CN105502970A - Anti-explosion vacuum glass and preparing method thereof - Google Patents

Anti-explosion vacuum glass and preparing method thereof Download PDF

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Publication number
CN105502970A
CN105502970A CN201510990040.XA CN201510990040A CN105502970A CN 105502970 A CN105502970 A CN 105502970A CN 201510990040 A CN201510990040 A CN 201510990040A CN 105502970 A CN105502970 A CN 105502970A
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Prior art keywords
explosion
glass
vacuum glass
protective coating
thermal protective
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Chinese (zh)
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顾黎明
徐峰
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TAICANG YAOHUA GLASS CO Ltd
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TAICANG YAOHUA GLASS CO Ltd
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Priority to CN201510990040.XA priority Critical patent/CN105502970A/en
Publication of CN105502970A publication Critical patent/CN105502970A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00Protective equipment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The invention discloses anti-explosion vacuum glass. The anti-explosion vacuum glass is characterized by comprising an anti-explosion film, an upper glass body, a lower glass body and supporters, the anti-explosion film comprises a PET base layer and a heatproof coating covering the PET base layer, and the heatproof coating is prepared from, by mass, 20-40 parts of acrylic resin, 5-10 parts of nano hollow microsphere, 0.1-0.5 part of dispersing agent, and 0.1-0.5 part of heat stabilizer. By coating the PET base layer of the anti-explosion film with the heatproof coating, heat absorption of the vacuum glass under the blazing sun can be reduced, and anti-explosion performance is high; furthermore, the anti-explosion film does not age easily after long-term use and is long in service life; besides, a preparing method of the anti-explosion vacuum glass is simple, film forming speed is high, production efficiency is high, the requirement for large-scale mass factory production can be met, and comprehensive benefits are high.

Description

A kind of explosion-proof vacuum glass and preparation method
Technical field
The present invention relates to the manufacturing of vacuum glass, particularly a kind of explosion-proof vacuum glass and preparation method.
Background technology
Glass is the indispensable integral parts of the vehicles such as buildings, automobile, carries many important functions, the outward appearance of such as beautifying constructure and automobile etc., daylighting, to bring the open visual field and insulation or heat insulation effect to indoor and outdoor.Along with the leap of modern science and technology and people are to the pursuit of quality of the life, the glass of various function is developed in succession.Wherein, the vacuum glass be composited by two glass sheets or many bat sheet glass is subject to people's attention day by day with its excellent sound insulation, heat-proof quality, vacuum glass is widely used in modern architecture field realizing insulation and noise isolation, also be used to manyly keep in relevant industry with temperature, such as refrigerator, solar water heater etc. simultaneously.
A large amount of uses of glass bring bright and beautiful while, also bring many difficult problems, such as: Glass breadks easily, and glass is more thin more frangible, glass rupture is that fragment splashes, and easily injures other people and causes environmental pollution, therefore, a kind of implosion guard arises at the historic moment.
Chinese patent 200510072530.8, discloses a kind of implosion guard and manufacture method thereof.Implosion guard of the present invention is made up of glass or toughened glass and water white silicon rubber, and water white silicon rubber covers the single or double of glass or toughened glass.The manufacture method of implosion guard of the present invention is as follows: use general technology technology as constructional methods such as spraying or brushings, water white silicon rubber is sprayed or brushes the single or double at glass or toughened glass, at the temperature of 80-150 degree Celsius, carry out 10-15 minute cure, make material qualitative in glass surface sulfuration, material is connected as a single entity at glass surface and glass.The functions such as present invention process is simple, and the implosion guard of support has transparent, explosion-proof, environmental protection, high temperature resistant, heat insulation, applying force is strong, tasteless, are applicable to building industry, automotive industry and other field and widely use.But silastic material easily occurs aging duration of service long afterwards, need periodic replacement, be unfavorable for the life-time service of implosion guard.
Summary of the invention
For solving above-mentioned Problems existing, the object of the present invention is to provide a kind of explosion-proof vacuum glass and preparation method.
For achieving the above object, technical scheme of the present invention is:
A kind of explosion-proof vacuum glass, comprise: rupture disk, upper glass, lower-glass and upholder, described rupture disk comprises the thermal protective coating that PET basic unit and PET basic unit apply, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 20-40 part, nano-hollow microballon: 5-10 part, dispersion agent: 0.1-0.5 part, thermo-stabilizer: 0.1-0.5 part.
Further, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 20-30 part, nano-hollow microballon: 6-8 part, dispersion agent: 0.2-0.5 part, thermo-stabilizer: 0.1-0.3 part.
Further, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 22 parts, nano-hollow microballon: 6.6 parts, dispersion agent: 0.4 part, thermo-stabilizer: 0.2 part.
Separately, the thickness of described PET basic unit is 40-80 μm, and the thickness of described thermal protective coating is 5-12nm.
And have, the particle diameter of described nano-hollow microballon is 30-100nm.
Again, described dispersion agent is any one in fatty acid dispersion agent, aliphatic amide type dispersion agent or ester class dispersion agent.
A preparation method for explosion-proof vacuum glass, comprises the steps:
(1) between upper glass and lower-glass, evenly place upholder, coat glass powder with low melting point at two panels glass side, carry out side sintering after placing extraction pipe, edge sealing powder melts, and cooling, vacuumizes after solidification, and sealing, obtains the head product of vacuum glass;
(2) in dust free chamber, adopt the mixing solutions of the vitriol oil and hydrogen peroxide to soak the upper glass top surface of head product, soak time is 3-6h, has soaked rear taking-up, clean with deionized water rinsing, and dries up by nitrogen gun;
(3) each component of thermal protective coating is added in organic solvent by said ratio, and at dispersion agent high speed dispersion more than 1h, and even spread and PET substrate surface form thermal protective coating, and coating linear speed is 15-20m/s, and in vacuum drying oven dryness finalization;
(4) the upper glass top surface in step (2) after process covers layer of adhesive, and the PET basic unit being coated with thermal protective coating is conformed to adhesive surface, namely obtains explosion-proof vacuum glass after to be bonded dose of solidification.
Meanwhile, described organic solvent is volatile organic solvent, in tetrahydrofuran (THF), ethanol, ethyl acetate, acetone, methylene dichloride, trichloromethane any one.
Beneficial effect of the present invention is:
(1) a kind of explosion-proof vacuum glass provided by the invention, be provided with rupture disk, described rupture disk is coated with thermal protective coating in PET basic unit, vacuum glass can be reduced when outdoor solar light is exposed to the sun to the absorption of heat, there is good explosion-proof performance, and described rupture disk in use between not easily aging long afterwards, long service life;
(2) preparation method of a kind of explosion-proof vacuum glass provided by the invention, easy and simple to handle, film forming speed is fast, production efficiency is high, can meet the requirement that factory is extensive, produce in enormous quantities, comprehensive benefit is high.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, further describe below in conjunction with embodiment.
Embodiment 1
A kind of explosion-proof vacuum glass, comprise: rupture disk, upper glass, lower-glass and upholder, described rupture disk comprises the thermal protective coating that PET basic unit and PET basic unit apply, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 22 parts, nano-hollow microballon: 6.6 parts, fatty acid dispersion agent: 0.4 part, thermo-stabilizer: 0.2 part, the thickness of described PET basic unit is 40 μm, and the thickness of described thermal protective coating is 5nm, and the particle diameter of described nano-hollow microballon is 30nm.
A preparation method for explosion-proof vacuum glass, comprises the steps:
(1) between upper glass and lower-glass, evenly place upholder, coat glass powder with low melting point at two panels glass side, carry out side sintering after placing extraction pipe, edge sealing powder melts, and cooling, vacuumizes after solidification, and sealing, obtains the head product of vacuum glass;
(2) in dust free chamber, adopt the mixing solutions of the vitriol oil and hydrogen peroxide to soak the upper glass top surface of head product, soak time is 3h, has soaked rear taking-up, clean with deionized water rinsing, and dries up by nitrogen gun;
(3) each component of thermal protective coating is added in acetone by said ratio, and at dispersion agent high speed dispersion 1.2h, and even spread and PET substrate surface form thermal protective coating, and coating linear speed is 20m/s, and in vacuum drying oven dryness finalization;
(4) the upper glass top surface in step (2) after process covers layer of adhesive, and the PET basic unit being coated with thermal protective coating is conformed to adhesive surface, namely obtains explosion-proof vacuum glass after to be bonded dose of solidification.
Embodiment 2
A kind of explosion-proof vacuum glass, comprise: rupture disk, upper glass, lower-glass and upholder, described rupture disk comprises the thermal protective coating that PET basic unit and PET basic unit apply, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 30 parts, nano-hollow microballon: 6.5 parts, fatty acid dispersion agent: 0.2 part, thermo-stabilizer: 0.2 part, the thickness of described PET basic unit is 50 μm, and the thickness of described thermal protective coating is 7nm, and the particle diameter of described nano-hollow microballon is 50nm.
A preparation method for explosion-proof vacuum glass, comprises the steps:
(1) between upper glass and lower-glass, evenly place upholder, coat glass powder with low melting point at two panels glass side, carry out side sintering after placing extraction pipe, edge sealing powder melts, and cooling, vacuumizes after solidification, and sealing, obtains the head product of vacuum glass;
(2) in dust free chamber, adopt the mixing solutions of the vitriol oil and hydrogen peroxide to soak the upper glass top surface of head product, soak time is 5h, has soaked rear taking-up, clean with deionized water rinsing, and dries up by nitrogen gun;
(3) each component of thermal protective coating is added in tetrahydrofuran (THF) by said ratio, and at dispersion agent high speed dispersion 1.5h, and even spread and PET substrate surface form thermal protective coating, and coating linear speed is 18m/s, and in vacuum drying oven dryness finalization;
(4) the upper glass top surface in step (2) after process covers layer of adhesive, and the PET basic unit being coated with thermal protective coating is conformed to adhesive surface, namely obtains explosion-proof vacuum glass after to be bonded dose of solidification.
Embodiment 3
A kind of explosion-proof vacuum glass, comprise: rupture disk, upper glass, lower-glass and upholder, described rupture disk comprises the thermal protective coating that PET basic unit and PET basic unit apply, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 26 parts, nano-hollow microballon: 9 parts, aliphatic amide type dispersion agent: 0.3 part, thermo-stabilizer: 0.4 part, the thickness of described PET basic unit is 60 μm, and the thickness of described thermal protective coating is 8nm, and the particle diameter of described nano-hollow microballon is 80nm.
A preparation method for explosion-proof vacuum glass, comprises the steps:
(1) between upper glass and lower-glass, evenly place upholder, coat glass powder with low melting point at two panels glass side, carry out side sintering after placing extraction pipe, edge sealing powder melts, and cooling, vacuumizes after solidification, and sealing, obtains the head product of vacuum glass;
(2) in dust free chamber, adopt the mixing solutions of the vitriol oil and hydrogen peroxide to soak the upper glass top surface of head product, soak time is 5h, has soaked rear taking-up, clean with deionized water rinsing, and dries up by nitrogen gun;
(3) each component of thermal protective coating is added in methylene dichloride by said ratio, and at dispersion agent high speed dispersion 2h, and even spread and PET substrate surface form thermal protective coating, and coating linear speed is 20m/s, and in vacuum drying oven dryness finalization;
(4) the upper glass top surface in step (2) after process covers layer of adhesive, and the PET basic unit being coated with thermal protective coating is conformed to adhesive surface, namely obtains explosion-proof vacuum glass after to be bonded dose of solidification.
Embodiment 4
A kind of explosion-proof vacuum glass, comprise: rupture disk, upper glass, lower-glass and upholder, described rupture disk comprises the thermal protective coating that PET basic unit and PET basic unit apply, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 38 parts, nano-hollow microballon: 10 parts, ester class dispersion agent: 0.5 part, thermo-stabilizer: 0.3 part, the thickness of described PET basic unit is 80 μm, and the thickness of described thermal protective coating is 12nm, and the particle diameter of described nano-hollow microballon is 30-100nm.
A preparation method for explosion-proof vacuum glass, comprises the steps:
(1) between upper glass and lower-glass, evenly place upholder, coat glass powder with low melting point at two panels glass side, carry out side sintering after placing extraction pipe, edge sealing powder melts, and cooling, vacuumizes after solidification, and sealing, obtains the head product of vacuum glass;
(2) in dust free chamber, adopt the mixing solutions of the vitriol oil and hydrogen peroxide to soak the upper glass top surface of head product, soak time is 6h, has soaked rear taking-up, clean with deionized water rinsing, and dries up by nitrogen gun;
(3) each component of thermal protective coating is added in ethyl acetate by said ratio, and at dispersion agent high speed dispersion 1.5h, and even spread and PET substrate surface form thermal protective coating, and coating linear speed is 18m/s, and in vacuum drying oven dryness finalization;
(4) the upper glass top surface in step (2) after process covers layer of adhesive, and the PET basic unit being coated with thermal protective coating is conformed to adhesive surface, namely obtains explosion-proof vacuum glass after to be bonded dose of solidification.
A kind of explosion-proof vacuum glass provided by the invention, be provided with rupture disk, described rupture disk is coated with thermal protective coating in PET basic unit, vacuum glass can be reduced when outdoor solar light is exposed to the sun to the absorption of heat, there is good explosion-proof performance, and described rupture disk in use between not easily aging long afterwards, long service life; And the preparation method of this explosion-proof vacuum glass, easy and simple to handle, film forming speed is fast, production efficiency is high, can meet the requirement that factory is extensive, produce in enormous quantities, comprehensive benefit is high.
It should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted.Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to the technical scheme of invention or equivalent replacement, and not depart from the scope of technical solution of the present invention, it all should be encompassed in right of the present invention.

Claims (8)

1. an explosion-proof vacuum glass, it is characterized in that, comprise: rupture disk, upper glass, lower-glass and upholder, described rupture disk comprises the thermal protective coating that PET basic unit and PET basic unit apply, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 20-40 part, nano-hollow microballon: 5-10 part, dispersion agent: 0.1-0.5 part, thermo-stabilizer: 0.1-0.5 part.
2. a kind of explosion-proof vacuum glass according to claim 1, it is characterized in that, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 20-30 part, nano-hollow microballon: 6-8 part, dispersion agent: 0.2-0.5 part, thermo-stabilizer: 0.1-0.3 part.
3. a kind of explosion-proof vacuum glass according to claim 1, is characterized in that, described thermal protective coating comprises each component of following mass fraction: acrylic resin: 22 parts, nano-hollow microballon: 6.6 parts, dispersion agent: 0.4 part, thermo-stabilizer: 0.2 part.
4. a kind of explosion-proof vacuum glass according to claim 1, is characterized in that, the thickness of described PET basic unit is 40-80 μm, and the thickness of described thermal protective coating is 5-12nm.
5. a kind of explosion-proof vacuum glass according to claim 1, is characterized in that, the particle diameter of described nano-hollow microballon is 30-100nm.
6. a kind of explosion-proof vacuum glass according to claim 1, is characterized in that, described dispersion agent is any one in fatty acid dispersion agent, aliphatic amide type dispersion agent or ester class dispersion agent.
7. a preparation method for explosion-proof vacuum glass, is characterized in that, comprises the steps:
(1) between upper glass and lower-glass, evenly place upholder, coat glass powder with low melting point at two panels glass side, carry out side sintering after placing extraction pipe, edge sealing powder melts, and cooling, vacuumizes after solidification, and sealing, obtains the head product of vacuum glass;
(2) in dust free chamber, adopt the mixing solutions of the vitriol oil and hydrogen peroxide to soak the upper glass top surface of head product, soak time is 3-6h, has soaked rear taking-up, clean with deionized water rinsing, and dries up by nitrogen gun;
(3) each component of thermal protective coating is added in organic solvent by said ratio, and at dispersion agent high speed dispersion more than 1h, and even spread and PET substrate surface form thermal protective coating, and coating linear speed is 15-20m/s, and in vacuum drying oven dryness finalization;
(4) the upper glass top surface in step (2) after process covers layer of adhesive, and the PET basic unit being coated with thermal protective coating is conformed to adhesive surface, namely obtains explosion-proof vacuum glass after to be bonded dose of solidification.
8. the preparation method of a kind of explosion-proof vacuum glass according to claim 7, is characterized in that, described organic solvent is volatile organic solvent, in tetrahydrofuran (THF), ethanol, ethyl acetate, acetone, methylene dichloride, trichloromethane any one.
CN201510990040.XA 2015-12-28 2015-12-28 Anti-explosion vacuum glass and preparing method thereof Pending CN105502970A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113585925A (en) * 2021-08-24 2021-11-02 安徽鸿玻玻璃科技有限公司 Production process of heat-insulation explosion-proof hollow glass

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102950848A (en) * 2011-08-25 2013-03-06 品诚塑胶科技(上海)有限公司 New sun sheet and production method thereof
CN103187468A (en) * 2011-12-30 2013-07-03 苏州中来光伏新材股份有限公司 Solar battery rear film with high heat dissipation performance and processing technology thereof
CN103819998A (en) * 2012-11-16 2014-05-28 苏州裕丰装饰门窗有限公司 Heat insulating coating as well as coating method, paint and preparing method thereof
CN104417000A (en) * 2014-10-30 2015-03-18 孟凡伟 Car explosion-proof membrane and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102950848A (en) * 2011-08-25 2013-03-06 品诚塑胶科技(上海)有限公司 New sun sheet and production method thereof
CN103187468A (en) * 2011-12-30 2013-07-03 苏州中来光伏新材股份有限公司 Solar battery rear film with high heat dissipation performance and processing technology thereof
CN103819998A (en) * 2012-11-16 2014-05-28 苏州裕丰装饰门窗有限公司 Heat insulating coating as well as coating method, paint and preparing method thereof
CN104417000A (en) * 2014-10-30 2015-03-18 孟凡伟 Car explosion-proof membrane and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113585925A (en) * 2021-08-24 2021-11-02 安徽鸿玻玻璃科技有限公司 Production process of heat-insulation explosion-proof hollow glass

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