CN105504905A - Highly wear-resistant transparent coating for metal surface - Google Patents
Highly wear-resistant transparent coating for metal surface Download PDFInfo
- Publication number
- CN105504905A CN105504905A CN201610077552.1A CN201610077552A CN105504905A CN 105504905 A CN105504905 A CN 105504905A CN 201610077552 A CN201610077552 A CN 201610077552A CN 105504905 A CN105504905 A CN 105504905A
- Authority
- CN
- China
- Prior art keywords
- silicate
- sol
- metallic surface
- high abrasion
- dispersion liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 239000011248 coating agent Substances 0.000 title claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 title abstract description 5
- 239000002184 metal Substances 0.000 title abstract description 5
- 239000006185 dispersion Substances 0.000 claims abstract description 21
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000080 wetting agent Substances 0.000 claims abstract description 10
- 239000003112 inhibitor Substances 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000012986 modification Methods 0.000 claims description 22
- 230000004048 modification Effects 0.000 claims description 22
- 238000005299 abrasion Methods 0.000 claims description 21
- 239000003973 paint Substances 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- -1 alkali-metal phosphoric acid salt Chemical class 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 235000019353 potassium silicate Nutrition 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 7
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 7
- 229910000077 silane Inorganic materials 0.000 claims description 7
- 239000004111 Potassium silicate Substances 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052912 lithium silicate Inorganic materials 0.000 claims description 6
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 6
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000001506 calcium phosphate Substances 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000011010 calcium phosphates Nutrition 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 2
- 229910000400 magnesium phosphate tribasic Inorganic materials 0.000 claims description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 2
- 229920000136 polysorbate Chemical class 0.000 claims description 2
- 229950008882 polysorbate Drugs 0.000 claims description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 2
- 229940093916 potassium phosphate Drugs 0.000 claims description 2
- 235000011009 potassium phosphates Nutrition 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 4
- 238000004381 surface treatment Methods 0.000 abstract description 3
- 239000002585 base Substances 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000009835 boiling Methods 0.000 description 3
- 230000003670 easy-to-clean Effects 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000001195 anabolic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a highly wear-resistant transparent coating for a metal surface. The transparent coating comprises the following components: at least one of silicate or sol or organic modified sol, nanometer oxide dispersion, alkali metal phosphates, an inhibitor, a wetting agent and a solvent. Compared with the existing wear-resistant coating, the highly wear-resistant transparent coating for the metal surface disclosed by the invention has high wear resistance, acid and alkali resistance and cleaning simplicity, is suitable for surface treatment of metalware such as kitchen ware and articles for toilet use and has a good effect of protecting base materials. The base material is prevented from being worn, and the surface of the base material has an easy-clean effect.
Description
Technical field
The present invention relates to technical field of coatings, especially relate to a kind of high abrasion Clear paint of metallic surface.
Background technology
Metal base plays very important effect in daily life, is requisite parts in equipment anabolic process.The wear resisting property how improving metal base needs the problem solved always.The wear resisting property of existing metallic substrate surface coating is low, and its adhesion strength and gloss difference, ageing-resistant performance is low.
Summary of the invention
In order to solve above-mentioned prior art problem; the invention provides a kind of high abrasion Clear paint of metallic surface; energy available protecting base material; base material is prevented to be worn; there is higher wear resistance, acid-fast alkali-proof, abrasion resistance and property easy to clean, be suitable for the surface treatments such as kitchen tools, toilet and glass.
Technical scheme of the present invention is: a kind of high abrasion Clear paint of metallic surface, comprises following component: at least one, nano-oxide dispersion liquid, alkali-metal phosphoric acid salt, inhibitor, wetting agent and solvent in silicate or colloidal sol or organics modifications colloidal sol; Wherein,
Described silicate is at least one in lithium silicate, water glass, potassium silicate, Calucium Silicate powder or zirconium silicate;
Described colloidal sol is at least one in silicon sol, Alumina gel;
Described organics modifications colloidal sol is at least one in organics modifications silicon sol or organics modifications Alumina gel;
Described nano-oxide dispersion liquid is at least one in aerosil dispersion liquid, nano calcium oxide dispersion liquid, nano-calcium carbonate dispersion liquid, nano zinc oxide fluid dispersion or nano zircite dispersion liquid;
Described alkali-metal phosphoric acid salt is at least one in trimagnesium phosphate, aluminum phosphate, sodium phosphate, potassiumphosphate and calcium phosphate;
Described inhibitor is at least one in trolamine or diethanolamine;
Described wetting agent is at least one in ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, modified siloxane or polysorbate;
Described solvent is water.
It is 0.5%-3% that the organic components of described organics modifications colloidal sol accounts for modification sol weight ratio, is preferably 1%-2%.
Described organic components is γ-glycidoxypropyltrimethoxysilane alkane or epoxy silane oligomer.
The addition of described wetting agent is 0.01% ~ 2% of coating total amount, is preferably 0.05% ~ 1%;
Preferably, the high abrasion Clear paint of metallic surface of the present invention, it comprises following component by mass percentage: silicate 0-30%, colloidal sol 0-20%, modification sol 0-20%, nano-oxide dispersion liquid 1-5%, alkali-metal phosphoric acid salt 1-5%, inhibitor 1-10%, wetting agent 0.01-2%, water surplus.
Preferably, the high abrasion Clear paint of metallic surface of the present invention, it comprises following component by mass percentage: lithium silicate 7%, sodium silicate 3%, potassium silicate 12%, silicon sol 13%, Alumina gel 2.5%, nano zircite dispersion liquid 2%, aluminum phosphate 2.2%, trolamine 6.5%, modified siloxane 0.8%, water 51%.
Preferably, the high abrasion Clear paint of metallic surface of the present invention, it comprises following component by mass percentage: silicon sol 12.8%, nano zircite dispersion liquid 2%, aluminum phosphate 2.2%, trolamine 6.5%, modified siloxane 0.8%, the water 50% of lithium silicate 7%, sodium silicate 3%, potassium silicate 12%, Alumina gel 3.7%, 2% epoxy silane oligomer modification.
Silicate of the present invention and colloidal sol or the moulding property of modification sol on coating have impact, the ratio of silicate and colloidal sol or modification sol is preferably 1:(0.7-1), the content of colloidal sol or modification sol too much can affect the transparency and the moulding property of coating, make coating transparency not and poor adhesive force coating easily come off.
Organics modifications colloidal sol of the present invention contributes to improving the sticking power of coating, scratch-resistant and water boiling resistance.
Nano-oxide dispersion liquid of the present invention has water-fast, washability, anti-pollution characteristic, contributes to the film-forming properties improving coating, improves sticking power, improve rub resistance, water boiling resistance, the abrasion resistance of paint coatings.
Phosphoric acid salt of the present invention contributes to the wetting ability improving coating, is conducive to the clean of base material.
Beneficial effect of the present invention is: the high abrasion Clear paint of metallic surface of the present invention has higher wear resistance, acid-fast alkali-proof and property easy to clean relative to current wear-resistant paint; be suitable for the surface treatment of the metalware such as kitchen tools, toilet; to base material, there is good provide protection; base material is prevented to be worn; and there is wetting ability, water boiling resistance, make substrate surface have effect easy to clean.
Embodiment
Below in conjunction with specific embodiment, the present invention is further elaborated.
The high abrasion Clear paint of the metallic surface of embodiment 1 to embodiment 5, its each component proportion is in table 1:
Table 1
Prepare coating according to the formula of the embodiment 1 ~ embodiment 7 in table 1, adopt spraying method to make coating on the wire drawing stainless steel plate of 120mm × 150mm; First (as 50 DEG C) toast 10min at low temperatures, then at 180 DEG C of baking 60min; The detection perform of embodiment 1 ~ 5 is in table 2.
Table 2
Can obtain from above-mentioned performance test results: embodiment 1 to embodiment 3 coating properties is more excellent, especially have employed the embodiment 3 of epoxy silane oligomer modified silicasol, although its hydrophilic angle is larger, but its rub resistance power is excellent compared with other embodiments, after 5000 rub(bing)tests, hydrophilic angle is changed to 18 ° from 15 °, change not obvious, visible epoxy silane oligomer modified silicasol has obvious help to the rub resistance improving coating; When embodiment 4 does not adopt nano-oxide dispersion liquid, rub resistance is the poorest, and when embodiment 5 does not adopt aluminum phosphate, its hydrophilic angle is comparatively large and rub resistance is poor.
The epoxy silane oligomer modified silicasol that the present invention uses is purchased from Shin-Etsu Chemial Co., Ltd MP200.
The above; be only preferred embodiment of the present invention; not in order to limit the present invention, every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalently replace and improve, all should be included in the protection domain of technical solution of the present invention.
Claims (10)
1. a high abrasion Clear paint for metallic surface, is characterized in that, comprises following component: at least one, nano-oxide dispersion liquid, alkali-metal phosphoric acid salt, inhibitor, wetting agent and solvent in silicate or colloidal sol or organics modifications colloidal sol; Wherein,
Described silicate is at least one in lithium silicate, water glass, potassium silicate, Calucium Silicate powder or zirconium silicate;
Described colloidal sol is at least one in silicon sol, Alumina gel;
Described organics modifications colloidal sol is at least one in organics modifications silicon sol or organics modifications Alumina gel;
Described nano-oxide dispersion liquid is at least one in aerosil dispersion liquid, nano calcium oxide dispersion liquid, nano-calcium carbonate dispersion liquid, nano zinc oxide fluid dispersion or nano zircite dispersion liquid;
Described alkali-metal phosphoric acid salt is at least one in trimagnesium phosphate, aluminum phosphate, sodium phosphate, potassiumphosphate and calcium phosphate;
Described inhibitor is at least one in trolamine or diethanolamine;
Described wetting agent is at least one in ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, modified siloxane or polysorbate;
Described solvent is water.
2. the high abrasion Clear paint of metallic surface according to claim 1, is characterized in that, it is 0.5%-3% that the organic components in described organics modifications colloidal sol accounts for modification sol weight ratio.
3. the high abrasion Clear paint of metallic surface according to claim 2, is characterized in that, it is 1%-2% that described organic components accounts for modification sol weight ratio.
4. the high abrasion Clear paint of metallic surface according to claim 2, is characterized in that, described organic components is γ-glycidoxypropyltrimethoxysilane alkane or epoxy silane oligomer.
5. the high abrasion Clear paint of metallic surface according to claim 1, is characterized in that, the addition of described wetting agent is 0.01% ~ 2% of coating total amount.
6. the high abrasion Clear paint of metallic surface according to claim 5, is characterized in that, the addition of described wetting agent is 0.05% ~ 1% of coating total amount.
7. the high abrasion Clear paint of metallic surface according to claim 1, it is characterized in that, comprise following component by mass percentage: silicate 0-30%, colloidal sol 0-20%, modification sol 0-20%, nano-oxide dispersion liquid 1-5%, alkali-metal phosphoric acid salt 1-5%, inhibitor 1-10%, wetting agent 0.01-2%, water surplus.
8. the high abrasion Clear paint of the metallic surface according to claim 1 or 7, it is characterized in that, comprise following component by mass percentage: lithium silicate 7%, sodium silicate 3%, potassium silicate 12%, silicon sol 13%, Alumina gel 2.5%, nano zircite dispersion liquid 2%, aluminum phosphate 2.2%, trolamine 6.5%, modified siloxane 0.8%, water 51%.
9. the high abrasion Clear paint of the metallic surface according to claim 1 or 7, it is characterized in that, comprise following component by mass percentage: silicon sol 12.8%, nano zircite dispersion liquid 2%, aluminum phosphate 2.2%, trolamine 6.5%, modified siloxane 0.8%, the water 50% of lithium silicate 7%, sodium silicate 3%, potassium silicate 12%, Alumina gel 3.7%, 2% epoxy silane oligomer modification.
10. the high abrasion Clear paint of metallic surface according to claim 1, is characterized in that, the ratio of described silicate and colloidal sol or modification sol is preferably 1:(0.7-1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610077552.1A CN105504905B (en) | 2016-02-03 | 2016-02-03 | A kind of high abrasion clear dope of metal surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610077552.1A CN105504905B (en) | 2016-02-03 | 2016-02-03 | A kind of high abrasion clear dope of metal surface |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105504905A true CN105504905A (en) | 2016-04-20 |
| CN105504905B CN105504905B (en) | 2018-07-03 |
Family
ID=55713224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610077552.1A Active CN105504905B (en) | 2016-02-03 | 2016-02-03 | A kind of high abrasion clear dope of metal surface |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105504905B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317974A (en) * | 2016-08-23 | 2017-01-11 | 江阴市大阪涂料有限公司 | Modified organic silicon-aluminum organic-solvent-resistant double-component paint and preparation method thereof |
| CN107033642A (en) * | 2017-05-04 | 2017-08-11 | 广州希森美克新材料科技有限公司 | Antifouling wear-resistant paint for metal surface and preparation method thereof |
| CN108977006A (en) * | 2018-06-27 | 2018-12-11 | 安徽国成顺风风力发电有限公司 | A kind of protective coating for aerogenerator vanes and preparation method thereof |
| CN109439042A (en) * | 2018-11-15 | 2019-03-08 | 九牧厨卫股份有限公司 | A kind of hydrophilic surface layer coating, relevant stainless steel sink and preparation method |
| WO2019051753A1 (en) * | 2017-09-14 | 2019-03-21 | 吴金凤 | Preparation method for high wear-resistant and easy-to-clean nano-coating layer |
| CN110054979A (en) * | 2018-01-19 | 2019-07-26 | 中国科学院福建物质结构研究所 | A kind of aqueous coating for plastic and its preparation method and application |
| CN111073360A (en) * | 2019-12-19 | 2020-04-28 | 湖南太子化工涂料有限公司 | Acid-resistant alkali-resistant water-based metal paint for engineering mechanical equipment |
| CN111362589A (en) * | 2020-04-29 | 2020-07-03 | 东莞南玻太阳能玻璃有限公司 | Weather-proof double-layer high-anti-reflection coated glass and preparation method thereof |
| CN111423751A (en) * | 2020-04-10 | 2020-07-17 | 浙江大学 | Efficient antistatic normal-temperature cured phosphate anticorrosive coating and preparation method thereof |
| CN112961520A (en) * | 2021-04-06 | 2021-06-15 | 广州大学 | Water-resistant long-acting inorganic zinc oxide super-hydrophilic coating and preparation method and application thereof |
| CN115537794A (en) * | 2022-09-29 | 2022-12-30 | 东莞市颖兴金属表面处理材料有限公司 | Multifunctional treatment fluid for metal surface and preparation method thereof |
| CN115975408A (en) * | 2022-12-26 | 2023-04-18 | 杭州老板电器股份有限公司 | High-temperature-resistant easy-to-clean inorganic coating, high-temperature-resistant easy-to-clean inorganic coating and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142859A (en) * | 1988-11-24 | 1990-05-31 | O K Furitsuto Service:Kk | Inorganic coating material |
| KR20020007274A (en) * | 2001-12-15 | 2002-01-26 | 정승교 | Agent for surface treatment of concrete structure |
| CN101007920A (en) * | 2007-01-22 | 2007-08-01 | 陈东阜 | Inorganic corrosion-proof fire-resistant abrasive-proof nano cementing agent |
| CN103627227A (en) * | 2013-11-27 | 2014-03-12 | 天津市职业大学 | Solar glass self-cleaning antireflection paint and production method thereof |
| CN103665973A (en) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | Preparation process of inorganic copper imitation coating and process for replacing protective and decorative copper layer of metal surface with inorganic copper imitation coating |
| CN104725903A (en) * | 2015-03-30 | 2015-06-24 | 佛山市新战略知识产权文化有限公司 | Non-sticking wear-resistant high-temperature-resistant paint and preparation method thereof |
-
2016
- 2016-02-03 CN CN201610077552.1A patent/CN105504905B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142859A (en) * | 1988-11-24 | 1990-05-31 | O K Furitsuto Service:Kk | Inorganic coating material |
| KR20020007274A (en) * | 2001-12-15 | 2002-01-26 | 정승교 | Agent for surface treatment of concrete structure |
| CN101007920A (en) * | 2007-01-22 | 2007-08-01 | 陈东阜 | Inorganic corrosion-proof fire-resistant abrasive-proof nano cementing agent |
| CN103627227A (en) * | 2013-11-27 | 2014-03-12 | 天津市职业大学 | Solar glass self-cleaning antireflection paint and production method thereof |
| CN103665973A (en) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | Preparation process of inorganic copper imitation coating and process for replacing protective and decorative copper layer of metal surface with inorganic copper imitation coating |
| CN104725903A (en) * | 2015-03-30 | 2015-06-24 | 佛山市新战略知识产权文化有限公司 | Non-sticking wear-resistant high-temperature-resistant paint and preparation method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317974A (en) * | 2016-08-23 | 2017-01-11 | 江阴市大阪涂料有限公司 | Modified organic silicon-aluminum organic-solvent-resistant double-component paint and preparation method thereof |
| CN107033642B (en) * | 2017-05-04 | 2019-11-08 | 广州希森美克新材料科技有限公司 | Antifouling wear-resistant paint and preparation method thereof for metal surface |
| CN107033642A (en) * | 2017-05-04 | 2017-08-11 | 广州希森美克新材料科技有限公司 | Antifouling wear-resistant paint for metal surface and preparation method thereof |
| WO2019051753A1 (en) * | 2017-09-14 | 2019-03-21 | 吴金凤 | Preparation method for high wear-resistant and easy-to-clean nano-coating layer |
| CN110054979A (en) * | 2018-01-19 | 2019-07-26 | 中国科学院福建物质结构研究所 | A kind of aqueous coating for plastic and its preparation method and application |
| CN108977006A (en) * | 2018-06-27 | 2018-12-11 | 安徽国成顺风风力发电有限公司 | A kind of protective coating for aerogenerator vanes and preparation method thereof |
| CN109439042A (en) * | 2018-11-15 | 2019-03-08 | 九牧厨卫股份有限公司 | A kind of hydrophilic surface layer coating, relevant stainless steel sink and preparation method |
| CN111073360A (en) * | 2019-12-19 | 2020-04-28 | 湖南太子化工涂料有限公司 | Acid-resistant alkali-resistant water-based metal paint for engineering mechanical equipment |
| CN111423751A (en) * | 2020-04-10 | 2020-07-17 | 浙江大学 | Efficient antistatic normal-temperature cured phosphate anticorrosive coating and preparation method thereof |
| CN111362589A (en) * | 2020-04-29 | 2020-07-03 | 东莞南玻太阳能玻璃有限公司 | Weather-proof double-layer high-anti-reflection coated glass and preparation method thereof |
| CN112961520A (en) * | 2021-04-06 | 2021-06-15 | 广州大学 | Water-resistant long-acting inorganic zinc oxide super-hydrophilic coating and preparation method and application thereof |
| CN115537794A (en) * | 2022-09-29 | 2022-12-30 | 东莞市颖兴金属表面处理材料有限公司 | Multifunctional treatment fluid for metal surface and preparation method thereof |
| CN115975408A (en) * | 2022-12-26 | 2023-04-18 | 杭州老板电器股份有限公司 | High-temperature-resistant easy-to-clean inorganic coating, high-temperature-resistant easy-to-clean inorganic coating and application |
| CN115975408B (en) * | 2022-12-26 | 2024-04-26 | 杭州老板电器股份有限公司 | High-temperature-resistant easy-to-clean inorganic coating, high-temperature-resistant easy-to-clean inorganic coating and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105504905B (en) | 2018-07-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105504905A (en) | Highly wear-resistant transparent coating for metal surface | |
| CN105482536B (en) | A kind of transparent antibacterial hydrophilic coating | |
| CN103881494A (en) | Metal anticorrosion antifouling paint | |
| CN101343428B (en) | Porcelain film composition based on siloxane and preparation method thereof | |
| CN101476118A (en) | Universal metallic surface silanization treating agent, preparation and use thereof | |
| CN103756377A (en) | Modified silicate waterborne zinc-rich anticorrosive coating employing organic montmorillonite as anti-settling dispersant | |
| TW200734283A (en) | Adhesive protective coatings, non-line of sight methods for their preparation, and coated articles | |
| CN107033642B (en) | Antifouling wear-resistant paint and preparation method thereof for metal surface | |
| CN108410321A (en) | A kind of water-base epoxy graphene inorganic scale anticorrosive paint | |
| JP5753871B2 (en) | Metal protective coating, its use, and hot dip metal material using it | |
| CN105176328B (en) | A kind of high performance alloys matrix anticorrosive paint and preparation method thereof | |
| CN109439042A (en) | A kind of hydrophilic surface layer coating, relevant stainless steel sink and preparation method | |
| CN107841175A (en) | A kind of chromium-free Dyclo paint of rub resistance | |
| CN102847671B (en) | Method for coating non-adhesive coating on surface of elevator or staircase and non-adhesive coating | |
| Wei et al. | Superior mechanical properties of hybrid organic-inorganic superhydrophilic thin film on plastic substrate | |
| CN109554110A (en) | A kind of thermostable heat-conductive self-cleaning coating and preparation method thereof | |
| CN108047774A (en) | For coating the Nano-meter SiO_2 of valve2Modified inorganic coating | |
| CN111995910B (en) | Anticorrosive paint for heat exchanger and preparation method thereof | |
| CN107955514A (en) | A kind of corrosion-proof fire-resistant coating | |
| CN209368169U (en) | A kind of steel construction high-temperature resistant anti-corrosive erosion resisting coating | |
| CN111073360A (en) | Acid-resistant alkali-resistant water-based metal paint for engineering mechanical equipment | |
| CN203864102U (en) | Trivalent chromium passivation protective layer | |
| CN109943200A (en) | Old pump transformation super hydrophobic coating of one kind and its preparation method and application | |
| CN109468036A (en) | A kind of acids enamel paint of environmental-friendly lead-free alcohol | |
| CN104341904A (en) | Bright water-based plastic paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Highly wear-resistant transparent coating for metal surface Effective date of registration: 20190701 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: 2019440000247 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Ke Feng Lu Science City, Guangzhou hi tech Development Zone in Guangdong province 510000 No. 31 Southern China new material innovation park building G2 321 Patentee after: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Address before: Ke Feng Lu Science City, Guangzhou hi tech Development Zone in Guangdong province 510000 No. 31 Southern China new material innovation park building G2 321 Patentee before: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200826 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: 2019440000247 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high wear resistant transparent coating for metal surface Effective date of registration: 20200826 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2020980005427 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP02 | Change in the address of a patent holder |
Address after: Room 601, G11 building, South China new materials innovation park, No.31 Kefeng Road, Science City, Guangzhou high tech Industrial Development Zone, Guangdong Province 510000 Patentee after: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Address before: Ke Feng Lu Science City, Guangzhou hi tech Development Zone in Guangdong province 510000 No. 31 Southern China new material innovation park building G2 321 Patentee before: Guangzhou Hisense Meike New Material Technology Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20211020 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2020980005427 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high wear-resistant transparent coating for metal surface Effective date of registration: 20211022 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2021980011154 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230223 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2021980011154 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |