CN105509318A - Complete energy storage recycling equipment - Google Patents

Complete energy storage recycling equipment Download PDF

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Publication number
CN105509318A
CN105509318A CN201610056299.1A CN201610056299A CN105509318A CN 105509318 A CN105509318 A CN 105509318A CN 201610056299 A CN201610056299 A CN 201610056299A CN 105509318 A CN105509318 A CN 105509318A
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CN
China
Prior art keywords
energy storage
hot
heat exchanger
water
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610056299.1A
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Chinese (zh)
Inventor
王裕福
王太祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YUTAI ANTI-EXPLOSION ELECTRIC HEATER Co Ltd ZHENJIANG
Original Assignee
YUTAI ANTI-EXPLOSION ELECTRIC HEATER Co Ltd ZHENJIANG
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Filing date
Publication date
Application filed by YUTAI ANTI-EXPLOSION ELECTRIC HEATER Co Ltd ZHENJIANG filed Critical YUTAI ANTI-EXPLOSION ELECTRIC HEATER Co Ltd ZHENJIANG
Priority to CN201610056299.1A priority Critical patent/CN105509318A/en
Publication of CN105509318A publication Critical patent/CN105509318A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H7/00Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release
    • F24H7/002Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release using electrical energy supply
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/0005Details for water heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/0052Details for air heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/18Arrangement or mounting of grates or heating means
    • F24H9/1809Arrangement or mounting of grates or heating means for water heaters
    • F24H9/1818Arrangement or mounting of electric heating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/18Arrangement or mounting of grates or heating means
    • F24H9/1854Arrangement or mounting of grates or heating means for air heaters
    • F24H9/1863Arrangement or mounting of electric heating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/20Arrangement or mounting of control or safety devices
    • F24H9/2007Arrangement or mounting of control or safety devices for water heaters
    • F24H9/2014Arrangement or mounting of control or safety devices for water heaters using electrical energy supply
    • F24H9/2028Continuous-flow heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/20Arrangement or mounting of control or safety devices
    • F24H9/2064Arrangement or mounting of control or safety devices for air heaters
    • F24H9/2071Arrangement or mounting of control or safety devices for air heaters using electrical energy supply

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)

Abstract

The invention relates to complete energy storage recycling equipment, and belongs to the technical field of energy utilization. An energy storage wall which is built from energy storage bricks is arranged in a shell of the complete energy storage recycling equipment; flow channels are formed among the energy storage bricks of ventilation layers of the energy storage wall, and gaps for arranging electric heating devices are formed among the energy storage bricks of electric heating layers; a hot-air outlet is communicated with an airflow inlet of a plate heat exchanger, an airflow outlet of the plate heat exchanger is communicated with an inlet of a hot-air circulating fan, an outlet of the hot-air circulating fan is communicated with a circulating air inlet, and a hot-air circulating circuit is formed; a water flow outlet of the plate heat exchanger is connected with a water inlet of a heating facility by a circulating water pump, a water outlet of the heating facility is connected with a water flow inlet of the plate heat exchanger, and a hot-water circulating circuit is formed. The complete energy storage recycling equipment has the advantages that the electric heating devices can be powered on under the control in power consumption off-peak periods, so that the energy storage wall can be heated, delivered water can be heated by heat energy, which is stored by the energy storage wall, via the plate heat exchanger when the hot-air circulating fan and the circulating water pump are started, and various heating requirements of industrial drying, drinking water boiling, rice steaming and the like can be met.

Description

A kind of energy storage recycles complete set of equipments
Technical field
The present invention relates to a kind of energy storage device, especially a kind of energy storage recycles complete set of equipments, belongs to technical field of energy utilization.
Background technology
Taking place frequently of haze weather forces energy-saving and emission-reduction imperative.In addition, peak load cutting can take trough-electricity in morning to preserve, and discharges, thus is not only conducive to energy-saving and emission-reduction, can also reduce costs when peak of power consumption.
Retrieval finds, application number be 201310210056 Chinese patent application disclose a kind of trough-electricity high-temperature heat accumulation steam generating system, employing be conduction oil, fused salt, generating equipment needs the steam of 250 DEG C ~ 300 DEG C, heat accumulation 85 DEG C-400 DEG C, its shortcoming is that efficiency and heat utilization rate are lower.Application number be 2008102022758 Chinese patent application disclose a kind of solar energy heat storage device, adopt and reclaim variegated glass making heat storage brick, because heater element is not settled in its inside, therefore only can the solar energy of memory limited, there is larger application limitation.Application number be 2014200235799 Chinese patent application disclose one " electric heating energy-storage brick laying structure ", only disclose the brick laying structure of heat storage brick, do not illustrate that stored energy is how actual and utilize.
Summary of the invention
The object of the invention is to: the shortcoming existed for above-mentioned prior art, propose a kind of can by peak load cutting high-efficiency energy-storage and the energy storage of economical recycles complete set of equipments, conscientiously to apply.
In order to reach above object, energy storage of the present invention recycles complete set of equipments and comprises the housing with circulated air import and hot-blast outlet, is mounted with the energy storage wall that energy storage brick assembles in described housing; Described energy storage wall has ventilating layer spaced apart up and down and electrothermal layer, form the runner extended towards hot-blast outlet direction by circulated air import between the energy storage brick of described ventilating layer, between the energy storage brick of described electrothermal layer, form the space of settling electrothermal device perpendicular to circulated air import to hot-blast outlet direction; Described hot-blast outlet is communicated with the airflow inlet of plate type heat exchanger, the air stream outlet of described plate type heat exchanger and the inlet communication of hot air circulation blower, the outlet of described hot air circulation blower and circulated air inlet communication, forms hot air circulation loop; The water export of described plate type heat exchanger connects the water inlet of heating facility by water circulating pump, the delivery port of described heating facility connects the flow inlet of plate type heat exchanger, forms hot water circulation loop.
Further, described energy storage wall is cuboid, between the top layer that described upper and lower ventilating layer spaced apart and electrothermal layer are clamped in close block and bottom.
Further, the energy storage brick of described ventilating layer and electrothermal layer staggers arrangement up and down.
Like this, in the low power consumption period, control electric heating device electrified regulation energy storage wall, can direct heat energy storage and intermediate storage electric energy.And when opening hot air circulation blower and water circulating pump, the water temperature rising that the heat energy that energy storage wall stores will can carry to heating facility by plate type heat exchanger, thus meet industrial stoving, boil water, the various heating needs such as steamed rice.
The present invention further improves, and also comprises the control circuit containing such as PLC and so on intelligent device and the temperature sensor being placed in described plate type heat exchanger water export side; The temperature signal input of the signal output part connection control circuit of described temperature sensor, the keying control output end of described control circuit and speed regulating control output are connect the power supply controlled end of electrothermal device respectively and are connect the drive motors controlled end of hot air circulation blower by frequency converter, described intelligent device in order to:
Cut-out, closed electrical thermal device power supply is controlled according to electric wind peak, paddy period;
Judge whether the temperature value that receives is in setting range, then keeps present situation in this way, as otherwise slow down or the control signal that raises speed higher or lower than corresponding outputs of setting range according to temperature value;
When exporting deceleration control signal, judge whether to reach setting lower limit, as otherwise control to lower described drive motors rotating speed, then control electrothermal device dump in this way;
When exporting speed-raising control signal, judge whether to reach capping, as otherwise control to promote described drive motors rotating speed, then control electrothermal device power supply in this way closed.
If the present invention and heating facility substantially adaptive, constantly circulate according to this control logic above, automatically can realize not only as far as possible the electric energy of low power consumption period being converted to heat energy accumulation, and the heat energy of satisfying the demand can be exported in real time.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the present invention is further illustrated.
Fig. 1 is the formation schematic diagram of the embodiment of the present invention one.
Fig. 2 is the perspective view of energy storage wall in Fig. 1.
Fig. 3 is the Energy control main circuit diagram of Fig. 1 embodiment.
Fig. 4 is the PLC terminal connection diagram of Fig. 1 embodiment control circuit.
Fig. 5 is the secondary circuit control chart of Fig. 1 embodiment.
Detailed description of the invention
Embodiment one
The energy storage of the present embodiment recycles complete set of equipments as shown in Figure 1, is mounted with the energy storage wall 4 that porcelain rock energy storage brick assembles in the metal shell 1 with circulated air import 3 and hot-blast outlet 7.The shell wall of metal shell 1 has alumina silicate heat-insulation layer 2.Hot-blast outlet 7 is communicated with the airflow inlet of plate type heat exchanger 16, the air stream outlet of this plate type heat exchanger 16 is by the inlet communication of circulation airduct 12 with hot air circulation blower 8, the outlet of this hot air circulation blower 8 is communicated with circulated air import 3 by airduct, thus forms hot air circulation loop.The water export of plate type heat exchanger 16 connects the water inlet of the place heating facility R such as such as hotel, retail shop, office, office building, classroom, laboratory after the outlet pipe 11 that temperature sensor 17 and temp. regulator 14 are housed by high pressured water circuling pump 13, the delivery port of heating facility R connects the flow inlet of plate type heat exchanger by water return pipeline 10, form hot water circulation loop.
The concrete structure of energy storage wall 4 as shown in Figure 2, is the cuboid by the brick one-tenth of porcelain rock energy storage, between the top layer 4-1 and bottom 4-4 of close block, has upper and lower ventilating layer 4-2 spaced apart and electrothermal layer 4-3.Form the runner 4-6 extended towards hot-blast outlet direction by circulated air import between the energy storage brick of ventilating layer 4-2, between the energy storage brick of electrothermal layer 4-3, form the space 4-5 settling electrothermal device 5 perpendicular to circulated air import 3 to hot-blast outlet 7 direction.The porcelain rock energy storage brick of ventilating layer 4-2 and electrothermal layer 4-3 staggers arrangement up and down.Electrothermal device 5 comes from the resistance silk ribbon of 10KV high pressure for power supply.The thermocouple 15 that hot-blast outlet 7 is settled is for monitoring hot blast temperature.Signals collecting in 10KV high voltage power distributing cabinet is in 15, so that temperature control.When adopting 10KV high voltage source, high-pressure section is arranged on nobody-is-safe district, adopts converting equipment to drop to 380V, eliminates expensive transformer, greatly saved cost.10KV power acquisition wye connection, is down to 5773V voltage, then by the method for connecting, the voltage of single channel silk ribbon is down to about 107V, thus both extended service life, be conducive to energy-conserving and environment-protective again, saves manufacturing cost, power bracket 1-100MW.Certainly, place with good conditionsi also can change low pressure into.
The signal output part of temperature sensor 17 connects the temperature signal input be placed in containing the control circuit of PLC in low-voltage distribution cabinet C.The wiring of this control circuit is see Fig. 3, Fig. 4, Fig. 5, and it opens and closes the power supply controlled end that control output end connects electrothermal device, and the speed regulating control output of this control circuit connects the drive motors 1M controlled end of hot air circulation blower 8 by frequency converter.2M is high pressured water circuling pump motor.
PLC is in order to control cut-out, closed electrical thermal device power supply according to electric wind peak, paddy period;
Judge whether the temperature value that receives is in setting range, then keeps present situation in this way, as otherwise slow down or the control signal that raises speed higher or lower than corresponding outputs of setting range according to temperature value;
When exporting deceleration control signal, judge whether to reach setting lower limit, as otherwise control to lower described drive motors rotating speed, then control electrothermal device dump in this way;
When exporting speed-raising control signal, judge whether to reach capping, as otherwise control to promote described drive motors rotating speed, then control electrothermal device power supply in this way closed.
Energy storage brick of the present invention is porcelain rock energy storage brick, is made by following steps:
The first step. pulverize---potsherd and limestone are crushed to particle diameter 20 ~ 35 order respectively;
Second step. mixing---using the pottery after flour and rock grain and as binding agent white clay (i.e. kaolin) by volume part 5:3 ~ 4 (best 3.5): the ratio of 1 ~ 2 (best 1.5) matches, and the water adding gross weight 10-15% (best 13%) stirs mixing;
3rd step. shaping---blank is made in mixed batching mold pressing;
4th step. sintering---keep constant temperature 24 hours (± 2 hours) to be shaped at the temperature sintering of about 1850 DEG C (± 50 DEG C) blank.
The energy storage brick not only twice laid adopting the present invention to make, economical, and pressed density is high, and (proportion can reach 2.30g/CM 3), there is higher thermal capacity, therefore there is desirable heat energy storage ability, and good insulation preformance under high temperature.
During operation, in the low power consumption period at a low price, electrothermal device (the present embodiment is specially electric heating silk ribbon) electrified regulation in energy storage wall, plate type heat exchanger is being passed through by hot air circulation blower, after water circulation system heat exchange, to heating facility heating while, also by unnecessary heat storage in energy storage wall.In the peak of power consumption period of high price, although electrothermal device power-off stops heating, the heat being stored in energy storage wall still can continue heating hot water by plate type heat exchanger, thus maintains the heat demand meeting heating facility; Only have when off-position really cannot by hot water heating to about 80 DEG C time, just temporarily electrified regulation, therefore operating cost economy, and be conducive to energy-conserving and environment-protective.Such as, low ebb electricity price before somewhere morning is 0.39 yuan/degree, and the electricity price 1.39 yuan in morning 7.30 to 12,12 is 1.15 yuan/degree to 0.91 yuan of average electricity price at midnight, and price difference is 1.15 yuan-0.39 yuan=0.76 yuan, and the heat therefore often storing up kilowatt-hour just can fall this about 0.76 yuan.

Claims (5)

1. energy storage recycles a complete set of equipments, comprises the housing with circulated air import and hot-blast outlet, is mounted with the energy storage wall that energy storage brick assembles in described housing; Described energy storage wall has ventilating layer spaced apart up and down and electrothermal layer, form the runner extended towards hot-blast outlet direction by circulated air import between the energy storage brick of described ventilating layer, between the energy storage brick of described electrothermal layer, form the space of settling electrothermal device perpendicular to circulated air import to hot-blast outlet direction; Described hot-blast outlet is communicated with the airflow inlet of plate type heat exchanger, the air stream outlet of described plate type heat exchanger and the inlet communication of hot air circulation blower, the outlet of described hot air circulation blower and circulated air inlet communication, forms hot air circulation loop; The water export of described plate type heat exchanger connects the water inlet of heating facility by water circulating pump, the delivery port of described heating facility connects the flow inlet of plate type heat exchanger, forms hot water circulation loop.
2. a kind of energy storage according to claim 1 recycles complete set of equipments, it is characterized in that: described energy storage wall is cuboid, between the top layer that described upper and lower ventilating layer spaced apart and electrothermal layer are clamped in close block and bottom.
3. a kind of energy storage according to claim 2 recycles complete set of equipments, it is characterized in that: the energy storage brick of described ventilating layer and electrothermal layer staggers arrangement up and down.
4. a kind of energy storage according to claims 1 to 3 recycles complete set of equipments, it is characterized in that: also comprise containing intelligent device control circuit and be placed in the temperature sensor of described plate type heat exchanger water export side; The temperature signal input of the signal output part connection control circuit of described temperature sensor, the keying control output end of described control circuit and speed regulating control output are connect the power supply controlled end of electrothermal device respectively and are connect the drive motors controlled end of hot air circulation blower by frequency converter, described intelligent device in order to:
Cut-out, closed electrical thermal device power supply is controlled according to electric wind peak, paddy period;
Judge whether the temperature value that receives is in setting range, then keeps present situation in this way, as otherwise slow down or the control signal that raises speed higher or lower than corresponding outputs of setting range according to temperature value;
When exporting deceleration control signal, judge whether to reach setting lower limit, as otherwise control to lower described drive motors rotating speed, then control electrothermal device dump in this way;
When exporting speed-raising control signal, judge whether to reach capping, as otherwise control to promote described drive motors rotating speed, then control electrothermal device power supply in this way closed.
5. a kind of energy storage according to claim 4 recycles complete set of equipments, it is characterized in that: described energy storage brick is made by following steps:
The first step. pulverize---potsherd and limestone are crushed to particle diameter 20 ~ 35 order respectively;
Second step. mixing---the ratio of the pottery after flour and rock grain and white clay by volume part 5:3 ~ 4:1 ~ 2 matched, the water adding gross weight 10-15% stirs mixing;
3rd step. shaping---blank is made in mixed batching mold pressing;
4th step. sintering---the temperature of blank at 1850 ± 50 DEG C is sintered and keep constant temperature to be shaped for 24 ± 2 hours.
CN201610056299.1A 2016-01-27 2016-01-27 Complete energy storage recycling equipment Pending CN105509318A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610056299.1A CN105509318A (en) 2016-01-27 2016-01-27 Complete energy storage recycling equipment

Publications (1)

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CN105509318A true CN105509318A (en) 2016-04-20

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106369663A (en) * 2016-08-30 2017-02-01 镇江裕太防爆电加热器有限公司 Multifunctional energy storage circulation device
CN106382672A (en) * 2016-08-30 2017-02-08 镇江裕太防爆电加热器有限公司 Integrated type energy-storage circulating device
CN107504505A (en) * 2017-08-28 2017-12-22 镇江裕太防爆电加热器有限公司 A kind of energy-saving circulating utilizes tail gas treatment device
CN111156846A (en) * 2018-11-07 2020-05-15 郑州尚格新能源有限公司 Heat storage unit, heat storage heating device and vehicle using heat storage heating device

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2458835A (en) * 1945-05-29 1949-01-11 Accuheat Electric Heating apparatus
CH344543A (en) * 1956-03-28 1960-02-15 Elektrische Anlagen Ag Ges Method for heating liquids, in particular water for heating or utility purposes, by means of storage heat and a device for carrying out the method
CN101265076A (en) * 2008-04-17 2008-09-17 淄博嘉环耐火材料有限公司 Lightweight magnesia brick for heat regenerator and manufacturing method thereof
CN101713564A (en) * 2009-12-08 2010-05-26 朱宇辉 High-voltage heat accumulating and heating device
CN202133111U (en) * 2011-07-19 2012-02-01 朱杰 Closed hot-air circulation high-temperature solid heat-accumulation electric water heater unit
CN102954586A (en) * 2011-08-30 2013-03-06 朱杰 Heating and refrigeration system of mobile high-temperature solid heat accumulation electric boiler
CN204693827U (en) * 2015-03-09 2015-10-07 马越焦 Electrical heat-storing device
CN105004053A (en) * 2015-07-17 2015-10-28 东南大学 High-temperature thermal storage valley energy utilization device with fused salt packaged by ferro magnesium bricks
CN105091337A (en) * 2015-09-02 2015-11-25 沈阳工业大学 Brick structure with electric heating energy storage function
CN205481750U (en) * 2016-01-27 2016-08-17 镇江裕太防爆电加热器有限公司 Energy storage cyclic utilization complete sets

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2458835A (en) * 1945-05-29 1949-01-11 Accuheat Electric Heating apparatus
CH344543A (en) * 1956-03-28 1960-02-15 Elektrische Anlagen Ag Ges Method for heating liquids, in particular water for heating or utility purposes, by means of storage heat and a device for carrying out the method
CN101265076A (en) * 2008-04-17 2008-09-17 淄博嘉环耐火材料有限公司 Lightweight magnesia brick for heat regenerator and manufacturing method thereof
CN101713564A (en) * 2009-12-08 2010-05-26 朱宇辉 High-voltage heat accumulating and heating device
CN202133111U (en) * 2011-07-19 2012-02-01 朱杰 Closed hot-air circulation high-temperature solid heat-accumulation electric water heater unit
CN102954586A (en) * 2011-08-30 2013-03-06 朱杰 Heating and refrigeration system of mobile high-temperature solid heat accumulation electric boiler
CN204693827U (en) * 2015-03-09 2015-10-07 马越焦 Electrical heat-storing device
CN105004053A (en) * 2015-07-17 2015-10-28 东南大学 High-temperature thermal storage valley energy utilization device with fused salt packaged by ferro magnesium bricks
CN105091337A (en) * 2015-09-02 2015-11-25 沈阳工业大学 Brick structure with electric heating energy storage function
CN205481750U (en) * 2016-01-27 2016-08-17 镇江裕太防爆电加热器有限公司 Energy storage cyclic utilization complete sets

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106369663A (en) * 2016-08-30 2017-02-01 镇江裕太防爆电加热器有限公司 Multifunctional energy storage circulation device
CN106382672A (en) * 2016-08-30 2017-02-08 镇江裕太防爆电加热器有限公司 Integrated type energy-storage circulating device
CN107504505A (en) * 2017-08-28 2017-12-22 镇江裕太防爆电加热器有限公司 A kind of energy-saving circulating utilizes tail gas treatment device
CN107504505B (en) * 2017-08-28 2024-03-22 镇江裕太防爆电加热器有限公司 Energy-saving type recycling tail gas treatment equipment
CN111156846A (en) * 2018-11-07 2020-05-15 郑州尚格新能源有限公司 Heat storage unit, heat storage heating device and vehicle using heat storage heating device

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