CN105506812A - Graphene smart clothes - Google Patents
Graphene smart clothes Download PDFInfo
- Publication number
- CN105506812A CN105506812A CN201511025777.4A CN201511025777A CN105506812A CN 105506812 A CN105506812 A CN 105506812A CN 201511025777 A CN201511025777 A CN 201511025777A CN 105506812 A CN105506812 A CN 105506812A
- Authority
- CN
- China
- Prior art keywords
- graphene
- graphene film
- sputtering
- mechanical stripping
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 256
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 181
- 239000000758 substrate Substances 0.000 claims abstract description 99
- 239000002103 nanocoating Substances 0.000 claims abstract description 42
- 238000004544 sputter deposition Methods 0.000 claims abstract description 42
- 238000012544 monitoring process Methods 0.000 claims abstract description 22
- 238000013480 data collection Methods 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 239000004744 fabric Substances 0.000 claims abstract description 15
- 238000012545 processing Methods 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- 239000004952 Polyamide Substances 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920002647 polyamide Polymers 0.000 claims abstract description 7
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 229920005594 polymer fiber Polymers 0.000 claims abstract description 7
- -1 polypropylene Polymers 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 84
- 229910002804 graphite Inorganic materials 0.000 claims description 65
- 239000010439 graphite Substances 0.000 claims description 65
- 230000008569 process Effects 0.000 claims description 60
- 239000002994 raw material Substances 0.000 claims description 42
- 239000000463 material Substances 0.000 claims description 32
- 206010037660 Pyrexia Diseases 0.000 claims description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 27
- 238000011065 in-situ storage Methods 0.000 claims description 22
- 239000000835 fiber Substances 0.000 claims description 20
- 238000005119 centrifugation Methods 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 16
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 8
- 239000011261 inert gas Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000005477 sputtering target Methods 0.000 claims description 7
- 239000013077 target material Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 6
- 238000009941 weaving Methods 0.000 claims description 6
- 230000009471 action Effects 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 5
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 238000005411 Van der Waals force Methods 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 230000006698 induction Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000007596 consolidation process Methods 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 238000005538 encapsulation Methods 0.000 claims description 3
- 239000013307 optical fiber Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 7
- 230000036760 body temperature Effects 0.000 abstract description 3
- 230000005855 radiation Effects 0.000 abstract description 3
- 230000004060 metabolic process Effects 0.000 abstract description 2
- 230000004089 microcirculation Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000011897 real-time detection Methods 0.000 abstract 1
- 239000004020 conductor Substances 0.000 description 25
- 239000010410 layer Substances 0.000 description 21
- 239000011889 copper foil Substances 0.000 description 13
- 239000012528 membrane Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000005670 electromagnetic radiation Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 206010053615 Thermal burn Diseases 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000003486 chemical etching Methods 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 238000000554 physical therapy Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 201000002481 Myositis Diseases 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000004210 Pressure Ulcer Diseases 0.000 description 1
- 206010043189 Telangiectasia Diseases 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 230000000202 analgesic effect Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 238000007603 infrared drying Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000009056 telangiectasis Diseases 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/06—Thermally protective, e.g. insulating
- A41D31/065—Thermally protective, e.g. insulating using layered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/145—Carbon only, e.g. carbon black, graphite
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/34—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
- H05B3/36—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs heating conductor embedded in insulating material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention relates to graphene smart clothes. The smart clothes are characterized in comprising a temperature monitoring part, a graphene heating sheet made by taking polyester, polypropylene or polyamide polymer fiber cloth as a substrate, and a data collection and processing part, wherein the graphene heating sheet comprises a graphene film which is arranged on the flexible substrate and is generated on the basis of a small mechanically-stripped graphene film in a solid carbon source sputtering way, and a nano-scale coating circuit obtained by taking the graphene film as a substrate in a sputtering or imprinting way; the intelligent clothes control the graphene heating sheet to emit heat based on monitoring data of the temperature monitoring part and control data of the data collection and processing part. The smart clothes have the characteristics of convenience in use and realization of real-time detection and control on human body temperature; moreover, far infrared radiation emitted by the graphene heating sheet is harmless to a human body, and good medical care effects of improving the body microcirculation system and promoting the metabolism are achieved.
Description
Technical field
The present invention relates to a kind of body temperature monitoring and compensate intelligent dress ornament, particularly relating to a kind of Graphene intelligence dress ornament.
Background technology
Intelligent clothing is long-standing, is mainly used in the leading-edge field such as aviation and military affairs at first.1989, the Gao Mujun of Japan should teach and information science is melted into material property and function, first proposes the concept of intellectual material.The nineties in 20th century MIT (MassachusettsInstituteofTechnology, the Massachusetts Institute of Technology) since the wearable multimedia computer of Media Lab comes out, Chinese scholars starts the research paying close attention to wearable technology and intelligent clothing gradually.
Along with growth in the living standard, people are no longer confined to comfortableness and fashion for the requirement of clothes, but hope can by wearing the object that clothes reach personal health nursing, amusement or exchange with other people.The development of modern electronic technology, sensing technology and material science etc. is simultaneously also for the progress of intelligent clothing provides multi-disciplinary technical support.The technical development of different field is that the research of intelligent clothing provides various method, but still rare for the research of intelligent clothing design general modfel.Intelligent clothing is the combination of electronics and fashion industry, but there is disequilibrium again in the two, the design of existing intelligent clothing often biases toward electronic technology, and possesses poor aesthetic property and comfortableness, and this and intelligent clothing Design Mode not yet maturation have comparatively Important Relations.
The realization of the intelligent functions of the intelligent clothing of current exploitation is mainly through 3 kinds of approach: (1) some intelligent fiber or modified fibre are enrolled fabric or woven into fabric makes clothes have intelligent characteristic; (2) by some SMART MATTER microencapsulation, be worked on fabric by methods such as dyeing and finishing processing or coatings; (3) method by inweaving or embedding makes electronic component combine with fabric, makes intelligent clothing.
A kind of temperature-regulation garment of patent of invention (application number: 201310358761.X) relates to a kind of based on can the temperature-regulation garment of variable resistance, comprises the garment surface bed of material, flexible semiconductor thermoelectric, garment lining layer, converter, tunable load, controller and external power supply connector.Flexible semiconductor thermoelectric is placed between garment surface bed of material kimonos fitted lining nexine, and flexible semiconductor thermoelectric connects tunable load or connection control device and external power supply connector successively by converter, and converter realizes the switching of annexation.This invention temperature regulates strong adaptability, and the alternating temperature in certain limit is based on the change of clothes self thermal resistance, and without the need to energy consumption, but the heater element flexible semiconductor focus array of this invention is made up of semi-conductor thermoelectric material.Described semi-conductor thermoelectric material generates heat based on electromagnetic radiation mode, is heated by electromagnetic radiation, exist electrothermal calefactive rate slow, with the shortcoming such as Body contact scope is little; And electromagnetic radiation can cause high-intensity microwave Continuous irradiation can make the rising of people's heart rate, blood pressure, accelerated breathing, pants, perspiration etc., and long-time dress there will be problem human body being had to side effect on the contrary.
Summary of the invention
For the deficiency of prior art, the invention provides a kind of Graphene intelligence dress ornament, it is characterized in that, described intelligent dress ornament comprises temperature monitoring portion, the Graphene fever tablet prepared for substrate with polyester, polypropylene or polyamide polymer fiber weaving cloth and data collection process portion;
Graphene fever tablet comprise flexible substrate is arranged on the basis of the small pieces graphene film through mechanical stripping through the solid carbon source sputtering graphene film that generates of mode and be the nanoscale coating circuit that substrate generates through sputtering mode with graphene film; Described intelligent dress ornament data collection process portion controls the Graphene fever tablet heating of described intelligent dress ornament based on the Monitoring Data of the hygrosensor in the fixed structure be on described substrate, wherein, for locating conducting electricity and the microstructure of adhesive force is formed in same procedure for improving of the fixed structure of described temperature monitoring portion hygrosensor and described substrate.
According to a preferred embodiment, the described graphene film generated through solid carbon source sputtering mode is from choosing a small pieces graphene film in advance through the described small pieces graphene film of the generation of mechanical stripping, described small pieces graphene film is transferred on temporary flexible substrate as induction graphene film growth starting point, on described substrate with small pieces graphene film for starting point adopt solid carbon source generate graphene film through sputtering mode.
According to a preferred embodiment, the production procedure through the described small pieces graphene film of mechanical stripping generation is:
High-temperature process portion is connected with in-situ reducing portion, adds nitrogen or inert gas carries out high-temperature process to graphite raw material under treatment temperature is 200 DEG C ~ 1200 DEG C conditions;
Described in-situ reducing portion is connected with mechanical stripping portion by the first feed pipe, receive the graphite raw material after the process of described high-temperature process portion, under 200 DEG C ~ 1200 DEG C temperature conditions, add at least one in nitrogen or hydrogen as reducing medium, reduction treatment is carried out to Graphene raw material, and the raw material after process is sent into mechanical stripping portion;
Described dosing portion is connected with described mechanical stripping portion by the second feed pipe, and described dosing portion is used for depositing surfactant additive, and carries out in stripping process in described mechanical stripping portion to graphite raw material, continues the cylindrical chamber's dosing to mechanical stripping portion;
The cylindrical chamber in described mechanical stripping portion is connected with in-situ reducing portion by the first feeding-passage, the cylindrical chamber in described mechanical stripping portion is connected with dosing portion by the second feeding-passage, turning cylinder is connected with rotating horizontal pole is vertical in cylindrical cavity indoor, it is indoor that abrading-ball is placed in described cylindrical cavity, and described abrading-ball is diameter 50 μm ~ 100 μm and hardness is greater than the pearl of graphite; The cylindrical chamber in described mechanical stripping portion is connected with centrifugation portion by discharging channel;
After described in-situ reducing portion to add graphite raw material to described cylindrical chamber and described dosing portion (304) adds surfactant additive to described cylindrical chamber, described turning cylinder drives square with the axis connected rotating horizontal pole in the indoor stirring of fixing cylindrical cavity, rotating horizontal pole drives the abrading-ball in cavity and graphite raw material mutually collide and rub in stirring, graphite raw material is under the shear action of described abrading-ball frictional force, in graphite, the Van der Waals force of each graphite layers is disintegrated, and obtains the turbid liquid of Graphene and graphite;
The turbid liquid of Graphene and graphite is sent into centrifugation portion by discharging channel by the cylindrical chamber in described mechanical stripping portion, through described centrifugation portion centrifugal treating, obtain Graphene turbid liquid, and send into drying section carry out drying process, obtain small pieces graphene film.
According to a preferred embodiment, described nanoscale coating circuit is the graphene film be adhered in flexible substrate with circuit die is put into magnetron sputtering apparatus as base material carry out the sputtering of nanoscale coating.
According to a preferred embodiment, described nanoscale coating circuit is: be adhered to sputtering generation copper film on the graphene film in flexible substrate, then by impression mode, generating nanoscale coating circuit.
According to a preferred embodiment, described coating sputter procedure magnetic control sputtering device sputtering operating pressure controls at 0.13Pa ~ 0.20Pa, base material temperature is less than 50 DEG C, target and base material distance 5cm ~ 10cm, sputtering 5 ° ~ 8 °, angle, sputtering power 100W ~ 200W, sputtering zinc coat thickness control is 50nm ~ 300nm, adopt base material upper sputtering target material structure.
According to a preferred embodiment, put into plasma processor to the described graphene film being adhered to flexible substrate, adopt oxygen, carry out sputter process carry out preliminary treatment in 60 seconds under the condition of power 50 watts after, sputtering target material comprises metallic aluminium, copper or silver.
According to a preferred embodiment, adopt the method for cored and looping that conductive fiber is made yarn, inweaved in polyester, polypropylene or polyamide polymer fiber weaving cloth fabric.
According to a preferred embodiment, described temperature monitoring portion comprises hygrosensor and distributed A/D acquisition module, and described temperature monitoring portion is connected with data collection process portion by described optical fiber conductive fiber; Data processing division comprises single-chip microcomputer, wireless data transmitter, mobile terminal, distributed digital input/output module and power conditioning module, and described data processing division is connected with Graphene fever tablet by described optic fibre wire.
According to a preferred embodiment, epoxy encapsulation is adopted to Graphene fever tablet, temperature detecting part, data collection process portion, conductive fiber and temperature monitoring portion, data collection process portion and Graphene fever tablet coupling part rubber or plastic consolidation waterproof.
Graphene intelligence dress ornament of the present invention at least has following advantage:
(1) because Graphene fever tablet has ultra-thin, light characteristic, therefore it can not have an impact to the outward appearance of the intelligent dress ornament heated based on Graphene.
(2) infra-red radiation of Graphene fever tablet generation, has good medical treatment and physiotherapy function.Grapheme material can launch far infrared life light wave, has almost identical frequency spectrum with human body, can effectively activate the biomolecule such as soma nucleic acid, protein, reach and improve blood circulation, anti-inflammatory, analgesic activity.
(3) Graphene fever tablet programming rate is fast.The heat energy that the mutual frictional impact of carbon atom of Graphene produces can make Graphene fever tablet rapid temperature increases in 3 seconds, only needs can be warming up to 35 DEG C in 10 seconds, therefore just can experience warm while putting on it.
Accompanying drawing explanation
Fig. 1 is the present invention's intelligence dress ornament high-level schematic functional block diagram;
Fig. 2 is Graphene fever tablet structural representation of the present invention;
Fig. 3 is mechanical stripping legal system small pieces graphene film schematic flow sheet of the present invention;
Fig. 4 is the mechanical stripping portion structural representation of mechanical stripping legal system small pieces graphene film of the present invention;
Fig. 5 shows the graphene film be adhered in flexible substrate covering copper film putting into forcing press;
Fig. 6 shows the graphene film being produced, be provided with three-dimensionally shaped printed conductor by the moulding process of Fig. 5.
Reference numerals list
101: hygrosensor 102: distributed A/D acquisition module 103: single-chip microcomputer
104: wireless data transmitter 105: mobile terminal 106: distributed digital input/output module
107: power conditioning module 108: Graphene fever tablet 201: overcoat
202: nanoscale coating circuit 203: graphene film 204: adhensive membrane
205: flexible substrate 301: graphite raw material 302: high-temperature process portion
303: in-situ reducing portion 304: dosing portion 305: centrifugation portion
306: drying section 307: graphene film 400: mechanical stripping portion
401: cylindrical chamber 402: the first feeding-passage 403: the second feeding-passage
404: turning cylinder 405: rotating horizontal pole 406: abrading-ball
407: discharging channel 501: substrate 502: micro-structural
503: copper film 504: impressing mould 505: stamping structure
506: forcing press 507: printed conductor 508: printed conductor plane
509: printed conductor sidewall 510: substrate trenches 511: bottom substrate trenches
512: protruding substrate plane 513: substrate sidewall 514: fixed structure
Detailed description of the invention
Be described in detail below in conjunction with drawings and Examples.
As shown in Figure 1, the functional module of Graphene intelligence dress ornament of the present invention comprises: temperature detecting part, Graphene fever tablet 108 and data processing division.Wherein said temperature monitoring portion comprises hygrosensor 101 and distributed A/D acquisition module 102; Data processing division comprises single-chip microcomputer 103, wireless data transmitter 104, mobile terminal 105, distributed digital input/output module 106 and power conditioning module 107.Described hygrosensor 101 is connected with distributed A/D acquisition module 102, for Real-time Collection human body temperature data, and the temperature data of collection is sent to distributed A/D acquisition module 102.Described distributed A/D acquisition module 102 is connected with single-chip microcomputer 103, and the temperature data of collection is transferred to single-chip microcomputer 103.Described single-chip microcomputer 103 is connected with heating power adjustment module 107 by distributed digital input/output module, and is connected with mobile terminal 105 by wireless data transmitter 104.The heating-up temperature that the temperature data collected and mobile terminal 105 are arranged is analyzed by described single-chip microcomputer 103, when the heating-up temperature that temperature is arranged lower than described mobile terminal 105 time, heating signal to be transferred to power conditioning module 107 by distributed input/output module and controls Graphene fever tablet 108 and heat by single-chip microcomputer 103.Meanwhile, human body real time temperature is sent to mobile terminal 105 through wireless data transmitter 104 by described single-chip microcomputer 103.User can also control Graphene fever tablet 108 according to health real-time condition by mobile terminal 105 and heat.
Intelligent dress ornament of the present invention adopts polyester, polypropylene or polyamide polymer fiber weaving cloth fabric, and adopts the method for cored and looping that conductive fiber is made yarn, is inweaved in polyester, polypropylene or polyamide polymer fiber weaving cloth fabric.Described temperature monitoring portion is connected with data collection process portion by described optical fiber conductive fiber; Described data processing division is connected with Graphene fever tablet 108 by described optic fibre wire.And epoxy encapsulation is adopted to Graphene fever tablet 108, temperature detecting part, data collection process portion.Conductive fiber and temperature monitoring portion, data collection process portion and Graphene fever tablet 108 coupling part rubber or plastic consolidation waterproof.
Shown in composition graphs 1 and Fig. 2, Graphene fever tablet 108 of the present invention comprises flexible substrate 205, described flexible substrate 205 arranges graphene film 203, graphene film 203 is arranged in flexible substrate 205 by adhensive membrane 204, described graphene film 203 is provided with the nanoscale coating circuit 202 generated through sputtering, and described nanoscale coating circuit 202 is electrically connected with graphene film 203; Described nanoscale coating circuit 202 is electrically connected with conductive fiber, and is connected with data collection process portion by conductive fiber.Graphene film 203 and nanoscale coating circuit 202 are coated with overcoat 201, and described overcoat 201 covers the junction of nanoscale coating and conductive fiber simultaneously.
The structure of the electrical-heating film of said structure, can be prepared by following technique, comprise particularly: provide flexible substrate 205, and in described flexible substrate 205 coated with adhesive film 204; The material of described flexible substrate 205 comprises PET film, in order to improve the required adhesive force forming print surface of flexible substrate 205, the printing surface of flexible substrate 205 carries out corona treatment or chemical attack frosted process, and then adhensive membrane 204 is coated on the printing surface of flexible substrate 205.Transfer in flexible substrate 205 by described graphene film 203, graphene film 203 is connected with flexible substrate 205 by adhensive membrane 204; On above-mentioned graphene film 203, sputtering generates nanoscale coating circuit 202; Above-mentioned nanoscale coating circuit 202 prints electrode, and described electrode is used for realizing nanoscale coating circuit 202 and is electrically connected with conductive fiber.At above-mentioned printed on electrodes overcoat 201, described overcoat 201 covers on electrode, and covers on graphene film 203 and nanoscale coating circuit 202.Described overcoat 201 has anti-scratch ability.
Flexible substrate 205 is installed on unwinding equipment in the mode of entire volume, continuously, so equidistant that to move to printing position, exactitude position is realized by color mark sensor, the chromatography of multiple pattern can be carried out, after printing, flexible substrate 205 enters rotary drying, carries out rolling for as intelligent dress ornament fever tablet after sufficient infra-red drying.
Because Graphene fever tablet 108 has ultra-thin, light characteristic, therefore it can not have an impact to the outward appearance of the intelligent dress ornament heated based on Graphene.The infra-red radiation that Graphene fever tablet 108 produces, has good medical treatment and physiotherapy function.Grapheme material can launch far infrared life light wave, after far infrared is absorbed by the body, hydrone in body can be made to produce resonance, make water molecule activation, strengthen its intermolecular adhesion, thus the large biological molecules such as activation of protein, make biological cell be in the highest vibration level.Because biological cell produces resonance effects, far infrared heat energy can be delivered to the subcutaneous darker part of human body, following deep layer temperature rises, and the warm of generation is distributed from inside to outside.This action intensity, makes telangiectasis, stimulates circulation, and strengthens the metabolism between each tissue, increases the power of regeneration of tissue, improves the immunocompetence of body, regulates the exaltation state of spirit, thus plays the effect of health care.In general, the infrared ray that fuel combustion, electric heating appliance thermal source etc. are released belongs near infrared ray more, because wavelength is shorter, therefore produces a large amount of fuel factors, can produce the injury such as skin ambustion and eyes crystalline after long-term irradiation human body.Shorter other electromagnetic wave of wavelength, as ultraviolet, X-ray and gamma-rays etc., can make the electronics on atom produce free, more have injury effect to human body.Far infrared is quite different, and because wavelength is longer, energy is relatively low, thus use time relatively less scald harm.
The low-frequency electromagnetic wave that far infrared also radiates with household electrical appliance is different, and the low-frequency electromagnetic wave that household electrical appliance disengage can wall through walls and change the characteristic of body current, and by its harmfulness of people's strong suspicion.Far infrared only has 0.01 to 0.1 centimetre in the penetration power of human body skin, and human body itself also can the far infrared of emit wavelength about 9 microns, so and low-frequency electromagnetic wave can not lump together.Far infrared is used in the auxiliary curing of numerous disease, and such as muscles and bones msuscle soreness, myotenositis, bedsore, scald and wound such as not easily to heal at the disease, can utilize the characteristic that far infrared stimulates circulation, and reach the object of auxiliary curing.
The preparation method of large-area graphene film adopts to select a small pieces graphene film 307 from the graphene film produced through mechanical stripping in advance, the small pieces graphene film 307 chosen is positioned on the substrate being adapted to graphene film particular application technology, utilizes the carbon atom discharged in the solid carbon source material come from containing carbon atom at temporary flexible Grown graphene film 203.
Described small pieces graphene film 307 selects the graphene film in being generated by micromechanics stripping means.Shape as the graphene film sheet bringing out graphene film growth is square, rectangle, circle, ellipse or irregular type; The number of plies as the graphene film sheet bringing out graphene film growth is 1 layer to 200 layers, and optimum is 1 layer to 20 layers, and the most optimum is 1 layer to 5 layers; Area as the small pieces graphene film 307 bringing out graphene film growth is 1nm
2to 50000cm
2, optimum is 1nm
2to 1000cm
2, the most optimum is 1nm
2to 100 μm
2.Described backing material is be applicable to the inorganic of graphene film particular application technology or organic conductor, semiconductor, insulator or its composite.The number of plies of the described graphene film at Grown is 1 layer to 200 layers, and optimum is 1 layer to 20 layers, and the most optimum is 1 layer to 5 layers.
Described nanoscale coating circuit 202 is the graphene film 203 be adhered in flexible substrate 205 with circuit die is put into magnetron sputtering apparatus as base material carry out the sputtering of nanoscale coating.Plasma processor is put into the described flexible substrate 205 that is adhered to circuit die, adopts oxygen, under the condition of power 50 watts, carry out preliminary treatment in 60 seconds.Described coating sputter procedure magnetic control sputtering device sputtering operating pressure controls at 0.13Pa ~ 0.20Pa, base material temperature is less than 50 DEG C, target and base material distance 5cm ~ 10cm, sputtering 5 ° ~ 8 °, angle, sputtering power 100W ~ 200W, sputtering zinc coat thickness control is 50nm ~ 300nm, adopt base material upper, sputtering target material structure.The material of nanoscale coating circuit 202 comprises aluminium, copper or silver, the frame structure that nanoscale coating circuit 202 is formed by some lines.The electrothermal film material that nanoscale coating circuit 202 and graphene film 203 form, has the advantages that thickness is little, pliability is high.Graphene film 203 be individual layer carbon atom composition there is cellular hexagonal two dimensional crystal structure, the nanoscale coating circuit 202 good with pliability is combined, nanoscale coating circuit 202 strengthens the connectivity of graphite and graphite, fill up the grid between all blank, the electric conductivity that electrothermal film material is good can be ensured, quality is light, cheap.The material of flexible substrate 205 comprises PET (Polyethyleneterephthalate).Graphene film 203 and nanoscale coating circuit 202 can produce required heating heat.
As shown in Figure 3 and Figure 4, the device of mechanical stripping method generation graphene film of the present invention comprises high-temperature process portion 302, in-situ reducing portion 303, dosing portion 304, mechanical stripping portion 400, centrifugation portion 305, drying section 306.Described high-temperature process portion 302 is connected with in-situ reducing portion 303, and high-temperature process portion 302 carries out high-temperature process to the graphite raw material 301 added wherein, and the graphite raw material 301 after process is delivered to in-situ reducing portion 303.High-temperature process temperature is 200 DEG C ~ 1200 DEG C, and processing environment remains air, vacuum, nitrogen or inert gas.One preferred embodiment for processing environment in high-temperature process remains inert gas environment.Graphite raw material 301 is heated to 200 DEG C ~ 1200 DEG C under inert gas shielding, and oxygen-containing functional group stability declines, and leaves with the form such as steam, carbon dioxide.In-situ reducing portion 103 is connected with mechanical stripping portion 400 with high-temperature process portion 302.In-situ reducing portion 303 accepts the graphite raw material 301 after high-temperature process portion 302 processes, and carries out reduction treatment to it, and the graphite raw material 301 after process delivers to mechanical stripping portion 400.In position in reduction portion 303, under 200 DEG C ~ 1200 DEG C temperature conditions, add at least one in nitrogen or hydrogen as reducing medium, reduction treatment is carried out to graphite raw material 301, remove the oxygen-containing functional group in graphite raw material 301 further.Dosing portion 304 is connected with mechanical stripping portion 400.Dosing portion 304 for depositing surfactant additive, and carries out, in stripping process, continuing to mechanical stripping portion 400 dosing at 400 pairs, described mechanical stripping portion graphite raw material 301.Surfactant additive is one or more in lauryl sodium sulfate, methyl anyl alcohol, sodium oxalate, sodium carboxymethylcellulose pyce, polyacrylamide, guar gum, fatty acid polyethylene glycol ester.Mechanical stripping portion 400 is connected with centrifugation portion 105.Mechanical stripping portion 400 for receive in-situ reducing portion 303 reduction treatment after graphite raw material 301 and the surfactant that provides of dosing portion 304, and the stripping of stirring ball milling is carried out to the graphite raw material 301 received, and the mixing turbid liquid of the Graphene after lift-off processing and graphite is sent into centrifugation portion 305.Centrifugation portion 305 is connected with drying section 306.The mixing turbid liquid of centrifugation portion 305 to the Graphene entered wherein and graphite carries out centrifugal treating, to Graphene turbid liquid, and send into drying section 306.Drying section 306 carries out drying process to the Graphene turbid liquid entered wherein, finally obtains graphene film 307.
Fig. 4 is mechanical stripping portion of the present invention structural representation.Shown in 2, mechanical stripping portion 400 comprises cylindrical chamber 401, first feeding-passage 402, second feeding-passage 403, turning cylinder 404, rotating horizontal pole 405 and abrading-ball 406.The cylindrical chamber 401 in mechanical stripping portion 400 is connected with in-situ reducing portion 303 by the first feeding-passage 402, the cylindrical chamber 401 in described mechanical stripping portion 400 is connected with dosing portion 304 by the second feeding-passage 403, turning cylinder 404 is connected with rotating horizontal pole 405 is vertical in cylindrical chamber 401, abrading-ball 406 is placed in described cylindrical chamber 401, and described abrading-ball 406 is diameter 50 μm ~ 100 μm and hardness is greater than the pearl of graphite.The cylindrical chamber 401 in described mechanical stripping portion 400 is connected with centrifugation portion 305 by discharging channel 407.In-situ reducing portion 303 adds graphite raw material 301 by the first feeding-passage 402 to the cylindrical chamber 401 in mechanical stripping portion 400.Dosing portion 304 adds surfactant additive by the second charging aperture 403 to the cylindrical chamber 401 in mechanical stripping portion 400.Turning cylinder 404 drives the rotating horizontal pole 405 that be connected vertical with turning cylinder 204 to stir in cylindrical chamber 401.Rotating horizontal pole 405 drives the abrading-ball 406 in cylindrical chamber 401 and graphite raw material 301 mutually to collide and friction in stirring, graphite raw material 301 is under the shear action of described abrading-ball 406 frictional force, in graphite, the Van der Waals force of each graphite layers is disintegrated, and obtains the turbid liquid of Graphene and graphite.
Embodiment 1
Composition graphs 3 and Fig. 4 illustrate that mechanical stripping method of the present invention produces the production process of graphene film.High-temperature process portion 302 is connected with in-situ reducing portion 303, high-temperature process portion 302 carries out 1 hour high-temperature process to the graphite raw material 301 added wherein under 1000 DEG C of high temperature and inert gas treatment environment, and the graphite raw material 301 after process is delivered to in-situ reducing portion 303.Graphite raw material 301 is heated to 1000 DEG C under inert gas shielding, and oxygen-containing functional group stability declines, and leaves Graphene raw material 301 with the form such as steam, carbon dioxide.In-situ reducing portion 303 is connected with high-temperature process portion 302, and is connected with the cylindrical chamber 401 in mechanical stripping portion 400 by the first feeding-passage 402.In-situ reducing portion 303 accepts the graphite raw material 301 after high-temperature process portion 302 processes, and under 1000 DEG C of temperature conditions, add at least one in nitrogen or hydrogen as reducing medium, carry out reduction treatment in 1 hour to it, the graphite raw material 301 after process delivers to the cylindrical chamber 401 in mechanical stripping portion 400.Graphite raw material 301 carries out reduction treatment, will remove the oxygen-containing functional group in graphite raw material 301 further.Dosing portion 304 is connected with the cylindrical chamber 401 in mechanical stripping portion 400 by the second feeding-passage 403.Dosing portion 304 for depositing surfactant additive, and carries out in stripping process at 400 pairs, described mechanical stripping portion graphite raw material 301, continues to add lauryl sodium sulfate to mechanical stripping portion 400 and water is made into the slurry that concentration is 80.0%.The turning cylinder 404 in mechanical stripping portion 400 is connected with rotating horizontal pole 405 is vertical in cylindrical chamber 401, abrading-ball 406 is placed in described cylindrical chamber 401, and in-situ reducing portion 303 adds graphite raw material 301 by the first feeding-passage 402 to the cylindrical chamber 201 in mechanical stripping portion 200.Dosing portion 304 adds surfactant additive by the second charging aperture 403 to the cylindrical chamber 401 in mechanical stripping portion 400.Turning cylinder 404 drives the rotating horizontal pole 405 that be connected vertical with turning cylinder 404 to stir in cylindrical chamber 401.Rotating horizontal pole 405 drives the abrading-ball 406 in cylindrical chamber 401 and graphite raw material 401 mutually to collide and friction in stirring, graphite raw material 301 is under the shear action of described abrading-ball 406 frictional force, in graphite, the Van der Waals force of each graphite layers is disintegrated, and obtains the turbid liquid of Graphene and graphite.Described abrading-ball 406 is diameter 50 μm ~ 100 μm and hardness is greater than the pearl of graphite.The abrading-ball 406 of the present embodiment is that the abrading-ball of 50 μm ~ 100 μm is for ball-milling medium with diameter, in graphite mechanical stripping process, for the ball-milling medium that diameter is greater than 100 μm, graphite flake layer is peeled off number of times repeatedly significantly to be increased, and improves mechanical stripping efficiency.And gained graphite flake layer thickness distribution is concentrated, the graphite flake layer thickness of more than 50% is all at below 4nm.
The cylindrical chamber 401 in described mechanical stripping portion 400 is connected with centrifugation portion 305 by discharging channel 407.The mixing turbid liquid of the Graphene after lift-off processing and graphite is sent into centrifugation portion 305 by discharging channel 407 by mechanical stripping portion 400.Centrifugation portion 305 is connected with drying section 306.The mixing turbid liquid of centrifugation portion 305 to the Graphene entered wherein and graphite carries out centrifugal treating, to Graphene turbid liquid, and send into drying section 306.Drying section 306 carries out drying process to the Graphene turbid liquid entered wherein, finally obtains graphene film 307.
Embodiment 2
Shown in composition graphs 2 Fig. 3, small pieces graphene film 307, as the grapheme platelet of induction Graphene large area deposition, is transferred to and interim growth flexible substrate Copper Foil brings out graphene film 203 is grown by the single-layer graphene utilizing mechanical stripping method to prepare.To the Copper Foil substrate of graphene film small pieces be had to be placed in sputtering chamber, adopt laser pulse to be splashed on Copper Foil substrate from solid carbon source target by carbon atom, thus with graphene film small pieces for starting point is at Copper Foil Grown graphene film 203.
Chemical etching and printing transferring method is adopted to transfer in flexible substrate 205 by graphene film 203 again, for the process that graphene film 203 is separated with temporary substrates, adhensive membrane 204 in flexible substrate 205 comprises PVB or ethyl cellulose etc., by superimposed with the adhensive membrane 204 in flexible substrate 205 for the graphene film 203 on temporary substrates, form temporary adhesion body; Remove above-mentioned temporary substrates, to obtain the graphene film 203 be positioned in flexible substrate 205.After graphene film 203 and flexible substrate 205 are bonded together, need to be separated as the Copper Foil of temporary substrates or nickel foil, the graphene film 203 grown on Copper Foil has just been transferred on target flexibility substrate 205 by complete like this.High by graphene film 203 purity obtained by described method, area is large.
Described nanoscale coating circuit 202 is the graphene film 203 be adhered in flexible substrate 205 with circuit die is put into magnetron sputtering apparatus as base material carry out the sputtering of nanoscale coating.Plasma processor is put into the described graphene film 203 be adhered in flexible substrate 205 with circuit die, adopts oxygen, under the condition of power 50 watts, carry out preliminary treatment in 60 seconds.Described coating sputter procedure magnetic control sputtering device sputtering operating pressure controls at 0.13Pa, base material temperature is 25 DEG C, target and base material distance 5cm, sputtering 8 °, angle, sputtering power 100W, sputtering target material is metallic copper, sputtering zinc coat thickness control is 50nm-300nm, adopt base material upper, sputtering target material structure, take off circuit die after having sputtered, namely coating circuit has been prepared.Above-mentioned nanoscale coating circuit 202 prints electrode, and described electrode is used for realizing nanoscale coating circuit 202 and is electrically connected with conductive fiber.At above-mentioned printed on electrodes overcoat 201, described overcoat 201 is epoxy resin, has waterproof, anti-scratch ability.Described overcoat 201 covers on electrode, and covers on graphene film 203 and nanoscale coating circuit 202.
Embodiment 3
Composition graphs 2, Fig. 3, Fig. 5 and Fig. 6, small pieces graphene film 307, as the grapheme platelet of induction Graphene large area deposition, is transferred to and interim growth flexible substrate Copper Foil brings out graphene film 203 is grown by the single-layer graphene utilizing mechanical stripping method to prepare.To the Copper Foil substrate of graphene film small pieces be had to be placed in sputtering chamber, adopt laser pulse to be splashed on Copper Foil substrate from solid carbon source target by carbon atom, thus be that starting point is at Copper Foil Grown graphene film 203 with small pieces graphene film 307.
Chemical etching and printing transferring method is adopted to transfer in flexible substrate 205 by graphene film 203 again, for the process that graphene film 203 is separated with temporary substrates, adhensive membrane 204 in flexible substrate 205 comprises PVB or ethyl cellulose etc., by superimposed with the adhensive membrane 204 in flexible substrate 205 for the graphene film 203 on temporary substrates, form cohesive body; Remove above-mentioned temporary substrates Copper Foil, to obtain the graphene film 203 be positioned in flexible substrate 205.After graphene film 203 and flexible substrate 205 are bonded together, need the Copper Foil as temporary substrates to be separated, the graphene film 203 of growth on Copper Foil has just been transferred on target flexibility substrate 205 by complete like this.High by graphene film 203 purity obtained by described method, area is large.
Described nanoscale coating circuit 202 manufacture process is: the graphene film 203 be adhered in flexible substrate 205 is put into magnetron sputtering apparatus as a substrate 501 and carries out the sputtering of nanoscale coating, the substrate 501 covering copper film 503 through sputtering is sent into forcing press 506, under the effect of impressing mould 504, the copper film 503 that lamination two is spaced apart from each other, vary in size on this substrate 501.In this impressing mould 504 region not only on copper film 503, a stamping structure 505 is set, and also there is a stamping structure 505 being arranged in the region outside this film 503, the micro-structural 502 shown in Fig. 6, especially a kind of fluid micro-structural 502 can be incorporated in substrate 501.This impressing mould 504 defines a fixed structure 514 simultaneously on a substrate 501, described fixed structure 514 can be used for the hygrosensor 101 in fixed temperature monitoring portion, the Graphene fever tablet 108 that the Monitoring Data of the hygrosensor 101 that described intelligent dress ornament data collection process portion goes out based on fixed structure 514 controls described intelligent dress ornament is generated heat, wherein, fixed structure 514 for locating described temperature monitoring portion is formed in same procedure with the microstructure 502 of described substrate 501, the forming process of described fixed structure 514 and described microstructure 502 is formed in a moulding process of impressing mould 504, this makes in commercial process, achieve the Quick-forming of described fixed structure 514 and described microstructure 502, improve nanoscale coating circuit 202 one-tenth product speed.As shown in Figure 6, this copper film 503 defines printed conductor that is three-dimensionally shaped, mutually insulated or circuit.Each printed conductor 507 have one flat, about micro-structural 502 protruding arrange and the printed conductor sidewall 509 of the printed conductor plane 508 extended to inside drawing and at least one and the angled setting of printed conductor plane 508.Can find out, according to the layout of printed conductor 507 on this substrate 501 and surely, or rather according to the layout of impression micro-structural 502 surely, a unique printed conductor plane 508 or there is an one-sided printed conductor sidewall 509, or there are two directions extending longitudinally and printed conductor sidewall 509 spaced apart from each other being transverse to printed conductor 507.This printed conductor sidewall 509 extends in the substrate trenches 510 of micro-structural 502 (also namely on impressing mould direction dorsad), but does not arrive respective substrate channel bottom 511.As shown in Figure 6, every two adjacent printed conductor planes 508 are arranged in identical height or plane at least approx, and by horizontal interval electrically insulated from one another.
As shown in Figure 6, this micro-structural has multiple spaced apart from each other, flat, protruding substrate plane 512 (protruding substrate section), wherein this protruding substrate plane 512 upper part impression printed conductor plane 508 (protruding printed conductor section).On the side of protruding substrate plane 512, the direction entering substrate 501 is connected with substrate trenches 510 that this impressing mould dorsad extends, that have two substrate sidewalls 513 respectively.Corresponding two adjacent substrate sidewalls 513 511 places bottom affiliated substrate trenches intersect.Substrate sidewall 513 is used as the loading end of printed conductor sidewall 509, and wherein substrate sidewall 513 extends in 511 directions bottom affiliated substrate trenches from this printed conductor sidewall 509.
In region between two adjacent, mutually relative printed conductor sidewalls 509, this substrate 501 does not have residue copper film 503.This can not cause removing residual copper film section 503 from this substrate 501 after this moulding process.Thus all copper film 503 is all that electricity is available, printed conductor cross section increases, and current capacity improves.
Above-mentioned printed conductor prints electrode and namely forms nanoscale coating circuit 202, more precisely, the printed conductor be connected above by electrode forms a nanoscale coating parallel circuit, and is used for realizing nanoscale coating circuit 202 by described electrode and is electrically connected with conductive fiber.At above-mentioned printed on electrodes overcoat 201, described overcoat 201 is epoxy resin, has insulation, waterproof, anti-scratch ability.Described overcoat 201 covers on electrode, and covers on graphene film 203 and nanoscale coating circuit 202.Because the micro-structural 502 that graphene film 203 has, expand the surface area of graphene film 203, increase the adhesive strength of overcoat 201 and graphene film, improve protection effect, improve nanoscale coating circuit 202 and the contact compactness of graphene film 203 simultaneously, increase the electric conductivity of graphene film 203.
It should be noted that; above-mentioned specific embodiment is exemplary; those skilled in the art can find out various solution under the inspiration of the disclosure of invention, and these solutions also all belong to open scope of the present invention and fall within protection scope of the present invention.It will be understood by those skilled in the art that description of the present invention and accompanying drawing thereof are illustrative and not form limitations on claims.Protection scope of the present invention is by claim and equivalents thereof.
Claims (10)
1. a Graphene intelligence dress ornament, is characterized in that, described intelligent dress ornament comprises temperature monitoring portion, the Graphene fever tablet (108) prepared for substrate with polyester, polypropylene or polyamide polymer fiber weaving cloth and data collection process portion;
Graphene fever tablet (108) comprises the upper graphene film (203) generated through solid carbon source sputtering mode on the basis of the small pieces graphene film (307) through mechanical stripping that arranges of flexible substrate (205) and the nanoscale coating circuit (202) generated through sputtering mode for substrate with graphene film (203);
Described intelligent dress ornament data collection process portion controls Graphene fever tablet (108) heating of described intelligent dress ornament based on the Monitoring Data of the hygrosensor (101) in the fixed structure (514) be on described substrate (501), wherein, to conduct electricity and the microstructure (502) of adhesive force is formed in same procedure for improving for the fixed structure (514) of locating described temperature monitoring portion hygrosensor (101) and described substrate (501).
2. Graphene intelligence dress ornament as claimed in claim 1, it is characterized in that, the described graphene film (203) generated through solid carbon source sputtering mode is from choosing a small pieces graphene film (307) in advance through the described small pieces graphene film of the generation of mechanical stripping, described small pieces graphene film (307) is transferred to as induction graphene film (203) starting point that grows on temporary flexible substrate, on described substrate with small pieces graphene film (307) for starting point adopts solid carbon source to generate graphene film (203) through sputtering mode.
3. Graphene intelligence dress ornament as claimed in claim 1 or 2, it is characterized in that, the production procedure through the described small pieces graphene film (307) of mechanical stripping generation is:
High-temperature process portion (302) is connected with in-situ reducing portion (303), adds nitrogen or inert gas carries out high-temperature process to graphite raw material (301) under treatment temperature is 200 DEG C ~ 1200 DEG C conditions;
Described in-situ reducing portion (303) is connected with mechanical stripping portion (400) by the first feed pipe (402), receive the graphite raw material (301) after described high-temperature process portion (302) process, under 200 DEG C ~ 1200 DEG C temperature conditions, add at least one in nitrogen or hydrogen as reducing medium, reduction treatment is carried out to Graphene raw material (301), and the raw material after process is sent into mechanical stripping portion (400);
Described dosing portion (304) is connected with described mechanical stripping portion (400) by the second feed pipe (403), described dosing portion (304) is for depositing surfactant additive, and carry out in stripping process described mechanical stripping portion (400) to graphite raw material (301), continue cylindrical chamber (401) dosing to mechanical stripping portion (400);
The cylindrical chamber (401) of described mechanical stripping portion (400) is connected with in-situ reducing portion (303) by the first feeding-passage (402), the cylindrical chamber (401) of described mechanical stripping portion (400) is connected with dosing portion (304) by the second feeding-passage (403), turning cylinder (404) is connected with rotating horizontal pole (405) is vertical in cylindrical chamber (401), abrading-ball (406) is placed in described cylindrical chamber (401), described abrading-ball (406) is for diameter 50 μm ~ 100 μm and hardness is greater than the pearl of graphite, the cylindrical chamber (401) of described mechanical stripping portion (400) is connected with centrifugation portion (305) by discharging channel (407),
After described in-situ reducing portion (303) to add graphite raw material (101) to described cylindrical chamber (401) and described dosing portion (304) adds surfactant additive to described cylindrical chamber (401), described turning cylinder (404) drives square with the axis connected rotating horizontal pole (405) to stir in fixing cylindrical chamber (401), rotating horizontal pole (405) drives the abrading-ball (406) in cavity and graphite raw material (301) mutually to collide and friction in stirring, graphite raw material (301) is under the shear action of described abrading-ball frictional force, in graphite, the Van der Waals force of each graphite layers is disintegrated, obtain the turbid liquid of Graphene and graphite,
The turbid liquid of Graphene and graphite is sent into centrifugation portion (365) by discharging channel (407) by the cylindrical chamber (401) of described mechanical stripping portion (400), through described centrifugation portion (305) centrifugal treating, obtain Graphene turbid liquid, and send into drying section (306) carry out drying process, obtain small pieces graphene film (307).
4. Graphene intelligence dress ornament as claimed in claim 1, it is characterized in that, described nanoscale coating circuit (202) is the graphene film (203) be adhered in flexible substrate (205) with circuit die is put into magnetron sputtering apparatus as base material carry out the sputtering of nanoscale coating.
5. Graphene intelligence dress ornament as claimed in claim 1, it is characterized in that, described nanoscale coating circuit (202) is: be adhered to the upper sputtering generation of the graphene film (203) in flexible substrate (205) copper film, again by impression mode, generate nanoscale coating circuit (202).
6. the Graphene intelligence dress ornament as described in claim 4 or 5, it is characterized in that, described coating sputter procedure magnetic control sputtering device sputtering operating pressure controls at 0.13Pa ~ 0.20Pa, base material temperature is less than 50 DEG C, target and base material distance 5cm ~ 10cm, sputtering 5 ° ~ 8 °, angle, sputtering power 100W ~ 200W, sputtering zinc coat thickness control is 50nm ~ 300nm, adopt base material upper sputtering target material structure.
7. the Graphene intelligence dress ornament as described in claim 4 or 5, it is characterized in that, plasma processor is put into the described graphene film (203) being adhered to flexible substrate (205), adopt oxygen, carry out sputter process carry out preliminary treatment in 60 seconds under the condition of power 50 watts after, sputtering target material comprises metallic aluminium, copper or silver.
8. Graphene intelligence dress ornament as claimed in claim 1, is characterized in that, adopt the method for cored and looping that conductive fiber is made yarn, inweaved in polyester, polypropylene or polyamide polymer fiber weaving cloth fabric.
9. Graphene intelligence dress ornament as claimed in claim 1, it is characterized in that, described temperature monitoring portion comprises hygrosensor (101) and distributed A/D acquisition module (102), and described temperature monitoring portion is connected with data collection process portion by described optical fiber conductive fiber; Data processing division comprises single-chip microcomputer (103), wireless data transmitter (104), mobile terminal (105), distributed digital input/output module (106) and power conditioning module (107), and described data processing division is connected with Graphene fever tablet (108) by described optic fibre wire.
10. Graphene intelligence dress ornament as claimed in claim 1, it is characterized in that, epoxy encapsulation is adopted to Graphene fever tablet (108), temperature detecting part, data collection process portion, conductive fiber and temperature monitoring portion, data collection process portion and Graphene fever tablet (108) coupling part rubber or plastic consolidation waterproof.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710937950.0A CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
| CN201511025777.4A CN105506812B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene intelligence dress ornament |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511025777.4A CN105506812B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene intelligence dress ornament |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710939461.9A Division CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
| CN201710937950.0A Division CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105506812A true CN105506812A (en) | 2016-04-20 |
| CN105506812B CN105506812B (en) | 2018-01-23 |
Family
ID=55715099
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511025777.4A Active CN105506812B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene intelligence dress ornament |
| CN201710937950.0A Active CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A Active CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710937950.0A Active CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A Active CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN105506812B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105898907A (en) * | 2016-06-12 | 2016-08-24 | 杭州白熊科技有限公司 | Graphene heating film and preparation method thereof |
| CN105901780A (en) * | 2016-05-04 | 2016-08-31 | 曾新民 | Manufacturing method for uterus warming healthcare briefs containing graphene and used for women |
| CN106473251A (en) * | 2016-06-29 | 2017-03-08 | 龙彩霞 | The electroluminescent health clothing of Graphene |
| WO2017185518A1 (en) * | 2016-04-28 | 2017-11-02 | 李仕会 | Far-infrared photo-thermal blanket |
| CN108260887A (en) * | 2017-12-30 | 2018-07-10 | 东莞市明骏智能科技有限公司 | A kind of carbon nanotube electric heating assembly, electric heating insole and Electrothermal shoes |
| CN109246869A (en) * | 2018-08-06 | 2019-01-18 | 利辛县飞亚强磁性软纱门有限公司 | Electric heat generating fiber film and the preparation method and application thereof |
| CN110027272A (en) * | 2019-04-18 | 2019-07-19 | 五邑大学 | A kind of intelligent textile based on heating power positioning |
| CN111276295A (en) * | 2020-02-20 | 2020-06-12 | 上海超碳石墨烯产业技术有限公司 | Preparation method of graphene primary coated copper wire |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109089339A (en) * | 2018-07-24 | 2018-12-25 | 董哲源 | A kind of glass deicing demister |
| CN109275210B (en) * | 2018-10-12 | 2021-02-09 | 重庆墨希科技有限公司 | High-reliability heating film based on graphene and preparation method thereof |
| TWI689225B (en) * | 2018-11-21 | 2020-03-21 | 國立清華大學 | Micro-scale wireless heater and fabrication method and applications thereof |
| CN109600866B (en) * | 2018-12-27 | 2024-05-28 | 中国科学院山西煤炭化学研究所 | Graphene infrared heating plate |
| CN112804775A (en) * | 2021-01-18 | 2021-05-14 | 安徽宇航派蒙健康科技股份有限公司 | Method for preparing electrothermal film by adopting transparent graphene |
| CN113104809A (en) * | 2021-04-08 | 2021-07-13 | 德州学院 | Method for preparing graphene nano-net by utilizing patterned substrate for imprinting |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101913598A (en) * | 2010-08-06 | 2010-12-15 | 浙江大学 | Method for preparing graphene membrane |
| CN103393237A (en) * | 2013-08-19 | 2013-11-20 | 青岛大学 | Thermoregulation garment |
| CN103991868A (en) * | 2014-06-13 | 2014-08-20 | 广东石油化工学院 | Preparation method of graphene |
| TW201441149A (en) * | 2013-04-19 | 2014-11-01 | Incubation Alliance Inc | Carbon fiber and method for producing same |
| CN104176727A (en) * | 2013-05-28 | 2014-12-03 | 安炬科技股份有限公司 | Graphene suspended solution and making method thereof |
| CN104585913A (en) * | 2013-11-01 | 2015-05-06 | 无锡慧思顿科技有限公司 | Water resistible and breathable human body air-conditioning intelligent garment with infrared stealth function |
| CN104902594A (en) * | 2015-06-01 | 2015-09-09 | 冯冠平 | Intelligent temperature control thermal underwear |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100469220C (en) * | 2007-06-14 | 2009-03-11 | 江南大学 | A method for making elastic circuit with the non-weaving cloth as base |
| DE102008040882A1 (en) * | 2008-07-31 | 2010-02-04 | Robert Bosch Gmbh | Method for hot embossing at least one printed conductor on a substrate, substrate with at least one printed conductor and embossing stamp |
| CN102796991B (en) * | 2011-05-27 | 2014-08-20 | 清华大学 | Method for preparing graphene carbon nanotube composite membrane structure |
| CN102897750B (en) * | 2011-07-29 | 2014-09-10 | 浙江大学 | PrPrearation method for graphene film |
| WO2013162309A1 (en) * | 2012-04-25 | 2013-10-31 | 그래핀스퀘어 주식회사 | Patterning method for graphene using hot-embossing imprinting |
| CN102659096A (en) * | 2012-04-27 | 2012-09-12 | 湖南大学 | Preparation methods of graphene dispersion solution and thin film of graphene |
| CN102883486B (en) * | 2012-09-28 | 2014-09-24 | 江苏物联网研究发展中心 | Graphene based transparent electric heating film and production method thereof |
| US9546294B2 (en) * | 2013-04-19 | 2017-01-17 | Incubation Alliance, Inc. | Carbon fiber and method for producing same |
| CN104498902B (en) * | 2014-12-12 | 2016-10-19 | 中国科学院重庆绿色智能技术研究院 | A kind of preparation method of aumospheric pressure cvd graphene film |
| CN104739403B (en) * | 2015-04-10 | 2017-08-25 | 中国科学院重庆绿色智能技术研究院 | Graphene nano wall flexibility electrocardioelectrode and preparation method thereof |
-
2015
- 2015-12-31 CN CN201511025777.4A patent/CN105506812B/en active Active
- 2015-12-31 CN CN201710937950.0A patent/CN107734722B/en active Active
- 2015-12-31 CN CN201710939461.9A patent/CN107675137B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101913598A (en) * | 2010-08-06 | 2010-12-15 | 浙江大学 | Method for preparing graphene membrane |
| TW201441149A (en) * | 2013-04-19 | 2014-11-01 | Incubation Alliance Inc | Carbon fiber and method for producing same |
| CN104176727A (en) * | 2013-05-28 | 2014-12-03 | 安炬科技股份有限公司 | Graphene suspended solution and making method thereof |
| CN103393237A (en) * | 2013-08-19 | 2013-11-20 | 青岛大学 | Thermoregulation garment |
| CN104585913A (en) * | 2013-11-01 | 2015-05-06 | 无锡慧思顿科技有限公司 | Water resistible and breathable human body air-conditioning intelligent garment with infrared stealth function |
| CN103991868A (en) * | 2014-06-13 | 2014-08-20 | 广东石油化工学院 | Preparation method of graphene |
| CN104902594A (en) * | 2015-06-01 | 2015-09-09 | 冯冠平 | Intelligent temperature control thermal underwear |
Non-Patent Citations (1)
| Title |
|---|
| 江莞等: "机械剥离法制备石墨烯及其在石墨烯/陶瓷复合材料制备中的应用", 《中国材料进展》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017185518A1 (en) * | 2016-04-28 | 2017-11-02 | 李仕会 | Far-infrared photo-thermal blanket |
| CN105901780A (en) * | 2016-05-04 | 2016-08-31 | 曾新民 | Manufacturing method for uterus warming healthcare briefs containing graphene and used for women |
| CN105898907A (en) * | 2016-06-12 | 2016-08-24 | 杭州白熊科技有限公司 | Graphene heating film and preparation method thereof |
| CN106473251A (en) * | 2016-06-29 | 2017-03-08 | 龙彩霞 | The electroluminescent health clothing of Graphene |
| CN108260887A (en) * | 2017-12-30 | 2018-07-10 | 东莞市明骏智能科技有限公司 | A kind of carbon nanotube electric heating assembly, electric heating insole and Electrothermal shoes |
| CN109246869A (en) * | 2018-08-06 | 2019-01-18 | 利辛县飞亚强磁性软纱门有限公司 | Electric heat generating fiber film and the preparation method and application thereof |
| CN110027272A (en) * | 2019-04-18 | 2019-07-19 | 五邑大学 | A kind of intelligent textile based on heating power positioning |
| CN110027272B (en) * | 2019-04-18 | 2021-02-02 | 五邑大学 | Intelligent textile based on thermal positioning |
| CN111276295A (en) * | 2020-02-20 | 2020-06-12 | 上海超碳石墨烯产业技术有限公司 | Preparation method of graphene primary coated copper wire |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105506812B (en) | 2018-01-23 |
| CN107734722B (en) | 2021-04-06 |
| CN107675137A (en) | 2018-02-09 |
| CN107734722A (en) | 2018-02-23 |
| CN107675137B (en) | 2019-03-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105506812A (en) | Graphene smart clothes | |
| CN208572471U (en) | A kind of graphene electrical heating bag | |
| CN108848586A (en) | A kind of wearable heating sheet of far-infrared flexible, preparation method and application | |
| CN204864563U (en) | Electrode paster of utensil complex function | |
| CN102510585A (en) | Carbon fiber far-infrared insulating device and far-infrared heating sheet | |
| CN104887227A (en) | Graphene flexible surface myoelectricity electrode and preparing method thereof | |
| CN104800978A (en) | Graphene far infrared generator and physiotherapy device adopting same | |
| CN110418444A (en) | A kind of graphene electrical heating bag | |
| CN208783122U (en) | A kind of wearable heating sheet of far-infrared flexible and intelligent heating clothes | |
| CN201114783Y (en) | Heating body structure with remote infrared function | |
| CN205125784U (en) | Yuzhen with temperature regulation function | |
| CN201862151U (en) | Far infrared heating membrane | |
| CN206237620U (en) | Downfield, existing fringing field far infrared electric heating plate | |
| CN204767068U (en) | Graphite alkene infrared generator far away and adopt its physiotherapy device | |
| CN107933006A (en) | Efficient Far infrared heating membrane, and physical therapy plaster, plaster, physical therapy footwear based on it | |
| CN205108774U (en) | Graphite alkene chip that generates heat with role of physical therapy | |
| CN210169166U (en) | Sterilization and heating physiotherapy insole made of graphene composite material | |
| CN210960459U (en) | Intelligence far infrared physiotherapy brassiere | |
| CN108042923A (en) | Multifunction physiotherapy instrument and physical therapeutic system | |
| CN209732734U (en) | Graphite alkene far infrared shoe-pad that generates heat | |
| CN209208184U (en) | Heating film based on graphene technology, physical therapy patch, plaster patch and physical therapy shoe | |
| CN206402471U (en) | Intelligent graphene heating pillow with neck | |
| CN203591108U (en) | Far-infrared heating blanket | |
| CN201585153U (en) | Infrared ray heating plate | |
| CN202918517U (en) | Novel carbon fiber far infrared warm device and far infrared heating film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |