CN105524570A - Adhesive tap component and binding product - Google Patents

Adhesive tap component and binding product Download PDF

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Publication number
CN105524570A
CN105524570A CN201610031217.8A CN201610031217A CN105524570A CN 105524570 A CN105524570 A CN 105524570A CN 201610031217 A CN201610031217 A CN 201610031217A CN 105524570 A CN105524570 A CN 105524570A
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CN
China
Prior art keywords
adhesive tape
stretching
shifting
bonded
except
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610031217.8A
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Chinese (zh)
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CN105524570B (en
Inventor
肖正华
殷冠南
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Speciality Materials Shanghai Co Ltd
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3M Innovative Properties Co
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Publication date
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Priority to CN201610031217.8A priority Critical patent/CN105524570B/en
Publication of CN105524570A publication Critical patent/CN105524570A/en
Priority to PCT/US2017/013348 priority patent/WO2017127293A1/en
Application granted granted Critical
Publication of CN105524570B publication Critical patent/CN105524570B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/10Adhesives in the form of films or foils without carriers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/33Applications of adhesives in processes or use of adhesives in the form of films or foils for batteries or fuel cells
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/308Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive tape or sheet losing adhesive strength when being stretched, e.g. stretch adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention provides an adhesive tap component and a binding product, which belong to the technical field of pull-to-remove adhesive tapes and solve the problem that the existing pull-to-remove adhesive tape is easily broken when being removed at a large pulling angle. The adhesive tape component is used for being bound on at least one base and comprises a pull-to-remove adhesive tape and an intermediate layer, wherein the pull-to-remove adhesive tape has a binding surface; the intermediate layer covers at least part of the bonding surface of the pull-to-remove adhesive tape and has a first surface and a second surface opposite to each other; the first surface is used for binding with the base; the second surface is bound on the binding surface and at least part of the second surface directly contacts with the binding surface. The second surface has a Ra value between 0.1mu m to 7mu m.

Description

Adhesive tape assembly, bonded product
Technical field
The invention belongs to and can remove tape technology field by stretching and shifting, be specifically related to a kind of Adhesive tape assembly, bonded product.
Background technology
For the consideration such as portability, aesthetic property, the battery in a lot of mobile terminal (as mobile phone, panel computer, notebook computer etc.) is bonded on housing by double sticky tape.When due to locate the reasons such as inaccurate, maintenance battery to be pulled down time because double sticky tape cannot be taken off between battery and housing, thus can only actuating battery so that it is pulled down from double sticky tape.But use lithium cell in mobile terminal, lithium cell soft pliable more, directly operate on it and easily cause cell damage, even may cause the electrolyte leakage of wherein severe toxicity and cause danger.For this reason, available can stretching and shifting except the battery in adhesive tape fixed cellular terminal.
As shown in Figure 1, can shrink except when adhesive tape 1 is stretched by stretching and shifting, thus its adhesive surface is subject to the power vertical with substrate 9 surface and is separated with substrate 9.Thus, if make can stretching and shifting except staying except substrate 9 (as battery and housing) in an end of adhesive tape 1, just can extract out between two substrates 9 except adhesive tape 1 by stretching and shifting by this end that stretches, and two substrates 9 be separated.
As shown in Figure 2, when shrinking and after being separated with substrate 9 except adhesive tape 1 by stretching and shifting, it also wants opposed substrate 9 segment distance that moves could deviate from between substrate 9.Due to the difference of substrate 9 structure, thus in a lot of situation can stretching and shifting except adhesive tape 1 can only with specific draw angle (namely draw direction and can stretching and shifting remove angle between adhesive tape 1 and substrate 9 contact surface) be stretched.In this case, an edge part of substrate 9 right part of the lower surface of upside substrate 9 (in the Fig. 2) with can contact and there is certain pressure because of the effect of drawing force except between adhesive tape 1 by stretching and shifting, so time can stretching and shifting can slide in substrate 9 and be subject to sliding resistance (comprising frictional force and cohesive force etc.) except adhesive tape 1, and this sliding resistance increases along with the increase of draw angle.Therefore, when draw angle excessive (as at 45 ° to 90 °), easily cause to be pulled off and cannot normally to remove except adhesive tape 1 by stretching and shifting.
Summary of the invention
An object of the present invention is to provide a kind of Adhesive tape assembly, use this Adhesive tape assembly can avoid can being pulled off (even large draw angle remove) removing in process except adhesive tape by stretching and shifting, improve its reliability.
This Adhesive tape assembly is for being bonded at least one substrate, and it comprises:
Can remove adhesive tape by stretching and shifting, it has adhesive surface;
Media layer, its cover described can stretching and shifting except at least part of adhesive surface of adhesive tape, and there is relative first surface and second; Wherein,
Described first surface is used for and described bond substrates;
Described second face is bonded on described adhesive surface, and have at least partly described second directly contact with described adhesive surface;
Described second mask has the Ra value between 0.1 μm to 7 μm.
According to a kind of embodiment of the present invention, described second mask has the Ra value between 0.15 μm to 6 μm.
According to a kind of embodiment of the present invention, described Adhesive tape assembly also comprises low-viscous layer, its be located at described media layer an end and described can stretching and shifting except between adhesive tape; And described low-viscous layer and described can stretching and shifting except in the cohesive strength between adhesive tape and the cohesive strength between described low-viscous layer and described media layer, have a cohesive strength be less than between described media layer and described substrate at least.
Another object of the present invention is to provide a kind of bonded product, wherein have can stretching and shifting except adhesive tape, this can not easily rupture when being stretched and removing (even large draw angle remove) except adhesive tape by stretching and shifting, and reliability is high.
This bonded product comprises:
First substrate, it has first to be bonded;
Can stretching and shifting except adhesive tape, it has adhesive surface, describedly can be bonded on described first to be bonded except a part for adhesive tape by stretching and shifting, and another part extends to outside described first to be bonded;
Media layer, its be at least located at described first to be bonded edge part and described can stretching and shifting except between adhesive tape, and there is relative first surface and second; Described first surface is bonded on the edge part of described first to be bonded at least partly, described second mask has the Ra value between 0.1 μm to 7 μm, and wherein relative with the described first surface being bonded in the edge part of first to be bonded second directly contacts described adhesive surface.
According to a kind of embodiment of the present invention, described bonded product also comprises the second substrate, and it has second to be bonded that is oppositely arranged with described first face to be bonded; And describedly can all have described adhesive surface except the both sides of adhesive tape by stretching and shifting, describedly can be bonded between described first to be bonded and second to be bonded except a part for adhesive tape by stretching and shifting.
According to a kind of embodiment of the present invention, described bonded product is mobile terminal; Described first substrate is battery; Described second substrate is the housing of described mobile terminal.
Accompanying drawing explanation
Fig. 1 is existing can being stretched the principle schematic removed except adhesive tape by stretching and shifting;
Fig. 2 be existing can the principle schematic that is stretched when removing with large draw angle except adhesive tape of stretching and shifting;
Fig. 3 be embodiments of the invention a kind of can stretching and shifting except the cross-sectional view of adhesive tape;
Fig. 4 be Fig. 3 can stretching and shifting except the plan structure schematic diagram of adhesive tape;
Fig. 5 be Fig. 3 can the cross-sectional view that is stretched when removing except adhesive tape of stretching and shifting;
Fig. 6 be embodiments of the invention another kind can stretching and shifting except the cross-sectional view of adhesive tape;
Fig. 7 be embodiments of the invention another can stretching and shifting except the cross-sectional view of adhesive tape;
Fig. 8 be use Fig. 7 of embodiments of the invention can stretching and shifting except a kind of cross-sectional view of bonded product of adhesive tape;
Fig. 9 be in the bonded product of Fig. 8 can a cross-sectional view being stretched when removing except adhesive tape of stretching and shifting;
Figure 10 be in the bonded product of Fig. 8 can another cross-sectional view of being stretched when removing except adhesive tape of stretching and shifting;
Wherein, Reference numeral is: 1, can remove adhesive tape by stretching and shifting; 11, adhesive surface; 2, media layer; 21, first surface; 22, second; 219, pressure sensitive adhesives; 3, low-viscous layer; 4, non-adhesive layer; 9, substrate; 91, the first substrate; 92, the second substrate.
Embodiment
For making those skilled in the art understand technical scheme of the present invention better, below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
terminological interpretation
In the present invention, the meaning of following term or describing mode is as follows:
" can stretching and shifting except adhesive tape " refers to when it is bonded in after in substrate, realizes the adhesive tape be separated with substrate by applying pulling force along its length to it.
" draw angle " refers to, to can stretching and shifting except the actual direction of motion stretched of adhesive tape, and can stretching and shifting except the angle between adhesive tape and substrate Contact face.
" pressure sensitive adhesive " refers to and can be bonded in suprabasil material, and it at least meets the following conditions under envrionment temperature (5 DEG C to 40 DEG C): (1) has lasting viscosity; (2) under the pressure pressed with finger, just bonding can be realized; (3) shape can be changed to be attached in substrate; (4) its cohesive strength is enough to make its substantially clean removing from substrate.
That states for each accompanying drawing waits the noun of locality up and down, is only the relative orientation for particular case in figure, does not form the restriction to the concrete direction of actual product of the present invention.
" mobile terminal " refers to and can be carried by user and the equipment with computing ability used in movement, and it includes but not limited to mobile phone, panel computer (as iPad), notebook computer etc.
adhesive tape assembly
As shown in Figures 3 to 10, embodiments of the invention provide a kind of Adhesive tape assembly, and it is for being bonded at least one substrate 9, and Adhesive tape assembly comprises:
Can remove adhesive tape 1 by stretching and shifting, it has adhesive surface 11;
Media layer 2, its covering can stretching and shifting except at least part of adhesive surface 11 of adhesive tape 1, and there is relative first surface 21 and the second face 22; Wherein,
First surface 21 is for boning with substrate 9;
Second face 22 is bonded on adhesive surface 11, and has at least part of second face 22 directly to contact with adhesive surface 11;
Second face 22 has the Ra value between 0.1 μm to 7 μm.
That is, as shown in Figure 3, Figure 4, the Adhesive tape assembly of the embodiment of the present invention comprise conventional can stretching and shifting except adhesive tape 1, this can be provided with adhesive surface 11 (i.e. the sticking face of tool) for boning with substrate 9 except at least one face of adhesive tape 1 by stretching and shifting.Adhesive surface 11 be coated with media layer 2 at least partially, media layer 2 is the second face 22 towards the side of adhesive surface 11, there is specific roughness in second face 22, i.e. its Ra value (profile arithmetic mean deviation, arithmeticalmeandeviationoftheprofile) between 0.1 μm to 7 μm, and part second face 22 is had at least to be directly contact with adhesive surface 11; And the opposite side of media layer 2 is first surface 21, this first surface 21 is for being bonded in substrate 9.
When Adhesive tape assembly is bonded in substrate 9, media layer 2 can stretching and shifting except between adhesive tape 1 and substrate 9, become " intermediary " of the two, and have specific roughness the second face 22 can with can contact except adhesive tape 1 (adhesive surface 11) by stretching and shifting.Thus as shown in Figure 5, to can stretching and shifting stretch except adhesive tape 1 time, can be separated with media layer 2 except adhesive tape 1 and to slide on this second face 22 by stretching and shifting, namely originally can removing the slip of adhesive tape 1 in substrate 9 and become the slip on the second face 22 by stretching and shifting.The beat all discovery of the present invention, if with can have specific roughness in the face (the second face 22) that contact except adhesive tape 1 of stretching and shifting, then itself and can stretching and shifting except the sliding resistance between adhesive tape 1 just lower.Therefore, above media layer 2 can reduce can the sliding resistance that is stretched when removing suffered by (when especially draw angle is larger) except adhesive tape 1 of stretching and shifting, thus avoids being pulled off except adhesive tape 1 by stretching and shifting, improves the reliability of Adhesive tape assembly.
Why have specific roughness face and can stretching and shifting except the sliding resistance between adhesive tape 1 lower, may be due to following reason (restriction of following statement not to action principle of the present invention): when can stretching and shifting be stretched except adhesive tape 1 time, there is height-oriented and surface undulation and be eliminated to a great extent in its surface molecular, can can become the very low shiny surface of roughness except adhesive tape 1 surface by stretching and shifting, if the face be now in contact with it is also very smooth, the contact area between the two is very large, cause still having certain viscosity can stretching and shifting can be well-bonded with this face except adhesive tape 1, sliding resistance increases.Accordingly, if with can the face that contact except adhesive tape 1 of stretching and shifting too coarse, then easily can be scratched by the spike of coarse structure in sliding process except adhesive tape 1 by stretching and shifting, thus cause sliding resistance to increase and make to remove adhesive tape 1 and easily rupture by stretching and shifting.And when roughness is positioned at specified range, the impact of above two aspects can be made to reach balance, sliding resistance dropped to minimum, best avoiding can be pulled off except adhesive tape 1 by stretching and shifting.
According to a kind of embodiment of the present invention, the second face 22 has the Ra value between 0.15 μm to 6 μm.
That is, this second face 22 preferably has the Ra value between 0.15 μm to 6 μm, more preferably has the Ra value between 0.2 μm to 5 μm, preferably has the Ra value between 0.5 μm to 4 μm further.
Wherein, above can stretching and shifting except adhesive tape 1 can adopt any known can stretching and shifting except adhesive tape product, the 6701-150 type of such as 3M Creative Company (U.S., the Minnesota State, Sao Paulo) can stretching and shifting except adhesive tape, be not described in detail at this.
Wherein, although in the drawings and in which all with can stretching and shifting except every side of adhesive tape 1 be completely adhesive surface 11 as an example, should be appreciated that if can stretching and shifting except the side of adhesive tape 1 in only have portion to be adhesive surface 11, and all the other positions are inviscid, are also feasible.Such as, can there is no viscosity except an end of adhesive tape 1 by stretching and shifting, using as handle when stretching.
Wherein, above media layer 2 can adopt any known rete, as long as its side can be bonded in substrate 9, opposite side has above specific roughness.Preferably, this media layer 2 can be made up of polymer materials, and such as polyimide, polyethylene terephthalate, polycarbonate etc., be not described in detail at this.
And the thickness of media layer 2 generally can at several microns between hundreds of micron, such as, between 5 μm to 800 μm, preferably between 10 μm to 500 μm, more preferably between 20 μm to 200 μm, preferred between 25 μm to 100 μm further.
According to a kind of embodiment of the present invention, first surface 21 is provided with pressure sensitive adhesives 219 or double sticky tape.
That is, because Adhesive tape assembly has part surface to be the first surface 21 of media layer 2, thus to realize Adhesive tape assembly with the bonding of substrate 9, then this first surface 21 will be bonded in substrate 9; Therefore, first surface 21 is preferably provided with pressure sensitive adhesives 219 or double sticky tape.This pressure sensitive adhesives 219 can be conventional Acrylate pressure sensitive binding agent, polyurethane pressure sensitive binding agent, polyvinyl chloride pressure sensitive adhesives etc., is not described in detail at this.
Certainly, if first surface 21 does not have binding agent, but the position will carrying out boning in substrate 9 arranges binding agent or double sticky tape, is also feasible.
According to a kind of embodiment of the present invention, can all have adhesive surface 11 except the both sides of adhesive tape 1 by stretching and shifting, wherein only have on an adhesive surface 11 and be bonded with media layer 2.
That is, as shown in Fig. 3, Fig. 6, can can all there is adhesive surface 11 in both sides except adhesive tape 1 by stretching and shifting, this is because inconvenient occasion of directly being torn from substrate 9 by adhesive tape can be generally used for except adhesive tape 1 by stretching and shifting, and general adhesive tape all will be bonded between two substrates 9 in this occasion, therefore preferably can all can bond except the both sides of adhesive tape 1 by stretching and shifting.And due in actual applications, which generally can determine will remove and direction can should stretch (can only stretch upward in as Figure 10) to except during adhesive tape 1 by stretching and shifting in advance, and can only slide the substrate 9 (the first substrate 91 as in Figure 10) near draw direction side is upper except adhesive tape 1 by stretching and shifting, as long as therefore media layer 2 can be provided with in this side except adhesive tape 1 by stretching and shifting.
According to a kind of embodiment of the present invention, media layer 2 can be there is no except at least one end of adhesive tape 1 by stretching and shifting.
That is, as shown in Fig. 3, Fig. 7, above media layer 2 can be set stretching and shifting except at least one end of adhesive tape 1.This is because remove can stretching and shifting except adhesive tape 1 time, first make to be separated with media layer 2 except adhesive tape 1 by stretching and shifting, to ensure to slide to reduce sliding resistance on media layer 2 except adhesive tape 1 by stretching and shifting.And if can also have media layer 2 except the end of adhesive tape 1 by stretching and shifting, then the end of the two flushes as shown in Figure 6, therefore is at this moment difficult to the two be separated in end.
According to a kind of embodiment of the present invention, can remove on the length direction of adhesive tape 1 by stretching and shifting, the size of the part that the second face 22 directly contacts with adhesive surface 11 is at least 5 millimeters.
That is, can remove in the media layer 2 that adhesive tape 1 is arranged by stretching and shifting, the second face 22 directly contacted with adhesive surface 11 will to the youthful and the elderly 5 millimeters (also can have between part second face 22 and adhesive surface 11 and be provided with other structure).This is because when stretching, actual only have substrate 9 edge part and can stretching and shifting comparatively large except the sliding resistance between adhesive tape 1, therefore at least must be provided with the media layer 2 (the second face 22) directly contacted with adhesive surface 11 in this position.And the present invention finds, the general length of the part that above sliding resistance is larger is within 5 millimeters, therefore the second face 22 directly contacted with adhesive surface 11 should to the youthful and the elderly 5 millimeters.Certainly, if the second face 22 length directly contacted with adhesive surface 11 is longer, thus better playing the effect reducing sliding resistance, is also feasible.
According to a kind of embodiment of the present invention, on the adhesive surface 11 being bonded with media layer 2, along can stretching and shifting except the length direction of adhesive tape 1, media layer 2 only covers a part for this adhesive surface 11; Or, on the adhesive surface 11 being bonded with media layer 2, along can stretching and shifting except the length direction of adhesive tape 1, media layer 2 covers this adhesive surface 11 completely.
That is, with on the adhesive surface 11 of media layer 2, media layer 2 as shown in Figure 3, can only cover a part for this adhesive surface 11.This is because as previously mentioned, length is less in fact for the higher part of sliding resistance, as long as therefore this part adhesive face 11 is provided with media layer 2, other position remains and can directly bond with substrate 9 except the adhesive surface 11 of adhesive tape 1 by stretching and shifting like this, can ensure as far as possible can stretching and shifting except the adhesive property of adhesive tape 1 script constant.
Or, also can as shown in Figure 6, if certain adhesive surface 11 is with media layer 2, then media layer 2 just covers this adhesive surface 11 completely.Obviously, if media layer 2 be only positioned at can stretching and shifting except the portion of adhesive tape 1, must carry out careful contraposition when attaching, to ensure that media layer 2 is positioned at the edge part (otherwise media layer 2 does not just have the effect reducing sliding resistance) of substrate 9, its operation easier is very large.And if media layer 2 covers whole adhesive surface 11, its operation is just simpler.
According to a kind of embodiment of the present invention, can stretching and shifting except on the width of adhesive tape 1, the size of media layer 2 be more than or equal to can stretching and shifting except the width of adhesive tape 1.
Obviously, from reduction sliding resistance and angle easy to use consider, the second face 22 should cover the whole width range of adhesive surface 11, namely as shown in Figure 4, media layer 2 should with can stretching and shifting except adhesive tape 1 with wide or wider than it.
Certainly, if the width of media layer 2 than can stretching and shifting except the width of adhesive tape 1 little, it also can play the effect of certain reduction sliding resistance.Typically, can be pulled off except adhesive tape 1 by stretching and shifting to reliable avoiding, then media layer 2 width at least should be can stretching and shifting except 30% of adhesive tape 1 width, be more preferably at least 50%, be preferably at least 80% further.Obviously, media layer 2 width be less than can stretching and shifting except adhesive tape 1 width time, its preferably should be located at can stretching and shifting except the middle part of adhesive tape 1 width.
According to a kind of embodiment of the present invention, Adhesive tape assembly also comprises low-viscous layer 3, and it is located at an end of media layer 2 and can removes between adhesive tape 1 by stretching and shifting; And low-viscous layer 3 and can stretching and shifting except in the cohesive strength between adhesive tape 1 and the cohesive strength between low-viscous layer 3 and media layer 2, have a cohesive strength be less than between media layer 2 and substrate 9 at least.
That is, as shown in Figure 7, an end of media layer 2 and can stretching and shifting except being also provided with low-viscous layer 3 between adhesive tape 1 (obviously, be provided with the position of low-viscous layer 3, then the second face 22 does not directly contact with adhesive surface 11), this low-viscous layer 3 has lower cohesive strength, thus ensure itself and can stretching and shifting except the cohesive strength between adhesive tape 1 and/or the cohesive strength between itself and media layer 2 lower than the cohesive strength between media layer 2 and substrate 9.Thus, the effect of this low-viscous layer 3 makes media layer 2 and can be less than cohesive force between media layer 2 and substrate 9 except the separation stresses between adhesive tape 1 by stretching and shifting, thus removing in process, can ensure necessarily can be separated with media layer 2 except adhesive tape 1 by stretching and shifting, and can not produce media layer 2 along with can stretching and shifting except adhesive tape 1 is together by situation about peeling off from substrate 9.
According to a kind of embodiment of the present invention, low-viscous layer 3 and cohesive strength between low-viscous layer 3 and media layer 2 can be greater than except the cohesive strength between adhesive tape 1 by stretching and shifting.
That is, as preferred mode, low-viscous layer 3 and can stretching and shifting except the cohesive strength between adhesive tape 1 comparatively large, and and cohesive strength between media layer 2 less.Like this can stretching and shifting except adhesive tape 1 be separated with media layer 2 time, low-viscous layer 3 will inevitably be bonded in can stretching and shifting except adhesive tape 1 is separated with media layer 2, along with can being pulled away (as shown in Figure 10) except the continuation stretching low-viscous layer 3 of adhesive tape 1 by stretching and shifting, thus do not affect can affect can stretching and shifting except the slip of adhesive tape 1 on media layer 2.
Concrete, above low-viscous layer 3 can adopt existing low adhesive film or low viscous coating.Or the face (the second face 22) contacted with low-viscous layer 3 due to media layer 2 does not have viscosity, therefore low-viscous layer 3 also can adopt one-faced tapes, to be clung by media layer 2 by its sticking one side.Certainly, due to preferred low-viscous layer 3 and cohesive strength between itself and media layer 2 can be greater than except the cohesive strength between adhesive tape 1 by stretching and shifting, therefore when using one-faced tapes as low-viscous layer 3, stripping strength between itself and media layer 2 can not be too large, usually can between 1 gram/inch to 200 grams/inch, more preferably between 1 gram/inch to 100 grams/inch, preferred between 0.5 gram/inch to 50 grams/inch further.
According to a kind of embodiment of the present invention, Adhesive tape assembly also comprises non-adhesive layer 4, its be located at can stretching and shifting except at least side of at least one end of adhesive tape 1, non-adhesive layer 4 is away from can not having viscosity except the face of adhesive tape 1 by stretching and shifting.
That is, as shown in Figure 7, can stretching and shifting except adhesive tape 1 end also can be provided with the noncohesive layer in outside (inside it can toughness be bonded in can stretching and shifting except on adhesive tape 1).As previously mentioned, can an end must be had after bonding to stay except substrate 9, to carry out stretched operation except adhesive tape 1 by stretching and shifting.And before stretching, be the bonding preventing this end from meeting accident, therefore non-adhesive layer 4 (effect is similar to release film) can be set thereon.The position, length etc. of this non-adhesive layer 4 can determine according to specific needs, such as, if can bend and be bonded in the first substrate 91, as long as then its side of not carrying out boning is provided with non-adhesive layer 4 except the end of adhesive tape 1 by stretching and shifting as shown in Figure 8.Concrete, this non-adhesive layer 4 can be known inviscid film (as release film), non-stick coating layer, one-faced tapes etc., is not described in detail at this.
Wherein, although depict above low-viscous layer 3 and non-adhesive layer 4 in Fig. 7 to Figure 10 all simultaneously, between the two, there is no positive connection.In an Adhesive tape assembly product, low-viscous layer 3 and non-adhesive layer 4 can be had simultaneously, also can only have one wherein.
Wherein, adhesive tape 1 (media layer 2, non-adhesive layer 4) outside can be removed by stretching and shifting, also can being provided with conventional release film or separate-type paper, for protecting adhesive surface 11 when not using, preventing the bonding that it meets accident.
In the part accompanying drawing of embodiments of the invention, media layer 2, low-viscous layer 3, non-adhesive layer 4 etc. be recessed can stretching and shifting except adhesive tape 1 inside, but this be only in order to schematically represent these structures should be positioned at can stretching and shifting except which side of adhesive tape 1, and do not represent can stretching and shifting except the actual depression be provided with for holding these structures in adhesive tape 1.
bonded product
Embodiments of the invention also provide a kind of bonded product, and it comprises:
First substrate 91, it has first to be bonded;
Can stretching and shifting except adhesive tape 1, it has adhesive surface 11, and can be bonded on first to be bonded except a part for adhesive tape 1 by stretching and shifting, another part extends to outside first to be bonded;
Media layer 2, it is at least located at the edge part of first to be bonded and can removes between adhesive tape 1 by stretching and shifting, and has relative first surface 21 and the second face 22; First surface 21 is bonded on the edge part of first to be bonded at least partly, and the second face 22 has the Ra value between 0.1 μm to 7 μm, and the second wherein relative with the first surface 21 of the edge part being bonded in first to be bonded face 22 directly contacts adhesive surface 11.
That is, as shown in Figure 8, the embodiment of the present invention provide a kind of comprise above-mentioned can stretching and shifting except the bonded product of adhesive tape 1 and media layer 2.Wherein, first to be bonded of first substrate 91 is provided with and can removes adhesive tape 1 by stretching and shifting, and at least first to be bonded edge part and can stretching and shifting except being provided with above-mentioned media layer 2 between adhesive tape 1, further, at least directly contact with adhesive surface 11 in second face 22 at this edge part place, with ensure can stretching and shifting except adhesive tape 1 stretching and shifting except time, media layer 2 can play reduce sliding resistance, avoiding can the effect that is pulled off except adhesive tape 1 of stretching and shifting.
Concrete, above bonded product can obtain by being bonded in by above-mentioned Adhesive tape assembly in the first substrate 91.But, if first attach media layer 2 separately in the first substrate 91, can be attached in this media layer 2 and the first substrate 91 except adhesive tape 1 by stretching and shifting more afterwards, also can obtain above bonded product.
According to a kind of embodiment of the present invention, the first substrate 91 also comprises the sidepiece that face to be bonded with first connects; Can be bonded at least partly on sidepiece except adhesive tape 1 by stretching and shifting; Sidepiece and can stretching and shifting except being also provided with media layer 2 between adhesive tape 1.
That is, the side of the first substrate 91 also can be provided with above can stretching and shifting except adhesive tape 1 and media layer 2.This is because as shown in Figure 8, can also to be bonded on the side of the first substrate 91 except adhesive tape 1 by stretching and shifting in a lot of situation, and when draw angle very large (as close to 90 °), first substrate 91 side and can stretching and shifting except also producing larger sliding resistance between adhesive tape 1, therefore this position is preferably also provided with media layer 2.
According to a kind of embodiment of the present invention, bonded product also comprises the second substrate 92, and it has second to be bonded that face to be bonded is oppositely arranged with first; And can all have adhesive surface 11 except the both sides of adhesive tape 1 by stretching and shifting, can be bonded between first to be bonded and second to be bonded except a part for adhesive tape 1 by stretching and shifting.
That is, as shown in Figure 8, first substrate 91 and the second substrate 92 can be bonded together by above Adhesive tape assembly, therefore can stretching and shifting should between two to be bonded except the part of adhesive tape 1, and as previously mentioned, for guaranteeing to remove except adhesive tape 1 stretching and shifting by stretching and shifting, therefore can at least one end also to be had to be positioned at except two to be bonded except adhesive tape 1 by stretching and shifting.
Certainly, in bonded product, also can comprise the structures such as above low-viscous layer 3, non-adhesive layer 4, and the existence of these structures can not affect and can remove the function of adhesive tape 1 own by stretching and shifting.Such as, if when there is low-viscous layer 3, as long as then it is positioned at an end of media layer 2, as can be only existed in the position of the upper surface (also can have side) of corresponding first substrate 91, then do not exist in the position of corresponding first substrate 91 bottom surface.For another example, if when having non-adhesive layer 4, then it should be positioned at outside two substrates in order to avoid the bonding of impact to substrate.
According to a kind of embodiment of the present invention, bonded product is mobile terminal; First substrate 91 is battery; Second substrate 92 is the housing of mobile terminal.
That is, the present invention is specially adapted to be fixed the battery of mobile terminal (as mobile phone, panel computer, notebook computer etc.), is specially and is bonded on the housing of mobile terminal by battery.Certainly, above example does not form limiting the scope of the present invention.
When the battery of above mobile terminal (as lithium cell) being pulled down, can as shown in Figure 9, first can peel off from substrate and media layer 2 except the end of adhesive tape 1 and low-viscous layer 3 by stretching and shifting.Afterwards as shown in Figure 10, stretching can stretching and shifting except the end of adhesive tape 1, make to be separated with media layer 2 with two substrates except adhesive tape 1 by stretching and shifting, and deviate from between two substrates, and in drawing process, to slide on media layer 2 except adhesive tape 1 by stretching and shifting at substrate 9 edge part (in figure the first substrate 91 lower surface right part), thus can the sliding resistance that removes suffered by adhesive tape 1 of stretching and shifting less, not easy fracture.And can stretching and shifting except after adhesive tape 1 thoroughly removed, battery (the first substrate 91) can be taken out and conversely, then the media layer 2 of remnants it on is torn, the dismounting of battery can be completed.
test method
1) roughness test
The testing method of the roughness of media layer comprises: be laid in after media layer being cut into the sheet of 10cm × 10cm on sheet glass, both sides one-faced tapes is fixed, with (the China of peak scientific & technical corporation in Beijing epoch, Beijing) TR-200 type roughness tester test its roughness (Ra value), each test stroke 4 millimeters, often kind of media layer surveys 5 data.
2) mechanical stretching
By mechanical means to can stretch except adhesive tape by stretching and shifting in above bonded product, test its maximum tensile stress and be that no fracture occurs, it specifically comprises:
In (the U.S. of 3M Creative Company, the Minnesota State, Sao Paulo) 9495LE type double sticky tape side laminating media layer, and be cut into the sheet of 20mm × 120mm together, afterwards double sticky tape opposite side is fitted in (part grown wraps in side and the back side of anodic oxidation aluminium block) on the anodic oxidation aluminium block of 20mm × 100mm × 2mm.
The 6701-150 type of 3M Creative Company (U.S., the Minnesota State, Sao Paulo) can be removed the sheet that adhesive tape (thickness 150 μm, bilateral is adhesive surface) cuts into 10mm × 80mm by stretching and shifting.
Can invest on media layer on anodic oxidation aluminium block (contacting with second of media layer) except tape sticker by stretching and shifting, 10mm is exposed as handle in end, and handle portion can be sticked PE film (polyethylene film) as non-adhesive layer except on adhesive tape by stretching and shifting.
By anodic oxidation aluminium block between two parties with fitting on stainless steel plate except adhesive tape opposite side by stretching and shifting, thus be equivalent in order to adhesive tape assembly, anodic oxidation aluminium block and stainless steel plate are bonded together.
Carry out pressurize in 15 seconds with the press of 6 kilograms, guarantee abundant laminating.
Resident 1 hour of sample segment, sample segment 65 DEG C temperature and 90% relative humidity under aging 72 hours.
Fixing stainless steel plate and anodic oxidation aluminium block, with (the U.S. of Instron Corporation, Massachusetts, promise Wood) Instron3365 type tension testing machine with the draw speed of the draw angle of 90 ° and 300mm/min to stretching except adhesive tape by stretching and shifting, whether record maximum tensile stress and rupture, 5 data surveyed by often kind of sample.
3) manual stretching
Whether by hand to can stretch except adhesive tape by stretching and shifting in above bonded product, test it and rupture, it specifically comprises:
In (the U.S. of 3M Creative Company, the Minnesota State, Sao Paulo) 9495LE type double sticky tape on side laminating media layer, and be cut into the sheet of 20mm × 20mm together, afterwards double sticky tape opposite side is fitted in bottom edge portion and the side of the HuaWeiHB417094EBC type battery of Huawei Tech Co., Ltd (China, Guangdong, Shenzhen), wherein lateral parts thickness is 6mm, therefore is attached to the long 14mm of media layer of battery bottom surface edge part.
The 6701-150 type of 3M Creative Company (U.S., the Minnesota State, Sao Paulo) can be removed the sheet that adhesive tape (thickness 150 μm, bilateral is adhesive surface) cuts into 10mm × 80mm by stretching and shifting.
The handle of 10mm can be reserved except tape sticker by stretching and shifting on the bottom surface and side of above battery, wherein in edge part and the side of battery bottom surface, can to be located on media layer (contact with second of media layer) except adhesive tape by stretching and shifting, adhesive tape can be removed then directly to be attached on battery by stretching and shifting in other position of battery bottom surface.
Carry out pressurize in 15 seconds with the press of 6 kilograms, guarantee abundant laminating, resident 1 hour of sample.
With hand with the speed of the draw angle of about 90 ° and about 2000mm/min to stretching except adhesive tape by stretching and shifting, whether record ruptures, and 5 data surveyed by often kind of sample.
specific embodiment
Embodiment 1
With (China of Rui Huatai film Science and Technology Ltd., Guangdong, Shenzhen) the former film of PI (polyimide film) of thickness 25 μm, to the one surface (U.S. of 3M Creative Company, the Minnesota State, Sao Paulo) 320 order sand paper polish after as media layer, be second with buffed surface.
Carry out above test after making bonded product with this media layer, test result is as following table.
Embodiment 2
With (China of Rui Huatai film Science and Technology Ltd., Guangdong, Shenzhen) the former film of PI (polyimide film) of thickness 25 μm, to the one surface (U.S. of 3M Creative Company, the Minnesota State, Sao Paulo) 500 order sand paper polish after as media layer, be second with buffed surface.
Carry out above test after making bonded product with this media layer, test result is as following table.
Comparative example 1
With the former film of PI (polyimide film) of the thickness 25 μm of Rui Huatai film Science and Technology Ltd. (China, Guangdong, Shenzhen), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Embodiment 3
With (Japan of east beautiful (TORAY) Co., Ltd., Tokyo) TORAYL01 type PET film (polyethylene terephthalate film), to the one surface (U.S. of 3M Creative Company, the Minnesota State, Sao Paulo) 320 order sand paper polish after as media layer, be second with buffed surface.
Carry out above test after making bonded product with this media layer, test result is as following table.
Embodiment 4
With (Japan of east beautiful (TORAY) Co., Ltd., Tokyo) TORAYL01 type PET film (polyethylene terephthalate film), to the one surface (U.S. of 3M Creative Company, the Minnesota State, Sao Paulo) 500 order sand paper polish after as media layer, be second with buffed surface.
Carry out above test after making bonded product with this media layer, test result is as following table.
Comparative example 2
By the TORAYL01 type PET film (polyethylene terephthalate film) in east beautiful (TORAY) Co., Ltd. (Japan, Tokyo), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Embodiment 5
With the 7585 type label materials of 3M Creative Company (U.S., the Minnesota State, Sao Paulo), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Comparative example 3
With the 57817 type label materials of 3M Creative Company (U.S., the Minnesota State, Sao Paulo), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Embodiment 6
By the ATL battery membranes in Beijing Xiaomi Technology Co., Ltd. (China, Beijing), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Comparative example 4
Do not use media layer, and the rete on HuaWeiHB417094EBC type battery surface with Huawei Tech Co., Ltd (China, Guangdong, Shenzhen) itself, directly test without polishing, test result is as following table.
Wherein, method and the above description of mechanical stretching are similar, and difference is not make double sticky tape, media layer and anodic oxidation aluminium block, and directly can be located between above battery and stainless steel plate except adhesive tape by stretching and shifting.The manual method stretched also with describes similar above, difference is not use media layer, and directly can remove the surface that adhesive tape is bonded in above battery by stretching and shifting.Certainly, now other parameter and mode etc. is constant in testing method.
Embodiment 7
With the GHF860M2AB type PC film (polycarbonate membrane) in Sumitomo (Sumitomo) group (Japan, Tokyo), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Comparative example 5
With the 2SLKN type release film in Mitsubishi (Mitsubishi) group (Japan, Tokyo), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
Embodiment 8
With the 1002BO type automobile black film of 3M Creative Company (U.S., the Minnesota State, Sao Paulo), when not polishing directly as media layer.
Carry out above test after making bonded product with this media layer, test result is as following table.
The roughness of the media layer second of table 1, each embodiment and comparative example
Project Ra value 1 (μm) Ra value 2 (μm) Ra value 3 (μm) Ra value 4 (μm) Ra value 5 (μm) Average Ra value
Embodiment 1 1.069 1.907 1.791 1.085 1.174 1.405
Embodiment 2 0.384 0.283 0.299 0.541 0.528 0.407
Comparative example 1 0.068 0.090 0.075 0.098 0.098 0.086
Embodiment 3 1.66 1.60 1.50 2.16 1.86 1.76
Embodiment 4 0.420 0.588 0.512 0.509 0.692 0.544
Comparative example 2 0.056 0.029 0.035 0.051 0.050 0.044
Embodiment 5 0.657 0.664 0.645 0.671 0.663 0.660
Comparative example 3 0.094 0.069 0.096 0.076 0.067 0.077
Embodiment 6 0.221 0.255 0.166 0.197 0.324 0.233
Comparative example 4 0.076 0.065 0.059 0.064 0.079 0.069
Embodiment 7 2.223 2.102 2.452 2.302 3.536 2.523
Comparative example 5 0.092 0.052 0.049 0.104 0.072 0.080
Embodiment 8 5.48 6.896 6.166 5.94 6.867 6.270
The maximum tensile stress (do not mark, represent and do not rupture) of the mechanical stretching of resident 1 hour of table 2, each embodiment and comparative example
The maximum tensile stress (do not mark, represent and do not rupture) of the mechanical stretching of aging 72 hours of table 3, each embodiment and comparative example
Protective layer Data 1 (N) Data 2 (N) Data 3 (N) Data 4 (N) Data 5 (N) On average (N)
Embodiment 1 5.88 5.86 6.72 7.48 6.56 6.50
Embodiment 2 7.31 11.057 5.05 4.90 8.90 7.44
Embodiment 3 7.82 8.30 7.81 8.21 7.12 7.85
Embodiment 4 7.53 6.62 4.67 7.62 7.51 6.79
Embodiment 5 4.47 8.11 8.05 4.36 5.64 6.13
Embodiment 6 10.77 7.24 9.38 12.36 10.24 10.00
Embodiment 7 8.04 8.96 6.83 7.16 8.91 7.98
Embodiment 8 6.17 6.24 6.68 (fractures) 5.42 5.44 5.99
The test result of the craft stretching of table 4, each embodiment and comparative example
Protective layer Data 1 Data 2 Data 3 Data 4 Data 5 On average
Embodiment 1 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Embodiment 2 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Comparative example 1 Fracture Fracture Fracture Fracture Fracture Fracture
Embodiment 3 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Embodiment 4 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Comparative example 2 Fracture Fracture Fracture Fracture Fracture Fracture
Embodiment 5 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Comparative example 3 Fracture Fracture Fracture Fracture Fracture Fracture
Embodiment 6 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Comparative example 4 Fracture Fracture Fracture Fracture Fracture Fracture
Embodiment 7 Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture Do not rupture
Comparative example 5 Fracture Fracture Fracture Fracture Fracture Fracture
Embodiment 8 Do not rupture Fracture Do not rupture Do not rupture Do not rupture Do not rupture
From above each embodiment, when the Ra value of media layer second is in the scope of 0.1 μm to 7 μm, except the embodiment 8 that Ra value is maximum has individual sample and ruptures, other are all can be removed and not rupture except adhesive tape by stretching and shifting smoothly.This roughness showing in above scope can effectively be avoided being pulled off except adhesive tape by stretching and shifting really.And, if when Ra value is excessive, to avoid can stretching and shifting except the fracture of adhesive tape be disadvantageous, therefore the Ra value of above media layer second is preferably less than 6 μm, is more preferably less than 5 μm.
Accordingly, from above each comparative example, respectively when the Ra value of media layer second is less than 0.1 μm, then can all be pulled off except adhesive tape majority by stretching and shifting in mechanical stretching, manual stretch in then all can all can be pulled off except adhesive tape by stretching and shifting.And in actual applications, generally can not adopt machinery can remove except tape shifter by stretching and shifting slowly, therefore the manual result stretched just more has referential.This shows, thinks that roughness is less in traditional concept, and the less idea of sliding resistance is incorrect, if the second surface roughness is too low, also can cause being pulled off except adhesive tape by stretching and shifting.
As can be seen here, no matter whether media layer is any material, what intended use is, through polishing, as long as but its roughness of second is in above specified range, can plays and avoid preferably to remove the effect be pulled off in process except adhesive tape by stretching and shifting; As long as and its roughness exceeds this scope, no matter be excessive or too small, all easily cause being pulled off except adhesive tape by stretching and shifting.This shows, only according to mode of the present invention, controls in this specified range by the roughness of media layer second, just can reach and avoid to remove adhesive tape breaking by stretching and shifting, improve the effect of its reliability.
Be understandable that, the illustrative embodiments that above embodiment is only used to principle of the present invention is described and adopts, but the present invention is not limited thereto.For those skilled in the art, without departing from the spirit and substance in the present invention, can make various modification and improvement, these modification and improvement are also considered as protection scope of the present invention.

Claims (15)

1. an Adhesive tape assembly, it is for being bonded at least one substrate, and wherein, described Adhesive tape assembly comprises:
Can remove adhesive tape by stretching and shifting, it has adhesive surface;
Media layer, its cover described can stretching and shifting except at least part of adhesive surface of adhesive tape, and there is relative first surface and second; Wherein,
Described first surface is used for and described bond substrates;
Described second face is bonded on described adhesive surface, and have at least partly described second directly contact with described adhesive surface;
Described second mask has the Ra value between 0.1 μm to 7 μm.
2. Adhesive tape assembly according to claim 1, wherein,
Described second mask has the Ra value between 0.15 μm to 6 μm.
3. Adhesive tape assembly according to claim 1, wherein,
Described first surface is provided with pressure sensitive adhesives or double sticky tape.
4. Adhesive tape assembly according to claim 1, wherein,
Described can all have described adhesive surface except the both sides of adhesive tape by stretching and shifting, wherein only has on a described adhesive surface and be bonded with described media layer.
5. Adhesive tape assembly according to claim 1, wherein,
Described can not have described media layer except at least one end of adhesive tape by stretching and shifting.
6. Adhesive tape assembly according to claim 1, wherein,
Described can stretching and shifting except on the width of adhesive tape, the size of described media layer be more than or equal to described can stretching and shifting except the width of adhesive tape.
7. Adhesive tape assembly according to claim 1, wherein,
Can remove on the length direction of adhesive tape by stretching and shifting described, the size of described second part directly contacted with described adhesive surface is at least 5 millimeters.
8. Adhesive tape assembly according to claim 1, wherein,
On the adhesive surface being bonded with described media layer, along can stretching and shifting except the length direction of adhesive tape, described media layer only covers a part for this adhesive surface;
Or
On the adhesive surface being bonded with described media layer, along can stretching and shifting except the length direction of adhesive tape, described media layer covers this adhesive surface completely.
9. Adhesive tape assembly according to claim 1, wherein, also comprises:
Low-viscous layer, its be located at described media layer an end and described can stretching and shifting except between adhesive tape; And described low-viscous layer and described can stretching and shifting except in the cohesive strength between adhesive tape and the cohesive strength between described low-viscous layer and described media layer, have a cohesive strength be less than between described media layer and described substrate at least.
10. Adhesive tape assembly according to claim 9, wherein,
Described low-viscous layer and describedly can be greater than cohesive strength between described low-viscous layer and described media layer except the cohesive strength between adhesive tape by stretching and shifting.
11. Adhesive tape assemblies according to claim 1, wherein, also comprise:
Non-adhesive layer, its be located at described can stretching and shifting except at least side of at least one end of adhesive tape, described non-adhesive layer can not have viscosity except the face of adhesive tape by stretching and shifting away from described.
12. 1 kinds of bonded products, wherein, comprising:
First substrate, it has first to be bonded;
Can stretching and shifting except adhesive tape, it has adhesive surface, describedly can be bonded on described first to be bonded except a part for adhesive tape by stretching and shifting, and another part extends to outside described first to be bonded;
Media layer, its be at least located at described first to be bonded edge part and described can stretching and shifting except between adhesive tape, and there is relative first surface and second; Described first surface is bonded on the edge part of described first to be bonded at least partly, described second mask has the Ra value between 0.1 μm to 7 μm, and wherein relative with the described first surface being bonded in the edge part of first to be bonded second directly contacts described adhesive surface.
13. bonded products according to claim 12, wherein,
Described first substrate also comprises the sidepiece connected with described first face to be bonded;
Describedly can be bonded on described sidepiece at least partly except adhesive tape by stretching and shifting;
Described sidepiece and described can stretching and shifting except being also provided with described media layer between adhesive tape.
14. bonded products according to claim 12, wherein, also comprise the second substrate, and it has second to be bonded that is oppositely arranged with described first face to be bonded; And
Described can all have described adhesive surface except the both sides of adhesive tape by stretching and shifting, describedly can be bonded between described first to be bonded and second to be bonded except a part for adhesive tape by stretching and shifting.
15. bonded products according to claim 14, wherein,
Described bonded product is mobile terminal;
Described first substrate is battery;
Described second substrate is the housing of described mobile terminal.
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