CN1055482A

CN1055482A - The conditioning shampoo that contains the long-chain alcohol component

Info

Publication number: CN1055482A
Application number: CN90103035A
Authority: CN
Inventors: 艾米利特·M·帕托; 克拉林思·R·罗宾
Original assignee: Colgate Palmolive Co
Current assignee: Colgate Palmolive Co
Priority date: 1990-04-09
Filing date: 1990-06-21
Publication date: 1991-10-23
Also published as: FI903130A; PT94423B; GR900100468A; AU5755690A; AU640143B2; KR910018628A; NZ234192A; PH31201A; JP2975644B2; NO902743L; ZA904836B; NO178748B; JPH03291212A; PL165265B1; PT94423A; HU210756B; PL285679A1; KR100192156B1; CA2019353A1; FI903130A0

Abstract

Fiber conbidioning compositions and Crinis Carbonisatus shampoo Compositions, be a kind of stable liquid with pearly-lustre or semisolid, contain surfactant in the said composition, the agent of water-insoluble fiber conbidioning, the saturated primary alconol or derivatives thereof of long-chain, the present invention also comprises the manufacture method of these care compositions and shampoo Compositions and is used for the method for conditioning fiber and Crinis Carbonisatus.

Description

The conditioning shampoo that contains the long-chain alcohol component

The present invention relates to fiber conbidioning compositions, more particularly, relate to Wo 2008069000, particularly shampoo is used to clean Crinis Carbonisatus, goes back conditioning hair simultaneously, thereby make behind the hair than the hair (be easy to combing, static is less) more easy to control after washing with conventional shampoo.

Conditioning shampoo is known in cosmetic industry, existing narration in various patents and patent application.As various polysiloxanes and other water-insoluble conditioner that comprises wax, tallow and oils.It is the same with shampoo to be used for rinse, and cationic surfactant is as quaternary ammonium salt, also in rinse and shampoo, make conditioner, shampoo can be made into solid, coagulates, Emulsion and liquid form, liquid form can make solution, emulsion, suspension or dispersion liquid.When shampoo is emulsion or suspension (or dispersion liquid), in storage process, tend to be in charge of, concerning will obtaining the commercial product of using, must prevent this layering.The invention provides a kind of fiber conbidioning compositions, a kind of especially conditioning shampoo, the saturated primary alconol or derivatives thereof of long-chain that this shampoo contains the water-insoluble conditioner and has certain chain length, find that this long-chain primary alconol or derivatives thereof can make emulsion or effect suspension stabilizationization, make shampoo have the desired pearly-lustre that has, and can also improve the hair conditioning effect.

Pearly-lustre fiber conbidioning compositions of the present invention, more can claim shampoo, be stable emulsion or form of suspension, said composition contains surfactant, the agent of water-insoluble fiber conbidioning, the saturated primary alconol or derivatives thereof of the long-chain of carbon number average out to 25～45, the ratio of these components will be enough to make emulsion or effect suspension stabilizationization, and makes shampoo be the pearly-lustre color, also contain aqueous medium, wherein can contain other component of adjuvant and this fiber conbidioning compositions.Contained long-chain alcohol or derivatives thereof usually can also be nursed one's health handled fiber better.

Prior art is retrieved, is found following United States Patent (USP):

3，969，550;4，707，293;4，824，602;4，470，982;4，726，944;4，850，732;4，701，322;4，728，457;4，885，130;4，704，272;4，803，237 4，859，500。

Pefrolite company is entitled as Unilin ^TMThe pamphlet of Alcohols also is highly significant, and this volume obtains royalty in 1985 and weighs, and book number is SP-1040.

Narrated the shampoo similar to another application that is entitled as " improved conditioning shampoo shampoo " (people such as Hartnett) that the application proposes on the same day to the present invention, with be certain type anionic detergent, contain the short alkyl (preferably octyl group or decyl) of chain as its lipophilic agent, this application is the application's improvement, must openly locate described a lot of content.

Though prior art has been narrated the pearl shining shampoo agent, and introduced various conditioners and be added in the shampoo, and confirm that the long-chain alcohol as present composition component is a known substance, but applicant and do not know to concentrate with reference to data or any reference material for any kind and relevantly cause people to produce the present invention or make people obtain the introduction of benefit of the present invention.

From in the broadest sense of the present invention, this fiber conbidioning compositions can be liquid, Emulsion, gel or paste form, and only need in aqueous medium, comprise agent of water-insoluble fiber conbidioning and the saturated primary alconol of long-chain, preferably also has cationic fiber conbidioning agent (also be a kind of surfactant, but can think a class conditioner herein).In the above in these forms some form may be not necessarily will be by omitting " or derivatives thereof " language after the saturated primary alconol of long-chain (for simplifying statement)) realize stabilisation, but this compounds also has other advantage, comprises the improvement of pearlescent effect and opsonic action.In the hair conditioning shampoo, also contain the synthetic organic detergent of water solublity, preferably anionic detergent, particularly high alkyl sulfate and (or) senior alkyl ethyoxyl sulfuric ester.This based composition can be various non-liquid forms, but preferably is the emulsion of medium or the form of suspension (or dispersion liquid) with water, is good with liquid especially.

Comparatively desirable having in the agent of water-insoluble fiber conbidioning: organo-silicon compound as non-volatile polysiloxanes (particularly amino silicones), comprise; First polysilane oxygen alkane; Polyethylene; Paraffin; Vaseline; Microwax; C _18～30(mixing) fatty acid and corresponding triglyceride; The stearic acid stearyl; And quaternary ammonium salt and amine salt (it being classified as conditioner rather than surfactant herein) although these two kinds of effects all have.Operable organosilicon and polysiloxanes comprise the various materials as fiber goods and materials conditioner, and some of them are described in aforesaid patent and application.Yet it is generally more effective than polysiloxanes commonly used to have now found that amino silicones is used as conditioner in the present composition, and in amino silicones, those amino silicones as herein described are better.Therefore, preferably use the amino silicones of following formula,

R in the formula ¹, R ², R ³, R ⁵, R ⁶And R ⁷Be C _1～6Alkyl preferably respectively contains a carbon atom, R ⁴Be-R ⁰-NH-CH ₂-CH ₂-NH ₂, R ⁸Be C _3～6Alkylidene, isobutylidene preferably, X be average 100～1, in 0000 the scope, Y is an average, in 1～10 scope, should be less than 5, preferably 1, this moment, amine equivalent was in 4000～60000 scope.X is preferably 200～10, and 000 or 300～10000, be more preferably 500～10000, preferably 750～800 or 850, for example about 800, and Y is 0～8, should preferably be about 1 less than 3.The amine equivalent of this amino silicones is preferably 5000～50000, and preferably 10,000～40,000.For preferred amino silicones used in the experiment of this description, the mole percent of amine is about 0.125, and the degree of polymerization is approximately 800, and X is 797, and Y is 1, and molecular weight is approximately 60,000 dalton.Because the molecular weight of high polymer is different with assay method sometimes, therefore suggestion mainly should be with reference to the definition molecular formula of described amino silicones, rather than mainly rely on measured molecular weight, described preferred amino silicones can obtain from Dow Corning company, naming with Dow Corning amino silicones A(applicant in this paper embodiment) expression.

The polyolefinic molecular weight that can be used as the water-insoluble conditioner in the present composition is preferably 1000～5000, be preferably 1000～4000, preferably 2000～2500, for example about 2000, the also oxidation product of available these olefin polymers, they are macromole hydroxyls that end has carboxyl.Though the alkene of these polymer is ethylene normally, but the polymer that uses the hydrocarbon contain 1～5 (best 2～3) carbon atom still within the scope of the present invention, the scope of the molecular weight of polymer can be 1000～10,000, in some cases even can be bigger, but the general polymerization thing be ethylene and (or) polymer of propylene, and the polymer of ethylene (polyethylene) always almost.

Spendable alkane has the chain length of 20～50 carbon atoms usually, preferably has the chain length of 20～40 carbon atoms, and the chain length of isoparaffin then can be 12～16 carbon atoms, preferably 13～14 carbon atoms.Vaseline is that petroleum jelly or mineral oil freeze, in 38～60 ℃ of fusings.The mean molecule quantity of microwax (is approximately 2 times of molecular weight of alkane) greatly between 500～800.C _18～36Fatty acid and corresponding triglyceride are higher fatty acids and triglyceride, can buy (for example commodity of triglyceride Syncrowax HGL-C by name) in Croda chemical company.Octadecyl stearate (Stearyl stearate) and be the representative of the useful ester that generates of high fatty alcohol and higher fatty acids can have been bought in Inolex company, and commodity are called Lexol SS.

Cationic conditioner (can regard the auxiliary conditioner in the care composition of the present invention as), preferably quaternary ammonium salt though other cationic compound with conditioning fiber performance also can use, is that part is used at least.For example known amine, amine salt, imidazoline salt and betanin, and at those cationic substances described in the United States Patent (USP) 4000077, all a part of quaternary ammonium salt can be replaced at least, also for example United States Patent (USP) 4,896 can be used, 422 and 4,888,119 and U.S. Patent application S.N.06/916, the complex of the cationic and anionic surfactant described in 069 replaces at least a portion quaternary ammonium salt.

The general formula of preferred quaternary ammonium salt is R ⁹, R ¹⁰, R ¹¹, R ¹²N ⁺X ^-, at least one R base is a low alkyl group in the formula, at least one R base is a senior alkyl, remaining R base then be senior and (or) low alkyl group, R ⁹Low alkyl group C for example preferably _1～4Alkyl, R ¹⁰And R ¹¹Be C _10～40Senior alkyl, R ¹²Also be such senior alkyl or low alkyl group, X ^-Be can salifiable anion, as halogen, low alkyl group sulfate radical or low-grade carboxylic acid's base, chlorine for example, bromine, methylsulfate, ethyl sulphate, citrate or acetate.Low alkyl group is preferably C _1～3Alkyl better is C _1～2Alkyl, methyl preferably in most of the cases, senior alkyl is preferably C _10～22Alkyl is preferably C _～18Or C ₂₀Alkyl, preferably C _14～18Alkyl, for example C ₁₆Or C ₁₈Alkyl.Anion is halogen preferably, and for example chlorine, bromine or iodine are preferably chlorine and bromine, preferably chlorine.

Lower alkyl radix on the quaternary nitrogen preferably 1 or 2, senior alkyl number usually preferably 2 or 3.Therefore, such chemical compound has 2 or 3 C _Ca _～20Chain alkyl and 2 or 1 C ₁Or C ₂Short-chain alkyl has now found that should have 30 carbon atoms at least and preferably have 34 carbon atoms at least in quaternary ammonium salt.Optimal senior alkyl is cetyl and octadecyl, and optimal low alkyl group is a methyl.Comparatively desirable quaternary ammonium halide comprises three ((cetyl) ammonio methacrylate and two (dodecyl) alkyl dimethyl ammonium chlorides, but other quaternary ammonium salt also can be selected for use, comprise two (cetyl) alkyl dimethyl ammonium chlorides and three (octadecyl) ammonio methacrylate, corresponding bromide, amine, amine salt, betanin, and the complex in the aforesaid U.S. Patent, (these United States Patent (USP)s are quoted here as a reference).These can use for the partial cation surfactant that the cationic surfactant of selecting for use and complex can be used as in the present composition at least.

Preferably a kind of hydroxyl of long-chain primary alconol in the present composition is positioned at terminal saturated compounds.This class alcohol is generally and is the alcohol that homology alcohol distributes, and generally all pure carbon numbers are even number, and 24～45 carbon atoms of average out to (according to the weight meter) are preferably 28～42 carbon atoms, are 30～40 carbon atoms preferably, are preferably 30～40 carbon atoms.And the average of carbon atom is less than 24 in the chain, then the Expected Results of this class alcohol in the present composition can descend, and Stabilization, fiber conbidioning effect and pearly-lustre effect also all weaken, and chain length is when for example on average being about 50 carbon atoms more than 45 carbon atoms, and this class alcohol can not disperse in the present composition satisfactorily.Except that above-mentioned long-chain alcohol, relevant chemical compound thing, as corresponding oxyalkylated alcohol, corresponding fatty acid and the saturated primary alconol ester of long-chain also can substitute, and can partly substitute at least, in those " derivants ", preferably oxyalkylated alcohols, wherein best is the alcohols of ethoxylation, and common every mole contains and is no more than 20 ethyoxyls, for example 10～20.Yet.Preferred alcohol of the present invention normally uses separately or mixes use with the allied compound that is obtained by " deriving " group, purely accounts for major part in " alcohol adds derivant " component.The example that can be used for the commercially available material of the present composition is that Petroliee company makes, and is called Unilin by the commodity that Pefrolite Specialty Polymeis Cronp sells ^TMThe material of Alcohols, as narrating in the above-mentioned technical bulletin of the application's book, this class alcohol can account for 75～90% of commercially available prod, for example 80～85%, the remainder of product is whole basically saturated hydrocarbon with suitable chain length, in this series products, the distribution curve of alcohol is bell shape basically, does not have a kind of chain dolichol can account for more than 10% of total content; And corresponding hydrocarbon content is smooth distribution curve substantially, and every kind of hydrocarbon has 1% or 2% approximately.This distribution curve is listed in the aforesaid Petrolie communique with the bar chart form.The alcohol (with corresponding hydrocarbon) that exists at least 80% has 18(or 20 usually)～chain length of 54 carbon atoms, the alcohol that is about 30 carbon atoms for average chain length, at least wherein the chain length of 80% alcohol is about 18(or 20)～44 carbon atoms, be about the alcohol of 40 carbon atoms for average chain length, at least wherein the chain length of 80% alcohol is about 38(or 30)～54 carbon atoms.The example of long-chain primary alconol has Unilin-425 alcohol, 30 carbon atoms of its chain length average out to; Uiilin-550 alcohol, 40 carbon atoms of its chain length average out to, also has Unilin-350, its chain length on average is about 26 carbon atoms, derivant Unilhox-550 is the ethoxylation long-chain primary alconol of 40 carbon atoms of alkyl chain length average out to, makes its ethoxylation with being no more than 20 (for example 13) ethyoxyls.

Be present in the shampoo example of the present invention and also also can nurse one's health the synthetic organic anion detergent of the water solublity that exists in the example at some, normally lipophilic sulfate or sulfonate, though also can use the hydrophilic group of other non-sulfuric acid salt and sulfonate, as phosphate and phosphonate.With the cation of these compound formation salt normally alkali metal, ammonium, alkanolamine, preferably sodium salt and ammonium salt.Anionic detergent is the mixture of lipotropy sulfate or sulfate preferably also, and the anion lipophilic group is alkyl, preferably C _12～13Senior fatty alkyl, though also consider more and more wide carbon atom scope, as 10,8 and 6 or 18 or 20 carbon atoms nearly.The compatibility of this detergent and described shampoo is fine, produce well to clean and conditioning effect, but the while is not disturbed the pearlescent effect and the conditioning effect of this compositions again.Especially satisfactory detergent is ammonium lauryl sulfate and every mole of dodecyl ethyoxyl ether sodium sulfate that contains 1～6 (preferably 2 or 3) ethyoxyl,

Though the preferred anionic surfactants detergent be above-mentioned those, but also available other this anionoid detergent replaces, at least can replace fraction, these other anionic detergent is shown Detergents and Emul sifiers(detergent and emulsifying agent at Mc Cutcheon) description is arranged in (the North America version was published in 1984) book.In addition, also available ampholytic detergent and amphoteric detergent in this compositions, also available sometimes a small amount of non-ionic detergent, these also have narration in last, quoted for reference hereby.At S.N.07/432, also remove in 452 and stated suitable detergent, this has mentioned in front and has quoted for reference.Sometimes in non-hair washing dosage form hair conditioner and fiber conbidioning compositions, also use a small amount of this class surfactant (this this term that is to use is generalized, comprises various emulsifying agents and dispersant)

Compositions for above mentioned preferred detergent, the ratio of alkyl sulfate and alkyl ethoxy sulfate preferably 2 in the compositions of higher fatty acid alkyl sulfate and senior fatty alkyl ethoxy sulfate: 1-8: 1, and the most handy ammonium salt of alkyl sulfate, the most handy sodium salt of alkyl alkoxy sulfate.Yet these two kinds of detergents all can use separately, have removed ethoxylated detergent in some is preferably filled a prescription.

The required various components of the present composition be the dissolving and (or) be emulsifiable in and (or) be suspended in the aqueous medium.This medium can comprise the fiber conbidioning compositions component and the shampoo Compositions component of various glitch-free routines known in the art, but to mention wherein several here especially, because they are components that the present composition needs especially, and play important effect, make compositions have required performance.People know that already senior fat alkane alcohol amide is foaming agent and foam stabiliser.The acyl group of this compounds has 12～16 carbon atoms usually; it and rudimentary (1～3 carbon atom) be single-or the reaction of double-stranded alkanolamine; best alkanolamide is the Laurel single ethanol amide in the present composition, but Cocodiethanolamide also has roughly suitable effect.Yet other known foam stabiliser and foaming agent also can use, and can be that part is used or all used, for example betanin and related substance.Various natural gum and other thickening agent also can be used for shampoo Compositions, but what found to be best suited for the present composition is hydroxyethyl-cellulose.This can buy in Aqualon company, and commodity are called Nefrosol, and for example Nafrosol250HHR and Nafrosol330CS preferably use the mixture of these two kinds of commodity, and the former consumption is 2～5 times of the latter.Though preferably use hydroxyethyl-cellulose, other paragutta and thickening agent, for example methylcellulose, hydroxypropyl-methylcellulose, Polyquaternum ^TM-10, modified starch and natural gum and thickening agent such as guar gum also can substitute, and can partly substitute at least, and this depends on the requirement of product.When polyethylene during with the hairdo conditioner, another important component of the present composition is a mineral oil.Mineral oil is used for making the polyethylene solubilization and helps its dispersion, can not disperse well in compositions as fruit polyethylene, and the effect of its conditioning hair is just very poor, and precipitation can occur.

Can be used for other component of the present invention comprises; Ethylene glycol-stearate, glycol distearate and propylene glycol distearate, all these has pearly-lustre character, and viscosity modifier is as propylene glycol and sodium chloride; The pH regulator agent is as citric acid and citrate; Chelating is as EDTA; Antifreezing agent is as propylene glycol; Solvent is as ethanol and isopropyl alcohol; Antiseptic and antioxidant, Germaben II (suthonlaborafories); Dandruff removing agent such as vancide ZP or Climbazole ^TM(seeing United States Patent (USP) U.S.4,867,971); Coloring agent and spice.

The water that is used for preparing aqueous medium not only exists in liquid preparation, also exists in gel, paste and Emulsion and preferably use deionized water and radiation water, its hardness is zero basically, but also available tap water, but preferably make hardness remain on calcium carbonate below 50p.p.m.But also available sometimes hardness is up to the tap water of 200ppm, but still will avoid usually using.

In order to make liquid conditioner compositions of the present invention and shampoo Compositions that described desired properties be arranged, the ratio of each component should be as described below.

The surface-active contents scope concerning two kinds of care compositions such as rinse and shampoo, all should be 1～35%, is 2～35% preferably, and preferably 3,5, or 8～25%.Will hang down for " care composition " this content range, for shampoo, it is high that this content range is wanted.For shampoo, this content range is generally 5～35%, is preferably 8～25 or 30%, and preferably 10～20%.This scope normally 5～25% is preferably 10～20% for the former for alkyl sulfate-alkyl ethoxyquin sulfate shampoo, and preferably 10～15%; For the latter, be no more than 15%, be preferably 0 or 1～10%, preferably 0 or 1～5%.When if this class sulfate detergent uses separately, adopt the content range of alkyl hydrochlorate.

The content of water-insoluble conditioner (content that does not comprise cationic surfactant) is a kind of conditioning ratio or a kind of like this ratio, promptly when share with the cationic surface active agent that exists, can reach the effect of satisfied conditioning fiber and hair, for fiber conbidioning compositions and shampoo Compositions, this content is usually all in 0.3～10% scope, be 0.3～7% preferably, preferably 0.3～5%.Cationic surfactant is present in fiber conbidioning or the additional care composition for fiber conbidioning compositions and shampoo, and its content is 0.1～5% usually, is preferably 0.1～3%, and preferably 0.1 or 0.3～0.7 or 1%.The saturated primary alconol of long-chain and (or) its " derivant " be generally 0.5～10%, be 0.5～5 or 6% preferably, preferably the content of 1～5% aqueous medium (can comprise various adjuvant) is generally in 75～99% scope, the water content of this shampoo is 60～90%, be 63～85% preferably, preferably 63～80%.Yet the content of water and aqueous medium is variable, and this depends on required adjuvant shared ratio in compositions.The saturated primary alconol of long-chain and (or) content of its " derivant " generally is 0.2～5 with the ratio of conditioner content, is preferably 0.3～3, is 0.5～2 preferably, the most about 1.

The ratio of all components can change in above-mentioned scope in the various shampoo Compositions of the present invention, below the ratio of each component in the dissimilar preferred composition of some that point out.

Shampoo for lipotropy sulfate, quaternary ammonium salt, amino silicones and the saturated primary alconol of long-chain, the content of aliphatic alcohol sulfate is generally 5～18% in water, the most handy its ammonium salt, the content of fatty alcohol ether sulphate is (0 or 1)～10%, the most handy its sodium salt (proportion can be 1: 10 to 10: 1), quaternary ammonium salt content is 0.2～2%, the content of amino silicones is 0.5～10%, the saturated primary alconol of long-chain and (or) content of its " derivant " is 0.5～5 or 6%, the content of water is that 65～85% remainders are the shampoo adjuvant.Preferred range is respectively 10～(15 or 20) %, (0 or 1)～5%, 0.1～0.7%, 0.8～4%, 1～5.0% and 63～80%.This compositions also can contain 0.2～2% hydroxyethyl-cellulose (or other suitable thickening agent), 2～5% Laurels-glycollic amide or Cocodiethanolamidl ethamine, (0 or 0.5)～2% microwax and (0 or 0.5)～1% vaseline.

It is identical with the above that the first six of another kind of this based composition planted components contents scope, but 0.3～2%(preferably 0.5～1.5% in addition) polyethylene and 0.3～2%(preferably 0.5～2%) mineral oil.Hydroxyethyl-cellulose is identical with foregoing with the content of Laurel one glycollic amide, but also contains 0.1～2%(preferably 0.1～1%) paraffin; With 0.1～2%(preferably 0.1～0.5%) isoparaffin.

In another embodiment of the present invention, contain polyethylene in the shampoo as basic hair conditioner, also contain quaternary ammonium halide and high-molecular weight lipid solubilizing agent (as mineral oil), so that the polyethylene solubilising.The ratio of each component and aforesaid anionic detergent, cationic conditioner, the saturated primary alconol of long-chain and (or) its " derivant ", water is identical with the ratio of the adjuvant that is adopted.But can save amino silicones in this compositions, the ratio of alkoxide detergent rises to 15%, and the ratio of polyethylene and mineral oil generally all respectively is 0.3～2%, and best scope is respectively 0.5～1.5% and 0.5～2%.Wish that other component that adopts comprises 0.2～2% hydroxyethyl-cellulose, 2～5% Laurels one glycollic amide, 0.1～1% paraffin and 0.1～0.5% isoparaffin.

In another kind of shampoo of the present invention, anionic detergent, cationic surfactant, amino silicones, the saturated primary alconol of long-chain with (or) ratio of its " derivant " other adjuvant and water etc. is identical with the ratio of aforementioned first prescription, is 2 or 3% average chain length those 40 carbon atoms approximately but good used average chain length is about the content of the saturated primary alconol of long-chain (also can contain its derivant) of 30 carbon atoms for the content of the saturated primary alconol of long-chain (also can contain its derivant) of (0.5 or 1)～(2 or 3) %.In a kind of prescription of improvement, also can contain 0.5～2% the saturated primary alconol of many ethoxylations long-chain (with " derivant "), wherein Chun average carbon atom number is about 40,10～20 moles of (for example 13 moles) oxirane ethoxylations of every mole of usefulness.These two prescriptions are not gummy or gummy (hydroxyethyl-cellulose), but can add 2～5% Laurels, one glycollic amide, 0.5～2%C _18～36The triglyceride and 0.1～0.5% citrate of acid, sodium citrate preferably, the further improvement of above-mentioned last a kind of prescription is that to contain 0.1～1% paraffin and 0.5～1.5% molecular weight be 1000～4000 the solid polyethylene hairdo conditioner that is generally, and containing 0.5～2%, molecular weight is that 300～800 mineral oil is as poly solvent medium.

The anionic detergent that other optimization formula contains, the ratio of cationic surfactant, nitrilo polysiloxanes, the saturated primary alconol of long-chain, water and shampoo adjuvant is identical with the ratio of above-mentioned last prescription, but also contains 0.25～5%C _18～36(mixing) acid glycerol three esters are conditioner as a supplement.Said composition also can contain 2～5% Laurels, one glycollic amide, 0.2～2% hydroxyethyl-cellulose, 0.5～2% microwax and 0.5～1% vaseline.Also available 0.5～1.5% aforesaid polyethylene and 0.5～2% aforesaid mineral oil replace microwax and vaseline.

For gel of the present invention, paste, condensed Emulsion and medicinal cake, required, optional general identical with the ratio of Aquo-composition with ratio helper component, just the ratio of water often will reduce, sometimes be reduced to 30 to 40%, water also can be replaced by another kind of solvent, for example replaced, can replace water in some cases, but generally not be higher than 20% up to 50% by ethanol or isopropyl alcohol.

Though conditioning fiber compositions of the present invention and care composition hair can be above-mentioned various physical state, the liquid form of washing liquid sample preferably, best embodiment of the present invention is liquid conditioning hair shampoo.Such compositions can be accepted by market being stable chemically and physically.When storing, should not go bad, should not precipitate or layering in the storage yet to unacceptable degree.The existence of above-mentioned long-chain primary alconol (Unilin or Unifhox type) is except making compositions and have attracting pearlescent appearance and improve the ability of conditioning fiber, outside can also make present composition stabilisation, and such shampoo has desirable viscosity, can pour into, but thinless in uncontrollable its mobile degree.The range of viscosities that requires is to be 1000～15000 centipoises under the room temperature (25 ℃), preferably 3000～6000 centipoises.

Shampoo of the present invention by carry out high temperature accelerated aging test proof can precipitation when storing and layering, can not chemometamorphism.The viscosity of shampoo possibility slight modification when depositing, but this variation can not have remarkable influence to the performance of shampoo.And the shampoo that can have certain viscosity (this viscosity considered use before viscosity change) by manufacturing, make shampoo have desirable viscosity in use.

Compare with the tester that has removed aforementioned conditioner with compositions of the present invention, even the user who uses shampoo of the present invention or other care compositions by chance can feel that also the hair conditioning effect of the improvement of assembly of the present invention is very significant, and available standards test determination, this test is in order to estimate the effect of conditioner and component thereof, content comprises the complexity of wet combing, do the complexity of combing, the residual degree of " controllability " electrostatic charge and " swollen flying " degree.Use the people of this shampoo can find to be used for the hair that shampoo washed by chance, compare, wet comb or do all combings easily of comb with the hair of washing with non-shampoo of the present invention (do not contain conditioner or remove some conditioner).Scientific experimentation also proves and makes comb to send out the power of distinguishing required by the standard of handling with reference substance little by send out the force rate of distinguishing required with shampoo of the present invention washing and rinsing standard, this result also is confirmed by panel test, this panel test is to look for several experienced judges, experiment product and reference substance are carried out blind test, estimate their complexities combing.The influence of controllability and static characteristic.

The using method that comprises the present composition of shampoo has nothing different with the general using method of conditioning hair shampoo and other fiber conbidioning compositions, care composition can be nursed one's health degree as required and use by general consumption under room temperature or summary high-temperature, can make it stay the different time on hair.The temperature of conditioner and hair is generally between 15～50 ℃, and preferably 20～40 ℃, care composition and hair time of contact are 30 seconds to 10 minutes, preferably 1 to 5 minute.The consumption of compositions generally is 0.1～25g, 0.2～10g commonly used, or 0.5～(2 or 5) g, this is to decide according to nonaqueous component in the compositions and non-solvent component, based on available shampoo, use amount can usually be that each consumption is 2～(15 or 20) g between 0.5～50g, often is each 5～10g.Used care composition can on hair, brush and (or) combing, wash off then, can allow it stay on the hair or partly and remove, as towel off and wipe away.When with this shampoo washing and conditioning hair, allow the resistance aqueous foam that forms after stopping time enough (being generally 1～5 minute) on the hair, so that conditioning hair satisfactorily, water washes shampoo then, comb then can wet, with the method drying that for example dries up, do comb again or driedly brush into desirable hair style.

In order to make the present composition that comprises shampoo, row need with complicated method, but in order to obtain best stability and pearly-lustre effect, and maximum opsonic activity, the present composition is after storage, should under higher temperature (as 70～95 ℃), make water-soluble lipophilic sulfate and (or) sulfonate shampoo and adjuvant form dispersion liquid in water, at high temperature use any lipophilic substance, for example alkane (comprises polyethylene, mineral oil, microwax, vaseline, alkane and isoparaffin, long-chain alcohol, triglyceride and stearic acid octadecane alcohol ester) make cation opsonizing agent (as quaternary ammonium salt dissolving and (or) disperse to form molten mass or liquid mixture, under this high temperature, these two kinds of mixture are mixed, mixing mutually with the mixture that obtains above (this compounding substances also contains lipophilic substance sometimes) through the amino silicones of heating, when mixing various mixture, each mixing portion will have roughly the same temperature then.Sometimes wish after main premixing, amino silicones to be sneaked into, so that product is more stable.When adjuvant exists, those water miscible with (or) dispersible adjuvant can mix mutually with aqueous phase substance, those water solublity or in aqueous medium not dispersive adjuvant then can mix with lipophilic substance (for example hydrocarbon), perhaps in some cases, before or after the mixture cool to room temperature of hydrophilic and lipophilic substance, adjuvant is added wherein.General spice is to add this blending ingredients behind another kind of blending ingredients cool to room temperature, and amino silicones then is at high temperature to add before cooling.It is to lose because of the volatilization of component in order to prevent that spice is added in the refrigerative compositions, also degrades in order to prevent Yin Jialie.If not operation as stated above, for example various components are mixed carelessly in the compositions, just can obtain unsettled product, meeting layering or precipitation in the storage, the conditioning performance of this unsettled compositions is poorer than stable care composition and the shampoo made according to method of the present invention.

Following embodiment will be illustrated the present invention, but the present invention is not limited to these.Except as otherwise noted, among the embodiment in other parts of this description and the claim all umbers all refer to weight portion, all temperature are degree centigrade.

Embodiment 1

%(weight)

Component 1A 1B 1C

Dodecane ammonium sulfate 12.50 12.50 12.50

Dodecane ether sodium sulfate (every mole of 2Eto) 2.50 2.50 2.50

Two (octadecyl) dimethyl ammonium chloride 0.50 0.50 0.50

Amino silicones A(Dow Corning) 2.50-1.50

Long-chain alcohol (Unilin ^TM425, Pofro

Lito company) 2.50 2.50 2.50

Polyethylene (molecular weight=2000,

Allied company)-0.75 0.75

Microwax (fusing point=82 ℃) 1.00--

Paraffin (fusing point=53 ℃, Boler oil

Company)-0.35 0.35

Isoparaffin (Isopar ^TMM, Exxon company)-0.25 0.25

White vaseline (Alba Profopet ^TM) 0.75--

Mineral oil (Brifol ^TM50 Bolev

The oil company)-1.00 1.00

Hydroxyethyl-cellulose 250HHR(Aqualon

Company) 0.57 0.67 0.67

Hydroxyethyl-cellulose 330CS(Aqualon company) 0.18 0.23 0.23

Laurel one glycollic amide 3.50 3.50 3.50

Sodium chloride 0.20 0.20 0.20

Antiseptic (Germaben ^TMII) 0.50 0.50 0.50

Spice 0.80 0.80 0.80

Coloring agent 0.10 0.10 0.10

Deionized water 71.90 73.65 72.15

100.00 100.00 100.00

Prescription 1A, 1B and 1C compositions are the method preparations described in to specifications, hydrophilic composition is mixed, in addition lipophilic ingredients is mixed, again two mixture are mixed, all these operations are all carried out under high temperature (for example 80 ℃), then the amino silicones component is mixed (if in the prescription sometimes), and add sodium chloride, add spice in not spiced shampoo cooling room temperature (25 ℃) and after pearly-lustre occurring at last to regulate viscosity.

The product of making all is the liquid shampoo with attracting pearly-lustre, and the viscosity under its 25 ℃ is 3000～6000 centipoises, and pH is 6～7, and proof all is stable in the high temperature shelf test, can not see component layering and deposited phenomenon.According to the test method described in the description, prove good conditioning shampoo after its opsonizing capacity tested, compare with the tester that does not contain the water-insoluble conditioner in the prescription, all properties is all good than tester.By described each care composition of obtaining of prescription at least with market on the best conditioning shampoo now sold suitable.The opsonic action of the shampoo of prescription 1C even more much better than this best commodity.

When removing the anionic detergent component among the prescription 1C, the hair conditioning of gained (and fiber conbidioning) compositions can be used to handle fibrous material, and can be used for cleaning Crinis Carbonisatus.In these two kinds of purposes, even water washes after the compositions, the toile electrostatic charge is still very low by locate to transfer, and softness, soft and slender sense, glossy is arranged, and outward appearance is tempting.Equally, handle Crinis Carbonisatus like this after, do not have fulsome " swollen flying ", and easier combing and control very much.

Other change of prescription 1A, 1B and 1C is outside the scope of the invention, resemble the change of above mentioned prescription 1C, when long-chain alcohol is removed and replaced by deionized water, when shampoo is deposited at high temperature from prescription, will become unstable, and separate into biphase and (or) have component to be precipitated out.The opsonic action of hair is also bad, and pearly-lustre or do not have or reduce is not attractive.

If the amino silicones among prescription 1A, the 1C is replaced by the nonvolatile polysiloxanes of routine or other amino silicones, then opsonic activity significantly reduces (but still existence).If the amino silicones A of adding 1% is to replace 1% deionized water in prescription 1C, then this active can further the raising, the result is that the percentage composition of amino silicones A is increased to 2.50%, content among the 1A equals to fill a prescription, equally, if 2.5% amino silicones A is added in the prescription of embodiment 1B, to replace 2.50% water, then opsonic action also can be improved greatly.

Embodiment 2

%(weight)

Composition 2A 2B 2C

Dodecane ammonium sulfate 12.50 12.50 12.50

Dodecane diethoxy sodium sulfate 2.50 2.50 2.50

Two (octadecyls) dimethyl

Ammonium chloride 0.50 0.50 0.50

Amino silicones A(Dow-

Cornig） 1.50 - 1.50

The long-chain linear alcohol (Unilin425,

Pelrolito company) 1.50 1.50 1.50

The long-chain linear alcohol (Unilin550,

Pofrolite company) 1.00 1.00 1.00

Ethoxylation long-chain linear alcohol

（Unithox ^TM550，

Pofrolita company) 1.00 1.00 1.00

C _18-36Acid glycerol three esters

（Syncrowax HGL-C

Croda company) 1.00 1.00 1.00

Paraffin (fusing point=53 ℃, Boloy

The oil company)-0.35 0.35

Polyethylene 617-A(Allied

Company)-0.75 0.75

(Brifol 50, Greensboro for mineral oil

The oil company)-1.00 1.00

Isoparaffin (Isopar M,

Exxon company)-0.25 0.25

Laurel one glycollic amide 3.50 3.50 3.50

Antiseptic (GermabenII) 0.50 0.50 0.50

Sodium citrate 0.25 0.25 0.25

Spice 0.80 0.80 0.80

Coloring agent 0.10 0.10 0.10

Deionized water 73.35 72.50 71.00

100.00 100.00 100.00

The shampoo of present embodiment be by the method described in embodiment 1 and description preparation, and find all attractive pearly-lustre of prepared all shampoos, and under the high temperature storage condition, be stable.In addition, they are splendid its hair washing abilities of conditioning hair shampoo and the conditioning hair performance is equivalent to or surpass the best conditioning hair shampoo of selling on the market, and prescription 2A and 2B are equivalent to the opsonizing capacity of commercially available best shampoo, and 2C then surpasses it.Three kinds of shampoos of this that makes have desirable viscosity and pH, and are the same with embodiment 1 compositions.

Embodiment 3

%(weight)

Composition 3A 3B

Dodecane ammonium sulfate 12.50 12.50

Dodecane ethyoxyl sulphuric acid (2Eto) 2.50 2.50

Two (octadecyl) dimethyl ammonium chloride 0.50 0.50

Amino silicones A(Dow-

Corning） 1.50 1.50

Long-chain alcohol (Unilin 425) 1.00 1.00

Microwax 1.00-

White vaseline 0.75-

Syncrowax HGL-C

(Croda company) 0.75 0.75

Polyethylene 617-A(Allied company)-0.75

Mineral oil (Brifor-so)-1.00

Laurel one glycollic amide 3.50 3.50

Hydroxyethyl-cellulose 0.75 0.75

Antiseptic (GermabenII) 0.50 0.50

Coloring agent 0.10 0.10

Spice 0.80 0.80

Deionized water 73.85 73.85

100.00 100.00

The preparation method of present embodiment shampoo Compositions and embodiment 1 and 2 identical with the method for the description of front (and U.S. Patent application S.N.07/432,952), these two kinds of shampoos have all used the saturated primary alconol of long-chain of Unilin425 type, it or and C _18～36(mixing) triglyceride, amino silicones and polyethylene use together, or use with amino silicones, microwax and vaseline, and as the water-insoluble conditioner, the shampoo that makes has tempting pearly-lustre, and be stable when high temperature is deposited.In addition, they have improved the conditioning hair performance, and the opsonic action of prescription 3B is also better than 3A.If the consumption of amino silicones A and Unilin425 is increased to 2.50% and 2.00%, reduce a little deionized waters, then opsonic action is more improved, and stability and pearly-lustre are still splendid.

Embodiment 4

%(weight)

Composition 4A 4B 4C 4D

Dodecane ammonium sulfate 12.50 12.50 12.50 12.50

Dodecane diethoxy sodium sulfate 2.50 2.50 2.50 2.50

Two (octadecyl) dimethyl

Ammonium chloride 0.50 0.50 0.50 0.50

Amino silicones A(Dow-

Corning） 1.50 1.50 1.50 1.50

Long-chain (C ₃₀On average) alcohol 2.50 2.50 1.50 2.50

Long-chain (C ₄₀On average) alcohol--1.00-

Unithox 550 ethoxylations

(13Eto) long-chain

(C ₄₀On average) alcohol--1.00-

Microwax 1.00---

White vaseline 0.75---

Syncrowax

HGL-C - - 1.00 -

Polyethylene 617-A(

Allied company)-0.75-0.75

Paraffin (fusing point=53 ℃)-0.35-0.35

Mineral oil (Brifol 50)-1.00-1.00

Isoparaffin M-0.25-0.25

Laurel one glycollic amide 3.50 3.50 3.50 3.50

Hydroxyethyl-cellulose 250HHR 0.57 0.67-0.67

Hydroxyethyl-cellulose 330CS 0.18 0.23-0.23

Antiseptic 0.50 0.50 0.50 0.50

Sodium chloride 0.20 0.20 0.20 0.20

Sodium citrate--0.25-

Coloring agent 0.10 0.10 0.10 0.10

Spice 0.80 0.80 0.80 0.80

Deionized water 72.90 72.15 73.15 73.65

100.00 100.00 100.00 100.00

The method for making of the compositions of present embodiment and embodiment 1～3 and U.S. Patent application S.N.07/432,952 is identical, the product that obtains all contains the long-chain alcohol or derivatives thereof described in the application, thereby has improved opsonic action and stability, and makes shampoo have pearly-lustre.These products all are the liquid with pearly-lustre that inhale to mend the people, and the viscosity under 25 ℃ is 3000～6000 centipoises, and pH is 6～7.Compare with the compositions that does not contain the long-chain alcohol or derivatives thereof, the stability of all products of present embodiment has all been improved, and all is splendid hair abluent and conditioners.It should be noted that all compositionss all contain preferred long-chain C ₃₀Average alcohol, prescription 4C also contains corresponding C ₄₀Average alcohol and this pure ethoxylated product.

Prescription 4C is gummy not also, and its opsonic action is mainly by amino silicones A, long-chain alcohol and derivant thereof, and chain fatty acid triglycerides (Syncrowax).Stable fixed the turning into of the conditioning performance of prescription 4C with best, but all four kinds of compositionss all are splendid conditioning shampoo conditioning performances gratifying with it, and stability all can be compared with commercially available best conditioning shampoo with outward appearance.

Embodiment 5

All used the mixture of preferred dodecane ammonium sulfate and dodecane ethyoxyl sodium sulfate in the above among the embodiment 1～4, but, for example used C if during with other higher alkyl sulfates _14～18When the sodium salt of alkylsurfuric acid and triethanolamine salt, can obtain similar result, same, dodecane ethyoxyl sodium sulfate can be by C _14～18Alkyl ethoxy sulphuric acid replaces, and wherein ethyoxyl is the individual carbon atoms in (1 or 2)～(5 or 6), is preferably 3 carbon atoms, and sodium can be replaced by ammonium or triethanolamine.Equally, also available other quaternary ammonium salt of two (octadecyl) alkyl dimethyl ammonium chloride replaces, for example three (cetyl) methyl bromination or ammonium chloride, two (dodecyl) diethyl ammonium chloride is sometimes even with trimethyl octadecyl ammonium chloride or its corresponding Adeps Bovis seu Bubali based compound (alkyl wherein is by obtaining in the Adeps Bovis seu Bubali) replacement.Other water-insoluble hair conditioner can change, promptly with the material of being narrated in the description, the carbon atom average that comprises the long-chain primary alconol alcohol chain of other kind ethoxylation is 24～40) and corresponding ester and acid, various adjuvant in the prescription are also replaceable, for example a glycollic amide can be used lauric acid and/or interior myristic acid one or diglycollic amide, or corresponding cocoa alkanolamide, or corresponding isopropanol amide is replaced, can add EDTA, the hydroxylation ethyl cellulose can use hydroxylation third methylcellulose, methylcellulose or other suitable natural gum or thickening agent to replace.In this case, the composition quality height that makes is the satisfactory stable shampoo with tempting pearly-lustre with desirable pH and viscosity of conditioning character.Equally, if when removing anionic detergent, obtain nursing one's health abluent and fiber conbidioning agent in the prescription, similar character is arranged, conditioning fiber shape material satisfactorily as previously mentioned is as hair.These compositionss can be liquid, gel, paste or Emulsion form.

Embodiment 6

Composition %(weight)

Part I A B

Radiation deionized water 72.19 72.89

Hydroxyethyl-cellulose (Natrosol

250 HHR） 0.20 -

Dodecane ammonium sulfate 15.00 15.00

Alkali valency-ammonium phosphate (buffer) 0.10 0.10

The part II

Unilin 425 3.00 3.00

Theobromic acid diglycollic amide 4.00 4.00

The part III

Amino silicones A 3.00 3.00

The part IV

Spice (CP, Paris K3-

157, new revised3) 0.80 0.80

Sodium chloride 0.50-

100.00 100.00

By the same described method basically, respectively the component of part I and part II is mixed earlier, again the two in 90 ℃ of mixing, order adds part III and IV then, will at room temperature carry out when adding the part IV.The existing pearly-lustre of the shampoo of making is attractive in appearance again, and viscosity and pH are also suitable.Conditioning hair and hair washing effect are not worse than the most effective main conditioning hair shampoo on the American market now.

The consumption of amino silicones A is calculated by pure amino silicones in the prescription that provides, though be visbreaking in use, per three parts of polysiloxanes mix (in other embodiments also usefulness like this, amount listed in the example is also calculated by pure amino silicones) with a solvent phase.The ratio of the slow liquid of ammonium phosphate can reach 0.20% in these prescriptions.

In a kind of prescription of change, without Unilin 425, and with Unilin550 or purified long-chain line style saturated alcohols (carbon number in the molecule is 30 or 36 (or its mixed number), and effect is the same.Yet, in prescription, add quaternary ammonium salt, (as two (octadecyl) alkyl dimethyl ammonium chloride) and other conditioner, for example when microwax, vaseline, polyethylene and Cera Flava, conditioning effect can further improve.Amino silicones also can be by for example polysiloxanes and the replacement of other nonvolatile (preferably) water-insoluble polysiloxanes in the U.S. Patent No. 4,702,272 of non-amino silicones and dimethicone.

Embodiment 7

The compositions of previous embodiment also can further be improved, its method is the ratio change ± 10% with its each component, ± 20% and ± 30%, but still remain in the scope that other places are mentioned in the description, compositions after the change is stable shampoo with pearly-lustre and fiber conbidioning product, has improved conditioning hair effect and fiber conbidioning character.When it is used to have one's hair wash or is used for the cleanout fluid of conditioning hair, according to the method described in this explanation, comprise it often being to be applied to fibrous matter or hair under the situation of water adding, then use water rinse, hair washing and handle to such an extent that feel quite pleased.When hair is done or easier combing when wet, and can not gather fulsome electrostatic charge, and the may command head, soft feeling is more arranged during touch.

Assembly of the present invention can be represented with prescription and explanation conduct that top embodiment narrated, in fiber conbidioning field and hair conditioning field, be progressive greatly, the long-chain primary alconol of being narrated (is preferably used saturated fully alcohol or its " derivant ", with water-insoluble conditioner and cationic surfactant) use, can declare and greatly improved conditioning hair compositions, the analogous composition of having bought on the shampoo for example, its conditioning character and former market is the same good or better.With the long-chain alcohol or derivatives thereof of mentioning, can accomplish these as Unilins and Unithoxes, though this class long-chain alcohol or derivatives thereof can have been bought on market, also the no one knows that they are components of conditioning hair compositions or shampoo before this.

In the above-mentioned various patents of this description, patent application and the data delivered and here quoted.

The application is U.S. Patent application S.N.07/432, and 644 and 07/432,952 part continues, and the latter two are S.N.07/369, and 361 part continues.

The present invention is not limited to described explanation and embodiment, and this is because the people that this area is familiar with illustrates according to this, though can use sub and equivalent in not going out scope of the present invention.

Claims

1, a kind of pearly-lustre fiber type care composition that is stable emulsion formula suspension state, it comprises surfactant, the agent of water-insoluble fiber conbidioning.The saturated primary alconol or derivatives thereof of the long-chain of 24～45 carbon atoms of chain length average out to, the ratio of these components will be enough to make emulsion or effect suspension stabilizationization and make it to have the pearly-lustre mother and also comprise aqueous medium.Other composition that can contain adjuvant and this fiber conbidioning compositions in the aqueous medium:

2, a kind of fiber conbidioning compositions of claim 1, it is a kind of conditioning hair compositions, wherein the ratio of surfactant, water-insoluble conditioner, the saturated primary alconol or derivatives thereof of long-chain and aqueous medium is respectively 1～35%, 0.3～10%, 0.5-10% and 50～98%, the ratio of the content of long-chain alcohol or derivatives thereof and conditioner are 0.2～5.

3, a kind of conditioning hair compositions of claim 2, it is a kind of shampoo, contain the synthetic organic anion detergent of 2～35% water solublity, water-insoluble conditioner system is selected from polysiloxanes, quaternary ammonium salt, amine, anion/cationic surface active agent complex, polyethylene, the polyalkylene of oxidation, alkane, different chain hydrocarbon, vaseline, microwax, C in this shampoo _18～36Fatty acid triglycercide; C _18～36Fatty acid, stearic stearolactone, Cera Flava and composition thereof, the saturated primary alconol or derivatives thereof of long key are that at least wherein 80% chain length is the alcohol of 20～54 carbon atoms, the percentage composition of water is 60～90% in the compositions.

4, the shampoo of claim 3, wherein synthetic organic anion detergent are lipotropy sulfate or lipotropy sulfonate, and water-insoluble conditioner system is selected from the chemical compound group that the amino silicones by following formula constitutes:

R in the formula ¹, R ², R ³, R ⁵, R ⁶And R ⁷Be C _1～5Alkyl, R ⁴Be-R ⁸-NH-CH ₂CH ₂-NH ₂, R ⁸Be C _3～6Alkylidene, X are average, are 100～10,000, Y is that average is 0～10, and it is equivalent to 4000～60000 amine equivalent, and logical to be the saturated primary alconol average chain length of the rudimentary imido grpup polymer of solid water-insoluble and composition thereof long-chain be 24～40 carbon numbers.

5, the shampoo of claim 4, wherein synthetic have anionic detergent be higher fatty acid alkyl salt sulphuric acid and (or) senior alkyl lower alkoxy sulfate; The water-insoluble conditioner comprises amino silicones, and it is that X in the above-mentioned formula is 300～10,000, and Y is 0～8, and amine equivalent is 5,000～50,000 o'clock a chemical compound; The water-insoluble conditioner comprises polyethylene.

6, the shampoo of claim 5, the senior fatty alkyl of wherein synthetic organic anion detergent has 6～18 carbon atoms; Exist at the quaternary ammonium salt conditioner; Amino silicones is that the X in the formula is 500～10,000, and Y is less than 5, and amine equivalent is 10,000～40,000 chemical compound; Poly molecular weight is 1000～5000; Exist saturated primary alconol, average nearly 30 carbon; The ratio of this anionic detergent, quaternary ammonium salt, amino silicones, polyethylene, saturated uncle's alcohol and water is respectively 5～35%, and 0.0～5%, 0.3～5%, 0.2-2%, 0.5～6% and 63～80%, all the other are the shampoo adjuvant.

7, the shampoo of claim 6, it contains 10～15% carbon numbers is 12～18 ammonium alkyl sulfate; 5% sulfur fatty alcohol-ether sodium sulfate, this aliphatic alcohol have 12～18 carbon atoms, and ethyoxyl has 1～6; 0.1～0.7% quaternary ammonium halide, this quaternary ammonium salt have 2 or 3 chain alkyls and 2 or 1 short-chain alkyls, carbon number is respectively 12～20 and 1 or 2; The 0.8-4% amino silicones, the saturated primary alconol of 1～5% long-chain, 63～80% water, all the other are adjuvant of shampoo.

8, the shampoo of claim 7, it comprises 2% hydroxyethyl-cellulose; 2～5% Laurels, one glycollic amide and (or) the theobromic acid diglycollic amide; 0.5～2% microwax and 0.5-1% vaseline.

9, the stable pearl shining shampoo agent sent out of a kind of tune of claim 6, it comprises 10～15% carbon numbers is 12～18 ammonium alkyl sulfate; Fatty alcohol-ether sodium sulfate up to 5%, this aliphatic alcohol have 12～18 carbon atoms, and 1-6 ethyoxyl arranged; 0.1～0.7% quaternary ammonium halide, this salt have 2 or 3 chain alkyls, 2 or 1 short-chain alkyls, the carbon number of alkyl are respectively 12～20 or 1 or 2; 0.8～4% amino silicones; 0.5～1.5% is generally solid polyethylene, molecular weight ranges is that the molecular weight ranges of 1000～4000:0.5～2% is 300～800 mineral oil: the saturated primary alconol of 1～5% long-chain; 63～80% water, all the other are the adjuvant of shampoo.

10, the shampoo of claim 9, it comprises 20% hydroxyethyl-cellulose; 2～5% Laurels, one glycollic amide or theobromic acid diglycollic amide; 0.1～1% paraffin and 0.1～0.5% isoparaffin.

11, pearl shining shampoo agent a kind of conditioning hair of claim 6, stable, it comprises the 10-152 carbon number is 12～18 sulfur ammonium alkyl sulfate, fatty alcohol-ether sodium sulfate up to 15% contains the 12-18 carbon atom in this high fatty alcohol, ethyoxyl has 1～6; 0.1～0.7% quaternary ammonium halide, this quaternary ammonium salt have 2 or 3 chain alkyls and 2 or 1 short-chain alkyls, carbon number is respectively 12～20 and 1 or 2; 0.5～15% is generally fixed polyethylene, molecular weight ranges is 1000～4000; 0.5～20% mineral oil, molecular weight are 300～800; The saturated primary alconol of 1～5% long-chain; 63～80% water, all the other are the adjuvant of shampoo.

12, the shampoo of claim 11, it comprises and is no more than 20% hydroxyethyl-cellulose, 2～5% Laurels, one glycollic amide or theobromic acid diglycollic amide; 0.1～1% paraffin and 0.1～0.5% isoparaffin.

13, a kind of shampoo as claimed in claim 6, it comprises 10～15% ammonium alkyl sulfates, and alcohol has 12～18 carbon atoms; Fatty alcohol-ether sodium sulfate up to 2% contains 1～6 ethyoxyl; 0.1～0.7% quaternary ammonium thing halogenide, this quaternary ammonium salt have 2 or 3 chain alkyls and 2 or 1 short-chain alkyls, carbon number is respectively 12～20 and 1 or 2; 0.8～4% amino silicones; The saturated primary alconol of 1～3% long-chain, average chain length are 30 carbon atoms; 0.5 the saturated primary alconol of～3% long-chain, average chain length are 40 carbon atoms; 63～80% water, all the other are the shampoo adjuvant.

14, a kind of shampoo as claimed in claim 13, it comprises the saturated primary alconol of long-chain of ethoxylation more than 0.5～2%, and wherein Chun average chain length is 30～40 carbon atoms, and every mole of usefulness 10～20 oxireme that rubs carries out ethoxylation; 2～5% Laurels, one glycollic amide or theobromic acid diglycollic amide; 0.5～2%C _18～36Acid glycerol three esters and 0.1～0.5% sodium citrate.

15, a kind ofly ask 14 described shampoos as right, it comprises 0.1-1% paraffin; 0.5～1.5% is generally solid polyethylene, molecular weight is 1000～4000; 0.5～2% mineral oil, molecular weight are 300～800.

16, a kind of shampoo as claimed in claim 6, it comprises 10～15% ammonium alkyl sulfates, and its alcohol has 12～18 carbon atoms; Be no more than 5% fatty alcohol-ether sodium sulfate, aliphatic alcohol has 12～18 carbon atoms, and ethyoxyl has 1～6; 0.1～0.7% quaternary ammonium halide, quaternary ammonium salt have 2 or 3 chain alkyls and 2 or 1 short-chain alkyls, contain 12～20 carbon and 1 or 2 carbon atom respectively, 0.8～4% amino silicones; 0.5 the saturated primary alconol of～4% long-chain; 0.25～5%C _18～36(mixing) acid glycerol three esters; 63～80% water, all the other are the adjuvant of shampoo.

17, a kind of shampoo as claimed in claim 16, it comprises 2～5% Laurels, one glycollic amide or theobromic acid diglycollic amide, the hydroxyethyl-cellulose up to 20%; 0.5～2% microwax and 0.5～1% vaseline.

18, a kind of shampoo as claimed in claim 16, it comprises 2～5% Laurels, one glycollic amide or theobromic acid diglycollic amide, the hydroxyethyl-cellulose up to 2%; 0.5 the mineral oil of～15% polyethylene and 0.5～2%, molecular weight are 300～600.

19, a kind of method of conditioning fiber material, this method comprises that the fiber conbidioning compositions with claim 1 compositions is used for this fibrous matter, wash this care composition on the fibrous matter then, thereby the conditioning amount of conditioner is stayed on the fibrous matter.

20, the method for a kind of hair washing and conditioning hair, it comprises that the conditioning with the shampoo of claim 3 partly is used for Crinis Carbonisatus, cleans the shampoo on the hair then, thereby the conditioner of conditioning is stayed on the hair.