CN105504393A - Environmentally-friendly oil resistant rubber pore-formed shoe sole - Google Patents
Environmentally-friendly oil resistant rubber pore-formed shoe sole Download PDFInfo
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- CN105504393A CN105504393A CN201410504533.3A CN201410504533A CN105504393A CN 105504393 A CN105504393 A CN 105504393A CN 201410504533 A CN201410504533 A CN 201410504533A CN 105504393 A CN105504393 A CN 105504393A
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- environmental protection
- pore
- engaging aperture
- hair engaging
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Abstract
The invention provides an environmentally-friendly oil resistant rubber pore-formed shoe sole, which is prepared from the following ingredients: nitrile rubber, an EVA renewable material, a vulcanization secondary accelerant, a vulcanization accelerant, a reinforcing agent, a plasticizer, a wear-resistant agent, a pore-forming agent H, a pore-forming aid and a cross-linking agent. By mixing nitrile rubber NBR and the EVA renewable material and simultaneously adding various aids, defects and deficiencies of nitrile rubber and EVA are greatly improved. The prepared shoe sole has good oil resistance and pore-forming performance.
Description
Technical field
The invention belongs to rubber item technical field, especially relate to a kind of environmental protection oil resisting rubber hair engaging aperture sole, relate to one especially and meet European Union environmental protection standard-required, oil resisting rubber hair engaging aperture sole.
Background technology
The features such as EVA (ethylene-vinyl acetate copolymer) foam material has light specific gravity, comfortable and easy to wear, are used in the grounds such as sports shoes, leather shoes, sandals.EVA is obtained ultralight foam material easily, but its foam material stretches, tears, rebound resilience and wear resisting property poor, the thermostability of depositing after expanding changes greatly, the defects such as be easily out of shape, non-skid property is poor, and feel is bad.
The oil-proofness of paracril is fabulous, and wear resistance is higher, and thermotolerance is better, and cohesive force is strong, and shortcoming is that elasticity is slightly low.
How to overcome the shortcoming of EVA and paracril simultaneously, retain its advantage simultaneously, prepare a kind of good springiness, oil-proofness is good, and the good rubber soles of hair engaging aperture just highly significant.
Summary of the invention
The problem to be solved in the present invention is for above-mentioned deficiency, provides a kind of environmental protection oil resisting rubber hair engaging aperture sole.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of environmental protection oil resisting rubber hair engaging aperture sole is prepared by each component comprising following parts by weight:
As preferred embodiments of the present invention, be prepared by each component comprising following parts by weight:
Preferably, every 8 parts of sulfuration secondary accelerators comprise 2 parts of stearic acid and 6 parts of zinc oxide.
Preferably, described vulcanization accelerator is altax and captax, and every 1.3 parts of vulcanization accelerators comprise 0.8 part of altax and 0.5 part of captax.
Preferably, described strengthening agent is white carbon black, and described softening agent is tributyl citrate, and described anti-wear agent is silicon-dioxide or silicon-69.
As the best preferred scheme of the present invention, be prepared by each component comprising following parts by weight:
The advantage that the present invention has and positively effect are: paracril NBR and EVA reworked material used in combination, add various auxiliary agent simultaneously, well improve defect and the deficiency of paracril and EVA, the sole prepared has good oil resistant and hair engaging aperture performance.
Embodiment
For the ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.
If no special instructions, various raw material of the present invention all can be obtained by commercially available; Or the ordinary method according to this area prepares.Unless otherwise defined or described herein, dialect used herein and those skilled in the art the same meaning be familiar with.
This rubber soles is prepared by following component:
The preparation method of this environmental protection oil resisting rubber hair engaging aperture sole is:
After being mixed with EVA reworked material by paracril, add the various Synergist S-421 95s except crosslinking aid S, under the condition of 120 ± 5 DEG C, smash refining 12min even to material, rear bottom sheet parks 24h, then carries out refining.
In epoxy glue, add crosslinking aid S, to smash after refining evenly sulfidization molding 20min under the condition of 150 ± 5 DEG C.
The performance perameter of the rubber soles adopting this kind of formula and method to prepare is: oil resistant: < 12%, wear-resisting: NBS > 30%, shore hardness: 70 ° ± 5.
Above one embodiment of the present of invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should still belong within patent covering scope of the present invention.
Claims (6)
1. an environmental protection oil resisting rubber hair engaging aperture sole, is characterized in that: be prepared by each component comprising following parts by weight:
2. environmental protection oil resisting rubber hair engaging aperture sole according to claim 1, is characterized in that: be prepared by each component comprising following parts by weight:
3. environmental protection oil resisting rubber hair engaging aperture sole according to claim 1 and 2, is characterized in that: every 8 parts of sulfuration secondary accelerators comprise 2 parts of stearic acid and 6 parts of zinc oxide.
4. environmental protection oil resisting rubber hair engaging aperture sole according to claim 3, is characterized in that: described vulcanization accelerator is altax and captax, and every 1.3 parts of vulcanization accelerators comprise 0.8 part of altax and 0.5 part of captax.
5. environmental protection oil resisting rubber hair engaging aperture sole according to claim 4, it is characterized in that: described strengthening agent is white carbon black, described softening agent is tributyl citrate, and described anti-wear agent is silicon-69.
6. environmental protection oil resisting rubber hair engaging aperture sole according to claim 5, is characterized in that: be prepared by each component comprising following parts by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410504533.3A CN105504393A (en) | 2014-09-26 | 2014-09-26 | Environmentally-friendly oil resistant rubber pore-formed shoe sole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410504533.3A CN105504393A (en) | 2014-09-26 | 2014-09-26 | Environmentally-friendly oil resistant rubber pore-formed shoe sole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105504393A true CN105504393A (en) | 2016-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410504533.3A Pending CN105504393A (en) | 2014-09-26 | 2014-09-26 | Environmentally-friendly oil resistant rubber pore-formed shoe sole |
Country Status (1)
| Country | Link |
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| CN (1) | CN105504393A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337182A (en) * | 2018-08-30 | 2019-02-15 | 福建豪威节能科技发展有限公司 | A kind of lightweight high-elastic wear-resistant rubber and plastic crosslinked of the EVA containing regeneration |
| CN109824966A (en) * | 2018-12-10 | 2019-05-31 | 华南理工大学 | A kind of wear-resistance and oil-resistance engineering sole material and preparation method thereof |
| CN110396228A (en) * | 2019-08-06 | 2019-11-01 | 浙江中瑞橡胶高分子材料股份有限公司 | A kind of resistance to wet and slippery outsole of lightweight and preparation method thereof |
-
2014
- 2014-09-26 CN CN201410504533.3A patent/CN105504393A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337182A (en) * | 2018-08-30 | 2019-02-15 | 福建豪威节能科技发展有限公司 | A kind of lightweight high-elastic wear-resistant rubber and plastic crosslinked of the EVA containing regeneration |
| CN109824966A (en) * | 2018-12-10 | 2019-05-31 | 华南理工大学 | A kind of wear-resistance and oil-resistance engineering sole material and preparation method thereof |
| CN109824966B (en) * | 2018-12-10 | 2020-12-15 | 华南理工大学 | Wear-resistant oil-resistant engineering sole material and preparation method thereof |
| CN110396228A (en) * | 2019-08-06 | 2019-11-01 | 浙江中瑞橡胶高分子材料股份有限公司 | A kind of resistance to wet and slippery outsole of lightweight and preparation method thereof |
| CN110396228B (en) * | 2019-08-06 | 2021-11-09 | 浙江中瑞橡胶高分子材料股份有限公司 | Light wet-skid-resistant outsole and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160420 |