CN105482072A - Sponge for automobile glove box - Google Patents

Sponge for automobile glove box Download PDF

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Publication number
CN105482072A
CN105482072A CN201511023626.5A CN201511023626A CN105482072A CN 105482072 A CN105482072 A CN 105482072A CN 201511023626 A CN201511023626 A CN 201511023626A CN 105482072 A CN105482072 A CN 105482072A
Authority
CN
China
Prior art keywords
parts
glove box
sponge
automobile glove
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201511023626.5A
Other languages
Chinese (zh)
Inventor
李守伦
吴云
夏春火
潘国梁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU XINYUAN SPONGE CO Ltd
Original Assignee
WUHU XINYUAN SPONGE CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHU XINYUAN SPONGE CO Ltd filed Critical WUHU XINYUAN SPONGE CO Ltd
Priority to CN201511023626.5A priority Critical patent/CN105482072A/en
Publication of CN105482072A publication Critical patent/CN105482072A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/20—Ternary blends of expanding agents
    • C08J2203/204—Ternary blends of expanding agents of chemical foaming agent and physical blowing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams

Abstract

The invention relates to sponge for an automobile glove box, and belongs to the technical field of automobile accessories. The sponge for the automobile glove box is prepared from, by weight, 150-180 parts of polyether polyol, 100-120 parts of toluene diisocynate, 8-30 parts of a foaming agent, 5-10 parts of a foam stabilizer, 2-4 parts of a catalyst, 1-3 parts of a chain extender, 1-3 parts of a cross-linking agent and 20-50 parts of a fire retardant. The sponge for the automobile glove box has the good elastic resilience and buffering effect. If the body touches the glove box, the buffering effect can be achieved, injuries are reduced, the good dust isolation and fire retardant performance is achieved, and objects inside the glove box can be better protected; if the glove box has the refrigeration performance, the effects of heat isolation and energy loss reduction can be achieved.

Description

A kind of automobile glove box uses sponge
Technical field
The present invention relates to a kind of automobile glove box with sponge, belong to Automobile Products technical field.
Background technology
Glove box is one of important parts of automotive interior, its Main Function is storing, but now along with the development of automotive industry, the effect of glove box is also not only confined to storing, for example present a lot of cars have started the air channel connecting air-conditioning with glove box, be used as the storage tank of cold storage function, and the position of glove box is in copilot front, therefore its structural sponge is just very important, not only want high resilience, resiliency, and good sealing will be had, thermal insulation etc., but current most of glove boxes are just added with one deck imitation leather outside structure, or easy sponge is housed below imitation leather, do not reach required effect.
Summary of the invention
The object of the invention is to solve the weak point that above-mentioned prior art exists, provide that a kind of rebound resilience, resiliency are good, heat insulation, dust-separation, fire-retardant automobile glove box use sponge.
The present invention is achieved by the following technical solutions:
A kind of automobile glove box is with sponge, and its special character is to be made up of following raw material by weight ratio: polyether glycol 150-180 part, tolylene diisocyanate 100-120 part, whipping agent 8-30 part, foam stabilizer 5-10 part, catalyzer 2-4 part, chainextender 1-3 part, linking agent 1-3 part, fire retardant 20-50 part;
Described whipping agent is the mixture of fluoro trichloromethane, water, carbonic acid gas;
Described foam stabilizer is silicone oil;
Described catalyzer is the mixture of dibutyl tin laurate, stannous octoate, triethylene diamine, two (dimethylaminoethyl) ether;
Described chainextender is the mixture of neopentyl glycol, sorbyl alcohol, glycerine;
Described linking agent is the mixture of cyanacrylate and dicumyl peroxide;
Described fire retardant is the mixture of melamine cyanurate and clorafin;
Described a kind of automobile glove box, with sponge, is made up of the raw material of following optimum proportioning by weight: polyether glycol 175 parts, tolylene diisocyanate 110 parts, whipping agent 20 parts, foam stabilizer 7 parts, catalyzer 3 parts, chainextender 2 parts, linking agent 2 parts, fire retardant 35 parts.
A kind of automobile glove box of the present invention is with sponge; not only there is good rebound resilience and resiliency; if health encounters glove box can play shock absorption; reduce injury; and possess good dust-separation, flame retardant properties; can better article in hand saver case, if glove box have refrigeration more can, heat insulation, to reduce energy waste effect can also be played.
Embodiment
Below provide the specific embodiment of the present invention, be used for being described in further detail formation of the present invention.
Embodiment 1
A kind of automobile glove box of the present embodiment, with sponge, is made up of following raw material by weight ratio: polyether glycol 150 parts, tolylene diisocyanate 100 parts, whipping agent 8 parts, foam stabilizer 5 parts, catalyzer 2 parts, chainextender 1 part, linking agent 1 part, fire retardant 20 parts;
Described whipping agent is the mixture of fluoro trichloromethane, water, carbonic acid gas;
Described foam stabilizer is silicone oil;
Described catalyzer is the mixture of dibutyl tin laurate, stannous octoate, triethylene diamine, two (dimethylaminoethyl) ether;
Described chainextender is the mixture of neopentyl glycol, sorbyl alcohol, glycerine;
Described linking agent is the mixture of cyanacrylate and dicumyl peroxide;
Described fire retardant is the mixture of melamine cyanurate and clorafin.
Embodiment 2
A kind of automobile glove box of the present embodiment, with sponge, is made up of following raw material by weight ratio: polyether glycol 180 parts, tolylene diisocyanate 120 parts, whipping agent 30 parts, foam stabilizer 10 parts, catalyzer 4 parts, chainextender 3 parts, linking agent 3 parts, fire retardant 50 parts.
Embodiment 3
Described a kind of automobile glove box of the present embodiment, with sponge, is made up of the raw material of following optimum proportioning by weight: polyether glycol 175 parts, tolylene diisocyanate 110 parts, whipping agent 20 parts, foam stabilizer 7 parts, catalyzer 3 parts, chainextender 2 parts, linking agent 2 parts, fire retardant 35 parts.
A kind of automobile glove box of above embodiment is with sponge; not only there is good rebound resilience and resiliency; if health encounters glove box can play shock absorption; reduce injury; and possess good dust-separation, flame retardant properties; can better article in hand saver case, if glove box have refrigeration more can, heat insulation, to reduce energy waste effect can also be played.

Claims (8)

1. automobile glove box is with a sponge, it is characterized in that being made up of following raw material by weight ratio: polyether glycol 150-180 part, tolylene diisocyanate 100-120 part, whipping agent 8-30 part, foam stabilizer 5-10 part, catalyzer 2-4 part, chainextender 1-3 part, linking agent 1-3 part, fire retardant 20-50 part.
2. a kind of automobile glove box, with sponge, is characterized in that described whipping agent is the mixture of fluoro trichloromethane, water, carbonic acid gas according to claim 1.
3. a kind of automobile glove box, with sponge, is characterized in that described foam stabilizer is silicone oil according to claim 1.
4. a kind of automobile glove box, with sponge, is characterized in that described catalyzer is the mixture of dibutyl tin laurate, stannous octoate, triethylene diamine, two (dimethylaminoethyl) ether according to claim 1.
5. a kind of automobile glove box, with sponge, is characterized in that described chainextender is the mixture of neopentyl glycol, sorbyl alcohol, glycerine according to claim 1.
6. a kind of automobile glove box, with sponge, is characterized in that described linking agent is the mixture of cyanacrylate and dicumyl peroxide according to claim 1.
7. a kind of automobile glove box, with sponge, is characterized in that described fire retardant is the mixture of melamine cyanurate and clorafin according to claim 1.
8. a kind of automobile glove box, with sponge, is characterized in that being made up of the raw material of following optimum proportioning by weight: polyether glycol 175 parts, tolylene diisocyanate 110 parts, whipping agent 20 parts, foam stabilizer 7 parts, catalyzer 3 parts, chainextender 2 parts, linking agent 2 parts, fire retardant 35 parts according to claim 1.
CN201511023626.5A 2015-12-30 2015-12-30 Sponge for automobile glove box Pending CN105482072A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511023626.5A CN105482072A (en) 2015-12-30 2015-12-30 Sponge for automobile glove box

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511023626.5A CN105482072A (en) 2015-12-30 2015-12-30 Sponge for automobile glove box

Publications (1)

Publication Number Publication Date
CN105482072A true CN105482072A (en) 2016-04-13

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Family Applications (1)

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CN201511023626.5A Pending CN105482072A (en) 2015-12-30 2015-12-30 Sponge for automobile glove box

Country Status (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105524253A (en) * 2015-12-15 2016-04-27 广东广山新材料有限公司 Isocyanate modified epoxy resin and application thereof
CN105968792A (en) * 2016-05-30 2016-09-28 青岛迦喜家纺有限公司 Temperature control sponge and preparation method thereof
CN113717345A (en) * 2021-09-07 2021-11-30 苏州思德新材料科技有限公司 Novel polyurethane foam material
CN114605608A (en) * 2022-04-11 2022-06-10 安徽太平海绵制品有限公司 High-elasticity flame-retardant sponge and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060047010A1 (en) * 2004-09-02 2006-03-02 O'leary Robert J Pseudo one part foam
CN101250320A (en) * 2008-04-06 2008-08-27 陈春潮 Flame-proof cotton
CN101805513A (en) * 2010-04-12 2010-08-18 无锡市井上海绵有限公司 Method for producing environmental-protection type sound-absorbing and flame-retardant sponge
CN102336885A (en) * 2011-07-02 2012-02-01 胡志刚 Polyurethane sponge with excellent environmental tolerance
CN104356352A (en) * 2014-12-02 2015-02-18 深圳雅兰家居用品有限公司 Sponge and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060047010A1 (en) * 2004-09-02 2006-03-02 O'leary Robert J Pseudo one part foam
CN101250320A (en) * 2008-04-06 2008-08-27 陈春潮 Flame-proof cotton
CN101805513A (en) * 2010-04-12 2010-08-18 无锡市井上海绵有限公司 Method for producing environmental-protection type sound-absorbing and flame-retardant sponge
CN102336885A (en) * 2011-07-02 2012-02-01 胡志刚 Polyurethane sponge with excellent environmental tolerance
CN104356352A (en) * 2014-12-02 2015-02-18 深圳雅兰家居用品有限公司 Sponge and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105524253A (en) * 2015-12-15 2016-04-27 广东广山新材料有限公司 Isocyanate modified epoxy resin and application thereof
CN105968792A (en) * 2016-05-30 2016-09-28 青岛迦喜家纺有限公司 Temperature control sponge and preparation method thereof
CN105968792B (en) * 2016-05-30 2019-03-01 青岛迦喜家纺有限公司 A kind of temperature control sponge and preparation method thereof
CN113717345A (en) * 2021-09-07 2021-11-30 苏州思德新材料科技有限公司 Novel polyurethane foam material
CN114605608A (en) * 2022-04-11 2022-06-10 安徽太平海绵制品有限公司 High-elasticity flame-retardant sponge and preparation method thereof

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Application publication date: 20160413

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