CN106397726A - Halogen-free flame retardant slowly-recoverable memory foam - Google Patents

Halogen-free flame retardant slowly-recoverable memory foam Download PDF

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Publication number
CN106397726A
CN106397726A CN201610771463.7A CN201610771463A CN106397726A CN 106397726 A CN106397726 A CN 106397726A CN 201610771463 A CN201610771463 A CN 201610771463A CN 106397726 A CN106397726 A CN 106397726A
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CN
China
Prior art keywords
halogen
parts
memory foam
polyether
low resilience
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610771463.7A
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Chinese (zh)
Inventor
赵军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huaian Tongchuang Foam Co Ltd
Original Assignee
Huaian Tongchuang Foam Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huaian Tongchuang Foam Co Ltd filed Critical Huaian Tongchuang Foam Co Ltd
Priority to CN201610771463.7A priority Critical patent/CN106397726A/en
Publication of CN106397726A publication Critical patent/CN106397726A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066Flame-proofing or flame-retarding additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses halogen-free flame retardant slowly-recoverable memory foam which is prepared from the following raw materials in parts by weight: 20 to 50 parts of polyether glycol 1030, 4 to 10 parts of polyether glycol 2000, 23 to 56 parts of MDI, 8 to 20 parts of slowly-recoverable polyether, 8 to 20 parts of white oil, 9 to 24 parts of a halogen-free flame retardant, 1.2 to 3 parts of an opening agent, 0.02 to 0.5 part of an amine catalyst and 0.3 to 0.9 part of silicon oil. The product retains certain crosslinking degree, so that the product is insensitive to low temperature and cannot be hardened in winter; the added slowly-recoverable polyether LR-00 is insensitive to temperature, so that the influence on the product due to the environmental temperature is low; during use, the halogen-free flame retardant slowly-recoverable memory foam can keep cool in summer and warm in winter; the comfortableness is greatly improved, and the slow recovery effect can be also improved.

Description

Halogen-free flameproof low resilience memory foam
Technical field
The present invention relates to sponge preparation field is and in particular to a kind of halogen-free flameproof low resilience memory foam.
Background technology
Low resilience memory foam is a kind of will not to be rebounded immediately by external force pressure deformation but delay several seconds time slow The sponge of reduction, it is soft, has significant low resilience ability, can absorb impulsive force, reduce vibrations, the release of low bounce-back power Ability is strong, and the article such as the medicated cushion made using slow-recovery sponge, medicated pillow, mattress can make one to feel more comfortable, natural.Sponge Product easily burns when running into naked light or red-hot flame, and low resilience memory foam is also such, once burning is just difficult to flutter Go out, the dense smoke of generation also has certain toxicity, fire-proof sponge adds fire retardant can play fireproof effect when prepared by sponge Fruit eliminates inflammable hidden danger, but the fire retardant that existing fire-proof sponge uses is contained within halogen, environment can be made after manufacture, discarding Become pollution.
Content of the invention
The invention discloses a kind of halogen-free flameproof low resilience memory foam, environment-friendly fireproof material, product itself is with the external world Temperature change is little, greatly improves the comfortableness of use.
Halogen-free flameproof low resilience memory foam, is made up of following raw materials by weight portion ratio:
Polyether polyol 1030 20-50 part
Polyether polyol 2000 4-10 part
MDI 23-56 part
Slow rebound polyether 8-20 part
White oil 8-20 part
Halogen-free flame retardants 9-24 part
Pore-creating agent 1.2-3 part
Amine catalyst 0.02-0.5 part
Silicone oil 0.3-0.9 part
The further improvement project of the present invention is that MDI is the MM5042 that Nanjing Chinese peaking work Materials Co., Ltd produces.
The further improvement project of the present invention is,:Described polyether polyol 1030 is produced by SKC Co., Ltd. of Korea S, polyethers Polyhydric alcohol 2000 is made tranquil Chemical Co., Ltd. by Shanghai gold and is produced.
The further improvement project of the present invention is, the LR-00 that described slow rebound polyether produces for Mitsui Chemicals, Inc..
The further improvement project of the present invention is that described halogen-free flame retardants produces for Zhejiang Wansheng Co., Ltd. HF560.
Compared to the prior art, the present invention has the following advantages:
The present invention adds 2000 a small amount of polyether polyol as sponge main body using 1030 polyether polyol, is equipped with MDI reaction, energy Enough make product keep certain degree of cross linking so that product insensitive to low temperature it is ensured that winter will not be hardening, the low resilience of addition Polyethers LR-00 has not response to temperature, makes product influenced by ambient temperature little, and during use, summer can keep feeling nice and cool, winter then can Enough feel warm, greatly improve and low resilience effect while comfortableness, can also be improved;The halogen-free flame retardants adding has high Fire resistance, without all kinds of harmful chemicals forbidden, using safety and environmental protection, makes sponge main body have the same of flameproof effect When, do not affect the low resilience effect of sponge main body itself.
Specific embodiment
Embodiment 1
Halogen-free flameproof low resilience memory foam, is made up of following raw materials by weight portion ratio:
1,030 20 parts of polyether polyol
2,000 4 parts of polyether polyol
23 parts of MDI
8 parts of slow rebound polyether
8 parts of white oil
9 parts of halogen-free flame retardants
1.2 parts of pore-creating agent
0.02 part of amine catalyst
0.3 part of silicone oil
Wherein, ethoxylated polyhydric alcohol 1030 is produced by SKC Co., Ltd. of Korea S;It is limited that polyether polyol 2000 makes tranquil chemistry by Shanghai gold Company produces;MDI is the MM5042 that Nanjing Chinese peaking work Materials Co., Ltd produces;Slow rebound polyether is given birth to for Mitsui Chemicals, Inc. The LR-00 producing;White oil is 2045 that Zhangjiagang Jia Yan Chemical Co., Ltd. produces;Halogen-free flame retardants is that Zhejiang ten thousand Sheng share is limited The HF560 that company produces, pore-creating agent is the KY1218 that Shenzhen Wei Hongxin Science and Technology Ltd. produces, and amine catalyst is BASF stock Part company produces to obtain A33.
Production technology is basically identical with existing production technology, specifically:
Each raw material is divided in different batch cans, adjusts each batch can temperature to 25 degree, equitemperature reaches standard, in foaming Input start foaming after above-mentioned formula number in computer on production line board, the foam sent out need to through room temperature 48 hours ripe Change can cut finished product.
The sponge made with the formula in the present embodiment through detection:Tensile strength 169mpa, rebound degree are 37.3%, pressure Sunken coefficient 2.09, low resilience effect is good;Average combustion coefficient 1.29mm/s (from fiery self-extinguishment), good flame retardation effect, 40 DEG C of hardness Value 7.3,0 DEG C of hardness number 14.5, the sensitivity of the temperature of more existing sponge substantially reduces, using more comfortable.
Embodiment 2
Halogen-free flameproof low resilience memory foam raw materials by weight portion ratio in this enforcement is as follows:
1,030 30 parts of polyether polyol
2,000 6 parts of polyether polyol
40 parts of MDI
15 parts of slow rebound polyether
15 parts of white oil
15 parts of halogen-free flame retardants
2 parts of pore-creating agent
0.2 part of amine catalyst
0.5 part of silicone oil
Other specification is same as Example 1.
Through detecting the sponge made using the formula in the present embodiment:Tensile strength 176mpa, rebound degree are 37.6%, Sag factor 2.09, low resilience effect is good;Average combustion coefficient 1.24mm/s (from fiery self-extinguishment), good flame retardation effect, 40 DEG C hard Angle value 7.8,0 DEG C of hardness number 12.1, the sensitivity of the temperature of more existing sponge substantially reduces, using more comfortable.
Embodiment 3
Halogen-free flameproof low resilience memory foam raw materials by weight portion ratio in this enforcement is as follows:
1,030 50 parts of polyether polyol
2,000 10 parts of polyether polyol
56 parts of MDI
20 parts of slow rebound polyether
20 parts of white oil
24 parts of halogen-free flame retardants
3 parts of pore-creating agent
0.5 part of amine catalyst
0.9 part of silicone oil
Other specification is same as Example 1.
Through detecting the sponge made using the formula in the present embodiment:Tensile strength 187mpa, rebound degree are 38.2%, Sag factor 2.07, low resilience effect is good;Average combustion coefficient 1.14mm/s (from fiery self-extinguishment), good flame retardation effect, 40 DEG C hard Angle value 7.5,0 DEG C of hardness number 12.1, the sensitivity of the temperature of more existing sponge substantially reduces, using more comfortable.

Claims (5)

1. halogen-free flameproof low resilience memory foam is it is characterised in that be made up of following raw materials by weight portion ratio:
Polyether polyol 1030 20-50 part
Polyether polyol 2000 4-10 part
MDI 23-56 part
Slow rebound polyether 8-20 part
White oil 8-20 part
Halogen-free flame retardants 9-24 part
Pore-creating agent 1.2-3 part
Amine catalyst 0.02-0.5 part
Silicone oil 0.3-0.9 part.
2. halogen-free flameproof low resilience memory foam according to claim 1 it is characterised in that:Described MDI is Nanjing Han Feng The MM5042 that chemical materialss company limited produces.
3. halogen-free flameproof low resilience memory foam according to claim 1 it is characterised in that:Described polyether polyol 1030 Produced by SKC Co., Ltd. of Korea S, polyether polyol 2000 is made tranquil Chemical Co., Ltd. by Shanghai gold and produced.
4. halogen-free flameproof low resilience memory foam according to claim 1 it is characterised in that:Described slow rebound polyether is three The LR-00 that well chemical company produces.
5. halogen-free flameproof low resilience memory foam according to claim 1 it is characterised in that:Described halogen-free flame retardants is Zhejiang The HF560 that Jiang Wansheng limited company produces.
CN201610771463.7A 2016-08-31 2016-08-31 Halogen-free flame retardant slowly-recoverable memory foam Pending CN106397726A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610771463.7A CN106397726A (en) 2016-08-31 2016-08-31 Halogen-free flame retardant slowly-recoverable memory foam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610771463.7A CN106397726A (en) 2016-08-31 2016-08-31 Halogen-free flame retardant slowly-recoverable memory foam

Publications (1)

Publication Number Publication Date
CN106397726A true CN106397726A (en) 2017-02-15

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Family Applications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118545A (en) * 2017-05-25 2017-09-01 德清舒华泡沫座椅有限公司 A kind of Slow-rebound polyether polyurethane sponge with anti-flaming function
CN109503791A (en) * 2018-10-18 2019-03-22 中山市宝龙海绵制品有限公司 A kind of halogen-free flameproof sponge and preparation method thereof
CN112159514A (en) * 2020-09-21 2021-01-01 东莞戎马家具有限公司 High-elasticity latex cotton for sofa and preparation method thereof
CN112239529A (en) * 2019-07-19 2021-01-19 巴中市天成高分子材料有限公司 Slow-resilience sponge and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101298490A (en) * 2008-06-13 2008-11-05 陈春潮 Memory foam and production method thereof
CN102643404A (en) * 2012-04-28 2012-08-22 德清舒华泡沫座椅有限公司 Slow-rebound polyether polyurethane sponge
CN103275294A (en) * 2013-06-05 2013-09-04 昆山中海工贸有限公司 Slow rebound sponge and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101298490A (en) * 2008-06-13 2008-11-05 陈春潮 Memory foam and production method thereof
CN102643404A (en) * 2012-04-28 2012-08-22 德清舒华泡沫座椅有限公司 Slow-rebound polyether polyurethane sponge
CN103275294A (en) * 2013-06-05 2013-09-04 昆山中海工贸有限公司 Slow rebound sponge and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118545A (en) * 2017-05-25 2017-09-01 德清舒华泡沫座椅有限公司 A kind of Slow-rebound polyether polyurethane sponge with anti-flaming function
CN109503791A (en) * 2018-10-18 2019-03-22 中山市宝龙海绵制品有限公司 A kind of halogen-free flameproof sponge and preparation method thereof
CN112239529A (en) * 2019-07-19 2021-01-19 巴中市天成高分子材料有限公司 Slow-resilience sponge and preparation process thereof
CN112159514A (en) * 2020-09-21 2021-01-01 东莞戎马家具有限公司 High-elasticity latex cotton for sofa and preparation method thereof

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Application publication date: 20170215