CN105504812A - Anti-impact engineering plastic - Google Patents

Anti-impact engineering plastic Download PDF

Info

Publication number
CN105504812A
CN105504812A CN201510961413.0A CN201510961413A CN105504812A CN 105504812 A CN105504812 A CN 105504812A CN 201510961413 A CN201510961413 A CN 201510961413A CN 105504812 A CN105504812 A CN 105504812A
Authority
CN
China
Prior art keywords
parts
engineering plastic
engineering plastics
shock resistance
impact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510961413.0A
Other languages
Chinese (zh)
Inventor
王长华
刘倩灵
赖玉蒸
谭富来
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN CITY CAS ENVIRONMENT AND SAFETY TESTING & CERTIFICATION CENTER Co Ltd
Original Assignee
FOSHAN CITY CAS ENVIRONMENT AND SAFETY TESTING & CERTIFICATION CENTER Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FOSHAN CITY CAS ENVIRONMENT AND SAFETY TESTING & CERTIFICATION CENTER Co Ltd filed Critical FOSHAN CITY CAS ENVIRONMENT AND SAFETY TESTING & CERTIFICATION CENTER Co Ltd
Priority to CN201510961413.0A priority Critical patent/CN105504812A/en
Publication of CN105504812A publication Critical patent/CN105504812A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention discloses anti-impact engineering plastic. The anti-impact engineering plastic is prepared from, by weight, 30-45 parts of polyester polyol, 35-45 parts of PPS, 24-30 parts of polybutadiene epoxy resin, 15-18 parts of stearic acid, 10-15 parts of polyvinyl alcohol fiber, 3-12 parts of carbon black, 2-8 parts of plasticizer and 1-2 parts of triphenyl phosphate. The anti-impact engineering plastic has tenacity higher than that of universal products, the anti-impact performance of the anti-impact engineering plastic is obviously better than that of present frequently-seen special engineering plastic, and meanwhile the existing high flame retardation is kept. Thus, the material can have high tenacity and good flame retardation and can be widely applied to the fields of aerospace, electronic products and military.

Description

A kind of shock resistance engineering plastics
Technical field
The present invention relates to polymeric material field, particularly relate to a kind of shock resistance engineering plastics.
Background technology
The special engineering plastics of the field such as current electronic apparatus, aerospace, Automobile Transportation, machinery and chemical industry application can realize excellent high temperature resistant, corrosion-resistant, radiation hardness and flame retardant properties, but common special engineering plastics simultaneously also ubiquity poor toughness, the problem that impact resistance is weak, this defect strongly limit the application of special engineering plastics.
Therefore, prior art also needs to further develop and improve.
Summary of the invention
The object of the present invention is to provide a kind of shock resistance engineering plastics, aim to provide one and there is superpower toughness, the special engineering plastics of strong shock resistance.
Technical scheme of the present invention is as follows:
A kind of shock resistance engineering plastics, wherein, it is composed of the following components by weight:
Polyester polyol 30 ~ 45 parts;
PPS35 ~ 45 part;
Polybutadiene epoxy resin 24 ~ 30 parts
Stearic acid 15 ~ 18 parts;
Polyvinyl alcohol fiber 10 ~ 15 parts;
Carbon black 3 ~ 12 parts;
2 ~ 8 parts, softening agent;
Triphenylphosphate 1 ~ 2 part.
Described shock resistance engineering plastics, wherein, it is composed of the following components by weight:
Polyester polyol 38 parts;
PPS40 part;
Polybutadiene epoxy resin 26 parts
Stearic acid 15 parts;
Polyvinyl alcohol fiber 12 parts;
Carbon black 6 parts;
6 parts, softening agent;
Triphenylphosphate 1 part.
Described shock resistance engineering plastics, wherein, it is composed of the following components by weight:
Polyester polyol 40 parts;
PPS35 part;
Polybutadiene epoxy resin 28 parts
Stearic acid 18 parts;
Polyvinyl alcohol fiber 15 parts;
Carbon black 10 parts;
2 parts, softening agent;
Triphenylphosphate 1 part.
Described shock resistance engineering plastics, wherein: described catalyzer is one or more in triethylamine, trolamine, stannous octoate, triethylene diamine.
Beneficial effect: the invention provides a kind of shock resistance engineering plastics, this special type composite material has the toughness stronger than the universal product, its shock resistance is obviously better than special engineering plastics common at present, and this project plastics also retains original high flame resistance simultaneously.Thus make this material have high tenacity and good flame-retardance, can aerospace be widely used in, electronic apparatus, military industry field.
Embodiment
For making object of the present invention, technical scheme and advantage clearly, clearly, the present invention is described in more detail below.
The invention provides a kind of shock resistance engineering plastics, wherein, it is composed of the following components by weight:
Polyester polyol 30 ~ 45 parts;
PPS35 ~ 45 part;
Polybutadiene epoxy resin 24 ~ 30 parts
Stearic acid 15 ~ 18 parts;
Polyvinyl alcohol fiber 10 ~ 15 parts;
Carbon black 3 ~ 12 parts;
2 ~ 8 parts, softening agent;
Triphenylphosphate 1 ~ 2 part.
Wherein, it is preferred that described catalyzer is one or more in triethylamine, trolamine, stannous octoate, triethylene diamine.
Technical scheme of the present invention is set forth further below by embodiment.
Embodiment 1
Described shock resistance engineering plastics, wherein, it is composed of the following components by weight:
Polyester polyol 38 parts;
PPS40 part;
Polybutadiene epoxy resin 26 parts
Stearic acid 15 parts;
Polyvinyl alcohol fiber 12 parts;
Carbon black 6 parts;
6 parts, softening agent;
Triphenylphosphate 1 part.
Embodiment 2
Described shock resistance engineering plastics, wherein, it is composed of the following components by weight:
Polyester polyol 40 parts;
PPS35 part;
Polybutadiene epoxy resin 28 parts
Stearic acid 18 parts;
Polyvinyl alcohol fiber 15 parts;
Carbon black 10 parts;
2 parts, softening agent;
Triphenylphosphate 1 part.
The invention provides a kind of shock resistance engineering plastics, this special type composite material has the toughness stronger than the universal product, and its shock resistance is obviously better than special engineering plastics common at present, and this project plastics also retains original high flame resistance simultaneously.Thus make this material have high tenacity and good flame-retardance, can aerospace be widely used in, electronic apparatus, military industry field.
Should be understood that, application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.

Claims (4)

1. shock resistance engineering plastics, is characterized in that, it is composed of the following components by weight:
Polyester polyol 30 ~ 45 parts;
PPS35 ~ 45 part;
Polybutadiene epoxy resin 24 ~ 30 parts
Stearic acid 15 ~ 18 parts;
Polyvinyl alcohol fiber 10 ~ 15 parts;
Carbon black 3 ~ 12 parts;
2 ~ 8 parts, softening agent;
Triphenylphosphate 1 ~ 2 part.
2. shock resistance engineering plastics according to claim 1, it is characterized in that, it is composed of the following components by weight:
Polyester polyol 38 parts;
PPS40 part;
Polybutadiene epoxy resin 26 parts
Stearic acid 15 parts;
Polyvinyl alcohol fiber 12 parts;
Carbon black 6 parts;
6 parts, softening agent;
Triphenylphosphate 1 part.
3. shock resistance engineering plastics according to claim 1, it is characterized in that, it is composed of the following components by weight:
Polyester polyol 40 parts;
PPS35 part;
Polybutadiene epoxy resin 28 parts
Stearic acid 18 parts;
Polyvinyl alcohol fiber 15 parts;
Carbon black 10 parts;
2 parts, softening agent;
Triphenylphosphate 1 part.
4. shock resistance engineering plastics according to claim 1, is characterized in that: described catalyzer is one or more in triethylamine, trolamine, stannous octoate, triethylene diamine.
CN201510961413.0A 2015-12-21 2015-12-21 Anti-impact engineering plastic Pending CN105504812A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510961413.0A CN105504812A (en) 2015-12-21 2015-12-21 Anti-impact engineering plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510961413.0A CN105504812A (en) 2015-12-21 2015-12-21 Anti-impact engineering plastic

Publications (1)

Publication Number Publication Date
CN105504812A true CN105504812A (en) 2016-04-20

Family

ID=55713132

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510961413.0A Pending CN105504812A (en) 2015-12-21 2015-12-21 Anti-impact engineering plastic

Country Status (1)

Country Link
CN (1) CN105504812A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040387A (en) * 2019-12-28 2020-04-21 广东生益科技股份有限公司 Halogen-free resin composition and flexible copper clad laminate comprising same

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1216021A (en) * 1996-12-16 1999-05-05 东丽株式会社 Conductive multilayer blow molding and conductive resin composition
CN101208380A (en) * 2005-06-25 2008-06-25 赢创德固赛有限责任公司 Thermoplastic compound/matrix
CN102942684A (en) * 2012-11-08 2013-02-27 广东生益科技股份有限公司 Thermosetting cyanate resin composition and application of thermosetting cyanate resin composition
CN103965631A (en) * 2014-04-23 2014-08-06 安徽依采妮纤维材料科技有限公司 Polyropylene fiber modified polyphenyl thioether material for automobile plastic part
CN104672902A (en) * 2013-12-02 2015-06-03 上海杰事杰新材料(集团)股份有限公司 Impact-resistant conductive polyphenylene sulfide material and preparation method thereof
CN104845369A (en) * 2015-05-11 2015-08-19 深圳华力兴新材料股份有限公司 Hyperbranched resin-toughened PPS (polyphenylene sulfite) engineering plastic and preparation method thereof
CN104974525A (en) * 2015-07-22 2015-10-14 广州高八二塑料有限公司 Polyvinyl-alcohol-fiber-reinforced polyphenyl thioether composite material and preparation method thereof
CN105062032A (en) * 2015-08-17 2015-11-18 苏州凯欧曼新材料科技有限公司 Impact-resistant thermally-conductive polymer material and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1216021A (en) * 1996-12-16 1999-05-05 东丽株式会社 Conductive multilayer blow molding and conductive resin composition
CN101208380A (en) * 2005-06-25 2008-06-25 赢创德固赛有限责任公司 Thermoplastic compound/matrix
CN102942684A (en) * 2012-11-08 2013-02-27 广东生益科技股份有限公司 Thermosetting cyanate resin composition and application of thermosetting cyanate resin composition
CN104672902A (en) * 2013-12-02 2015-06-03 上海杰事杰新材料(集团)股份有限公司 Impact-resistant conductive polyphenylene sulfide material and preparation method thereof
CN103965631A (en) * 2014-04-23 2014-08-06 安徽依采妮纤维材料科技有限公司 Polyropylene fiber modified polyphenyl thioether material for automobile plastic part
CN104845369A (en) * 2015-05-11 2015-08-19 深圳华力兴新材料股份有限公司 Hyperbranched resin-toughened PPS (polyphenylene sulfite) engineering plastic and preparation method thereof
CN104974525A (en) * 2015-07-22 2015-10-14 广州高八二塑料有限公司 Polyvinyl-alcohol-fiber-reinforced polyphenyl thioether composite material and preparation method thereof
CN105062032A (en) * 2015-08-17 2015-11-18 苏州凯欧曼新材料科技有限公司 Impact-resistant thermally-conductive polymer material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040387A (en) * 2019-12-28 2020-04-21 广东生益科技股份有限公司 Halogen-free resin composition and flexible copper clad laminate comprising same
CN111040387B (en) * 2019-12-28 2022-06-03 广东生益科技股份有限公司 Halogen-free resin composition and flexible copper clad laminate comprising same

Similar Documents

Publication Publication Date Title
EP2383311B1 (en) High-strength polyphenylene sulfide/polyethylene terephthalate blended resin composition and a production method therefor
CN107216542B (en) Halogen-free flame-retardant polypropylene material
CN1995130A (en) Halogen-free environment-friendly flame-proof polyoxymethylene resin and its preparation method
CN104861595A (en) Halogen-free flame retardant PBT material and preparation method thereof
CN105385032A (en) Isotropous polypropylene compound and preparation method thereof
CN103030905A (en) High-strength and high-stability modified PVC and preparation method thereof
KR20140092454A (en) Polyphenylenesulfide resins composition
CN103059447A (en) Environment-friendly flame retardant polyvinyl chloride wire and cable material
CN109867935A (en) High fire-retardance high rigidity PC/ABS material and products thereof
CN105504812A (en) Anti-impact engineering plastic
CN104497522A (en) Composite material used for automobile interior decorative parts
WO2018036039A1 (en) Flame-retardant carbon fiber-reinforced polyketone composite material
CN101445654B (en) Material of filling and glass fibre reinforced nylon 6 and preparation method thereof
CN105086437A (en) Anti-static polyamide composite material and preparation method thereof
CN104086989A (en) High-impact renewable carbon fiber ball-modified carbon fiber composite material and preparation method thereof
CN103665611A (en) Anticorrosive polyvinyl chloride plastic
CN104788915B (en) A kind of weather-proof polybutylene terephthalate (PBT) composite and preparation method thereof
CN103525010A (en) High-strength engineering plastic
CN105400050A (en) High-strength environment-friendly plastic
CN104693802A (en) High-strength polyphenylene sulfide composite material and preparation method thereof
CN103194034A (en) Reinforced flame-retardant POM (Polyoxymethylene) material and preparation method thereof
CN106750878A (en) Hollow glass micropearl filling modified polypropylene material
CN106800700A (en) Hollow glass micropearl filling modified polypropylene material
CN105038148A (en) Plastic product material
CN104962072A (en) Flame-retardant PPO/PA (poly-p-phenylene oxide /poly-A) alloy

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160420

WD01 Invention patent application deemed withdrawn after publication