CN105542596A - Anti-penetration gloss oil for IR (Infrared) ink and application of anti-penetration gloss oil - Google Patents

Anti-penetration gloss oil for IR (Infrared) ink and application of anti-penetration gloss oil Download PDF

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Publication number
CN105542596A
CN105542596A CN201510966554.1A CN201510966554A CN105542596A CN 105542596 A CN105542596 A CN 105542596A CN 201510966554 A CN201510966554 A CN 201510966554A CN 105542596 A CN105542596 A CN 105542596A
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Prior art keywords
gloss oil
impermeable
ink
penetration
application
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CN201510966554.1A
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CN105542596B (en
Inventor
周群飞
饶桥兵
阳谋
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Lens Technology Changsha Co Ltd
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Lens Technology Changsha Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses anti-penetration gloss oil and application thereof. The anti-penetration gloss oil contains printing ink, a hardener, a cross-linker and a diluent. The anti-penetration gloss oil is anti-penetration interlayer oil having the characteristics of good light transmittance, high density and high adhesive power; and before printing an IR (Infrared) ink layer on the surface of a base body, the surface of the base body is firstly printed with an anti-penetration gloss oil layer, and then, the anti-penetration gloss oil layer is printed with the IR ink layer, so that the problem of ghosting caused by IR ink penetration can be effectively solved.

Description

A kind of impermeable gloss oil for IR ink and application thereof
Technical field
The present invention relates to a kind of impermeable gloss oil for IR ink, and impermeable gloss oil is preventing the application in IR ink penetration, belongs to the processing technique field of electronic touch panel.
Background technology
IR is exactly the abbreviation of English infrared waves.
IR ink divides two types: (1), IR clear ink: be exactly the light wave of energy selectivity through needs, and shield unwanted light wave selectively, infrared rays can be allowed to pass through, and visible light and ultraviolet are blocked.(2), IR photosensitive-ink: be exactly react and variable color under some light wave selectively, the color of rear ink becomes again original color again but these light waves disappear.
IR ink is with the relevant ink of infrared waves, general touch-screen mobile phone all has infrared induction hole, when face pressed close to by mobile phone, in order to avoid face error touch control mobile phone, automatically screen will be closed when mobile phone infrared inductor senses face, and IR ink is exactly the main raw of gear before infrared sense hole; This ink can make 800nm (the infrared light consistent wavelength that human body sends) pass through, and filters the light wave of other wavelength.
Because above shielding or selective light wave energy need be met, IR ink main component is formed by the raw material cooperation that the perviousness such as pigment, resin, gloss oil, photoactivation compound are strong, so existing electronic touch panel processing technique field, all there is the technical barrier of IR infiltration in IR ink printing on the main surface printing ink such as white, gold, grey.
IR ink is functional ink, and it is quite high to the requirement of impermeable interlayer oil, and IR ink major function need meet the light wave function that shielding light wave not or selection are wanted, and therefore requires that impermeable interlayer preservative oil need meet and does not stop light wave effect.IR is with transmission region management and control, and in order to light wave is unaffected, impermeable interlayer preservative oil light transmission need reach more than 91%; IR has color management and control requirement, and therefore impermeable interlayer preservative oil need reach high brightness, clear, the high transparency of light, does not affect color effects; Impermeable interlayer preservative oil sticking power need reach 5B; Impermeable interlayer preservative oil need reach high-density 4.5, has high anti-permeability; Impermeable interlayer preservative oil technique connects can not have step sense need reach ultra-thin effect; And the performance of existing impermeable oil reservoir can not reach requirement far away, its light transmission can only reach 89%, brightness is partially dark, transparency is vaporific, sticking power 3B, density 3.5, is difficult to meet application requiring.
Summary of the invention
For the defect that existing impermeable interlayer oil exists, the object of the invention is to be to provide one can effectively prevent IR ink penetration, and have that light transmission is good, density is high, the impermeable interlayer oil of strong adhesion.
Another object of the present invention is the application being to provide described impermeable interlayer oil, prints the impermeable interlayer oil of one deck effectively can solve IR ink penetration ghost problems at IR ink and matrix surface.
The invention provides a kind of impermeable gloss oil, this impermeable gloss oil comprises following content of component: 100 parts, ink; Stiffening agent 6 ~ 15 parts; Linking agent 1 ~ 5 part; Thinner 2 ~ 9 parts;
Described ink by urethane and polyacrylic ester in mass ratio 35 ~ 45%:55 ~ 65% form;
Described stiffening agent is reflected by aliphatic amide, alicyclic ring and forms with polymeric amide 75 ~ 85%:8 in mass ratio ~ 16%:5 ~ 11%;
Described linking agent is epoxy silane.
The ink resin (BMR-S-800) that technical scheme of the present invention adopts has the feature such as high permeability, hardness and wear-resisting, luminosity, brightness; The stiffening agent (as D stiffening agent) adopted is for promoting resin solidification film forming; Thinner (as T-980) mainly rises and dissolves dissemination; Linking agent (CARE73) has the effect strengthening density of film, improve impermeable effect.
Preferred scheme, impermeable gloss oil is made up of following content of component: 100 parts, ink; Stiffening agent 8 ~ 12 parts; Linking agent 2 ~ 4 parts; Thinner 3 ~ 6 parts;
Described ink by urethane and polyacrylic ester in mass ratio 40%:60% form;
Described stiffening agent by aliphatic amide, alicyclic ring reflect with polymeric amide in mass ratio 80%:12%:8% form;
Preferred scheme, thinner by aliphatic hydrocarbon and aromatic hydrocarbon in mass ratio 50 ~ 70%:30 ~ 50% form; Most preferably be 60%:40% composition in mass ratio.
Ink of the present invention (urethane, polyacrylic ester), stiffening agent (aliphatic amide, alicyclic ring reflect, polymeric amide), the medicaments such as thinner (aliphatic hydrocarbon and aromatic hydrocarbon), linking agent (epoxy silane) are all commercially available conventional dose, all can buy in Jiaxing, Shenzhen printing apparatus company limited or Nanjing Cai Yao novel material Science and Technology Ltd. etc.
Present invention also offers a kind of application of described impermeable gloss oil, impermeable gloss oil is applied to and prevents IR ink penetration.
Technical scheme of the present invention, impermeable oil reservoir is by being printed on matrix surface, hot setting again, formation density is high, the rete of stable chemical nature, effectively can prevent the infiltration of IR ink, the macromolecule membranous layer light transmission simultaneously formed after resin solidification is good, and the macromolecule membranous layer particularly formed is strong at surface adhesion forces such as glass, good with the consistency of IR ink.Efficiently solve IR ink penetration ghost problems.
Preferred scheme, before matrix surface printing IR ink layer, first prepares the impermeable gloss oil layer of one deck at matrix surface.
More preferably scheme, infiltration gloss oil layer thickness is 2 ~ 4 μm.
More preferably scheme, matrix is electronic product panel or film against sunshine.
More preferably scheme, first prints the impermeable gloss oil of one deck at matrix surface, after baking-curing, republishes one deck IR ink.
Preferred scheme further, baking toasts 9 ~ 11min at 170 ~ 180 DEG C of temperature.
Hinge structure, the Advantageous Effects that technical scheme of the present invention is brought:
1, after impermeable gloss oil layer solidification of the present invention, transparency will reach more than 90%, and light is clear, does not affect the attractive in appearance of IR ink;
2, the density of film, the stable chemical nature that are formed after impermeable gloss oil layer solidification of the present invention, reach and prevent IR ink penetration effect;
3, impermeable gloss oil layer solidification postadhesion power of the present invention is strong, reaches 5B;
4, have wide range of applications, electric appliance remote controller, smart mobile phone, panel computer, phone housing, solar film, sunbonnet, automobile etc. can be used in.
Accompanying drawing explanation
[Fig. 1] is for having printed the Product Rendering sheet of impermeable oil reservoir before printing IR ink;
[Fig. 2] directly prints the Product Rendering sheet of IR ink.
Embodiment
Following examples are intended to further illustrate content of the present invention, instead of the protection domain of restriction the claims in the present invention.
Embodiment 1
The first step: design the anti-IR protection of penetration oil film (on the basis of hole 1:1 externally expanding single edge 0.2MM);
Second step: design the anti-IR oil film (on the basis of hole 1:1 externally expanding single edge 0.3MM);
3rd step: carry out alignment operation by the film screen frame made to 45PA printing machine platform;
4th step: allocate impermeable gloss oil (BMR-S-800:D stiffening agent: epoxy silane: T-980=100:10:3:5);
5th step: install scraper, returning blade, (parameter: scraper speed 300mm/s ± 100, time black speed 300mm/s ± 100);
6th step: debugging printing (all wave band transmittance management and control 90%);
7th step: impermeable gloss oil is printed onto the product surface (mainly making IR and the effect of face version oil interlayer) treating IR;
8th step: the product having printed impermeable gloss oil drops into baking, and (180 DEG C ± 10 DEG C/10 ± 1min makes surface tissue solidify, and strengthens impermeabilisation ability;
9th step: IR oil is printed on impermeable gloss oil reaches and prevents IR ink penetration effect (IR wave band management and control on request: 550nm/15 ± 5%, 850nm/≤80%).
The transparency of impermeable layer will reach more than 90%; Sticking power reaches 5B.
As can be seen from Figure 1 before printing IR ink, print the impermeable gloss oil layer of one deck, blocked the perviousness of IR oil by impermeable gloss oil layer, product I R clear attractive in appearance, reach anti-IR osmosis process effect.
As can be seen from Figure 2 IR ink penetration crosses product face version, forms uneven black circle in ink; Have a strong impact on product aesthetic.

Claims (10)

1. an impermeable gloss oil, is characterized in that: comprise following content of component:
100 parts, ink;
Stiffening agent 6 ~ 15 parts;
Linking agent 1 ~ 5 part;
Thinner 2 ~ 9 parts;
Described ink by urethane and polyacrylic ester in mass ratio 35 ~ 45%:55 ~ 65% form;
Described stiffening agent is reflected by aliphatic amide, alicyclic ring and forms with polymeric amide 75 ~ 85%:8 in mass ratio ~ 16%:5 ~ 11%;
Described linking agent is epoxy silane.
2. impermeable gloss oil according to claim 1, is characterized in that: be made up of following content of component:
100 parts, ink;
Stiffening agent 8 ~ 12 parts;
Linking agent 2 ~ 4 parts;
Thinner 3 ~ 6 parts;
Described ink by urethane and polyacrylic ester in mass ratio 40%:60% form;
Described stiffening agent by aliphatic amide, alicyclic ring reflect with polymeric amide in mass ratio 80%:12%:8% form.
3. impermeable gloss oil according to claim 1 and 2, is characterized in that: described thinner by aliphatic hydrocarbon and aromatic hydrocarbon in mass ratio 50 ~ 70%:30 ~ 50% form.
4. impermeable gloss oil according to claim 3, is characterized in that: thinner by aliphatic hydrocarbon and aromatic hydrocarbon in mass ratio 60%:40% form.
5. the application of the impermeable gloss oil described in claim 1 or 2, is characterized in that: be applied to and prevent IR ink penetration.
6. the application of impermeable gloss oil according to claim 5, is characterized in that: before matrix surface printing IR ink layer, first print impermeable gloss oil layer at matrix surface, then print IR ink layer on impermeable gloss oil layer.
7. the application of impermeable gloss oil according to claim 6, is characterized in that: described infiltration gloss oil layer thickness is 2 ~ 4 μm.
8. the application of impermeable gloss oil according to claim 6, is characterized in that: described matrix is electronic product panel or film against sunshine.
9. the application of the impermeable gloss oil layer according to any one of claim 6 ~ 8, is characterized in that: first print impermeable gloss oil layer at matrix surface, after baking-curing, republishes IR ink layer.
10. the application of impermeable gloss oil according to claim 9, is characterized in that: described baking toasts 9 ~ 11min at 170 ~ 180 DEG C of temperature.
CN201510966554.1A 2015-12-21 2015-12-21 A kind of impermeable gloss oil and its application for IR ink Active CN105542596B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109569983A (en) * 2018-12-22 2019-04-05 东莞市诚嘉隆植绒制品有限公司 A kind of paper jam flocking method
CN110757973A (en) * 2019-11-11 2020-02-07 保定永丽印务有限公司 Kraft paper suitable for low-temperature printing and black card flat screen printing process
CN112172372A (en) * 2020-09-29 2021-01-05 中星中大印刷(深圳)有限公司 Plastic-free coating laminating process and plastic-free coating laminating paper
CN114714783A (en) * 2022-01-26 2022-07-08 东莞华清光学科技有限公司 Process for improving printing effect of IR (infrared radiation) ink

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220568A (en) * 2007-11-30 2008-07-16 大亚科技股份有限公司 Water and mist preventing UV antiseptic varnish formula
CN102863849A (en) * 2012-09-29 2013-01-09 苏州安洁科技股份有限公司 IR (infrared) purple ink

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220568A (en) * 2007-11-30 2008-07-16 大亚科技股份有限公司 Water and mist preventing UV antiseptic varnish formula
CN102863849A (en) * 2012-09-29 2013-01-09 苏州安洁科技股份有限公司 IR (infrared) purple ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109569983A (en) * 2018-12-22 2019-04-05 东莞市诚嘉隆植绒制品有限公司 A kind of paper jam flocking method
CN110757973A (en) * 2019-11-11 2020-02-07 保定永丽印务有限公司 Kraft paper suitable for low-temperature printing and black card flat screen printing process
CN112172372A (en) * 2020-09-29 2021-01-05 中星中大印刷(深圳)有限公司 Plastic-free coating laminating process and plastic-free coating laminating paper
CN114714783A (en) * 2022-01-26 2022-07-08 东莞华清光学科技有限公司 Process for improving printing effect of IR (infrared radiation) ink

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