CN105536399A - Flue gas purifying apparatus - Google Patents

Flue gas purifying apparatus Download PDF

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Publication number
CN105536399A
CN105536399A CN201510927997.XA CN201510927997A CN105536399A CN 105536399 A CN105536399 A CN 105536399A CN 201510927997 A CN201510927997 A CN 201510927997A CN 105536399 A CN105536399 A CN 105536399A
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CN
China
Prior art keywords
flow
flue gas
absorber portion
purifier according
disturbing parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510927997.XA
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Chinese (zh)
Inventor
周俊虎
刘茂省
杨雪峰
刘晓燕
金圣�
孙琦明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Pyneo Technology Co Ltd
Original Assignee
Zhejiang Pyneo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Pyneo Technology Co Ltd filed Critical Zhejiang Pyneo Technology Co Ltd
Priority to CN201510927997.XA priority Critical patent/CN105536399A/en
Publication of CN105536399A publication Critical patent/CN105536399A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

Abstract

The invention discloses a flue gas purifying apparatus. The apparatus comprises a flue gas purifying unit, an absorbent supplying unit, a slurry oxidizing unit, and a gypsum dehydration unit. The flue gas purifying unit comprises a flue gas outlet flue, a demisting segment, a spray layer, and an absorption segment; at least one wet electrostatic precipitator is arranged between the flue gas outlet flue and the demisting segment. The apparatus has the advantages of simple structure, convenient installation, cleanliness of the discharged flue gas, and reduced discharge content of pollutants from the flue gas to the atmosphere.

Description

Smoke eliminator
Technical field
The invention belongs to filed of flue gas purification, especially relate to a kind of smoke eliminator.
Background technology
If conventional desulfurization method of limestone-gypsum does not arrange synergistic device, may occur flue gas and grout distribution inequality in absorption tower, time of contact is short, and gas-liquid contact face is inadequate, the phenomenons such as mass transfer effect is not good.In addition, conventional flue gas purification system, cannot be less than the soot emissions requirement of 5mg/Nm, and often occur gypsum rain phenomenon, affect whole process for purifying flow process.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides the smoke eliminator that a kind of structure is simple, gas cleaning is effective.
The technical solution adopted for the present invention to solve the technical problems is: a kind of smoke eliminator, comprise gas cleaning unit, absorbent feeding unit, slurries oxidation unit and gypsum dehydration unit, described gas cleaning unit comprises exhanst gas outlet flue, demist section, spraying layer and absorber portion, is provided with at least one wet electrical dust precipitator between described exhanst gas outlet flue and demist section.
Further, wet electrical dust precipitator is connected with heating blower.The motor of protection wet electrical dust precipitator, avoids it to damage under too high moisture.
Further, absorbent feeding unit comprises the slurry tank be connected with absorber portion by pipeline, the first agitator be located at first pump housing on pipeline and be located in slurry tank; Described slurries oxidation unit comprises the second agitator be located in absorber portion and the oxidation fan passed in absorber portion; Described gypsum dehydration unit comprise be connected with absorber portion second pump housing, circulator, thin pulp case, the 3rd agitator be located in thin pulp case, belt filter and for liquid in thin pulp case is pumped into absorber portion the 3rd pump housing.
Further, synergistic device layer is provided with below spraying layer.Further raising reaction efficiency, improves removal effect.
Further, synergistic device layer comprises at least one group of flow-disturbing parts, and these flow-disturbing parts comprise multiple the first body be arranged in parallel and are located at multiple second bodys below this first body, and between described first body and second pipe body, parallel interval is arranged.Synergistic device layer changes flowing velocity and the flow field of flue gas, counteract the adverse effect of some Imported inequality and whirlpool stream field, make the Flow Field Distribution in tower more even, enhance the mass transfer of slurries and flue gas, heat transfer simultaneously, even if under low flue gas flow, also can ensure that absorber portion stably completes gas-liquid mass transfer, prolong smoke flows through route, increase the time of contact of flue gas and slurries, thus improve the utilization rate of desulfurizing agent, and there will not be the phenomenon such as fouling or blocking.
Further, synergistic device layer comprises at least two group flow-disturbing parts be arranged in parallel up and down, arranges in the same way between the first flow-disturbing parts in top and the second flow-disturbing parts in below.
Further, synergistic device layer comprises at least two group flow-disturbing parts be arranged in parallel up and down, has the anglec of rotation and arrange between the first flow-disturbing parts in top and the second flow-disturbing parts in below.
Further, the first body is provided with for the deflector by flue gas shunting.
Further, deflector is reverse V-shaped structure.
The invention has the beneficial effects as follows, structure is simple, and it is convenient to install, add wet electrical dust precipitator not only sulfur dioxide to be removed, also the fine solid particle in flue gas is processed, add the cleanliness factor of discharge flue gas, effectively prevent the phenomenon such as " gypsum rain ", " plume "; The setting of synergistic device layer increases again gas-liquid contact face, add mass transfer effect, make the absorbent added in tower reach peak use rate, and then improve removal efficiency and the removal effect of sulfur dioxide, further reduce the pollutant load finally draining into flue gas in air.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is the main TV structure schematic diagram of synergistic device layer of the present invention.
Fig. 3 is the plan structure schematic diagram of synergistic device layer of the present invention.
Fig. 4 is the structural representation of the present invention first body and deflector.
Fig. 5 is the part structure for amplifying schematic diagram of synergistic device layer.
Detailed description of the invention
Better the present invention program is understood in order to make those skilled in the art person, below in conjunction with the accompanying drawing in the embodiment of the present invention, clear, complete description is carried out to the technical scheme in the embodiment of the present invention, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, should belong to the scope of protection of the invention.
With reference to shown in Fig. 1, a kind of smoke eliminator, comprises gas cleaning unit, absorbent feeding unit, slurries oxidation unit and gypsum dehydration unit.Gas cleaning unit comprises exhanst gas outlet flue 1 and is located at demist section 21, spraying layer 22, the absorber portion 23 in tower body from top to bottom, at least one wet electrical dust precipitator 3 is provided with between exhanst gas outlet flue 1 and demist section 21, this wet electrical dust precipitator 3 can be arranged in tower body, also can independently be arranged on tower body outside, wet electrical dust precipitator 3 is also connected with heating blower 31.Absorbent feeding unit comprise be connected with absorber portion 23 by pipeline slurry tank 41, be connected in first pump housing 42 on pipeline and be located at for stirring the first agitator 43 of slurries in slurry tank 41, in the present embodiment, absorbent is lime stone suspension.Slurries oxidation unit comprises the second agitator 51 be located in absorber portion 23 and the oxidation fan 52 passed into by air in absorber portion 23.Gypsum dehydration unit comprise with second pump housing 61 be connected bottom absorber portion 23, circulator 62, thin pulp case 63, the 3rd agitator 64 be located in thin pulp case 63, for carrying the belt filter 65 of finished product gypsum and the 3rd pump housing 66 for liquid in thin pulp case 63 being pumped into absorber portion 23.
With reference to shown in Fig. 2-5, the below of spraying layer 22 is provided with synergistic device layer 24, it comprises at least one group of flow-disturbing parts, flow-disturbing parts comprise be connected to tower body inwall brace summer 244, be connected to multiple first body 241 of brace summer 244 upper surface and be connected to multiple second bodys 242 of brace summer 244 lower surface, certainly for the tower body that tower diameter is less, flow-disturbing parts can save brace summer 244, are directly connected on the inwall of tower by the end winding support of the first body 241 and the second body 242.Diameter is first body 241 of D and the second body 242 are fixedly connected on brace summer 244 upper and lower surface respectively by fastener.Parallel laying between adjacent first body 241, and distance is S, parallel laying between same adjacent second body 242, and distance is S, the vertical range up and down of the first body 241 and the second body 242 is H, ensures H≤3D, S:D=1-1.5,50≤D≤150mm, 50≤S≤200mm.Between first body 241 and the second body 242, parallel interval is arranged, i.e. the lower position in the second body 242 gap between two adjacent first bodys 241.In order to reach desirable desulfurized effect, can two groups of flow-disturbing parts be set up and down abreast, the first flow-disturbing parts namely in top and arranging in the same way between the second flow-disturbing parts of below.Also the first flow-disturbing parts being positioned at top can be arranged in certain anglec of rotation abreast with the second flow-disturbing parts being positioned at below.In order to alleviate the weight of flow-disturbing parts, the first body 241 and the second body 242 are tubular structure.First body 241 and the second body 242 all adopt FRP, 2205,2507 or 1.4529 materials, and brace summer 244 adopts carbon steel, and outer setting is anticorrosion.Worn and torn by the slurries that spraying layer 22 sprays to prevent body, also in order to shunt slurries, can arrange deflector 243 respectively directly over the first body 241, this deflector 243 can be reverse V-shaped structure, also can be inverted U structure, in the present embodiment, it be for being inverted angle steel.
When pending flue gas from the below of flow-disturbing parts through the gap the second body 242, because space diminishes, the flow velocity of flue gas increases, flow-disturbing effect is formed from the flue gas passed through between adjacent segment, and the flow velocity of flue gas reduces, flue gas afterwards between adjacent segment converges again by the gap between the first body 241, the flow velocity of flue gas becomes large again, its with spray above the first body 241 and slurries formed and clash into, because slurries are through the shunting action of deflector 243, more effective turbulence is formed again between slurries and flue gas, thus add the time of contact of flue gas and slurries, the mixed effect of flue gas and slurries is better.According to external diameter and the pending flue gas flow difference of tower body, the quantity of the first body 241 and the second body 242 can adjust, and the number of superposition group up and down of flow-disturbing parts also can correspondingly adjust.
Workflow of the present invention is, is added by agstone in slurry tank 41, and the first agitator 43 constantly stirs it, ensures that the slurries in slurry tank 41 are in suspended state.Lime stone suspension is delivered in the absorber portion 23 in tower body by first pump housing 42, before being delivered in tower body, is also furnished with lime stone slurry return duct.Liquid in second 51 pairs, agitator absorber portion 23 constantly stirs.Liquid in absorber portion 23 is pumped into spraying layer 22 by the 4th pump housing 221.Flue gas enters in tower body from the passage being located at tower body sidewall, it moves upward and to be uniformly distributed after synergistic device layer 24, the reverse haptoreaction of liquid sprayed with spraying layer 22, under the reaction temperature and pH value condition of the best, in flue gas, most sulfur dioxide, flue dust are neutralized, and washing also falls in absorber portion 23 along with desulfurization slurry.Flue gas after washing continues to move upward and enters demist section 21, removes drop.This demist section 21 is also accompanied with fresh water (FW) flusher.Flue gas enters wet electrical dust precipitator 3 after demist section 21, and this wet electrical dust precipitator 3 entrance arranges guiding device, and flue gas is evenly entered in it.The subsidiary hot wind supply system of wet electrical dust precipitator 3, i.e. heating blower 31, and spray irrigation system, established technology water flows in wet electrical dust precipitator 3 from B punishment, and the waste water of simultaneously discharging through wet electrical dust precipitator 3 recycles.Flue gas is disposed in air by exhanst gas outlet flue 1 after wet electrical dust precipitator 3.
In absorber portion 23, also constantly stir the second agitator 51 by oxidation fan 52 input air oxidation reaction occurs, generate gypsum, absorber portion 23 has enough volumes, ensures the time of staying needed for gypsum crystallization.Liquid in absorber portion 23 is pumped into spraying layer 22 again by the 4th pump housing 221, constantly carries out circular response.
Gypsum slurries in absorber portion 23 is delivered to cyclone 62 by second pump housing 61, and cyclone 62 underflow enters belt filter 65, and its top flows to into thin pulp case 63, and the slurries in thin pulp case 63 are delivered in absorber portion 23 by the 3rd pump housing 66 again and carry out circular response.Gypsum slurries obtains finished product gypsum through belt filter 65.
Above-mentioned detailed description of the invention is used for explaining and the present invention is described, instead of limits the invention, and in the protection domain of spirit of the present invention and claim, any amendment make the present invention and change, all fall into protection scope of the present invention.

Claims (9)

1. a smoke eliminator, comprise gas cleaning unit, absorbent feeding unit, slurries oxidation unit and gypsum dehydration unit, described gas cleaning unit comprises exhanst gas outlet flue (1), demist section (21), spraying layer (22) and absorber portion (23), it is characterized in that: be provided with at least one wet electrical dust precipitator (3) between described exhanst gas outlet flue (1) and demist section (21).
2. purifier according to claim 1, is characterized in that: described wet electrical dust precipitator (3) is connected with heating blower (31).
3. purifier according to claim 1, is characterized in that: described absorbent feeding unit comprises the slurry tank (41) be connected with absorber portion (23) by pipeline, the first agitator (43) be located at first pump housing (42) on pipeline and be located in slurry tank (41); Described slurries oxidation unit comprises the second agitator (51) be located in absorber portion (23) and the oxidation fan (52) passed in absorber portion (23); Described gypsum dehydration unit comprises second pump housing (61), circulator (62), thin pulp case (63), the 3rd agitator (64) be located in thin pulp case (63), belt filter (65) and the 3rd pump housing (66) for thin pulp case (63) interior liquid being pumped into absorber portion (23) that are connected with absorber portion (23).
4. purifier according to claim 1, is characterized in that: described spraying layer (22) below is provided with synergistic device layer (24).
5. purifier according to claim 1, it is characterized in that: described synergistic device layer (24) comprises at least one group of flow-disturbing parts, these flow-disturbing parts comprise multiple the first body (241) be arranged in parallel and multiple second bodys (242) being located at this first body (241) below, and between described first body (241) and the second body (242), parallel interval is arranged.
6. purifier according to claim 1, is characterized in that: described synergistic device layer (24) comprises at least two group flow-disturbing parts be arranged in parallel up and down, arranges in the same way between the first flow-disturbing parts in top and the second flow-disturbing parts in below.
7. purifier according to claim 1, it is characterized in that: described synergistic device layer (24) comprises at least two group flow-disturbing parts be arranged in parallel up and down, between the first flow-disturbing parts in top and the second flow-disturbing parts in below, there is the anglec of rotation and arrange.
8. purifier according to claim 1, is characterized in that: described first body (241) is provided with for the deflector (243) by flue gas shunting.
9. purifier according to claim 1, is characterized in that: described deflector (243) is in reverse V-shaped structure.
CN201510927997.XA 2015-12-15 2015-12-15 Flue gas purifying apparatus Pending CN105536399A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109200721A (en) * 2018-10-12 2019-01-15 安徽天诚环保机械有限公司 A kind of Multistage Circulating high-effective dust-removing technique
CN112999839A (en) * 2021-03-26 2021-06-22 四川利弘陶瓷有限公司 Flue gas desulfurization system of drying tower kiln

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CN201760285U (en) * 2010-07-10 2011-03-16 山西天大化工工程有限公司 Novel grating filler
CN202237786U (en) * 2011-10-14 2012-05-30 华南理工大学 Tangent circle type spiral injection wet flue gas desulphurization device
CN102500223A (en) * 2011-12-02 2012-06-20 武汉永清环保科技工程有限公司 Equipment for performing wet-method flue gas desulfurization and producing gypsum by discarded carbide slag
CN102764582A (en) * 2012-08-09 2012-11-07 武汉钢铁(集团)公司 High-quality spray absorber for wet flue gas desulfurization
CN102805999A (en) * 2012-08-23 2012-12-05 北京威肯众合环保科技有限公司 Turbulent ball type turbocharging compound desulfurization dust removal tower
CN102872709A (en) * 2012-09-17 2013-01-16 江苏和亿昌环保工程科技有限公司 Process of efficiently capturing aerosol in desulfurized flue gas
CN202822831U (en) * 2012-10-31 2013-03-27 重庆恒远晋通科技有限公司 Rectification tower plate combination block and rectification tower
CN104607135A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Common jujube seed-shaped grid type structured packing

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995033547A1 (en) * 1994-06-09 1995-12-14 Abb Environmental Systems Improved wet scrubbing method and apparatus for removing sulfur oxides from combustion effluents
US20110002828A1 (en) * 2009-07-06 2011-01-06 Mitsubishi Heavy Industries, Ltd. Mercury reduction system and mercury reduction method of flue gas containing mercury
CN101670223A (en) * 2009-09-18 2010-03-17 山东泰山建能机械集团有限公司 Method and device for desulfurizing flue gas
CN201760285U (en) * 2010-07-10 2011-03-16 山西天大化工工程有限公司 Novel grating filler
CN202237786U (en) * 2011-10-14 2012-05-30 华南理工大学 Tangent circle type spiral injection wet flue gas desulphurization device
CN102500223A (en) * 2011-12-02 2012-06-20 武汉永清环保科技工程有限公司 Equipment for performing wet-method flue gas desulfurization and producing gypsum by discarded carbide slag
CN102764582A (en) * 2012-08-09 2012-11-07 武汉钢铁(集团)公司 High-quality spray absorber for wet flue gas desulfurization
CN102805999A (en) * 2012-08-23 2012-12-05 北京威肯众合环保科技有限公司 Turbulent ball type turbocharging compound desulfurization dust removal tower
CN102872709A (en) * 2012-09-17 2013-01-16 江苏和亿昌环保工程科技有限公司 Process of efficiently capturing aerosol in desulfurized flue gas
CN202822831U (en) * 2012-10-31 2013-03-27 重庆恒远晋通科技有限公司 Rectification tower plate combination block and rectification tower
CN104607135A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Common jujube seed-shaped grid type structured packing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109200721A (en) * 2018-10-12 2019-01-15 安徽天诚环保机械有限公司 A kind of Multistage Circulating high-effective dust-removing technique
CN112999839A (en) * 2021-03-26 2021-06-22 四川利弘陶瓷有限公司 Flue gas desulfurization system of drying tower kiln

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Inventor after: Liu Maosheng

Inventor after: Yang Xuefeng

Inventor after: Liu Xiaoyan

Inventor after: Jin Sheng

Inventor after: Sun Qiming

Inventor before: Zhou Junhu

Inventor before: Liu Maosheng

Inventor before: Yang Xuefeng

Inventor before: Liu Xiaoyan

Inventor before: Jin Sheng

Inventor before: Sun Qiming

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Application publication date: 20160504