CN105504710A - Composite automobile interior decorating piece capable of being resistant to acid and alkali wiping and preparation method thereof - Google Patents
Composite automobile interior decorating piece capable of being resistant to acid and alkali wiping and preparation method thereof Download PDFInfo
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- CN105504710A CN105504710A CN201510912650.8A CN201510912650A CN105504710A CN 105504710 A CN105504710 A CN 105504710A CN 201510912650 A CN201510912650 A CN 201510912650A CN 105504710 A CN105504710 A CN 105504710A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a composite automobile interior decorating piece capable of being resistant to acid and alkali wiping. The composite automobile interior decorating piece is prepared from the following raw materials in parts by weight: 100 to 103 parts of polylactic acid, 3.5 to 4 parts of nanometer antimony trioxide, 10 to 11 parts of decabromodiphenyl ethane, 25 to 27 parts of SEBS, 60 to 62 parts of ambary fiber, 9 to 10 parts of straw, 7 to 8 parts of basalt powder, 5 to 6 parts of polytetrafluoroethylene emulsion, 2 to 3 parts of dimethyl polysiloxane, 5 to 6 parts of sodium alginate, an appropriate amount of water, and 1 to 1.3 parts of alkali resistant penetrating agent AEP. The composite automobile interior decorating piece adopts mixed fiber dipped into pulp modified by components including the straw, the polytetrafluoroethylene emulsion and the basalt powder, has the effect of acid and alkaline corrosion resistance, is environmentally friendly and natural, has excellent bending resistance, has no fractures and cracks on the surface, and is cold-proof, flame-retardant, fireproof, acid and alkali wiping resistant, long in service life, and applicable to manufacture of automobile platform surfaces and automobile instruments.
Description
Technical field
The present invention relates to automotive interior material technical field, particularly relate to a kind of can the composite automobile inner decoratire part material and preparation method thereof of acid and alkali-resistance wiping.
Background technology
The inside gadget of car generally refers to component and the material such as dividing plate, door panel, panel assembly, handrail, carpet of car.For other parts on car, they do not have anything to affect on the operating performance of vehicle, but its appearance is covered all at one glance, and represent the image of whole car, which is better and which is worse, decide reputation and the class of car, decide the purpose that people select car.In addition, for car, although the inside gadget spare and accessory parts that to be some complementary, they will bear vibration damping, heat insulation, the function such as sound-absorbing and screening sound, play very important effect to the comfortableness of car.Automobile industry while flourish, also brings environmental pollution and the serious greatly negative impact of energy shortage two all over the world.According to investigations, nearly 35% used as the fuel of automobile in oil consumption product, along with consuming excessively of petroleum resources, automobile industry must be adjusted accordingly, and lightweight and energy-conserving and environment-protective become the theme of international automobile industrial research.
Biodegradable high-molecular and goods thereof are focuses of various countries scientist research in the last few years, exploitation, production, developed country not only government's substantial contribution drops into, and also drops into a large amount of people's material resourcess to major company, scientific research institution and university research department and researches and develops.Because poly(lactic acid) has excellent biological degradability and biocompatibility, be finally decomposed into carbonic acid gas and water in the environment, environment is not polluted, therefore one of study hotspot becoming degradable material.Polylactic resin derives from the biological raw material of non-petroleum base, there is again good over-all properties, receive attention and the favor of automobile industry, the Japanese firms such as Toyota, Mitsubishi, Mazda have taken the lead in applying poly(lactic acid) interior products on its brand automobile, domestic if Chery Automobiles is also at the automobile-used poly-lactic acid products of exploitation.But due to crystallization of polylactic acid resin speed very slow, moulded products shrinking percentage is large, and matter own is crisp, and processing heat stability is poor, and the shortcoming such as goods poor durability, limits its application as engineering plastics.Therefore, in the urgent need to carrying out activeness and quietness, the multiple elements design study on the modification such as heat-resisting to green plastic polylactic resin.Add automobile fire phenomenon frequently to occur, private car fire is in rising trend, the reason of automobile fire is because automobile self-technique level is uneven on the one hand, on the other hand automobile self uses in structured material that some is inflammable material, comprises automotive trim macromolecular material polypropylene, polycarbonate and degradation material poly(lactic acid) etc.Therefore, the flame retardant resistance of poly-lactic acid material is also needed to carry out modification.Simultaneously because car noise brings very large impact to occupant in the process of moving, be directly connected to the health of occupant.So car noise just becomes the major criterion weighing automobile its own mechanical performance and comfort property quality.So, be badly in need of a kind of automotive interior material having the functions such as environmental protection, fire-retardant, sound-absorbing concurrently of invention.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provide a kind of can the composite automobile inner decoratire part material and preparation method thereof of acid and alkali-resistance wiping.
The present invention is achieved by the following technical solutions:
Can the composite automobile inner decoratire part material of acid and alkali-resistance wiping, be made up of the raw material of following weight part: poly(lactic acid) 100-103, nanmeter antimong trioxide 3.5-4, TDE 10-11, SEBS25-27, bastose 60-62, straw 9-10, basalt stone flour 7-8, ptfe emulsion 5-6, polydimethylsiloxane 2-3, sodium alginate 5-6, water are appropriate, alkali-resistant penetrant AEP1-1.3.
The matrix material of described a kind of automotive trim opposing ultraviolet ageing, be made up of following concrete steps:
(1) by stand-by for poly(lactic acid) 80 DEG C of dryings 10 hours in vacuum drying oven, nanmeter antimong trioxide, TDE respectively in baking oven at 60 DEG C dry 5 hours and 8 hours stand-by; Dried material is put into homogenizer, after stirring 10 minutes with the speed of 1000 revs/min, add SEBS, mixture is sent into the temperature at 175 DEG C in twin screw extruder by continuation stirring after 10 minutes, screw speed is extruding pelletization under the processing condition of 150 revs/min, obtains polydactyl acid master batch;
(2) will polydactyl acid master batch send in extruder type spinning machine carry out blended melting and extruding spinning (controlling Screw Extrusion speed is 250 revs/min, spray silk melt temperature controls at 200 DEG C), then the protofilament of ejection is cooled through water-bath, control bath temperature at 20 DEG C, by the warm air drying of fiber with 120-130 DEG C after water-bath cooling, obtain modified polylactic acid fiber; Bastose is carried out shredding process, and the bastose after process and modified polylactic acid fiber carry out blending drafting, obtain blend fiber bar;
(3) straw is put into baking oven with the temperature of 90 DEG C drying 3 hours, then segment is shredded into, send in pulverizer and be ground into rice straw powder, cross 200 mesh sieves, then mix with basalt stone flour, put into shredder, add ptfe emulsion and grind 2 hours, pour out post-drying and pulverized 400 mesh sieves, form modified powder; Sodium alginate is put into stirring tank, adds the water of 30 times amount, be heated to 40 DEG C, be stirred to after dissolving completely and add alkali-resistant penetrant AEP, after stirring 10 minutes with the speed of 200 revs/min, count above-mentioned modified powder, stir 30 minutes with the speed of 300 revs/min, obtain dipping sizing agent;
(4) the blend fiber bar that step (2) obtains is put into dipping sizing agent process to take out after 30 minutes, put into air dry oven, be dried to water content with the temperature of 90 DEG C and be less than 0.2%, then the blend fiber bar of drying is imported twin screw extruder, controlling extrusion temperature is 170 DEG C, and namely extruding pelletization obtains material of the present invention.
Advantage of the present invention is: first the present invention adds nanmeter antimong trioxide, in the polymeric material scattered, can form shell at burning surface, plays heat insulation and intercepts the effect that inflammable gas moves to burning surface; The interpolation of collaborative TDE, react with nanmeter antimong trioxide the antimony tribro-generated, slow down further or stop combustion reactions, play good flame retardant effect, improve the shock strength of polymkeric substance, elongation at break, flow rate, there is good molding processibility; Simultaneously using the toughner of SEBS as poly(lactic acid), the modified polylactic acid fiber made is made to have good toughness, simultaneously the shock strength of the great improving product of energy.
Blend fiber is immersed in containing in the modified slurry of the compositions such as straw, ptfe emulsion, basalt stone flour by the present invention, has effect of acid-alkali-corrosive-resisting; Material environment friendly of the present invention is natural, has excellent anti-bending strength, surperficial crack-free, be full of cracks, cold-proof, fire-retardant fireproof, acid and alkali-resistance wiping, long service life, is applicable to manufacturing automobile table top, automobile instrument panel etc.
Embodiment
Can the composite automobile inner decoratire part material of acid and alkali-resistance wiping, be made up of the raw material of following weight part (kilogram): poly(lactic acid) 100, nanmeter antimong trioxide 3.5, TDE 10, SEBS25, bastose 60, straw 9, basalt stone flour 7, ptfe emulsion 5, polydimethylsiloxane 2, sodium alginate 5, water are appropriate, alkali-resistant penetrant AEP1.
The matrix material of described a kind of automotive trim opposing ultraviolet ageing, be made up of following concrete steps:
(1) by stand-by for poly(lactic acid) 80 DEG C of dryings 10 hours in vacuum drying oven, nanmeter antimong trioxide, TDE respectively in baking oven at 60 DEG C dry 5 hours and 8 hours stand-by; Dried material is put into homogenizer, after stirring 10 minutes with the speed of 1000 revs/min, add SEBS, mixture is sent into the temperature at 175 DEG C in twin screw extruder by continuation stirring after 10 minutes, screw speed is extruding pelletization under the processing condition of 150 revs/min, obtains polydactyl acid master batch;
(2) will polydactyl acid master batch send in extruder type spinning machine carry out blended melting and extruding spinning (controlling Screw Extrusion speed is 250 revs/min, spray silk melt temperature controls at 200 DEG C), then the protofilament of ejection is cooled through water-bath, control bath temperature at 20 DEG C, by the warm air drying of fiber with 120 DEG C after water-bath cooling, obtain modified polylactic acid fiber; Bastose is carried out shredding process, and the bastose after process and modified polylactic acid fiber carry out blending drafting, obtain blend fiber bar;
(3) straw is put into baking oven with the temperature of 90 DEG C drying 3 hours, then segment is shredded into, send in pulverizer and be ground into rice straw powder, cross 200 mesh sieves, then mix with basalt stone flour, put into shredder, add ptfe emulsion and grind 2 hours, pour out post-drying and pulverized 400 mesh sieves, form modified powder; Sodium alginate is put into stirring tank, adds the water of 30 times amount, be heated to 40 DEG C, be stirred to after dissolving completely and add alkali-resistant penetrant AEP, after stirring 10 minutes with the speed of 200 revs/min, count above-mentioned modified powder, stir 30 minutes with the speed of 300 revs/min, obtain dipping sizing agent;
(4) the blend fiber bar that step (2) obtains is put into dipping sizing agent process to take out after 30 minutes, put into air dry oven, be dried to water content with the temperature of 90 DEG C and be less than 0.2%, then the blend fiber bar of drying is imported twin screw extruder, controlling extrusion temperature is 170 DEG C, and namely extruding pelletization obtains material of the present invention.
Material of the present invention directly through injection moulding machine injection moulding, can make various automotive upholstery.The material that the present invention makes is through detecting, and flame retardant properties reaches UL-94V-0 level, and flexural strength is 105.1MPa, and shock strength is 110J/m.
Claims (2)
1. one kind can the composite automobile inner decoratire part material of acid and alkali-resistance wiping, it is characterized in that, be made up of the raw material of following weight part: poly(lactic acid) 100-103, nanmeter antimong trioxide 3.5-4, TDE 10-11, SEBS25-27, bastose 60-62, straw 9-10, basalt stone flour 7-8, ptfe emulsion 5-6, polydimethylsiloxane 2-3, sodium alginate 5-6, water are appropriate, alkali-resistant penetrant AEP1-1.3.
2. a kind of automotive trim resists the matrix material of ultraviolet ageing according to claim 1, it is characterized in that, is made up of following concrete steps:
(1) by stand-by for poly(lactic acid) 80 DEG C of dryings 10 hours in vacuum drying oven, nanmeter antimong trioxide, TDE respectively in baking oven at 60 DEG C dry 5 hours and 8 hours stand-by; Dried material is put into homogenizer, after stirring 10 minutes with the speed of 1000 revs/min, add SEBS, mixture is sent into the temperature at 175 DEG C in twin screw extruder by continuation stirring after 10 minutes, screw speed is extruding pelletization under the processing condition of 150 revs/min, obtains polydactyl acid master batch;
(2) will polydactyl acid master batch send in extruder type spinning machine carry out blended melting and extruding spinning (controlling Screw Extrusion speed is 250 revs/min, spray silk melt temperature controls at 200 DEG C), then the protofilament of ejection is cooled through water-bath, control bath temperature at 20 DEG C, by the warm air drying of fiber with 120-130 DEG C after water-bath cooling, obtain modified polylactic acid fiber; Bastose is carried out shredding process, and the bastose after process and modified polylactic acid fiber carry out blending drafting, obtain blend fiber bar;
(3) straw is put into baking oven with the temperature of 90 DEG C drying 3 hours, then segment is shredded into, send in pulverizer and be ground into rice straw powder, cross 200 mesh sieves, then mix with basalt stone flour, put into shredder, add ptfe emulsion and grind 2 hours, pour out post-drying and pulverized 400 mesh sieves, form modified powder; Sodium alginate is put into stirring tank, adds the water of 30 times amount, be heated to 40 DEG C, be stirred to after dissolving completely and add alkali-resistant penetrant AEP, after stirring 10 minutes with the speed of 200 revs/min, count above-mentioned modified powder, stir 30 minutes with the speed of 300 revs/min, obtain dipping sizing agent;
(4) the blend fiber bar that step (2) obtains is put into dipping sizing agent process to take out after 30 minutes, put into air dry oven, be dried to water content with the temperature of 90 DEG C and be less than 0.2%, then the blend fiber bar of drying is imported twin screw extruder, controlling extrusion temperature is 170 DEG C, and namely extruding pelletization obtains material of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510912650.8A CN105504710A (en) | 2015-12-11 | 2015-12-11 | Composite automobile interior decorating piece capable of being resistant to acid and alkali wiping and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510912650.8A CN105504710A (en) | 2015-12-11 | 2015-12-11 | Composite automobile interior decorating piece capable of being resistant to acid and alkali wiping and preparation method thereof |
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| CN105504710A true CN105504710A (en) | 2016-04-20 |
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| CN201510912650.8A Pending CN105504710A (en) | 2015-12-11 | 2015-12-11 | Composite automobile interior decorating piece capable of being resistant to acid and alkali wiping and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108939172A (en) * | 2018-08-13 | 2018-12-07 | 瞿向东 | A kind of degradation material for disposable uterine probe |
| CN115160750A (en) * | 2022-07-26 | 2022-10-11 | 扬州丽华汽车内饰件有限公司 | Environment-friendly degradable jute fiber reinforced polylactic acid composite material and preparation method thereof |
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| CN101260228A (en) * | 2008-04-24 | 2008-09-10 | 同济大学 | Method for preparing natural fiber/polylactic acid composite material with anti-flaming function |
| CN101691045A (en) * | 2009-10-14 | 2010-04-07 | 奇瑞汽车股份有限公司 | Plate and manufacture method thereof |
| CN102717577A (en) * | 2012-07-04 | 2012-10-10 | 北京汽车股份有限公司 | Environment-friendly composite material for automobile decoration and preparation method as well as application thereof |
| CN102746625A (en) * | 2012-07-02 | 2012-10-24 | 同济大学 | Natural fiber reinforced polylactic acid composite material with halogen-free flame retardant and method for preparing same |
-
2015
- 2015-12-11 CN CN201510912650.8A patent/CN105504710A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260228A (en) * | 2008-04-24 | 2008-09-10 | 同济大学 | Method for preparing natural fiber/polylactic acid composite material with anti-flaming function |
| CN101691045A (en) * | 2009-10-14 | 2010-04-07 | 奇瑞汽车股份有限公司 | Plate and manufacture method thereof |
| CN102746625A (en) * | 2012-07-02 | 2012-10-24 | 同济大学 | Natural fiber reinforced polylactic acid composite material with halogen-free flame retardant and method for preparing same |
| CN102717577A (en) * | 2012-07-04 | 2012-10-10 | 北京汽车股份有限公司 | Environment-friendly composite material for automobile decoration and preparation method as well as application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108939172A (en) * | 2018-08-13 | 2018-12-07 | 瞿向东 | A kind of degradation material for disposable uterine probe |
| CN108939172B (en) * | 2018-08-13 | 2020-12-25 | 台州市中心医院（台州学院附属医院） | Degradable material for disposable uterine probe |
| CN115160750A (en) * | 2022-07-26 | 2022-10-11 | 扬州丽华汽车内饰件有限公司 | Environment-friendly degradable jute fiber reinforced polylactic acid composite material and preparation method thereof |
| CN115160750B (en) * | 2022-07-26 | 2024-04-02 | 扬州丽华汽车内饰件有限公司 | Environment-friendly degradable jute fiber reinforced polylactic acid composite material and preparation method thereof |
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Application publication date: 20160420 |