的多个聚合物网络143,其中所述多个液晶分子141与所述多个聚合物网络143是分离的二个相。在一实施例中,所述多个液晶分子141可以是多个正型液晶分子或多个负型液晶分子。
在液晶面板10中,所述第二光配向层15设在所述液晶组合物层14上。在一实施例中,所述第二光配向层15可以是受偏振紫外光(倾斜)照射过的垂直光配向材料或水平光配向材料。在一具体实施例中,所述多个液晶分子141、所述第一光配向层13及所述第二光配向层15的材质具有配对关系,例如若所述多个液晶分子141采用多个负型液晶分子,则所述第一光配向层13及所述第二光配向层15皆采用受偏振紫外光(倾斜)照射过的垂直光配向材料;若所述多个液晶分子141采用多个正型液晶分子,则所述第一光配向层13及所述第二光配向层15皆采用受偏振紫外光(倾斜)照射过的水平光配向材料。
在液晶面板10中,所述第二透明导电层16设在所述第二光配向层15上。在一实施例中,所述第二透明导电膜16的材质是氧化铟锡。
在液晶面板10中,所述第二基板17设在所述第二透明导电层16上。在一实施例中,所述第二基板17是一彩膜基板。
在一实施例中,所述液晶面板10采用纳米相分离液晶技术制得,所以具有优良的液晶响应速度,可采用场序显示模式输出彩色影像,故不需额外制作一彩色滤光片。
请参照图2A至2D,图2A至2D是本发明实施例的液晶面板10的各个制造阶段的剖面示意图。首先请参照图2A,提供一第一基板11及一第二基板17。接着,形成一第一透明导电膜12在所述第一基板11上,并形成一第二透明导电膜16在所述第二基板17上。在一实施例中,所述第一透明导电膜12及第二透明导电膜16的材质是氧化铟锡。在另一实施例中,沉积所述第一透明导电膜12在所述第一基板11上,并沉积所述第二透明导电膜16在所述第二基板17上。之后,形成一第一光配向层13在所述第一透明导电膜12上,并形成一第二光配向层15在所述第二透明导电膜16上。在一实施例中,沉积所述第一光配向层13在所述第一透明导电膜12上,并沉积所述第二光配向层15在所述第二透明导电膜16上。
请参照图2B,进行一光配向步骤,提供一第一偏振紫外光131予所述第一光配向层13,其中所述第一偏振紫外光131相对于所述第一光配向层13的垂直方向132的一第一预倾角度A1在0至90度之间,并提供一第二偏振紫外光151予所述第二光配向层15,其中所述第二偏振紫外光151相对于所述第二光配向层15的垂直方向152的一第二预倾角度A2在0至90度之间。所述第一预倾角度A1及第二预倾角度A2例如分别为0.5度、1度、3度、5度、8度、10度、12度、15度、20度、25度、30度、45度、60度、75度、80度、85度、89度、89.5度等。在一实施例中,在进行所述光配向步骤时,更包含提供一第一光掩膜133在所述第一偏振紫外光131及所述第一光配向层13之间;及一第二光掩膜153在所述第二偏振紫外光151及所述第二光配向层15之间。所述第一光掩膜133及所述第二光掩膜153主要设计来将所述液晶面板10的像素(pixel,未绘示)区分成多个畴(domain,未绘示)。在一实施例中,所述第一光掩膜133的狭缝宽度是大于0微米且小于等于50微米;及所述第二光掩膜153的狭缝宽度是大于0微米且小于等于50微米。在另一实施例中,所述第一偏振紫外光131的主反应波长是250纳米至370纳米;及所述第二偏振紫外光151的主反应波长是250纳米至370纳米。
请参照图2C,提供一混合物层18,夹设在所述第一光配向层13及所述第二光配向层15之间,其中所述混合物层18包含多个液晶分子141及多个反应单体142。在一实施例中,所述多个液晶分子141、所述第一光配向层13及所述第二光配向层15的材质具有配对关系,例如若所述多个液晶分子141采用多个负型液晶分子,则所述第一光配向层13及所述第二光配向层15皆采用垂直光配向材料;若所述多个液晶分子141采用多个正型液晶分子,则所述第一光配向层13及所述第二光配向层15皆采用水平光配向材料。
请参照图2D,进行一聚合步骤,提供一紫外光144予所述混合物层18以形成一液晶组合物层14,其中所述液晶组合物层14包含所述多个液晶分子141及由所述多个反应单体142聚合形成的多个聚合物网络143,及所述多个液晶分子141与所述多个聚合物网络143是分离的二个相。在一实施例中,所述紫外光的一主反应波长是313纳米或365纳米,及所述聚合步骤的一反应温度是摄氏30度至摄氏60度。
图3是本发明实施例的液晶面板的制造方法30的流程图。本发明提出一种液晶面板的制造方法30,包含:提供一第一基板及一第二基板(步骤31);形成一第一透明导电膜在所述第一基板上,并形成一第二透明导电膜在所述第二基板上(步骤32);形成一第一光配向层在所述第一透明导电膜上,并形成一第二光配向层在所述第二透明导电膜上(步骤33);进行一光配向步骤,提供一第一偏振紫外光予所述第一光配向层,其中所述第一偏振紫外光相对于所述第一光配向层的垂直方向的一第一预倾角度在0至90度之间,并提供一第二偏振紫外光予所述第二光配向层,其中所述第二偏振紫外光相对于所述第二光配向层的垂直方向的一第二预倾角度在0至90度之间(步骤34);提供一混合物层,夹设在所述第一光配向层及所述第二光配向层之间,其中所述混合物层包含多个液晶分子及多个反应单体(步骤35);及进行一聚合步骤,提供一紫外光予所述混合物层以形成一液晶组合物层,其中所述液晶组合物层包含所述多个液晶分子及由所述多个反应单体聚合形成的多个聚合物网络,及所述多个液晶分子与所述多个聚合物网络是分离的二个相(步骤36)。
要提到的是,本发明的液晶面板及其制造方法是通过对第一光配向层及第二光配向层进行光配向,由于所述第一光配向层及第二光配向层的垂直或水平光配向材料已预先进行光配向使其材料分子具有预倾角(0~90度),因此在进行聚合步骤时,可促使多个液晶分子具有相同倾斜的倾向,并在聚合之后提高多个液晶分子的倾倒方向的一致性,从而解决现有技术所存在的光线穿透率降低的问题。
本发明已由上述相关实施例加以描述,然而上述实施例仅为实施本发明的范例。必需指出的是,已公开的实施例并未限制本发明的范围。相反地,包含于权利要求书的精神及范围的修改及均等设置均包括于本发明的范围内。

Claims (10)

1.一种液晶面板,其特征在于:所述液晶面板包含:
一第一基板;
一第一透明导电膜,设在所述第一基板上;
一第一光配向层,设在所述第一透明导电膜上;
一液晶组合物层,设在所述第一光配向层上,并包含:多个液晶分子;及
由多个反应单体聚合形成的多个聚合物网络,其中所述多个液晶分子与所述多个聚合物网络是分离的二个相;
一第二光配向层,设在所述液晶组合物层上;
一第二透明导电层,设在所述第二光配向层上;及
一第二基板,设在所述第二透明导电层上。
2.如权利要求1所述的液晶面板,其特征在于:所述第一基板是一薄膜晶体管阵列基板。
3.如权利要求1所述的液晶面板,其特征在于:所述第二基板是一彩膜基板。
4.如权利要求1所述的液晶面板,其特征在于:所述多个液晶分子是多个负型液晶分子;及所述第一光配向层及所述第二光配向层皆是受偏振紫外光照射过的垂直光配向材料。
5.如权利要求1所述的液晶面板,其特征在于:所述多个液晶分子是多个正型液晶分子;及所述第一光配向层及所述第二光配向层皆是受偏振紫外光照射过的水平光配向材料。
6.一种液晶面板的制造方法,其特征在于:所述液晶面板的制造方法包含步骤:
提供一第一基板及一第二基板;
形成一第一透明导电膜在所述第一基板上,并形成一第二透明导电膜在所述第二基板上;
形成一第一光配向层在所述第一透明导电膜上,并形成一第二光配向层在所述第二透明导电膜上;
进行一光配向步骤,提供一第一偏振紫外光予所述第一光配向层,其中所述第一偏振紫外光相对于所述第一光配向层的垂直方向的一第一预倾角度在0至90度之间,并提供一第二偏振紫外光予所述第二光配向层,其中所述第二偏振紫外光相对于所述第二光配向层的垂直方向的一第二预倾角度在0至90度之间;
提供一混合物层,夹设在所述第一光配向层及所述第二光配向层之间,其中所述混合物层包含多个液晶分子及多个反应单体;及
进行一聚合步骤,提供一紫外光予所述混合物层以形成一液晶组合物层,其中所述液晶组合物层包含所述多个液晶分子及由所述多个反应单体聚合形成的多个聚合物网络,及所述多个液晶分子与所述多个聚合物网络是分离的二个相。
7.如权利要求6所述的液晶面板的制造方法,其特征在于:在进行所述聚合步骤中,所述紫外光的一主反应波长是313纳米或365纳米,及所述聚合步骤的一反应温度是摄氏30度至摄氏60度。
8.如权利要求6所述的液晶面板的制造方法,其特征在于:在进行所述光配向步骤中,更包含提供一第一光掩膜在所述第一偏振紫外光及所述第一光配向层之间;及一第二光掩膜在所述第二偏振紫外光及所述第二光配向层之间。
9.如权利要求6所述的液晶面板的制造方法,其特征在于:所述多个液晶分子是多个负型液晶分子;及所述第一光配向层及所述第二光配向层皆是垂直光配向材料。
10.如权利要求6所述的液晶面板的制造方法,其特征在于:所述多个液晶分子是多个正型液晶分子;及所述第一光配向层及所述第二光配向层皆是水平光配向材料。
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