CN105529332B - A kind of codec type vertical gate 3D NAND and forming method thereof - Google Patents

A kind of codec type vertical gate 3D NAND and forming method thereof Download PDF

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Publication number
CN105529332B
CN105529332B CN201610018226.3A CN201610018226A CN105529332B CN 105529332 B CN105529332 B CN 105529332B CN 201610018226 A CN201610018226 A CN 201610018226A CN 105529332 B CN105529332 B CN 105529332B
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layer
nand
substrate
type vertical
codec type
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CN105529332A (en
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邓宁
吴华强
丰伟
钱鹤
舒清明
朱明�
朱一明
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Zhaoyi Innovation Technology Group Co ltd
Tsinghua University
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Tsinghua University
GigaDevice Semiconductor Beijing Inc
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B69/00Erasable-and-programmable ROM [EPROM] devices not provided for in groups H10B41/00 - H10B63/00, e.g. ultraviolet erasable-and-programmable ROM [UVEPROM] devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42356Disposition, e.g. buried gate electrode

Abstract

The invention discloses a kind of codec type vertical gate 3D NAND and forming method thereof, and the method comprising the steps of: providing substrate;One or more layers semiconductor layer is formed in substrate;One or more layers semiconductor layer is etched to form multiple grooves;Gate structure is formed on the top in multiple grooves and across multiple grooves;Polysilicon layer is formed across the top of multiple grooves;Multiple grid materials are etched to gate structure and fill hole, hole is filled to polysilicon layer etching source material;Deposition of electrode material in hole and multiple grid materials filling hole is filled in source electrode material.The present invention has the advantage that having vertical direction more better than BICS structure to expand potentiality, influence of the increase of the number of plies for the performance of single storage tube is much smaller compared to the three-dimensional storage of vertical-channel, and this structure is also easier in technique, reduce the step of zanjon etches this complicated and time consumption, entire technique and current technology are completely compatible.

Description

A kind of codec type vertical gate 3D NAND and forming method thereof
Technical field
The present invention relates to semiconductor fields, and in particular to a kind of codec type vertical gate 3D NAND and forming method thereof.
Background technique
With the diminution of process, the cost that the storage density based on planar structure improves is also higher and higher, then produces Three-dimensional storage organization is given birth to.BiCS (Bit Cost Scalable) structure is the very extensive 3D flash knot of existing research Structure, the storage unit that the storage density of BiCS structure compares planar structure has large increase, but space utilization rate is still insufficient.
Summary of the invention
The present invention is directed at least solve one of above-mentioned technical problem.
For this purpose, an object of the present invention is to provide a kind of codec type vertical gate 3D NAND forming methods.
Two purposes of the invention are to propose a kind of codec type vertical gate 3D NAND.
To achieve the goals above, embodiment of the invention discloses a kind of codec type vertical gate 3D NAND forming method, The following steps are included: providing substrate;The first separation layer is formed in the substrate;One is formed on first separation layer Layer or multi-lager semiconductor layer;One or more layers described semiconductor layer is etched to form multiple grooves, the multiple groove extends to The top surface of first separation layer;Silica tunnel layer is formed to the deposit silica of the multiple groove;Institute State deposit silicon nitride electric charge capture layer and silicon dioxide blocking layer on silica tunnel layer;It is in the multiple groove and horizontal Gate structure is formed on the silicon dioxide blocking layer at the top across the multiple groove;Across the top of the multiple groove Polysilicon layer is formed on the silicon dioxide blocking layer in portion;Multiple grid materials are etched to the gate structure and fill hole, The multiple grid material filling hole extends to the top surface of first separation layer, to the polysilicon layer etching source material Material filling hole, source electrode material filling hole hole extend to the top surface of first separation layer;It is filled out in the source electrode material Fill deposition of electrode material in hole and the multiple grid material filling hole.
Codec type vertical gate 3D NAND forming method according to an embodiment of the present invention has and preferably erects than BICS structure For histogram to potentiality are expanded, influence of the increase of the number of plies for the performance of single storage tube is small compared to the three-dimensional storage of vertical-channel Much, and it is also easier in technique, reduce the step of zanjon etches this complicated and time consumption, entire technique and current work Skill technology is completely compatible.
In addition, codec type vertical gate 3D NAND forming method according to the above embodiment of the present invention, can also have as follows Additional technical characteristic:
Further, the substrate has patterned surface.
Further, the substrate is Si, SiGe, SiC, GaAs, Ge, GaN, GaP, InP, Ga2O3、Al2O3、AlN、 ZnO、LiGaO2、LiAlO2One of.
Further, further comprising the steps of: heavy doping is carried out to the specified region of one or more layers semiconductor layer.
To achieve the goals above, embodiment of the invention discloses a kind of codec type vertical gate 3D NAND, comprising: lining Bottom;It is formed in the first separation layer of the substrate;It is formed in one or more layers semiconductor layer on first separation layer, Wherein, multiple grooves are provided in one or more layers described semiconductor layer, the multiple groove extends to first separation layer Top surface, multiple holes are etched on one or more layers described semiconductor layer, the multiple hole extends to first isolation The top surface of layer;The silica tunnel layer being formed on the multiple groove;It is formed in the silica tunnel layer On silicon dioxide blocking layer;Multiple gate structures, the multiple gate structure are separately positioned in the multiple groove, are horizontal In multiple holes on top and one or more layers described semiconductor layer across the multiple groove;Polysilicon layer, the polysilicon Layer across the multiple groove top and be formed on silicon dioxide blocking layer, source is set on the polysilicon layer.
Codec type vertical gate 3D NAND according to an embodiment of the present invention, codec type vertical gate 3D NAND are to be totally different from There is three bit memories of the vertical gate structure of BiCS structure better vertical direction to expand potentiality, and the increase of the number of plies is for list The influence of the performance of a storage tube is much smaller compared to the three-dimensional storage of vertical-channel, and this structure is also simpler in technique Just, reduce the step of zanjon etches this complicated and time consumption, entire technique and current technology are completely compatible.
In addition, codec type vertical gate 3D NAND according to the above embodiment of the present invention, can also have following additional skill Art feature:
Further, the substrate has patterned surface.
Further, the substrate is Si, SiGe, SiC, GaAs, Ge, GaN, GaP, InP, Ga2O3、Al2O3、AlN、 ZnO、LiGaO2、LiAlO2One of.
Further, heavily doped region is provided on one or more layers described semiconductor layer.
Additional aspect and advantage of the invention will be set forth in part in the description, and will partially become from the following description Obviously, or practice through the invention is recognized.
Detailed description of the invention
Above-mentioned and/or additional aspect of the invention and advantage will become from the description of the embodiment in conjunction with the following figures Obviously and it is readily appreciated that, in which:
Fig. 1-8 is the forming process schematic diagram of the codec type vertical gate 3D NAND forming method of one embodiment of the invention;
Fig. 9 is the structural schematic diagram of the codec type vertical gate 3D NAND of one embodiment of the invention.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, and for explaining only the invention, and is not considered as limiting the invention.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", "upper", "lower", The orientation or positional relationship of the instructions such as "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is It is based on the orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than instruction or dark Show that signified device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as pair Limitation of the invention.In addition, term " first ", " second " are used for description purposes only, it is not understood to indicate or imply opposite Importance.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can To be mechanical connection, it is also possible to be electrically connected;It can be directly connected, can also can be indirectly connected through an intermediary Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood at this with concrete condition Concrete meaning in invention.
Referring to following description and drawings, it will be clear that these and other aspects of the embodiment of the present invention.In these descriptions In attached drawing, some particular implementations in the embodiment of the present invention are specifically disclosed, to indicate to implement implementation of the invention Some modes of the principle of example, but it is to be understood that the scope of embodiments of the invention is not limited.On the contrary, of the invention Embodiment includes all changes, modification and the equivalent fallen within the scope of the spirit and intension of attached claims.
Codec type vertical gate 3D NAND forming method according to an embodiment of the present invention is described below in conjunction with attached drawing.
Fig. 1-7 is the forming process schematic diagram of the codec type vertical gate 3D NAND forming method of one embodiment of the invention. Please refer to Fig. 1-7, a kind of codec type vertical gate 3D NAND forming method the following steps are included:
S1: as shown in Figure 1, providing substrate 100.Specifically, substrate 100 can be the substrate with patterned surface, such as Si with patterned structures or the Sapphire Substrate with patterned structures (PSS), this patterned structures advantageously reduce Dislocation density in epitaxial layer, be also beneficial to LED goes out light.Substrate 100 can be Si, SiGe, SiC, Al2O3、AlN、ZnO、 Ga2O3、LiGaO2Or LiAlO2One of.Preferably, substrate 100 is Si, and Si substrate is cheap and easy to get, is easy to adulterate, while easily Heterogeneous separation layer is generated in reacting.
S2: as shown in Fig. 2, forming the first separation layer 200 on substrate 100.Specifically, the first separation layer 200 is two Silica material, effect are to realize the electric isolation of one layer of conductive layer on silicon substrate and the first separation layer 200.
S3: as shown in figure 3, forming one or more layers semiconductor layer on the first separation layer 200.At of the invention one In example, four-level semiconductor layer 301/302/303/304 and four layers of separation layer 401/402/403/ are formed on the first separation layer 404。
Optionally, heavy doping is carried out in the specified region of four-level semiconductor layer 301/302/303/304, heavily doped region is For making the substrate of depletion type MOS tube, without heavy doping, then the metal-oxide-semiconductor formed is enhanced metal-oxide-semiconductor.
S4: as shown in figure 4, etching one or more layers semiconductor layer to form multiple grooves, multiple grooves extend to first The top surface of separation layer 200.
S5: silica tunnel layer is formed to the deposit silica of multiple grooves.Specifically, silica conduct is deposited The gate medium of metal-oxide-semiconductor, in the region for forming storage tube, appropriate etching is that silica is thinning, the dioxy as SONOS storage tube SiClx tunnel layer;Or in the region suitable control thickness for forming storage tube, the dioxy of formation when depositing silica SiClx is than the relatively thin silica tunnel layer as SONOS storage tube.
S6: deposit silicon nitride electric charge capture layer and silicon dioxide blocking layer on silica tunnel layer form charge Capture composite layer.
S7: as shown in figure 5, being formed in multiple grooves and on the silicon dioxide blocking layer at the top of multiple grooves Gate structure 501/502.
S8: make as shown in fig. 6, forming polysilicon layer 600 on the silicon dioxide blocking layer at the top of multiple grooves For source line, or when four-level semiconductor layer 301/302/303/304 retain partial region as depositing polysilicon conduct Source line.
S9: as shown in fig. 7, etching multiple grid materials to gate structure 501/502 fills hole 5011/5021, multiple grid Pole material filling hole 5011/5021 extends to the top surface of the first separation layer 200.To 600 etching source material of polysilicon layer Hole 601 is filled, source electrode material filling hole hole 601 extends to the top surface of the first separation layer 200.To four-level semiconductor layer 301/ 302/303/304 and four layers of separation layer 401/402/403/404 also etch deep hole 4041, increase space efficiency utilization.
S10: it is deposited as shown in figure 8, being filled in hole 5011/5021 and multiple grid materials filling hole 601 in source electrode material Electrode material 5012/5022/602 is completed to be electrically connected.
The codec type vertical gate 3D NAND forming method of the embodiment of the present invention has vertical side preferably than BICS structure To potentiality are expanded, influence of the increase of the number of plies for the performance of single storage tube is small compared to the three-dimensional storage of vertical-channel to be obtained It is more and also easier in technique, reduce the step of zanjon etches this complicated and time consumption, entire technique and current technique The completely compatible effect of technology.
Below with reference to Detailed description of the invention codec type vertical gate 3D NAND of the invention.
Referring to FIG. 9, a kind of codec type vertical gate 3D NAND, comprising: substrate 100, be formed on substrate 100 One separation layer 200 and it is formed in one or more layers semiconductor layer 301/302/303/304 on the first separation layer 200.Wherein, one Multiple grooves are provided in layer or multi-lager semiconductor layer 301/302/303/304, multiple grooves extend to the top of the first separation layer Portion surface.Be etched with multiple holes 401 on one or more layers semiconductor layer 301/302/303/304, multiple holes extend to first every The top surface of absciss layer 200.Codec type vertical gate 3D NAND further includes the silica tunnelling being formed on multiple grooves Layer, the silicon dioxide blocking layer and multiple gate structures 4042/5012/5022, polycrystalline being formed on silica tunnel layer Silicon layer 600.Wherein, multiple gate structures 4042/5012/5022 are separately positioned in multiple grooves, across the top of multiple grooves In multiple holes 4041 in portion and one or more layers semiconductor layer.Polysilicon layer 600 across multiple grooves top and be formed in On silicon dioxide blocking layer.Source 6012 is set on polysilicon layer 600.
In one embodiment of the invention, substrate 100 has the substrate of patterned surface.
In one embodiment of the invention, substrate Si, SiGe, SiC, GaAs, Ge, GaN, GaP, InP, Ga2O3、 Al2O3、AlN、ZnO、LiGaO2、LiAlO2One of.Preferably silicon substrate.
In one embodiment of the invention, it is provided on one or more layers semiconductor layer 301/302/303/304 heavily doped Miscellaneous region.
In order to clearly illustrate the beneficial effect of codec type vertical gate 3D NAND of the invention, will be carried out by below table Explanation.
Grid voltage 0 0 0 0 State
First layer ON OFF ON OFF off
The second layer OFF ON ON OFF off
Third layer ON OFF OFF ON off
4th layer OFF ON OFF ON off
The conducting situation of each layer under voltage status is not added in the grid that table 1 represents selection layer
Grid voltage 0 1 0 1 State
First layer ON ON ON ON on
The second layer OFF ON ON ON off
Third layer ON ON OFF ON off
4th layer OFF ON OFF ON off
Table 2 indicates that first layer is connected under this pressurized conditions
Grid voltage 1 0 0 1 State
First layer ON OFF ON ON off
The second layer ON ON ON ON on
Third layer ON OFF OFF ON off
4th layer ON ON OFF ON off
Table 3 indicates that the second layer is connected under this pressurized conditions
Grid voltage 0 1 1 0 State
First layer ON ON ON OFF off
The second layer OFF ON ON OFF off
Third layer ON ON ON ON on
4th layer OFF ON ON ON off
Table 4 indicates that third layer is connected under this pressurized conditions
Grid voltage 1 0 1 0 State
First layer ON OFF ON OFF off
The second layer ON ON ON OFF off
Third layer ON OFF ON ON off
4th layer ON ON ON ON on
Table 5 indicates the 4th layer of conducting under this pressurized conditions
By upper table 1-5 it is found that selecting the voltage of tube grid by control decoding, the selection to a certain layer is realized.Position end Selecting pipe is the 3D NAND string in order to distinguish inner side and outer side.When the number of plies changes, appropriate adjustment also can guarantee completion pair The selection of a certain layer.
In addition, the other compositions and effect of codec type vertical gate 3D NAND of the embodiment of the present invention and forming method thereof All be for a person skilled in the art it is known, in order to reduce redundancy, do not repeat them here.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any One or more embodiment or examples in can be combined in any suitable manner.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: not A variety of change, modification, replacement and modification can be carried out to these embodiments in the case where being detached from the principle of the present invention and objective, this The range of invention is by claim and its equivalent limits.

Claims (8)

1. a kind of codec type vertical gate 3D NAND forming method, which comprises the following steps:
Substrate is provided;
The first separation layer is formed in the substrate;
One or more layers semiconductor layer is formed on first separation layer;
One or more layers described semiconductor layer is etched to form multiple grooves, the multiple groove extends to first separation layer Top surface;
Silica tunnel layer is formed to the deposit silica of the multiple groove;
Deposit silicon nitride electric charge capture layer and silicon dioxide blocking layer on the silica tunnel layer;
Grid is formed in the multiple groove and on the silicon dioxide blocking layer at the top of the multiple groove Structure;
Polysilicon layer is formed on the silicon dioxide blocking layer at the top of the multiple groove;
Multiple grid materials are etched to the gate structure and fill hole, the multiple grid material filling hole extends to described first The top surface of separation layer fills hole to the polysilicon layer etching source material, and source electrode material filling hole extends to institute State the top surface of the first separation layer;
Deposition of electrode material in hole and the multiple grid material filling hole is filled in the source electrode material.
2. codec type vertical gate 3D NAND forming method according to claim 1, which is characterized in that the substrate has Patterned surface.
3. codec type vertical gate 3D NAND forming method according to claim 1, which is characterized in that the substrate be Si, SiGe、SiC、GaAs、Ge、GaN、GaP、InP、Ga2O3、Al2O3、AlN、ZnO、LiGaO2、LiAlO2One of.
4. codec type vertical gate 3D NAND forming method according to claim 1, which is characterized in that further include following step It is rapid:
Heavy doping is carried out to the specified region of one or more layers semiconductor layer.
5. a kind of codec type vertical gate 3D NAND characterized by comprising
Substrate;
It is formed in the first separation layer of the substrate;
It is formed in one or more layers semiconductor layer on first separation layer, wherein in one or more layers described semiconductor layer Multiple grooves are provided with, the multiple groove extends to the top surface of first separation layer, and described one or more layers is partly led Multiple holes are etched on body layer, the multiple hole extends to the top surface of first separation layer;
The silica tunnel layer being formed on the multiple groove;
The silicon dioxide blocking layer being formed on the silica tunnel layer;
Multiple gate structures, the multiple gate structure are separately positioned in the multiple groove, across the multiple groove In multiple holes on top and one or more layers described semiconductor layer;
Polysilicon layer, the polysilicon layer across the multiple groove top and be formed on silicon dioxide blocking layer, institute It states and source is set on polysilicon layer.
6. codec type vertical gate 3D NAND according to claim 5, which is characterized in that the substrate has graphical table Face.
7. codec type vertical gate 3D NAND according to claim 5, which is characterized in that the substrate be Si, SiGe, SiC、GaAs、Ge、GaN、GaP、InP、Ga2O3、Al2O3、AlN、ZnO、LiGaO2、LiAlO2One of.
8. codec type vertical gate 3D NAND according to claim 5, which is characterized in that one or more layers described semiconductor Heavily doped region is provided on layer.
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CN106024700B (en) * 2016-07-04 2019-04-30 武汉新芯集成电路制造有限公司 Improve the method for three dimensional NAND channel filling

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN103226973A (en) * 2012-01-30 2013-07-31 群联电子股份有限公司 NAND flash memory unit, NAND flash memory array, and methods for operating them
CN104392997A (en) * 2014-11-12 2015-03-04 清华大学 Step type vertical gate NAND and forming method thereof
US9024374B2 (en) * 2010-07-06 2015-05-05 Macronix International Co., Ltd. 3D memory array with improved SSL and BL contact layout

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
US9024374B2 (en) * 2010-07-06 2015-05-05 Macronix International Co., Ltd. 3D memory array with improved SSL and BL contact layout
CN103226973A (en) * 2012-01-30 2013-07-31 群联电子股份有限公司 NAND flash memory unit, NAND flash memory array, and methods for operating them
CN104392997A (en) * 2014-11-12 2015-03-04 清华大学 Step type vertical gate NAND and forming method thereof

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