CN105524573A - Label adhesive - Google Patents
Label adhesive Download PDFInfo
- Publication number
- CN105524573A CN105524573A CN201410511307.8A CN201410511307A CN105524573A CN 105524573 A CN105524573 A CN 105524573A CN 201410511307 A CN201410511307 A CN 201410511307A CN 105524573 A CN105524573 A CN 105524573A
- Authority
- CN
- China
- Prior art keywords
- trademark adhesive
- vinyl alcohol
- alcohol system
- system polymer
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a label adhesive. The label adhesive is characterized by comprising a carboxyl-contained vinyl alcohol polymer and being prepared through copolymerization and alcoholysis of a vinyl ester monomer and a carboxyl-contained unsaturated monomer, wherein the adhesive has a saponification degree of more than 75% mol, a polymerization degree of 100 to 4000 and a carboxyl content of 0.1 to 20% mol. The label adhesive provided by the invention has the advantages of good water resistance, high initial adhesion capacity, fast curing speed, good fluidity, easy label removal and good storage stability.
Description
Technical field
The present invention relates to trademark adhesive, particularly relate to the trademark adhesive be attached on vial.
Background technology
Along with beverage, brewing industry develop rapidly in recent years, the production rate of beverage, beer production line has brought up to 4 ~ 60,000 bottles/hour, this just requires trademark adhesive to possess, and solid content is high, initial bonding strength is large, bonding strength is high, the performance of good fluidity, to adapt to the requirement of high speed machine adhesive label.Because living standards of the people improve constantly, consumer taste also improves thereupon, people are to the beverage of glass bottle, fruit syrup, soft drink and beer carries out " icing " as often all will being placed in frozen water, make it more refrigerant good to eat, thus also need trademark adhesive to have good water tolerance, a couple of days can be kept in water not fall mark.In addition, conveniently packing bottle is recycled, and also requires de-mark easily.
Generally use casein, amylan and conventional PVA glue both at home and abroad at present.It is large that casein has initial bonding strength, and bonding force is strong, the features such as water resistance is good, but owing to involving great expense, is difficult to apply.Amylan because paste degree is large, fast drying, cheap, although also can be used for mechanical labeling, after glued membrane drying, fragility falls mark, poor water resistance greatly, easily.Normally used conventional PVA glue tack is poor, and leakage subsides rate is high, poor water resistance.
Summary of the invention
The object of the present invention is to provide that a kind of low production cost, tack are large, water-tolerant, de-mark are easy to trademark adhesive product.
The object of the invention is to be realized by following measures:
A kind of trademark adhesive, is characterized in that: comprise carboxylic vinyl alcohol system polymer.Described carboxylic vinyl alcohol system polymer is obtained through alcoholysis with containing after the unsaturated monomer copolymerization of carboxyl by vinyl acetate monomer (as vinyl acetate between to for plastic etc.), preferably, saponification deg is more than 75%mol, and the polymerization degree is the scope of 100 ~ 4000, and carboxyl-content is 0.1 ~ 20%mol.The described unsaturated monomer containing carboxyl is preferably toxilic acid (acid anhydride) monomer, methylene-succinic acid monomer or Acrylic Acid Monomer, reduces product cost simultaneously, and product environmental protection.
Above-mentioned trademark adhesive also comprises water, and carboxylic vinyl alcohol system polymer and water weight ratio are 1/99 ~ 30/70.In order to improve the stability of product further, above-mentioned trademark adhesive also comprises linking agent, linking agent: carboxylic vinyl alcohol system polymer=1/99 ~ 60/40, with mass ratio range.Described linking agent is one or more in polyamide polyamine epichlorhydrin resin or Polyamide Polyamine Epichlorohydrin Resin, polyacrylamide, alkyl diamine and derivative (as quadrol, octamethylenediamine, 1,6-hexane diamine etc.) thereof, copper sulfate, cupric chloride, lime acetate, zirconium carbonate ammonium, zirconium acetate, zirconium tetrachloride, venus crystals, zinc acetate, zinc sulfate, zinc chloride, Tai-Ace S 150.
In order to improve film-forming properties, the snappiness of glue, above-mentioned trademark adhesive also comprises dispersion agent, described dispersion agent is one or more in urea, polyacrylamide, Dyhard RU 100, thiocyanate-, and dispersion agent and carboxylic vinyl alcohol system polymer weight ratio are 0/10 ~ 20/10.
The pH value of above-mentioned trademark adhesive is adjusted to 7 ~ 10.
Above-mentioned trademark adhesive, can also add viscosity stabilizer, vinyl alcohol system polymer, defoamer, sanitas, softening agent, pH value regulator, rheology control agent etc.Each component can be added by random order.
The trademark adhesive that the present invention makes for the stickup of vial label, preferably for the stickup of beer bottle label.
beneficial effect
1. trademark adhesive water-tolerant of the present invention, initial bonding strength is large, and curing speed is fast, good fluidity, and de-mark is easy, excellent storage stability.
2. the present invention select low in raw material price, be easy to get, environmental protection, preparation technology is simple to operation, is applicable to suitability for industrialized production.
Embodiment
Below by embodiment, the present invention is specifically described; what be necessary to herein means out is; the present embodiment is only used to further illustrate the present invention; can not be interpreted as limiting the scope of the invention, the person skilled in the art in this field can make some nonessential improvement and adjustment according to the content of foregoing invention to the present invention.In the following example, unless otherwise, all % and number are all in units of weight.
embodiment 1
Formula: linking agent Polyamide Polyamine Epichlorohydrin Resin solution (solid content 12.5%) 12 parts, the carboxylic vinyl alcohol system polymer 25 parts that the polymerization degree 1700, saponification deg are 97%mol, carboxyl-content is 1.2%mol, 25 parts, urea, 150 parts, water.
Process for preparation: carboxylic vinyl alcohol system polymer water is heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, urea is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 8.5, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
embodiment 2
Formula: linking agent polyamide polyamine epichlorhydrin resin solution (solid content 12.5%) 10 parts, the carboxylic vinyl alcohol system polymer 20 parts that the polymerization degree 1700, saponification deg are 95%mol, carboxyl-content is 1.5%mol, the vinyl alcohol system polymer of the polymerization degree 2000, saponification deg 88%mol 15 parts, 12 parts, urea, 200 parts, water.
Process for preparation: vinyl alcohol system polymer water is heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, urea is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 8.5, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
embodiment 3
Formula: linking agent is Polyamide Polyamine Epichlorohydrin Resin solution (solid content 12.5%) 4 parts and zirconium acetate solution (solid content 20%) 2 parts, the carboxylic vinyl alcohol system polymer of the polymerization degree 1500, saponification deg 92%mol, carboxyl-content 2.0%mol 25 parts, Sodium Thiocyanate 99 5 parts, 240 parts, water.
Process for preparation: carboxylic vinyl alcohol system polymer water is heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, Sodium Thiocyanate 99 is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 8, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
embodiment 4
Formula: linking agent zirconium carbonate ammonium solution (solid content 20%) 3 parts, the carboxylic vinyl alcohol system polymer of the polymerization degree 2000, saponification deg 88%mol, carboxyl-content 2.0%mol 5 parts, the vinyl alcohol system polymer of the polymerization degree 2400, saponification deg 88%mol 20 parts, 25 parts, urea, 185 parts, water.
Process for preparation: carboxylic vinyl alcohol system polymer and vinyl alcohol system polymer water are heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, urea is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 8.5, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
embodiment 5
Formula: linking agent alkyl diamine solution (solid content 12.5%) 7 parts, the carboxylic vinyl alcohol system polymer of the polymerization degree 1700, saponification deg 98%mol, carboxyl-content 1.6%mol 7 parts, the vinyl alcohol system polymer of the polymerization degree 2600, saponification deg 88%mol 18 parts, 20 parts, urea, 200 parts, water.
Process for preparation: carboxylic vinyl alcohol system polymer and vinyl alcohol system polymer water are heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, urea is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 8.5, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
embodiment 6
Formula: linking agent polyacrylamide solution (solid content 12.5%) 5 parts, copper acetate solution (solid content 20%) 1 part, liquor zinci chloridi (solid content 20%) 1 part, the carboxylic vinyl alcohol system polymer of the polymerization degree 1700, saponification deg 96%mol, carboxyl-content 1.0%mol 12.5 parts, the vinyl alcohol system polymer of the polymerization degree 2000, saponification deg 88%mol 12.5 parts, 15 parts, urea, 240 parts, water.
Process for preparation: vinyl alcohol system polymer water is heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, urea is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 8, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
embodiment 7
Formula: linking agent calcium acetate solution (solid content 20%) 2 parts, ethylenediamine solution (solid content 20%) 2 parts, zirconium acetate (solid content 20%) 2 parts, 2 parts, Tai-Ace S 150 (solid content 20%), the carboxylic vinyl alcohol system polymer of the polymerization degree 1700, saponification deg 97%mol, carboxyl-content 1.2%mol 16 parts, the vinyl alcohol system polymer of the polymerization degree 2400, saponification deg 88%mol 9 parts, 12 parts, urea, 220 parts, water.
Process for preparation: vinyl alcohol system polymer water is heated to about 90 DEG C dissolvings, make water-soluble polymers, be cooled to less than 60 DEG C, urea is dissolved in macromolecular solution, then linking agent is added in macromolecular solution and stir, make that pH value is 9, the trademark adhesive of about viscosity 40000mPas.
The trademark adhesive good stability made, stores three moonsets and occurs phenomenon of phase separation.Curing speed is fast, can meet the labeling speed of 40000 bottles/more than h.For the Beer Bottle of sticking glass material or the label of beverage bottle, after the label of stickup soaks 5 days in frozen water, still remain intact.2%NaOH aqueous solution soaking is used at 80 DEG C, can wash-out label in 15 minutes.
Claims (12)
1. a trademark adhesive, is characterized in that: comprise carboxylic vinyl alcohol system polymer.
2. trademark adhesive as claimed in claim 1, described carboxylic vinyl alcohol system polymer is obtained through alcoholysis with containing after the unsaturated monomer copolymerization of carboxyl by vinyl acetate monomer.
3. trademark adhesive as claimed in claim 1 or 2, the saponification deg of described carboxylic vinyl alcohol system polymer is more than 75%mol, the polymerization degree is 100 ~ 4000, and carboxyl-content is 0.1 ~ 20%mol.
4. trademark adhesive as claimed in claim 2, the described unsaturated monomer containing carboxyl is toxilic acid (acid anhydride) monomer, methylene-succinic acid monomer or Acrylic Acid Monomer.
5. the trademark adhesive as described in claim 1,2 or 4, also comprises water, and carboxylic vinyl alcohol system polymer and water weight ratio are 1/99 ~ 30/70.
6. trademark adhesive as claimed in claim 5, also comprises linking agent, linking agent: carboxylic vinyl alcohol system polymer=1/99 ~ 60/40, with mass ratio range.
7. trademark adhesive as claimed in claim 6, described linking agent is one or more in polyamide polyamine epichlorhydrin resin or Polyamide Polyamine Epichlorohydrin Resin, polyacrylamide, alkyl diamine and derivative thereof, copper sulfate, cupric chloride, lime acetate, zirconium carbonate ammonium, zirconium acetate, zirconium tetrachloride, venus crystals, zinc acetate, zinc sulfate, zinc chloride, Tai-Ace S 150.
8. trademark adhesive as claimed in claim 5, also comprises dispersion agent, and described dispersion agent is one or more in urea, polyacrylamide, Dyhard RU 100, thiocyanate-, and dispersion agent and carboxylic vinyl alcohol system polymer weight ratio are 0/10 ~ 20/10.
9. trademark adhesive as claimed in claim 6, also comprises dispersion agent, and described dispersion agent is one or more in urea, polyacrylamide, Dyhard RU 100, thiocyanate-, and dispersion agent and carboxylic vinyl alcohol system polymer weight ratio are 0/10 ~ 20/10.
10. trademark adhesive as claimed in claim 8 or 9, the pH value of described trademark adhesive is 7 ~ 10.
11. as arbitrary in claim 1-10 as described in trademark adhesive be used for the stickup of vial label.
12. as arbitrary in claim 1-10 as described in trademark adhesive be used for the stickup of beer bottle label.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410511307.8A CN105524573B (en) | 2014-09-29 | 2014-09-29 | A kind of trademark adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410511307.8A CN105524573B (en) | 2014-09-29 | 2014-09-29 | A kind of trademark adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105524573A true CN105524573A (en) | 2016-04-27 |
| CN105524573B CN105524573B (en) | 2018-07-24 |
Family
ID=55767108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410511307.8A Active CN105524573B (en) | 2014-09-29 | 2014-09-29 | A kind of trademark adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105524573B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753064A (en) * | 2016-12-21 | 2017-05-31 | 李晓慧 | Modified water-tolerant polyvinyl alcohol trade mark adhesive and preparation method thereof |
| CN107118718A (en) * | 2017-04-21 | 2017-09-01 | 唐林元 | A kind of preparation method of water-fast quick dried environment protection beer label adhesive |
| CN110922915A (en) * | 2019-11-04 | 2020-03-27 | 河南中包科技有限公司 | Adhesive for label glue spraying device of beer labeling machine and preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000109628A (en) * | 1998-10-07 | 2000-04-18 | Kuraray Co Ltd | Composition and adhesive |
| CN1613946A (en) * | 2004-09-09 | 2005-05-11 | 陈平绪 | Waterproof environmental protective label glue |
| CN1869143A (en) * | 2006-06-30 | 2006-11-29 | 上海天之冠可再生能源有限公司 | High speed water resistant metal label glue and its preparation method |
| CN102731710A (en) * | 2011-04-07 | 2012-10-17 | 中国石油化工集团公司 | Carboxyl modified polyvinyl alcohol and method for preparing same |
| CN102757747A (en) * | 2012-08-06 | 2012-10-31 | 河南中医学院 | Aldehyde-free odorless environment-friendly and transparent polyvinyl alcohol (PVA) glue and preparation method thereof |
-
2014
- 2014-09-29 CN CN201410511307.8A patent/CN105524573B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000109628A (en) * | 1998-10-07 | 2000-04-18 | Kuraray Co Ltd | Composition and adhesive |
| CN1613946A (en) * | 2004-09-09 | 2005-05-11 | 陈平绪 | Waterproof environmental protective label glue |
| CN1869143A (en) * | 2006-06-30 | 2006-11-29 | 上海天之冠可再生能源有限公司 | High speed water resistant metal label glue and its preparation method |
| CN102731710A (en) * | 2011-04-07 | 2012-10-17 | 中国石油化工集团公司 | Carboxyl modified polyvinyl alcohol and method for preparing same |
| CN102757747A (en) * | 2012-08-06 | 2012-10-31 | 河南中医学院 | Aldehyde-free odorless environment-friendly and transparent polyvinyl alcohol (PVA) glue and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753064A (en) * | 2016-12-21 | 2017-05-31 | 李晓慧 | Modified water-tolerant polyvinyl alcohol trade mark adhesive and preparation method thereof |
| CN107118718A (en) * | 2017-04-21 | 2017-09-01 | 唐林元 | A kind of preparation method of water-fast quick dried environment protection beer label adhesive |
| CN110922915A (en) * | 2019-11-04 | 2020-03-27 | 河南中包科技有限公司 | Adhesive for label glue spraying device of beer labeling machine and preparation method |
| CN110922915B (en) * | 2019-11-04 | 2021-07-20 | 河南中包科技有限公司 | Adhesive for label glue spraying device of beer labeling machine and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105524573B (en) | 2018-07-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2009074006A1 (en) | An adhesive, preparation and use thereof | |
| CN105524573A (en) | Label adhesive | |
| CN105018005A (en) | Water-proofing soy protein trademark glue for liquor drink bottle trademark pasting and preparing method of water-proofing soy protein trademark glue | |
| CN104403089A (en) | High-performance modified epoxy alicyclic amine curing agent and preparation method thereof | |
| CN104194695A (en) | Grafted nano ambary fiber crystal whisker modified urea formaldehyde resin adhesive and preparation method thereof | |
| CN104327769B (en) | The environmental protection label tackiness agent of the easy alkali cleaning excellent property of a kind of mildew-proof water-resistant and method for making thereof | |
| CN103374090A (en) | Method for preparing carboxyl styrene-butadiene latex for artificial turf back coating through soap-free polymerization | |
| CN110305618B (en) | Preparation method of water-resistant label adhesive for processing glass bottled drink | |
| CN109293803A (en) | A kind of method of production of low-temperature polyethylene butyral composition | |
| CN106753064A (en) | Modified water-tolerant polyvinyl alcohol trade mark adhesive and preparation method thereof | |
| CN103254841A (en) | Adhesive for production of corrugated board | |
| CN103694930B (en) | A kind of preparation method of water-resistant polyvinyl alcohol trade mark adhesive | |
| CN110862788A (en) | Wear-resistant water-resistant environment-friendly label adhesive and preparation method thereof | |
| CN104530277A (en) | Polyvinyl alcohol and preparation method thereof | |
| CN110746910B (en) | Fast-adhesion water-resistant environment-friendly label adhesive and preparation method thereof | |
| CN101864256A (en) | Method for preparing composite adhesive | |
| CN102391825A (en) | Label adhesive | |
| CN108192535B (en) | Plastic bottle environment-friendly label adhesive for automatic labeling machine and preparation method thereof | |
| CN1814685A (en) | Blush resistant adhesives used in bottle labeling | |
| CN110343491B (en) | Water-resistant crystal plastic trademark adhesive and preparation method thereof | |
| CN101851475A (en) | Preparation method of energy-saving, environment-protecting and sag-resistant water-based instant adhesive | |
| CN104558656A (en) | Method for preparing high barrier thin film by using modified polyvinyl alcohol | |
| CN110922915B (en) | Adhesive for label glue spraying device of beer labeling machine and preparation method | |
| CN100567434C (en) | A kind of quick-setting water-proof paper tag adhesive and preparation method thereof | |
| CN101012359A (en) | Environment-friendly type multifunctional self-adhesive and preparing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |