Summary of the invention
Main purpose of the present invention is to overcome the deficiencies in the prior art, a kind of carbon fiber metal composite electron product airframe structure and preparation method thereof is provided, the weight solving existing aluminium alloy fuselage is comparatively large but hardness is not high, and fuselage anti-pressure ability is poor, is easy to problems such as being bent.
For achieving the above object, the present invention is by the following technical solutions:
A kind of carbon fiber metal composite electron product airframe structure, comprise aluminum alloy frame and to be arranged in inside described aluminum alloy frame, with the carbon fiber deckle board of described aluminum alloy frame one volume recombination, described aluminum alloy frame has the microvoid structure formed through surface corrosion process, in described carbon fiber, deckle board combines with the surface with described microvoid structure of described aluminum alloy frame, is molded as one through hot-press solidifying.
Further:
The aperture of described micropore is 20 ~ 100 nanometers, and described micropore is evenly distributed on aluminum alloy frame surface.
In described carbon fiber, deckle board is the carbon fiber structural formed through 3D plastotype and hot-press solidifying process by the carbon cloth of staggered laying inside described aluminum alloy frame.
A making method for carbon fiber metal composite electron product airframe structure, comprises the following steps:
S1, preparation aluminum alloy frame;
S2, surface corrosion process is carried out to described aluminum alloy frame thus forms microvoid structure on the surface of described aluminum alloy frame;
S3, carbon cloth is placed on inside described aluminum alloy frame, 3D plastotype and hot-press solidifying process are carried out to described carbon cloth, form deckle board in the carbon fiber be combined as a whole with described aluminum alloy frame after process, wherein said aluminum alloy frame is hardened by the surface and described carbon fiber center with described microvoid structure and closes.
Further:
In step S2, described surface corrosion process comprises galvanic corrosion process.
The phosphoric acid mixed solution of the hydrochloric acid of described galvanic corrosion process employing 0.5 ~ 2mol/L, the sulfuric acid of 0.5 ~ 1.0mol/L, 0.5 ~ 1.0mol/L is as electrolytic solution.
Step S2 comprises: described aluminum alloy frame is put into the sodium hydroxide solution that mass concentration is 2% ~ 10%, heating in water bath 2 ~ 5 minutes, after cleaning, put into 1% ~ 10% salpeter solution, soak 3 ~ 10 minutes, again after cleaning, put in electrolyzer, the hydrochloric acid into 0.5 ~ 2mol/L is contained in groove, the sulfuric acid of 0.5 ~ 1.0mol/L, the phosphoric acid mixed solution of 0.5 ~ 1.0mol/L is as electrolytic solution, and add appropriate inhibiter, using described aluminum alloy frame as anode, in electrolyzer, graphite is as negative electrode, DC electrolysis 20 ~ 40s, current density controls at 0.10 ~ 0.30A/cm
2, tank liquor temperature controls at 30 ~ 50 DEG C, immerse acetone solution 5 ~ 10s after processing, afterwash and dry.
Step S3 comprises: carbon fibre initial rinse fabric is cut into predetermined size, then by the carbon cloth laying that cuts inside described aluminum alloy frame, for deckle board in the described carbon fiber of formation.
Step S3 also comprises: the carbon cloth that laying is good and described aluminum alloy frame put into 3D plastotype mould, and then plastotype 30 ~ 60s is transformed in heat pressing forming machines and carries out hot-press solidifying, solidification value is 135 ~ 150 DEG C, pressure 40 ~ 60kg, solidification 10 ~ 15min, then cools.
Also comprise after step S3: molding structure is carried out to the epoxy resin overflowed after carbon fibre initial rinse molding with cloth is removed in polishing.
Beneficial effect of the present invention:
The present invention adopts the airframe structure of deckle board composite molding in aluminum alloy frame and carbon fiber, solve existing aluminium alloy center hardness not high, the problems such as anti-pressure ability is poor and be easily bent, also reduce the weight of aluminium alloy fuselage, and can not destroy the metal-like of mobile phone complete machine.Be integrated to make aluminum alloy frame and carbon fiber center sheet metal forming, in the present invention, aluminum alloy frame has the microvoid structure formed through surface corrosion process, aluminum alloy frame has deckle board in the surface of microvoid structure and carbon fiber by it and forms bonding interface, be molded as one through hot-press solidifying, microvoid structure on aluminum alloy frame effectively strengthens the bonding force between both interfaces, improves the adhesion strength that carbon fiber is combined with aluminium alloy.Carbon-fibre composite quality is light, intensity large, and weight is only equivalent to 20% to 30% of steel, and hardness is but more than 10 times of steel.Carbon fiber metal composite airframe structural provided by the invention takes full advantage of carbon-fibre composite lightweight, high-strength, Gao Mo, resistance to chemical attack, the characteristics such as thermal expansivity is little, relative to existing aluminium alloy center, the invention enables whole fuselage middle frame structure intensity to strengthen 1/3, quality can reduce 1/3.
Embodiment
Below embodiments of the present invention are elaborated.It is emphasized that following explanation is only exemplary, instead of in order to limit the scope of the invention and apply.
Consult Fig. 1 and Fig. 2, in one embodiment, a kind of carbon fiber metal composite electron product airframe structure, comprise aluminum alloy frame 1 and to be arranged in inside described aluminum alloy frame 1, with the carbon fiber deckle board 2 of described aluminum alloy frame 1 one volume recombination, described aluminum alloy frame 1 has the microvoid structure (not shown) formed through surface corrosion process, in described carbon fiber, deckle board 2 combines with the surface with described microvoid structure of described aluminum alloy frame 1, is molded as one through hot-press solidifying.
In a preferred embodiment, the aperture of the micropore on aluminum alloy frame 1 is 20 ~ 100 nanometers, and described micropore is evenly distributed on the surface of aluminum alloy frame 1.
In a preferred embodiment, in described carbon fiber, deckle board 2 is the carbon fiber structurals formed through 3D plastotype and hot-press solidifying process by the carbon cloth of staggered laying inside described aluminum alloy frame 1.
In a kind of preferred embodiment, in carbon fiber, the thickness of deckle board 2 is 0.5mm.
Consult Fig. 1 and Fig. 2, in one embodiment, a kind of making method of carbon fiber metal composite electron product airframe structure, comprises the following steps:
S1, preparation aluminum alloy frame 1;
S2, surface corrosion process is carried out to described aluminum alloy frame 1 thus forms microvoid structure on the surface of described aluminum alloy frame 1;
S3, carbon cloth is placed on inside described aluminum alloy frame 1,3D plastotype and hot-press solidifying process are carried out to described carbon cloth, form deckle board 2 in the carbon fiber be combined as a whole with described aluminum alloy frame 1 after process, wherein said aluminum alloy frame 1 is combined by surface deckle board 2 in described carbon fiber with described microvoid structure.
In a preferred embodiment, in step S2, described surface corrosion process comprises galvanic corrosion process.In a more preferred embodiment, described galvanic corrosion process adopts the phosphoric acid mixed solution of the sulfuric acid of the hydrochloric acid of 0.5 ~ 2mol/L, 0.5 ~ 1.0mol/L, 0.5 ~ 1.0mol/L as electrolytic solution.
In a more preferred embodiment, step S2 comprises: described aluminum alloy frame 1 is put into the sodium hydroxide solution that mass concentration is 2% ~ 10%, heating in water bath 2 ~ 5 minutes, after cleaning, put into 1% ~ 10% salpeter solution, soak 3 ~ 10 minutes, again after cleaning, put in electrolyzer, the hydrochloric acid into 0.5 ~ 2mol/L is contained in groove, the sulfuric acid of 0.5 ~ 1.0mol/L, the phosphoric acid mixed solution of 0.5 ~ 1.0mol/L is as electrolytic solution, and add appropriate inhibiter, using described aluminum alloy frame 1 as anode, in electrolyzer, graphite is as negative electrode, DC electrolysis 20 ~ 40s, current density controls at 0.10 ~ 0.30A/cm
2, tank liquor temperature controls at 30 ~ 50 DEG C, immerse acetone solution 5 ~ 10s after processing, afterwash and dry.
In a preferred embodiment, step S3 comprises: carbon fibre initial rinse fabric is cut into predetermined size, then by the carbon cloth laying that cuts inside described aluminum alloy frame 1, for deckle board 2 in the described carbon fiber of formation.
In a preferred embodiment, step S3 also comprises: the carbon cloth that laying is good and described aluminum alloy frame 1 put into 3D plastotype mould, plastotype 30 ~ 60s, then be transformed in heat pressing forming machines and carry out hot-press solidifying, solidification value is 135 ~ 150 DEG C, pressure 40 ~ 60kg, solidification 10 ~ 15min, then cool, obtain aluminum alloy frame 1 and the integrated composite structure of deckle board 2 in carbon fiber.
In a preferred embodiment, also comprise after step S3: molding structure is carried out to the epoxy resin overflowed after carbon fibre initial rinse molding with cloth is removed in polishing.
In a particular embodiment, time prepared by aluminum alloy frame 1, first by the aluminium sheet of extruded aluminium stockline cutting fixed measure, CNC machine milling inner cavities can be re-used, then through precision work process, obtains aluminum alloy frame product.When aluminum alloy frame 1 carries out micropore process, aluminum alloy frame 1 product first can be placed in scavenging solution to process, chemical surface treatment is carried out again in acid solution and alkali lye, then be placed in chemical corrosion liquid and carry out micropore process, thus obtain the aluminum alloy frame 1 with certain microvoid structure, the aperture of micropore is 20 ~ 100 nanometers, is evenly distributed on aluminum alloy frame 1 surface.Deckle board 2 one compound tense in aluminum alloy frame 1 with carbon fiber, the aluminum alloy frame 1 with microvoid structure can be placed in 3D plastotype mould, ready carbon cloth is interlocked in the middle of laying and aluminum alloy frame, then 3D plastotype is carried out, then putting into hot-press solidifying again, to carry out hot-press solidifying shaping, after taking-up, carry out corresponding surface treatment and namely obtain aluminium alloy carbon fiber compound center product.
Aluminum alloy frame 1 and carbon fiber are combined into an overall center, carbon-fibre composite is utilized to have light and strong, light and firm, corrosion-resistant, antifatigue, scantlings of the structure good stability, the hardness of center can not only be increased, improve the anti-pressure ability of middle frame structure, also reduce the weight of center, and overall performance and the metal-like effect of center can not be affected, its quality compares all aluminium alloy center can alleviate 10%, intensity can increase by 30%, anti-pressure ability can increase by 20%, and the crushing resistance of middle deckle board 2 can play self-regeneration effect for nondestructive pressure.
Example
The preparation of aluminum alloy frame
Aluminum or aluminum alloy aluminium extruded is fixed on fixture, cuts out the aluminium alloy plate of 160mm*80mm*10mm with Linear cut, then this aluminium alloy plate is loaded in CNC board and rough mill inner chamber and locating dowel, then fix frame with fixture, precision work inner-cavity structure.Taking-up greasy dirt cleaning machine cleaning aluminum alloy frame after processing, wipe oil, then clean by washed with de-ionized water, dry in an oven.
The process of aluminum alloy frame micropore
First above-mentioned aluminum alloy frame is put into 2% ~ 10% sodium hydroxide solution, 40 DEG C of heating in water bath are in 2 ~ 5 minutes, then clean by washed with de-ionized water; Then will put into 1% ~ 10% salpeter solution, soak 3 ~ 10 minutes, same washed with de-ionized water after having soaked; Then frame is put in electrolyzer, phosphoric acid mixed solution into the sulfuric acid of the hydrochloric acid of 0.5 ~ 2mol/L, 0.5 ~ 1.0mol/L, 0.5 ~ 1.0mol/L is contained as electrolytic solution in groove, and add certain inhibiter, using frame as anode, in electrolyzer, graphite is as negative electrode, DC electrolysis 20 ~ 40s, current density controls at 0.10 ~ 0.30A/cm
2, tank liquor temperature controls at 40 DEG C; Then take out and immerse acetone 5 ~ 10s, then clean with deionized water and dry.
Aluminum alloy frame and carbon fibre integrated compound
The frame of micropore process is encased in 3D plastotype mould, location is fixing, then by carbon fibre initial rinse fabric cut into 140mm*80mm, again by the carbon cloth that cuts according to demand laying in scuncheon, and put into 3D plastotype mould and carry out inner-cavity structure plastotype, plastotype 30 ~ 60s, then hot-press solidifying in heat pressing forming machines is transformed into, solidification value is 135 ~ 150 DEG C, pressure 40 ~ 60kg, solidification 10 ~ 15min, cooling die is to room temperature, the product taken out inside mould just obtains integral product, and then carry out the epoxy resin that shaping spilling is removed in the meticulous polishing of inner frame structure, aluminum alloy frame and carbon fibre integrated composite rim can be obtained.
Through actual measurement, the carbon fiber metal composite airframe structural weight obtained by above-mentioned example is 63g, compared with specification of the same race but the overall airframe structure weight (70g) of aluminium alloy center that adopts approximately alleviates 7g, wherein in carbon fiber, the ultimate compression strength (6.5MP power) of the compressive strength rate aluminium alloy center of deckle board increases 2MP.
Above content combines concrete/preferred embodiment further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention; without departing from the inventive concept of the premise; its embodiment that can also describe these makes some substituting or modification, and these substitute or variant all should be considered as belonging to protection scope of the present invention.