CN105504510A - High cold-resistant toughening masterbatch and preparation method thereof - Google Patents
High cold-resistant toughening masterbatch and preparation method thereof Download PDFInfo
- Publication number
- CN105504510A CN105504510A CN201610002187.8A CN201610002187A CN105504510A CN 105504510 A CN105504510 A CN 105504510A CN 201610002187 A CN201610002187 A CN 201610002187A CN 105504510 A CN105504510 A CN 105504510A
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- cold
- resistant
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- female
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses high cold-resistant toughening masterbatch. The high cold-resistant toughening masterbatch is prepared from 40-60 parts of polypropylene resin, 30-40 parts of color powder, 5-10 parts of a dispersing agent, 10-20 parts of a plasticizer, 1-5 parts of a coupling agent, 0.5-1 part of an antioxidant, 30-40 parts of a cold-resistant modifying agent, 10-20 parts of a reinforcing modifying agent and 10-20 parts of a toughening agent; a mixture of one or more of nano calcium carbonate, nano silicon and nano barium sulfate is adopted as the reinforcing modifying agent, and a mixture of one or more of a methacrylate-acrylate copolymer (ACR), a methyl methacrylate-butadiene-styrene ternary graft copolymer (MBS) and ethylene-methyl acrylate-glycidyl methacrylate (E-MA-GMA) is adopted as the toughening agent. According to the high cold-resistant toughening masterbatch, by adding the cold-resistant modifying agent, the reinforcing modifying agent and the toughening agent, the masterbatch can not generate toughness changes in an extremely cold environment in the using process, and the service life of the masterbatch is greatly prolonged.
Description
Technical field
The present invention relates to look female preparing technical field, particularly relate to a kind of high cold-resistant toughened look mother and preparation method thereof.
Background technology
Plastic cement formed primarily of carbon, oxygen, hydrogen and nitrogen and other organic or inorganic elements, and the plasthetics of different shape, color can be formed, be widely used in each field in the modern life at present, such as household electrical appliance, instrument, electric wire, construction equipment, communication electronics, automotive industry, aerospace, haberdashery and hardware etc.Prior art produces the colorize method of plasthetics that toner is painted, painted and painted three kinds of the Masterbatch of grain is drawn in dyeing, when adopting Masterbatch painted, pigment is through pre-treatment and be dispersed in vector resin, substantially increase dispersing property and the coloration efficiency of pigment, there is the advantages such as simple to operate, with low cost, environmentally safe.
Add the color that look mother can be used for allocating plasthetics.But; once goods in use; often because use in extremely cold environment; shrinking percentage can be caused large; the problem of poor toughness; shorten the work-ing life of plasthetics greatly, thus make that traditional look female use range is narrow, environment for use too normalizing, multi-field user demand can not be met.
Summary of the invention
The object of the invention is to solve the shortcoming existed in prior art, and high cold-resistant toughened look mother of the one proposed and preparation method thereof.
To achieve these goals, present invention employs following technical scheme:
A kind of high cold-resistant toughened look female, and this high cold-resistant toughened look mother formula is as follows:
Acrylic resin: 40-60 part;
Toner: 30-40 part;
Dispersion agent: 5-10 part;
Softening agent: 10-20 part;
Coupling agent: 1-5 part;
Oxidation inhibitor: 0.5-1 part;
Cold-resistant properties-correcting agent: 30-40 part;
Reinforced modifier: 10-20 part;
Toughner: 10-20 part;
Preferably, described cold-resistant properties-correcting agent is the mixture of one or more of styrene-butadiene-styrene ternary block copolymer, ethylene-vinyl acetate copolymer and ethylene-octene copolymer.
Preferably, described reinforced modifier is the mixture of one or more of nano-calcium carbonate, nano-silicon and nano barium sulfate.
Preferably, described toughner is the mixture of one or more of Methylacrylate-Acrylate Copolymer ACR, MBS ternary graft copolymer MBS and ethylene-methyl acrylate-glyceryl methacrylate E-MA-GMA.
Preferably, described coupling agent is titanate coupling agent.
A kind of high cold-resistant toughened look female and preparation method thereof, and concrete steps are as follows:
(a): weighing of selecting materials: take above-mentioned raw materials by the weight part of constitutive material;
(b): mixing: the above-mentioned raw material taken is put into mixing machine, fully mixes 5-10min;
(c): adhesion-molded: above-mentioned mixed raw material is put into kneader kneaded and formed, kneaded and formed temperature is 200 DEG C-250 DEG C, and the kneaded and formed time is 10-15min;
(d): extruding pelletization: the raw material after shaping is passed through twin screw extruder extruding pelletization, obtained high cold-resistant toughened look female, and wherein prilling temperature is 150 DEG C-250 DEG C;
(e): pack shaping: shaping according to specification requirement class wrapping after the female drying of the cold-resistant toughened look of the height that forcing machine is extruded.
The high cold-resistant toughened look of one provided by the invention is female and preparation method thereof, this high cold-resistant toughened look mother makes simple, with look parent phase ratio, in the making processes of this high cold-resistant toughened look mother, add the formula of cold-resistant properties-correcting agent, reinforced modifier and toughner, thus the look making to make mother has the high cold-resistant performance characteristics with high tenacity, thus the user demand of multiple fields, multiple environment can be met, extend the work-ing life of plasthetics greatly.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with specific embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
A kind of high cold-resistant toughened look female, and this high cold-resistant toughened look mother formula is as follows:
Acrylic resin: 40 parts;
Toner: 30 parts;
Dispersion agent: 5 parts;
Softening agent: 10 parts;
Coupling agent: 1 part;
Oxidation inhibitor: 0.5 part;
Cold-resistant properties-correcting agent: 30 parts;
Reinforced modifier: 10 parts;
Toughner: 10 parts;
Preferably, described cold-resistant properties-correcting agent is the mixture of one or more of styrene-butadiene-styrene ternary block copolymer, ethylene-vinyl acetate copolymer and ethylene-octene copolymer.
Preferably, described reinforced modifier is the mixture of one or more of nano-calcium carbonate, nano-silicon and nano barium sulfate.
Preferably, described toughner is the mixture of one or more of Methylacrylate-Acrylate Copolymer ACR, MBS ternary graft copolymer MBS and ethylene-methyl acrylate-glyceryl methacrylate E-MA-GMA.
Preferably, described coupling agent is titanate coupling agent.
A kind of high cold-resistant toughened look female and preparation method thereof, and concrete steps are as follows:
(a): weighing of selecting materials: take above-mentioned raw materials by the weight part of constitutive material;
(b): mixing: the above-mentioned raw material taken is put into mixing machine, fully mixes 5min;
(c): adhesion-molded: above-mentioned mixed raw material is put into kneader kneaded and formed, kneaded and formed temperature is 200 DEG C, and the kneaded and formed time is 10min;
(d): extruding pelletization: the raw material after shaping is passed through twin screw extruder extruding pelletization, obtained high cold-resistant toughened look female, and wherein prilling temperature is 250 DEG C;
(e): pack shaping: shaping according to specification requirement class wrapping after the female drying of the cold-resistant toughened look of the height that forcing machine is extruded.
Embodiment 2
A kind of high cold-resistant toughened look female, and this high cold-resistant toughened look mother formula is as follows:
Acrylic resin: 60 parts;
Toner: 40 parts;
Dispersion agent: 10 parts;
Softening agent: 20 parts;
Coupling agent: 5 parts;
Oxidation inhibitor: 1 part;
Cold-resistant properties-correcting agent: 40 parts;
Reinforced modifier: 20 parts;
Toughner: 20 parts;
Preferably, described cold-resistant properties-correcting agent is the mixture of one or more of styrene-butadiene-styrene ternary block copolymer, ethylene-vinyl acetate copolymer and ethylene-octene copolymer.
Preferably, described reinforced modifier is the mixture of one or more of nano-calcium carbonate, nano-silicon and nano barium sulfate.
Preferably, described toughner is the mixture of one or more of Methylacrylate-Acrylate Copolymer ACR, MBS ternary graft copolymer MBS and ethylene-methyl acrylate-glyceryl methacrylate E-MA-GMA.
Preferably, described coupling agent is titanate coupling agent.
A kind of high cold-resistant toughened look female and preparation method thereof, and concrete steps are as follows:
(a): weighing of selecting materials: take above-mentioned raw materials by the weight part of constitutive material;
(b): mixing: the above-mentioned raw material taken is put into mixing machine, fully mixes 10min;
(c): adhesion-molded: above-mentioned mixed raw material is put into kneader kneaded and formed, kneaded and formed temperature is 250 DEG C, and the kneaded and formed time is 15min;
(d): extruding pelletization: the raw material after shaping is passed through twin screw extruder extruding pelletization, obtained high cold-resistant toughened look female, and wherein prilling temperature is 250 DEG C;
(e): pack shaping: shaping according to specification requirement class wrapping after the female drying of the cold-resistant toughened look of the height that forcing machine is extruded.
Embodiment three
A kind of high cold-resistant toughened look female, and this high cold-resistant toughened look mother formula is as follows:
Acrylic resin: 50 parts;
Toner: 35 parts;
Dispersion agent: 7.5 parts;
Softening agent: 15 parts;
Coupling agent: 2.5 parts;
Oxidation inhibitor: 0.75 part;
Cold-resistant properties-correcting agent: 35 parts;
Reinforced modifier: 15 parts;
Toughner: 15 parts;
Preferably, described cold-resistant properties-correcting agent is the mixture of one or more of styrene-butadiene-styrene ternary block copolymer, ethylene-vinyl acetate copolymer and ethylene-octene copolymer.
Preferably, described reinforced modifier is the mixture of one or more of nano-calcium carbonate, nano-silicon and nano barium sulfate.
Preferably, described toughner is the mixture of one or more of Methylacrylate-Acrylate Copolymer ACR, MBS ternary graft copolymer MBS and ethylene-methyl acrylate-glyceryl methacrylate E-MA-GMA.
Preferably, described coupling agent is titanate coupling agent.
A kind of high cold-resistant toughened look female and preparation method thereof, and concrete steps are as follows:
(a): weighing of selecting materials: take above-mentioned raw materials by the weight part of constitutive material;
(b): mixing: the above-mentioned raw material taken is put into mixing machine, fully mixes 7.5min;
(c): adhesion-molded: above-mentioned mixed raw material is put into kneader kneaded and formed, kneaded and formed temperature is 225 DEG C, and the kneaded and formed time is 12.5min;
(d): extruding pelletization: the raw material after shaping is passed through twin screw extruder extruding pelletization, obtained high cold-resistant toughened look female, and wherein prilling temperature is 200 DEG C;
(e): pack shaping: shaping according to specification requirement class wrapping after the female drying of the cold-resistant toughened look of the height that forcing machine is extruded.
Claims (6)
1. one kind high cold-resistant toughened look female, it is characterized in that: this high cold-resistant toughened look mother formula is as follows:
Acrylic resin: 40-60 part;
Toner: 30-40 part;
Dispersion agent: 5-10 part;
Softening agent: 10-20 part;
Coupling agent: 1-5 part;
Oxidation inhibitor: 0.5-1 part;
Cold-resistant properties-correcting agent: 30-40 part;
Reinforced modifier: 10-20 part;
Toughner: 10-20 part.
2. the high resistance to cool colour of one according to claim 1 is female, it is characterized in that: described cold-resistant properties-correcting agent is the mixture of one or more of styrene-butadiene-styrene ternary block copolymer, ethylene-vinyl acetate copolymer and ethylene-octene copolymer.
3. the high resistance to cool colour of one according to claim 1 is female, it is characterized in that: described reinforced modifier is the mixture of one or more of nano-calcium carbonate, nano-silicon and nano barium sulfate.
4. the high resistance to cool colour of one according to claim 1 is female, it is characterized in that: described toughner is the mixture of one or more of Methylacrylate-Acrylate Copolymer ACR, MBS ternary graft copolymer MBS and ethylene-methyl acrylate-glyceryl methacrylate E-MA-GMA.
5. the high resistance to cool colour of one according to claim 1 is female, it is characterized in that: described coupling agent is titanate coupling agent.
6. one kind high cold-resistant toughened look mother and preparation method thereof, is characterized in that: concrete steps are as follows:
(a): weighing of selecting materials: take above-mentioned raw materials by the weight part of constitutive material;
(b): mixing: the above-mentioned raw material taken is put into mixing machine, fully mixes 5-10min;
(c): adhesion-molded: above-mentioned mixed raw material is put into kneader kneaded and formed, kneaded and formed temperature is 200 DEG C-250 DEG C, and the kneaded and formed time is 10-15min;
(d): extruding pelletization: the raw material after shaping is passed through twin screw extruder extruding pelletization, obtained high cold-resistant toughened look female, and wherein prilling temperature is 150 DEG C-250 DEG C;
(e): pack shaping: shaping according to specification requirement class wrapping after the female drying of the cold-resistant toughened look of the height that forcing machine is extruded.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610002187.8A CN105504510A (en) | 2016-01-06 | 2016-01-06 | High cold-resistant toughening masterbatch and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610002187.8A CN105504510A (en) | 2016-01-06 | 2016-01-06 | High cold-resistant toughening masterbatch and preparation method thereof |
Publications (1)
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| CN105504510A true CN105504510A (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610002187.8A Pending CN105504510A (en) | 2016-01-06 | 2016-01-06 | High cold-resistant toughening masterbatch and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084454A (en) * | 2016-06-12 | 2016-11-09 | 苏州昊顺塑胶有限公司 | A kind of cold-resistant impact modification polypropylene and preparation method thereof |
| CN106589591A (en) * | 2016-12-08 | 2017-04-26 | 滁州麦迪尔塑胶有限公司 | Flame-retardant toughening color master batch and preparation method thereof |
| CN106589848A (en) * | 2016-12-08 | 2017-04-26 | 滁州麦迪尔塑胶有限公司 | Polytrimethylene terephthalate toughened color master batch and preparing method thereof |
| CN106674737A (en) * | 2016-12-19 | 2017-05-17 | 钦州市科学技术开发中心 | Toughening colorant with high cold resistance and preparation method thereof |
| CN108912499A (en) * | 2018-08-02 | 2018-11-30 | 青岛东海塑工贸有限公司 | A kind of PP Masterbatch and preparation method thereof |
| CN109930233A (en) * | 2019-02-26 | 2019-06-25 | 杭州泰富纺织化纤有限公司 | A kind of long-acting high-elastic negative-ion fiber |
| CN115850876A (en) * | 2022-11-17 | 2023-03-28 | 深圳市华鹰塑胶原料有限公司 | Polyolefin modified plastic and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850658A (en) * | 2012-10-18 | 2013-01-02 | 重庆澳彩科鼎塑染色母有限责任公司 | Novel high-efficiency PPR (pentatricopeptide repeat) pipe cold-resistant toughening color master batch |
| CN103865171A (en) * | 2014-03-06 | 2014-06-18 | 抚顺易桂塑胶科技有限公司 | PP (Polypropylene) color master batch with cold-resistant and toughening functions and preparation method thereof |
-
2016
- 2016-01-06 CN CN201610002187.8A patent/CN105504510A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850658A (en) * | 2012-10-18 | 2013-01-02 | 重庆澳彩科鼎塑染色母有限责任公司 | Novel high-efficiency PPR (pentatricopeptide repeat) pipe cold-resistant toughening color master batch |
| CN103865171A (en) * | 2014-03-06 | 2014-06-18 | 抚顺易桂塑胶科技有限公司 | PP (Polypropylene) color master batch with cold-resistant and toughening functions and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084454A (en) * | 2016-06-12 | 2016-11-09 | 苏州昊顺塑胶有限公司 | A kind of cold-resistant impact modification polypropylene and preparation method thereof |
| CN106589591A (en) * | 2016-12-08 | 2017-04-26 | 滁州麦迪尔塑胶有限公司 | Flame-retardant toughening color master batch and preparation method thereof |
| CN106589848A (en) * | 2016-12-08 | 2017-04-26 | 滁州麦迪尔塑胶有限公司 | Polytrimethylene terephthalate toughened color master batch and preparing method thereof |
| CN106674737A (en) * | 2016-12-19 | 2017-05-17 | 钦州市科学技术开发中心 | Toughening colorant with high cold resistance and preparation method thereof |
| CN108912499A (en) * | 2018-08-02 | 2018-11-30 | 青岛东海塑工贸有限公司 | A kind of PP Masterbatch and preparation method thereof |
| CN109930233A (en) * | 2019-02-26 | 2019-06-25 | 杭州泰富纺织化纤有限公司 | A kind of long-acting high-elastic negative-ion fiber |
| CN115850876A (en) * | 2022-11-17 | 2023-03-28 | 深圳市华鹰塑胶原料有限公司 | Polyolefin modified plastic and preparation method thereof |
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Application publication date: 20160420 |