CN105505176A - Liquid state wallpaper and imposing process - Google Patents

Liquid state wallpaper and imposing process Download PDF

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Publication number
CN105505176A
CN105505176A CN201610066111.1A CN201610066111A CN105505176A CN 105505176 A CN105505176 A CN 105505176A CN 201610066111 A CN201610066111 A CN 201610066111A CN 105505176 A CN105505176 A CN 105505176A
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CN
China
Prior art keywords
liquid wallpaper
wallpaper
percent
screen frame
tight
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Granted
Application number
CN201610066111.1A
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Chinese (zh)
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CN105505176B (en
Inventor
张雪
张达
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Harbin Green-Coatings Science & Technology Co Ltd
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Harbin Green-Coatings Science & Technology Co Ltd
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Priority to CN201610066111.1A priority Critical patent/CN105505176B/en
Publication of CN105505176A publication Critical patent/CN105505176A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/12Stencil printing; Silk-screen printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/18Particular kinds of wallpapers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention relates to liquid state wallpaper and an imposing process. The liquid state wallpaper comprises the following components in percentage by weight: 50 to 60 percent of deionized water, 4.0 to 8.0 percent of pigment slurry, 32 to 42 percent of a film forming component, 1.0 to 3.0 percent of a flame retardant, 0.1 to 0.5 percent of a defoaming agent, 0.5 to 2.0 percent of a leveling agent, 1.0 to 3.0 percent of a film forming auxiliary, 0.2 to 1.0 percent of a bactericide and 0.5 to 5.0 percent of a thickening agent, wherein the film forming component comprises polyurethane resin and acrylic resin. According to the liquid state wallpaper, the specific film forming component is adopted, so that the problems of complex components and poor environmental friendliness of the liquid state wallpaper can be effectively solved. According to the imposing process provided by the invention, through the use of a silk screen and photosensitive resist, the complexity of an imposing preparation process is reduced, and the imposing cost is reduced.

Description

A kind of liquid wallpaper and layout technique
Technical field
The invention belongs to the technical field of wallpaper in material of construction, refer to a kind of liquid wallpaper and layout technique especially.
Background technology
Wallpaper is simple because of its use procedure at furnishing fields, can reduce the time of fitting up, and finishing flexibly, ought to account for the market share that tool is larger, but the price of wallpaper remains high always, has influence on wallpaper occupying in furnishing fields share.
Can find by analysis, having influence on reason that wallpaper holds at high price is that the production cost of wallpaper is too high, has directly had influence on the selling price of wallpaper.Existing traditional wallpaper need of production is through following operation: body paper sends, coating, dry-softening-embossing-cooling-cutting edge-buildup between dry (gel)-cooling-printing-version, and check-batch-packaging-vanning-process of complexity such as to put in storage.The complicacy of wallpaper technique directly causes market value high, and traditional wallpaper is very high for splicing gap construction requirement, splices badly directly to cause figure deviations, and seam edge time length can tilt.
On the other hand, owing to considering Environmental Factors, wallpaper material and layout glue material require also very high, and this just needs producer's input high cost to go to make new wallpaper material or layout glue material, thus result also in holding at high price of traditional wallpaper.
The price of tradition wallpaper is not only higher, and traditional wallpaper also exist non-moistureproof, the problem such as be not durable, easily crack, easily turn yellow and fade.In order to overcome the above-mentioned defect of traditional wallpaper, prior art uses liquid wallpaper to replace traditional wallpaper, and liquid wallpaper is exactly with emulsion paint printing metope or the metope with brush emulsion paint after putty moulding.
Liquid wallpaper, compared with traditional wallpaper, uses simple, economy and durability, environmental protection, without seam, is easy to clear up letter and facilitates secondary decoration, and can according to the random layout of the demand of client.But still there is the complicated and feature of environmental protection difference of composition and its layout operation is many afterwards problem in the existing liquid wallpaper used.
Summary of the invention
Order of the present invention be to provide a kind of liquid wallpaper and, the complicated and problem of feature of environmental protection difference with the component overcoming existing liquid wallpaper.
Another object of the present invention is to provide a kind of layout technique, to overcome the problem of existing layout complex procedures.
The present invention is achieved by the following technical solutions:
A kind of liquid wallpaper, comprises by weight percentage:
Described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Described deionization electrical conductivity of water is less than 5.0 μ S/cm.
The number-average molecular weight of described film-forming components is 5500-8500.
Described defoamer is not containing organosilyl defoamer.
Described film coalescence aid is alcohols and ethers modified material ethylene glycol monomethyl ether.
Described thickening material is nonionic polyurethane thickening material; Described thickening material is about 20000mPa.s 20 DEG C time, and nonvolatile component is 60%.
A kind of layout technique, for liquid wallpaper according to any one of brushing the claims 1 to 6, comprises the following steps:
Prepare the screen frame that stretches tight, with stretching tight, network folder clamps silk screen, is fixed on base frame by described silk screen; To stretch tight net glue at described silk screen lower surface and the brushing of described base frame contact part; After the described net glue that stretches tight parches, remove described silk screen namely complete described in stretch tight screen frame preparation;
Stretch tight described in use sense optical cement is evenly coated on screen frame tow sides after, drying and processing;
The described screen frame that stretches tight is fitted with design sheet original text, in setting-up time, carries out exposure-processed; The screen frame that stretches tight described in after exposure is through rinsing and drying.
Further, the time shutter is 7.5 minutes.
Described layout technique also comprises scrapes sample, and the described screen frame that stretches tight is compressed article to be undertaken the printing of, and uses described liquid wallpaper to carry out blade coating, make described liquid wallpaper through after the described screen frame that stretches tight to described in article to be undertaken the printing of, stretch tight described in removing screen frame, scrapes sample described in completing.
The invention has the beneficial effects as follows:
The present invention by adopting specific film-forming components, the complicated and problem of feature of environmental protection difference of the component that effectively can overcome existing liquid wallpaper.
Layout technique of the present invention, by the use of silk screen and photoresists, reduces the complicacy of layout preparation technology, reduces layout cost.
Embodiment
Describe technical scheme of the present invention in detail by the following examples, following embodiment is only exemplary, only can be used for explaining and technical scheme of the present invention being described, and can not be interpreted as being the restriction to technical solution of the present invention.
The invention provides a kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Polyurethane resin component is adopted to be utilize the high strength of this resin, anti tear and antiwear characteristic in the application, the one-tenth film strength, anti tear and the wear resisting property that make wallpaper last are high, in film-forming components, add acrylic resin simultaneously, utilize the film forming properties of acrylic resin, make last wallpaper rete smooth, and have certain toughness, not only increase the outward appearance sensation of wallpaper, and improve the feel of wallpaper.
In this application, the number-average molecular weight of the film-forming components selected is 5500-8500, and the application selects the number-average molecular weight of this scope, and can ensure that the film forming of wallpaper is even, the mobility of the liquid wallpaper when brushing is applicable to; If the number-average molecular weight selected is less than 5500, then the film-formation result of liquid wallpaper is poor, and mobility is high, in use can cause into lepthymenia and uneven; If the number-average molecular weight selected is greater than 8500, then the film forming properties of liquid wallpaper is poor, and the fragility after film forming becomes large, and rete is uneven.
In this application, the pH value of film-forming components is between 8.3-9.0, and the second-order transition temperature of film-forming components is at 110-125 DEG C; The pH value of liquid wallpaper is between 8.3-9.0, and this pH value has influence on the pH value of liquid wallpaper; The too high or too low quality of forming film all affecting liquid wallpaper of pH value, if pH value is too low, has influence on the film formation time of liquid wallpaper; If pH value is too high, the time of drying of liquid wallpaper is long, is vulnerable to the pollution of environment for use and the problem of water resistance difference.
Described deionization electrical conductivity of water is less than 5.0 μ S/cm.
In this application, fire retardant is inorganic combustion inhibitor, selects magnesium hydroxide or aluminium hydroxide, the use of fire retardant, is conducive to the security improving liquid wallpaper, and by using inorganic combustion inhibitor, meets environmental requirement.
Described defoamer is not containing organosilyl defoamer, in this application, the model that the defoamer used is produced for German enlightening high (tego) is 830 defoamers, and the application does not specially require defoamer, can select the defoamer of other model as required.
Described film coalescence aid is alcohols and ethers modified material ethylene glycol monomethyl ether, reaches emulsion film forming speed moderate, and hardness increases.
Described thickening material is nonionic polyurethane thickening material; Described thickening material is about 20000mPa.s 20 DEG C time, and nonvolatile component is 60%.
In this application, flow agent and sterilant are now conventional flow agent and sterilant, do not illustrate in this application.
Embodiment 1
A kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Add deionized water in a kettle., start homogenizer slowly adds corresponding amount while stirring successively by formula order each component with 200 revs/min, after reinforced, homogenizer is regulated to stir 2 hours with 700 revs/min, pack after using 200 order filter-cloth filterings, without the need to Pressurized-heated in whole preparation process.
Embodiment 2
A kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Add deionized water in a kettle., start homogenizer slowly adds corresponding amount while stirring successively by formula order each component with 200 revs/min, after reinforced, homogenizer is regulated to stir 2 hours with 700 revs/min, pack after using 200 order filter-cloth filterings, without the need to Pressurized-heated in whole preparation process.
Embodiment 3
A kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Add deionized water in a kettle., start homogenizer slowly adds corresponding amount while stirring successively by formula order each component with 200 revs/min, after reinforced, homogenizer is regulated to stir 2 hours with 700 revs/min, pack after using 200 order filter-cloth filterings, without the need to Pressurized-heated in whole preparation process.
Embodiment 4
A kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Add deionized water in a kettle., start homogenizer slowly adds corresponding amount while stirring successively by formula order each component with 200 revs/min, after reinforced, homogenizer is regulated to stir 2 hours with 700 revs/min, pack after using 200 order filter-cloth filterings, without the need to Pressurized-heated in whole preparation process.
Embodiment 5
A kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Add deionized water in a kettle., start homogenizer slowly adds corresponding amount while stirring successively by formula order each component with 200 revs/min, after reinforced, homogenizer is regulated to stir 2 hours with 700 revs/min, pack after using 200 order filter-cloth filterings, without the need to Pressurized-heated in whole preparation process.
Embodiment 6
A kind of liquid wallpaper, its composition comprises by weight percentage:
In this application, described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
Add deionized water in a kettle., start homogenizer slowly adds corresponding amount while stirring successively by formula order each component with 200 revs/min, after reinforced, homogenizer is regulated to stir 2 hours with 700 revs/min, pack after using 200 order filter-cloth filterings, without the need to Pressurized-heated in whole preparation process.
The present invention also provides a kind of layout technique, and for brushing above-mentioned liquid wallpaper, this layout technique comprises the following steps:
Prepare the screen frame that stretches tight, with stretching tight, network folder clamps silk screen, is fixed on base frame by described silk screen, and the shape of base frame can be determined as required, does not carry out certain illustrated in this application; To stretch tight net glue at described silk screen lower surface and the brushing of described base frame contact part, in this application, the net glue that stretches tight is the glue now commonly using bonding, and the kind of glue can change as required, not within the technical scope that this application claims protection; After the described net glue that stretches tight parches, remove described silk screen namely complete described in stretch tight screen frame preparation.
Stretch tight described in use sense optical cement is evenly coated on screen frame tow sides after, in this application, apply twice altogether, make coating evenly and after ensureing all to cover silk screen, drying and processing; Be drying and processing in unglazed situation herein, in drying course, the drying mode with ray can not be used to dry, expose phenomenon in advance to prevent photoresists.
Fitted with design sheet original text by the described screen frame that stretches tight, design original text is that client waits the pattern original text needed, and carries out exposure-processed in 7.5 minutes; In this application, crucial technology is the time shutter, if the time shutter is short, then layout is because exposing insufficient and causing the disappearance of pattern, if the time shutter is long, not only has influence on the careful of pattern, and cause photoresists to rinse well, screen frame stretch tight described in after exposure through high pressure water washing, unexposed photoresists are rinsed out completely, then after drying, complete layout preparation.
Described layout technique also comprises scrapes sample, and the described screen frame that stretches tight is compressed article to be undertaken the printing of, and uses described liquid wallpaper to carry out blade coating, make described liquid wallpaper through after the described screen frame that stretches tight to described in article to be undertaken the printing of, stretch tight described in removing screen frame, scrapes sample described in completing.
After completing layout, construction brushing can be carried out:
First, first piece of layout is placed on the correct position of metope, compress layout, brush, after guaranteeing that liquid wallpaper evenly infiltrates layout, remove layout, first piece of layout decorative pattern is printed on metope.
Then rinse layout, this first piece of layout rinsed well, dry up stand-by, the metope simultaneously brushed first needs certain hour to dry, and is using the flash-off time about 30 minutes of liquid wallpaper of the application.
If continuous pattern splicing is constructed after needing half an hour again, if disconnected pattern or multiple patterns splicing, then can sequential production.
Can also with locating device in the layout of the application, if secondary brushing is carried out in the layout of splicing continuously, only need locating device and brushing justified margin first, or planning reserves corresponding gap and can carry out splicing and brush.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (9)

1. a liquid wallpaper, is characterized in that: comprise by weight percentage:
Described film-forming components is urethane resin and acrylic resin; Described urethane resin accounts for 97.2% of described film-forming components by weight percentage; Described acrylic resin accounts for 2.8% of described film-forming components.
2. liquid wallpaper according to claim 1, is characterized in that: described deionization electrical conductivity of water is less than 5.0 μ S/cm.
3. liquid wallpaper according to claim 1, is characterized in that: the number-average molecular weight of described film-forming components is 5500-8500.
4. liquid wallpaper according to claim 1, is characterized in that: described defoamer is not for containing organosilyl defoamer.
5. liquid wallpaper according to claim 1, is characterized in that: described film coalescence aid is alcohols and ethers modified material ethylene glycol monomethyl ether.
6. liquid wallpaper according to claim 1, is characterized in that: described thickening material is nonionic polyurethane thickening material; Described thickening material is about 20000mPa.s 20 DEG C time, and nonvolatile component is 60%.
7. a layout technique, for liquid wallpaper according to any one of brushing the claims 1 to 6, is characterized in that: comprise the following steps:
Prepare the screen frame that stretches tight, with stretching tight, network folder clamps silk screen, is fixed on base frame by described silk screen; To stretch tight net glue at described silk screen lower surface and the brushing of described base frame contact part; After the described net glue that stretches tight parches, remove described silk screen namely complete described in stretch tight screen frame preparation;
Stretch tight described in use sense optical cement is evenly coated on screen frame tow sides after, drying and processing;
The described screen frame that stretches tight is fitted with design sheet original text, in setting-up time, carries out exposure-processed; The screen frame that stretches tight described in after exposure is through rinsing and drying.
8. layout technique according to claim 7, is characterized in that: the time shutter is 7.5 minutes.
9. layout technique according to claim 7, it is characterized in that: described layout technique also comprises scrapes sample, the described screen frame that stretches tight is compressed article to be undertaken the printing of, described liquid wallpaper is used to carry out blade coating, make described liquid wallpaper through after the described screen frame that stretches tight to described in article to be undertaken the printing of, stretch tight described in removing screen frame, scrapes sample described in completing.
CN201610066111.1A 2016-01-29 2016-01-29 A kind of liquid wallpaper and layout technique Active CN105505176B (en)

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CN105505176B CN105505176B (en) 2018-04-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106010182A (en) * 2016-06-21 2016-10-12 程巧娜 Antistatic liquid decorative wallpaper
CN106116246A (en) * 2016-06-21 2016-11-16 程巧娜 A kind of moistureproof environment protection liquid of resistance to standby wallpaper
CN112172365A (en) * 2020-09-30 2021-01-05 伍海宏 Screen printing method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101157812A (en) * 2007-11-15 2008-04-09 李望龙 Aqueous texture wallpaper paint and method for making same
CN101168988A (en) * 2007-11-15 2008-04-30 李望龙 Construction method for water-based texture wallpaper paint and special-purpose tool for the same
CN101880987A (en) * 2010-06-19 2010-11-10 贺佑康 Low carbon wallpaper paint and preparation method thereof
CN102002297A (en) * 2010-12-10 2011-04-06 现代精密化工(郑州)有限公司 Liquid wall paper paint
CN102049898A (en) * 2009-11-02 2011-05-11 王思力 Technology for producing liquid wallpaper silk screen mould

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101157812A (en) * 2007-11-15 2008-04-09 李望龙 Aqueous texture wallpaper paint and method for making same
CN101168988A (en) * 2007-11-15 2008-04-30 李望龙 Construction method for water-based texture wallpaper paint and special-purpose tool for the same
CN102049898A (en) * 2009-11-02 2011-05-11 王思力 Technology for producing liquid wallpaper silk screen mould
CN101880987A (en) * 2010-06-19 2010-11-10 贺佑康 Low carbon wallpaper paint and preparation method thereof
CN102002297A (en) * 2010-12-10 2011-04-06 现代精密化工(郑州)有限公司 Liquid wall paper paint

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106010182A (en) * 2016-06-21 2016-10-12 程巧娜 Antistatic liquid decorative wallpaper
CN106116246A (en) * 2016-06-21 2016-11-16 程巧娜 A kind of moistureproof environment protection liquid of resistance to standby wallpaper
CN112172365A (en) * 2020-09-30 2021-01-05 伍海宏 Screen printing method
CN112172365B (en) * 2020-09-30 2022-10-28 佛山市顺德区联固印刷有限公司 Screen printing method

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